WO1998057905A1 - Aqueous suspensions of metakaolin and a method of producing cementitious compositions - Google Patents
Aqueous suspensions of metakaolin and a method of producing cementitious compositions Download PDFInfo
- Publication number
- WO1998057905A1 WO1998057905A1 PCT/GB1998/001758 GB9801758W WO9857905A1 WO 1998057905 A1 WO1998057905 A1 WO 1998057905A1 GB 9801758 W GB9801758 W GB 9801758W WO 9857905 A1 WO9857905 A1 WO 9857905A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- suspension
- metakaolin
- weight
- per cent
- production
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/10—Clay
- C04B14/106—Kaolin
Definitions
- Calcined kaolin pigments are used in low concentrations in aqueous suspensions in the paper industry. Such pigments are quite different in several respects from metakaolin to be used for the inorganic particulate material used in the compositions of the present invention. Such differences may be summarised as follows.
- Calcined kaolin pigments are produced by calcining kaolin at temperatures substantially greater than 1000°C, eg 1050°C to 1150°C. On cooling after calcining at these higher temperatures, recrystallisation in crystal phases quite different from the original occurs. Such pigments have no substantial pozzolanic activity and would not therefore be useful as additives for use in cementitious materials as described herein.
- Metakaolin when formed into an aqueous suspension by addition to water or an aqueous solution normally has a pH of between 6 and 7.
- the solids concentration (on a dry weight basis) of such a suspension is 40 per cent or more, especially 50 per cent or more, the viscosity of the suspension is unduly high, eg greater than 2000 mPa.s.
- the pH of the suspension is increased by addition of a basic substance the viscosity can be reduced to a level whereby the suspension is usable in applications similar to those in which silica fume suspensions are used.
- incorporation in the suspension of a thickening agent allows the suspension to retain a suitable stable, non-sedimenting form which benefits its suitability for transport to and use by a user.
- the pH of the suspension according to the first aspect of the present invention is in the range 7.5 to 9.5 especially in the range 8.5 to 9.0.
- the pH of the suspension may be adjusted by simple addition of a suitable alkali or base other than lime which does not substantially react with the metakaolin present.
- the alkali or base is preferably a material which is readily available commercially, has minimal effect on the end use of the aqueous suspension and gives suitable pH adjusting effect for minimum dose.
- the alkali or base may be selected from hydroxides and conjugate base salts of alkali metals, eg hydroxides, silicates, or carbonates of sodium or potassium. Sodium hydroxide in dry or solution form is preferred as pH adjuster.
- alkali or base added will depend upon the particular alkali or base used and its concentration. In general, active alkali amounts of much less than 1% are likely to be required to achieve the required pH. For example, to achieve a pH in the desired range 8.5 to 9.0, about 0.2% by weight of sodium hydroxide added in dry form is required (based on the dry weight of inorganic particulate material) .
- the aqueous suspension according to the first aspect of the present invention has a solids concentration of at least 40 per cent by weight, desirably at least 50 per cent by weight although it may be 60 per cent or more, based on the dry weight of solids (the inorganic particulate material) contained in the aqueous medium.
- the maximum solids concentration will be that at which the suspension is still a wet, flowable, stable slurry which may be determined by experimentation.
- the maximum solids concentration of the suspension may be about 65% by weight or in some cases even from 70% to 80% by weight.
- no sedimentation occurs in the suspension for at least two weeks after its preparation or, at least, if a limited degree of sedimentation occurs in this period, it is easily reworked, eg by simple mechanical agitation and/or pumping and/or mixing.
- the amount of thickening agent employed is such that no gellation occurs in the suspension for a period of at least two weeks or, at least, if a limited degree of gellation occurs it is easily broken down by simple mechanical agitation and/or pumping and/or mixing.
- Suitable thickening agents which may be incorporated in the aqueous suspension according to the first aspect to deter sedimentation (without substantial gellation) include materials known as thickening/gelling agents especially for use in aqueous media, eg selected from hydrophilic polymers such as polysaccharides, eg starches or gums, eg xanthan gum or guar gum, alginates, cellulose ethers, modified celluloses such as carboxy methyl cellulose and the like known to make an aqueous phase more viscous, absorbent clays such as attapulgite and smectite clays, eg bentonite, which absorb water and give a thickening (water-reducing) effect, ultrafine siliceous particulate materials, eg silica, which form a siliceous polymer in the aqueous phase thus increasing viscosity, particulate minerals, eg hydrotalcite, having a charged (cationic) mineral surface which interacts with particle surfaces of the
- suspensions or less over a reasonable period of time eg 7 days or more, often 10 days or more, eg two weeks or more, and can, as noted above, therefore be flowable and pumpable and can be stirred and/or mixed and conveniently transported and used as a flowable ready mixed additive for addition to cementitious or cement -forming materials and concrete- making compositions and the like.
- Such suspensions may advantageously be prepared and used without the use of added dispersing agents, although dispersing agents may optionally be employed if desired.
- the kaolin from which the metakaolin employed in the suspension according to the first aspect of the invention is produced is relatively pure, ie has an impurity metallic oxide content (ie other than Al 2 0) and Si0 2 ) of less than 10 weight per cent desirably less than 6 weight per cent with an alkali metal oxide content of less than 3 weight per cent .
- Such suspensions can be suitable for delivery to and use at a user site without the user encountering serious problems, eg substantial deposit of solid material at the base of the storage tank in which the delivered suspension is contained, the deposit being difficult to rehomogenise, or strong gellation giving difficulty in stirring or pumping.
- the aqueous suspension according to the first aspect of the present invention may show the following viscosity properties:
- the viscosity of the suspension is not greater than 1000 mPa . s over a one week period, preferably over a two week period, after makedown where the solids concentration of the suspension is at least 60 per cent by weight and is not greater than 700 mPa . s over a one week period, preferably over a two week period, after makedown where the solids concentration of the suspension is at least 50 per cent by weight.
- the suspension is made fluid by pH adjustment prior to addition of thickening agent.
- partial or complete pH adjustment may be made during or after addition of thickening agent.
- a preferred sequence of addition of ingredients to water, eg in an efficient mixer, is pH adjuster followed by metakaolin containing inorganic particulate material and then thickener.
- aqueous suspensions in accordance with the first aspect of the present invention provide excellent materials suitable for use in known applications for aqueous suspensions of pozzolanic particulate materials, eg as additives to cementitious compositions or as additives to alkali activators to form cements and cement-containing products.
- pozzolanic particulate materials eg as additives to cementitious compositions or as additives to alkali activators to form cements and cement-containing products.
- Pozzolanic particulate materials for additives to cementitious compositions or to form cements or cement products are preferred by users in some applications to be in slurry rather than dry form, eg because this offers ease of handling and ease of mixing.
- Such suspensions in accordance with the first aspect of the present invention can, as noted above, be produced in high solids form, eg having a solids content of 40 weight per cent or more, eg 50 per cent or more, and they can be flowable, pumpable, stirrable and transportable and can show no sedimentation and no or little gellation for at least ten days, even two weeks or more after preparation. Furthermore, they may be stable to excessive temperature variations, eg over the range -50°C to +100°C, and may show no substantial dilatancy of the particles of the inorganic particulate material in the suspension.
- the suspensions according to the first aspect of the present invention may be prepared more easily than known silica fume suspensions for use in the same applications.
- the suspensions according to the invention require thorough but less intensive mixing and show less tendency to produce aggregates or agglomerates than silica fume suspensions. This allows the suspensions according to the first aspect of the present invention to be used over a wider range of concentrations than those of silica fume to give a wider range of potential beneficial effects in cementitious compositions, cements and cement- containing products.
- Additives in the various known classes of materials incorporated in aqueous particulate suspensions for use by addition to cementitious compositions or formation of cements or cement- containing products may be incorporated in the suspension according to the first aspect.
- Such optional additives include, for example, (i) dispersing agents, eg water soluble polymers such as polycarboxylates, eg polyacrylic acids and their salts, lignosulphonate salts and sulphonated melamine or naphthalene formaldehydes and also alkali silicates; (ii) water repellents, eg stearates of calcium, zinc or aluminium or other chemicals with hydrophobic imparting properties;
- dispersing agents eg water soluble polymers such as polycarboxylates, eg polyacrylic acids and their salts, lignosulphonate salts and sulphonated melamine or naphthalene formaldehydes and also alkali silicates
- colouring agents eg pigments such as iron oxides
- shrinkage control agents eg., silicone oils
- fibres, whiskers, rods, strands, foils, beads and the like to play a part in the cementitious material produced from the suspension eg as a shrinkage control agent and/or as a tensile strength improver; such additives may be made of materials known for this application, eg fibres may be made of glass and/or thermoplastic materials, (viii) biocides.
- the metakaolin forms at least 70 per cent by weight, eg at least 85 per cent by weight of the particulate solids present in the suspension.
- suspensions according to the first aspect of the present invention may be employed in the same known applications as silica fume suspensions.
- the suspensions according to the first aspect of the present invention may be employed to form settable cementitious compositions in known materials incorporating hydraulic cements, eg for use in the following applications:
- the suspension according to the first aspect of the present invention may also be added to alkaline materials known as alkali activators to form hardenable cementitious compositions or cements.
- alkali activators are known per se in the art, eg for use to form alkali activated slags, and will in general be added in greater amounts than that previously added to establish the pH of the suspension to facilitate flowability etc. as described hereinbefore.
- the relative amounts by weight of metakaolin to alkali activator present in the cementitious composition formed may be in the range of from 1% to 99% especially 30% to 70%.
- the following materials are suitable for use as alkali activators for forming cementitious compositions in this way: hydroxides and conjugate base salts of alkali metals especially sodium and potassium hydroxide and sodium and potassium silicate .
- cementitious compositions formed by use of alkali activators may be employed in any of the applications as described hereinbefore (for compositions including an hydraulic cement) although the production of paving products, tiles and the like is likely to be a particularly suitable application for such compositions.
- the settable cementitious composition may incorporate other known optional additives, eg: (i) any of the additives specified above for optional addition to the aqueous suspension according to the first aspect of the present invention;
- chemicals to entrain air in cement or composites thereof to impart freeze-thaw resistance chemicals to entrain air in cement or composites thereof to impart freeze-thaw resistance
- Hardenable cementitious compositions eg concrete compositions, produced by addition of suspensions according to the first aspect of the present invention to cement or cement forming material, eg alkali activator, and optionally other ingredients, eg sand and aggregate to form concrete, show various advantages over those produced using known silica fume suspensions.
- the presence of aggregates and agglomerates in the composition can be avoided thereby avoiding the problems due to such aggregates and agglomerates described hereinbefore.
- the inorganic particulate material of the suspension according to the first aspect of the present invention may be incorporated at higher dose levels, eg up to about 25% on a dry weight basis of the settable cementitious composition to be prepared.
- the pozzolanic activity of metakaolin can be greater than that of silica fume and this allows better bonding into the settable cementitious composition thereby providing improved mechanical (compressive) strength when the composition eventually sets and hardens.
- the hardened material compared with materials formed from silica fume suspensions
- the hardened material can have a better capacity to resist chemical degradation. It can have a better capacity to resist ingress of contaminants such as chlorides because it can provide a hardened material having a more limited pore structure and it can also have an improved chemical resistance resulting from a better conversion of chemically reactive calcium hydroxide .
- Water may be added to the cement and/or alkali activator prior to and/or during and/or after addition of the said suspension to the hydraulic cement and/or alkali activator.
- the settable composition may, depending on the intended use, include further additives, eg ingredients and reinforcements etc. as described hereinbefore to form concrete or reinforced concrete .
- further additives eg ingredients and reinforcements etc. as described hereinbefore to form concrete or reinforced concrete .
- a slurry was prepared by addition of a metakaolin to a dilute (lime-free) solution of sodium hydroxide to give a solids content on a dry weight basis of 60 per cent .
- the metakaolin employed had the following properties :
- Example 2 A slurry S2 was produced in a manner similar to that given in Example 1 except that the metakaolin employed had the following properties:
- the final slurry S2 produced showed the following properties :
- Example 3 Samples of the slurry SI prepared in Example 1 were added to standard portland cement whereby 10% by weight and 20% by weight of the solids present respectively in the composition formed consisted of the metakaolin present. Water was added to give a standard consistency as determined by the well known VICAT test (BS EN 196-3:1995) thereby forming cement slurries CI and C2 respectively. Further cement slurries C3 and C4 respectively having the same compositions as CI and C2 were made using dry metakaolin instead of the slurries SI and S2. The initial setting time and the final setting time of each of the cement compositions CI to C4 was measured. The results obtained are given in Table 2 as follows:
- metakaolin form ie slurry or dry powder form, does not significantly affect the final setting time of the cement composition.
- Example 5 A sample C5a of cement composition C5 prepared as in Example 4 was cooled to a temperature of about -5°C and remained at this temperature for a period of 72 hours. The temperature of the sample was then allowed to rise naturally to ambient temperature (20°C) . The compressive strength and density after 7 hours and after 28 hours were measured. The results obtained are shown in Table 4 below.
- a further sample C5b of composition C5 prepared as in Example 4 was heated to a temperature of 90 °C for a period of 24 hours. The sample was then allowed to cool slowly to ambient temperature (20°C) . The same properties as measured for sample C5a were measured and the results are shown in Table 4 as follows.
- a metakaolin slurry was prepared as in Example 1.
- a silica fume slurry of known composition having the same solids concentration as the metakaolin slurry was also prepared for comparison.
- Various cement and concrete compositions were made from the silica fume slurry and separately from the metakaolin slurry (each composition formed from silica fume slurry having a corresponding composition formed from metakaolin slurry) , by adding the slurry in each case to portland cement forming 85 to 95 per cent by weight of the solids present in each case and water forming 50 per cent by dry weight of the solids present and thoroughly mixing the compositions produced.
- Example 6 to each concrete composition having the following properties: binder: metakaolin or silica fume (15% weight) plus portland cement; water: 50% by dry weight of binder; aggregate : present with the binder in an aggregate to binder weight ratio of 4.65 to 1.
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU82224/98A AU8222498A (en) | 1997-06-17 | 1998-06-16 | Aqueous suspensions of metakaolin and a method of producing cementitious compositions |
EP98932268A EP0991605A1 (en) | 1997-06-17 | 1998-06-16 | Aqueous suspensions of metakaolin and a method of producing cementitious compositions |
JP50396999A JP2002504882A (en) | 1997-06-17 | 1998-06-16 | Aqueous suspension of metakaolin and method for producing cement composition |
CA002294372A CA2294372A1 (en) | 1997-06-17 | 1998-06-16 | Aqueous suspensions of metakaolin and a method of producing cementitious compositions |
NO996245A NO996245L (en) | 1997-06-17 | 1999-12-16 | Aqueous suspensions of metakaolin and method of preparing cementitious compositions |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9712479.6A GB9712479D0 (en) | 1997-06-17 | 1997-06-17 | Aqueous suspensions of inorganic particulate materials |
GB9712479.6 | 1997-06-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998057905A1 true WO1998057905A1 (en) | 1998-12-23 |
Family
ID=10814219
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB1998/001758 WO1998057905A1 (en) | 1997-06-17 | 1998-06-16 | Aqueous suspensions of metakaolin and a method of producing cementitious compositions |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0991605A1 (en) |
JP (1) | JP2002504882A (en) |
CN (1) | CN1260769A (en) |
AU (1) | AU8222498A (en) |
CA (1) | CA2294372A1 (en) |
GB (1) | GB9712479D0 (en) |
NO (1) | NO996245L (en) |
WO (1) | WO1998057905A1 (en) |
ZA (1) | ZA985252B (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6027561A (en) * | 1999-04-12 | 2000-02-22 | Engelhard Corporation | Cement-based compositions |
WO2000050362A1 (en) * | 1999-02-22 | 2000-08-31 | Keele University | Cementitious compositions |
FR2815629A1 (en) * | 2000-10-25 | 2002-04-26 | Coatex Sas | Improving mechanical strength of hydraulic binder mix comprises adding mineral filler as aqueous dispersion containing ethylenic alkoxy-polyethylene glycol urethane copolymer |
FR2815627A1 (en) * | 2000-10-25 | 2002-04-26 | Coatex Sas | Improving mechanical strength of hydraulic binder mix comprises adding mineral filler as milled aqueous dispersion containing grinding aid |
WO2003078348A2 (en) * | 2002-03-19 | 2003-09-25 | Cdem Holland B.V. | Method of improving material comprising a pozzolanic component |
EP2145868A1 (en) * | 2008-07-18 | 2010-01-20 | Lafarge | Aqueous formulations |
WO2016059232A1 (en) * | 2014-10-17 | 2016-04-21 | Imerys Minerals Limited | Aluminosilicate |
Families Citing this family (5)
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CN100376641C (en) * | 2002-10-11 | 2008-03-26 | 董智才 | Efficient thickening agent of latex paint coating |
EP2634153A1 (en) * | 2012-02-28 | 2013-09-04 | Omya Development AG | Process for the preparation of cement, mortars, concrete compositions containing a calcium carbonate-based filler containing an aluminosiliceous material, the said "filler(s) blend" being treated with a superplastifier, cement compositions and cement products obtained, and their applications. |
CN104312558B (en) * | 2014-11-13 | 2017-03-08 | 中国海洋石油总公司 | Metakaolin waterborne suspension and its preparation method and application and reinforcing oil well cement mortar |
CN106519770A (en) * | 2015-09-14 | 2017-03-22 | 庄少玉 | Universal environment-friendly nano-powder |
CN107760090A (en) * | 2016-08-17 | 2018-03-06 | 庄少玉 | Seaweeds powder of lacquer putty for use on |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4793861A (en) * | 1986-07-10 | 1988-12-27 | Vetrotex Saint-Gobain | Glass reinforced compositions |
US4975396A (en) * | 1988-03-18 | 1990-12-04 | Vetrotex Saint-Gobain | Process for producing reinforced cementitious compositions and the products produced thereby |
US5420190A (en) * | 1990-11-29 | 1995-05-30 | Ecc International Limited | Paper coating |
-
1997
- 1997-06-17 GB GBGB9712479.6A patent/GB9712479D0/en not_active Ceased
-
1998
- 1998-06-16 JP JP50396999A patent/JP2002504882A/en active Pending
- 1998-06-16 CA CA002294372A patent/CA2294372A1/en not_active Abandoned
- 1998-06-16 AU AU82224/98A patent/AU8222498A/en not_active Abandoned
- 1998-06-16 EP EP98932268A patent/EP0991605A1/en not_active Withdrawn
- 1998-06-16 CN CN98806268A patent/CN1260769A/en active Pending
- 1998-06-16 WO PCT/GB1998/001758 patent/WO1998057905A1/en not_active Application Discontinuation
- 1998-06-17 ZA ZA985252A patent/ZA985252B/en unknown
-
1999
- 1999-12-16 NO NO996245A patent/NO996245L/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4793861A (en) * | 1986-07-10 | 1988-12-27 | Vetrotex Saint-Gobain | Glass reinforced compositions |
US4975396A (en) * | 1988-03-18 | 1990-12-04 | Vetrotex Saint-Gobain | Process for producing reinforced cementitious compositions and the products produced thereby |
US5420190A (en) * | 1990-11-29 | 1995-05-30 | Ecc International Limited | Paper coating |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000050362A1 (en) * | 1999-02-22 | 2000-08-31 | Keele University | Cementitious compositions |
EP1183217A4 (en) * | 1999-04-12 | 2005-08-10 | Engelhard Corp | Improved cement-based compositions |
EP1183217A1 (en) * | 1999-04-12 | 2002-03-06 | Engelhard Corporation | Improved cement-based compositions |
US6027561A (en) * | 1999-04-12 | 2000-02-22 | Engelhard Corporation | Cement-based compositions |
FR2815629A1 (en) * | 2000-10-25 | 2002-04-26 | Coatex Sas | Improving mechanical strength of hydraulic binder mix comprises adding mineral filler as aqueous dispersion containing ethylenic alkoxy-polyethylene glycol urethane copolymer |
EP1201625A1 (en) | 2000-10-25 | 2002-05-02 | Coatex S.A.S. | Process for increasing the mechanical strength of cement matrixes, in particular at early stages, cement matrixes thus obtained and their uses |
EP1201624A1 (en) * | 2000-10-25 | 2002-05-02 | Coatex S.A.S. | Process for increasing the mechanical strength of cement matrixes, in particular at early stages, cement matrixes thus obtained and their uses |
FR2815627A1 (en) * | 2000-10-25 | 2002-04-26 | Coatex Sas | Improving mechanical strength of hydraulic binder mix comprises adding mineral filler as milled aqueous dispersion containing grinding aid |
WO2003078348A2 (en) * | 2002-03-19 | 2003-09-25 | Cdem Holland B.V. | Method of improving material comprising a pozzolanic component |
WO2003078348A3 (en) * | 2002-03-19 | 2004-02-12 | Cdem Holland Bv | Method of improving material comprising a pozzolanic component |
US7438756B2 (en) | 2002-03-19 | 2008-10-21 | Minplus B.V. | Method of improving material comprising a pozzolanic component |
EP2145868A1 (en) * | 2008-07-18 | 2010-01-20 | Lafarge | Aqueous formulations |
WO2010007534A2 (en) * | 2008-07-18 | 2010-01-21 | Lafarge | Aqueous formulations |
WO2010007534A3 (en) * | 2008-07-18 | 2010-04-29 | Lafarge | Aqueous formulations |
WO2016059232A1 (en) * | 2014-10-17 | 2016-04-21 | Imerys Minerals Limited | Aluminosilicate |
Also Published As
Publication number | Publication date |
---|---|
GB9712479D0 (en) | 1997-08-20 |
EP0991605A1 (en) | 2000-04-12 |
JP2002504882A (en) | 2002-02-12 |
NO996245D0 (en) | 1999-12-16 |
NO996245L (en) | 2000-02-11 |
ZA985252B (en) | 1999-02-18 |
CA2294372A1 (en) | 1998-12-23 |
CN1260769A (en) | 2000-07-19 |
AU8222498A (en) | 1999-01-04 |
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