WO1998057541A1 - Dispositif d'apport de pesticides agricoles - Google Patents

Dispositif d'apport de pesticides agricoles Download PDF

Info

Publication number
WO1998057541A1
WO1998057541A1 PCT/EP1998/004007 EP9804007W WO9857541A1 WO 1998057541 A1 WO1998057541 A1 WO 1998057541A1 EP 9804007 W EP9804007 W EP 9804007W WO 9857541 A1 WO9857541 A1 WO 9857541A1
Authority
WO
WIPO (PCT)
Prior art keywords
film
plant
bag
outer layer
vegetal
Prior art date
Application number
PCT/EP1998/004007
Other languages
English (en)
Inventor
Juan Bocanegra
Jorge Cepeda
Glenn C. Knudsen
Original Assignee
Rhone Poulenc Agro
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Agro filed Critical Rhone Poulenc Agro
Priority to BR9810043-2A priority Critical patent/BR9810043A/pt
Priority to AU86306/98A priority patent/AU8630698A/en
Priority to EP98937556A priority patent/EP0989803A1/fr
Publication of WO1998057541A1 publication Critical patent/WO1998057541A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group

Definitions

  • the invention relates to a new delivery device suitable for pesticides, and especially for hazardous pesticides. This is also applicable to eg. plant nutrients and antibiotics.
  • An object of the instant invention is to provide a delivery device for pesticides, as well as a cultivation method, whereby contact between the pesticides and the workers is still further reduced, i.e. a cultivation method which reduces worker exposure to pesticides.
  • Another object of the instant invention is to provide a direct delivery device for pesticides to the plant, as well as a cultivation method, whereby the pesticide is easy to apply to the vegetal organism.
  • the advantage of the invention is to deliver the pesticide, premeasured, so as not to exceed the labeled rate.
  • Another object of the instant invention is to provide a direct delivery device for pesticides to the plant, as well as a cultivation method, which is simple and cheap, and which requires a very reduced amount of material for the application.
  • the present invention provides a device for the controlled and/or altered release delivery of pesticidal substances, contained in solid or gel compositions, to a plant which device comprises an outer layer of perforated plastics film having eg. several holes generally small in size and an inner water soluble or water dispersible film or bag within the said outer layer.
  • the solid or gel composition is such that it need not be diluted before use or application.
  • the device generally contains a pesticidal solid or gel composition.
  • the delivery of the active ingredient comprised in the composition is made gradually in a time generally extending over a period of time of up to 4 weeks. In practice the time should generally not exceed four weeks; however this may be more depending on products or mixtures contained in the device.
  • a banana plant may be cut, and the device inserted into the mother plant.
  • the device will release the active ingredient into the plant and this will then move into the daughter plant over a period of time.
  • the active ingredient does move into the daughter plant it can provide, for example, nematicide/insecticide protection to the plant over the next 180 days as it matures.
  • undesired residues of pesticide in the fruit of the banana plant at harvest may be avoided or reduced.
  • the instant invention provides a device
  • a container which container contains one dose of pesticidal composition which is not to be diluted before use or application and which is appropriate for, or suitable for, or designed to the treatment of one vegetal system.
  • the word vegetal in the instant specification designates a plant or a tree or any intermediate vegetal organism such as a bush or the like.
  • the solidity and/or rigidity of the container, when filled, of the instant invention is generally such that it does not substantially flex under pressure or under normal conditions. Flexing under pressure is not necessarily important but it must not burst under pressure in normal use before being put into a vegetal.
  • the device of the invention may resemble a Ketchup packet, or a very small pillow. It is generally made from flexible packaging films and filled on a machine used for flexible packaging materials. Thus, the packets are not completely rigid. The film is somewhat flexible so there is not the rigidity seen with eg. condiments that are packaged in foil wrap.
  • the instant invention provides a device having no space between the inner bag or film and the outer layer. Thus, there is no material such as active ingredients, adjuvant or carrier or the like in the space between the inner bag or film and the outer layer of plastic film.
  • the instant invention provides a device wherein the inner bag or film is adhering to the outer layer.
  • the instant invention provides a device wherein the inner bag or film is coated on the outer layer.
  • the instant invention provides a device wherein the inner bag or film is applied as an ink would be applied on the inside surface of the outer layer.
  • the ink-like water soluble or water dispersible material will seal off the small holes of the outer layer.
  • the size of the container may vary in a large range according to the size of the vegetal to be treated and according to the amount of pesticide which is to be delivered to the said vegetal.
  • the container is smaller than 50 ml, preferably smaller than 20 ml.
  • containers of the invention are from 1 to 6 cm wide and from 4 to 15 cm long.
  • Preferred containers are from 2 cm wide and 4 cm long to 5 cm wide and 15 cm long. More preferred is a container such as a bag about 4 cm wide and about 7 cm long.
  • the shape of the container may also vary in relation to the prescribed dose. Generally it may have a cylindrical, or cylinderlike shape in order to be able to be introduced easily in a soft plant, the section of the cylinder being not limited to a circle nor to a square or other polygonal form.
  • the term cylindrical shape indicates the general arrangement of the container, but some narrowing and/or some broadening of the cross section is possible. It may also be advantageous to have at least one extremity of the container having a conic shape. This general conic shape may have itself a round end, or a spike to aid in application to the vegetal.
  • the container may also resemble a Ketchup packet, or a very small pillow as mentioned above.
  • the shape of the container is advantageously such that the ratio longer size / smaller transverse size is in the range from 1 or 1.5 to 5, preferably 2 to 4.
  • the material which constitutes the inner film or bag may be any water dispersible or, preferably, water soluble polymer, such as PVOH, gelatin, starch, etc..
  • Polyvinyl alcohol (PVOH) is particularly preferred for its mechanical properties which work well from a handling and machinability view. It is also easily available and has outstanding odour barrier properties. In the future, new films suitable for use in the invention may also be developed.
  • said bag is generally closed by at least one water soluble heat seal.
  • the thickness of the walls of the inner water soluble bag or film may be determined to provide appropriate release of the pesticidally active ingredient in the vegetal. A thicker wall provides a slower release. A thinner wall may provide a quicker release.
  • the thickness is also important to influence the rate of solubility of a water soluble material constituting the inner film or bag.
  • the water solubility is generally such that the material constituting the inner water soluble film or bag may be dissolved at normal temperatures of cultivation of plants, that it is to say at temperature higher than 10°C, preferably higher than 15°C. It is not really necessary that the dissolving takes place rapidly in the plant. A lengthy dissolution due to a low solubility may be very convenient as providing a slower release of the pesticidal compound.
  • the plastics film constituting the outer layer of the device according to the invention comprises at least one polymeric material, including polymers and copolymers and is preferably water insoluble and optionally biodegradable.
  • a preferred polymer is polyethylene terephthlate (PET).
  • PET polyethylene terephthlate
  • the size and number of small holes is determined according to the desired delivery or release time. Preferably, the size of each small hole is from 0.025 to 0J25 cm (0.01 to 0.05 inches) and the number of small holes is at least 1 hole and no more than 25 per square cm of the plastics film surface. More holes can be used, for example up to 150, eg up to about 100. Holes are not necessarily identical as far as diameters are concerned.
  • the aim of the outer plastics film is also to prevent the inner film or bag being dissolved, for instance by the user, and to prevent individual packets from sticking together for example during storage..
  • the plastic film may be replaced by a degradable material, eg paper, such as tea bag paper, made generally from a type of banana tree pulp, which therefore will be very degradable in for instance a banana plant. In this case, it would not require any holes. If desired holes could, of course be formed, eg stamped, in it.
  • a degradable material eg paper, such as tea bag paper
  • the inner bag may be also such that it is separated by an additional plastics sheet (either PVOH or PET or, in general, a water insoluble, water dispersible or water soluble material) thus leading to an inner bag having two compartments each of which having one different pesticide inside.
  • the individual packet will therefore have a two cell unit that could hold two products.
  • one part of the bag may contain a fungicide (such as fosetyl-Al) and the other part an insecticide (such as aldicarb).
  • fungicide such as fosetyl-Al
  • insecticide such as aldicarb
  • the pesticidally active formulation which is contained in the container may be a solid or a gel.
  • solid formulations are preferred because they are more favourable in reducing the risk of exposure of the people who are handling or manufacturing the said compositions or formulations.
  • substantially dustless formulations for example those whose particle size is more than OJ mm, preferably from 0.4 to 8 mm.
  • the pesticidally active formulation which is contained in the device of the invention is preferably concentrated.
  • Pure pesticidally active ingredient may be used and enclosed in the device, but, it is often desired to have the said active ingredient or pesticide incorporated in an appropriate formulation which may help the dissolving inside the vegetal, and/or the spreading of the said ingredient in the whole vegetal. It may also be desirable to have a formulation which itself controls the release of the active ingredient in the vegetal. Concentrations higher than 15 % (w/w) are thus generally used. Preferably the concentrations of these formulations are even higher than 20 % or even better, higher than 40 %.
  • the main criterion is the water solubility of the pesticide rather than the concentration of the pesticide.
  • the release would not be intentionally delayed because there is only a short period of time before the mother plant will begin to die and as it dies, the ability to transfer the pesticide, as desired to the daughter plant will decrease. Fast release and transfer is desired. A phytotoxic response at this time is not a great concern since the mother plant has already been harvested and the release of the pesticide to the daughter plant will be somewhat gradual.
  • the instant invention provides a delivery device as already defined which contains one or more pesticides which are naturally toxic at low dose for mammals, and/or which are at least partially soluble in water.
  • the instant invention provides a delivery device wherein the active ingredient, or pesticidal substance, of the solid or gel composition is systemic.
  • systemic is meant that the active ingredient is able to use the natural flow of material in the plant in order to move inside said plant.
  • the active ingredient is aldicarb.
  • the composition is a composition comprising aldicarb and gypsum.
  • aldicarb is adsorbed on gypsum.
  • other aldicarb formulations are suitable, such as aldicarb adsorbed on corn cob grits.
  • the invention provides a method of treating a plant with a pesticide which method comprises inserting into a plant a device according to the invention.
  • the device may, for example, be inserted into a hole cut or bored into the plant.
  • the instant invention provides a method for vegetal cultivation, in which the said vegetal contains a soft part and at least one device as defined above is inserted into the vegetal by pressure and/or in a hole previously made in, eg bored or cut in the vegetal, eg the mother trunk in the case of a banana.
  • the inner film or bag of the device is sufficiently dissolved so as to release the pesticide included therein directly inside the vegetal.
  • the vegetal is soft enough so as to make possible the introduction of the said container inside the said vegetal without a substantial damage to the said plant.
  • the method of the instant invention is especially suitable for banana or plantain trees, especially banana or plantain trees which have been cut after harvesting.
  • the place of cutting is generally rather soft and well suited to the introduction of a delivery device therein.
  • the introduction of the delivery device inside a banana plant then protects the next generation of plant which grows from the bottom of the said cut mother plant.
  • Other plants or trees may of course be treated, eg date palms. Due to the controlled release which can be obtained by variation of different characteristics of the container as indicated hereabove, it is possible to have a variable release rate in the tree from very slow to a rapid release of product.
  • the method may involve more than one device per plant. Each device may be at separate locations in the plant, eg in bored or cut holes.
  • one or more device as described above may be inserted by pressure and/or in a hole previously bored in the daughter trunk of a plant.
  • the pesticide of the instant invention may be for example a herbicide, a fungicide, a nematocide, a bactericide, an antibiotic, a plant growth regulator or plant nutrient or an insecticide or combination thereof.
  • the invention is especially advantageous for pesticides having high acute or chronic toxicity for mammals at certain rates and in certain conditions.
  • the invention is especially of interest for insecticides / nematocides.
  • Pesticides which are well suited for use in the invention have some water solubility and systemic activity so as to be able to move inside the vegetal.
  • examples include methyl carbamates, such as aldicarb ; the 1-arylpyrazoles such as fipronil ; imidacloprid ; fosetyl-Al ; carbofuran ; benomyl ; terbufos ; oxamyl ; fosthiazate ; these active ingredients being well known to persons skilled in the art.
  • One of the advantages of the device and method of the invention is illustrated by its use to deliver aldicarb to bananas: it minimizes the residue of aldicarb in the banana plant and contamination of the surrounding soil (more than 99% of the active ingredient goes into the plant and substantially no aldicarb goes into the soil). Therefore less material is needed and the speed of absorption by the plant is greatly accelerated.
  • the aldicarb flows from a mother plant to a daughter plant without being applied to the soil or to the daughter plant directly. This limits the contamination of the soil by aldicarb and provides thus a safe and novel method of applying aldicarb to the new plant. It may be that a minimal amount of aldicarb may leave the plant through root exudates. Substantially no pesticide is expected to be released into the soil.
  • aldicarb (as Temik TM GG 15 % w/w on gypsum granules) were placed in a packet that is approximately 8 cm long by 3 cm wide and 1.5 cm thick.
  • This packet was made of water soluble polyvinyl alcohol.
  • the packet was filled and then sealed using a high temperature seaFer.
  • This water soluble packet was itself put in a second packet made of a plastic film with several small size (about 0.075 cm (0.03 inches)) holes.
  • the outer plastic packet is a little larger than the inner polyvinyl alcohol packet so as to enclose it without further substantial freedom of movement.
  • the packet was placed into a freshly cut banana plant and left for about a week, after which time the granules were recovered.
  • the percentage of aldicarb left on the granules was less than 2% by weight.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Dispositif permettant la libération régulée et/ou modifiée de substances pesticides qui sont contenues dans des compositions solides ou sous forme de gel et destinées à être apportées à des plantes. Ledit dispositif comporte un film ou sachet interne soluble ou dispersible dans l'eau, qui contient la composition, et une couche protectrice externe qui permet la libération de la substance pesticide lors de l'utilisation.
PCT/EP1998/004007 1997-06-16 1998-06-12 Dispositif d'apport de pesticides agricoles WO1998057541A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
BR9810043-2A BR9810043A (pt) 1997-06-16 1998-06-12 Dispositivo para a liberação controlada e/ou alterada de substáncias pesticidas contidas em composições sólidas ou em gel para suprimento a uma planta, e, processo para o tratamento de um vegetal com um pesticida
AU86306/98A AU8630698A (en) 1997-06-16 1998-06-12 Delivery device for agricultural pesticides
EP98937556A EP0989803A1 (fr) 1997-06-16 1998-06-12 Dispositif d'apport de pesticides agricoles

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US4976697P 1997-06-16 1997-06-16
US60/049,766 1997-06-16

Publications (1)

Publication Number Publication Date
WO1998057541A1 true WO1998057541A1 (fr) 1998-12-23

Family

ID=21961611

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1998/004007 WO1998057541A1 (fr) 1997-06-16 1998-06-12 Dispositif d'apport de pesticides agricoles

Country Status (12)

Country Link
EP (1) EP0989803A1 (fr)
AU (1) AU8630698A (fr)
BR (1) BR9810043A (fr)
CO (1) CO4810377A1 (fr)
HN (1) HN1998000097A (fr)
ID (1) ID24517A (fr)
OA (1) OA11609A (fr)
PA (1) PA8453701A1 (fr)
PE (1) PE100899A1 (fr)
SV (1) SV1998000068A (fr)
WO (1) WO1998057541A1 (fr)
ZA (1) ZA985185B (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001013719A2 (fr) * 1999-08-19 2001-03-01 Aventis Cropscience S.A. Nouveau dispositif
CN114271272A (zh) * 2022-01-21 2022-04-05 李汉承 一种农药凝珠及其制备方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3001549C (fr) 2016-04-13 2019-04-30 Monosol, Llc Film hydrosoluble, paquets utilisant ce film et leurs procedes de fabrication et d'utilisation
EP3468885A1 (fr) 2016-06-13 2019-04-17 Monosol, LLC Utilisation d'un article à dose unitaire hydrosoluble pour améliorer l'expérience de dosage de l'utilisateur
WO2017218402A1 (fr) 2016-06-13 2017-12-21 Monosol, Llc Articles solubles dans l'eau en doses unitaires formés à partir d'une combinaison de films différents
EP3468888A1 (fr) 2016-06-13 2019-04-17 Monosol, LLC Emballages hydrosolubles
MX2018015442A (es) 2016-06-13 2019-09-13 Monosol Llc Articulos de dosis unitaria solubles en agua hechos de una combinacion de diferentes peliculas.
US10907117B2 (en) 2016-06-13 2021-02-02 Monosol, Llc Use of a first film and a second film to improve seal strength of a water-soluble unit dose article
CN109863237A (zh) 2016-10-27 2019-06-07 蒙诺苏尔有限公司 具有低摩擦系数的水溶性膜
AU2019262762B2 (en) 2018-05-02 2024-06-13 Monosol, Llc Water-soluble polyvinyl alcohol blend film, related methods, and related articles
WO2019212723A1 (fr) 2018-05-02 2019-11-07 Monosol, Llc Film à base de mélange de d'alcool polyvinylique soluble dans l'eau, procédés associés et articles associés
JP7443360B2 (ja) 2018-10-26 2024-03-05 モノソル リミテッド ライアビリティ カンパニー 多層水分散性物品
BR112021021216A2 (pt) 2019-04-24 2022-01-04 Monosol Llc Artigo não tecido dispersível em água para acondicionamento de dose unitária
BR112022007571A2 (pt) 2019-10-25 2022-07-05 Monosol Llc Artigos multicamadas dispersíveis em água
AU2021285853A1 (en) 2020-06-02 2023-01-05 Monosol, Llc Water soluble fibers with post process modifications and articles containing same
EP4015568A1 (fr) 2020-12-15 2022-06-22 Monosol, LLC Films solubles dans l'eau, articles de dose unitaire solubles dans l'eau et leurs procédés de fabrication et d'utilisation
EP4015567A1 (fr) 2020-12-15 2022-06-22 Monosol, LLC Films solubles dans l'eau, articles de dose unitaire solubles dans l'eau et leurs procédés de fabrication et d'utilisation
US20230250246A1 (en) 2022-02-04 2023-08-10 Monosol, Llc High Clarity Water-Soluble Films and Methods of Making Same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1535854A (en) * 1975-03-05 1978-12-13 Barnes D Soil nutrient pack
DE4113786A1 (de) * 1990-05-02 1991-11-07 Rhone Poulenc Agriculture Folienbehaelter zur aufbewahrung von chemikalien
WO1993022215A1 (fr) * 1992-04-27 1993-11-11 Rhone Poulenc Agrochimie Emballage pour compositions toxiques

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1535854A (en) * 1975-03-05 1978-12-13 Barnes D Soil nutrient pack
DE4113786A1 (de) * 1990-05-02 1991-11-07 Rhone Poulenc Agriculture Folienbehaelter zur aufbewahrung von chemikalien
WO1993022215A1 (fr) * 1992-04-27 1993-11-11 Rhone Poulenc Agrochimie Emballage pour compositions toxiques

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001013719A2 (fr) * 1999-08-19 2001-03-01 Aventis Cropscience S.A. Nouveau dispositif
WO2001013719A3 (fr) * 1999-08-19 2002-09-26 Aventis Cropscience Sa Nouveau dispositif
CN114271272A (zh) * 2022-01-21 2022-04-05 李汉承 一种农药凝珠及其制备方法

Also Published As

Publication number Publication date
CO4810377A1 (es) 1999-06-30
AU8630698A (en) 1999-01-04
PE100899A1 (es) 1999-10-15
EP0989803A1 (fr) 2000-04-05
ZA985185B (en) 1999-02-08
HN1998000097A (es) 2000-03-24
PA8453701A1 (es) 2000-05-24
BR9810043A (pt) 2000-08-29
ID24517A (id) 2000-07-20
OA11609A (en) 2004-08-12
SV1998000068A (es) 1998-09-25

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