WO1998055402A1 - Verfahren und vorrichtung zur behandlung von abwässern - Google Patents
Verfahren und vorrichtung zur behandlung von abwässern Download PDFInfo
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- WO1998055402A1 WO1998055402A1 PCT/EP1998/003316 EP9803316W WO9855402A1 WO 1998055402 A1 WO1998055402 A1 WO 1998055402A1 EP 9803316 W EP9803316 W EP 9803316W WO 9855402 A1 WO9855402 A1 WO 9855402A1
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F7/00—Fertilisers from waste water, sewage sludge, sea slime, ooze or similar masses
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F3/00—Fertilisers from human or animal excrements, e.g. manure
- C05F3/04—Fertilisers from human or animal excrements, e.g. manure from human faecal masses
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/24—Treatment of water, waste water, or sewage by flotation
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/002—Grey water, e.g. from clothes washers, showers or dishwashers
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/005—Black water originating from toilets
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/28—Anaerobic digestion processes
- C02F3/286—Anaerobic digestion processes including two or more steps
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
- Y02A20/131—Reverse-osmosis
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Definitions
- the present invention relates to a method for recycling wastewater, which comprises the separate detection of gray water and / or black water and the membrane filtration of the separately recorded gray water and / or the solid / liquid separation of the separately recorded black water.
- the present invention preferably relates to a method for producing drinking water from gray water or one or more of its substreams.
- a device for producing drinking water from gray water and a device for recycling black water and their use are described.
- the method presented here involves treatment and recycling of the separately recorded wastewater individual flows, gray water and black water, which can preferably be subdivided again into faecal wastewater and urine wastewater and recorded separately in order to provide a prerequisite for highly efficient water management for areas with water problems.
- the method is preferably based on the separate discharge of black and gray water and also preferably on the use of water-saving toilets.
- the gray water can be used to produce drinking water.
- a separate pretreatment of individual gray water partial flows and their use for drinking water production is possible.
- One point of the procedure here is to use the sea water desalination plants that are often found in these areas in gray water treatment.
- the desalination plant achieves a strong reduction in osmotic pressure.
- the basic idea of the method is to maximize the concentration of mineral fertilizers in the effluent of waste water treatment plants by means of an open liquid cycle by collecting the waste water together with the organic waste fraction.
- the nutrients of the urine wastewater can be recorded separately with separate toilets and urinals and applied anaerobically.
- the black or faecal wastewater is oxidized until nitrification and reused for flushing the toilets and urinals, and is therefore only used as a transport medium in which the nutrients can be concentrated and removed.
- nitrate can be used as a flotation aid for the solids in the abaerobic first solid / liquid separation. In the case of composting, there is another cycle.
- this liquid cycle begins with the completion of an aerobic wastewater treatment stage.
- the nutrients released by composting are thereby rinsed out and concentrated by supplying the irrigation water to the aerobic treatment stage in the wastewater treatment plant.
- Suitable measures to largely prevent denitrification can also be taken, depending on the process variant.
- the theoretically smallest drain volume of approx. 2 l / (PE * d) and the possible drying of the mineralized nutrients enables problem-free handling and the odor-free return of the nutrients to the nutrient cycle.
- the organic waste is processed together with the resulting sludge to produce biogas and compost.
- the input substrates are the input substrates.
- Wastewater and wastewater are the sum parameters for all types of wastewater streams of industrial or domestic origin.
- the following individual wastewater flows are of particular interest here:
- Faecal wastewater is defined as wastewater contaminated with faeces (e.g. from the faecal waste from urine separation toilets), although similar wastewater from other sources can also be mixed in here.
- Urine wastewater is defined as only urine-contaminated waste water from all types of urinals and / or the urine-contaminated outlet of the urine separation toilets, whereby similar wastewater from other sources can also be admixed in terms of its composition.
- Black water is defined as urine and faecal contaminated wastewater, for example from all types of toilets and urinals.
- Urine and / or faecal waste water can be derived and collected in a separate line network.
- the black water and / or its partial flows of urine and faecal waste water can also be recorded in gushes in common drainage networks and treated separately.
- other wastewater can be added from agriculture (e.g. pig manure) and / or other sources.
- Greywater is defined as domestic wastewater and / or other similarly composed wastewater from laundries and / or other sources that is not, or almost not, urine and / or faecal contaminated, that can be collected with one or more separate drainage networks. It can be divided into several gray water sub-streams based on origin and / or composition.
- the gray water can be composed of all conceivable combinations of all conceivable numbers of domestic and similar wastewater sources, but must not contain black water (faeces and / or urine), whereby a faecal and / or urine wastewater portion added to one or more sub-streams of the gray water does nothing to this definition changes.
- Toilets are the generic term for all types of toilets. Toilets with water flow can be divided into flush toilets and water-saving toilets.
- Flush toilets are normal, commercially available toilets that can also be equipped with water-saving devices (e.g. water-saving button).
- Water-saving toilets are highly water-saving special designs, such as Vacuum toilets, urine separation toilets, etc.
- Urinals are all types of separated urine outlets with or without water flushing, e.g. simple channels, urinals with individual or automatic water flushing, water-free urinals, etc.
- Organic waste is defined as solid, biodegradable waste that can also contain biologically inert components.
- Carbon is defined here as all organic carbon compounds (COD & BOD) that can be contained in black and gray water as well as in organic waste. Carbonates can also be meant analogously.
- Nitrogen is defined here as all organic and inorganic nitrogen compounds that can be contained in black and gray water as well as in organic waste.
- Phosphorus is defined here as all organic and inorganic phosphorus compounds that can be contained in black and gray water as well as in organic waste.
- Filtration includes all coarse and / or fine sieve, filtration and / or membrane (filtration) processes that can be used in wastewater treatment and drinking water treatment. This includes all filtration and / or membrane processes known to the person skilled in the art, e.g. Ultra or microfiltration as e.g. in the ATV volumes, Ulmann's encyclopedia and other specialist literature as well as specialist journals such as Correspondence sewage, etc. are described, and / or are available on the market. Process-supporting additives can also be added.
- Solid / liquid separation encompasses all suitable (e.g. hydrocyclone processes are not suitable for solid / liquid separation in larger connection large) separation processes of liquid and solid substances that can be used in domestic wastewater treatment and drinking water treatment, e.g. sedimentation.
- all types of filtration processes such as reverse osmosis and / or other membrane processes can also be used for solid / liquid separation.
- Process-supporting additives can also be added.
- Fixed bed processes include all processes in which microorganisms grow sessily on a fixed and / or mobile matrix, e.g. Trickling filter, immersion drip and disc immersion filter, all types of floor filters, floating bed processes, sand filters, plant clarification processes, etc. This includes all processes known to the person skilled in the art, such as those e.g. in the ATV volumes, Uhlmann's encyclopedia and other specialist literature as well as specialist journals, e.g. Correspondence sewage, etc. are described, and / or are available on the market. Process-supporting additives can also be added.
- Activation processes include all processes in which microorganisms float freely in the liquid to be treated, such as activated sludge processes, SBR plants, etc. These include all oxidation processes known to the person skilled in the art Microorganisms such as those described in the ATV volumes, Uhlmann's encyclopedia and other specialist literature as well as specialist journals such as waste water correspondence, etc., and / or are available on the market. Process-supporting additives can also be added.
- Oxidation by microorganisms, aerobic treatment stage and wet oxidation have the same meaning in the sense of this invention and are the generic term of oxidative fixed bed and revitalization processes and also other near-date processes. This includes all methods known to those skilled in the art, such as oxidation by microorganisms, e.g. in the ATV volumes, Ulmann's encyclopedia and other specialist literature as well as specialist journals such as Correspondence sewage, etc. are described, and / or are available on the market. Process-supporting additives can also be added.
- Carbon removal includes all methods of removing carbon from a liquid. This includes all methods known to those skilled in the art, such as Oxidation by microorganisms, e.g. Adsorption processes, e.g. Precipitation process and e.g. chemical oxidation processes, etc., e.g. in the ATV volumes and other specialist literature as well as specialist magazines, e.g. Correspondence sewage, etc. are described, and / or are available on the market.
- partial wastewater stream is used synonymously with partial stream.
- Table 1 summarizes the approximate distribution of the ingredients from black and gray water.
- the black and gray water columns show the percentage distribution of the wastewater constituents:
- Table 1 The values given in Table 1 are maximum values that can vary in individual cases. There are still too few confirmed surveys. Table 1 shows how little it makes sense to mix black and gray water. If there is a lack of nutrients in the gray water or in any combination of gray water partial flows, a part of the oxidized nutrients of the black water can be added to completely decompose the carbon.
- Table 2 shows the sources from which the individual material loads result:
- Table 2 shows the different loads of carbon, nitrogen and phosphorus from the gray water, faeces and urine sources.
- Black water Waste water from toilets and urinals is referred to as black water, as mentioned above. It is made up of feces, urine and water. In urine, over 80% of the daily nitrogen produced by humans (urea) is dissolved in water. Approximately 50% of the daily human-produced carbon and over 50% of the phosphorus and 10% of the nitrogen can be found in the feces in solid form. Almost the entire range of impurities can be found here: carbon, phosphorus and potassium mainly in the faeces, nitrogen mainly in the urine. Black water also contains pathogenic bacteria from the human intestinal tract (one speaks of coliform bacteria). The bacteria in the settled sludge can be completely destroyed by subsequent fermentation and composting, and those in the water must be sterilized.
- the amount of black water corresponds to about 30% of the total domestic wastewater, but this amount can be reduced to less than 15% by choosing suitable water-saving toilets.
- the construction costs and operating costs of the process can be drastically reduced by separating the black water, but a second sewer network has to be installed. However, since it can be laid in parallel with the sewer network to be installed anyway, only the pipe costs and minor additional costs for the construction of the pipeline network are added.
- faeces and organic waste consist of the substances that also make up life: mainly carbon (C), oxygen (O), hydrogen (H), nitrogen (N), sulfur (S) and phosphorus (P), but also the whole range of trace elements, such as Potassium (K).
- C carbon
- O oxygen
- H hydrogen
- N nitrogen
- S sulfur
- P phosphorus
- K Potassium
- the compositions vary depending on eating habits and / or economic circumstances. Mainly carbon, nitrogen and phosphorus are environmentally relevant for water pollution. They are energy-intensive and they are removed from the water with conventional sewage treatment plants for expensive money.
- Carbon is biologically converted into CO 2 in water together with oxygen by bacteria, so a lot of oxygen is consumed in the process.
- One of the consequences of this is that the fish suffocate in the water. Plants can take up the resulting CO 2 from the air and use it again. So carbon is not a fertilizer. Nitrogen, phosphorus and potassium are deficient factors for the growth of plants and thus the main components of fertilizer. Potassium is environmentally neutral in water, while nitrogen and phosphorus in wastewater can lead to explosive algae growth. Algae are also plants, so they also absorb the carbon from the air, and in the presence of nutrients lead to an accumulation of carbon in the water, which leads to the development of catabolic food chains and to a strong consumption of oxygen in the water and thus to the death of the fish. It is then said that a body of water "tilts over" or "eutrophises”.
- the nutrients When applied in agriculture, the nutrients are suitable fertilizers.
- Commercial mineral fertilizers include saltpetre (KNO 3 ) and phosphate (PO 4 ). Exactly these substances are produced by the process and can be returned to production in dissolved or solid form.
- Greywater is the wastewater from all other domestic sources (see definitions above) such as showers, sinks, washing machines, kitchen wastewater, etc.
- the greywater is practically nitrogen and phosphorus free; it can therefore be cleaned up to the highest quality with relatively little effort.
- the wastewater from dishwashers is generally classified as gray water, but should be fed into black water due to the composition of the pollution.
- gray water The pollution of the gray water is low compared to that of the black water and can be cleaned with relatively little effort.
- gray water there are only very slight traces of nitrogen contamination and it is also considered to be practically phosphate-free, since washing is mainly carried out with phosphate-free detergents.
- Greywater represents the largest amount with approx. 70% - 80% of the daily wastewater and is particularly suitable for recycling for the following reasons:
- sewage treatment plants that treat wastewater, i.e. remove the wastewater constituents at a high price and send the purified water to the sea via rivers. This water is thus salted and withdrawn from the fresh water cycle.
- the drinking water is e.g. obtained from desalination plants in arid areas where the process presented here offers a cost-effective alternative.
- the prior art comprises a pure flow management and essentially has the following disadvantageous properties: 1. Mixing of different types of waste water from commerce, industry and households.
- the black water is transferred to a compensation tank for volume compensation. After heating and a subsequent solid / liquid separation, the black water is diluted 1:20 with fresh water and subjected to an activated sludge process. b) Anaerobic treatment (anaerobic digestion process)
- the black water is treated aerobically after coarse material removal and volume equalization, and after a subsequent solid / liquid separation, the black water is diluted 1:20 with fresh water and subjected to an activated sludge process.
- Two-stage activated sludge process Two-stage activated sludge process
- the black water is diluted 1:10 with water after coarse material removal and volume equalization and treated in the first activated sludge process. After a subsequent solid / liquid separation, the black water is again diluted 1:10 with fresh water and subjected to a second activated sludge process.
- gray water treatment allows its recycling as rinsing water for toilets and urinals.
- the invention thus relates to a method for recycling waste water, which comprises the following steps:
- the method for producing drinking water from gray water or one or more of its substreams comprises the following steps:
- the membrane filtration is carried out by means of reverse osmosis or ultra or microfiltration.
- desalination is connected to the ultra or microfiltration.
- membranes with a pore size of up to a maximum of 2 ⁇ m are used for ultra or microfiltration.
- membranes with a pore size of up to 0.2 ⁇ m are used for ultra or microfiltration.
- one or more mechanical, physical and / or chemical cleaning steps are connected upstream of (b).
- the process according to (a) comprises the following steps:
- a solid / liquid separation is carried out after step (ii).
- the solid / liquid separation is carried out by means of flotation, sedimentation, filtration or precipitation.
- the carbon removal is carried out by means of oxidation by microorganisms.
- the method according to (b) comprises the following step:
- the sanitization is chlorination.
- the utilization of black water comprises the following steps:
- the black water is collected separately in faecal and urine waste water, and the faecal waste water is treated in accordance with steps (a) to (f).
- At least part of the urine waste water is added to the faecal waste water before (c).
- Another particularly preferred embodiment of the invention is the solid-liquid separation in (d) a filtration.
- the solid / liquid separation in (b) is sedimentation or filtration.
- the product from (d) is temporarily stored in a store and, if the power requirement is increased, is fed back to the oxidation device while increasing the air supply.
- the oxidized black water and / or faecal waste water is subjected to a sanitation and / or a change in the water structure before being recycled.
- the solids are removed from the urine waste water by filtration.
- the solids from gray water and / or black water and / or faecal waste water are subjected to one or two-stage anaerobic digestion together with or without comminuted organic waste.
- the drinking water is filled into containers.
- the mineral fertilizer and / or the compost is filled into containers.
- the invention further relates to a device for performing the invention
- a method comprising a reactor in which steps (b), (c) and (d) are carried out.
- the device according to the invention comprises membranes, as set out above, also a stirrer, an aerator, a floating sludge vent and optionally further
- the device comprises a separation device in which the method steps characterized in the method according to the invention are carried out. Furthermore, the invention relates to the use of the device according to the invention for recycling black water.
- the invention relates to the use of the device according to the invention for producing drinking water from gray water.
- Figure 1 shows the black water and organic waste module.
- the black water cycle is shown here with or without urine waste water.
- the gearing with the organic waste treatment is shown here, the treatment of the organic waste being a preferred embodiment of the method according to the invention.
- Figure 2 shows the gray water module and its return for reuse.
- An important process step is the treatment of the gray water and one or more of its partial streams in a desalination plant.
- the desalination plant can be used multifunctionally due to the low osmotic pressure.
- Process step 2d shows the optional interlocking with the organic waste module.
- Figure 3 shows the cycle of nutrients between seizure and recovery. In particular, the cycle of the compost water and the achievable concentration of nutrients is shown here.
- Figure 4 shows an example of a possible compact design of the device according to the invention of the black water module.
- an active sludge store is shown here, which allows the entire module to be flexibly adapted to the quantity and freight daily rate curve of a hotel or settlement, etc.
- Figure 5 shows an example of the black water circuit in the embodiment of this compact black water module.
- this new drainage network to be installed should be easy to implement in addition to the existing one in the course of a renovation or a new building in the supply shafts, with appropriate planning also in ongoing hotel operations.
- Sewerage networks and sewage treatment plants are only partially available in European tourist areas, which are, however, completely overloaded by the constantly growing tourism.
- Example 1 Possibility of implementing the method in an infrastructure with a central sewage treatment plant and sewer network
- the existing sewer network can be used for collection and the sewage treatment plant for treating the gray water.
- the black water from toilets and urinals is suspended from the central network and collected in small decentralized networks and processed and returned in black water modules.
- Greywater recycling significantly increases the capacity of the existing wastewater treatment plant; Overloading is avoided and a good drainage quality is guaranteed.
- Example 2 Possibility of implementing the process in an infrastructure without a central sewage treatment plant and sewer network
- FIG. 1 The black water and organic waste module
- the method and the device are preferably to be accommodated as a compact module in basements of single or multi-family houses, and thus make the installation of sewers completely unnecessary.
- the method is preferably based on the separate discharge of black and gray water and also preferably on the use of water-saving toilets.
- the processed waste water and / or preferably black water can be applied to green areas after possible sanitation or disinfection and / or supplied to the ground water.
- the black water and organic waste modules are closely interlinked; therefore a common description seems appropriate.
- the dashed process arrows or borders in FIG. 1 represent options or process variants.
- the method is preferably used from a connection size of more than 20 toilets.
- the aim of this partial flow process is the production of mineral fertilizer, compost and biogas from black water.
- the most important core point of the process is the circulation of the black water between toilets, solid / liquid separation, oxidation (oxidation by microorganisms and / or carbon removal) and solid / liquid separation.
- the nutrient loads can be concentrated as desired, so that the volume in which the nutrient loads are dissolved is very small.
- Another characteristic of the partial flow process is the solid-liquid separation of the black water and the black water cycle for compost water, all of which are explained in the following process steps with reference to Fig. 1.
- the numbers in this description correspond to the numbered method steps in FIG. 1.
- Process steps (1) to (6) show the black water cycle with oxidative nutrient production without the use of separation toilets (thick arrows).
- Process step (7) shows the exit of the oxidized liquid fertilizer.
- process steps (1) to (6) show the fecal water cycle.
- Process step (la) shows the urine output of the separation toilet. In this case, process step (lb) is omitted.
- Process steps (la), (8), and (8a) show the process using urine separation toilets with reductive nutrient production.
- the thin solid arrows show flows of solids (sludge, etc.).
- Process steps (2a), (2b), (3a), (7a) and (7d) lead to (3c) and show the solids discharge from the black water module into the bio waste stream.
- the solid sources can be added in any conceivable combination before comminution, and / or before hydrolysis and / or before methane fermentation.
- one or more mechanical, physical and / or chemical pre-clarification processes can be used, from which fermentable sludge can also be produced (2b).
- the pretreatment processes should be as gentle as possible, and the coarse-grained solid structure of the black water should be improved and / or not destroyed. Residues are separated (2a) and can be further processed.
- the nitrate can be used for denitrification.
- the solid / liquid separation can be carried out particularly preferably by means of anaerobic flotation.
- Flotation, sedimentation and / or filtration processes are preferably used here for solid / liquid separation.
- the separable carbon in the sludge of the black water (it can be added to the biogas production: (3a) & (3c)) is thus separated from the main part from the nitrogen of the urine in the liquid phase, which is important for the operational stability of the biogas plant.
- the black water from process step (2) is now subjected to oxidation by microorganisms and / or carbon removal.
- Aerobic treatment stage oxidation by microorganisms and / or carbon removal
- the dissolved carbon remaining in the black water thus releases gas as CO 2 .
- Oxidation by microorganisms also includes nitrification (urea is oxidized to nitrate).
- the liquid phase from the biogas plant from process step (VII) can also be fed in and oxidized here.
- An activation process is preferably used here, which works with a high dry matter content (approx. 15 kg oTS / m 3 ) of active biomass in order to keep the reactor volume small. Then, however, there are special requirements for the downstream solid / liquid separation (4).
- the oxidation by microorganisms and / or carbon removal of carbon and nitrogen can be single-stage or two-stage and two-stage in each case also multi-stage, all combinations of fixed bed and activation processes being possible here.
- the solid / liquid separation of process step (2) and the oxidation by microorganisms (3) can preferably be carried out in the same device.
- the nitrification runs smoothly and optimally in a small pH window between pH 6-7.
- the nitrifying bacteria are inhibited by HNO 2 - N, in the basic range by NH 3 -N.
- the nitrification process is accompanied by a pH drop in the medium. Due to the inflow quantities dependent on the toilets used (vacuum toilets: 7 - 10 l / (PE * d), flush toilets: 30 - 60 l / (PE * d)) and the dependency on the solid / liquid separation used in process step (4) Oxidation reactor sizes (eg microfiltration: reactor size approx.
- a suitable quantity of nitrified black water and / or urine waste water and / or faecal waste water for accelerated anaerobic denitrification in the upstream solid / liquid separation is preferably supplied via (3b) and / or (5a).
- the solids are transferred to the gas bubbles (N 2 ) Surface transported and can be peeled off.
- the denitrifying bacteria can also be added via (III) and / or (5a). In the event that the solid / liquid separation is carried out in the same device, the separated biomass or necessary portions can remain in the device.
- the process sequence is preferably a) solid / liquid separation (process step (2)) & denitrification, b) oxidation by microorganisms (process step (3)), and c) solid / liquid separation (process step (4)) sequencing - batchwise operation (similar like SBR) in two alternately charged reactors, preferably with a buffer tank.
- process step (3) second paragraph
- the feed can be carried out in gushes and flourish with subsequent anaerobiosis. All three process steps preferably take place in the same device. In the temperature range below approx.
- Nitrosomonas (NH 4 + -> NO 2 ) has a slower metabolic rate than Nitrtobacter (NO 2 " -> NO 3 ' ).
- NO 2 " produced in the oxidation reactor is metabolized quickly and the formation of the toxic HNO 2 -N prevented.
- the metabolic rate of Nitrosomonas is faster than that of Nitrobacter. This can lead to an accumulation of HNO 2 -N in the reactor and inhibit the nitrification process. Since one of the target groups of the process presented here is hotel complexes in hot and sunny areas and because the released heat of oxidation releases the reactor itself, suitable countermeasures (e.g.
- a feature of the process is the active sludge storage (7b), with which the required concentration of active biomass in the oxidation device can be specifically controlled depending on the volume and daily load curve of the black water attack in connection with demand-controlled oxygen supply (7c) in order to ensure constant drainage quality.
- the process can be carried out using a computer and / or EDI (remote data transmission). Sensor-based operational monitoring can be provided.
- the demand-dependent and controllable biomass concentration in the oxidation device could have an influence on the special requirements of the method according to the invention.
- the acidification surges and / or the enrichment of HNO 2 -N in the oxidation device could thus be counteracted by targeted supply of active biomass and / or biomass enriched with Nitrobacter from the active sludge storage. It allows the system to be adapted to the daily flow lines with the smallest reactor design, even with appropriate control.
- Measures to prevent autolytic digestion of the biomass can be taken in the active sludge storage. Excess active biomass from the storage (7d) is fed to the biogas plant. (5)
- the liquid product from process step (4) can go through an optional sanitation process step. By choosing the appropriate filtration method (4), this can also be omitted. After process step (5), a further hygiene process step can be provided. However, if possible, chlorination of the liquid product from (5) should be avoided due to the risk of salting up in the black water circuit, in order to keep the mineral fertilizer formed pedologically faultless.
- the product from (5) is a clear, concentrated mineral fertilizer solution that can be reused via a storage tank for flushing the toilets and / or urinals.
- the open black water cycle is closed.
- the toilet water consumption can be reduced from approx. 50 l / (E * d) to a maximum of 0 l / (E * d).
- Entry volumes into the black water cycle are approx. 1.5 - 2.2 l / (E * d) from human excretions.
- the exit volume of liquid mineral fertilizer is calculated from the entry volume minus sludge deductions and evaporation losses. If these deductions equal or exceed the entry volume, water must be added to this circuit.
- the amount of extraneous water supplied is determined by the water consumption of the toilets and urinals and the biologically compatible nitrogen concentrations in the oxidation reactor.
- the end product is a highly concentrated, odorless liquid mineral fertilizer that can be stored and / or used for fertilization.
- the carbon content in the mineral fertilizer solution is so low that denitrification processes hardly take place.
- Process step (8) now shows the process using urine separation toilets. Even under these conditions, the separately collected faecal wastewater should be subjected to a solid / liquid separation in order to keep the volume of the biogas plant small. If the liquid supernatant is to be oxidized in order to close the black water cycle and oxidize NH -N to NO 3 -N, because this prevents an odor-intensive stripping of the nitrogen, since the same applies to the urine wastewater, the urine wastewater with the faecal water supernatant reunite.
- separation toilets for the oxidative application of nutrients (mineral fertilizers (KNO 3 , P 2 O 5 , K 2 O, etc.)) makes little sense.
- the use of urine separation toilets only makes sense in this process if you want to apply the nutrients from the urine wastewater anaerobically. Then, after filtration to remove pathogenic microorganisms, the urine can be combined with the digested fermentation broth from the biogas plant (8a) without causing denitrification processes.
- the pure urine wastewater can also be sent separately for drying and / or use (spreading) and / or further processing (8a). Concentration by reverse osmosis is also useful.
- MAP precipitation magnesium ammonium phosphate
- other precipitation processes in urine wastewater, optionally after hygienization, would also be conceivable here.
- anaerobic hydrolysis of the urine wastewater for acidification would make sense before reunification, in order to shift the NH 3 - NH 4 + solubility balance in favor of the NH 4 + concentration.
- Adsorptive processes for ammonium can also be useful and thus be part of the process. Combinations of precipitation, adsorption and / or drying are also possible.
- the Fes liquid separation of the faecal wastewater still makes sense to keep the volume of the biogas plant small.
- the faecal waste water from process step (3) can be oxidized by the elimination of approx. 88% of the nitrogen with considerably less energy consumption than with the urine waste water, which the Operating costs of the oxidizer in the black water cycle would greatly reduce.
- the reactor size of the oxidation device would also be significantly smaller.
- the reductive nutrient application of the urine wastewater complements the oxidative nutrient application of the faecal wastewater and prevents the problems of the process steps (3) and (4) described above.
- nitrogen losses due to NH 3 outgassing must be expected.
- the organic waste stream and its interlocking with the gray and black water cycle is described below.
- the aim of this partial process stream should be a good biogas yield and extensive sanitation of the organic material.
- the separation is provided as an optional process component.
- a separation of residues by means of separation by specific weight or other processes can also be provided as an additional process component at another point in the bio-waste stream (e.g. (III)).
- the residual or interfering substances are separated and can be further processed.
- the organic waste which is as pure as possible is now subjected to comminution.
- the comminution can take place with or without the sludges from the black water stream ((2b), (3a), (7d) and / or (7a)).
- the organic waste is preferably shredded without the sludge using a "cutter" as used in large butchers for sausage production. Cutters cause very good size reduction and homogenization of the organic waste.
- the hydrolysis is preferably operated thermophilically with the appropriate retention time in order to achieve a simultaneous sanitation of the organic material.
- the hydrolyzed material is subjected to a preferably mesophilic methane fermentation in this process step.
- Methane fermentation is the interface to the gray water module.
- the separated material from the fat separators or flotation processes of the kitchen wastewater is added directly to the methane fermenter, since the hydrolysis of fats is the speed-limiting step in the anaerobic catabolism of fats.
- the digested fermentation broth can now be subjected to an optional solid-liquid separation.
- the liquid supernatant contains many nutrients and can be added to the oxidation (3) (VII), or preferably before the filtration to the reductive process line of the urine waste water (Vllb).
- the aim of this partial process flow is the production of highly purified service water.
- the final goal can be the production of drinking water from gray water or partial flows of gray water.
- This goal can be achieved by membrane filtration using reverse osmosis and / or micro- and / or ultrafiltration followed by salt removal.
- attention must be paid to the suitable pore sizes; z. B. for residual COD retention, sanitation, etc.
- the carbon in the gray water is first removed by wetoidation (possibly with the addition of nutrients from the black water) or other biological, chemical or physical processes. It is not necessary to remove nitrogen and phosphorus, but it can be done by other processes (e.g. precipitation of carbon) or it can be provided as a separate biological, chemical or physical process step (s).
- the activated sludge resulting from biological carbon degradation is fixed (fixed bed process) or is returned (activated sludge process).
- the excess sludge or precipitated sludge is separated by means of common solid / liquid separation processes and can e.g. be fed to a biogas plant.
- the hardly degradable COD fraction remaining in the liquid phase can be oxidized to CO 2 by ozonization or other processes and / or removed by other biological, chemical or physical processes. After an optional further solid / liquid separation (eg filtration), the substances remaining in the gray water are then removed by activated carbon filtration or other processes (eg filtration or adsorption processes).
- gray water contains relatively few salts
- salt removal eg reverse osmosis
- the oxidized gray water can be multi-functionally processed into drinking water by the already existing desalination plants: Simultaneous retention of salts, pathogenic microorganisms, as well as any nutrients and residual COD that may still be present can be achieved.
- Hygiene and chlorination are process options.
- a process step for changing or neutralizing the water structure can be inserted at a suitable point (e.g. after activated carbon adsorption).
- a Grundwasse ⁇ assage can also be interposed to the process due to the legal regulations, but is not technically necessary.
- dashed boxes or lines and arrows represent options and process variants.
- the kitchen waste water contains fats, oils, floating and removable solids as well as surfactants and dissolved organic substances. Flotation is recommended as a pretreatment process, with which the fats, oils, floating and settable solids as well as parts of the dissolved BOD and COD can be drawn off and introduced into the methane fermenter of the black water and bio waste module.
- the use of fat separators, filtration, precipitation and other separation processes is also possible here.
- the pool and / or rest area consists of the return sludge from the pool water purification system, the pool water itself, and other gray water sources, mostly outdoors. Due to the hunanogenic entry, body oils, nitrogen and other nutrients as well as salts are found here, which are sweated out through the skin, but are also introduced through the chlorination of the pool water. Epidemiological concerns do not exist because of the permanent chlorination of the pool water, so that this gray water is suitable for avoiding over-fertilization (the N loads are low compared to black water) without treatment for watering and fertilizing nearby green areas.
- the pretreated gray water flows are reunited before oxidation (oxidation by microorganisms and / or carbon removal) and fed to a suitable oxidation process by microorganism processes (ventilated sand filter, plant sewage treatment plant, unplanted vertically intermittently loaded soil filter, etc.).
- microorganism processes ventilation sand filter, plant sewage treatment plant, unplanted vertically intermittently loaded soil filter, etc.
- mineral fertilizer solution from the black water cycle can be added.
- one or more mechanical, physical, chemical and / or biological cleaning processes can be interposed.
- the purified gray water can be mixed with sea water or separately in a sea water desalination plant at more favorable conditions because of the lower osmotic pressure to make drinking water.
- the salty residue from the desalination plant is discharged into the sea (14).
- chlorination can be interposed before the reused and / or storage (11) of the purified gray water.
- FIG. 3 shows the black water sedimentation and the oxidative removal of nutrients from the organic waste stream as a flow diagram.
- C, N, P, K mean the reduced organic compounds of these elements, CO 2 , KNO 3 , and PO 4 the oxidized.
- CH 4 means the withdrawal of carbon as an energy source (biogas).
- the carbon must be removed from the wastewater. This happens in two ways: firstly by settling (1) (sludge is heavier than water) and secondly by biological "burning" (2) of the remaining dissolved carbon by bacteria. Most of the carbon is now in the form of sludge and waste ((1) & (2)). These can either be composted (6), which is also a biological "burning" of the readily biodegradable carbon compounds. This releases a lot of energy.
- sludge and waste (1) & (2)
- These can either be composted (6), which is also a biological "burning" of the readily biodegradable carbon compounds. This releases a lot of energy.
- Another possibility is to ferment the easily degradable carbon compounds in the absence of air (4). Since oxygen is no longer available, biogas (CH 4 ) is produced instead of CO. This energy source can be used in many ways.
- N, P & K elixir of life for cultivated areas.
- Plants absorb nitrogen in two ways via the roots: as nitrate NO 3 or as ammonium NH 4 .
- Phosphorus is taken up as phosphate PO 4
- potassium as potassium ion K + .
- the biological "burning" of the carbon in the wastewater (2) releases a lot of potassium, nitrate and phosphate in addition to CO 2 , which, however, remain dissolved in the water.
- Figure 4 shows the use of the method as a compact module that can be installed in basements.
- the production of mineral fertilizers may not be desirable.
- Another feature of the process is that the denitrification and biological phosphate removal can be switched on and off, since the application of nutrients to green areas in winter is not desirable.
- the method will now be explained in more detail with reference to FIGS. 4 & 5:
- the raw waste water or preferably black water is fed via a line (1) into a chamber filter.
- This chamber filter press can be replaced by other common methods for solid-liquid separation.
- the solid-containing filtrate can be adjusted to a desired dry matter content with the device for solid-liquid separation, which is desirable for reducing the volume of the reduction device.
- the filtrate containing solids is separated via a line (2) or passed together with the organic waste (3) into a reduction device for anaerobic conditioning and production of biogas.
- the fermentation broth is returned via the line (FIG. 4: (10), FIG. 5: (11)) to the device for solid-liquid separation.
- the resulting filter cake (Fig. 4: (11), Fig. 5: (12)) can be disposed of in a waste bin, applied in the garden, or further processed.
- the liquid filtrates from (FIG. 4: (11), FIG. 5: (12)) and (1) are fed to the oxidation device (oxidation by microorganisms and / or carbon removal) via line (4) when nutrient preparation and application or storage or storage is desired ) fed.
- the carbon compounds are oxidized to CO, and the nutrients are mineralized to KNO 3 , K 2 O, PO 4 , etc.
- the resulting active biomass is fed via line (5) to the device for solid-liquid separation and pressed.
- the desired dry matter content can also be set here.
- the solid-free mineralized black water is used again via line (Fig. 5: (9)) for flushing the toilet. The black water is thus conducted in an open cycle in which the nutrients are concentrated.
- the pressed biomass is fed via line (6) into an active sludge storage. Measures to prevent autolytic digestion of the biomass can be taken in the active sludge storage. If the oxidizer is in high demand active biomass (with a high mass flow rate and / or a high degree of contamination), the concentrated active biomass is fed to the oxidation device and the oxygen supply is increased accordingly, thus increasing the rate of degradation. Excess active biomass via line (8) is fed to the reduction device.
- the oxidized nitrogen (NO 3 ) is denitrified, for example in the oxidation device, using conventional methods and phosphorus is biologically fixed or removed in some other way after complete oxidation. This is preferably done in the oxidation device, which becomes a reduction device by turning off the aeration and stirring. Carbon can be provided and mixed via line (4).
- the denitrification due to the high nitrate concentrations available through the black water cycle can be used for flotation in the first solid / liquid separation of the black water and / or faecal waste water. Since a high concentration of facultative anaerobic bacteria can be found in the active sludge storage, denitrification can also be increased very efficiently by adding active biomass via line (7).
- Ventilation can be carried out intermittently and / or additional solid-liquid separations can be interposed in the breakdown process.
- Excess active biomass is fed to the reduction device via line (8).
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- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
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Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
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US09/445,249 US6379546B1 (en) | 1997-06-04 | 1998-06-03 | Method and device for sewage treatment |
BR9809944-2A BR9809944A (pt) | 1997-06-04 | 1998-06-03 | Processo e aparelho para o tratamento de águas de refugo |
EP98932110A EP0991594A1 (de) | 1997-06-04 | 1998-06-03 | Verfahren und vorrichtung zur behandlung von abwässern |
NZ501895A NZ501895A (en) | 1997-06-04 | 1998-06-03 | Process and apparatus for treating waste waters |
HU0004105A HU225517B1 (en) | 1997-06-04 | 1998-06-03 | Method and device for sewage treatment |
AU82124/98A AU751277B2 (en) | 1997-06-04 | 1998-06-03 | Method and device for sewage treatment |
US10/044,094 US6838000B2 (en) | 1998-06-03 | 2002-01-11 | Method and device for sewage treatment |
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DE19723477 | 1997-06-04 | ||
DE19723477.1 | 1997-06-04 | ||
DE19748691.6 | 1997-11-04 | ||
DE19748691 | 1997-11-04 | ||
DE19752588 | 1997-11-27 | ||
DE19752588.1 | 1997-11-27 | ||
DE19804040.7 | 1998-02-03 | ||
DE19804040 | 1998-02-03 |
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US09/445,249 A-371-Of-International US6379546B1 (en) | 1997-06-04 | 1998-06-03 | Method and device for sewage treatment |
US10/044,094 Continuation US6838000B2 (en) | 1998-06-03 | 2002-01-11 | Method and device for sewage treatment |
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WO1998055402A1 true WO1998055402A1 (de) | 1998-12-10 |
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US (1) | US6379546B1 (de) |
EP (1) | EP0991594A1 (de) |
AU (1) | AU751277B2 (de) |
BR (1) | BR9809944A (de) |
HU (1) | HU225517B1 (de) |
NZ (1) | NZ501895A (de) |
OA (1) | OA11228A (de) |
WO (1) | WO1998055402A1 (de) |
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- 1998-06-03 BR BR9809944-2A patent/BR9809944A/pt not_active IP Right Cessation
- 1998-06-03 WO PCT/EP1998/003316 patent/WO1998055402A1/de active IP Right Grant
- 1998-06-03 AU AU82124/98A patent/AU751277B2/en not_active Ceased
- 1998-06-03 HU HU0004105A patent/HU225517B1/hu not_active IP Right Cessation
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Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2001009048A1 (de) * | 1999-08-02 | 2001-02-08 | Nopa Ltd. | Verfahren zur nutzwasseraufbereitung für einen wenigstens teilweise geschlossenen wasserkreislauf |
EP1086929A1 (de) * | 1999-08-02 | 2001-03-28 | NOPA Ltd. | Verfahren zur Nutzwasseraufbereitung für einen wenigstens teilweise geschlossenen Wasserkreislauf |
FR2804105A1 (fr) * | 2000-01-25 | 2001-07-27 | Lothaire Le | Procedes de traitements des effluents pour les rendre conformes aux normes europeennes et dispositifs de mise en oeuvre de ces procedes permettant un recyclage complet des petits effluents |
WO2003062156A1 (en) * | 2002-01-18 | 2003-07-31 | Watervision Sweden Ab | System for desalination and distribution of saline raw water |
CN101967031A (zh) * | 2010-10-20 | 2011-02-09 | 江苏兆盛环保集团有限公司 | 垃圾渗滤液处理方法 |
CN101967031B (zh) * | 2010-10-20 | 2012-09-26 | 江苏兆盛环保集团有限公司 | 垃圾渗滤液处理方法 |
DE102010060420A1 (de) * | 2010-11-08 | 2012-05-10 | Borda E.V. Bremen Overseas Research And Development Association | Anlage in Modulbauweise zur anaeroben Behandlung von Fäkalschlämmen aus Siedlungsabwässern und Verfahren zur anaeroben Behandlung von Fäkalschlämmen aus Siedlungsabwässern |
WO2012062688A3 (de) * | 2010-11-08 | 2012-09-13 | Borda E. V. Bremen Overseas Research And Development Association | Anlage in modulbauweise zur anaeroben behandlung von fäkalschlämmen aus siedlungsabwässern und verfahren zur anaeroben behandlung von fäkalschlämmen aus siedlungsabwässern |
CN102198997A (zh) * | 2011-04-15 | 2011-09-28 | 四川省环保科技工程有限责任公司 | 脱落酸生产废水处理工艺方法 |
CN102198997B (zh) * | 2011-04-15 | 2012-10-10 | 四川省环保科技工程有限责任公司 | 脱落酸生产废水处理工艺方法 |
WO2013013689A1 (de) * | 2011-07-28 | 2013-01-31 | Areal Vertriebs- Und Service Gmbh & Co. Kg | Verfahren und anlagen zur semizentralen behandlung, aufbereitung und nutzung von biogenen stoffströmen in agro-urbanen siedlungssystemen im sinne einer ressourcenschonenden kreislaufwirtschaft |
CN107324588A (zh) * | 2017-07-18 | 2017-11-07 | 绵阳市自创科技有限公司 | 生态链窖库及处理方法 |
CN107324588B (zh) * | 2017-07-18 | 2020-08-04 | 绵阳市自创科技有限公司 | 生态链窖库及处理方法 |
CN108753844A (zh) * | 2018-06-27 | 2018-11-06 | 陈盛联 | 固态发酵动物粪便生产沼气的方法 |
Also Published As
Publication number | Publication date |
---|---|
HU225517B1 (en) | 2007-01-29 |
NZ501895A (en) | 2002-11-26 |
EP0991594A1 (de) | 2000-04-12 |
US6379546B1 (en) | 2002-04-30 |
AU8212498A (en) | 1998-12-21 |
AU751277B2 (en) | 2002-08-08 |
HUP0004105A2 (en) | 2001-03-28 |
HUP0004105A3 (en) | 2003-10-28 |
BR9809944A (pt) | 2000-08-01 |
OA11228A (en) | 2003-07-16 |
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