WO1998045072A1

WO1998045072A1 - Dry die wall lubrication

Info

Publication number: WO1998045072A1
Application number: PCT/US1998/007090
Authority: WO
Inventors: Terry M. Cadle; Joel H. Mandel; Paul R. Roskopf
Original assignee: Zenith Sintered Products, Inc.
Priority date: 1997-04-09
Filing date: 1998-04-08
Publication date: 1998-10-15
Also published as: CA2286159A1; DE69810916T2; EP0973624A1; US6190605B1; EP0973624B1; ES2190586T3; CA2286159C; DE69810916D1

Abstract

A method for high density long fill compaction of metallic powders uses a precisely temperature controlled mold and a dry sprayed lubricant which has the characteristic of softening on contact with the mold and smearing on the mold wall during compaction, yet on ejection not causing powder adherence.

Description

DRY DIE WALL LUBRICATION

FIELD OF THE INVENTION

This invention relates to lubrication of molds used for the compaction of metal

powders, as is done in preparing metal powder compacts for sintering.

BACKGROUND OF THE INVENTION

Powder metallurgy is a well established process for the manufacture of a wide

range of products for various applications. In its simplest form, the process involves

pouring fine powders into a precision metal mold which has moveable elements (Fig. 1)

and then applying pressure to the powder to form a "compact". The compact is then

ejected from the mold by a relative upwards motion of the bottom tool element (punch).

Holes can be formed in the compact by use of "core-pins". The compact is then subjected

to a thermal process called "sintering" which involves heating the compact in a

temperature controlled furnace under a protective atmosphere to effect powder particle

bonding and alloying which results in a strong metal product that can be used for

structural and mechanical purposes.

It is also well known that the physical and mechanical properties of the "sintered

product" are highly dependent upon its density. Since both static and dynamic strength

are highly valued properties of materials, there has been extensive work in both academic

and industrial arenas to increase the density at low cost. There are several costly ways

of achieving this high density goal: double processing which involves restriking the

sintered product and then resintering it, hot forging the sintered product, and recently

"warm pressing" of powder mixes involving special expensive lubricants and binder powder additives plus a system for precision heating of the powder mixture prior to

compaction in warm tooling.

The present invention, however, is an improvement on another approach which

involves lubrication of the vertical surfaces of the mold elements (tools). This invention

allows elimination of powder lubricants normally added to the mix to facilitate ejection

of the compact from the mold to occur without scoring or galling of the tools from cold

welding of metal powder particles to metal tool elements. Elimination of the pressing

lubricants which are light soap-like powders such as an organic stearate, clears the way

for extra metal powder densification at high compacting pressures.

Mold wall lubrication is not new. In fact, it has been practiced commercially at

Zenith Sintered Products, Germantown, Wisconsin U.S.A. since before 1985 under the

trade name Z95 Plus. This, however, involved a liquid lubricant spray onto the tool

surfaces. A drawback to the process is that the resulting compact surface is wet, and this

collects and holds loose powder which bonds to the compact in the sintering stage. The

result can be unacceptable quality products. The washing of compacts has been used to

overcome this problem, but the washing process has its own problems. The liquid carrier

medium also presents problems since it must be volatile yet meet stringent safety

regulations.

The search for a dry powder sprayed on mold coating was therefore a direction

of research. Recently a process involving charging the lubricant powder particles

electrostatically and spraying them onto the mold which is electrically grounded has been

developed and the results published widely. A major limitation with this process is with

respect to the depth of mold that can be effectively coated to permit ejection of a compact

under high pressing pressures. A variety of lubricant powders were sprayed onto mold wall surfaces using a "Tribostatic Sprayer" which was attached to a production

compacting press using production tooling to make a right cylinder of approximate

dimensions 1.5 inches outer diameter, 1.0 inches inner diameter. It was found by

experimentation that at high pressing pressures (above 50 tons per square inch) the

maximum density achievable of an iron-carbon-copper powder mix was limited to 7.25

grams per cubic centimeter and the vertical length (height) was limited to about 0.5

inches. The limiting mechanism governing the height of the compact was the removal

of powder lubricant from the top half of the mold surface during the powder compaction

stage. Since the powder height is about halved during compaction, the top half of the

mold wall, past which the compact must be ejected, is dry and unlubricated prior to

ejection. This leads to scoring and galling of the mold surface on ejection. It was

confirmed that wet spraying of the mold surface did not suffer from this effect, since a

wet residue is left on the upper half of the mold wall during compaction, that provides

lubrication during compact ejection.

SUMMARY OF THE INVENTION

An object of the invention, therefore, is to take advantage of the dry powder spray

system yet provide a residual "wet" type wall lubrication, and yet avoid a wet compact

when it is ejected to avoid powder adherence.

In practicing the invention the mold is precisely heated prior to and during

compaction to a narrow temperature band, and a dry powder lubricant is selected that has

an ideal softening and melting characteristic to match that temperature range. As a result,

on contact with the warm mold wall the lubricant powder particle softens and sticks to

the surface. When the metallic powder is compacted, it "wipes" the soft lubricant powder

down the mold wall surface, thereby smearing a residual film for effective subsequent ejection. Careful selection and control of lubricant type, condition, and mold temperature

range is essential for optimum performance.

Using this process has resulted in the ability to compact rings on the annular

tooling described earlier to above 7.35 grams per cubic centimeter density, with a height

of at least 1.0 inches which is at the limitation of the tooling. On ejection, the compacts

were non-adherent to loose powder.

Other objects and advantages of the invention will be apparent from the detailed

description.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

This invention provides a method of achieving an increased length and density

product by powder metallurgy by dry powder lubricant spraying onto temperature

controlled mold walls where the lubricant softening and melting temperatures produce

a smeared but not wet coating on the mold walls. This allows taller compacts to be

produced than is possible with current dry powder mold wall processing.

EXAMPLE OF PROCESS

A powder blend of pre-alloyed iron-nickel molybdenum powder (0.7% nickel,

0.5% molybdenum) plus 0.7% graphite was poured into a mold made from tungsten

carbide with high speed steel punches. The annular mold dimensions were 1.5 inches

outer diameter, 1.0 inches inner diameter with a powder fill depth of 2.0 inches. The

mold walls were heated and temperature controlled using 4 rod type heating elements

and a controller to a range of 175°F to 200 °F which was measured by a built-in

thermocouple, and checked by a hand held surface contact thermocouple. The powder

lubricant used was synthetic polyethylene wax with a softening point of 145 °F and a

melting point of 207 °F. The powder was delivered by a commercially available "Tribostatic powder spray system" which is not part of this invention. It was found

that cold mold compaction using the following lubricants: zinc stearate, lithium

stearate, stearic acid, acrawax, and including the lubricant of this example, could only

achieve 7.25 grams per cubic centimeter density to a maximum depth of only 0.5

inches of compaction. It was found that substitution of a wet spray enabled a full 1.0

inches of compaction to be achieved, but the result was a wet compact which collected

loose powder on the surface and suffered from excess lubricant in some corners of the

tooling.

When the mold was pre-heated to 175°F and the wax powder lubricant was

sprayed onto the mold surface, an immediate improvement was evident. The full 1.0

inch length capability of the tooling was useable and a density of 7.35 grams per cubic

centimeter was readily achieved. The resulting compacts were hot to the touch but

dry enough not to collect loose powders. This was found to be consistent and

reproducible in a short production run, which indicated it will be a commercially

viable process.

Therefore, the invention provides a process for high density long fill

compaction of metallic powders using a precisely temperature controlled mold and a

dry sprayed lubricant powder which has the characteristic of softening on contact with

the mold and smearing on the mold wall during compaction, yet on ejection not

causing powder adherence.

In a preferred form, the mold wall is heated by any suitable means to a

temperature range which is between the softening and melting points of the lubricant,

and the warmed wall is sprayed or otherwise coated with the lubricant. As the metal

powder and punch wipe along the mold wall during compaction, the lubricant coating is smeared on the wall, leaving a lubricant residue on the wall to lubricate the ejection

of the compact from the mold.

A preferred method of practicing the invention has been described in

considerable detail. Many modifications and variations to the method described will

be apparent to those skilled in the art. For example, a lubricant other than

polyethylene wax could be used, and it could be coated on the die walls by any

suitable means of application, whether by spraying or not.

Claims

We Claim:

1. A method of compacting metal powder in a compaction mold to

prepare a metal powder compact for sintering, comprising:

controlling the surface temperature of walls of said mold to be at a temperature

which is between a softening temperature and a melting temperature of a lubricant;

applying said lubricant to said walls;

charging said mold with powder metal, with said powder metal contacting said

lubricant applied to said walls;

compacting said powder metal in said mold; and

ejecting said compacted powder metal as a single part from said mold.

2. A method as claimed in claim 1, wherein said lubricant is in solid

phase at room temperature.

3. A method as claimed in claim 1, wherein said compacting step is

carried out until said powder metal has reached fifty percent or less of its original

uncompacted height.

4. A method as claimed in claim 1, wherein said lubricant softens upon

contact with said walls of said mold.

5. A method as claimed in claim 1, wherein said lubricant is smeared on

said walls of said mold during said compaction step.

6. A method as claimed in claim 1, wherein powder metal particles do not

adhere to said compacted powder metal part after ejection.