WO1998035091A1 - Procede et dispositif de cuisson continue de pate - Google Patents

Procede et dispositif de cuisson continue de pate Download PDF

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Publication number
WO1998035091A1
WO1998035091A1 PCT/SE1998/000225 SE9800225W WO9835091A1 WO 1998035091 A1 WO1998035091 A1 WO 1998035091A1 SE 9800225 W SE9800225 W SE 9800225W WO 9835091 A1 WO9835091 A1 WO 9835091A1
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WO
WIPO (PCT)
Prior art keywords
digester
zone
liquid
vessel
liquor
Prior art date
Application number
PCT/SE1998/000225
Other languages
English (en)
Inventor
Johan ENGSTRÖM
Vidar Snekkenes
Krister Olsson
Sören GUSTAVSSON
Christofer Lindgren
Mikael Lindström
Original Assignee
Kvaerner Pulping Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kvaerner Pulping Ab filed Critical Kvaerner Pulping Ab
Priority to AT98903344T priority Critical patent/ATE201064T1/de
Priority to DE69800767T priority patent/DE69800767T2/de
Priority to PCT/SE1998/000225 priority patent/WO1998035091A1/fr
Priority to EP98903344A priority patent/EP0909353B1/fr
Priority to CA002279283A priority patent/CA2279283C/fr
Priority to AU60109/98A priority patent/AU6010998A/en
Publication of WO1998035091A1 publication Critical patent/WO1998035091A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C7/00—Digesters
    • D21C7/14—Means for circulating the lye
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00—Pulping cellulose-containing materials
    • D21C3/02—Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00—Pulping cellulose-containing materials
    • D21C3/22—Other features of pulping processes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00—Pulping cellulose-containing materials
    • D21C3/22—Other features of pulping processes
    • D21C3/24—Continuous processes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C7/00—Digesters

Definitions

  • the present invention relates to a novel method for producing pulp, preferably sulphate cellulose, with the aid of a continuous cooking process.
  • the method is preferably directed towards exploiting, m both steam/liquid-phase digesters and hydraulic digesters, the advantages associated with impregnating the chips with the aid of hot black liquor.
  • ITC ⁇ One recent brake through within the field of cooking is ITC ⁇ , which was developed by us in 1992-1993. ITC is described m O-9411566, which shows that very good results concerning pulp quality could be achieved when using ITC ⁇ ', which mainly is based on using almost the same temperature (relatively low compared to prior art) m all cooking zones m combination with moderate alkaline levels.
  • the ITC" ' -concept doe not merely relate to the equalisation of temperatures between different cooking zones, but a considerable contribution of the ITC" -concept relate 0 to enabling an equalised alkaline profile also in th ⁇ lower part ot the counter-current cooking zone.
  • impregnation with the aid of black liquor can improve the strength properties of the fibres m the pulp pro meed.
  • the aim of the impregnation is, m the first place, thoroughly to soak each chips so that it becomes susceptible, by penetration and diffusion, to the active cooking chemicals which, m the context of sulphate cellulose, principally consist of sodium hydroxide and sodium sulphide .
  • strainers m the impregnation vessel, hanging central pipes, etc., making an installation much simpler and considerably cheaper.
  • Fig. 1 shows a preferred embodiment of a continuous two vessel steam/liquid-pnase digester arrangement according to the invention
  • Fig. 2 shows a preferred top separator to be used m a steam/vapour-phase digester according to the invention
  • Fig. 3 shows a preferred top separator to be used m an hydraulic digester according to the invention
  • Fig. 4 shows a preferred embodiment of a one vessel hydraulic digester according to the invention
  • Fig. 5 shows a diagram presenting the advantages related to the H-factor when using the invention.
  • Fig. 6 shows which conditions were used m the laboratory for one of the ITC-references and one of the cooks according to the invention (so called modified ITC) .
  • Fig. 7 is a schematic flow diagram of a second embodiment of a two vessels steam/liquid phase digester system according to the present invention
  • Fig. 8 is a schematic flow diagram of a one vessel steam/liquid phase digester system according to the present invention
  • Fig. 9 is a schematic flow diagram of a two vessel hydraulic digester system according to the present invention.
  • Fig. 10 is a schematic flow diagram of a further one vessel hydraulic digester system according to the present invention.
  • Fig. 11 shows test data related to peroxide consumption and brightness for the present method compared to a conventional process
  • Fig. 12 shows test data related to tensile index and tear index for unbleached pulp according to the present method compared to a conventional process
  • Fig. 13 shows test data related to tensile index and tear index for bleached pulp according to the present method compared to a conventional process
  • Fig. 14 shows test data related to Cl charge and brightness for the present method compared to a conventional process
  • Fig. 15 shows a further embodiment according to the invention.
  • Fig. 16 shows further embodimen t according to the invention.
  • Fig. 17 shows further embodiment according to the invention.
  • Fig. 18 shows further embodiment according to the invention.
  • Fig. 19 shows further embodiment according to the invention.
  • Fig. 20 shows further embodiment according to the invention.
  • Fig. 21 shows further embodiment according to the invention.
  • Fig. 22 shows a further embodiment according to the invention.
  • Fig. 23 shows a preferred embodiment of the inlet of an hydraulic vessel according to the invention.
  • Figure 1 shows a preferred embodiment of a two vessel steam/liquid-phase digester for producing chemical pulp according to the invention.
  • the main components of the digesting system consist of an impregnation vessel 1 and a steam/liquid-phase digester 6.
  • the impregnation vessel 1 which normally is totally liquid filled, possesses a feedmg-m device 2 at the top, which feedmg-m device is of a conventional type, i.e. a top separator with screw-feed device which feeds the chips m a downward direction at the same time as transport liquid is drawn off.
  • the impregnation vessel possesses a feed g-out device 3 comprising a bottom scraper.
  • a conduit 17 for adding hot black liquor As seen the black liquor is preferably supplied at the top of the impregnation vessel.
  • no draw-off screen is located on the impregnation vessel.
  • the chips are fed from the chip bin 20A, through the steaming vessel 20B and the chip chute 20C.
  • a feeding device preferably a high-pressure feeder 19, feeds the chips via a conduit
  • a conduit 21 for transporting chips leads from the bottom of the impregnation vessel 1 up to the top 5 of the digester 6 having a steam space, wherein the liquid level being indicated by means of a broken line.
  • a supply line for steam at the top provides for heating of the steam space.
  • Conduit 21 opens out at the bottom of a top separator 7 which feeds by means of a screw m an upwardly moving direction. The screen of the separator is used to draw off the liquid D (which is then returned m line 15) together with which the chips are transported up to the top.
  • annular ring 2 J At the upper edge of the screen (over which edge the chips tumble out), there is arranged an integrated annular ring 2 J .
  • the annular ring 23 is connected to a conduit 24 which (preferably via a heat-exchanger 13A) leads to a white-liquor container (not shown) .
  • a screen girdle section 8 is arranged m conjunction with a step-out approximately m the middle of the digester 6. Draw-off from this screen girdle section 8 can be conducted directly via conduit 17 to the impregnation vessel 1.
  • the black liquor is drawn off via conduit 28 to a first flash cyclone 9.
  • "cold- blow” is carried out, the temperature of the pulp being cooled down at the bottom of the digester with the aid of relatively cold (preferably 70-80 °C) liquid ( wash liquid) which is added by means of the scraping element 22 and/or other liquid-addmg devices 25 (appropriately annular pipes) at the bottom, and then subsequently conducted upwards m counter-current.
  • relatively cold (preferably 70-80 °C) liquid ( wash liquid) which is added by means of the scraping element 22 and/or other liquid-addmg devices 25 (appropriately annular pipes) at the bottom, and then subsequently conducted upwards m counter-current.
  • This lower circulation consists of a screen girdle sections 12 (m the shown embodiment consisting of three rows) which is arranged at sufficient height above the lower liquid-addition point 22 and/or 25 to permit the attainment of a desired flow from the latter liquid-addition point towards the screen section 12.
  • the draw-off from the said screen girdles 12, is recirculated (for displacing black liquor m counter-current to the draw-off screen 8) into the digester with the aid of a central pipe 14 (or alternately a stand pipe from the bottom of the digester) which opens out approximately on a level with the said screen girdle section 12.
  • a heat exchanger 13 for temperature regulation (raising the temperature of the re-mtroduced liquid) and a pump are also located m the conduit 11 which connects the screen girdle 12 with the pipe 14.
  • the recirculation loop 11 is also connected via a branch conduit 27 to the white liquor supply so that fresh alkali can be supplied and, in the form of counter-current cooking, further reducing the kappa number.
  • the digester construction described is notable for the lack of a plurality or central pipes arranged from above and hanging downwards, as well as of feed pipes connected to them and of other necessary parts for the circulations.
  • a preferred installation according to the invention functions as follows.
  • the chips are fed a conventional manner into a chip bin 20A, subsequently steamed 20B and thereafter into a chute 20C.
  • a high- pressure feeder 19 (which m a known manner is supplied with a minor amount of white liquor ( ⁇ 5 of the total amount) in order to lubricate it) , with the aid of which the chips are fed into conduit 18 together with transport liquid.
  • the slurry of chips and liquid which is fed to the top of the impregnation vessel m this way have a temperature of about 110 - 120 °C on entry to the impregnation vessel (excluding recirculated transport liquor) .
  • the latter In addition to the actual fibre, in the wood, the latter also conveys its own moisture (the wood moisture) , which normally constitutes about 50 of the original weight, to the impregnation vessel. Over and above this, some condense is present from the steaming, i.e. at least a part of the steam (principally low- pressure steam) which was supplied to the steaming vessel 20B is cooled down to such a low level that it condenses and is then recovered as liquid together with the wood and the transport liquid.
  • the wood moisture normally constitutes about 50 of the original weight
  • the chips which are fed out from the bottom of the top screen 2 then move slowly downwards a plug flow through the impregnation vessel 1 m a liquid/wood ratio between 2/1-10/1 preferably between 3/1-8/1, more preferred of about 5/1-7/1.
  • Hot black liquor which is drawn off from the first flash 9, is added, via conduit 17, in the top of the impregnation vessel 1.
  • the high temperature of the black liquor (100 - 160 °C) , preferably exceeding 130 °C, more preferred between 130 - 160 °C, ensures rapid heating of the chips.
  • the relatively high pH, exceeding pH 10 of the black liquor neutralises acidic groups in the wood and also any acidic condensate accompanying the chips, thereby, i.e.
  • the black liquor supplied into the impregnation vessel has a high content of residual alkali, (EA as NaOH) , at least 13g/l, preferably about or above 16g/l and more preferred between 13 - 30g/l in the top of the impregnation vessel.
  • This alkali mainly comes from the black liquor due to the high amount of alkali in the con-current zone of the digester.
  • the strength properties of the fibres are positively affected by the impregnation because the high amount of sulphides.
  • the major portion of black liquor is directly (or via one flash) fed to the impregnation vessel 1.
  • a minor amount of the black liquor may be used for transferring the chips from the HP-feeder to the inlet of the impregnation vessel. This minor flow then has to be cooled (not shown) before it is entered into the feeder.
  • the two flows of black liquor are preferably used to regulate the temperature within the impregnation zone, which average temperature would normally not exceed 140 °C.
  • the total supply of black liquor to the impregnation vessel exceeds 80, of the amount drawn off from the draw-off strainers 8, preferably more than 90?, and optimally about 100' of the total flow, which normally is about 8 - 12 ⁇ X/ADT.
  • the chips which have been thoroughly impregnated and partially delignified in the impregnation vessel, are fed to the top of the digester 6 and conveyed into the upwardly-feeding top separator 7.
  • the chips are thus fed upwards through the screen, meanwhile free transport liquid is withdrawn outwardly through the screen and finally the chips fall out over the edge of the screen down through the steam space.
  • the chips pieces are drained with cooking liquor which is supplied by means of the top separator 7.
  • the white liquor is preferably heated by means of a heat exchanger 13A which preferably is supplied with heat steam from flash tank 9.
  • the quantity of white liquor which is added here depends on how much white liquor possibly is added else where, but the total amount corresponds to the quantity of white liquor which is required for achieving desired delignification of the wood.
  • a major part of it is added here, i.e. more than 60 c o , which also improves the diffusion velocity, since it increases in relation to the concentration difference (chip-surroundmg liquid) .
  • the thoroughly impregnated chips extra rapidly assimilate the active cooking chemicals by diffusion, since the concentration of alkali (EA as NaOH) is relatively high, at least 20g/l, preferably between 30g/l and 50g/l and more preferred about 40g/l.
  • the chips then move down m the con-current through the digester 6 at a relatively low cooking temperature, i.e. between 130 - 160 °C, preferably about 140 - 150 °C.
  • the major part of the delignification takes place m the first con-current cooking zone.
  • the retention time m this first cooking zone should be at least 20 minutes, preferably at least 30 minutes and more preferred at least 4 ⁇ minutes.
  • the liquid-wood ratio should be at lest 2/1 and should be below 7/1, preferably m the range of 3/1 - 5.5/1, more preferred between 3.5/1 and 5/1. (The liquid wood-ratio m the counter-current cooking zone should be about the same as the con-current cooking zone.)
  • the cooking liquid mingled with released lignms, etc., is drawn off at the draw-off screen 8.
  • liquid finally is also supplied m the lower part of the digester which moves counter- current. It can be describes as the pipe 14 displacing it from the wood upwards towards the draw-off screen 8. This results, consequently, the delignification being prolonged in the digester 6.
  • the temperature m this lower zone C is preferably higher than in the con-current zone B, i.e. preferably exceeding 140 °C, preferably about 145 - 165 °C, m order to dissolve remaining lignm.
  • the alkali content the lowermost part of the counter-current cooking zone should preferably be lower than the beginning of the concurrent zone, above 5g/l, but below 40g/l. Preferably less than 30g/l and more preferred between 10 - 20g/l.
  • the aim is to have a temperature difference of about 10 °C between the cooking zones.
  • the lower circulation 11, 12, 13, 14 is charged with about 5 - 20 o, preferably 10 - 15 , white liquor.
  • the temperature of the liquid which is recirculated via the pipe 14 is regulated with the aid of a heat exchanger 13 so that the desired cooking temperature is obtained at the lowermost part of the counter-current cooking zone.
  • washing liquid having a low temperature, preferably about 70 - 80 °C, is added m a known manner using the scraping element and an outer annular conduit 25 arranged at the bottom. This liquid consequently displaces the boiling hot liquor m the pulp upwards in counter-current and thereby imparts a temperature to the remaining pulp which can be cold-blown, i.e. depressurised and disintegrated without any real loss of strength.
  • Fig. 2A there is shown a preferred embodiment of a separator to be used m connection with one of the embodiments of steam/liquid phase digester systems disclosed herein. It is often preferred to have an upwardly feeding top separator for a steam/liquid phase digester.
  • the separator may comprise a screen basket 61 which a rotatable screw feeder 62 is positioned.
  • the screw feeder is fixedly attached to a shaft 63 which at its upper end is operatively attached to a drive unit 30.
  • the drive unit 30 is attached to a plate 65 which is attached to the digester shell 6.
  • a liquid collecting space 67 which may be connected to the return pipe circulation 15.
  • a liquid supply space or opening 23 which is connected to the supply line 24 that supplies white liquor (F) .
  • the separator has a plurality of inlet apertures 37 defined therein to subject the fiber chips with white liquor.
  • the inlet apertures preferably has a total area that exceeds 400 mm2. More preferred, the total area of the inlet apertures is at least 500 mm2. Most preferred, the total area of the inlet apertures exceeds 600 mm2 to achieve a sufficient flow into the chip pile.
  • top separator Between the outer peripheral wall 66 of the liquid collecting space 67 and the liquid supply space 23 respectively, and the digester shell 6 at the top, there exist an annular space 70 which opens up down into the upper part of the digester 6.
  • the functioning of the top separator may be described as follows.
  • the thoroughly heated and impregnated chips are transferred by means of the supply line 21 into the bottom portion of the screen basket 61.
  • the screw feeder 62 moves the chips upwardly at the same time as the transport liquid D is separated from the chips, by being withdrawn outwardly through the screen basket 61 and further out of the digester through return line 15. More and more liquid will be withdrawn from the chips during their transport within the screen basket 61.
  • the chips will reach the level of the supply space 23.
  • the desired amount of cooking liquor preferably white liquor, is added through the supply space 23 and the openings 37, having a temperature and effective alkaline content m accordance with the invention.
  • a minor amount of free liquid (at least about 0.5 m3/ADT) should be left together with the chips, which free liquid will then be mixed with the supplied cooking liquor.
  • a minor amount of free liquid (at least about 0.5 m3/ADT) should be left together with the chips, which free liquid will then be mixed with the supplied cooking liquor.
  • about one m3/ADT should be left together with the fiber material.
  • the white liquor should be provided at a point that is downstream of the flow of the suspension of the fiber material and the free liquid that is being fed through the screw member.
  • the chips and the cooking liquor flow over the upper edge thereof and fall into the steam/liquid space 70 and further on to the top of the chips pile withm the digester, where the concurrent cooking zone (B) starts.
  • a major advantage of the separation device is that they provide for establishing a distinguished change of zones (they enable almost a total exchange of free liquid at this point), which means t at for a two vessel system the desired conditions m the beginning of the concurrent zone (B) can easily be established.
  • FIG. 2 B there is shown a further embodiment of a separator to be used m connection with a steam/vapour phase digester, as described m figure 1.
  • the separator of Fig. 2 B is almost identical with the one shown m Fig. 2 A except for the existence of a further supply space 25, being positioned below the first supply space 23.
  • This further supply space 25 has as its object to provide for the possibility of supplying a further liquid to the up-moving chip pile. Especially for the possibility of supplying black liquor m order to secure a minimum amount of free liquid flowing upwardly m the chips pile, to eliminate back flow of the cooking liquor supplied above, m 23.
  • FIG 3 there is shown a preferred embodiment of a separator to be used together with a hydraulic digester. Only a part of the top of the digester (6) is shown.
  • the slurred fibre material pre- impregnated or not
  • the screw- feeder (31) is attached to a shaft (32) connected to a drive-unit (33) which is attached to a mounting-plate (34) on the top of the digester shell (6) .
  • the drive- shaft (32) is rotated in a direction so as to force the screw to feed in a down-ward direction.
  • a cylindrical screen-basket (35) surrounds the screw-feeder (31) .
  • the screen-basket (35) is arranged within the digester shell (6) so as to form a liquid collecting space (36) between the digester shell and the outer surface of the screen-basket (35).
  • the liquid collecting space (36) which preferably is annular, communicates with a conduit (17) for withdrawing liquid from the liquid collecting space (36), which in turn is replenished by liquid from the slurry within the screen basket (35) .
  • the major part of the free liquid within the slurry entering the screen basket is withdrawn into the liquid collecting space (36), but a small portion of free liquid, at least about 0.5 mVADT should not be withdrawn from the slurry.
  • a liquid supply device (37) Adjacent the outlet end of the screen basket (35) there is arranged a liquid supply device (37), preferably comprising an annular distribution ring which opens up into the chips pile for supply of liquid into the fibre material moving down into the digester (6) .
  • the liquid supply device (37) is replenished by means of line 38 wherein a desired liquid is supplied. If it is a two-vessel hydraulic digester system the liquid supplied through the liquid supply device (37) would be hot cooking liquor having a relatively high amount of effective alkaline, in order to provide for the possibility of establishing a con-current cooking zone (B) having a desired temperature of about 145 - 150 °C, and a desired content of effective alkaline, e.g. about 45g/l.
  • the invention is also applicable m connection with one vessel digesters of both kinds, as will be exemplified below.
  • a major advantage with both kinds of the shown separation devices is that they provide for establishing a distinguished change of zones (they enable almost a total exchange of free liquid at this point) , which means that for a two vessel system the desired conditions m the beginning of the con-current zone (B) can easily be established.
  • FIG 4 it is shown a preferred embodiment for applying the invention to a one-vessel hydraulic digester.
  • the same kind of basic equipment before and m connection with the HP-feeder as shown m fig. 1 is used, which therefore is not described m detail.
  • the basically same kind of top separator arrangement as described m figure 3 is mounted at the top of the digester 6.
  • withdrawal strainers (8) are arranged in the middle part of the digester.
  • the lowermost part of the digester is m principle similar to the one shown m figure 1, with a supply line (25) for wash liquid and a blow line (26) for the digested pulp.
  • a stand pipe (39) which opens up at about the same level as the lowermost strainer girdle (12) .
  • the upper strainer (40) is arranged for withdrawing liquid which has passed the impregnation zone (A) .
  • Some of the withdrawn liquid E> is taken out via line 46 to a flash tank 47.
  • the other part of the withdrawn liquid is recirculated for re-mtroduc g liquid withdrawn by means of a central pipe (42A) which opens up at a level adjacent the strainer (40) .
  • the second strainer (41), which is positioned intermediate the upper strainer (40) and the withdrawal strainer (8) is a also part of a re-circulation .
  • the withdrawn liquid is recirculated for re-mtroducmg it by means of a central pipe (42B) which opens up at a level adjacent the strainer (41) .
  • a central pipe (42B) which opens up at a level adjacent the strainer (41) .
  • the mam part white liquor is added thereto by means of a supply-lme (43B) and thereafter the liquid is heated to the desired temperature by means of a heat exchanger (44B) .
  • the digesting process within a digester shown m Figure 4 is as follows.
  • the slurry of chips and transport liquid is transferred, e.g. by means of high pressure feeder, within the feeding line (21) to the top of the digester where it is introduced into the top of the screen basket (35) of the separator, wherein the major part of transport liquid is separated from the chips.
  • impregnation liquor E is supplied by means of line 38.
  • the impregnation liquor is hot black liquor which is taken from the withdrawal screen (8) via a flash tank 9 by means of the supply conduit (38) . If all the desired amount cannot be withdrawn via line 46 to flash tank 47 there is provided for the possibility to also withdraw from the outlet of the first flash tank 9 via line 45.
  • a minor amount of the black liquor withdrawn from flash tank 9 may be used for transferring the chips from the HP-feeder to the inlet of the digester 6. This minor flow then has to be cooled m a cooler 80 before it is entered into the feeder.
  • the two flows of black liquor are preferably used to regulate the temperature within the impregnation zone, which average temperature normally should not exceed 140 °C.
  • the amount of effective alkaline m the supplied black liquor E is relatively high, at least 13g/l, preferably about 20g/l, which provides for the impregnation zone (A) to be established without any substantial additional supply of white liquor at this position.
  • the chips is then impregnated and heated when moving down towards the upper screen (40) , where spent liquor (D) is withdrawn and transferred by means of a conduit (46) to a flash tank (47) .
  • the chips are heated and alkali is introduced by means of the above described cooking circulations (40, 42A, 43A, 44A, 1, 42B,43B, 44B) m order to obtain desired cooking conditions.
  • the temperature at the beginning of the con-current zone is about 145 - 160 °C for soft wood and about 140 - 155 °C for hard wood and an alkaline content of about 30 - 50g/l. Thanks to the exothermic reaction of the chemicals the temperature is slightly further increased when the fibre material is moving downwardly m the con-current cooking zone (B) . Liquid having a relatively high content of effective alkaline is withdrawn at the strainers (8) positioned adjacent the middle. The alkaline content of this withdrawn spent liquor (E) would normally exceed 15g/l.
  • a higher temperature is maintained than m the concurrent zone (B) .
  • This is achieved by means of heating the liquid drawn from the lower withdrawal strainer (12), m a heat exchanger (51) before introducing it through the stand pipe (39) .
  • a minor amount, about 10 - 15 of the total amount, of white liquor is added m this recirculation line, to achieve the desired alkali concentration m the counter-current cooking zone (C) .
  • pulp produced m this manner will have higher quality and better bleachability then pulp produced with known methods.
  • FIG 5 there is shown a diagram comparing the H-factor for pulp produced according to conventional ITCTM-cookmg and the invention.
  • the H- factor is a function of time and temperature m relation to the delignification process (degree of delignification) during cooking.
  • the H-factor is used to control the delignification process of a digester, i.e. maintaining a certain H-factor principally leads to the same Kappa number of the produced pulp (remaining lignm content of the fibre material) independent of temperature variations during the cooking.
  • the H-factor for pulp produced according to the invention is extremely much lower (about 40 - 50 lower) compared to pulp produced according to ITC T .
  • the lower H-factor demand is achieved by a high alkali concentration and a low cooking temperature m the con-current cooking zone, which is shown fig. 6 which presents one reference ITC-cook (ITC 1770) and one cook according to the invention (modified ITC 1763) .
  • the temperature m the counter-current cooking zone is higher than in the con-current zone but still lower than the temperature m the counter-current zone m the ITC- reference .
  • Fig. 7 shows a preferred second embodiment of a two vessel steam/liquid phase digester system for producing chemical pulp according to the present invention, especially m relation to a retrofit of an MCC digester.
  • the mam components of the digesting system consist of an impregnation vessel lb and a steam/liquid-phase digester 6b.
  • a first screen girdle section 8b may be disposed at the upper middle portion of the digester 6b. If the digester 6 is an MCC digester, this screen section may be used to withdraw spent liquor that is conducted to a recovery unit. According to the invention, draw-off from this screen girdle section 8b may be conducted directly via the conduit 17b to the impregnation vessel lb.
  • a second screen girdle section 104b may be arranged below the first screen girdle section 8b (m an MCC digester, the screen girdle section 104b would normally be called the MCC screen) .
  • a second concurrent cooking zone C is defined between the sections 8b and 104b.
  • Draw-off from the second screen section 104b such as spent liquor, i.e., black liquor, may be conducted via a conduit 106b to a first flash tank 108b to recover steam and let pressure off before the liquor is conducted to a recovery unit 110b.
  • the spent liquor is also conducted through a second flash tank 112b via a conduit 114b to further reduce the pressure and temperature of the spent liquor before the liquor is conducted to the recovery unit 110b.
  • a conduit 124b conducts the spent liquor from the return conduit 15b (preferably at least 4mVADT; more preferably at least about 5mVADT) to the second flash tank 112b.
  • Conduits 128b and 130b may be connected to the flash tanks 108b, 112b, respectively, to supply steam to the chip bin 20A and the steaming vessel 20B.
  • a third lower screen girdle section 12b is disposed at the bottom 10b of the digester 6b.
  • a counter-current cooking zone D is defined between the sections 12b and 104b.
  • the girdle section 12b may, for example, include three rows of screens for withdrawing liquid, which is heated and to which some white liquor, preferably about 10 of the total amount of the white liquor conduit 24b, is added via a branch conduit 117b before it is recirculated by mean of a central pipe 123b, which opens up at about the same level as the lowermost strainer girdle 12b.
  • the draw-off from screen girdles 12b and the white liquor from the branch conduit 117b are preferably conducted via a heat exchanger 120b back to the bottom 10b of the digester 6b.
  • the temperature of this draw off is somewhat lower than in the cooking zone D (e.g., about 140°C) , since the liquid is a mix of wash liquid and black liquor.
  • the white liquor is supplied m a counter-current direction via the central pipe 123b to the screen girdle section 12b.
  • the white liquor provides fresh alkali and, m the form of counter-current cooking, further reducing the Kappa number.
  • a conduit 122b is connected to the high pressure steam conduit 102b to provide the heat exchanger with steam to regulate the temperature of the liquid supplied via the standpipe 123b.
  • a blow line 26b is connected to the bottom 10b of the digester for conducting the digested pulp away from the digester 6b.
  • the temperature of the black liquor m the impregnation vessel should be between about 140°C and about 160°C. More preferred, the temperature is between about 140°C and about 155°C. Most preferred, the temperature is between about 140°C and about 150°C.
  • the retention time in the impregnation zone A should be at least 20 minutes, preferably at least 30 minutes and more preferred at least 40 minutes. However, a shorter retention time than 20 minutes, such as 15-20 minutes may also be used.
  • the chips After the chips have been passed through the top separator, the chips then move down into the concurrent zones B, C through the digester 6b at a relatively low cooking temperature, i.e., between 130°C to 160°C, preferably about 140°C to 150°C.
  • a relatively low cooking temperature i.e., between 130°C to 160°C, preferably about 140°C to 150°C.
  • the major part of the delignification takes place m the first and second concurrent cooking zones B, C.
  • a further modification would be to have the cooking zone C to be a counter-current zone or a mixture of con/counter-current.
  • the temperature in the counter-current zone D is preferably higher than in the concurrent zones B, C, i.e., preferably exceeding 140°C, preferably about 145°C to 165°C, in order to dissolve remaining lignm.
  • the alkali content m the lowermost part of the concurrent cooking zone C should preferably be lower than in the beginning of the concurrent zone B, above 5g/l, but below 40g/l. Preferably less than 30g/l and more preferred between 10-20g/l.
  • the aim is to have a temperature difference of about 10°C between the first and the second concurrent cooking zones.
  • the conduit 116b may be charged with about 5-20°o, preferably 10-15., white liquor from the conduit 24b via the conduit 117b.
  • Below the draw- off screen section 104b is the counter-current zone D that is defined between the screen girdle section 104b and the screen girdle section 12b.
  • the temperature of the liquid which is recirculated via the pipe 123b up to the screen girdle section 12b is regulated with the aid of the heat exchanger 120b so that the desired cooking temperature is obtained at the lowermost part of the counter-current cooking zone D.
  • cool wash liquid is added in order to displace, in counter- current, hot liquid which is subsequently withdrawn at the lowermost screen girdle 12b.
  • Fig. 8 illustrates a preferred embodiment of a one vessel steam/liquid phase digester system of the present invention. Some of the important differences compared to Figs. 1 and 4 are described below.
  • a high- pressure feeder 19h feeds the chips suspended in a transport liquid D via a conduit 18h to the top of a digester 6h.
  • the conduit 18h extends from the feeder 19h up to a top 5h of the digester 6h .
  • the conduit 18h may open up at the bottom of a top separator 7h that feeds by means of a screw in an upwardly moving direction.
  • the separator 7h is preferably identical or very similar to the top separator 7 that is shown m Fig. 1 and described in detail above.
  • the screen of the separator may be used to draw off the transport liquid D (which is then returned m a return line 15h) together with which the chips are transported from the feeder 19h up to the top 5h of the digester 6h.
  • a first screen girdle section 8h may be disposed immediately below or adjacent the separator 7h.
  • a recirculation line 17h may withdraw liquor and bring it back to a space that is defined between the first screen girdle section 8h and the separator 7h. The recirculation improves the distribution of the liquor m the digester.
  • a second screen girdle section 51n is disposed below the first screen girdle section 8h so that an impregnation zone A is defined between the screen girdle sections 8h and 51h.
  • an impregnation zone A is defined between the screen girdle sections 8h and 51h.
  • Spent liquor may be withdrawn from the upper screen of the section 51h and conducted with a conduit lllh to a second flash tank 112h.
  • Spent liquor is withdrawn via a conduit 109h from a lower screen of the section 51h and conducted back to the space defined above the first screen girdle section 8h so that the spent liquor may be remtroduced back to the lower screen of the second screen girdle section 51h via a central pipe 105h.
  • the temperature of the spent liquor may be controlled by a heat exchanger 13h.
  • the heat exchanger 13h is m operative engagement with a high pressure steam line 102h via a conduit 122h.
  • a cooking liquor conduit 24h is operatively attached to the conduit 109h to supply a cooking liquor, such as white liquor, to the conduit 109h.
  • the effective alkali of the liquor m the conduit 109h is at least about 35g/l; more preferably at least about 40g/l; and, most preferably, between about 45g/l and about 55g/l.
  • a third screen girdle section 104h may be arranged below the second screen girdle section 51h so that a concurrent cooking zone B is defined between the screen girdle sections 51h and 104h.
  • Draw-off from the third screen section 104h such as spent liquor, i.e., black liquor, may be conducted via a conduit 106h back to the conduit 17h.
  • the effective alkali of the spent liquor conducted m the conduit 106h is about lJg/1 or more.
  • a minor portion of the black liquor in the conduit 106h may be conducted to a first flash tan. 108h via a conduit 107h to cool the spent liquor before the liquor is conducted to a recovery unit llOh.
  • the spent liquor is also conducted through a second flash tank 112h via a conduit 114h to further reduce the temperature and pressure of the spent liquor before the liquor is conducted to the recovery unit 11 Oh.
  • the spent liquor from both flash tanks 108h, 112h are then conducted with a conduit 126h to the recovery unit llOh.
  • Conduits 128h and 130h may be connected to the flash tanks 108h, 112h, respectively, to provide steam that is sent to the chip bin 20A and the steaming vessel 20B.
  • a fourth lower screen girdle section 12h is disposed at the bottom lOh of the digester 6h so that a concurrent cooking zone C is defined between the sections 104h and 12h.
  • the girdle section 12h may, for example, include three rows of screens for withdrawing liquid, which is heated and to which some white liquor, preferably about 10. of the total amount of the white liquor the conduit 24h, is added via a branch conduit 117h before it is recirculated by means of a central pipe 123h, which opens up at about the same level as the lowermost strainer girdle 12h.
  • the draw-off from screen girdles 12h and the white liquor from the branch conduit 117h are preferably conducted via a heat exchanger 120h back to the bottom lOh of the digester 6h.
  • the conduit 122h is connected to the heat exchanger 120h to provide the heat exchanger 120h with steam to regulate the temperature of the white liquor m the conduit 116h.
  • the temperature of this draw off is normally about 130°C to 140°C.
  • the white liquor is supplied m a counter-current direction via the central pipe 123h to the screen girdle section 12h.
  • the white liquor provides fresh alkali and, m the form of counter-current cooking, further reducing the kappa number.
  • a blow line 26h may be connected to the bottom lOh of the digester for conducting the digested pulp away from the digester 6h.
  • a preferred installation according to the present invention may be described as follows.
  • the chips are fed into the chip bin 20A and are subsequently steamed m the vessel 20B and, thereafter, conveyed into the chute 20C.
  • the high-pressure feeder 19h which is supplied with a minor amount of white liquor (approximately 5 of the total amount to lubricate the feeder) , feeds the chips into the conduit 18h together with the transport liquid.
  • the slurry of chips and the liquid are fed to the top of the digester 6h and may have a temperature of about 110-120° C when entering the digester 6h (excluding recirculated transport liquor) .
  • top separator 7h Inside the top of the digester 6h, there is the top separator 7h that pushes chips in an upward direction through the separator and then the chips move slowly downwards in a plug flow through the impregnation zone A in a liquid/wood ratio between 2/1-10/1 preferably between 3/1-8/1, more preferred of about 4/1-6/1.
  • the liquor which is drawn off from the screen girdle section 8h, may be recirculated via the conduit 17h to the space below the top separator 7h. The chips are then thoroughly impregnated in the impregnation zone A.
  • a spent liquor is withdrawn at the upper segment of the screen section 51h and conducted to the second flash tank 112h.
  • a spent liquor is also withdrawn at the lower segment of the section 51h and remtroduced via the central pipe 105h with the addition of white liquor supplied by the conduit 24h.
  • the chips move down in the concurrent zone B through the digester 6h at a relatively low cooking temperature, i.e., between 130-160°C, preferably about 140-150° C.
  • the major part of the delignification takes place in the first concurrent cooking zone B.
  • the temperature in the lower counter-current zone C is preferably higher than in the concurrent zone B, i.e., preferably exceeding 140°C, preferably about 145-165°C, in order to dissolve remaining lignin.
  • the alkali content in the lowermost part of the counter-current cooking zone C should preferably be lower than in the beginning of the concurrent zone B, above 5g/l, but below 40g/l. Preferably less than 30g/l and more preferred between 10-20g/l.
  • the aim is to have a temperature difference of about 10°C between the concurrent zone B and the counter-current cooking zone C.
  • the conduit 116h may be charged with about 5-20., preferably 10-15O, white liquor from the conduit 24h via the conduit 117h.
  • the temperature of the liquid which is recirculated via the pipe 123h up to the screen girdle section 12h is regulated with the aid of the heat exchanger 120h so that the desired cooking temperature is obtained at the lowermost part of the counter- current cooking zone.
  • Fig. 9 shows a preferred embodiment of a two vessel hydraulic digesting system of the present invention.
  • This embodiment is very similar to the embodiment shown in Fig. 7 except that the digester 6d is a hydraulic digester so that the digester has a downwardly feeding top separator, as shown in Fig. 3.
  • the rest of the digesting system is virtually identical to the other embodiment.
  • the screen section 8d may be used to withdraw spent liquor that is conducted to a recovery unit. Draw-off from this screen girdle section 8d can also be conducted directly via the conduit 17d to the impregnation vessel Id.
  • a second screen girdle section 104d may be arranged below the first screen girdle section 8d (in an MCC digester, the screen girdle section 104d would normally be called the MCC screen) .
  • Draw-off from the second screen section 104d such as spent liquor, i.e., black liquor, may be conducted via a conduit 106d to a first flash tank 108d to recover steam and let pressure off before the liquor is conducted to a recovery unit llOd, as described in relation to Fig. 7.
  • Fig. 10 illustrates a further embodiment of the digesting system of the present invention. More particularly, the digesting system is a single vessel hydraulic digester system. Only the significant differences between this embodiment and the embodiments described earlier are detailed below.
  • a high-pressure feeder 19e feeds the chips suspended in a transport liquid D via a conduit 18e to the top of a digester 6e.
  • the conduit 18e may open up at the top of a top separator 7e that feeds by means of a screw in a downwardly moving direction.
  • the separator 7e is preferably identical or very similar to the top separator 7s that is shown in Fig. 3 and described in detail above.
  • the screen of the separator may be used to draw off the transport liquid D (which is then returned in a return line 15e) together with which the chips are transported from the feeder 19e up to the top 5e of the digester 6e.
  • a first screen girdle section 8e may be arranged in conjunction with a step-out approximately in the middle of the digester 6e .
  • Draw-off of spent liquor from a lower portion of the screen girdle section 8e may be conducted via the conduit 17e to an impregnation zone A that is defined between the screen girdle section 8e and the top 5e of the digester 6e.
  • the spent liquor that is withdrawn from an upper portion of the screen girdle section 8e may be conducted via a conduit llle to a second flash tank 112e.
  • a cooking liquor conduit 24e is operatively attached to the conduit 17e to supply a major part of the cooking liquor, such as white liquor, to the conduit 17e.
  • the effective alkali of the liquor in the conduit 17e is at least about 35g/l; more preferably at least about 40g/l; and, most preferably, between about 45g/l and about 55g/l.
  • Approximately 95 of the total supply of the white liquor in conducted in the conduit 24e and the remaining 5v. is supplied to the high pressure feeder 19e via a conduit 132e and a conduit 134e to lubricate the high pressure feeder 19e.
  • a second screen girdle section 104e may be arranged below the first screen girdle section 8e.
  • Draw-off from the second screen section 104e such as spent liquor, i.e., black liquor, may be conducted via a conduit 106e back to a top portion of the impregnation zone A.
  • the effective alkali of the spent liquor conducted in the conduit 106e is about 10-20 g/1.
  • a portion of the black liquor in the conduit 106e may be conducted to the flash tanks as described in the earlier embodiments.
  • the temperature of this draw off is about 130-150° C. The temperature may depend on how much washing-liquid that has penetrated to the screen is withdrawn.
  • the white liquor is supplied in a counter- current direction via a central pipe 123e to the screen girdle section 12e.
  • a major portion of the black liquor may directly (or via one flash tank) be fed into the impregnation zone A.
  • the total supply of black liquor to the impregnation zone A may exceed 80 of the amount drawn off from a draw-off screen girdle section 104e, preferably more than 90" and optimally about 100 of the total flow, which normally is about 8-12 m /ADT .
  • the chips then move down in the concurrent zone B through the digester 6e at a relatively low cooking temperature, i.e., between 130-160°C, preferably about 140-150°C.
  • a relatively low cooking temperature i.e., between 130-160°C, preferably about 140-150°C.
  • the major part of the delignification takes place in the first concurrent cooking zone B.
  • the temperature in the lower counter-current zone C is preferably higher than in the concurrent zone B, i.e., preferably exceeding 140°C, preferably about 145-165°C, in order to dissolve remaining lignin.
  • the alkali content in the lowermost part of the counter-current cooking zone C should preferably be lower than in the beginning of the concurrent zone B, above 5g/l, but below 40g/l. Preferably less than 30g/l and more preferred between 10-20g/l.
  • the aim is to have a temperature difference of about 10°C between the concurrent zone B and the counter-current cooking zone C.
  • the conduit 116e may be charged with about 5-20.,, preferably 10-15.>, white liquor from the conduit 24e via the conduit 117e.
  • Fig. 11 shows results from TCF bleaching using the cooking process (so called "new concept") of the present invention compared to a conventional reference cooking process.
  • the present invention provides a TCF- bleached pulp having extremely good bleachability a higher brightness is achieved compared to the conventional process for the same amount of peroxide consumption, and also a higher brightness ceiling is obtained.
  • Fig. 12 shows the tear index relative to the tensile index.
  • the test data that are related to the "new concept" are using the cooking process of the present invention and the conventional cooking process was using in reference ITC-digester .
  • FIG. 13 illustrates test data for the "new concept" (the present invention) and reference ITC-digester.
  • the present invention exhibits better tensile index compared to the conventional method.
  • Fig. 14 shows the brightness level by using the present invention (new concept) and reference cooked pulp (conventional process) .
  • the cooking process of the present invention results in a pulp that is much easier to bleach compared to the conventional cooking process, i.e. consumes less chemicals at a given brightness.
  • FIG. 15 shows a way of running the process in connection with an overloaded two vessel steam/liquid digester. Due to the overload (normally more than 30 ADMT pulp/hour and area as square meter in the final cooking zone (C) ) such a digester normally has difficulties to obtain a distinguished up-flow in the so called counter-current cooking zone. The final cooking zone C will therefore bee in form of a concurrent final cooking zone (C) . To run according to the invention this necessitate the existence/retrofit of a withdrawal strainer (12) positioned close to the bottom and retrofit of a withdrawal line 99 from said strainer 12. As can be seen, figure 15 is almost identical to Fig.
  • This wash liquor will partly flow upwards and displace the hot cooking liquor in the pulp moving downwards below the screen 12, and partly go out in the blowline 26 together with the pulp.
  • some wash liquor may be added by means of the central pipe 14 in order to radially displace hot cooking liquor.
  • the latter can be achieved by means of a stand pipe.
  • This method can also be used in connection with non over loaded digesters having problems to keep a sufficient up-flow (normally recommended to be at least 1.5 m3/ADMT pulp dilution factor for counter current cooking) m the final cooking zone C.
  • Fig. 16 describes a further embodiment of a two vessel hydraulic digester according to the present invention.
  • a conduit 24e conducts white liquor to a return line 15e.
  • the temperature of the white liquor may be controlled by a heat exchanger 13e that is adapted to receive steam from a high pressure steam conduit 102e.
  • the return line 15e terminates at a liquid exchanger 31e, which fulfils the same function as a top separator, i.e., it provides a very distinct exchange of treatment zones by almost totally withdrawing a first liquid from the chips and, subsequently, adding a second liquid so that any undesired mixing is avoided, the liquid changer 31e, m turn, has a mid-portion that is connected via a return line 33e to a bottom portion of an impregnation vessel le.
  • a slurry or the chips and transport liquid may be conducted from the bottom portion of the impregnation vessel le via a conduit 35e to a bottom end of the liquid exchanger 31e after exchange of liquid the chips are transported m a conduit 21e to the top of a digester 6e.
  • a portion of the spent liquor m the return line 33e is diverted and conducted to a second flash tank 114e via a conduit 137e for recovery.
  • Black liquor is withdrawn from a girdle section 8e of the digester 6e and conducted via a conduit 17e back to a top portion of the impregnation vessel le.
  • Spent liquor is also drawn off from a screen girdle section 104e and is conducted to a first flash tank 108e via a conduit 106e.
  • Fig. 17 shows an embodiment of the present invention which is similar to fig. 16. Only some of the most important differences are described. This embodiment has a digester 6f that does not have a screen girdle section at the top of the digester.
  • Fig. 18 illustrates an embodiment of the present invention which is similar to the embodiment shown m Fig. 17. Only some of the mam differences are described.
  • a high pressure feeder 19g feeds a slurry of chips to a bottom portion of a liquid exchanger 31g.
  • the object of this liquid exchanger is to ensure safe operation of the high pressure feeder at the same time as a high temperature (e.g., 130°C) is maintained at the top of an impregnation vessel lg, which is achieved by supplying hot black liquor to a conduit 21g via a conduit 17g.
  • the slurry is further conducted to a top of the impregnation vessel lg via a conduit 18g.
  • Relatively cool transport fluid is returned to the high pressure feeder 19g via a conduit 23g.
  • the temperature of the transport liquid can be kept low thanks to the total exchange of free liquid.
  • Fig. 19 illustrates a further embodiment of a single vessel hydraulic digester system of the present invention.
  • the chips are fed from a chip bin 20Ah, through a steaming vessel 20Bh and a chip chute 20Ch.
  • a feeding device preferably a high-pressure feeder 19h feeds the chips suspended m a transport liquid D via a conduit 18h to the top of a digester 6h.
  • the feeder 19h is co-operatmg with the chute 20Ch, and is connected to the necessary liquid circulations and replenishment.
  • the conduit 18h extends from the feeder 19h up to a top 5h of the digester 6h .
  • the conduit 18h may open up at the top of a top separator 7h that feeds by means of a screw m a downwardly moving direction.
  • the separator 7h is preferably identical or very similar to the top separator 7 that is shown m Fig. 3 and described m detail above.
  • the screen of the separator may be used to draw off the transport liquid D (which is then returned m a return line 15h) together with which the chips are transported from the feeder 19h up to the top 5h of the digester 6h .
  • a first screen girdle section 8h may be arranged conjunction with a step-out approximately m the middle of the digester 6h.
  • Draw-off of spent liquor from this screen girdle section 8 may be conducted via the conduit 17h to an impregnation zone A that is defined between the screen girdle section 8h and the top 5h of the digester 6h .
  • a portion of the spent liquor may be withdrawn from the screen girdle section 8h via a conduit lllh that conducts the spent liquor to a second flash tank 112h.
  • a cooking liquor conduit 24h is operatively attached to the conduit 17h to supply a major part of the cooking liquor, such as white liquor, to the conduit 17h.
  • a heat-exchanger 13h may heat up the white liquor and the spent liquor to a suitable temperature before the liquor enters the top 5h.
  • the heat exchanger 13h may be m operative engagement with a high pressure steam line 102h.
  • the effective alkali of the liquor m the conduit 17h is at least about 35g/l; more preferably at least about 40g/l; and, most preferably, between about 45g/l and about 55g/l.
  • Approximately 95 of the total supply of the white liquor m conducted m the conduit 24h and the remaining 5 is supplied to the high pressure feeder 19h via a conduit 132h and a conduit 134h to lubricate the high pressure feeder 19h.
  • a second screen girdle section 104h may be arranged below the first screen girdle section 8h.
  • Draw-off from the second screen section 104h such as spent liquor, i.e., black liquor, may be conducted via a conduit 106h back to a top portion of the impregnation zone A.
  • the effective alkali of the spent liquor conducted m the conduit 106h is about 10-20g/l.
  • a portion of the black liquor m the conduit lU6h may be conducted to a first flash tank 108h via a conduit 107h to cool the spent liquor before the liquor is conducted to a recovery unit llOh.
  • the spent liquor is also conducted through a second flash tank 112h via a conduit 114h to further reduce the temperature and pressure of the spent liquor before the liquor is conducted to the recovery unit llOh.
  • the spent liquor from both flash tanks 108h, 112h are then conducted with a conduit 126h to the recovery unit llOh.
  • Conduits 128h and 130h may be connected to the flash tanks 108h, 112h, respectively, to provide steam that is sent to the chip bin 20Ah and the steaming vessel 20Bh.
  • a third lower screen girdle section 12h is disposed at the bottom lOh of the digester 6h .
  • the girdle section 12h may, for example, include three rows of screens for withdrawing liquid, which is heated and to which some white liquor, preferably about 10 of the total amount of the white liquor m the conduit 24h, is added via a branch conduit 117h before it is recirculated by means of a central pipe 123h, which opens up at about the same level as the lowermost strainer girdle 12h.
  • the draw-off from screen girdles 12h and the white liquor from the branch conduit 117h are preferably conducted via a heat exchanger 120h back to the bottom lOh of the digester 6h.
  • the high pressure steam conduit 102h is connected to the heat exchanger 120h to provide the heat exchanger 120h with steam to regulate the temperature of the white liquor m the conduit 116h.
  • the temperature of this draw off is about 130-150°C. The temperature may depend on how much washmg-liquor that has penetrated to the screen is withdrawn.
  • the white liquor is supplied m a counter-current direction via the central pipe 123h to the screen girdle section 12h.
  • the white liquor provides fresh alkali and, in the form of counter-current cooking, further reducing the kappa number.
  • a blow line 26h may be connected to the bottom lOh of the digester for conducting the digested pulp away from the digester 6h.
  • a preferred installation according to the present invention may be described as follows.
  • the chips are fed into the chip bin 20Ah and are subsequently steamed m the vessel 20Bh and, thereafter, conveyed into the chute 20Ch.
  • the high-pressure feeder 19h which is supplied with a minor amount of white liquor (approximately 5 of the total amount to lubricate the feeder) , feeds the chips into the conduit 18h together with the transport liquid.
  • the slurry of chips and the liquid are fed to the top of the digester 6h and may have a temperature up to 110-120° C when entering the digester 6h (excluding recirculated transport liquor).
  • Hot black- liquor which is drawn off from the screen girdle section 104h, may be added, via the conduit 106h, to the top of the impregnation zone A of the digester 6h.
  • the black liquor may also be added to other sections of the digester such as to an intermediate section thereof.
  • the high temperature of the black liquor (100-160° C) , preferably exceeding 130° C, more preferred between 130-160° C, ensures rapid heating of the chips flowing through the impregnation zone A.
  • the relatively high pH, exceeding pH 10 of the black liquor neutralises acidic groups in the wood and also any acidic condensate accompanying the chips, thereby, i.e., counteracting the formation of encrustation, so-called scaling.
  • an additional advantage of the method of the present invention is that the black liquor supplied into the impregnation zone A has a high content of rest alkali, (effective alkali EA as NaOH), at least 13g/l, preferably about or above 16g/l and more preferred between 13-30g/l in the top of the impregnation zone A.
  • This alkali mainly comes from the black liquor due to the high amount of alkali in the concurrent zone B of the digester 6h.
  • the strength properties of the fibers are positively affected by the impregnation because of the high amount of sulphide.
  • a major portion of the black liquor may directly (or via one flash tank) be fed into the impregnation zone A.
  • the total supply of black liquor to the impregnation zone A may exceed 80. of the amount drawn off from the draw-off screen girdle section 104h, preferably more than 90" and optimally about 100 of the total flow, which normally is about 8-12 ⁇ X/ADT.
  • the retention time in the impregnation zone A should be at least 20 minutes, preferably at least 30 minutes and more preferred at least 40 minutes. However, a shorter retention time than 20 minutes, such as 15-20 minutes may also be used.
  • the chips which have been thoroughly impregnated and partially delignified in the impregnation zone A, may be fed to the top of the digester 6h and conveyed into the downwardly-feeding top separator 7h.
  • the chips are thus fed upwards through the screen, meanwhile free transport liquid may be withdrawn outwardly through the separator screen and finally the chips fall down into the digester 6h.
  • the chips pieces are drained with cooking liquor, such as white liquor, which is supplied at the top separator 7h.
  • the quantity of white liquor that is added at the top separator 7h depends on how much white liquor possibly is added else where.
  • the thoroughly impregnated chips very rapidly assimilate the active cooking chemicals by diffusion, since the concentration of alkali (EA as NaOH) is relatively high, at least 20g/l, preferably between 30g/l and SOg/1 and more preferred about 40g/l.
  • the chips then move down in the concurrent zone B through the digester 6h at a relatively low cooking temperature, i.e., between 130-160°C, preferably about 140-150°C.
  • a relatively low cooking temperature i.e., between 130-160°C, preferably about 140-150°C.
  • the major part of the delignification takes place the first concurrent cooking zone B.
  • the liquid-wood ratio should be at least 2/1 and should be below 7/1, preferably m the range of 3/1-5.5/1, more preferred between 3.5/1 and 5/1. (The liquid wood-ratio m the counter-current cooking zone should be about the same as m the concurrent cooking zone . )
  • the temperature m the lower counter-current zone C is preferably higher than m the concurrent zone B, i.e., preferably exceeding 140°C, preferably about 145-165°C, order to dissolve remaining lignm.
  • the alkali content m the lowermost part of the counter-current cooking zone C should preferably be lower than m the beginning of the concurrent zone B, above 5g/l, but below 40g/l. Preferably less than 30g/l and more preferred between 10-20g/l.
  • the aim is to have a temperature difference of about 10°C between the concurrent zone B and the counter-current cooking zone C.
  • the conduit 116h may be charged with about 5-20 , preferably 10-15o, white liquor from the conduit 24h via the conduit 117h.
  • the temperature of the liquid which is recirculated via the pipe 123h up to the screen girdle section 12h is regulated with the aid of the heat exchanger 120h so that the desired cooking temperature is obtained at the lowermost part of the counter-current cooking zone.
  • Fig. 20 illustrates an embodiment of the present invention, which is substantially similar to the embodiment shown in Fig. 19.
  • Chips and a transport fluid is pumped up in a conduit 18i and a conduit 119i to a top section 5i of a digester 6i via a liquid exchanger 33i.
  • the function and operation of the liquid exchanger is similar to the liquid exchanger 31g shown in Fig. 18. As described earlier, liquid is exchanged in the liquid exchanger 33i before the chips enter the top section 5i of the digester 6i.
  • a portion of the transport liquid may be returned in return line 15i that leads from the top portion 5i to a mid-section of the liquid exchanger 33i and then back to a feeder 19i via a conduit 25i .
  • the conduit 106i conducts the spent liquor withdrawn from a screen girdle section 104i to the liquid from 117i and to the conduit 15i.
  • a portion of the liquor in the conduit 106i may be sent to a flash tank 108i.
  • Fig. 21 also shows an embodiment of the present invention, which is similar to what is shown in Fig. 19. Some of the more important differences are described herein.
  • the eleventh embodiment has a digester 6j having a return line 15j attached to a top portion 5j of the digester 6j .
  • a recirculation line lOlj is in fluid communication with the return line 15j so that a portion of the liquid in the return line 15j may be diverted back to the top portion 5j via the line lOlj .
  • the temperature of the liquid in the recirculation line lOlj may be regulated with a heat exchanger 113j that is operatively engaged with a high pressure steam line 102j .
  • the recirculation line is used to heat the liquid from the return line 15 before the liquid is introduced.
  • the temperature m the return line 15j must not exceed about 100°C to avoid undesirable flashing m the high pressure feeder.
  • a flash tank 108 is m fluid communication via a conduit 106j to a screen girdle section 104j so that spent liquor from the section 104j may be conducted to the flash tank 108j .
  • a bottom portion of the flash tank 108j has a conduit 103 connected thereto to conduct a portion of the spent liquor back to a conduit 134j that carries some white liquor from the ( ookmg liquor conduit 24j .
  • Fig. 22 describes an embodiment of the present invention, which is similar to the embodiment shown Fig. 21 but it does not have the recirculation line lOl that is associated with the return line. Instead the embodiment includes a digester 6k having an additional screen girdle section 200k that is disposed immediately below a top section 5k.
  • the girdle section 200k has a recirculation line 201k in fluid communication therewith.
  • the recirculation line 201k withdraws cooking liquor from the girdle section 200k and recirculates it back up to a point that is immediately below a top separator 7k disposed inside the top portion 5k.
  • the temperature of the liquor m the line 201k may be controlled by a heat exchanger 203k that is m operative engagement with a high pressure steam line 102k.
  • the mam reason for using the recirculation line 201k is to improve the distribution of the white liquor that is withdrawn from the girdle section 200k.
  • the method of recirculating the cooking liquor is often called quench circulation.
  • Fig. 23 shows a preferred embodiment of a separator to be used together with a hydraulic digester or an impregnation vessel that is part of a digester system, such as the digester system shown in Fig. 1, where there is a need for a heat seal.
  • the advantage of providing the heat seal adjacent the separator is to enable the injection of hot black liquor (above 100°C) into the top of the vessel without risking to operate the high pressure feeder at too high of a temperature.
  • the heat seal reduces or even eliminates the risk of any hot liquor being inadvertently conducted back through the top separator to the high pressure feeder which may damage the feeder.
  • the separator may also be used m a single vessel hydraulic digester if required. Only a top portion of such an impregnation vessel 1 or a digester is shown.
  • the non-impregnateci slurred fiber material is transferred to the top of the impregnation vessel or the digester by means of the transfer line 321, which is peripherally attached to the vessel wall 1 and opens up into a inlet space 330.
  • the screw-feeder is attached to a shaft 332 connected to a drive-unit 333 which is attached to a mountmg-plate 334 at the top of the vessel shell 1.
  • the drive-shaft 332 is rotated m a direction so as to force the screw to feed the chips and the transport fluid a downward direction.
  • the new design eliminates the prior problem m relation to the mounting plate, which prior had to be moulded due to the inlet passing there through.
  • the plate 334 may be made from any suitable standard steel (which is much cheaper) .
  • the rotor 332 would not normally be equipped witn screw blades.
  • the top of the screen 335 is integrated with a cylindrical shell 338 having a flange 339 resting on the top of the vessel.
  • the top portion 341 of the screen 335 is supported by the vessel 1 but merely radially, i.e.
  • the screen-basket 335 is arranged withm the vessel shell 1 so as to define a liquid collecting space 336 between the digester shell and the outer surface of the screen-basket 335.
  • the liquid collecting space 336 which preferably is annular, communicates with a conduit for withdrawing liquid from the liquid collecting space 336, which m turn is replenished by liquid from the slurry withm the screen basket 335.
  • the major part of the free liquid withm the slurry entering the screen basket is withdrawn into the liquid collecting space 336, but a small portion of free liquid, at least about 0.5 m /ADT should not be withdrawn from the slurry.
  • the top section of the vessel 1 has a diameter (d) that is less than a diameter (D) of the vessel at a mid-portion and bottom portion thereof, preferably d ⁇ D/2. Furthermore the length/height of the top section (having d) has to be substantially more than d.
  • the distance h between the lowermost part of the screen-basket 335 and the transition zone 65 (cylmdrical/frustoconical ) is equal to or larger than d, more preferred h>l,2 d.
  • the diameter (d) is small to reduce or even avoid any substantial heat transfer to the T-C lines so that the T-C lines may maintain a maximum temperature that is maximum slightly above 100°C, but normally below 100°C. In this way, a heat lock zone is formed between the liquid supply devices (for supplying hot black liquor) and the liquid collecting space 336.
  • new on-line measuring systems for example using NIR-spectroscopy
  • new on-line measuring systems provide for the possibility of exactly measuring specific contents of the fibre material and the liquids entering the digesting system, which will make it feasible to more precisely determine and control the supply/addition of specific fluids/chemicals and also their withdrawal m order to establish optimised conditions.
  • Different kind of additives can be very beneficial to use, especially for example poly-sulphide which has a better effect in a low temperature environment than m high temperatures.
  • AQ Application AQ (Anthraqumone) would be very beneficial since it combines very well with high alkaline environments.
  • a centrally arranged inlet as described in WO-havmg a spreading device can be contrived, which device, in a known way, provides a mushroom-like film of liquid, as can a centrally arranged showering element or an annular pipe with slots, etc.
  • the number of screen girdles shown is m no way limiting for the invention but, instead, the number can be varied m dependence on different requirements. It is likewise obvious that the invention is m no way limited to a certain screen configuration and it is understood that bar screens can be exchanged by, for example, such as screens having slots cut out of sheet metal. Also some installations moveable screens are preferred. Furthermore, it will be evident to the person skilled m the art that, m order to amplify the heat economy, measures can be taken which decrease heat losses from the digester, such as, for example, insulation of the digester shell and/or maximisation of the volume in relation to the outwardly exposed surface, i.e. increasing the cross-sectional area.
  • the shown system m front of the digester is in no way limiting to the invention, e.g. it is possible to exclude the steaming vessel and have a direct connection between the chip bm (for example, a partly filled atmospheric vessel) and the chip chute.
  • the chip bm for example, a partly filled atmospheric vessel
  • other kind of feeding systems than an HP- feeder may be used, e.g. DISCFLO '" -pumps) .

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  • Inorganic Chemistry (AREA)
  • Paper (AREA)

Abstract

Nouveau procédé amélioré de cuisson continue de matière fibreuse, selon lequel les températures et les teneurs en alcalis sont régulées de manière à être maintenues à des niveaux spécifiques dans différentes zones du processus de lessivage afin d'optimiser la consommation de produits chimiques et les économies de chaleur et parallèlement, d'obtenir une pâte présentant d'excellentes propriétés. La matière fibreuse est chauffée et imprégnée à l'aide de liqueur noire à une température inférieure à 140 °C et transférée dans un courant principal vers une zone d'imprégnation (A). La matière fibreuse chauffée et imprégnée est transférée dans une zone de cuisson (B) à courant principal située dans une partie supérieure d'un lessiveur (6). Au moins 60 % de la quantité de liqueur (F) requise pour la réaction de cuisson est introduite dans l'extrémité amont de la zone de cuisson (B) à courant principal afin d'obtenir une teneur effective en alcalis dépassant 35g/l. La température de cuisson dans la zone de cuisson (B) à courant principal est inférieure à 160 °C. La liqueur épuisée (E), dont la teneur effective en alcalis est d'au moins 13g/l, est retirée par passage à travers une ceinture-filtre (8). Une partie importante de la liqueur épuisée est transférée dans la zone d'imprégnation.
PCT/SE1998/000225 1997-02-09 1998-02-09 Procede et dispositif de cuisson continue de pate WO1998035091A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
AT98903344T ATE201064T1 (de) 1997-02-09 1998-02-09 Verfahren und vorrichtung zur kontinuierlichen zellstoffkochung
DE69800767T DE69800767T2 (de) 1997-02-09 1998-02-09 Verfahren und vorrichtung zur kontinuierlichen zellstoffkochung
PCT/SE1998/000225 WO1998035091A1 (fr) 1997-02-09 1998-02-09 Procede et dispositif de cuisson continue de pate
EP98903344A EP0909353B1 (fr) 1997-02-09 1998-02-09 Procede et dispositif de cuisson continue de pate
CA002279283A CA2279283C (fr) 1997-02-09 1998-02-09 Procede et dispositif de cuisson continue de pate
AU60109/98A AU6010998A (en) 1998-02-09 1998-02-09 Method and device for the continuous cooking of pulp

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ALPCT/SE97/00192 1997-02-09
PCT/SE1998/000225 WO1998035091A1 (fr) 1997-02-09 1998-02-09 Procede et dispositif de cuisson continue de pate

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WO1998035091A1 true WO1998035091A1 (fr) 1998-08-13

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011066189A1 (fr) * 2009-11-24 2011-06-03 Andritz Inc. Procédé et système pour la cuisson de copeaux minces dans un lessiveur
WO2016038251A1 (fr) * 2014-09-12 2016-03-17 Andritz Oy Chauffage de digesteurs hydrauliques

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2639987A (en) * 1947-07-09 1953-05-26 Ass Pulp & Paper Mills Two-stage pulping process
US5089086A (en) * 1989-04-27 1992-02-18 Jaakko Poyry Oy Process for continuous cooking of cellulose
WO1995018261A1 (fr) * 1993-12-29 1995-07-06 Kvaerner Pulping Technologies Ab Procede et dispositif pour la cuisson continue de la pate a papier
WO1996007786A1 (fr) * 1994-09-02 1996-03-14 Kamyr, Inc. Procede de cuisson continue de pate kraft avec pretraitement de la liqueur noire
US5635026A (en) * 1995-11-13 1997-06-03 Ahlstrom Machinery Inc. Cooking cellulose material with high alkali concentrations and/or high pH

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2639987A (en) * 1947-07-09 1953-05-26 Ass Pulp & Paper Mills Two-stage pulping process
US5089086A (en) * 1989-04-27 1992-02-18 Jaakko Poyry Oy Process for continuous cooking of cellulose
WO1995018261A1 (fr) * 1993-12-29 1995-07-06 Kvaerner Pulping Technologies Ab Procede et dispositif pour la cuisson continue de la pate a papier
WO1996007786A1 (fr) * 1994-09-02 1996-03-14 Kamyr, Inc. Procede de cuisson continue de pate kraft avec pretraitement de la liqueur noire
US5635026A (en) * 1995-11-13 1997-06-03 Ahlstrom Machinery Inc. Cooking cellulose material with high alkali concentrations and/or high pH

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011066189A1 (fr) * 2009-11-24 2011-06-03 Andritz Inc. Procédé et système pour la cuisson de copeaux minces dans un lessiveur
CN102666974A (zh) * 2009-11-24 2012-09-12 安德里兹有限公司 用于薄碎屑蒸煮器蒸煮的方法和系统
US8641865B2 (en) 2009-11-24 2014-02-04 Andritz Technology And Asset Management Gmbh Method and system for thin chip digester cooking
AU2010324993B2 (en) * 2009-11-24 2014-05-22 Andritz Inc. Method and system for thin chip digester cooking
CN102666974B (zh) * 2009-11-24 2015-09-09 安德里兹有限公司 用于薄碎屑蒸煮器蒸煮的方法和系统
WO2016038251A1 (fr) * 2014-09-12 2016-03-17 Andritz Oy Chauffage de digesteurs hydrauliques
US10240287B2 (en) 2014-09-12 2019-03-26 Andritz Oy Heating of hydraulic digesters

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