WO1998021373A2 - Process for reducing fume emissions during molten metal transfer - Google Patents
Process for reducing fume emissions during molten metal transfer Download PDFInfo
- Publication number
- WO1998021373A2 WO1998021373A2 PCT/EP1997/006938 EP9706938W WO9821373A2 WO 1998021373 A2 WO1998021373 A2 WO 1998021373A2 EP 9706938 W EP9706938 W EP 9706938W WO 9821373 A2 WO9821373 A2 WO 9821373A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- carbon dioxide
- snow
- beaching
- molten metal
- station
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D45/00—Equipment for casting, not otherwise provided for
- B22D45/005—Evacuation of fumes, dust or waste gases during manipulations in the foundry
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
- C21B7/14—Discharging devices, e.g. for slag
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/06—Constructional features of mixers for pig-iron
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0037—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00 by injecting powdered material
Definitions
- molten crude iron or ferro anganese is currently introduced into a casting bed when tapping a blast furnace, in open air, that is, free air access to the molten material is permitted.
- free air access causes several problems.
- the atmospheric oxygen oxidizes the crude iron or f rromanganese and the resultant oxides rise as pollutants or dust and pollute the surrounding air.
- some of the carbon released from crude iron during cooling burns off in atmospheric oxygen resulting in additional emissions.
- Liquid nitrogen has been used in the region of the tapping runner in an attempt to reduce iron oxide pollution by preventing free-air access.
- liquid nitrogen is extremely cold, thus, requiring additional and expensive safety measures for storage and handling.
- undesired nitriding of the crude iron may reduce the quality of the steel produced.
- Fume emission remains problematic wherever molten steel or iron is transferred in steelmaking processes, regardless, of whether it be from container to container or from container to ground or a pit, whether indoors or outdoors. Notably, when iron beaching operations are performed indoors, it is usually necessary to evacuate all mill personnel due to the large amount of red or brown iron oxide fumes produced. Of course, when such operations are effected outside, the iron oxide fumes escape into the atmosphere unabated.
- a process for transferring molten metal with reduced fume, dust and/or smoke emission which entails blanketing the molten metal with, at least, solid carbon dioxide, and allowing the solid carbon dioxide to sublime, thereby restricting free air access to the molten metal, and reducing fume, dust and/or smoke emission therefrom.
- Figure 1 illustrates an overall schematic of a fume suppression system of the present invention.
- Figure 2 illustrates a snow horn or cannon of the present invention for iron beaching.
- Figure 3 illustrates a snow cannon housing for iron beaching in accordance with the present invention with a) showing a side view and b) showing a front or rear view.
- a means is now provided for reducing dust and pollutant emission during the transfer of molten metals, particularly steel or iron in steelmaking processes, without introducing additional atmospheric nitrogen and oxygen into the molten metal and with or without using protective hoods.
- Carbon dioxide in solid state is applied in the vicinity (i.e. over, under and/or around) of the molten material.
- the solid carbon dioxide is applied to a molten metal to prevent air access in the region of the tapping runner, the downstream rocking runner, the torpedo ladle and/or at least a portion of a casting bed, for example.
- the solid carbon dioxide may be applied directly on top of and/or below the molten material and/or to these runners and vessels before and/or during contact with the molten material .
- a convenient technique for applying the carbon dioxide in a solid state in accordance with this aspect of the present invention entails, for example, the use of one or more carbon dioxide snow horns or cannons for charging the tapping region with carbon dioxide.
- the carbon dioxide may be applied to the tapping region at the time of, or just before, the application of the molten metal.
- it may be convenient to charge the system with carbon dioxide in the same sequence as the molten metal. That is, the carbon dioxide is applied to the tapping region in the following sequence: the tapping runner, rocking runner, torpedo ladle and/or the casting bed.
- the carbon dioxide may be applied in a solid, or even, if desired, in a combined solid and gaseous mixture, by means of a special snow cannon, both directly on the tapping side and at several points along the runner.
- the carbon dioxide snow floats on the molten material up to the entrance to the rocking runner.
- additional carbon dioxide gas is continually released into the atmosphere reducing the partial pressures of atmospheric oxygen and nitrogen.
- the exclusion of air can readily be controlled and adjusted in accordance with the conditions at the time by the use of varying amounts of carbon dioxide snow.
- the carbon dioxide snow of the present invention is similar to water-ice snow at a temperature of about -110°F. Further, solid carbon dioxide sublimes to carbon dioxide gas at 8.5 ft /lb. at STP . Generally, in accordance with the present invention, solid carbon dioxide is preferable to gaseous carbon dioxide in application as the former has a lesser cooling effect on the overall system heat .
- the surface area of the molten material is increased many times as the material is transferred from the tapping runner to the rocking runner by the casting jet.
- the surface area also increases substantially as the molten material is transferred from the rocking runner to the torpedo ladle.
- these increases in surface area lead to a substantial intensification of undesired oxidation, dust and pollution emissions and nitriding of the molten material .
- gaseous carbon dioxide displaces atmospheric oxygen and nitrogen as the carbon dioxide snow is applied simultaneously to both the molten material within the rocking runner and to the casting jet from the crude iron runner to the rocking runner, for example.
- the use of carbon dioxide in accordance with the present invention substantially reduces not only the fume, dust and/or smoke emissions associated with the tapping region of a blast furnace but also the nitriding of the molten material and the addition wear of refractory material .
- the substantial reductions in down time for relining and repair dramatically reduces costs and extends service life and capacity.
- the present invention provides a carbon dioxide fume suppression system having one or more stations .
- This system may be widely used in molten metal transfers in modern iron or steel-making or non- ferrous metal production, such as production of aluminum, magnesium or copper.
- An example of this system may be seen in Figure 1.
- Figure 1 illustrates a fume suppression system having six stations, each having four snow horns. Each station has a corresponding test panel which, in turn, is in electrical communication with a main operator panel. Each station is fed from a carbon dioxide storage tank which is in electrical communication with telemonitoring means for monitoring liquid level and refrigeration status. From Figure 1, it is seen that the system also includes various ball and check valves, pressure and relief switches as well as vapor solenoid and vent solenoid valves.
- This system utilizes a process wherein carbon dioxide, either alone or in admixture with other non-oxidizing gases such as argon, is used as an inert gas to blanket the molten metal from exposure to oxygen and nitrogen in the atmosphere. This inhibits the formation of iron oxide which is the reddish- brown or orange fume typically created in the transfer of molten iron or steel, such as is observed when beaching torpedo ladle cars .
- carbon dioxide is transported from a bulk liquid storage tank or cylinders to the area of application in a refrigerated liquid state about, at pressures ranging from about 200 to 300 psig.
- the liquid carbon dioxide is subjected to a pressure drop down to atmospheric pressure through a flow restricting discharge nozzle on the end of the snow horn or cannon to allow a specific amount of liquid carbon dioxide flow.
- the liquid carbon dioxide initially converts to a solid dry ice and cold gas mixture at about -110°F inside the horn or cannon.
- the horn is especially designed to focus the trajectory of the solid carbon dioxide snow to the application point .
- Figure 2 illustrates an exemplary snow horn of the present invention.
- the snow horn contains a snow nozzle inside of a socket and conic plug as shown.
- the particular snow horn shown in Figure 2 has a hexagonal nipple R 3/8" conic, welded cap 1 1/4", socket R 3/8" and conic plug R 3/8".
- Figure 3 illustrates an exemplary snow horn housing of the present invention. Specifically, Figure 3a illustrates a side view of a torpedo ladle at the housing with snow horns, whereas Figure 3b illustrates with a front or rear view of the same.
- an important aspect of the present invention entails the use of properly designed snow horns, cannon or devices to increase the effectiveness of carbon dioxide in inerting and blanketing applications, by taking advantage of the density of solid snow so that it can be carried to the desired application point, and by also taking advantage of the tremendous solid-to-gas sublimation expansion factor to facilitate purging atmospheric oxygen from the area.
- an inert environment is provided to protect molten metal from oxidation, and, hence, reduce formation of the ambiguously observed reddish-brown fume in the case of iron or steel.
- carbon dioxide gas has a density of about
- Solid carbon dioxide snow has a density of about 20 to 30 lbs/ft. after settling. Further, in accordance with the present invention, the snow horns or devices have a length to diameter ratio in the range of about 1.5:1 to 3:1.
- the number of snow horns and size of the discharge nozzles may vary in accordance with the overall objective of blanketing the top and sides of the molten metal. By carefully positioning the horns or devices to effect a preferred distribution of snow relative to the molten iron stream flow path, it is possible to increase utilization effectiveness .
- the present system presents a viable alternative to a more capital and labor intensive dust capturing system, which would typically involve an overhead canopy, baghouse, fan, and interconnecting ductwork with dampers and controls.
- this more complicated methodology may now be avoided.
- the present system In addition to significantly reducing visible emissions, the present system also dramatically reduces the time required for the beaching building air quality analyzers (CO,S0 2 ) to indicate "all clear” after the dump. This reduction in ambient air “clearout” time allows personnel to enter the building more quickly after a ladle dump. This allows for a reduction in ladle turnaround time and, hence, improves overall productivity.
- CO,S0 2 beaching building air quality analyzers
- the present invention also provides a storage system which may include an automated telemonitoring system for continuous remote monitoring of liquid cryogen level and refrigeration unit status, however, any conventional tank monitoring system may be used.
- the system may be advantageously connected via a telephone line to a local monitoring station whereby liquid cryogen level in the vessel and refrigeration unit status may be monitored daily or even more frequently as deemed necessary.
- Liquid level in the vessel may be measured continuously by an electronic liquid level transmitter. If the liquid level falls below a prescribed lower limit, notification may be made automatically via the telemonitoring system. Refrigeration unit status is determined by tank pressure; likewise, if tank pressure rises above the normal prescribed operating range, indicating that the refrigeration unit has malfunctioned, notification may be made via the telemonitoring station.
- the system of the present invention significantly reduces visible fumes given off during the beaching of iron torpedo car ladles. When carbon dioxide is employed, upon sublimation of the carbon dioxide snow from solid to gas, a tremendous expansion occurs which causes a purging effect in the immediate area of the iron or steel.
- Carbon Dioxide Snow Horns An adequate number of carbon dioxide snow horns or cannons are provided for each station.
- Each carbon dioxide snow horn includes a liquid carbon dioxide discharge nozzle. Liquid carbon dioxide, at a supply pressure of about 200 to 300 psig, is discharged through the nozzle into the horn.
- the snow horns are specially designed to facilitate formation of solid carbon dioxide snow, and to focus the trajectory of the snow to the application point. Specifically, it is important to project the snow with sufficient velocity to overcome air flow caused by hot metal. This improves the utilization efficiency of the carbon dioxide in inerting applications, by taking advantage of the density of solid snow so that it can be carried to the application point, and by also taking advantage of the extremely large solid-to-gas sublimation expansion factor.
- the carbon dioxide snow is carried by cold gas and not by itself.
- each iron beaching station different horn sizes in combination with various discharge nozzle sizes are used in order to maximize efficiency and the flowrate and trajectory of carbon dioxide snow at each distribution point.
- a total of 2 different horn sizes and 3 different discharge nozzle sizes are typically implemented
- hoods are installed at each station over the pouring area in front of each car.
- the hoods help contain emitted fumes and carbon dioxide, cut down on "chimney effect" air infiltration into the pouring area which is a source of oxygen for iron oxidation, and provide a framework for mounting the snow horns.
- the mounting position of each horn within the mounting hoods is adjusted so that carbon dioxide snow is distributed in desired areas relative to the molten iron stream being poured from the ladle car.
- each snow horn or cannon within the mounting hoods is generally adjusted so that carbon dioxide snow is distributed in areas to where the molten metal stream is being poured from the ladle car, the horns or cannons are mounted primarily in areas where air would be drawn into contact with the molten metal stream.
- the present system may utilize , one or more commercially available bulk carbon dioxide storage tanks. Typical sizes range from about 6 to 100 tons.
- a commercial bulk carbon dioxide storage tank which is preferred in accordance with the present invention is an ASME coded pressure vessel rated for an approximately 350 psig working pressure, and insulated to reduce heat input.
- a mechanical refrigerator unit may be used to recondense vaporized liquid.
- a pressure building vaporizer may be required to maintain a uniform storage pressure and compensate for the pressure decrease caused by carbon dioxide withdrawal .
- the housing should preferably snugly house the torpedo.
- it is the volume of carbon dioxide that creates the requisite pressure and pushes air out.
- the opening of the torpedo car be completely covered.
- a plurality of snow horns which are well placed as described above. Any number or size of horns may be used as needed. The specifics of the snow horns are shown on the following schematic. carbon dioxide Supply: 30 ton bulk tank.
- a control system consisting of a set of valves and other required major components, along with a main operator control panel plus individual station test panels, is included in the equipment package.
- the operator can energize the system, pressurize the system piping, discharge carbon dioxide to the selected station, automatically purge the system piping of liquid carbon dioxide when complete, and depressurize the system.
- liquid carbon dioxide forms dry ice that can block piping if the pressure falls below the triple point (60 psig, -70°F) .
- the operator control panel may be tied in with the existing facility control panel for movement of ladle cars so that car movement and carbon dioxide discharge is properly coordinated.
- the system is, of course, designed and manufactured to comply with applicable codes and standards and, in particular, with OSHA 1910-147 lockout/tagout energy control procedures for U.S. installations.
- Hood(s) are placed into position at desired station (s) .
- Limit switch interlock requires hood to be in position before carbon dioxide discharge is allowed at any given station.
- Ladle car(s) are set in position at each hood.
- Relay interlock requires (tilt motor) power to be activated at any given ladle car before carbon dioxide discharge is allowed at dW station.
- Carbon dioxide system control panel is energized (main on-off lever) .
- Panel "test bypass” selector switch is turned to the off position.
- Carbon dioxide system piping is pressurized.
- Relay interlock allows carbon dioxide discharge only at station selected for tilting in step 5 above. Carbon dioxide discharge is allowed at only one station at a time.
- Carbon dioxide discharge rate is preferably constant throughout the pouring process.
- ambient carbon dioxide concentration levels inside the building workspace should be reduced to safe levels within the same time required for the other currently monitored species (CO, S0 2 ) to be reduced to safe levels.
- the "test bypass" selector switch on the main operator panel allows testing or demonstrating the system without a "live" pour. After first moving the hood(s) into position, and then energizing and pressurizing the system from the main operator panel and selecting "test bypass on", the individual station test panels can then be used to discharge carbon dioxide snow to each individual station (one station at a time only) . When each station test panel is turned off, liquid carbon dioxide is automatically purged, as in step 9 above.
- in-line vapor check valve pressure gauges as required stainer(s) as required - one main operator control panel, in stainless steel cabinet includes pre-wired and pre-assembled pushbuttons, selectors switches, indicator lights, relays and other components as required six individual station test panels, pre-wired and pre-assembled (each includes selector switches, and other components as required) .
- pre-wired and pre-assembled pushbuttons as required for a pre-wired and pre-assembled pushbuttons
- selectors switches indicator lights
- relays and other components as required six individual station test panels, pre-wired and pre-assembled (each includes selector switches, and other components as required) .
- interconnecting piping and minor piping components such as tees, elbows, and fittings are not included.
- the carbon dioxide storage system of the present invention also may include a system for telemonitoring of liquid level and refrigeration unit status.
- fume suppression system is merely one example of the system of the present invention and many variations therefrom are contemplated within the scope of this invention.
- torpedo ladle cars of about 200 to 250 tons capacity are often used, any capacity may be used.
- any number and size of carbon dioxide snow horns may be employed. For example, if torpedo ladle cars of reduced capacity (relative to 200-250 tons) are used, fewer carbon dioxide snow horns might be used, such as from 1 to 3 per station, for a total of 6 to 18 for 6 stations. Conversely, if torpedo ladle cars of enhanced capacity (relative to 200-250 tons) are used more carbon dioxide snow horns might be used, such as from 5 to 8 per station, for a total of 30 to 48 for 6 stations .
- the present system may be used in many applications in steel and other metals production, from oxygen lancing to molten metal transfer.
- molten metal transfers above, the following applications may be noted: blast furnace tapping, beach iron dumping, re-ladling, mixer tapping, BOF tapping and EAF tapping.
- metal slag or scrap cutting the following applications may be noted: slag button lancing; continuous caster tundish lancing; ladle slide gate lancing; scrap, billet, and revert cutting; and carbon powder injection.
- the present invention is preferably used in iron beaching operations.
- the processes and systems of the present invention may be used to advantage.
- sulfur in copper is liberated as sulfur dioxide if the molten copper is transferred through air.
- the present invention may be used to great advantage in alleviating such problems.
- cryogenic carbon dioxide is transformed in solid carbon dioxide snow when exposed to a pressure drop of from at lest about 200 psig, preferably at least about 250 psig, more preferably about at least 280 psig to atmospheric pressure.
- the carbon dioxide snow is directed in a transfer vessel to purge out all atmospheric gases, such as nitrogen and oxygen. As the carbon dioxide snow sublimates it expands, thereby creating a positive pressure inside the transfer vessel. With the removal of atmospheric gases, gas pick-up and fume generation are dramatically reduced.
- Fume suppression was impressive. - Fume development is not a determined size. Even during one run-off and under apparently same conditions changes can be measured Due to carbon dioxide regulation which is adapted to the fume development, the specific high consumption of 10 kg carbon dioxide/to pig iron was considerably reduced. The measured carbon dioxide content which is intensified directly near the housing, was reduced by a defined stack effect to the maximum working place concentration (30 ppm) .
- Torpedo capacity 220 to hot metal normally: 150-170 to hm
- Pouring speed without carbon dioxide 5 to hot metal/min. with carbon dioxide 15 to hot metal/min.
- Specific consumption 5 kg carbon dioxide/to hot metal
- Results - fume suppression of 90-95% was obtained; and an increase of pouring speed was thereby, made possible.
- the objective of this experiment was to reduce airborne emissions and iron oxide fumes during beaching of iron.
- a carbon dioxide cannon was placed under a torpedo car aimed at a molten metal stream.
- Fume suppression of greater than 90% was noted. It was also noted that carbon dioxide worked surprisingly better than an additional fume capture hood.
- the present invention is used for fume suppression, using either pure carbon dioxide or carbon dioxide in admixture with other inert gases, during iron beaching operations in a steel mill.
- the present invention affords a reduction of fume of greater than 90%.
- the present multi-station system affords a dramatically reduced required time for beaching building air quality analyzers (CO, S0 2 ) to indicate "all clear" after the dump. This reduces ladle turnaround time and improves overall productivity.
- the present invention generally provides fume reduction of 90% or more, reduced dust generation, reduced pick-up of oxygen and nitrogen, increased operator visibility, reduced dust load to baghouse and a cleaner, safer working environment .
- Inert gases in general may be used instead of carbon dioxide, preferably nitrogen (especially liquid nitrogen) or argon (especially liquid argon) , alone or in combination with carbon dioxide or even a small amount of air which does not cause substantial fumes.
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97950207A EP0946762A2 (en) | 1996-11-08 | 1997-11-03 | Process for reducing fume emissions during molten metal transfer |
AU53234/98A AU5323498A (en) | 1996-11-08 | 1997-11-03 | Process for reducing fume emissions during molten metal transfer |
JP52220098A JP2001503817A (en) | 1996-11-08 | 1997-11-03 | A method for reducing fume emissions during the movement of molten metal. |
CA002270949A CA2270949A1 (en) | 1996-11-08 | 1997-11-03 | Process for reducing fume emissions during molten metal transfer |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US74631096A | 1996-11-08 | 1996-11-08 | |
US08/746,310 | 1996-11-08 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1998021373A2 true WO1998021373A2 (en) | 1998-05-22 |
WO1998021373A3 WO1998021373A3 (en) | 1998-08-20 |
Family
ID=25000290
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1997/006938 WO1998021373A2 (en) | 1996-11-08 | 1997-11-03 | Process for reducing fume emissions during molten metal transfer |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0946762A2 (en) |
JP (1) | JP2001503817A (en) |
AU (1) | AU5323498A (en) |
CA (1) | CA2270949A1 (en) |
WO (1) | WO1998021373A2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012098169A1 (en) * | 2011-01-19 | 2012-07-26 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method and nozzle for suppressing the generation of iron-containing vapor |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5407186B2 (en) * | 2008-06-09 | 2014-02-05 | Jfeスチール株式会社 | Dust generation prevention method in remaining hot water return work |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0071359A1 (en) * | 1981-07-23 | 1983-02-09 | Uss Engineers And Consultants, Inc. | Methods and apparatus for molten metal fume supression |
US4666511A (en) * | 1985-04-01 | 1987-05-19 | L'air Liquide | Process for producing killed steel having a low nitrogen content |
FR2607829A1 (en) * | 1986-12-09 | 1988-06-10 | Cootec Deutschland Gmbh | Process for the treatment of steel in a ladle |
EP0383184A1 (en) * | 1989-02-14 | 1990-08-22 | INTRACON Handelsgesellschaft für Industriebedarf mbH | Method of decreasing the fume emission and the free entry of air in the tap hole region of a blast furnace |
EP0544967A1 (en) * | 1991-11-28 | 1993-06-09 | Carbagas | Process for suppression of dust and fumes during electric steel production |
EP0639650A1 (en) * | 1993-08-18 | 1995-02-22 | The Commonwealth Industrial Gases Limited | CO2 snow discharge apparatus |
-
1997
- 1997-11-03 WO PCT/EP1997/006938 patent/WO1998021373A2/en not_active Application Discontinuation
- 1997-11-03 AU AU53234/98A patent/AU5323498A/en not_active Abandoned
- 1997-11-03 EP EP97950207A patent/EP0946762A2/en not_active Withdrawn
- 1997-11-03 CA CA002270949A patent/CA2270949A1/en not_active Abandoned
- 1997-11-03 JP JP52220098A patent/JP2001503817A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0071359A1 (en) * | 1981-07-23 | 1983-02-09 | Uss Engineers And Consultants, Inc. | Methods and apparatus for molten metal fume supression |
US4666511A (en) * | 1985-04-01 | 1987-05-19 | L'air Liquide | Process for producing killed steel having a low nitrogen content |
FR2607829A1 (en) * | 1986-12-09 | 1988-06-10 | Cootec Deutschland Gmbh | Process for the treatment of steel in a ladle |
EP0383184A1 (en) * | 1989-02-14 | 1990-08-22 | INTRACON Handelsgesellschaft für Industriebedarf mbH | Method of decreasing the fume emission and the free entry of air in the tap hole region of a blast furnace |
EP0544967A1 (en) * | 1991-11-28 | 1993-06-09 | Carbagas | Process for suppression of dust and fumes during electric steel production |
EP0639650A1 (en) * | 1993-08-18 | 1995-02-22 | The Commonwealth Industrial Gases Limited | CO2 snow discharge apparatus |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012098169A1 (en) * | 2011-01-19 | 2012-07-26 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method and nozzle for suppressing the generation of iron-containing vapor |
US9162785B2 (en) | 2011-01-19 | 2015-10-20 | L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude | Method and nozzle for suppressing the generation of iron-containing vapor |
RU2606666C2 (en) * | 2011-01-19 | 2017-01-10 | Л'Эр Ликид Сосьете Аноним Пур Л'Этюд Э Л'Эксплуатасьон Де Проседе Жорж Клод | Method and nozzle for suppressing generation of iron-containing vapour |
Also Published As
Publication number | Publication date |
---|---|
EP0946762A2 (en) | 1999-10-06 |
CA2270949A1 (en) | 1998-05-22 |
WO1998021373A3 (en) | 1998-08-20 |
AU5323498A (en) | 1998-06-03 |
JP2001503817A (en) | 2001-03-21 |
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