WO1998015261A1 - Wässrige perlglanzdispersionen - Google Patents
Wässrige perlglanzdispersionen Download PDFInfo
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- WO1998015261A1 WO1998015261A1 PCT/EP1997/005347 EP9705347W WO9815261A1 WO 1998015261 A1 WO1998015261 A1 WO 1998015261A1 EP 9705347 W EP9705347 W EP 9705347W WO 9815261 A1 WO9815261 A1 WO 9815261A1
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- pearlescent
- carbon atoms
- fatty
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- alkyl
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Definitions
- the invention relates to aqueous pearlescent concentrates containing monoglyceride (ether) sulfates, emulsifiers and optionally polyols, a process for their preparation, a further process for the production of pearlescent surface-active preparations using the concentrates and the use of the fatty substances as pearlescent waxes.
- the prior art knows a large number of formulations which give surface-active agents the desired pearlescence.
- pearlescent concentrates in the form of flowable aqueous dispersions which contain 15 to 40% by weight of pearlescent components, 5 to 55% by weight.
- Emulsifiers and 0.1 to 5 or 15 to 40 wt .-% polyols contain.
- the pearlescent waxes are acylated polyalkylene glycols, monoalkanolamides. linear, saturated fatty acids or ketosulfones.
- nonionic, flowable pearlescent dispersions can also be obtained by mixing mixtures of 5 to 30% by weight of acylated polyglycols and 0.1 to 20% by weight of selected nonionic surfactants manufactures.
- EP-A2 0 581 193 (Hoechst) flowable, preservative-free pearlescent dispersions are also known which contain acylated polyglycol ethers, betaines, anionic surfactants and glycerol.
- polyglycerol esters as crystallization aids for the production of pearlescent concentrates is proposed in European patent application EP-A1 0 684 302 (Th.Goldschmidt).
- the invention relates to aqueous pearlescent concentrates containing - based on the nonaqueous fraction -
- the monoglyceride (ether) sulfates have excellent pearlescent properties and are distinguished from the products of the prior art by a higher brilliance with less use, particularly fine particle size and storage stability.
- the pearlescent waxes are easily biodegradable, thin in a concentrated form and allow also the incorporation of problematic ingredients such as silicones in cosmetic preparations.
- Monoglyceride sulfates and monoglyceride ether sulfates are known anionic surfactants which can be obtained by the relevant methods of preparative organic chemistry.
- the usual starting point for their preparation is triglycerides, which, if appropriate, are transesterified to the monoglycerides after ethoxylation and subsequently sulfated and neutralized.
- suitable sulfating agents preferably gaseous sulfur trioxide or chlorosulfonic acid [cf. EP-B1 0 561 825, EP-B1 0 561 999 (Henkel)].
- the neutralized substances can be subjected to ultrafiltration in order to reduce the electrolyte content to a desired level [DE-A1 42 04 700 (Henkel)].
- Overviews of the chemistry of the monoglyceride sulfates are, for example, by A.K.Biswas et al. in J.Am.Oil.Chem.Soc. 37, 171 (1960) and F.U.Ahmed J.Am.Oil.Chem.Soc. 67, 8 (1990).
- R 1 CO stands for a linear or branched acyl radical with 6 to 22 carbon atoms, x, y and z in total for 0 or for numbers from 1 to 30, preferably 2 to 10, and X stands for an alkali or alkaline earth metal.
- Typical examples of monoglyceride (ether) sulfates suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyceride and tallow fatty acid onoglyceride as well as their ethylene oxide adducts or their formulated with sulfuric acid with sulfuric acid trioxide.
- Monoglyceride sulfates of the formula (I) are preferably used in which R 1 CO represents a linear acyl radical having 8 to 18 carbon atoms.
- the pearlescent concentrates according to the invention can contain nonionic surfactants from at least one of the following groups as emulsifiers: (b1) adducts of 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide with linear
- Glycerin (b3) Glycerol mono- and diesters and sorbitan mono- and diesters of saturated and unsaturated
- Fatty acids with 6 to 22 carbon atoms and their ethylene oxide addition products (b4) alkyl mono- and oligoglycosides with 8 to 22 carbon atoms in the alkyl radical and their ethoxylated analogs; (b5) adducts of 15 to 60 moles of ethylene oxide with castor oil and / or hardened castor oil; (b6) polyol and especially polyglycerol esters such as e.g. Polyglycerol polyricinoleate or polyglycerol poly-12-hydroxystearate.
- the adducts of ethylene oxide and / or of propylene oxide with fatty alcohols, fatty acids, alkylphenols, glycerol mono- and diesters, and sorbitan mono- and diesters with fatty acids or with castor oil are known, commercially available products. These are mixtures of homologs, the middle of which Degree of alkoxylation corresponds to the ratio of the amounts of ethylene oxide and / or propylene oxide and substrate with which the addition reaction is carried out.
- Ci2 / i8 fatty acid monoesters and diesters of adducts of ethylene oxide with glycerol are known from DE-PS 20 24 051 as refatting agents for cosmetic preparations.
- C ⁇ / i ⁇ alkyl mono- and oligoglycosides their preparation and their use as surface-active substances are, for example, from US 3,839,318, US 3,707,535, US 3,547,828, DE-OS 19 43 689, DE-OS 20 36 472 and DE-A1 30 01 064 and EP-A 0 077 167 are known. They are produced in particular by reacting glucose or oligosaccharides with primary alcohols with 8 to 18 carbon atoms.
- the glycoside residue it applies that both monoglycosides in which a cyclic sugar residue is glycosidically bonded to the fatty alcohol and oligomeric glycosides with an oligomerization degrees up to preferably about 8 are suitable.
- the degree of cigomerization is a statistical mean value which is based on a homolog distribution customary for such technical products.
- anionic emulsifiers of the alkyl ether sulfate type which follow the formula (II) are used as component (b),
- R 2 is a linear or branched alkyl and / or alkenyl radical having 6 to 22 carbon atoms
- n is a number from 1 to 10
- X is an alkali metal and / or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium.
- Typical examples are the sulfates of addition products with an average of 1 to 10 and in particular 2 to 5 moles of ethylene oxide with capron alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, oleostyl alcohol, isostyl alcohol Elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures, in the form of their sodium and / or magnesium salts.
- the ether sulfates can have both a conventional and a narrow homogeneous distribution. It is particularly preferred to use ether sulfates based on adducts of an average of 2 to 3 mol ethylene oxide with technical C12 / 14 or C12 / 18 coconut oil alcohol fractions in the form of their sodium and / or magnesium salts.
- Zwitterionic surfactants can also be used as emulsifiers.
- Zwitterionic surfactants are surface-active compounds that contain at least one quaternary ammonium group and at least one carboxylate and one sulfonate group in the molecule.
- Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, Nd imethylammonium glycinate, for example coconut alkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate, for example coconut acylaminopropyldimethylammonium glycinate, and 2-alkyl-3-carboxylm 3-hydroxy-ethylimidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group, as well as the cocoacylaminoethylhydroxyethylcarboxymethylglycinate.
- betaines such as the N-alkyl-N, Nd imethylammonium glycinate, for example coconut alkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate
- fatty acid amide derivative known under the CTFA name Cocamidopropyl Betaine is particularly preferred.
- Suitable emulsifiers are ampholytic surfactants.
- Ampholytic surfactants are surface-active compounds which, in addition to a C ⁇ / i ⁇ -alkyl or -acyl group, contain at least one free amino group and at least one -COOH or -SO3H group in the molecule and are capable of forming internal salts.
- ampholytic surfactants are N-alkylglycine, N-alkylpropionic acid, N-alkylaminobutyric acid, N-alkylimino dipropionic acid, N-hydroxyethyl-N-alkylamidopropylglycine, N-alkyltaurine, N-alkyl sarcosine, 2-alkylaminopropionic acid and alkylaminoacetic acid each with about 8 to 18 carbon atoms in the alkyl group.
- Particularly preferred ampholytic surfactants are N-coconut alkyl aminopropionate, the Kokosacylaminoethylaminopropionat and the C ⁇ 2 / ⁇ -acylsarcosine.
- quaternary emulsifiers are also suitable, those of the esterquat type, preferably methyl-quaternized difatty acid triethanolamine ester salts, being particularly preferred.
- the pearlescent concentrates according to the invention can contain the emulsifiers in amounts of 0.1 to 90, preferably 5 to 50 and in particular 10 to 40% by weight.
- Polyols which are considered as component (c) in the context of the invention preferably have 2 to 15 carbon atoms and at least two hydroxyl groups. Typical examples are
- Alkylene glycols such as, for example, ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols with an average molecular weight of 100 to 1,000 daltons;
- Methyl compounds such as in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol;
- Lower alkyl glucosides especially those with 1 to 8 carbons in the alkyl radical such as methyl and butyl glucoside;
- Sugar alcohols having 5 to 12 carbon atoms such as, for example, sorbitol or mannitol,
- Aminosugars such as glucamine.
- the pearlescent concentrates according to the invention can contain the polyols, preferably glycerol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols with an average molecular weight in the range from 100 to 10000 in amounts of 0.1 to 40, preferably 0.5 to 15 and in particular 1 to 5% by weight. % contain.
- the pearlescent concentrates are prepared by producing a mixture of components (a), (b) and (c), heated to a temperature which is 1 to 30 ° C. above the melting point of the mixture lies, mixes with the required amount of water at about the same temperature and then cools to room temperature. It is also possible to provide a concentrated aqueous (anion) surfactant paste, stir in the pearlescent wax while hot and then dilute the mixture to the desired concentration with further water, or to mix in the presence of polymeric hydrophilic thickeners, such as hydroxypropyl celluloses, xanthan gum or To carry out polymers of the carbomer type.
- a concentrated aqueous (anion) surfactant paste stir in the pearlescent wax while hot and then dilute the mixture to the desired concentration with further water, or to mix in the presence of polymeric hydrophilic thickeners, such as hydroxypropyl celluloses, xanthan gum or To carry out polymers of the carbomer type.
- the pearlescent concentrates according to the invention are suitable for setting turbidity in surface-active preparations such as, for example, hair shampoos or manual dishwashing detergents.
- Another object of the invention therefore relates to a process for the preparation of cloudy and pearlescent liquid, aqueous preparations of water-soluble surfactants, in which the clear aqueous preparations at 0 to 40 ° C, the pearlescent concentrates in an amount of 0.5 to 40, preferably 1 to 20% by weight of the preparation is added and distributed therein with stirring.
- the preparations according to the invention can contain further typical pearlescent waxes.
- Typical representatives of this are glycol mono- and / or difatty acid esters, e.g. Glycol mono- and / or distearate, fatty acid alkanolamides, e.g. Stearic acid monoethanolamide, partial glycerides, e.g. Glycerol monostearate, esters of polyvalent carboxylic acids with fatty alcohols, e.g. Malonic acid distearate and long chain dialkyl ethers, e.g. Distearyl ether.
- glycol mono- and / or difatty acid esters e.g. Glycol mono- and / or distearate
- fatty acid alkanolamides e.g. Stearic acid monoethanolamide
- partial glycerides e.g. Glycerol monostearate
- esters of polyvalent carboxylic acids with fatty alcohols e.g. Malonic acid diste
- the surface-active preparations which generally have a non-aqueous content in the range from 1 to 50 and preferably 5 to 35% by weight, can contain nonionic, anionic, cationic and / or amphoteric or amphoteric surfactants, the proportion of which in the Average is usually about 50 to 99 and preferably 70 to 90 wt .-%.
- anionic surfactants are soaps, alkylbenzenesulfonates, aikansulfonates, olefin sulfonates, alkyl ether sulfonates, glycerin ether sulfonates, ⁇ -methyl ester sulfonates, sulfo fatty acids, alkyl sulfates, glycerin ether sulfates, hydroxymixed ether sulfates, fatty acid amide sulfate, monosulfonate sulfate amate sulfate amate sulfate amate sulfate amate sulfate amate sulfate amate sulfate amate sulfate amate sulfate amate sulfate amate and sulfate amate sulfate amate sulfate amate sulfate, Sulfotriglycerides, amide soap
- anionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
- Typical examples of nonionic surfactants are fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, fatty acid polyglycol esters, fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, alkoxylated triglycerides, mixed ethers or mixed formals, alk (en) yl oligoglycosides, fatty acid N-alkyl glucose acid, vegetable ester polyglycol acid, vegetable hydrolysate, vegetable hydrolysate, vegetable hydrolysate, vegetable hydrolysate, vegetable hydrolysate, vegetable hydrolysate, vegetable hydrolysate, vegetable hydrolysate, vegetable hydrolysate, vegetable hydrolysate, protein hydrolysate, protein hydrolysate, and protein hydrolysate, especially , Sorbitan esters, polysorbates and
- nonionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
- Typical examples of cationic surfactants are quaternary ammonium compounds and ester quats, in particular quaternized fatty acid trialkanolamine ester salts.
- Typical examples of amphoteric b-zw. zwitterionic surfactants are alkyl betaines, alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines. The surfactants mentioned are exclusively known compounds.
- the surface-active preparations, to which the pearlescent concentrates according to the invention are added can contain further auxiliaries and additives, such as, for example, oil bodies, superfatting agents, stabilizers, waxes, consistency agents, thickeners, cation polymers, silicone compounds, biogenic active ingredients, antidandruff agents, film formers, preservatives, hydrotropes, solu bilisators, UV adsorbers, dyes and fragrances.
- auxiliaries and additives such as, for example, oil bodies, superfatting agents, stabilizers, waxes, consistency agents, thickeners, cation polymers, silicone compounds, biogenic active ingredients, antidandruff agents, film formers, preservatives, hydrotropes, solu bilisators, UV adsorbers, dyes and fragrances.
- Suitable oil bodies are, for example, Guerbet alcohols preferably containing 8 to 10 carbon atoms, esters of linear C6-C come based on fatty alcohols having 6 to 18, 20 fatty acids with linear C6-C20 fatty alcohols, esters of branched C6-Ci3-carboxylic acids with linear C6-C 2 o-fatty alcohols, esters of linear C6-Ci8 fatty acids with branched alcohols, in particular 2-ethylhexanol, esters of linear and / or branched fatty acids with polyhydric alcohols (such as dimer diol or trimer triol) and / or Guerbet alcohols, triglycerides based C ⁇ -Cio fatty acids, vegetable oils, mixed branched primary alcohols, substituted cyclohexanes, Guerbet carbonates, dialkyl ethers and / or aliphatic or naphthenic hydrocarbons.
- esters of linear C6-C come
- Substances such as lanolin and lecithin and polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides can be used as superfatting agents, the latter simultaneously serving as foam stabilizers.
- As consistency agents primarily fatty alcohols with 12 to 22 and preferably 16 to 18 carbon atoms come into consideration. A combination of these substances with alkyl oligoglucosides and / or fatty acid N-methyl glucamides of the same chain length and / or polyglycerol poly-12-hydroxystearates is preferred.
- Suitable thickeners are, for example, polysaccharides, in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, and also higher molecular weight polyethylene glycol mono- and diesters of fatty acids, polyacrylates, polyvinyl alcohol and polyvinyl pyrodon, surfactants such as for example ethoxylated fatty acid glycerides, esters of fatty acids with polyols such as pentaerythritol or trimethylolpropane, fatty alcohol ethoxylates with a narrow homolog distribution or alkyl oligoglucosides as well as electrolytes such as table salt and ammonium chloride.
- polysaccharides in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose
- Suitable cationic polymers are, for example, cationic cellulose derivatives, cationic starch, copolymers of diallylammonium salts and acrylamides, quaternized vinylpyrrolidone / vinylimidazole polymers such as e.g. Luviquat® (BASF AG, Ludwigshafen / FRG), condensation products of polyglycols and amines, quaternized collagen polypeptides such as lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat®L, Grünau GmbH), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers such as e.g.
- Amidomethicone or Dow Corning, Dow Corning Co./US copolymers of adipic acid and dimethylaminohydroxypropyldiethylenetrimamine (Cartaretine®, Sandoz / CH), polyaminopoiyamides such as e.g. described in FR-A 22 52 840 and its crosslinked water-soluble polymers, cationic chitin derivatives such as quaternized chitosan, optionally microcrystalline, condensation products of dihaloalkylene such as e.g. Dibromobutane with bisdialkylamines such as Bis-dimethylamino-1, 3-propane, cationic guar gum such as e.g. Jaguar® CBS, Jaguar® C-17, Jaguar® C-16 from Celanese / US, quaternized ammonium salt polymers such as Mirapol® A-15, Mirapol® AD-1, Mirapol® AZ-1 from Miranol / US.
- Suitable silicone compounds are, for example, dimethylpolysiloxanes, methylphenylpolysiloxanes, cyclic silicones and amino-, fatty acid-, alcohol-, polyether-, epoxy-, fluorine- and / or alkyl-modified silicone compounds, which can be both liquid and resinous at room temperature.
- Typical examples of fats are glycerides; beeswax, paraffin wax or microwaxes may be used as waxes, if appropriate in combination with hydrophilic waxes, for example cetylstearyl alcohol.
- pearlescent waxes such as, in particular, mono- and difatty acid esters of polyalkylene glycols, partial and triglycerides as well Esters of fatty alcohols with polyvalent carboxylic acids or hydroxycarboxylic acids are used.
- Metal salts of fatty acids such as magnesium, aluminum and / or zinc stearate can be used as stabilizers.
- Biogenic active substances are understood to mean, for example, bisabolol, allantoin, phytantriol, panthenoi, AHA acids, plant extracts and vitamin complexes. Climbazole, octopirox and zinc pyrethione can be used as anti-dandruff agents.
- Common film formers are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone-vinyl acetate copolymers, polymers of the acrylic acid series, quaternary cellulose derivatives, collagen, hyaluronic acid or its salts and similar compounds.
- Hydrotropes such as ethanol, isopropyl alcohol, propylene glycol or glucose can also be used to improve the flow behavior.
- Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, parabens, pentanediol or sorbic acid.
- the dyes which can be used are those substances which are suitable and approved for cosmetic purposes, as compiled, for example, in the publication "Cosmetic Dyes” by the Dye Commission of the German Research Foundation, Verlag Chemie, Weinheim, 1984, pp. 81-106. These dyes are usually used in concentrations of 0.001 to 0.1% by weight, based on the mixture as a whole.
- the total proportion of auxiliaries and additives can be 1 to 50, preferably 5 to 40,% by weight, based on the composition.
- the agents can be produced by customary cold or hot processes; the phase inversion temperature method is preferably used.
- the pearlescent concentrates R1 to R6 according to the invention and the comparison mixture R7 were stored at 40 ° C. for 14 days and the viscosity was determined using the Brookfield method in an RVT viscometer (23 ° C., 10 rpm, spindle 5).
- Aqueous hair shampoo formulations were then prepared by mixing the starting materials at 20 ° C., each containing 2 g of the pearlescent concentrates R1 to R7, 15 g coconut oil alcohol + 2EO sulfate sodium salt, 3 g dimethylpolysiloxane, 5 g coconut alkyl glucoside and 1.5 g of an ester quat (water ad 100 wt .-%) contained.
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
- Colloid Chemistry (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97910388A EP0930872B1 (de) | 1996-10-07 | 1997-09-29 | Wässrige perlglanzdispersionen |
JP10517144A JP2001501634A (ja) | 1996-10-07 | 1997-09-29 | 水性の真珠光沢分散物 |
DE59707439T DE59707439D1 (de) | 1996-10-07 | 1997-09-29 | Wässrige perlglanzdispersionen |
AU47794/97A AU4779497A (en) | 1996-10-07 | 1997-09-29 | Aqueous pearly lustre dispersions |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19641280.3 | 1996-10-07 | ||
DE19641280A DE19641280C2 (de) | 1996-10-07 | 1996-10-07 | Verwendung von Monoglycerid(ether)sulfaten als Perlglanzwachse |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998015261A1 true WO1998015261A1 (de) | 1998-04-16 |
Family
ID=7808060
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1997/005347 WO1998015261A1 (de) | 1996-10-07 | 1997-09-29 | Wässrige perlglanzdispersionen |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0930872B1 (de) |
JP (1) | JP2001501634A (de) |
AU (1) | AU4779497A (de) |
DE (2) | DE19641280C2 (de) |
ES (1) | ES2177950T3 (de) |
WO (1) | WO1998015261A1 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004506592A (ja) * | 1999-05-07 | 2004-03-04 | コグニス・ドイチュラント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | 真珠光沢剤界面活性剤組成物の製法 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0031824D0 (en) * | 2000-12-29 | 2001-02-14 | Unilever Plc | Detergent compositions |
ES2339187T5 (es) * | 2006-12-08 | 2013-12-12 | Unilever N.V. | Procedimiento de fabricación de composiciones tensioactivas concentradas |
MX352278B (es) | 2011-06-23 | 2017-11-16 | Procter & Gamble | Proceso de formacion de cristales para usar en una composicion para el cuidado personal. |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2158122A1 (de) * | 1970-11-27 | 1972-06-22 | Colgate Palmolive Co | Zahnreinigungsmittel und Verfahren zu deren Herstellung |
US4329334A (en) * | 1980-11-10 | 1982-05-11 | Colgate-Palmolive Company | Anionic-amphoteric based antimicrobial shampoo |
US4368147A (en) * | 1974-10-03 | 1983-01-11 | Colgate-Palmolive Company | Liquid detergent of controlled viscosity |
GB2126603A (en) * | 1982-09-02 | 1984-03-28 | Colgate Palmolive Co | Transuculent soaps and processes for manufacture thereof |
EP0407041A2 (de) * | 1989-06-21 | 1991-01-09 | Colgate-Palmolive Company | Gelöste Polyniedrigalkylen enthaltende faserpflegende Mittel |
EP0413417A2 (de) * | 1989-06-21 | 1991-02-20 | Colgate-Palmolive Company | Haarpflegendes Shampoo |
WO1995006702A1 (de) * | 1993-09-02 | 1995-03-09 | Henkel Kommanditgesellschaft Auf Aktien | Wässrige detergensgemische |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5224144A (en) * | 1991-09-12 | 1993-06-29 | American Science And Engineering, Inc. | Reduced mass flying spot scanner having arcuate scanning lines |
GB2280682A (en) * | 1993-06-30 | 1995-02-08 | Procter & Gamble | Effective control of ammonia odor in hexangonal phase detergent gels containing urea |
-
1996
- 1996-10-07 DE DE19641280A patent/DE19641280C2/de not_active Expired - Fee Related
-
1997
- 1997-09-29 JP JP10517144A patent/JP2001501634A/ja active Pending
- 1997-09-29 ES ES97910388T patent/ES2177950T3/es not_active Expired - Lifetime
- 1997-09-29 DE DE59707439T patent/DE59707439D1/de not_active Expired - Fee Related
- 1997-09-29 WO PCT/EP1997/005347 patent/WO1998015261A1/de active IP Right Grant
- 1997-09-29 EP EP97910388A patent/EP0930872B1/de not_active Expired - Lifetime
- 1997-09-29 AU AU47794/97A patent/AU4779497A/en not_active Abandoned
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2158122A1 (de) * | 1970-11-27 | 1972-06-22 | Colgate Palmolive Co | Zahnreinigungsmittel und Verfahren zu deren Herstellung |
US4368147A (en) * | 1974-10-03 | 1983-01-11 | Colgate-Palmolive Company | Liquid detergent of controlled viscosity |
US4329334A (en) * | 1980-11-10 | 1982-05-11 | Colgate-Palmolive Company | Anionic-amphoteric based antimicrobial shampoo |
GB2126603A (en) * | 1982-09-02 | 1984-03-28 | Colgate Palmolive Co | Transuculent soaps and processes for manufacture thereof |
EP0407041A2 (de) * | 1989-06-21 | 1991-01-09 | Colgate-Palmolive Company | Gelöste Polyniedrigalkylen enthaltende faserpflegende Mittel |
EP0413417A2 (de) * | 1989-06-21 | 1991-02-20 | Colgate-Palmolive Company | Haarpflegendes Shampoo |
WO1995006702A1 (de) * | 1993-09-02 | 1995-03-09 | Henkel Kommanditgesellschaft Auf Aktien | Wässrige detergensgemische |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004506592A (ja) * | 1999-05-07 | 2004-03-04 | コグニス・ドイチュラント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | 真珠光沢剤界面活性剤組成物の製法 |
Also Published As
Publication number | Publication date |
---|---|
EP0930872A1 (de) | 1999-07-28 |
JP2001501634A (ja) | 2001-02-06 |
ES2177950T3 (es) | 2002-12-16 |
EP0930872B1 (de) | 2002-06-05 |
AU4779497A (en) | 1998-05-05 |
DE59707439D1 (de) | 2002-07-11 |
DE19641280A1 (de) | 1998-04-16 |
DE19641280C2 (de) | 1999-09-16 |
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