Keratin Fibre Modifying Compositions
Technical Field
This invention relates to modification of keratin fibres, particularly permanently altering the configuration of hair such as permanent waving. Background Art
The stability of keratin fibres is due to disulfide bonds and hydrogen bonds between neighbouring polypeptide chains. Keratin fibres such as hair are softened by wetting with water as water enters the hydrogen bonds of the hair. Temporary reshaping of hair can be obtained by deformation of wet hair. After drying, the new shape will be held until the hair contacts moisture whereupon it will soften again.
Permanent reshaping of hair can be obtained using a reducto- oxidative process whereby the disulfide bonds of the hair are broken using a reducing agent; the hair is set into the desired configuration such as straight or wavy; the hair is then rinsed to remove the reducing agent followed by oxidisation using an oxidising agent such as hydrogen peroxide or a bromate salt to reform disulfide bonds and harden the hair into the new imposed shape.
By "reducto-oxidative process" is meant treating the keratin fibre first with a reducing agent, removing said reducing agent and then treating the keratin fibre with an oxidative agent.
Typical reducing agents include sulphites and mercaptans (thiols) such as thioglycolic acid salts, eg ammonium thioglycolate, and thioglycolic acid esters, eg glycerol thioglycolate. Other thiol containing reagents such as thiolactic acid, beta-mercapto propionic acid, beta-mercapto butyric acid, mercapto succinic acid and the like are also effective.
The effectiveness of the reduction/oxidation process in permanently altering the configuration of hair depends on many factors including the condition of the hair, the nature of the reducing agent and the skill of the operator in setting the hair into the desired configuration and applying the reducing/oxidising agents. A disadvantage of the reduction/oxidation process is a loss of mechanical properties of the hair such as reduced tensile strength and elasticity and increased porosity. Various additives for the reducing agent have been proposed to reduce the loss of mechanical properties and improve the end result of the process.
Disclosure of the Invention
It has now been found that the effectiveness of the reducing agent in relation to subsequent curl retention after a permanent waving process can be enhanced by applying a quaternaiy ammonium compound having at least one C12.22 carbon chain substituent to the hair simultaneously with the reducing agent or subsequent to application of the reducing agent but before application of the oxidising agent.
The invention is equally applicable to permanent straightening of hair and subsequent retention of the straightened configuration and to modifying the configuration of keratin fibres in general. The term "keratin fibres" includes human hair, wool and animal hair and bristles.
In a first aspect, the present invention provides a method for modifying a keratin fibre comprising: applying a reducing agent to the keratin fibre and setting the fibre into a desired configuration; simultaneously or subsequently applying an aqueous solution comprising at least 1% w/w, preferably 1 to 20% w/w of one or more non- polymeric quaternary ammonium compounds having one C12.2Z carbon chain substituent and three C^ alkyl substituents each being the same or different; rinsing the keratin fibre to substantially remove the reducing agent; and applying an oxidising agent to the keratin fibre.
Preferably, the keratin fibre is then rinsed with water. In a second aspect, the present invention provides a method for the permanent waving or straightening of hair comprising: applying a reducing agent to the hair and setting the hair into a desired configuration; simultaneously or subsequently applying an aqueous solution comprising at least 1%, preferably 1 to 20% WIVJ of one or more non - polymeric quaternary ammonium compounds having one C
12-22 carbon chain substituent and three
alkyl substituents each being the same or different; rinsing the hair to substantially remove the reducing agent; and applying an oxidising agent to the hair.
The hair may then be rinsed with water.
In a third aspect, the present invention provides the use of one or more substantially water-soluble non-polymeric quaternary ammonium compounds having one C12.22 carbon chain substituent and three C1-6 alkyl substituents each being the same or different in a reducto-oxidative process for permanent waving or straightening of hair.
In a fourth aspect, the present invention provides a composition for use in the permanent waving or straightening of hair comprising 1 to 20% w/w of one or more substantially water-soluble non-polymeric quaternary ammonium compounds having one C12.22 carbon chain substituent and three alkyl substituents each being the same or different, and a reducing agent. As used herein, the term "quaternary ammonium compound" means a non-polymeric ammonium compound in which all four hydrogen atoms are substituted by radicals.
The quaternary ammonium compounds of the present invention have one C12.22 carbon chain substituent. The C1Z.22 carbon chain may be straight or branched. Preferably, the carbon chain is of 14 to 18 carbon atoms, more preferably 14 to 16 carbon atoms. Other substituents are preferably the same or different and are lower alkyl groups of 1 to 6 carbon atoms, more preferably methyl groups. The substituents of the quaternary ammonium compound are selected so that the quaternary ammonium compound is substantially water soluble and may form a 1 to 20% w/w aqueous solution. Examples of suitable quaternary ammonium compounds are cetyl trimethyl ammonium salts including halides, sulphates (such as methosulphate salt), saccharinate and tosylate. Cetyl trimethyl ammonium bromide (CTAB) is most preferred. The quaternary ammonium compounds may be used with conventional reducing agents. Preferred reducing agents are monoethanolamine and ammonium thioglycolate. Preferably, the reducing agent is in the form of an aqueous composition comprising 1-12% w/w, preferably 5-10% w/w, of reducing agent, having a pH of 5 to 10, more preferably 9-9.5.
The quaternary ammonium compounds may be included in the composition comprising the reducing agent or applied to the hair subsequent to application of the reducing agent. Where the quaternary ammonium compounds are included in the composition comprising the reducing agent,
other conventional ingredients may also be included such as surfactants, perfumes, preservatives (if necessary) and colorants.
Conventional nonionic surfactants may be included, such as ethoxylated alcohols. Preservatives may not be necessary at high pH; however if preservatives are included, the preservatives may be selected from sodium hydroxymethyl glycinate (SUTTOCIDE A™, Sutton),
7-ethylbicyclooxazolidine (OXABAN-E™, Angus), methylparaben and diazolidinyl urea (GERMALL II™, Sutton). Perfumes and colorants may be selected by the person skilled in the art to provide the desired organoleptic properties to satisfy the end user.
Modes for CarrvinR Out the Invention
The following examples further illustrate the present invention.
Example 1 The permanency of wave of human hair treated with a composition of the present invention (composition 1) was compared with the permanency of wave of human hair treated with a commercially available permanent waving solution (control) by measuring the curl retention after immersing in boiling water. The control composition was a commercially available permanent waving solution including ammonium thioglycolate, 1.2% w/v ammonia, trideceth-12, fragrance and water.
Com osition 1:
Ingredients and availability
Ammonium thioglycolate solution: ammonium thioglycolate solution about
59% as audited (AJAX);
Ammonia solution: ammonia 28% solution (AJAX);
CTAB solution: cetyl trimethyl ammonium bromide solution 40%-Vantoc N40(ICI).
Human hair samples were wound on a stainless steel rod of diameter of about 1.6mm for 20 revolutions (100 counts), immersed in the waving solution for 20 minutes then immersed in an oxidising (neutralising) solution for 1 minute. The samples were removed from the roller and immersed in boiling water for 1 minute. At the end of one minute the samples were withdrawn and the number of counts were recorded. The samples were then immersed in boiling water for 5 minutes and withdrawn and the number of counts recorded. The results are set out in Table 1.
TABLE 1
As can be seen from Table 1, Composition 1 containing 5% CTAB solution retains curl significantly better than the control composition.
Example 2
The process of Example 1 was repeated using the same control composition and Composition 1 as well as a second composition of the present invention (Composition 2 - ingredients and availability as for Composition 1).
Composition 2
The results are set out below in Table 2.
TABLE 2
As shown in Table 2, the 5% CTAB solution gives greater curl retention than the 10% CTAB solution and both are significantly better than the control composition.
CTAB in compositions 1 and 2 may be replaced by other cetyl trimethyl ammonium salts such as cetrimonium chloride, cetrimonium methosulphate, cetrimonium saccharinate or cetrimonium tosylate. Example 3
The uptake of CTAB solutions by human hair at 35°C was measured. Dry human hair samples were weighed then immersed in compositions 1 and 2 of examples 1 and 2 and compositions 3 and 4 as shown below. The immersion time was 20 minutes. The hair samples were then removed, dried and reweighed. The weight differences found are shown in Tables 3 and 4 as set out. Theses weight differences are indicative of the uptake of the compositions.
TABLE 3
Composition 3
Composition 4
Ingredients and availability
Ammonium thioglycolate solution, ammonia solution, CTAB solution as for example 1.
Renex 30: Polyoxy Ethylene (12) Tridecylether (ICI).
Comparing Tables 3 and 4, it can be seen that uptake of CTAB solutions is lower in the presence of surfactant but nevertheless, the solution is taken up by the hair samples. It is theorised that the improved effectiveness of the present invention comes about through uptake of the quaternary ammonium compound into the reduced hair thereby improving the stability of the altered configuration (curly or straightened) after oxidation.
It will be appreciated by persons skilled in the art that numerous variations and/or modifications may be made to the invention as shown in the specific embodiments without departing from the spirit or scope of the invention as broadly described. The present embodiments are, therefore, to be considered in all respects as illustrative and not restrictive.