WO1997035544A1 - Compositions pour shampooing traitant - Google Patents

Compositions pour shampooing traitant Download PDF

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Publication number
WO1997035544A1
WO1997035544A1 PCT/US1997/003695 US9703695W WO9735544A1 WO 1997035544 A1 WO1997035544 A1 WO 1997035544A1 US 9703695 W US9703695 W US 9703695W WO 9735544 A1 WO9735544 A1 WO 9735544A1
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WO
WIPO (PCT)
Prior art keywords
cationic
dialkylaminoalkyl
meq
anionic
carbon atoms
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PCT/US1997/003695
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English (en)
Inventor
Susan Marie Guskey
Douglas Allan Royce
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to AU23201/97A priority Critical patent/AU2320197A/en
Priority to EP97915890A priority patent/EP0889714A1/fr
Priority to JP9534420A priority patent/JPH11507077A/ja
Priority to BR9708436A priority patent/BR9708436A/pt
Publication of WO1997035544A1 publication Critical patent/WO1997035544A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic

Definitions

  • the present invention relates to hair conditioning shampoo compositions which comprise crosslinked hair conditionmg polymers which have a high cationic charge density
  • shampoo products are commercially available or otherwise known, many of which also contain hair conditionmg agents These products provide users with both hair cleaning and conditioning performance from a single product, and conveniently allows for single application of a conditioner and shampoo during the shampooing process
  • Hair conditioning agents used in such products include silicone, hydrocarbon oils, fatty esters, cationic hair conditionmg agents and combinations thereof
  • Cationic hair conditionmg agents are especially desirable for use in these hair conditionmg shampoos to control static, detangle wet hair, and provide a silky, conditioned wet hair feel dunng and after rinsing
  • These cationic hair conditionmg agents often present compatibility problems when used in combination with many of the anionic surfactants known for use in shampoo compositions
  • Cationic surfactants as hair conditionmg agents in the presence of some anionic detersive surfactants form a soluble ionic complex that does not deposit well on the hair Such deposition is important for providing good conditioning performance
  • Other cationic surfactants as hair conditionmg agents in the presence of anionic detersive surfactants form an insoluble complex which deposits well on hair but often does not provide good conditionmg performance, and causes the hair to have a dirty, coated feel
  • Cationic polymers have also been used as hair conditionmg agents in shampoos, but these polymers tend to build up on the hair and cause the hair to have an unclean, coated feeling Moreover, many of these cationic polymers have relatively high cationic charge density values which presents even more compatibility problems when used in combination with anionic surfactants These highly charged cationic polymers typically form insoluble, highly viscous, clumps when combined with an anionic surfactant in a shampoo composition The concentration and/or charge density of such canonic polymers, therefore, are often limited to help minimize the extent of these problems, or these highly charged polymers are used only in conditioning compositions that do not contain anionic surfactant limiting the concentration or amount of these polymers, however, can also limit the overall hair conditioning performance delivered from the conditioning shampoo composition
  • select, highly charged, cationic hair conditioning polymers can be used in combmation with an anionic detersive surfactant in a shampoo composition, which then provides improved hair conditioning performance and improved product stability
  • the select polymers must be crosslinked, and have cationic charge density of from about 4.0 meq/gm to about 7 meq/gm, and consist essentially of a crosslinking agent in combination with a monomer unit selected from the group consisting dialkylaminoalkyl acrylamides, dialkylaminoalkyl methacryiamides, dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, and combinations thereof, wherein each of the monomer units is cationic at the pH of the composition.
  • the present invention is directed to hair conditioning shampoo compositions which comprise (A) from about 5% to about 50% by weight of an anionic surfactant component selected from the group consisting of anionic surfactants, zwitterionic or amphoteric surfactants having an attached group that is anionic at the pH of the composition, and combinations thereof; (B) from about 0.025% to about 5% by weight of an organic, crosslinked, cationic polymer having a cationic charge density of from about 4 meq/gm to about 7 meq/gm, and wherein polymer consists essentially of a crosslinking agent in combination with a monomer unit selected from the group consisting dialkylaminoalkyl acrylamides, dialkylaminoalkyl methacryiamides, dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, and combinations thereof, wherein each of the monomer units is cationic at the pH of the composition; and (C) from about 20% to
  • the shampoo compositions of the present invention can comprise, consist of, or consist essentially of the essential elements and limitations of the invention described herein, as well any of the additional or optional ingredients, components, or limitations described herein. All percentages, parts and ratios are based upon the total weight of the shampoo compositions of the present invention, unless otherwise specified. All such weights as they pertain to listed ingredients are based on the active level and, therefore, do not include carriers or by-products that may be included in commercially available materials, unless otherwise specified.
  • the term “soluble” refers to any material that is sufficiently soluble in water to form a substantially clear solution to the naked eye at a concentration of 0.1% by weight of the material in water at 25°C
  • the term “insoluble” refers to all other materials that are therefore not sufficiently soluble in water to form a substantially clear solution to the naked eye at a concentration of 0 1% by weight of the other material in water at 25 °C
  • the shampoo compositions of the present mvention comprise an anionic detersive surfactant component to provide cleaning performance to the composition
  • the anionic detersive surfactant component in turn comp ⁇ ses anionic detersive surfactant, zwitterionic or amphoteric detersive surfactant which has an attached group that is anionic at the pH of the composition, or a combmation thereof, preferably anionic detersive surfactant
  • Such surfactants should be physically and chemically compatible with the essential components described herein, or should not otherwise unduly impair product stability, aesthetics or performance
  • Suitable anionic detersive surfactant components for use in the shampoo composition herein include those which are known for use in hair care or other personal care cleansing compositions
  • concentration of the anionic surfactant component in the shampoo composition should be sufficient to provide the desired cleaning and lather performance, and generally range from about 5% to about 50%, preferably from about 8% to about 30%, more preferably from about 10% to about 25%, even more preferably from about 12% to about 18%, by weight of the composition
  • Preferred anionic surfactants suitable for use in the shampoo compositions are the alkyl and alkyl ether sulfates These materials have the respective formulae ROSO3M and RO(C2H4 ⁇ ) x S ⁇ 3M, wherem R is alkyl or alkenyl of from about 8 to about 18 carbon atoms, x is an integer having a value of from I to 10, and M is a cation such as ammonium, alkanolammes.
  • anionic detersive surfactant component is water soluble Solubility of the surfactant will depend upon the particular anionic detersive surfactants and cations chosen
  • R has from about 8 to about 18 carbon atoms, more preferably from about 10 to about 16 carbon atoms, even more preferably from about 12 to about 14 carbon atoms, in both the alkyl and alkyl ether sulfates
  • the alkyl ether sulfates are typically made as condensation products of ethylene oxide and monohyd ⁇ c alcohols havmg from about 8 to about 24 carbon atoms
  • the alcohols can be synthetic or they can be de ⁇ ved from fats, e g , coconut oil, palm kernel oil, tallow Lauryl alcohol and straight chain alcohols derived from coconut oil or palm kernel oil are preferred Such alcohols are reacted with between about 0 and about 10, preferably from about 2 to about 5, more preferably about 3, molar proportions of ethylene oxide, and the resultmg mixture of molecular species having, for example, an average of 3 moles of ethylene oxide per mole of alcohol, is sulfated and neutralized Specific non limiting examples of alkyl ether sulf
  • Suitable anionic detersive surfactants are the water-soluble salts of organic, sulfuric acid reaction products conforming to the formula [ R'-S ⁇ 3-M ] where R is a straight or branched chain, saturated, aliphatic hydrocarbon radical having from about 8 to about 24, preferably about 10 to about 18, carbon atoms, and M is a cation described herembefore
  • Non limiting examples of such detersive surfactants are the salts of an organic suifunc acid reaction product of a hydrocarbon of the methane series, including iso-, neo-, and n-paraffms, havmg from about 8 to about 24 carbon atoms, preferably about 12 to about 18 carbon atoms and a sulfonating agent, e g , SO3, H2SO4, obtained accordmg to known sulfonation methods, including bleaching and hydrolysis
  • Preferred are alkali metal and ammonium sulfonated C 1 Q to C j g n-paraff
  • anionic detersive surfactants are the reaction products of fatty acids esterified with isethionic acid and neutralized with sodium hydroxide where, for example, the fatty acids are denved from coconut oil or palm kernel oil, sodium or potassium salts of fatty acid amides of methyl taunde in which the fatty acids, for example, are derived from coconut oil or palm kernel oil
  • Other similar anionic surfactants are descnbed in U S Patent 2,486,921 , U S Patent 2,486,922, and U S Patent 2,396,278, which desc ⁇ ptions are incorporated herein by reference
  • anionic detersive surfactants suitable for use in the shampoo compositions are the succinnates, examples of which include disodium N-octadecylsulfosuccinnate, disodium lauryl sulfosucc ate, diammonium lauryl sulfosuccinate, tetrasodium N-( 1 ,2-d ⁇ carboxyethyl)-N-octadecylsulfosucc ⁇ nnate, diamyl ester of sodium sulfosuccmic acid, dihexyl ester of sodium sulfosuccmic acid, and dioctyl esters of sodium sulfosuccmic acid
  • olefin sulfonates havmg about 10 to about 24 carbon atoms
  • the term "olefin sulfonates” refers to compounds which can be produced bv the sulfonation of alpha-olefins by means of uncomplexed sulfur trioxide, followed by neutralization of the acid reaction mixture in conditions such that any sulfones which have been formed in the reaction are hydrolyzed to give the corresponding hydroxy-alkanesulfonates
  • the sulfur trioxide can be liquid or gaseous, and is usually, but not necessarily, diluted by inert diluents, for example by liquid SOo, chlorinated hydrocarbons, etc , when used in the liquid form, or by air, nitrogen, gaseous SO2, etc , when used in the gaseous form
  • the alpha-olefins from which the olefin sulfonates are de ⁇ ved are mono-olef
  • anionic detersive surfactants suitable for use in the shampoo compositions are the beta-alkyloxy alkane sulfonates These surfactants conform to the formula
  • R' IS a straight chain alkyl group havmg from about 6 to about 20 carbon atoms
  • R ⁇ is a lower alkyl group havmg from about 1 to about 3 carbon atoms, preferably 1 carbon atom
  • M is a water-soluble cation as described hereinbefore
  • Preferred anionic detersive surfactants for use in the shampoo compositions include ammonium lauryl sulfate, ammonium laureth sulfate, triethylamine lauryl sulfate, triethylamine laureth sulfate, t ⁇ ethanolamme lauryl sulfate, tnethanolamine laureth sulfate, monoethanolamine lauryl sulfate, monoethanolamine laureth sulfate, diethanolamine lauryl sulfate, diethanolamine laureth sulfate, lau ⁇ c monoglyceride sodium sulfate, sodium lauryl sulfate, sodium laureth sulfate, potassium lauryl sulfate, potassium laureth sulfate, sodium lauryl sarcosinate, sodium lauroyl sarcosmate, lauryl sarcosine, cocoyl sarcosine.
  • Suitable amphote ⁇ c or zwitterionic detersive surfactants for use in the shampoo composition herein include those which are known for use hair care or other personal care cleansing composition, and which contain a group that is anionic at the pH of the shampoo composition Concentration of such amphoteric detersive surfactants preferably ranges from about 0 5 % to about 20%, preferably from about 1% to about 10%, by weight of the composition
  • suitable zwitterionic or amphoteric surfactants are described U S Patents 5,104,646 (Bolich Jr et al ), U S Patent 5, 106,609 (Bohch Jr et al ), which descriptions are incorporated herein by reference
  • Amphoteric detersive surfactants suitable for use in the shampoo composition are well known in the art, and include those surfactants broadly described as derivatives of aliphatic secondary and tertiary amines in which the aliphatic radical can be straight or branched chain and wherein one of the aliphatic substituents cont
  • Zwitterionic detersive surfactants suitable for use in the shampoo composition are well known in the art, and include those surfactants broadly described as derivatives of aliphatic quaternary ammonium, phosphonium, and sulfonium compounds, in which the aliphatic radicals can be straight or branched chain, and wherein one of the aliphatic substituents contams from about 8 to about 18 carbon atoms and one contams an anionic group such as carboxy, sulfonate, sulfate, phosphate or phosphonate Zwitte ⁇ onics such as betaines are preferred
  • the shampoo compositions of the present invention may further comprise additional surfactants for use in combmation with the anionic detersive surfactant component descnbed hereinbefore Suitable optional surfactants include nonionic surfactants, cationic surfactants, and combinations thereof Any such surfactant known in the art for use in hair or personal care products may be used, provided that the optional additional surfactant is also chemically and physically compatible with the essential components of the shampoo composition, or does not otherwise unduly impair product performance, aesthetics or stability
  • concentration of the optional additional surfactants in the shampoo composition may vary with the cleansing or lather performance desired, the optional surfactant selected, the desired product concentration, the presence of other components in the composition, and other factors well known in the art
  • Non limiting examples of other anionic, zwitterionic, amphoteric or optional additional surfactants suitable for use in the shampoo compositions are described in McCutcheon's, Emulsifiers and Detergents. 1989 Annual, published by M C Publishing Co , and U S Patent 3,929,678, U S Patent 2,658,072, U S Patent 2,438,091 , U.S Patent 2,528,378, which descriptions are inco ⁇ orated herein by reference
  • the shampoo compositions of the present invention comprise cationic, crosslinked, hair conditioning polymers havmg a relatively high, cationic charge density These highly charged, cationic polymers, when crosslinked and used in combmation with the anionic detersive surfactant component described herembefore, form a stable shampoo composition with unproved conditionmg performance
  • concentration of the crosslinked polymer in the shampoo composition is from about 0 025% to about 5%, preferably from about 0 1% to about 3%, more preferably from about 0 25% to about 1%, by weight of the composition
  • the hair conditioning polymers for use in the shampoo composition herein must be water dispersible, crosslinked, cationic polymers havmg a cationic charge density of from about 4 meq/gm to about 7 meq/gm, preferably from about 4 meq/gm to about 6 meq/gm, more preferably from about 4 2 meq/gm to about 5 5 meq/gm
  • the hair conditionmg polymers herein consist essentially of a crosslinking agent in combmation with one or more cationic substituted monomer units, wherein the cationic substituent on each of the monomer units is a quaternary ammonium or protonated amino group (acid addition salt), and wherein the monomer units are selected from the group consisting of cationic substituted dialkylaminoalkyl acrylamides, dialkylaminoalkyl methacryiamides, dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, and combinations thereof, preferably dialkylaminoalkyl acrylamides, dialkylaminoalkyl methacryiamides, and combinations thereof
  • Preferred cationic substituted monomers are the cationic substituted dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, and combinations thereof These preferred monomers conform to the formula
  • R' IS hydrogen, methyl or ethyl
  • each of R ⁇ , R ⁇ and R ⁇ are independently hydrogen or a short chain alkyl havmg from about 1 to about 8 carbon atoms, preferably from about 1 to about 5 carbon atoms, more preferably from about I to about 2 carbon atoms
  • n is positive integer having a value of from about 1 to about 8, preferably from about 1 to about 4
  • X is an anionic counte ⁇ on
  • the nitrogen attached to R R3 and R ⁇ may be a protonated amme (primary, secondary or tertiary), but is preferably a quaternary ammonium wherem each of R ⁇ , R ⁇ and R ⁇ are alkyl groups
  • the anionic countenon ( X) in association with the cationic conditionmg polymers may be any known countenon so long as the polymers remain soluble or dispersible m water, m the shampoo composition, or in a coacervate phase of the shampoo composition, and so long as the counterions are physically and chemically compatible with the essential components of the shampoo composition or do not otherwise unduly impair product performance, stability or aesthetics
  • Non limiting examples of such counte ⁇ ons include halides (e g , chlorme, fluorine, bromine, iodine), sulfate and methylsulfate
  • the crosslinking agent herein may be any conventional or otherwise known crosslinking material for use with the cationic substituted monomer units described herembefore
  • These crosslinking agents are typically materials that conta two or more unsaturated functional groups, which are reacted with the monomer units of the polymer to form either links or covalent bonds between two or more mdividual polymer chains or between two or more sections of the same polymer chain
  • suitable crosslinking agents include methylenebisacryla ides, diacrylates, dimethacrylates, di-vinyl aryl (e g di-vinyl phenyl ring) compounds, polyalkenyl polyethers of polyhydric alcohols, allyl acrylates vinyloxyalkylacrylates, and polyfunctional vinylidenes.
  • crosslinking agents include ethylene glycol, propylene glycol, butylene glycol, di-(meth)acrylate, di- (meth)acrylamide, cyanomethylacrylate, vinyloxyethylmethacrylate, allyl pentaerythritol, trimethylolpropane diallylether, allyl sucrose, butadiene, isoprene, 1 ,4 di-ethylene benzene, divinyl naphthalene, ethyl vinyl ether, methyl vinyl ether, and allyl acrylate.
  • Other suitable crosslinking agents include formaldehyde and glyoxal. Preferred is the methyienebisacrylamide crosslinking agent.
  • the crosslinking agent will typically comprise from about 1 ppm to about 10,000 ppm, preferably from about 5 ppm to about 750 ppm, more preferably from about 25 ppm to about 500 ppm, even more preferably from about 100 ppm to about 500 ppm, and most preferably from about 250 ppm to about 500 ppm of the total weight of the polymer on a weight/weight basis.
  • the intrinsic viscosity of the crosslinked, cationic polymer herein can be measured to more specifically characterize the polymer for pu ⁇ oses of the present invention.
  • the intrinsic viscosity of the crosslinked polymer as measured in a one molar sodium chloride solution at 25°C is generally above 6, preferably from about 8 to 14.
  • the average molecular weight of these crosslinked cationic polymers ranges generally from about 1 million to about 30 million.
  • the specific molecular weight is not critical and lower or higher weight average molecular weights can be used.
  • the crosslinked polymers are preferably characterized in a 1.0% solution of the polymer in deionized water to have a viscosity, at 25°C, of at least about 20,000 centipoise, more preferably at least about 30,000 centipoise, when measured at 20 RPM by a Brookfield RVT (Brookfield Engineering Laboratories, Inc. Stoughton, MA, USA).
  • crosslinked cationic polymers can be prepared by methods well known in the art.
  • these polymers can be made by polymerization of an aqueous solution containing from about 20% to about 60%, generally from about 25% to about 40%, by weight monomer, in the presence of an initiator (usually redox or thermal) until the polymerization terminates.
  • the crosslinking agent can also be added to the solution of the monomers to be polymerized, to inco ⁇ orate it into the polymer. In the polymerization reactions, the temperature generally starts between about 0° and 95°C.
  • the polymerization can be conducted by forming a reverse phase dispersion of an aqueous phase of the monomers (and also any additional crosslinking agents) into a nonaqueous liquid, e.g. mineral oil, lanolin, isododecane, oleyl alcohol, and other volatile and nonvolatile esters, ethers, and alcohols, and the like.
  • This preferred crosslinked polymer can be used alone in the shampoo composition or in a suitable carrier such as mineral oil or propylene glycol dicaprylate/dicaprate.
  • This polymer is commercially available as a mineral oil dispersion also containing PPG-1 trideceth-6 as a dispersing aid, from Allied Colloids Ltd, Norfolk, Virginia, U.S.A., under the trade name Salcare® SC95 or as a dispersion in propylene glycol dicaprylate/dicaprate also containing PPG-1 tr ⁇ deceth-6 as a dispersing aid, from Allied Colloids Ltd, (Norfolk, VA) under the trademark Salcare® SC96
  • compositions of the present invention are aqueous systems which comprise from about 20% to about 94%, preferably from about 50% to about 90%, more preferably from about 60% to about 85%, water by weight of the composition
  • the shampoo compositions of the present invention may further comp ⁇ se one or more optional components known for use m hair care or personal care products, provided that the optional components are physically and chemically compatible with the essential component desc ⁇ bed herein, or do not otherwise unduly impair product stability, aesthetics or performance Concentrations of such optional components typically and individually range from about 0 001% to about 10% by weight of the shampoo compositions
  • optional components for use m the shampoo composition include anti static agents, anti dandruff agents, conditionmg agents (hydrocarbon oils, fatty esters) dyes, organic solvents or diluents, pearlescent aids, foam boosters, additional surfactants or cosurfactants (nonionic, cationic), pediculocides, pH adjusting agents, perfumes, preservatives, prote s, skin active agents, styling polymers, sunscreens, vitamins, and viscosity adjusting agents
  • the shampoo composition of the present invention may further comprises a suspending or thickening agent Suitable suspendmg agents for
  • the shampoo compositions of the present invention also preferably comprises a silicone hair conditioning agent, more preferably a silicone hair conditioning agent in combination with an optional suspendmg agent for the silicone
  • the silicone hair conditionmg agent is preferably non volatile, and is preferably present in the shampoo composition at concentrations ranging from about 0 01 % to about 10%, by weight of the shampoo composition
  • suitable silicone hair conditioning agents, and optional suspending agents for the silicone are described in U.S. Reissue Patent 34,584 (Grote et al.), U.S. Patents 5, 104,646 (Bolich Jr. et al.), U.S. Patent 5, 106,609 (Bolich Jr. et al.), which descriptions are inco ⁇ orated herein by reference.
  • the optional silicone hair conditioning agent, and optional suspending agents for the optional silicone are described in more detail hereinafter.
  • the shampoo compositions of the present invention may further comprise an optional silicone hair conditioning agent at concentrations effective to provide hair conditioning benefits.
  • concentrations range from about 0.01% to about 10%, preferably from about 0.1% to about 8%, more preferably from about 0.1% to about 5%, most preferably from about 0.2% to about 3%, by weight of the shampoo compositions.
  • the optional silicone hair conditioning agents are insoluble in the shampoo compositions, and are preferably nonvolatile. Typically it will be intermixed in the shampoo composition so as to be in the form of a separate, discontinuous phase of dispersed, insoluble particles, also referred to as droplets. These droplets are typically suspended with an optional suspending agent described hereinafter.
  • the optional silicone hair conditioning agent phase will comprise a silicone fluid hair conditioning agent such as a silicone fluid and can also comprise other ingredients, such as a silicone resin to improve silicone fluid deposition efficiency or enhance glossiness of the hair (especially when high refractive index (e.g. above about 1.46) silicone conditioning agents are used (e.g. highly phe ⁇ ylated silicones).
  • the optional silicone hair conditioning agent phase may comprise volatile silicone, nonvolatile silicone, or combinations thereof. Typically, if volatile silicones are present, it will be incidental to their use as a solvent or carrier for commercially available forms of nonvolatile silicone materials ingredients, such as silicone gums and resins.
  • the optional silicone hair conditioning agents for use in the shampoo compositions preferably have a viscosity of from about 20 to about 2,000,000 centistokes, more preferably from about 1 ,000 to about 1 ,800,000 centistokes, even more preferably from about 50,000 to about 1 ,500,000 centistokes, most preferably from about 100,000 to about 1,500,000 centistokes, as measured at 25°C .
  • Optional silicone fluids include silicone oils which are flowable silicone materials having a a viscosity of less than 1,000,000 centistokes, preferably between about 5 and 1,000,000 centistokes, more preferably between about 10 and about 100,000 centistokes, at 25°C.
  • Suitable silicone oils include polyalkyl siloxanes, polyaryl siloxanes, polyalkylaryl siloxanes, polyether siloxane copolymers, and combinations thereof.
  • Other insoluble, nonvolatile silicone fluids having hair conditioning properties can also be used.
  • Optional silicone oils include polyalkyl or polyaryl siloxanes which conform to the following formula (I) where R is aliphatic, preferably alkyl or alkenyl, or aryl, R can be substituted or unsubstituted, and x is an mteger from 1 to about 8,000 Suitable unsubstituted R groups include alkoxy, aryloxy, alkaryl, arylalkyl, arylalkenyl, alkamino, and ether-substituted, hydroxyl-substituted, and halogen-substituted aliphatic and aryl groups Suitable R groups also mclude cationic amines and quaternary ammonium groups
  • the aliphatic or aryl groups substituted on the siloxane chain may have any structure so long as the resultmg silicones remain fluid at room temperature, are hydrophobic, are neither irritating, toxic nor otherwise harmful when applied to the hair, are compatible with the other components of the shampoo compositions, are chemically stable under normal use and storage conditions, are insoluble in the shampoo compositions herein, and are capable of bemg deposited on and conditionmg the hair
  • the two R groups on the silicon atom of each monomeric silicone unit may represent the same or different groups
  • the two R groups represent the same group
  • Preferred alkyl and alkenyl substituents are C ⁇ -C5 alkyls and alkenyls, more preferably from C
  • the aliphatic portions of other alkyl-, alkenyl-. or alkynyl-containing groups can be straight or branched chains and preferably have from one to five carbon atoms, more preferably from one to four carbon atoms, even more preferably from one to three carbon atoms, most preferably from one to two carbon atoms
  • the R substituents hereof can also contain ammo functionalities, e g alkamino groups, which can be primary, secondary or tertiary amines or quaternary ammonium These mclude mono-, di- and tn- alkylamino and alkoxyammo groups wherem the aliphatic portion chain length is preferably as descnbed above
  • the R substituents can also be substituted with other groups, such as halogens (e g chloride, fluoride, and bromide), halogenated alipha
  • Suitable halogenated R groups could mclude, for example, tn-halogenated (preferably fluoro) alkyl groups such as -R'-C(F 3, wherem R' IS CAC3 alkyl
  • tn-halogenated (preferably fluoro) alkyl groups such as -R'-C(F 3, wherem R' IS CAC3 alkyl
  • polysiloxanes examples include polymethyl -3,3,3 t ⁇ fluoropropylsiloxane
  • Suitable R groups mclude methyl, ethyl, propyl, phenyl, methylphenyl and phenylmethyl
  • the pre ⁇ ferred silicones are polydimethyl siloxane, polydiethylsiloxane, and polymethylphenylsiloxane Polydimethylsiloxane is especially preferred
  • Other suitable R groups include methyl, methoxy, ethoxy, propoxy, and aryloxy
  • the three R groups on the end caps of the silicone may also represent the same or different groups
  • the nonvolatile polyalkylsiloxane fluids that may be used include, for example, polydimethylsiloxanes These siloxanes are available, for example, from the General Electric Company in their Viscasil R and SF 96 series, and from Dow Corning in their Dow Corning 200 series
  • the polyalkylaryl siloxane fluids that may be used also include, for example, polymethylphenylsiloxanes. These siloxanes are available, for example, from the General Electric Company as SF 1075 methyl phenyl fluid or from Dow Corning as 556 Cosmetic Grade Fluid.
  • the polyether siloxane copolymers that may be used include, for example, a polypropylene oxide modified polydimethylsiloxane (e.g., Dow Coming DC- 1248) although ethylene oxide or mixtures of ethylene oxide and propylene oxide may also be used.
  • ethylene oxide and polypropylene oxide concentrations must be sufficiently low to prevent solubility in water and the composition hereof.
  • Suitable alkylamino substituted silicones include those which conform to the following structure
  • Suitable cationic silicone fluids include those which conform to the formula (III) (R j ) a G3. a -Si-(-OSiG2) n -(-OSiGb(R j )2.5) m -0-SiG3_ a (R j ) a , wherein G is selected from the group consisting of hydrogen, phenyl, hydroxy, C ] -Cg alkyl and preferably methyl; a is 0 or an integer having a value from 1 to 3, preferably 0; b is 0 or 1, preferably 1 ; the sum n+m is a number from 1 to 2,000 and preferably from 50 to 150, n being able to denote a number from 0 to 1,999 and preferably from 49 to 149 and m being able to denote an integer from 1 to 2,000 and preferably from 1 to 10; R j is a monovalent radical conforming to the formula CqH2 q L in which q is an integer having a
  • R2 is selected from the group consisting of hydrogen, phenyl, benzyl, a saturated hydrocarbon radical, preferably an alkyl radical containing from 1 to 20 carbon atoms, and A is a halide ion.
  • silicone cationic polymers which can be used in the shampoo compositions are represented by the formula (V):
  • R ⁇ denotes a monovalent hydrocarbon radical having from I to 18 carbon atoms, preferably an alkyl or alkenyl radical such as methyl;
  • R denotes a hydrocarbon radical, preferably a C ] -C ] g alkylene radical or a C ⁇ -C ⁇ g, and more preferably C j -Cg, alkyleneoxy radical;
  • Q is a halide ion, preferably chloride;
  • r denotes an average statistical value from 2 to 20, preferably from 2 to 8;
  • s denotes an average statistical value from 20 to 200, and preferably from 20 to 50.
  • a preferred polymer of this class is available from Union Carbide under the name "UCARE SILICONE ALE 56.”
  • silicone gums are polyorganosiloxane materials having a viscosity at 25°C of greater than or equal to 1,000,000 centistokes. Silicone gums are described in U.S. Patent 4,152,416; Noll and Walter, Chemistry and Technology of Silicones. New York: Academic Press 1968; and in General Electric Silicone Rubber Product Data Sheets SE 30, SE 33, SE 54 and SE 76, all of which are inco ⁇ orated herein by reference.
  • the silicone gums will typically have a mass molecular weight in excess of about 200,000, generally between about 200,000 and about 1,000,000, specific examples of which include polydimethylsiloxane, (polydimethylsiloxane) (methylvinylsiioxane) copolymer, poly(dimethylsiloxane) (diphenyl siloxane)(methylvinylsiloxane) copolymer and mixtures thereof.
  • nonvolatile, insoluble silicone fluid conditioning agents are the high refractive index silicones, having a refractive index of at least about 1.46, preferably at least about 1.48, more preferably at least about 1.52, most preferably at least about 1.55.
  • the refractive index of the polysiloxane fluid will generally be less than about 1.70, typically less than about 1.60.
  • polysiloxane "fluid" includes oils as well as gums.
  • the high refractive index polysiloxane fluid includes those represented by general Formula (I) above, as well as cyclic polysiloxanes such as those represented by Formula (VI) below:
  • n is from about 3 to about 7, preferably from 3 to 5.
  • the high refractive index polysiloxane fluids contain a sufficient amount of aryl-containing R substituents to increase the refractive index to the desired level, which is described above.
  • R and n must be selected so that the material is nonvolatile, as defined above.
  • Aryl-containing substituents contain alicyclic and heterocyclic five and six membered aryl rings, and substituents containing fused five or six membered rings.
  • the aryl rings themselves can be substituted or unsubstituted.
  • Substituents include aliphatic substituents, and can also include alkoxy substituents, acyl substituents, ketones, halogens (e.g., Cl and Br), amines, etc.
  • Exemplary aryl-containing groups include substituted and unsubstituted arenes, such as phenyl, and phenyl derivatives such as phenyls with C .
  • alkyl or alkenyl substituents e.g., allylphenyl, methyl phenyl and ethyl phenyl, vinyl phenyls such as styrenyl, and phenyl alkynes (e.g. phenyl C_-C alkynes).
  • Heterocyclic aryl groups include substituents derived from furan, imidazole, pyrrole, pyridine, etc.
  • Fused aryl ring substituents include, for example, napthalene, coumarin, and purine.
  • the high refractive index polysiloxane fluids will have a degree of aryl-containing substituents of at least about 15%, preferably at least about 20%, more preferably at least about 25%, even more preferably at least about 35%, most preferably at least about 50%.
  • the degree of aryl substitution will be less than about 90%, more generally less than about 85%, preferably from about 55% to about 80%.
  • the polysiloxane fluids are also characterized by relatively high surface tensions as a result of their aryl substitution.
  • the polysiloxane fluids hereof will have a surface tension of at least
  • Preferred high refractive index polysiloxane fluids have a combination of phenyl or phenyl derivative substituents (preferably phenyl), with alkyl substituents, preferably C 1-C4 alkyl (most preferably methyl), hydroxy, C C4 alkylamino (especially -R ' NHR ⁇ NH2 where each R and R ⁇ independently is a C -C, alkyl, alkenyl, and/or alkoxy
  • High refractive index polysiloxanes are available from Dow Coming Co ⁇ oration (Midland, Michigan, U S A ) Huls America (Piscataway, New Jersey, U S A ), and General Electric Silicones (Waterford, New York, U S A ) It is preferred to utilize high refractive index silicones in solution with a spreading agent, such as a silicone resin or a surfactant, to reduce the surface tension by a sufficient amount to enhance spreading and thereby enhance glossiness (subsequent to drying) of hair treated with the
  • the surface tension of the mixture of the polysiloxane fluid and the spreading agent, at the i proportions present in the final product is preferably 30 dynes cm or less, more preferably about 28
  • the surface tension will be in the range of from about 15 to about 30, more typically from about 18 to about 28, and most generally from
  • the weight ratio of the highly arylated polysiloxane fluid to the spreading agent will, in general, be between about 1000 1 and about 1 1, preferably between about 100 1 and about 2 1, more preferably between about 50 1 and about 2 1, most preferably from about 25 1 to about 2 1
  • fluorinated surfactants particularly high polysiloxane spreading agent ratios may be effective due to the efficiency of these surfactants
  • ratios significantly above 1000 1 may be used
  • silicone fluids for use in the shampoo compositions include U S Patent 2,826,551, U S Patent 3,964,500, U S Patent 4,364,837, British Patent 849,433, and Silicon Compounds, Petrarch Systems, Inc (1984), all of which are inco ⁇ orated herein bv reference Silicone resins can be mcluded in the silicone conditioning agent These resms are highly crosslinked polymeric siloxane systems The crosslinking is introduced through the inco ⁇ oration of trifunctional and tetrafunctional silanes with monofunctional or difunctional, or both, silanes during manufacture of the silicone resin As is well understood in the art, the degree of crosslinking that is required m order to result in a silicone resm will vary according to the specific silane units inco ⁇ orated into the silicone resin In general, silicone materials which have a sufficient level of trifunctional and tetrafunctional siloxane monomer units (and hence, a sufficient Ievel of crosslinking) such that they dry down to
  • Silicone materials and silicone resms in particular can conveniently be identified accordmg to a shorthand nomenclature system well known to those skilled in the art as "MDTQ" nomenclature Under this system, the silicone is described accordmg to presence of various siloxane monomer units which make up the silicone Briefly, the symbol M denotes the monofunctional unit (C ⁇ SiO 5, D denotes the difunctional unit (Gr ⁇ SiO, T denotes the tnfunctional unit (CH3)S ⁇ O j 5, and Q denotes the quadn- or tetra- functional unit S1O2 Primes of the unit symbols, e g , M', D', T, and Q' denote substituents
  • the silicone resms for use herem which are preferred are MQ, MT, MTQ, MDT and MDTQ resms
  • the preferred silicone substituent is methyl
  • MQ resms wherein the M Q ratio is from about 0 5 1 0 to about 1 5 1 0 and the average molecular weight of the res is from about 1000 to about 10,000
  • the weight ratio of the nonvolatile silicone fluid, having refractive index below 1 46, to the silicone resin component, when used, is preferably from about 4 1 to about 400 1 , preferably this ratio is from about 9 1 to about 200 1 , more preferably from about 19 1 to about 100 1 , particularly when the silicone fluid component is a polydmiethylsiloxane fluid or a mixture of polydimethylsiloxane fluid and O 97/35544 PCIYUS97/03695
  • silicone resin forms a part of the same phase in the compositions hereof as the silicone fluid, i.e. the conditioning active, the sum of the fluid and resin should be included in determining the level of silicone conditioning agent in the composition.
  • the shampoo compositions of the present invention may further comprise a suspending agent at concentrations effective for suspending the optional silicone hair conditioning agent, or other water- insoluble material, in dispersed form in the shampoo compositions.
  • concentrations range from about 0.1% to about 10%, preferably from about 0.3% to about 5.0%, by weight of the shampoo compositions.
  • Optional suspending agents include crystalline suspending agents that can be categorized as acyl derivatives, long chain amine oxides, or combinations thereof, concentrations of which range from about 0.1% to about 5.0%, preferably from about 0.5% to about 3.0%, by weight of the shampoo compositions. When used in the shampoo compositions, these suspending agents are present in crystalline form. These suspending agents are described in U.S. Patent 4,741,855, which description is inco ⁇ orated herein by reference. These preferred suspending agents include ethylene glycol esters of fatty acids preferably having from about 16 to about 22 carbon atoms. More preferred are the ethylene glycol stearates, both mono and distearate, but particularly the distearate containing less than about 7% of the mono stearate.
  • suspending agents include alkanol amides of fatty acids, preferably having from about 16 to about 22 carbon atoms, more preferably about 16 to 18 carbon atoms, preferred examples of which include stearic monoethanolamide, stearic diethanolamide, stearic monoisopropanolamide and stearic monoethanolamide stearate.
  • long chain acyl derivatives include long chain esters of long chain fatty acids (e.g., stearyl stearate, cetyl palmitate, etc.); glyceryl esters (e.g., glyceryl distearate) and long chain esters of long chain alkanol amides (e.g., stearamide diethanolamide distearate, stearamide monoethanolamide stearate).
  • Long chain acyl derivatives, ethylene glycol esters of long chain carboxyiic acids, long chain amine oxides, and alkanol amides of long chain carboxyiic acids in addition to the preferred materials listed above may be used as suspendmg agents.
  • suspending agents with long chain hydrocarbyls having C -C22 chains may be used.
  • acyl derivatives suitable for use as suspending agents include N,N-dihydrocarbyl amido benzoic acid and soluble salts thereof (e.g., Na, K), particularly N,N-di(hydrogenated) C ] g, C
  • Suitable long chain amine oxides for use as suspending agents include alkyl (C ] -C22> dimethyl amine oxides, e.g., stearyl dimethyl amine oxide
  • Suitable suspending agents include xanthan gum at concentrations ranging from about 0.3% to about 3%, preferably from about 0.4% to about 1.2%, by weight of the shampoo compositions.
  • xanthan gum as a suspending agent in silicone containing shampoo compositions is described, for example, in U S Patent 4,788,006, which description is inco ⁇ orated herein by reference
  • Combinations of long chain acyl derivatives and xanthan gum may also be used as a suspending agent m the shampoo compositions
  • suitable suspending agents include carboxyvinyl polymers Preferred among these polymers are the copolymers of acrylic acid crosslinked with polyallylsucrose as described in U S Patent 2,798,053, which description is inco ⁇ orated herem by reference Examples of these polymers include Carbopol 934, 940, 941, and 956, available from B F Goodrich Company
  • suspending agents include primary ammes havmg a fatty alkyl moiety havmg at least about 16 carbon atoms, examples of which include palmitamme or stearamme, and secondary ammes havmg two fatty alkyl moieties each having at least about 12 carbon atoms, examples of which include dipalmitoylamine or d ⁇ (hydrogenated tallow)am ⁇ ne
  • Still other suitable suspendmg agents include d ⁇ (hydrogenated tallow)phthal ⁇ c acid amide, and crosslinked maleic anhydride-methyl vinyl ether copolymer
  • Other suitable suspendmg agents may be used in the shampoo compositions, cludmg those that can impart a gel-like viscosity to the composition, such as water soluble or colloidally water soluble polymers like cellulose ethers (e g , methylcellulose, hydroxybutyl methylcellulose, hyroxypropylcellulose, hydroxypropyl methylcellulose, hydroxyethyl eth
  • the shampoo compositions of the present mvention are used m a conventional manner for cleansing and conditionmg hair or skin
  • An effective amount of the composition for cleansing and conditionmg the hair or skm is applied to the hair or skm, that has preferably been wetted with water, and then rinsed off
  • Such effective amounts generally range from about 1 gm to about 50gm, preferably from about lgm to about 20gm
  • Application to the hair typically includes working the composition through the hair such that most or all of the hair is contacted with the composition
  • This method for cleansing and conditionmg the hair or skm comp ⁇ ses the steps of a) wetting the hair or skin with water, b) applying an effective amount of the shampoo composition to the hair or skin, and c) rinsing the applied areas of skin or hair with water These steps can be repeated as many times as desired to achieve the desired cleansing and conditioning benefit
  • Examples I-XV are specific embodiments of the shampoo compositions of the present mvention, but are not intended to be limiting thereof Other modifications can be undertaken by the skilled artisan without departmg from the spirit and scope of this invention. These exemplified embodiments of the shampoo compositions of the present invention provide cleansing of hair and improved hair conditioning performance.
  • compositions can be prepared by conventional formulation and mixing techniques.
  • Component amounts are listed as weight percents and exclude minor materials such as diluents, filler, and so forth.
  • the listed formulations therefore, comprise the listed components and any minor materials associated with such components.
  • Dimethicone is a 40(gum)/60(flu ⁇ d) weight ratio blend of SE-76 dimethicone gum available from General Elect ⁇ c Silicones Division and a dimethicone fluid having a viscosity of 350 centistokes
  • Polyquatern ⁇ um-37 is a crosslinked cationic polymer available from Allied Colloids

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Abstract

L'invention porte sur des compositions aqueuses pour shampooing traitant à stabilité et pouvoir traitant améliorés. Ces compositions comprennent un composant tensioactif détersif anionique et un polymère organique destiné à la mise en forme du cheveu, réticulé et cationique, d'une densité de charge cationique relativement élevée, comprise entre environ 4 mEq/gm et environ 7 mEq/gm. Ce polymère réticulé est essentiellement constitué d'un agent de réticulation et de monomères choisis dans le groupe constitué par des dialkylaminoalkyl acrylamides, des dialkylaminoalkyl méthacrylamides, des dialkylaminoalkyl acrylates, et des dialkylaminoalkyl méthacrylates ainsi que par leurs combinaisons, chaque monomère du polymère réticulé étant cationique au pH de la composition pour shampoing.
PCT/US1997/003695 1996-03-27 1997-03-18 Compositions pour shampooing traitant WO1997035544A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AU23201/97A AU2320197A (en) 1996-03-27 1997-03-18 Conditioning shampoo compositions
EP97915890A EP0889714A1 (fr) 1996-03-27 1997-03-18 Compositions pour shampooing traitant
JP9534420A JPH11507077A (ja) 1996-03-27 1997-03-18 コンディショニングシャンプー組成物
BR9708436A BR9708436A (pt) 1996-03-27 1997-03-18 Composições de xampu condicionador

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US62277696A 1996-03-27 1996-03-27
US08/622,776 1996-03-27

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0893117A2 (fr) † 1997-07-24 1999-01-27 Basf Aktiengesellschaft Copolymères cationiques de haute masse moléculaire
FR2773070A1 (fr) * 1997-12-31 1999-07-02 Oreal Compositions pour le traitement des matieres keratiniques contenant l'association d'un polymere zwitterionique et d'une silicone non-volatile et insoluble dans l'eau
EP1068857A1 (fr) * 1999-07-16 2001-01-17 L'oreal Utilisation en cosmétique de copolymères amphotères réticulés ou branchés; compositions mises en oeuvre
US6410005B1 (en) * 2000-06-15 2002-06-25 Pmd Holdings Corp. Branched/block copolymers for treatment of keratinous substrates
WO2003045341A1 (fr) * 2001-11-28 2003-06-05 Shin-Etsu Chemical Co., Ltd. Produits de soins capillaires
EP1504748A1 (fr) * 2003-08-08 2005-02-09 KPSS-Kao Professional Salon Services GmbH Composition pour le traitement des cheveux
US20070110695A1 (en) * 2005-11-16 2007-05-17 Kpss-Kao Professional Salon Services Gmbh Conditioning Composition for Hair
US7422735B1 (en) 1999-06-29 2008-09-09 Basf Aktiengesellschaft Use of crosslinked cationic polymers in skin cosmetic and dermatological preparations
WO2009112419A1 (fr) * 2008-03-14 2009-09-17 Unilever Plc Composition

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010079100A1 (fr) * 2009-01-06 2010-07-15 Unilever Plc Améliorations se rapportant à des agents de traitement de tissus
GB201207443D0 (en) * 2012-04-30 2012-06-13 Unilever Plc Polymers of trialkyl quaternary ammonium methacrylate salts as squeakiness enhancers in cleansing compositions
FR3040301B1 (fr) * 2015-09-01 2017-10-13 Oreal Composition comprenant au moins un tensioactif anionique, au moins deux tensioactifs non ioniques particuliers, au moins un tensioactif amphotere et au moins un polymere cationique particulier

Citations (4)

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GB2124245A (en) * 1982-07-27 1984-02-15 Kao Corp Liquid detergent composition
WO1994021224A1 (fr) * 1993-03-16 1994-09-29 L'oreal Utilisation en cosmetique ou en application topique d'une dispersion aqueuse a base d'organopolysiloxanes non volatils et d'un polymere reticule de chlorure de methacryloyloxyethyl trimethylammonium, de type homopolymere ou copolymere avec l'acrylamide
EP0627217A2 (fr) * 1993-05-17 1994-12-07 Helene Curtis, Inc. Shampooing de conditionnement stable ayant une action moussante élevée contenant un conditionneur silicone, un copolymère acrylate cationique quaternaire, un tensioactive anionique et polyethyleneimine
WO1995009600A1 (fr) * 1993-10-01 1995-04-13 The Procter & Gamble Company Compositions de soins capillaires contenant des alcools gras a bas point de fusion et des epaississants polymeres reticules

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Publication number Priority date Publication date Assignee Title
GB2124245A (en) * 1982-07-27 1984-02-15 Kao Corp Liquid detergent composition
WO1994021224A1 (fr) * 1993-03-16 1994-09-29 L'oreal Utilisation en cosmetique ou en application topique d'une dispersion aqueuse a base d'organopolysiloxanes non volatils et d'un polymere reticule de chlorure de methacryloyloxyethyl trimethylammonium, de type homopolymere ou copolymere avec l'acrylamide
EP0627217A2 (fr) * 1993-05-17 1994-12-07 Helene Curtis, Inc. Shampooing de conditionnement stable ayant une action moussante élevée contenant un conditionneur silicone, un copolymère acrylate cationique quaternaire, un tensioactive anionique et polyethyleneimine
WO1995009600A1 (fr) * 1993-10-01 1995-04-13 The Procter & Gamble Company Compositions de soins capillaires contenant des alcools gras a bas point de fusion et des epaississants polymeres reticules

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0893117A2 (fr) † 1997-07-24 1999-01-27 Basf Aktiengesellschaft Copolymères cationiques de haute masse moléculaire
EP0893117B2 (fr) † 1997-07-24 2012-02-08 Basf Se Utilisation de polymères cationiques comme agents de soin capillaire
US6555100B1 (en) 1997-12-31 2003-04-29 L'ORéAL S.A. Compositions for treating keratinous materials containing a combination of a zwitterion polymer and a water insoluble non-volatile silicon
FR2773070A1 (fr) * 1997-12-31 1999-07-02 Oreal Compositions pour le traitement des matieres keratiniques contenant l'association d'un polymere zwitterionique et d'une silicone non-volatile et insoluble dans l'eau
WO1999034770A1 (fr) * 1997-12-31 1999-07-15 L'oreal Compositions pour le traitement des matieres keratiniques contenant l'association d'un polymere zwitterionique et d'une silicone non-volatile et insoluble dans l'eau
US7422735B1 (en) 1999-06-29 2008-09-09 Basf Aktiengesellschaft Use of crosslinked cationic polymers in skin cosmetic and dermatological preparations
EP1068857A1 (fr) * 1999-07-16 2001-01-17 L'oreal Utilisation en cosmétique de copolymères amphotères réticulés ou branchés; compositions mises en oeuvre
US6589539B1 (en) 1999-07-16 2003-07-08 L'oreal S.A. Cosmetic and dermatological compositions comprising crosslinked and branched amphoteric copolymers and their use
FR2796277A1 (fr) * 1999-07-16 2001-01-19 Oreal Utilisation en cosmetique de copolymere amphoteres reticules ou branches; compositions mises en oeuvre
US6410005B1 (en) * 2000-06-15 2002-06-25 Pmd Holdings Corp. Branched/block copolymers for treatment of keratinous substrates
WO2003045341A1 (fr) * 2001-11-28 2003-06-05 Shin-Etsu Chemical Co., Ltd. Produits de soins capillaires
EP1504748A1 (fr) * 2003-08-08 2005-02-09 KPSS-Kao Professional Salon Services GmbH Composition pour le traitement des cheveux
US20070110695A1 (en) * 2005-11-16 2007-05-17 Kpss-Kao Professional Salon Services Gmbh Conditioning Composition for Hair
US8597623B2 (en) * 2005-11-16 2013-12-03 Kao Germany Gmbh Conditioning composition for hair
WO2009112419A1 (fr) * 2008-03-14 2009-09-17 Unilever Plc Composition

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CN1219862A (zh) 1999-06-16
JPH11507077A (ja) 1999-06-22

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