MXPA98007939A - Compositions of champu acondiciona - Google Patents

Abstract

Aqueous shampoo conditioner compositions with improved stability and conditioning are disclosed which comprise a surfactant, detergent, anionic component and a crosslinked organic hair conditioning cationic polymer having a relatively high cationic charge density from about 4 meg / gm to about 7 meg / gm. The cationic polymer consists essentially of the crosslinking agent and monomer units selected from the group consisting of dialkylaminoalkylacrylamides, dialkylaminoalkylmetracrylamides, dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, and combinations thereof, wherein each of the monomer units in the cross-linked polymer they are cationic at the pH of the composition

Description

COMPOSITIONS OF AIR CONDITIONER SHAMPOO FIELD OF THE INVENTION The present invention relates to shampoo hair conditioner compositions, which comprise cross-linked hair conditioning polymers having a high cationic charge density.

BACKGROUND OF THE INVENTION Many shampoo products are commercially available or otherwise known, many of which also contain hair conditioning agents. These products provide users with both cleansing and hair conditioning performance from an individual product, and conveniently allows the individual application of a conditioner and shampoo during the shampooing process. Hair conditioning agents used in these products include silicone, hydrocarbon oils, fatty esters, hair conditioning agents, cationic, and combinations thereof. Cationic hair conditioning agents (cationic surfactants, cationic polymers) are especially desirable for use in these hair conditioner shampoos to control static, disentangle wet hair, and provide a damp, conditioned, silky hair feel, during and after rinsing. These cationic hair conditioning agents, however, frequently exhibit compatibility problems when used in combination with many of the known anionic surfactants for use in shampoo compositions. Cationic surfactants such as hair conditioning agents in the presence of some detergent, anionic surfactants form a soluble ionic complex which does not deposit well on the hair. This deposit is important to provide good conditioning performance. Other cationic surfactants such as hair conditioning agents in the presence of anionic detergent surfactants form a soluble complex which deposits well on the hair, but which often does not give good conditioning performance and causes hair to have an unkempt, coated appearance. Cationic polymers have also been used as hair conditioning agents in shampoos, but these polymers tend to accumulate in the hair and cause the hair to have a cleaner, coated feel. In addition, many of these cationic polymers have relatively high cationic charge density values, which present even more compatibility problems when used in combination with cationic surfactants. These highly charged cationic polymers form highly viscous, insoluble agglomerates when combined with an anionic surfactant in a shampoo composition. The concentration and / or charge density of these cationic polymers, therefore, is often limited to keep the degree of these problems to a minimum, or these highly charged polymers are used only in conditioning compositions that do not contain anionic surfactant. The limitation of the concentration in amounts of polymers, however, which can not limit the full performance of the hair conditioning supplied with the conditioning shampoo composition. It has now been found that selected, highly charged, cationic hair conditioning polymers can be used in combination with an anionic detergent surfactant in a shampoo composition which then provides improved hair conditioning performance and improved hair stability. product. To realize these benefits, the selected polymers must be crosslinked and have a cationic loading requirement of about 4.0 P681 meq / gm to about 7 meq / gm, and consist essentially of a crosslinking agent in combination with a monomer unit selected from the group consisting of dialkylaminoalkyl acrylamides, dialkylaminoalkyl methacrylamides, dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, and combinations thereof, wherein each of the monomer units is cationic at the pH of the composition. Therefore, it is an object of the present invention to provide a conditioning shampoo composition with improved hair conditioning performance and also to provide a composition containing a cationic hair conditioning polymer. Furthermore, it is an object of the present invention to provide a conditioning shampoo composition with improved stability of the product containing an anionic surfactant component in combination with a cationic hair conditioning polymer, and to further provide this composition, wherein the cationic polymers they are crosslinked and have a relatively high cationic charge density from about 4.0 meq / gm to about 7 meq / gm.

SUMMARY OF THE INVENTION The present invention relates to compositions P681 of hair conditioning shampoo comprising a) from about 5% to about 50% of an anionic surfactant component selected from the group consisting of cationic surfactants, zwitterionic or amphoteric surfactants having a bonded group that is anionic to the pH of the composition, and combinations thereof; b) from about 0.025% to about 5% by weight of a cationic, crosslinked, organic polymer having charge density, cationic, from about 4 meq / gm to about 7 meq / gm, wherein the former consists essentially of a crosslinking agent in combination with a monomer unit selected from the group consisting of dialkylaminoalkyl acrylamides, dialkylaminoalkyl methacrylamides, dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, and combinations thereof, wherein each of the monomer units is cationic to the pH of the composition; and c) from about 20% to about 94% by weight of water. The highly charged, cross-linked cationic polymers provide improved conditioning performance and are physically compatible with the anionic, detergent surfactant component of the composition.

DETAILED DESCRIPTION OF THE INVENTION The shampoo compositions of the present invention may comprise, consist of, or consist essentially of the essential elements and limitations of the invention described herein, as well as of any of the additional or optional ingredients, components, or limitations described herein. All percentages, parts and ratios are based on the total weight of the shampoo compositions of the present invention, unless otherwise specified. All of these weights since they correspond to the ingredients listed are based on the active level and therefore do not include carriers or by-products that can be included in the commercially available materials, unless otherwise specified. As used herein, the term "soluble" refers to any material that is sufficiently soluble in water to form a substantially clear solution to the naked eye at a concentration of 0.1% by weight of the material in water at 25aC. Conversely, the term "insoluble" refers to all other materials which are therefore not sufficiently soluble in water to form a substantially clear solution to the naked eye at a concentration of 0.1% by weight of another material in water at 25aC.

The shampoo compositions of the present invention, which include the essential and optional components thereof, are described in detail below.

Surfactant, Detergent, Anionic Agent Component The shampoo compositions of the present invention comprise a surfactant, detergent, anionic component to provide cleaning performance to the composition. The surfactant, detergent, anionic component, in turn, comprises a surfactant, detergent, anionic agent, a zwitterionic, amphoteric, detergent surfactant having a bonded group which is anionic to the pH of the composition, or a combination thereof. themselves, preferably a surfactant, detergent, anionic agent. These surfactants must be physically and chemically compatible with the essential components described herein, or otherwise they should not unduly damage the stability, aesthetics or performance of the product. Suitable surfactant, detergent, anionic components for the use of a shampoo composition herein include those that are known for the use of hair care or other personal care cleansing compositions. The concentration of the surfactant component, anionic, in the composition of the shampoo should be sufficient to provide the desired cleaning and foaming performance, and ranges in general from about 5% to about 50%, preferably from about 8% to about 30%, in the form more preferably from about 10% to about 25%, still more preferably from about 12% to about 18% by weight of the composition. Preferred and suitable anionic surfactants for use in shampoo compositions are alkyl sulfates and alkyl ether. These materials have the specific formulas ROS03M and RO (CH2H40) xS03M, wherein R is alkyl or alkenyl from about 8 to about 18 carbon atoms, x is an integer having a value from 1 to 10, and R is a cation such as ammonium, alkanolamines, such as triethanolamine, monovalent metals such as sodium and potassium, and polyvalent metal cations, such as magnesium and calcium. The cation N should be selected such that the surfactant, detergent, anionic component is soluble in water. The solubility of the surfactant will depend on the detergent, anionic, particular surfactants, and the chosen cations. Preferably, R has from about 8 to about 18 carbon atoms, more preferably from about 10 to about 16 carbon atoms, still more preferably from about 12 to about 14 carbon atoms, both in the sulphates of alkyl as alkyl ether. Alkyl ether sulfates are typically made as condensation products of ethylene oxide and monohydric alcohols having from about 8 to about 24 carbon atoms. The alcohols can be synthetic or they can be derived from fats, for example, coconut oil, palm oil, tallow. Lauryl alcohol and straight-chain alcohols derived from coconut oil or palm oil are preferred. These alcohols are reacted with between about 0 and about 10, preferably from about 2 to about 5, more preferably about 3, molar proportions of ethylene oxide, and the resulting mixture of the molecular species which has, for example , an average of (moles of ethylene oxide per mole of alcohol, is sulfated and neutralized.) Non-limiting examples, specific to the alkyl ether sulfates that can be used in the shampoo compositions of the present invention, include sodium salts. and alkyl ammonium sulfate of alkyl triethylene glycol, coconut, tallow alkyl ether triethylene glycol sulfate, and tallow alkyl hexamethylene sulfate Highly preferred alkyl ether sulfates are those comprising a mixture of the individual compounds , wherein the compounds in the mixture have an average alkyl chain length from about 10 to about between 16 carbon atoms, and an average degree of ethoxylation from about 1 to about 24 ethylene oxide atoms. Other suitable surfactants, detergents, anionics, are the water-soluble salts of the organic sulfuric acid reaction products, which conform to the formula: [R ^ SOj-M], wherein R 1 is a straight chain or branched, aliphatic hydrocarbon radical, saturated, having from about 8 to about 24, preferably from about 10 to about 18, carbon atoms; and M is a cation described hereinabove. Non-limiting examples of the detergent surfactants are the salts of a reaction product of sulfuric acid, organic, of a P681 hydrocarbon of the methane series, including iso-neo-, paraffins, having from about 8 to about 24 carbon atoms, preferably from about 12 to about 18 carbon atoms and a sulfonating agent, for example, S03, H2S04, obtained according to the known sulphonation methods, including bleaching and hydrolysis. Preferred are N-paraffins of 10 to 18 carbon atoms, sulfonated, alkali metal and ammonium. Still other suitable surfactants, detergents, anionics, are the reaction products of the fatty acids esterified with isethionic acid and neutralized with sodium hydroxide, where, for example, the fatty acids are derived from coconut oil or oil. palm; sodium or potassium salts of methyl tauride fatty acid amides in which the fatty acids, for example, are derived from coconut oil or palm oil. Other, anionic, similar surfactants are disclosed in U.S. Patent No. 2,486,921; U.S. Patent No. 2,486,922; and U.S. Patent No. 2,396,278, descriptions which are incorporated herein by reference. Other surfactants, detergents, anionics, suitable for use in the compositions of P681 shampoo are succinates, examples of which include disodium N-octadecyl sulfosuccinate, disodium lauryl sulfosuccinate; diammonium lauryl sulfosuccinate; N- (1,2-dicarboxyethyl) -N-octadecylsulfosuccinate tetrasodium; diamyl ether of sodium sulfosuccinic acid; dihexyl ester of sodium sulfosuccinic acid; dioctyl esters of sodium sulfosuccinic acid. Other suitable anionic detergent surfactants include olefin sulfonates having from about 10 to about 24 carbon atoms. The term "olefin sulfonates" is used herein to mean compounds that can be produced by the sulfonation of the alpha-olefins by means of sulfur trioxide, not rendered complex, followed by neutralization of the acidic reaction mixture in conditions such that any sulfone that has been formed in the reaction is hydrolysed to give the corresponding hydroxy-alkane sulfonates. Sulfur trioxide may be liquid or gaseous, and usually, but not necessarily, divided by inert ingredients, for example, by SO, liquid, chlorinated hydrocarbons, etc., when used in the liquid form, or by air, nitrogen, S02 gas, etc., when used in the gaseous form. The alpha-olefins from which the olefin sulfonates are derived are the mono-olefins which have P681 about 10 to about 24 carbon atoms, preferably about 12 to about 16 carbon atoms. Preferably, they are the straight chain olefins. In addition to the true alkene sulfonates of a proportion of hydroxy alkane sulphonates, the olefin sulfonates may contain minor amounts of other materials, such as alkene disulfonates, depending on the reaction conditions, proportion of the reactants, the nature of the olefins. of start and impurities in the side and concentrated reactions of olefin, during the sulphonation process. A limiting example such as a mixture of alpha-olefin sulfonate is described in US Patent No. 3,332,880, which description is incorporated herein by reference. Another class of detergent, anionic surfactants suitable for use in shampoo compositions are the beta-alkyloxy alkane sulphonates. These compounds have the following formula: wherein R1 is a straight chain alkyl group having from about 6 to about 20 carbon atoms; R2 is a lower alkyl group having from P681 about 1 to about 3 carbon atoms, and M is a water soluble cation as described hereinabove. The detergent surfactants, anionic, preferred, for use in shampoo compositions include ammonium lauryl sulfate, ammonium laureth sulfate, triethylamine lauryl sulfate, triethylamine laureth sulfate, triethanolamine lauryl sulfate, and triethanolamine laureth sulfate, lauryl monoetholamine sulfate, monoethanolamine laureth sulfate, diethanolamine lauryl sulfate, diethanolamine laureth sulfate, lauric monoglyceride sodium sulfate, sodium lauryl sulfate, sodium laureth sulfate, potassium lauryl sulfate, laureth sulfate potassium, sodium lauryl sarcocinate, sodium lauroyl sarcocinate, lauryl sarcocin, cocoyl sarcosine, ammonium cocoyl sulfate, ammonium lauroyl sulfate, sodium cocoyl sulfate, sodium lauroyl sulfate, potassium cocoyl sulfate, potassium lauryl sulfate, potassium lauryl sulfate, triethanolamine lauryl sulfate, triethanolamine lauryl sulfate, triethanolamine lauryl sulfate, monoethanolamine cocoyl sulfate, monoethanolamine lauryl sulfate, sodium tridecylbenzene sulfonate, sodium dodecylbenzene sulfonate, and combinations thereof. The detergent, ammonia surfactants P681 or zwitterionic, suitable for use in the composition of the shampoo herein include those which are known for use in hair care or other cleaning, personal care composition and which contain a group that is anionic at the pH of the shampoo composition. The composition of the anionic, amphoteric, detergent surfactants preferably ranges from about 0.5% to about 20%, preferably from about 1% to about 10%, by weight of the composition. Non-limiting examples of suitable surfactants, zwitterionics, or amphoteric agents, are described in U.S. Patent No. 5,104,646 (Bolich Jr et al.), U.S. Patent No. 5,106,609 (Bolich Jr. et al.), Descriptions which are incorporated herein by reference. present by reference. Amphoteric detergent surfactants suitable for the use of the shampoo composition are well known in the art, and include those surfactants broadly described as derivatives of the secondary and tertiary aliphatic amines, in which the aliphatic radical can be straight or branched chain and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains P681 an anionic group of solubilization in water, such as carboxy, sulfonate, sulfate, phosphate or phosphonate. Detersive, zwitterionic surfactants suitable for use in the shampoo composition are well known in the art, and include those surfactants broadly described as derivatives of ammonium, phosphonium, sulfonium, quaternary, aliphatic compounds, in which the aliphatic radicals they may be straight or branched chain, and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains the anionic group such as carboxy, sulfonate, sulfate, phosphate or phosphonate. Zwitterionics such as betaines are preferred. The shampoo compositions of the present invention may further comprise additional surfactants for use in combination with the surfactant, detergent, anionic component described above. Suitable optional surfactants include surfactants, nonionics, cationic surfactants, and combinations thereof. Any surfactant known in the art for use in hair or personal care products may be used, provided that the additional, optional surfactant is also chemically P681 or physically compatible with the essential components of the shampoo composition, or otherwise not unduly damaging the performance, aesthetics or stability of the product. The concentration of the surfactants, additives, optionals in the shampoo composition can vary with the desired cleaning or foam performance, the optional surfactant selected, the desired concentration of the product, the presence of other components in the composition, and others. factors well known in the art. Non-limiting examples of additional, optional, or amphoteric, zwitterionic, anionic surfactants suitable for use in shampoo compositions are described in McCutcheon's, Emulsifiers and Detergents, 1989 Annual, published by M.C. Publisching Co., and U.S. Patent No. 3,962,678, U.S. Patent No. 2,658,072; U.S. Patent No. 2,438,091; U.S. Patent No. 2,528,378, descriptions which are incorporated herein by reference.

Cationic hair conditioning polymer The shampoo compositions of the present invention comprise hair conditioning, crosslinked, cationic polymers having a density P681 cationic charge, relatively high. The cationic polymers, highly chargedWhen crosslinked and used in combination with the surfactant, detergent, anionic component described above, they form a stable shampoo composition with improved conditioning performance. The concentration of the crosslinked polymer in the shampoo composition is from about 0.025% to about 5%, preferably from about 0.1% to about 3%, more preferably from about 0.25% to about 1% by weight of the composition. Hair conditioning polymers for use in the shampoo composition herein must be water dispersible, crosslinked, cationic polymers having a cationic charge density of from about 4 meq / gram to about 7 meq / gram, preferably from about 4 meq / gram to about 6 meq / gram, more preferably from about 4.2 meq / gram to about 5.5 meq / gram. The hair conditioning polymers herein essentially consist of a crosslinking agent in combination with one or more monomer units, substituted, cationic, where the substituent Cationic P681 in each of the monomer units is an amino, protonated, or quaternary ammonium group (acid addition salt), and wherein the monomer units are selected from the group consisting of dialkylaminoalkyl-acrylamides, substituted , cationic, dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, and combinations thereof, preferably dialkylaminoalkyl acrylamides, dialkylaminoalkyl methacrylamides and combinations thereof. The preferred cationic substituted monomers are the dialkylaminoalkyl acrylates, substituted as cationic, dialkylaminoalkyl methacrylates and combinations thereof. These preferred monomers conform to the formula: wherein R1 is hydrogen, methyl or ethyl; each of R :, R3 P681 and R4 are independently hydrogen or a short chain alkyl having from about 1 to about 8 carbon atoms, preferably from about 1 to about 5 carbon atoms, more preferably from about 1 to about 2 carbon atoms; n is an integer having a value from about 1 to about 8, preferably from about 1 to about 4; and X is an anionic counterion. The nitrogen bound to R2, R3, and R4 can be a protonated amine (primary, secondary or tertiary), but is preferably a quaternary ammonium, wherein R2, R3, and R4 are alkyl groups. The anionic counterion (X) in association with the cationic conditioning polymers can be any known counterion as long as the polymers remain soluble or dispersible in water, in the shampoo composition, or in a coacervate phase of the shampoo composition, and while that the counterions are physically and chemically compatible with the essential components of the shampoo composition, or do not otherwise damage the performance, stability or aesthetics of the product unduly. Non-limiting examples of these counterions include halides (eg, chlorine, fluorine, bromine, iodine), sulfate and methyl sulfate.

P681 The crosslinking agent herein may be any known crosslinking material, conventional or otherwise, for use with the substituted, cationic monomer units described hereinabove. These crosslinking agents are typically materials containing two or more unsaturated functional groups, which are reacted with the monomer units of the polymer to form either covalent bonds or bonds between two or more individual polymer chains or between two or more sections. in the same polymer chain. Non-limiting examples of suitable crosslinking agents include methylene bisacrylamides, diacrylates, dimethacrylates, di-vinyl-aryl compounds (eg, di-vinyl phenyl ring), polyalkenyl polyethers, polyhydric alcohols, allyl acrylates. , vinyloxyalkyl acrylates, and polyfunctional vinylidenes. Non-limiting, specific examples of said crosslinking agents include ethylene glycol, propylene glycol, butylene glycol, di- (meth) acrylate, di- (meth) acrylamide, cyanomethylacrylate, vinyl oxyethyl methacrylate, allyl pentaeritol, diallyl ether of trimethylolpropane, allyl sucrose, butadiene , isoprene, 1,4-di-ethylene-benzene, divinyl-naphthalene, ethyl vinyl ether, methyl vinyl ether, and allyl acrylate. Other suitable crosslinking agents include formaldehyde and P681 glyoxal. The methylene bisacrylamide crosslinking agent is preferred. The widely varying amounts of crosslinking agents can be employed depending on the desired properties in the general polymer, for example, effect on viscosity. The crosslinking agents will typically comprise from about 1 ppm to about 10,000 ppm, preferably from about 5 ppm to about 750 ppm, more preferably from about 25 ppm to about 500 ppm, still more preferably from about 100 ppm to about 500 ppm, and more preferably from about 250 ppm to about 500 ppm of the total weight of the polymer on a weight / weight basis. The intrinsic viscosity of the cross-linked cationic polymer can be measured to more specifically characterize the polymer for purposes of the present invention. The intrinsic viscosity of the crosslinked polymer as measured in a sodium chloride solution, molar, at 25 aC is generally above 6, preferably from about 8 to 14. Average molecular weight of these cationic, crosslinked polymers vary in general from about 1,000,000 to about 30,000,000. Molecular weight Specific P681 is not critical and higher or lower weight average molecular weights may be used. The crosslinked polymers are preferably characterized in a 1.0% solution of the polymer in deionized water to have a viscosity, 25SC, of at least about 20,000 centipoise, more preferably at least about 30,000 centipoise, when measured at 20 RPM by a Brookfield RVT (Brookfield Engineering Laboratories, Inc. Stoughton, MA, USA). These cross-linked cationic polymers can be prepared by methods well known in the art. For example, these polymers can be made by polymerizing an aqueous solution containing from about 20% to about 60%, generally from about 25% to about 40%, by weight of monomer, in the presence of an initiator. (usually redox or thermal) under polymerization finishes. The crosslinking agent can also be added to the solution of the monomers to be polymerized, to be incorporated in the polymer. In the polymerization reactions, the temperature generally starts between approximately 08 and 958C. the polymerization can be; carried out by forming an inverted phase dispersion of an aqueous phase of the monomers (and also any of the additional crosslinking agents) in P681 a non-aqueous liquid, for example, mineral oil, lanolin, isododecane, oleyl alcohol, and other volatile and non-volatile esters, ethers, and alcohols and the like. A non-limiting example of a cross-linked cationic polymer preferred for use in the shampoo composition, as described herein above, is Polyquaternium 37. This preferred cross-linked polymer is to be used only in the shampoo composition or in a suitable carrier such as a mineral oil or a propylene glycol dicaprylate / dicaprate. This polymer is commercially available as a dispersion in mineral oil which also contains PPG-1 tridecet-6 as a dispersion aid, from Allied Colloids Ltd, Norfolk, Virginia, U.S.A. under the trade name Saleare "SC95 or as an expression in propylene glycol dicaprylate / dicaprate which also contains PPG-1 tridecet-6 as a dispersion aid, from Allied Colloids Ltd, (Norfolk, VA) under the trade name Saleare" SC96.

Water The shampoo compositions of the present invention are aqueous systems comprising from about 20 1 to about 94%, preferably from about 50% to about 94%, most preferably from about 60% P681 up to about 85% by weight of water in the composition.

Other Optional Components The shampoo compositions of the present invention may further comprise one or more optional components known for the use of hair care or personal care products, provided that the optional components are physically and chemically compatible with the essential component described. in the present, or not otherwise wrongly damage the stability, aesthetics or performance of the product. The concentrations of these optional components typically vary from about 0.001% to about 10% by weight of the shampoo compositions. Non-limiting examples of the optional components for use in the shampoo composition include antistatic agents, anti-dandruff agents, conditioning agents (hydrocarbon oils, fatty esters), dyes, organic solvents or diluents, pearlescent aids, foam boosters, additional surfactants or co-surfactants (non-ionic, cationic, zwitterionic), pediculocides, pH adjusting agents, perfume, preservatives, proteins, active agents P681 on the skin, dispersing agents, styling polymers, sunscreens, thickeners, vitamins and viscosity adjusting agents. This list of optional components does not mean that it is exclusive, and other optional components can be used. The shampoo composition of the present invention may further comprise a suspending or thickening agent. Suitable suspending agents for these materials are well known in the art and include crystalline and polymeric suspension or crosslinking agents. Crystalline suspending agents are preferred, and include the known acyl derivatives and amine oxides, are described in US Patent No. 4,741,855, which description is incorporated herein by reference. Non-limiting examples of the optional polymeric crosslinking agents for use in the shampoo composition include carboxyvinyl polymers, cellulose ethers, guar ethers, polyvinyl alcohol, polyvinyl pyrrolidone, hydroxypropyl guar gum, starch and derivatives thereof. starch, and xanthan gums. Suspension and thickening agents are described in U.S. Patent No. 2,798,053, U.S. Patent No. 4,686,254, U.S. Patent No. 4,788,006, and U.S. Patent No. 5,275,761.; descriptions that P681 are incorporated herein by reference. Optional suspension or thickening agents are described in more detail later herein. The shampoo compositions of the present invention also generally comprise a hair conditioning silicone agent, more preferably a silicone hair dressing in combination with an optional suspending agent for the silicone. The hair conditioning silicone agent is preferably non-volatile and is preferably present in the shampoo composition at concentrations ranging from about 0.01% to about 10%, by weight of the shampoo composition. Non-limiting examples of suitable hair conditioning agents, silicone agents, and optional suspending agents for silicone are described in US Pat. No. 34,584 (Grote et al.), US Patent No. 5,104-606 (Grote et al. Bolich Jr. et al.), US Patent No. 5,106,609 (Bolich Jr. Et al.), Descriptions which are incorporated herein by reference. Optional silicone hair conditioning agent and optional suspension agents for the optional silicone are described in more detail hereinafter.

P681 Silicone Hair Conditioner, Optional The shampoo compositions of the present invention may further comprise any optional silicone hair conditioning agent at effective concentrations to provide hair conditioning benefits. These concentrations will vary from about 0.01% to about 10%, preferably from about 0.1% to about 10%, more preferably from about 0.1% to about 8%, more preferably from about 0.1% to about 5%, more preferably from about 0.2% to about 3% by weight of the shampoo compositions. Optional silicone hair conditioning agents are unsaturatable in shampoo compositions, and are preferably non-volatile. Typically, a shampoo composition will be intermixed to be in the form of a discontinuous, separate, phase of insoluble, dispersed particles, also referred to as drops. These droplets are typically dispersed as an optional suspending agent, described hereinafter. The phase of the hair conditioning agent, silicone, optional, will comprise a hair conditioning agent, fluid of P681 silicone, such as a silicone fluid can also comprise other ingredients, such as a silicone resin to improve the efficiency of deposition of the silicone fluid or improve the shine of the hair (especially when silicone conditioning agents must be used (e.g. , highly phenylated silicones) of high refractive index (eg, above 1.46) The optional phase of the hair conditioning silicone agent should comprise volatile silicone, non-volatile silicone, or mixtures thereof, typically, if present Volatile silicones will be incidental to their use as a solvent or carrier for commercially available forms of ingredients of non-volatile silicone materials, such as silicone gums and resins Optional silicone hair conditioning agents for use in shampoo compositions preferably have a viscosity from about 20 to about 2.00 0.000 centistokes, more preferably from about 1,000 to about 1,800,000 centistokes, still more preferably from about 50,000 to about 1,500,000 centistokes, more preferably from about 100,000 to about 1,500,000 centistokes, to P681 252C. The optional silicone fluid includes silicone oil which are fluid silicone materials with a viscosity of less than 1, 000,000 centistokes, preferably between about 5 and 1,000,000 centistokes, more preferably between about 10 and about 600,000 centistokes, more preferably between about 10 and about 500,000 centistokes, more preferably between 10 and 100,000 centistokes at 25SC. Suitable silicone oils include polyethylsiloxanes, polyarylsiloxanes, polyalkyl aryl siloxanes, polyether siloxane copolymers, and mixtures thereof. Other non-volatile, insoluble silicone fluids having hair conditioning properties can also be used. Optional silicone oils include polyalkyl or polyaryl-siloxanes that conform to the following formula: where R is preferably aliphatic alkyl or alkenyl, or aryl, R may be substituted or unsubstituted, and x is a P681 integer from 1 to approximately 8,000. Suitable unsubstituted R groups include alkoxy, aryloxy, alkaryl, arylalkyl, arylalkenyl, alkanamino, and aryl and aliphatic groups, substituted with halogen and substituted with hydroxyl, substituted with ether. Suitable R groups also include cationic amines and quaternary ammonium groups. The aliphatic or substituted aryl groups in the siloxane chain may have any structure so long as the resulting silicones remain fluid at room temperature, are hydrophobic, are not irritating, toxic or otherwise dangerous when applied to the hair, are compatible with the other components of the shampoo compositions, are chemically stable under normal use and storage conditions, are insoluble in the shampoo compositions, and are capable of being deposited on, and conditioned, the hair. The two R groups on the silicon atom of each monomeric silicone unit can represent the same group or different groups, preferably the two L groups represent the same group. Preferred alkyl and alkenyl substituents are alkyls and alkenyls of 1 to 5 carbon atoms, more preferably 1 to 4 carbon atoms.

P68 carbon, more preferably 1 to 2 carbon atoms. The aliphatic portions of the groups containing alkyl, alkenyl or alkynyl (such as alkoxy, alkaryl and alkanamino) can be straight or branched chains and preferably have from one to five carbon atoms, more preferably from one to four carbon atoms , still more preferably from one to three carbon atoms, more preferably from one to two carbon atoms. As discussed above, the R substituents herein may contain amino functionalities, for example, alkamino groups, which may be primary, secondary or tertiary amines or quaternary ammonium. These include mono-, di- and tri-alkylamino and alkoxyamino groups, wherein the chain length of the aliphatic portion is preferably as described above. The substituents R may also be substituted with other groups, for example, halogens (for example, chloride, fluoride and bromide), aliphatic or aryl groups, halogenated, and hydroxy (for example, aliphatic groups substituted with hydroxy) - The halogenated R groups Suitable examples may include, for example, tri-halogenated alkyl groups (preferably fluorine) such as -R1-C (F) 3, where R1 is alkyl of 1 to 3 carbon atoms Examples of these polysiloxanes include poly-3, 3, 3-trifluoropropylsiloxane.

P681 Suitable R groups include methyl, ethyl, propyl, phenyl, methylphenyl and phenylmethyl. Preferred silicones are polydimethyl siloxane, polydiethylsiloxane and polymethylphenylsiloxane. Polydimethylsiloxane is especially preferred. Other suitable R groups include methyl, methoxy, ethoxy, propoxy and aryloxy. The three R groups in the end caps of the silicone may also represent the same or different groups. Non-volatile polyalkylsiloxane fluids which may be used include, for example, polydemethylsiloxanes. These siloxanes are available, for example, from General Electric Company in their Viscasil R and SF 96 series, and from Dow Corning and their Dow Corning 200 series. The polyalkyl aryl siloxane fluids, which can be used, also include, for example , polymethylphenylsiloxanes. These siloxanes are available, for example, from the General Electric Company as the SF 1075 methyl phenyl fluid or from Dow Corning as the cosmetic grade fluid 556. The polyether siloxane copolymers, which can be used, include, for example, a polydimethylsiloxane modified with polypropylene oxide (for example, Dow Corning DC-1248) although ethylene oxide or mixtures of ethylene oxide and propylene oxide can also be used.

P681 The level of ethylene oxide and polypropylene oxide should be sufficiently low to prevent solubility in water and the composition herein. Suitable substituted alkylamino silicones include those that conform to the following formula: where x and y are integers. This polymer is also known as "amodimethicone". Suitable silicone, cationic fluids include those that conform to the formula described hereinabove, wherein (RJ aGJa-Si (-OSiG2) n - (- OSiGb (Rj2-b) m-0-SiG3- a (Rja in which G is selected from the group consisting of hydrogen, phenyl, OH, alkyl of 1 to 8 carbon atoms, and preferably methyl; a denotes an integer of 1 to 3, and preferably equal to 0, b denotes = or 1 and preferably equal to 1, the sum n + m is a number from 1 to 2,000, and preferably from 50 to 150, n P681 which is capable of denoting a number from 0 to 1999 and preferably from 49 to 149 and m which is capable of denoting an integer from 1 to 2000, and preferably from 1 to 10; Rl is a monovalent radical of the formula CqH2qL in which q is an integer from 2 to 8, and L is chosen from the groups. -N (RJ2-N (RJ3A- in which R2 is chosen from the group consisting of hydrogen, phenyl, benzyl, a saturated hydrocarbon radical, preferably an alkyl radical containing from 1 to 20 carbon atoms, and A denotes a halide ion A silicone, cationic, especially preferred, corresponding to formula (III) is the polymer known as "trimethylsilylamodimethicone", which conforms to formula (IV): P681 m Other cationic, silicone polymers that can be used in shampoo compositions are those that are represented by the following formula: where R3 denotes a monovalent hydrocarbon radical, having from 1 to 18 carbon atoms, preferably an alkyl or alkenyl radical such as methyl; R4 denotes a hydrocarbon radical, preferably an alkylene radical of 1 to 18 carbon atoms or alkyleneoxy, of 1 to 18 carbon atoms, and preferably 1 to 8 carbon atoms; Q- is a halide ion, preferably chloride; r denotes an average statistical value of 2 to 20, preferably 2 to 8; s denotes a statistical value P681 averages from 20 to 200, and preferably from 20 to 50. A preferred polymer of this class is available from Union Carbide under the name "UCAR SILICONE ALE 56." Other silicone fluids, suitable for use in silicone conditioning agents, are insoluble silicone gums. These gums are polyorganosiloxane materials that have a 25 s C viscosity of more than or equal to 1,000,000 centistokes. Silicone gums are described in U.S. Patent No. 4,152,416; by Noli and Walter, Chemistry and Technology of Silicones, New York: Academis Press 1968; and in General Electric Silicone Rubber Product Data Sheets SE 30, SE 33, SE 54 and SE 76, all of which are incorporated herein by reference. Silicone gums will typically have a mass molecular weight in excess of 200,000, in general between about 200,000 and about 1,000,000, specific examples of which include polydimethylsiloxane, (polydimethylsiloxane) copolymer (methylvinylsiloxane), poly (dimethylsiloxane) (diphenylsiloxane) copolymer (methylvinylsiloxane), and mixtures thereof. Another category of insoluble, non-volatile, silicone fluid conditioning agents are high refractive index silicones, having a refractive index of at least about 1.46, in the form of P681 preferred at least about 1.48, more preferably at least about 1.52, more preferably at least about 1.55. The refractive index of the polysiloxane fluid will generally be less than about 1.70, typically less than about 1.60. in this context, the "fluid" of polysiloxane includes oils as well as gums. The polysiloxane fluid of high refractive index includes those represented by the general formula (I) above, as well as cyclic polysiloxanes such as those represented by the formula (VI) w: The high refractive index polysiloxane fluids contain a sufficient amount of substituents of R containing aryl, to increase the refractive index to the desired level, which is described above. In addition, R and n must be selected so that the material is not volatile, as defined above. The substituents containing aryl contain 5 and 6 membered aryl rings, alicyclic and P681 heterocyclic, and substituents containing rings of 5 or 6 members, fused. The aryl rings themselves can be substituted or unsubstituted. Substituents include substituents include aliphatic substituents, and may also include alkoxy substituents, acyl substituents, ketones, allogens (e.g., Cl and Br), amines, etc. Aryl-containing groups, for example, include substituted and unsubstituted lows, such as phenyl, and phenyl derivatives such as phenyls with alkyl or alkenyl substituents of 1 to 5 carbon atoms, for example, allylphenyl, methylphenyl and ethylphenyl, vinylphenyls, such as styrenyl, and phenyldolalkynes (for example, phenyl C2-C4 alkyne). Heterocyclic aryl groups include substituents derived from furan, imidazole, pyrol, pyridine, etc. Substituents of the fused aryl ring include, for example, naphthalene, comarin and purine. In general, polysiloxane fluids of high refractive index will have a degree of substituents containing aryl of at least about 15%, preferably at least about 20%, more preferably at least about 25%, even more preferably at least 35%, more preferably at least about 50%. Although it is not proposed that the invention be necessarily limited, the degree of substitution of P681 aryl will be less than about 90%, more generally less than about 85%, preferably from about 55% to about 80%. Polysiloxane fluids are also characterized by relatively high surface tensions, as a result of aryl substitution. In general, the polysiloxane fluids herein will have a surface tension of at least about 24 dynes / cm2 typically at least about 27 dynes / cm2. The surface tension for the purpose of this is measured by a Nouy ring tensiometer according to test method CTM 0461, Dow Corning Corporate, November 23, 1971. Changes in surface tension can be measured in accordance with the previous test method or according to the ASTM 1331 method. Preferred high refractive index polysiloxane fluids have a combination of substituents derived from phenyl, or phenyl (preferably phenyl), with alkyl substituents, preferably alkyl of 1 to 4 carbon atoms (most preferably methyl), hydroxy, alkylamino of 1 to 4 carbon atoms (especially -RXNHR2NH2 where each R1 and R2 independently is alkyl of 1 to 3 carbon atoms, alkenyl and / or alkoxy.The high refractive index polysiloxanes are available from Dow Corning P681 Corporation (Midland, Michigan, USA) Huís America (Piscataway, New Jersey, USA), and General Electric Silicones (Waterford, New York, USA.): It is preferred to use high refractive index silicones in solution with a propagation agent , such as a silicone resin or a surfactant, to reduce the surface tension by an amount sufficient to improve the spread and thereby improve the gloss (subsequent to drying) of the hair treated with the composition. In general, a sufficient amount of the propagation agent to reduce the surface tension of the polysiloxane fluid of high refractive index by at least about 15%, preferably at least about 10%, more preferably at least about 15%, in the form even more preferred at least about 20%, more preferably at least about 25%. Reductions in the surface tension of the polysiloxane fluid / spreading agent mixture can provide an improvement in hair shine. Also, the propagation agent will preferably reduce the surface tension by at least about 2 dynes / cm 2, preferably at least about 3 dynes / cm 2, even more preferably 4 dynes / cm 2, most preferably at least about P681 5 dynes / cm2. The surface tension of the mixture of the polysiloxane fluid and the propagation agent, in the proportions presented in the final product, is preferably 30 dynes / cm 2 or less, more preferably at least about 28 dynes / cm 2 or less in more preferred at approximately 25 dynes / cm2 or less. Typically, the surface tension will be in the range of from about 15 to about 30, more typically from about 18 to about 28, and more generally from about 20 to about 25 dynes / cm2. The weight ratio of the highly arylated polysiloxane fluid to the propagation people will generally be between about 1000: 1 and about 1: 1, preferably between about 100: 1 to about 2: 1, more preferably between about 50. : 1 and about 2: 1, more preferably from about 25: 1 to about 2: 1. When fluorinated surfactants are used, particularly high polysiloxane: propagation agent ratios, they can be effective due to the efficiency of their surfactants. In this way, it is contemplated that ratios can be used significantly above 1000: 1.

P681 References that describe the examples of some silicone fluids as suitable for use in shampoo compositions include U.S. Patent No. 2,826,551, U.S. Patent No. 3,964,500, U.S. Patent No. 4,364,837, U.S. Patent No. 849,433, and Silicos Compounds, Petrarch Systems, Inc. (1984), all of which are incorporated herein by reference. The silicone resins can be included in the silicone conditioning agent. These resins are siloxane, polymeric, highly crosslinked systems. The crosslinking is introduced through the incorporation of trifunctional and tetrafunctional xylan with monofunctional or difunctional xylanes, or both, during the manufacture of the silicone resin. As is well understood in the art, the degree of crosslinking that is required in order to result in a silicone resin will vary according to the specific units of xylan incorporated in the silicone resin. In general, silicone materials having a sufficient level of trifunctional and tetrafunctional siloxane monomer units (and therefore, a sufficient level of crosslinking) such that they dry to a film, rigid or hard, are considered to be resins of silicone. The ratio of oxygen atoms to silicon atoms is indicative of the P681 level of crosslinking in a particular silicone material. The silicone materials having at least about 1.1 oxygen atoms per silicon atoms will generally be silicone resins herein. Preferably, the ratio of oxygen: silicon atoms is at least about 1.2: 1.0. The xylans used in the manufacture of silicone resins include monomethyl-, dimethyl-, trimethyl-, monophenyl-, diphenyl-, methylphenyl-, monovinyl-, and methylvinyl-chloroxylans, and tetrachloroxylan, with the methyl-substituted xylanes which are the most commonly used. Preferred resins are offered by General Electric as GE SS4230 and SS4267. Commercially available silicone resins will generally be supplied in a form dissolved in a silicone fluid, nonvolatile, or volatile, low viscosity. The silicone resins for use herein should be supplied and incorporated into the present compositions in the dissolved form, as will be readily apparent to those skilled in the art. Background material in silicones that include sections that cover silicone fluids, gums and resins, as well as the manufacture of silicones, can be found in Encyclopedia of Polymer Science and Engineering, Volume 15, Second Edition, pp 204-308, John Wiley & Sons, Inc., 1989, incorporated herein by P681 reference. The silicone materials and silicone resins in particular, can be conveniently identified according to a shorthand nomenclature system well known to those skilled in the art as the "MDTQ" nomenclature. Under this system, the silicone is described according to the presence of several siloxane monomer units, which constitute the silicone. Briefly, the symbol M denotes the monofunctional unit (CH 3Si05; D denotes the difunctional unit (CH 2SiO; T denotes the trifunctional unit (CH3) Si015; Q denotes the quadtri or tetra-functional unit Si02.) The cousins of the unit symbols , for example, M ', D', T 'and Q' denote different substituents of methyl, and must be defined specifically for each occurrence Typical alternative substituents include groups such as vinyl, phenyl, amines, hydroxyls, etc. molars of the various units, either in terms of the subscripts to the symbols indicating a total number of each type of unit in the silicone (or an average thereof) or as specifically indicated ratios in combination with the full molecular weight of the description of the silicone material under the MDTQ system The relative, higher molar amounts of T, Q, T 'and / or Q' to D, D 'M and / or M' in a silicone resin is indicative of the high P681 levels of crosslinking. As discussed above, however, the total level of crosslinking can also be indicated by the oxygen to silicon ratio. The silicone resins for use herein that are preferred are MQ, MT, MTQ, MDT and MDTQ resins. In this way, the preferred silicone substituent is methyl. Especially preferred are MQ resins wherein the M: Q ratio is from about 0.5: 1.0 to about 1.5: 1.0 and the average molecular weight of the resin is from about 1000 to about 10,000. The weight ratio of the non-volatile silicone fluid, having a refractive index below 1.46, to the silicone resin component, when used, is preferably from about 4: 1 to about 400: 1, preferably this ratio is from about 9: 1 to about 200: 1, more preferably from about 19: 1 to about 100: 1, particularly, when the silicone fluid component is a polydimethylsiloxane fluid or a mixture of polydimethylsiloxane fluid and gum of polydimethylsiloxane as described above. As for the silicone resin forms a part of the same phase in the compositions herein as the silicone fluid, ie the active of P681 conditioning, the sum of the fluid and resin should be included in the determination of the level of the silicone conditioning agent in the composition.

Suspension Agent, Optional The shampoo compositions of the present invention may further comprise a suspending agent at concentrations effective to suspend the optional silicone hair conditioning agent, or other water-insoluble material, in the form dispersed in the compositions of the present invention. shampoo. These concentrations vary from about 0.1% to about 10%, preferably from about 0.3% to about 5.0%, the weight of the shampoo compositions. The suspending agents include crystalline suspending agents, which can be categorized as acyl derivatives, long chain amino oxides, combinations thereof, the concentrations of which range from about 0.1% to about 5.0%, preferably from about 0.5% to about 3.0% by weight of the shampoo compositions. When the shampoo compositions are used, these suspending agents are present in the crystalline form. The agents of P681 suspension are described in U.S. Patent No. 4,741,855, which description is incorporated herein by reference. These suspension agents, preferred, include ethylene glycol ethers of fatty acids preferably having from about 16 to about 22 carbon atoms. The ethylene glycol stearates are preferred, but particularly the mono and distearate, but in particular the distearate contains less than about 7% of the monostearate. Other suitable suspending agents include fatty acid alkanolamides, preferably having from about 16 to about 22 carbon atoms, more preferably from about 16 to 18 carbon atoms, preferred examples of which include stearic mono-stenolamide, diethanolaide stearic, stearic monoisopropanolamide, and stearic monoethanolamide stearate. Other long chain acyl derivatives include long chain esters of long chain fatty acids (eg, stearyl stearate, cetyl palmitate, etc.); glyceryl esters, (e.g., glyceryl distearate), and long chain esters of the long chain alkanol amides (e.g., stearamide-diethanolamide distearate, stearamide-monoethanolamide stearate). The long chain acyl derivatives, esters of P681 ethylene glycol of long chain carboxylic acids, the long chain amine oxides, and the alkanolamines of the long chain carboxylic acids in addition to the preferred materials listed above can be used as suspending agents. For example, it is contemplated that suspending agents with long chain hydrocarbons having chains of 8 to 22 carbon atoms can be used. Other long chain acyl derivatives suitable for use as suspending agents include N, N-dihydrocarbyl-amidobenzoic acid and soluble salts thereof (e.g., Na, K), particularly N, N-di (hydrogenated) C16 Cl8, and sebo-amido-benzoic acid species of this family, which are commercially available from Stepan Company (Nortyhfield, Illinois, USA). Examples of suitable long chain amine oxides for use as suspending agents include (C 16 -C 22) alkyl dimethyl amine oxides, for example, stearyl dimethyl amine oxide. Other suitable suspending agents include xanthan gum at concentrations ranging from about 0.3% to about 3%, preferably from about 0.4% to about 1.2%, by weight of the shampoo compositions. The use of xanthan gum with an agent of P681 suspension in shampoo compositions containing silicone, are described, for example, in US Patent No. 4,788,006, which description is incorporated herein by reference. Combinations of long chain acyl derivatives and xanthan gum can also be used as a suspending agent in the shampoo compositions. These combinations are described in U.S. Patent No. 4,704,272, which description is incorporated herein by reference. Other suitable suspending agents include carboxyvinyl polymers. Preferred among these polymers are copolymers of acrylic acid crosslinked with polyallylsucrose as described in US Patent No. 2,978,053, which description is incorporated herein by reference. Examples of these polymers include Carbopol 934, 940, 941 and 956, available from F. B. Goodrich Company. Other suitable suspending agents include primary amines having a fatty alkyl portion having at least about 16 carbon atoms, examples of which include parmitamine or steramine and secondary amines having two fatty alkyl portions each having at least about 12 carbon atoms, and examples of which include dipalmitolamine or di (hydrogenated tallow) amine. Still others Suitable p681 suspending agents include di (hydrogenated tallow) phthalic acid amide, and crosslinked maleic anhydride-methyl vinyl ether copolymer. Other suspending agents, suitable for use in combination with the insoluble conditioning agent include those which can impart a gel-like viscosity to the composition, such as water-soluble or colloidally water-soluble polymers such as cellulose ethers (e.g. , methyl cellulose, hydroxybutyl methyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl ethyl cellulose, and hydroxyethyl cellulose), guar gum, polyvinyl alcohol, polyvinyl pyrrolidone, hydroxypropyl guar gum, starch and starch derivatives, and other thickeners, modifiers of viscosity, gelation agents, and so on. Mixtures of these materials can be used.

Method of Use The shampoo compositions of the present invention are a conventional manner for cleaning and conditioning the hair or skin. An effective amount of the composition is applied to clean and condition the hair or skin to the hair or skin, which has been preferably wetted with water, and then thoroughly rinsed. These effective amounts vary in P681 generally from about 1 g to about 50 g, preferably from about 1 g to about 20 g. Application to the hair typically includes the work of the composition through the hair such that most or all of the hair is brought into contact with the composition. This method for cleaning and conditioning the hair comprises the steps of: a) wetting the hair with water b) applying an effective amount of the shampoo composition to the hair and c) rinsing the shampoo composition of the hair using water. These steps can be repeated as many times as desired to achieve the desired benefit of cleaning and conditioning.

EXAMPLES The shampoo compositions illustrated in Examples I-XV illustrate specific embodiments of the shampoo compositions of the present invention, but are not intended to limit the same. Other modifications may be understood by those skilled in the art without departing from the spirit and scope of this invention. These exemplary embodiments of the shampoo compositions of the present invention provide for hair cleansing and improved hair conditioning performance.

P681 All the exemplified compositions can be prepared by conventional formulation and mixing techniques. The amounts of the components are listed as per hundred by weight and exclude minor materials such as diluents, filler, and so on. Therefore, the formulations listed, comprise the listed components and any minor material associated with these components Component Example Number I II III IV And Laureth-3 Ammonium sulfate 10.00 10.00 10.00 10.00 10.00 ammonium lauryl Ammonium sulfate 6.00 6.00 6.00 6.00 6.00 Polyquaternium-37 (2) 0.50 0.25 0.75 0.50 0.50 Cocamida MEA 0.80 0.80 0.80 0.80 0.80 Cetyl Alcohol 0.42 0.42 0.42 0.42 0.42 Stearyl Alcohol 0.18 0.18 0.18 0.18 0.18 Ethylene glycol distearate 1.50 1.50 1.50 1.50 1.50 Dimethicone (1) 1.00 1.00 1.00 1.00 1.00 Perfume solution 0.70 0.70 0.70 0.70 0.70 DMDM hydantoin 0.37 0.37 0.37 0.37 0.37 Color Solution (ppm) 64 64 64 64 64 Water and minors c.s for 100% Component Number of Example P681 II III IV V Laureth-3 Ammonium sulphate 10.00 10.00 12.00 10.00 12.00 lauryl ammonium sulfate 6.00 6.00 4.00 6.00 4.00 Polyquaternium-37 (2) 0.50 0.25 0.50 0.50 0.25 Cocamida MEA 0.80 0 0.68 0.80 0.68 Cetyl Alcohol 0.42 0.42 0.42 0.42 Stearyl Alcohol 0.18 0.18 0.18 0.18 Ethylene glycol distearate 1 1..5500 1.50 1.50 1.50 1.50 Dimethicone (1) 0 0 1.00 1.00 1.00 Perfume solution 0.60 0.60 0.60 0.60 0.60 DMDM hydantoin 0.37 0.37 0.37 0.37 0.37 Color Solution (ppm) 64 64 64 64 64 Water and minors - c. s for 100% --- Component Number of Example I II III IV V Laureth-3 Ammonium Sulfate 5.80 5.80 5.80 5.80 5.80 Ammonium Lauryl Sulfate 5.70 5.70 5.70 5.70 5.70 Cocamidopropyl betaine 2.50 2.50 2.50 2.50 2.50 Polyquaternium-37 (2) 0.50 0.25 0.50 0.75 1.00 Cocamida MEA 0.68 0.68 0.68 0.68 0.68 Cetyl Alcohol 0.42 0.42 0.42 0.42 0 Stearyl Alcohol 0.18 0.18 0.18 0.18 0 Ethylene glycol distearate 1.50 1.50 1.50 1.50 1.50 Dimethicone (1) 1.50 1.50 0 1.00 0 P681 Perfume solution 0.60 0.60 0.60 0.60 0.60 DMDM hydantoin 0.37 0.37 0.37 0.37 0.37 Color solution (ppm) 64 64 64 64 64 Water and lower CS for 100% (1) Dimethicone is a mixture with weight ratio of 40 (rubber ) / 60 (fluid) dimethicone rubber SE-76 available from General Electric, Silicones Division and a dimethicone fluid having a viscosity of 350 centiestoks. (2) Polyquaternium-37 is a cross-linked cationic polymer available from Allied Colloids.

P681

Claims (10)

1. CLAIMS. A stable, shampooing conditioner composition comprising: (A) from 5% to 50%, preferably 8% to 30%, by weight of an anionic surfactant component, selected from the group consisting of surfactants anionics, zwitterionic or amphoteric surfactants having a bound group that is anionic to the pH of the composition, and combinations thereof; (B) from 0.025% to 5% by weight of a cationic, crosslinked, organic polymer having a cationic charge density of from 4 meq / gm to 7 meq / gm, preferably from 4.2 meq / gm to 5.5 meq / gm , and wherein the cationic polymer consists essentially of a crosslinking agent and a monomer unit selected from the group consisting of dialkylaminoalkyl acrylamides, dialkylaminoalkyl methacrylamides, dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, and combinations thereof, in wherein each of the monomer units is cationic at the pH of the composition; and (C) from 20% to 94% by weight of water.
2. 2. The shampoo composition according to claim 1, wherein the agent component P681 anionic surfactant is an alkyl sulfate, an alkyl ether sulfate surfactant, or a combination thereof. The shampoo composition according to claim 1, wherein the monomer units are selected from the group consisting of substituted dialkylaminoalkyl acrylates, cationic, dialkyliminoalkyl methacrylates, and combinations thereof, preferably the monomer units are adjusted to the formula wherein R 1 is hydrogen, methyl or ethyl; each of R2, R3 and R4 are independently hydrogen or a short chain alkyl having from 1 to 8 carbon atoms, preferably from 1 to 5 carbon atoms; n is a positive integer having a value from 1 to 8, preferably from 1 to 4; and X is an anionic counterion. P681 4. The shampoo composition according to claim 3, wherein R2, R3 and R4 are independently a short chain alkyl having from 1 to 2 carbon atoms. 5. A stable shampoo conditioner composition comprising: (A) from 5% to 50%, preferably 8% to 30%, by weight of an anionic surfactant component selected from the group consisting of surfactants anionics, zwitterionic or amphoteric surfactants having a bound group that is anionic to the pH of the composition, and combinations thereof; (B) from 0.025% to 5% by weight of a cationic, cross-linked, organic polymer, having a cationic charge density, from 4 meq / gm to 7 meq / gm, preferably from 4.2 meq / gm to 5.5 meq / gm, and wherein the cationic polymer consists essentially of a crosslinking agent and a monomer unit selected from the group consisting of dialkylaminoalkyl acrylamides, dialkylaminoalkyl methacrylamides, dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, and combinations thereof, wherein each of the monomer units is cationic at the pH of the composition; Y P681 (C) from 0.01% to 10% by weight of the hair conditioning agent, in silicone; and (D) from 20% to 94% by weight of water. The shampoo composition according to claim 5, wherein the hair conditioning agent, in silicone, comprises a non-volatile, insoluble, polyalkylsiloxane fluid, preferably dimethylsiloxane. The shampoo composition according to claim 5, wherein the anionic surfactant component is alkyl sulfate, alkyl ether sulfate, or combinations thereof. The shampoo composition according to claim 5, wherein the monomer units are selected from the group consisting of dialkylaminoalkyl acrylates, substituted, cationic, dialkylaminoalkyl-methacrylates, and combinations thereof, preferably the monomer units are fit the formula P681 wherein R1 is hydrogen, methyl or ethyl; each of R2, R3 and R4 are independently hydrogen or a short chain alkyl having from 1 to 8 carbon atoms, preferably from 1 to 5 carbon atoms; n is a positive integer having a value from 1 to 8, preferably from 1 to 4; and X is an anionic counterion. 9. The shampoo composition according to claim 8, wherein each of R2, R3 and R4 are independently a short chain alkyl having from 1 to 5 carbon atoms; n is a positive integer having a value of 1 to 4. The shampoo composition according to claim 9, wherein R 1 is hydrogen or methyl and R 2, R 3 and R4 are independently a short chain alkyl having 1 to 2 carbon atoms. P681