WO1996030202A1 - Honeycomb core of a moisture sealing material - Google Patents

Honeycomb core of a moisture sealing material Download PDF

Info

Publication number
WO1996030202A1
WO1996030202A1 PCT/NL1996/000124 NL9600124W WO9630202A1 WO 1996030202 A1 WO1996030202 A1 WO 1996030202A1 NL 9600124 W NL9600124 W NL 9600124W WO 9630202 A1 WO9630202 A1 WO 9630202A1
Authority
WO
WIPO (PCT)
Prior art keywords
moisture
layers
honeycomb core
honeycomb
layer
Prior art date
Application number
PCT/NL1996/000124
Other languages
French (fr)
Inventor
Johannes Philippus Ludovicus Maria Diderich
Original Assignee
Besin B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Besin B.V. filed Critical Besin B.V.
Priority to BR9607911A priority Critical patent/BR9607911A/en
Priority to EP96906099A priority patent/EP0869866A1/en
Priority to AU49579/96A priority patent/AU4957996A/en
Priority to PL96322528A priority patent/PL322528A1/en
Priority to JP8529206A priority patent/JPH11502787A/en
Publication of WO1996030202A1 publication Critical patent/WO1996030202A1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
    • B32B3/12—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/30—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the shape or structure
    • E04C2/34—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the shape or structure composed of two or more spaced sheet-like parts
    • E04C2/36—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the shape or structure composed of two or more spaced sheet-like parts spaced apart by transversely-placed strip material, e.g. honeycomb panels
    • E04C2/365—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the shape or structure composed of two or more spaced sheet-like parts spaced apart by transversely-placed strip material, e.g. honeycomb panels by honeycomb structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/02—Cellular or porous
    • B32B2305/024—Honeycomb
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2317/00—Animal or vegetable based
    • B32B2317/12—Paper, e.g. cardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/04—Polyethylene

Definitions

  • the present invention relates to a honeycomb core, built up of strips made with a material, such as cellulose material, the strength and/or the shape of which is sensi ⁇ tive to the action of moisture, and to a honeycomb panel in the form of a sandwich construction, comprising such a honeycomb core and two cover plates which define panel faces, between which the core is glued.
  • moisture resistance can be achieved by impregnating the paper with a moisture-repellant means.
  • the usual method for recovering paper for recycling is, however, stirring the paper to pulp in water in a so-called pulper. Since the water cannot penetrate the im ⁇ pregnated, moisture-repellant paper, this method is not usable for impregnated paper. Consequently, the paper can no longer be recovered from that.
  • the invention aims at providing a material for the honey ⁇ comb core and the honeycomb panel which is moisture-resis ⁇ tant, easily workable in the usual paper processing pro ⁇ duction processes and furthermore easily recoverable for re-use.
  • the honeycomb core according to the invention is characterized in that the strips are built up in layers and comprise a layer of plastic, and the honey ⁇ comb panel according to the invention is characterized in that at least one of the cover plates is moisture-proof.
  • the core and the panel according to the invention are characterized in that the strips are built up in layers and comprise a layer of plastic, and the panel according to the invention is characterized in that at least one of the cover plates is moisture-proof.
  • the core and the panel according to the invention are thus provided with moisture-sealed layers.
  • Moisture, and in particular water can only affect the exposed outer surfa ⁇ ce of the core or the panel, and cannot reach the material which is closed in, for instance by further processing and mounting of the material. Apart from that the moisture- sensitive material can be recovered for re-use.
  • All the strips of the honeycomb core comprise the plastic layer so that the core or the panel can be cut to an arbitrary size and still remain moisture-proof.
  • both cover plates of the panel are thus moisture-proof, these will cooperate with the moisture-sealing layers of the honeycomb core, so that the honeycomb cells are sepa ⁇ rated from the outside and from each other. If the panel is now damaged locally and a moisture sealing layer is broken there, the moisture can indeed penetrate the cell there, and moisten the paper layers inside it, but the moisture cannot spread any further, because the cell in question is isolated from its surroundings by moisture- sealing layers. The moisture impairment in local damage is thus localised.
  • the cover plates of the honeycomb panel can also be manu- factured with a material such as cellulose material, the strength and/or the form of which is sensitive to the action of moisture. In that case it is preferable that at least one of the cover plates is built up in layers and comprises a layer of plastic.
  • the material of the cover plates of such a panel, for example paper, can also be recovered for re-use.
  • the cover plates can, however, be made of another material which is or is made moisture-proof, such as, for instance, wood, metal, plastic, coated paper or laminates thereof, if this material is inherently moisture-resistant. For the purpose of re-use the paper should be separable from these materials.
  • the plastic layer of the honeycomb core is to be found between two layers of the moisture-sensitive material of the strips, and is thus integrated with it. If the plastic layer is built in in that way in the moisture-sensitive material of the core strips, the surface thereof retains the character of moisture-sensitive material.
  • the strips can be processed in the usual ways as paper, for example by trimming, cutting and glu ⁇ eing, for the production of the honeycomb core and with that the honeycomb panel.
  • the cover plate concerned of the honeycomb panel comprises two layers of the moisture-sensitive material, between which the plastic layer thereof is located, which is integral with that.
  • the cover plate surfaces retain the character of the moisture-sensitive material, and the cover plates can be cut, glued and processed further in the usual ways for producing honeycomb panels.
  • the principal faces of the produced panels then also retain the character of the moisture-sensitive material (for example paper) so that these panels can then be cut in the usual manner to size, and so that for example paper honeycomb blocks or honeycomb panel parts can be glued against them, with the usual glueing methods.
  • Common products such as pallets and interior parts for cars can be made without radical production changes.
  • the built-in plastic layers are melted together with the paper layers resting against them.
  • a paper product melted in that way can easily be used as initial material in the usual production processes for the honeycomb core and the honeycomb panel based on paper.
  • the paper layers of the core material can have a surface density between 50 and 125 g/m 2 , and preferably have a surface density of about 70 g/m 2 , whereas the cover plates of the honeycomb panel have a total surface density of between 150 and 750 g/m 2 . In that way an optimal balance between weight and strength of the material is attained.
  • plastic layers used are made of polyethene. This material can be melted easily with paper.
  • the polyethene layers have a surface density between 5 and 50 g/m 2 and preferably have a surface density of about 12 g/m 2 . Layer densities like this melt well with paper and are not penetrable by moisture.
  • the honeycomb core can be built up by glueing the strips together with a moisture-resistant glue, and the cover plates of the honeycomb panel can be glued together with the honeycomb core thereof with a moisture-resistant glue.
  • a suitable moisture-resistant glue is, for example, polyvi- nyl acetate glue.
  • a glue is selected which impregnates the strips and the cover plates at the glue locations. Then the strip and cover plate material cannot absorb any moisture at the glueing sites. In this way, moisture migration between adjacent honeycomb cells, parallel to the glueing bonds and the moisture-sealing layers right through the materi ⁇ al, is blocked in an effective way.
  • Polyethene and similar polymers just as glue residues and small paper fractions impregnated with water-resistant glue, can easily be separated from the paper in a pulper, by scooping it out of the pulp slurry. The separated pulp can thus easily be recovered for re-use in paper products.
  • figure 1 is a perspective view of a honeycomb panel provi- ded with a honeycomb core
  • figure 2 is a top view of a honeycomb core in a folded-up position
  • figure 3 is a top view of a honeycomb core in a partially drawn out position
  • figure 4 is a top view of a honeycomb core in fully drawn out position
  • figure 5 is a cross sectional view of one of the paper strips of which the honeycomb core according to the inven ⁇ tion is built up.
  • FIG. 1 shows a honeycomb panel 1 which comprises a honeycomb core 2 and cover plates 3 and 4 glued to it.
  • the honeycomb core 2 is built up of trapezoid-shaped corrugated strips 5 which consist for the most part of paper.
  • a light or heavy paper quality (card ⁇ board) another cellulose material can be used.
  • top views of the honeycomb core are shown in folded-up and partially and fully drawn out positions.
  • the strips 5 extend in longitudinal direction along each other, and parts 6 thereof are glued at least in part along their longitudinal direction, alternately to the adjacent strips on both sides, for example with poly- vinyl acetate glue (PVAC glue) , the parts 7, of approxi ⁇ mately the same length, located between the glued parts 6, remaining unglued.
  • PVAC glue poly- vinyl acetate glue
  • the honeycomb core is drawn out in a direction perpendicular to the plane of the strips 5 (figure 3) , a grid of more or less regular hexagonal cells 8 is formed, with approximately the same cell diameter D, the cell sides of which being formed by the glued parts 6 and the intermediate parts 7 (figure 4) .
  • the cells can, for instance, be 13 mm in diameter D and 50 mm in height (strip width) .
  • the strips 5 form the walls 9 of the cells 8 of the hexagonal grid and can be folded at their ends and be turned back for forming the adjacent strip.
  • a honeycomb panel can be formed with it by glueing (for example with PVAC glue) the cover plates 3 and 4 to the upper and lower edges of the cell walls 9 (figure 1) . It is, however, also possible to provide a honeycomb panel with a honeycomb core 2 accor- ding to the invention, in which a cover plate 3 is glued to only one side of the core 2.
  • the cells of the honeycomb panel 1 can be empty or filled with an insulating material.
  • the panel can be manufactured cheaply of inherently flexurally slack material, but has as a whole a high resistance to compression in a direction perpendicular to the principal plane and has a high flexural stiffness.
  • the structure of the material of the strip 5 is shown schematically in figure 5.
  • the strips 5 are layered and consist of two layers of paper 10 and 11 (another cellulo ⁇ se material is also possible) , between which there is a layer of polyethene 12, which is melted together with the paper layers.
  • polyethene layer 12 has a surfa- ce density between 5 and 50 g/m 2 and preferably has a density of approximately 12 g/m .
  • the paper layers 10 and 11 have surface densities betweeen 50 and 125 g/m 2 and preferably have a surface density of 70 g/m .
  • the polyethene layer 12 is not moisture-penetrable and the strips 5 are therefore moisture-sealed. If the material of the strips 5 is exposed on one side to moisture, only the paper layer 10 or 11 on that side will get wet and the other paper layer will stay dry.
  • a honeycomb panel is built up of a honeycomb core of the moisture-sealed paper described, against which on one or both panel sides a cover plate is glued, then at least one of the cover plates can have the same structure as that of the strips 5 according to figure 5.
  • the polyethene layer 12 can then have the same surface density as that of the strips 5, whereas the paper layers 10 and 11 of the cover plates can have a surface density such that the total surface density of each cover plate is between 150 and 750 g/m 2 .
  • the cells 8 of the hexagonal grid are separated by moisture-sealed poly ⁇ ethene layers 12 from each other and from the outside.
  • moisture cannot penetrate through the panel surfaces or through the cell walls 9 at one of the circumferential edges of the panel, and can only moisten a paper layer on an outer side of the panel. If the panel is damaged local- ly, and the moisture-sealed polyethene layer 12 is broken there, moisture can penetrate into the respective cell or cells 8 and moisten the paper layers exposed therein.
  • the other moisture-sealed polyethene layers 12 of those cells 8 prevent the moisture from spreading further in the panel 1, thus limiting the moisture damage to the damaged cells 8.
  • a water-resistant glue is used for glueing, which impreg ⁇ nates the paper.
  • the relatively slow migration of moisture through the paper, parallel to a glueing bond and the moisture-sealed layers, or in between two strips, or across a strip edge through the paper of a cover plate, to an adjacent, undamaged cell, is effectively blocked by the local paper impregnations.
  • Honeycomb panels 1 according to the invention can, for instance, be used in pallets, which are almost completely made up of paper, with decks and foot blocks formed from honeycomb panels according to the invention. Such pallets can stand in a puddle of water without any problem, since they are not sensitive to weakening by the penetration of moisture therein.
  • Honeycomb panels according to the invention can, in addi- tion, be used as filling material in car doors, for insu ⁇ lating and for cushioning the impact in sideward collisi ⁇ ons.
  • suitable packs of such honeycomb panels 1 are formed, which are arranged vertically in the car door. Because of fluctuations in the relative air humidity and the temperature, water can condense in the inside of the door, as a result of which the panel pack will get wet through direct condensation thereon or indi- rectly. Moreover, on account of ageing of the rubber seals of the door window, rain water can leak into the inside of the door, so that the panel pack, initially the edges thereof, will get wet.
  • the polyethene layers 12 in the strips 5 of the honeycomb core 2 and also those in the cover plates 3 and 4 provide an effective seal against this moisture.
  • the material By building in the moisture-sealing polyethene layer 12 in the paper, the material retains the character of paper.
  • the material can be processed using the usual methods and materials in the production process for honeycomb cores and honeycomb panels (and further for pallets and car door fillings) , among others by the usual cutting and glueing actions.
  • the material has the thermal stabi ⁇ lity and the mechanical strength of paper, that is to say, for example, that at 150° C it retains its shape and strength which is not the case with a material built up entirely of polyethene, polypropene or another cheap plastic.
  • the material of the honeycomb core and the honeycomb panel according to the invention can easily be recovered for re ⁇ use by shredding it and stirring it into water in a so- called pulper.
  • the water then penetrates the paper and because of the stirring the paper is mechanically separa ⁇ ted from the polyethene, so that a paper slurry, the pulp, is formed.
  • the polyethene can then be scooped out of the paper slurry after which the latter can be reused for producing paper products.
  • This method for recovery does not work in the case of impregnated paper, in view of the fact that the water cannot penetrate it. Water-resistant glue residues and small paper fractions impregnated with water-resistant glue can, however, also be easily scooped up out of the paper slurry.

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Laminated Bodies (AREA)
  • Panels For Use In Building Construction (AREA)
  • Pallets (AREA)

Abstract

A honeycomb core is built up of strips made with a material such as cellulose material, the strength and/or the shape of which is sensitive to the action of moisture. The strips are built up in layers and comprise a layer of plastic. The plastic layer can be located between two layers of the moisture-sensitive material and be integral with this. With this honeycomb core a honeycomb panel in the shape of a sandwich construction can be built up, which comprises two cover plates made with a material such as cellulose material, the strength and/or the shape of which is sensitive to the action of moisture, which cover plates form panel faces, between which the core is glued, in which at least one of the cover plates is moisture-proof. At least one of the cover plates can be built up in layers and can comprise a layer of plastic. The cover plate concerned can comprise two layers of the moisture-sensitive material, between which the plastic layer thereof is located which is integral with this.

Description

HONEYCOMB CORE OF A MOISTURE SEALING MATERIAL
The present invention relates to a honeycomb core, built up of strips made with a material, such as cellulose material, the strength and/or the shape of which is sensi¬ tive to the action of moisture, and to a honeycomb panel in the form of a sandwich construction, comprising such a honeycomb core and two cover plates which define panel faces, between which the core is glued.
For many uses, for example in pallets or in interior parts for cars it is desirable that such a honeycomb core or such a honeycomb panel is moisture-proof and particularly water-proof. Moisture resistance can be achieved by using a plastic instead of the moisture-sensitive material. Most plastics, however, have a much lower temperature stability than cellulose material such as, for instance paper, and they are in most cases more expensive. Moreover, plastics have the disadvantage that an environmentally harmful product is obtained, and that the conventional manfactu- ring methods which are geared to paper processing, in particular the cutting and glueing thereof, will have to be completely revised.
Apart from this, moisture resistance can be achieved by impregnating the paper with a moisture-repellant means. The usual method for recovering paper for recycling is, however, stirring the paper to pulp in water in a so- called pulper. Since the water cannot penetrate the im¬ pregnated, moisture-repellant paper, this method is not usable for impregnated paper. Consequently, the paper can no longer be recovered from that.
The invention aims at providing a material for the honey¬ comb core and the honeycomb panel which is moisture-resis¬ tant, easily workable in the usual paper processing pro¬ duction processes and furthermore easily recoverable for re-use. For this purpose the honeycomb core according to the invention is characterized in that the strips are built up in layers and comprise a layer of plastic, and the honey¬ comb panel according to the invention is characterized in that at least one of the cover plates is moisture-proof.
The core and the panel according to the invention are characterized in that the strips are built up in layers and comprise a layer of plastic, and the panel according to the invention is characterized in that at least one of the cover plates is moisture-proof.
The core and the panel according to the invention are thus provided with moisture-sealed layers. Moisture, and in particular water, can only affect the exposed outer surfa¬ ce of the core or the panel, and cannot reach the material which is closed in, for instance by further processing and mounting of the material. Apart from that the moisture- sensitive material can be recovered for re-use.
All the strips of the honeycomb core comprise the plastic layer so that the core or the panel can be cut to an arbitrary size and still remain moisture-proof.
If both cover plates of the panel are thus moisture-proof, these will cooperate with the moisture-sealing layers of the honeycomb core, so that the honeycomb cells are sepa¬ rated from the outside and from each other. If the panel is now damaged locally and a moisture sealing layer is broken there, the moisture can indeed penetrate the cell there, and moisten the paper layers inside it, but the moisture cannot spread any further, because the cell in question is isolated from its surroundings by moisture- sealing layers. The moisture impairment in local damage is thus localised.
The cover plates of the honeycomb panel can also be manu- factured with a material such as cellulose material, the strength and/or the form of which is sensitive to the action of moisture. In that case it is preferable that at least one of the cover plates is built up in layers and comprises a layer of plastic. The material of the cover plates of such a panel, for example paper, can also be recovered for re-use.
The cover plates can, however, be made of another material which is or is made moisture-proof, such as, for instance, wood, metal, plastic, coated paper or laminates thereof, if this material is inherently moisture-resistant. For the purpose of re-use the paper should be separable from these materials.
Preferably the plastic layer of the honeycomb core is to be found between two layers of the moisture-sensitive material of the strips, and is thus integrated with it. If the plastic layer is built in in that way in the moisture- sensitive material of the core strips, the surface thereof retains the character of moisture-sensitive material. In the case of paper the strips can be processed in the usual ways as paper, for example by trimming, cutting and glu¬ eing, for the production of the honeycomb core and with that the honeycomb panel.
Preferably the cover plate concerned of the honeycomb panel comprises two layers of the moisture-sensitive material, between which the plastic layer thereof is located, which is integral with that. By building in the plastic layer here as well, the cover plate surfaces retain the character of the moisture-sensitive material, and the cover plates can be cut, glued and processed further in the usual ways for producing honeycomb panels. The principal faces of the produced panels then also retain the character of the moisture-sensitive material (for example paper) so that these panels can then be cut in the usual manner to size, and so that for example paper honeycomb blocks or honeycomb panel parts can be glued against them, with the usual glueing methods. Common products such as pallets and interior parts for cars can be made without radical production changes.
It is preferable that the built-in plastic layers are melted together with the paper layers resting against them. A paper product melted in that way can easily be used as initial material in the usual production processes for the honeycomb core and the honeycomb panel based on paper.
The paper layers of the core material can have a surface density between 50 and 125 g/m2, and preferably have a surface density of about 70 g/m2, whereas the cover plates of the honeycomb panel have a total surface density of between 150 and 750 g/m2. In that way an optimal balance between weight and strength of the material is attained.
It is preferable that the plastic layers used are made of polyethene. This material can be melted easily with paper.
The polyethene layers have a surface density between 5 and 50 g/m2 and preferably have a surface density of about 12 g/m2. Layer densities like this melt well with paper and are not penetrable by moisture.
The honeycomb core can be built up by glueing the strips together with a moisture-resistant glue, and the cover plates of the honeycomb panel can be glued together with the honeycomb core thereof with a moisture-resistant glue.
In this way the structure of the core or the panel remains intact when becoming moist and local moisture damage to the panel is fixed and located in an effective manner. A suitable moisture-resistant glue is, for example, polyvi- nyl acetate glue. Preferably a glue is selected which impregnates the strips and the cover plates at the glue locations. Then the strip and cover plate material cannot absorb any moisture at the glueing sites. In this way, moisture migration between adjacent honeycomb cells, parallel to the glueing bonds and the moisture-sealing layers right through the materi¬ al, is blocked in an effective way.
Polyethene and similar polymers, just as glue residues and small paper fractions impregnated with water-resistant glue, can easily be separated from the paper in a pulper, by scooping it out of the pulp slurry. The separated pulp can thus easily be recovered for re-use in paper products.
The invention will be elucidated below with reference to an exemplary embodiment which is illustrated in the accom¬ panying drawings, in which:
figure 1 is a perspective view of a honeycomb panel provi- ded with a honeycomb core;
figure 2 is a top view of a honeycomb core in a folded-up position;
figure 3 is a top view of a honeycomb core in a partially drawn out position;
figure 4 is a top view of a honeycomb core in fully drawn out position; and
figure 5 is a cross sectional view of one of the paper strips of which the honeycomb core according to the inven¬ tion is built up.
Figure 1 shows a honeycomb panel 1 which comprises a honeycomb core 2 and cover plates 3 and 4 glued to it. The honeycomb core 2 is built up of trapezoid-shaped corrugated strips 5 which consist for the most part of paper. Instead of a light or heavy paper quality (card¬ board) another cellulose material can be used.
In the figures 2, 3 and 4 top views of the honeycomb core are shown in folded-up and partially and fully drawn out positions. The strips 5 extend in longitudinal direction along each other, and parts 6 thereof are glued at least in part along their longitudinal direction, alternately to the adjacent strips on both sides, for example with poly- vinyl acetate glue (PVAC glue) , the parts 7, of approxi¬ mately the same length, located between the glued parts 6, remaining unglued. If the honeycomb core is drawn out in a direction perpendicular to the plane of the strips 5 (figure 3) , a grid of more or less regular hexagonal cells 8 is formed, with approximately the same cell diameter D, the cell sides of which being formed by the glued parts 6 and the intermediate parts 7 (figure 4) . The cells can, for instance, be 13 mm in diameter D and 50 mm in height (strip width) .
The strips 5 form the walls 9 of the cells 8 of the hexagonal grid and can be folded at their ends and be turned back for forming the adjacent strip. After stret- ching the honeycomb core a honeycomb panel can be formed with it by glueing (for example with PVAC glue) the cover plates 3 and 4 to the upper and lower edges of the cell walls 9 (figure 1) . It is, however, also possible to provide a honeycomb panel with a honeycomb core 2 accor- ding to the invention, in which a cover plate 3 is glued to only one side of the core 2.
The cells of the honeycomb panel 1 can be empty or filled with an insulating material. The panel can be manufactured cheaply of inherently flexurally slack material, but has as a whole a high resistance to compression in a direction perpendicular to the principal plane and has a high flexural stiffness.
The structure of the material of the strip 5 is shown schematically in figure 5. The strips 5 are layered and consist of two layers of paper 10 and 11 (another cellulo¬ se material is also possible) , between which there is a layer of polyethene 12, which is melted together with the paper layers. Of course another plastic, in particular a polymer, can be used. The polyethene layer 12 has a surfa- ce density between 5 and 50 g/m2 and preferably has a density of approximately 12 g/m . The paper layers 10 and 11 have surface densities betweeen 50 and 125 g/m2 and preferably have a surface density of 70 g/m .
The polyethene layer 12 is not moisture-penetrable and the strips 5 are therefore moisture-sealed. If the material of the strips 5 is exposed on one side to moisture, only the paper layer 10 or 11 on that side will get wet and the other paper layer will stay dry.
If a honeycomb panel is built up of a honeycomb core of the moisture-sealed paper described, against which on one or both panel sides a cover plate is glued, then at least one of the cover plates can have the same structure as that of the strips 5 according to figure 5. The polyethene layer 12 can then have the same surface density as that of the strips 5, whereas the paper layers 10 and 11 of the cover plates can have a surface density such that the total surface density of each cover plate is between 150 and 750 g/m2.
In a honeycomb panel according to figure 1 in which the strips 5 of the core 2 as well as both the cover plates 3 and 4 are provided with a moisture-sealed polyethene layer 12 built into the paper as described above, the cells 8 of the hexagonal grid are separated by moisture-sealed poly¬ ethene layers 12 from each other and from the outside. Thus moisture cannot penetrate through the panel surfaces or through the cell walls 9 at one of the circumferential edges of the panel, and can only moisten a paper layer on an outer side of the panel. If the panel is damaged local- ly, and the moisture-sealed polyethene layer 12 is broken there, moisture can penetrate into the respective cell or cells 8 and moisten the paper layers exposed therein. However, the other moisture-sealed polyethene layers 12 of those cells 8 prevent the moisture from spreading further in the panel 1, thus limiting the moisture damage to the damaged cells 8.
A water-resistant glue is used for glueing, which impreg¬ nates the paper. The relatively slow migration of moisture through the paper, parallel to a glueing bond and the moisture-sealed layers, or in between two strips, or across a strip edge through the paper of a cover plate, to an adjacent, undamaged cell, is effectively blocked by the local paper impregnations.
Honeycomb panels 1 according to the invention can, for instance, be used in pallets, which are almost completely made up of paper, with decks and foot blocks formed from honeycomb panels according to the invention. Such pallets can stand in a puddle of water without any problem, since they are not sensitive to weakening by the penetration of moisture therein.
Honeycomb panels according to the invention can, in addi- tion, be used as filling material in car doors, for insu¬ lating and for cushioning the impact in sideward collisi¬ ons. For that purpose suitable packs of such honeycomb panels 1 are formed, which are arranged vertically in the car door. Because of fluctuations in the relative air humidity and the temperature, water can condense in the inside of the door, as a result of which the panel pack will get wet through direct condensation thereon or indi- rectly. Moreover, on account of ageing of the rubber seals of the door window, rain water can leak into the inside of the door, so that the panel pack, initially the edges thereof, will get wet. The polyethene layers 12 in the strips 5 of the honeycomb core 2 and also those in the cover plates 3 and 4 provide an effective seal against this moisture.
By building in the moisture-sealing polyethene layer 12 in the paper, the material retains the character of paper. The material can be processed using the usual methods and materials in the production process for honeycomb cores and honeycomb panels (and further for pallets and car door fillings) , among others by the usual cutting and glueing actions. In addition, the material has the thermal stabi¬ lity and the mechanical strength of paper, that is to say, for example, that at 150° C it retains its shape and strength which is not the case with a material built up entirely of polyethene, polypropene or another cheap plastic.
The material of the honeycomb core and the honeycomb panel according to the invention can easily be recovered for re¬ use by shredding it and stirring it into water in a so- called pulper. The water then penetrates the paper and because of the stirring the paper is mechanically separa¬ ted from the polyethene, so that a paper slurry, the pulp, is formed. The polyethene can then be scooped out of the paper slurry after which the latter can be reused for producing paper products. This method for recovery does not work in the case of impregnated paper, in view of the fact that the water cannot penetrate it. Water-resistant glue residues and small paper fractions impregnated with water-resistant glue can, however, also be easily scooped up out of the paper slurry.

Claims

C L A I M S
1. Honeycomb core, built up of strips made with a material, such as cellulose material, the strength and/or the shape of which is sensitive to the action of moisture, characterized in that the strips are built up in layers and comprise a layer of plastic.
2. Honeycomb core according to claim 1, characterized in that the plastic layer is located between two layers of the moisture-sensitive material and is integral with this.
3. Honeycomb core according to claim 2, in which the moisture-sensitive material is paper, characterized in that the plastic layer is melted together with the paper layers.
4. Honeycomb core according to claim 3, characterized in that the paper layers have a surface density between 50 and 125 g/m .
5. Honeycomb core according to claim 4, characterized in that the paper layers have a surface density of about 70 g/m2.
6. Honeycomb core according to any one of the preceding claims, characterized in that the plastic layer is made of polyethene.
7. Honeycomb core according to claim 6, characterized in that the polyethene layer has a surface density between 5 and 50 g/m2.
8. Honeycomb core according to claim 7, characterized in that the polyethene layer has a surface density of about 12 g/m2.
9. Honeycomb core according to any one of the preceding claims, characterized in that it is built up by gluing the strips together with a moisture-proof glue.
10. Honeycomb core according to claim 9, charac¬ terized in that the strips are impregnated by the glue at the locations where they are glued together.
11. Honeycomb panel in the form of a sandwich construction, comprising a honeycomb core according to any one of the preceding claims or any one of the claims 21- 27, and two cover plates which define panel faces, between which the core is glued, characterized in that at least one of the cover plates is moisture-proof.
12. Honeycomb panel according to claim 11, of which the cover plates are made with a material, such as cel¬ lulose material, the strength and/or the shape of which is sensitive to the action of moisture, characterized in that at least one of the cover plates is built up in layers and comprises a layer of plastic.
13. Honeycomb panel according to claim 12, charac¬ terized in that the cover plate concerned comprises two layers of the moisture-sensitive material, between which the plastic layer thereof is located which is integral with this.
14. Honeycomb panel according to claim 13, in which the moisture-sensitive material of the cover plates is paper, characterized in that the plastic layer of the cover plate concerned is melted together with the paper layers thereof.
15. Honeycomb panel according to claim 14, charac¬ terized in that the plastic layer of the cover plate concerned is made of polyethene.
16. Honeycomb panel according to claim 15, charac¬ terized in that the polyethene layer of the cover plate concerned has a surface density between 5 and 50 g/m2.
17. Honeycomb panel according to claim 16, charac¬ terized in that the polyethene layer of the cover plate concerned has a surface density of about 12 g/m2.
18. Honeycomb panel according to any one of the claims 11-17, characterized in that the cover plates have a surface density between 150 and 750 g/m2.
19. Honeycomb panel according any one of the claims 11-18, characterized in that the cover plates and the core are glued together with a moisture-proof glue.
20. Honeycomb panel according to claim 19, charac¬ terized in that the cover plates and the strip edges are impregnated by the glue at the locations where they are glued together.
21. Honeycomb core, built up of strips made with a material, such as cellulose material, the strength and/or the shape of which is sensitive to the action of moisture, characterized in that the strips are built up in layers and comprise a layer of plastic, located between two layers of the mois- ture-sensitive material and being integral with this, that the honeycomb core is built up by gluing the strips together with a moisture-proof glue, and that the strips are impregnated by the glue at the locations where they are glued together.
22. Honeycomb core, built up of strips made with a material, such as cellulose material, the strength and/or the shape of which is sensitive to the action of moisture, characterized in that the strips are built up in layers and comprise a layer of plastic, located between two layers of the mois¬ ture-sensitive material and being integral with this, and that the plastic layer is melted together with the moisture-sensitive layers.
23. Honeycomb core, built up of strips made with a material, such as cellulose material, the strength and/or the shape of which is sensitive to the action of moisture, characterized in that the strips are built up in layers and comprise a layer of plastic, located between two layers of the mois¬ ture-sensitive material and being integral with this, and that the plastic layer is made of polyethene.
24. Honeycomb core according to claim 23, charac¬ terized in that the polyethene layer has a surface density of between 5 and 50 g/m2.
25. Honeycomb core according to claim 24, charac¬ terized in that the polyethene layer has a surface density of about 12 g/m2.
26. Honeycomb core according to any one of the claims 21 - 25, in which the moisture-sensitive material is paper, characterized in that the paper layers have a surface density between 50 and 125 g/m2.
27. Honeycomb core according to claim 26, charac¬ terized in that the paper layers have a surface density of about 70 g/m2.
PCT/NL1996/000124 1995-03-31 1996-03-22 Honeycomb core of a moisture sealing material WO1996030202A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BR9607911A BR9607911A (en) 1995-03-31 1996-03-22 Honeycomb core of a moisture sealing material
EP96906099A EP0869866A1 (en) 1995-03-31 1996-03-22 Honeycomb core of a moisture sealing material
AU49579/96A AU4957996A (en) 1995-03-31 1996-03-22 Honeycomb core of a moisture sealing material
PL96322528A PL322528A1 (en) 1995-03-31 1996-03-22 Middle layer of a structural member of honeycomb structure, made of damp-proofing material
JP8529206A JPH11502787A (en) 1995-03-31 1996-03-22 Honeycomb core of moisture-proof seal material

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL9500623 1995-03-31
NL9500623A NL9500623A (en) 1995-03-31 1995-03-31 Honeycomb core of moisture-resistant material.

Publications (1)

Publication Number Publication Date
WO1996030202A1 true WO1996030202A1 (en) 1996-10-03

Family

ID=19865781

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/NL1996/000124 WO1996030202A1 (en) 1995-03-31 1996-03-22 Honeycomb core of a moisture sealing material

Country Status (12)

Country Link
EP (1) EP0869866A1 (en)
JP (1) JPH11502787A (en)
CN (1) CN1183076A (en)
AU (1) AU4957996A (en)
BR (1) BR9607911A (en)
CA (1) CA2216841A1 (en)
CZ (1) CZ304097A3 (en)
HU (1) HUP9801935A3 (en)
NL (1) NL9500623A (en)
PL (1) PL322528A1 (en)
TR (1) TR199701067T1 (en)
WO (1) WO1996030202A1 (en)

Cited By (3)

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Publication number Priority date Publication date Assignee Title
US10197708B2 (en) 2013-12-19 2019-02-05 Hrl Laboratories, Llc Structures having selectively metallized regions and methods of manufacturing the same
US10710326B1 (en) 2013-11-26 2020-07-14 Hrl Laboratories, Llc Open cellular sandwich structures having sealed edges and methods of manufacturing the same
US11148375B1 (en) 2017-08-29 2021-10-19 Hrl Laboratories, Llc Method of repairing sandwich structure and repaired sandwich structure

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010050872B4 (en) * 2010-11-09 2016-10-20 Daimler Ag Sandwich component and method for its production

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GB803259A (en) * 1954-01-26 1958-10-22 Dufaylite Dev Ltd Improvements in or relating to cellular structures made from paper and other sheet materials
US3673058A (en) * 1969-04-07 1972-06-27 Hexcel Corp Honeycomb having laminates of unidirectional strands
US4247583A (en) * 1978-10-30 1981-01-27 Roy Paul D Insulating structure with polygonal cells
EP0068873A2 (en) * 1981-06-26 1983-01-05 Quinton & Kaines (Holdings) Limited Composite boards and panels
EP0474161A2 (en) * 1990-09-04 1992-03-11 Mitsubishi Rayon Co., Ltd. Honeycomb core

Patent Citations (5)

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Publication number Priority date Publication date Assignee Title
GB803259A (en) * 1954-01-26 1958-10-22 Dufaylite Dev Ltd Improvements in or relating to cellular structures made from paper and other sheet materials
US3673058A (en) * 1969-04-07 1972-06-27 Hexcel Corp Honeycomb having laminates of unidirectional strands
US4247583A (en) * 1978-10-30 1981-01-27 Roy Paul D Insulating structure with polygonal cells
EP0068873A2 (en) * 1981-06-26 1983-01-05 Quinton & Kaines (Holdings) Limited Composite boards and panels
EP0474161A2 (en) * 1990-09-04 1992-03-11 Mitsubishi Rayon Co., Ltd. Honeycomb core

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10710326B1 (en) 2013-11-26 2020-07-14 Hrl Laboratories, Llc Open cellular sandwich structures having sealed edges and methods of manufacturing the same
US11305509B1 (en) 2013-11-26 2022-04-19 Hrl Laboratories, Llc Open cellular sandwich structures having sealed edges and methods of manufacturing the same
US10197708B2 (en) 2013-12-19 2019-02-05 Hrl Laboratories, Llc Structures having selectively metallized regions and methods of manufacturing the same
US10775534B2 (en) 2013-12-19 2020-09-15 Hrl Laboratories, Llc Structures having selectively metallized regions and methods of manufacturing the same
US11148375B1 (en) 2017-08-29 2021-10-19 Hrl Laboratories, Llc Method of repairing sandwich structure and repaired sandwich structure
US11806956B1 (en) 2017-08-29 2023-11-07 Hrl Laboratories, Llc Method of repairing sandwich structure

Also Published As

Publication number Publication date
MX9707445A (en) 1998-07-31
TR199701067T1 (en) 1998-04-21
PL322528A1 (en) 1998-02-02
HUP9801935A2 (en) 1998-12-28
CN1183076A (en) 1998-05-27
EP0869866A1 (en) 1998-10-14
BR9607911A (en) 1998-06-09
NL9500623A (en) 1996-11-01
HUP9801935A3 (en) 1999-03-01
AU4957996A (en) 1996-10-16
JPH11502787A (en) 1999-03-09
CZ304097A3 (en) 1998-01-14
CA2216841A1 (en) 1996-10-03

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