WO1996025461A1 - Compositions de melanges de fluoroelastomere et de silicone et agent de fusion les contenant - Google Patents

Compositions de melanges de fluoroelastomere et de silicone et agent de fusion les contenant Download PDF

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Publication number
WO1996025461A1
WO1996025461A1 PCT/US1996/002057 US9602057W WO9625461A1 WO 1996025461 A1 WO1996025461 A1 WO 1996025461A1 US 9602057 W US9602057 W US 9602057W WO 9625461 A1 WO9625461 A1 WO 9625461A1
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WO
WIPO (PCT)
Prior art keywords
fluoroelastomer
polysiloxane
sio
blend
hfp
Prior art date
Application number
PCT/US1996/002057
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English (en)
Inventor
Chris F. Delrosario
Carl A. Aufdermarsh
Original Assignee
Ames Rubber Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ames Rubber Corporation filed Critical Ames Rubber Corporation
Priority to EP96906456A priority Critical patent/EP0809675A1/fr
Publication of WO1996025461A1 publication Critical patent/WO1996025461A1/fr

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Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G15/00—Apparatus for electrographic processes using a charge pattern
    • G03G15/20—Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat
    • G03G15/2003—Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat using heat
    • G03G15/2014—Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat using heat using contact heat
    • G03G15/2053—Structural details of heat elements, e.g. structure of roller or belt, eddy current, induction heating
    • G03G15/2057—Structural details of heat elements, e.g. structure of roller or belt, eddy current, induction heating relating to the chemical composition of the heat element and layers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/20—Homopolymers or copolymers of hexafluoropropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes

Definitions

  • This invention relates to blends of fluoroelastomer and silicone, and more particularly to blends of polysiloxane particles dispersed in a matrix of fluoroelastomer vulcanizate suitable for use in fusing applications and to fuser members with improved copy life having a top coat of the blend.
  • a fuser member is designed to apply direct heat and pressure to a toner image on a recording medium.
  • the surface top coat permits toner to be fixed to the recording medium without adhering to the fuser member surface and can withstand continuous exposure to high temperatures, silicone oils, toners, toner additives and paper product residue without unacceptable physical degradation.
  • an image formed of a heat fusible toner powder is selectively disposed on a web-like surface of a recording medium, such as paper, by electrostatic forces.
  • Toner powders are commonly formed of a mixture of thermoplastic and/or thermosetting resin carriers and additives such as amorphous carbon and magnetic particles. They are conventionally fixed to the recording paper by direct contact with a fuser member such as a roller which applies pressure and heat at temperatures between about 200 to 400°F.
  • the fusing process is conventionally accomplished by feeding a recording medium having the toner image thereon between the nip where two mated rollers meet.
  • One or both of the rollers are heated, typically by an internal heat source within the roller, so that the surface temperature of the roller will be above the softening point of the resinous carrier of the toner.
  • the recording medium with the toner image thereon is fed between the two rollers which press towards each other to apply direct heat and pressure to the toner image.
  • the amount of pressure and the length of time that the toner is heated determines the degree of fusing.
  • the actual temperature range suitable for fixing toner images to recording paper is referred to as the "fusing window".
  • the fusing window, T w can be defined by the formula:
  • T w T 0FF - T MIN wherein T 0FF is the hot offset temperature and T MIN is the minimum fusing temperature.
  • Hot offset temperature is the temperature at which the cohesive forces within the molten toner layer are less than the adhesive forces between the toner and roller surface so that toner adheres to the fuser roller.
  • T MIN is the minimum temperature at which toner can be acceptably fixed to the recording paper. This temperature range is dependent on the raw materials, type of toner, release agents and the pressure applied by the rollers. It is important that the toner is fixed without "offset" occurring, in order to produce copies of acceptable quality.
  • a fusing window of at least 30°F is acceptable for some applications. However, it is preferable to have as large a fusing window as possible. Thus, a 60°F fusing window is desirable and a 100°F fusing window is particularly ideal.
  • Softened toner generally has an affinity for the surface of the fuser roller it contacts. When toner adheres to the surface of a fuser roller, it can unintentionally be deposited on an unselected portion of the recording medium during the next rotation of the roller. This phenomenon is referred to as "offset. "
  • a thin coating of a release agent such as polysiloxane fluid is commonly spread over the surface of the fuser roller which contacts the surface of the toner image.
  • the polysiloxane fluid reduces the surface free energy of the roller surface and decreases the affinity of the toner for the roller.
  • Surface energy values for several conventional fuser roller materials are set forth below in Table I.
  • PTFE Polytetrafluoroethylene
  • PVF 2 Polyvinylidene fluoride
  • metal oxides are typically included to act as an acid acceptor, cure activator, reinforcing filler and/or as an additive to promote improved chemical resistance.
  • Commercially available fuser rollers generally have a fluoroelastomer surface which contains metal oxide particles in at least the fluoroelastomer surface layer.
  • U.S. Patent Nos. 4,257,699, 4,264,181 and 4,272,179 describe fuser rollers in which additional metal oxide filler particles beyond that needed to promote cure of the material are added to the fluoroelastomer surface material to increase the metal oxide content of the surface of the fuser rollers. Fluoroelastomers described in U.S. Patent No.
  • a blend of polysiloxane particles dispersed in a fluoroelastomer particularly well suited for the topcoat of a fusing member for applying heat and pressure to fix toner to a recording medium is provided.
  • the fluoroelastomer material are those having high molar content of hexafluoropropylene (HFP) , with a molar content above about 23.4 mole per cent.
  • the fluoroelastomer and silicone blend can be formed by a first insitu method, wherein a hydropolysiloxane is crosslinked in the presence of a catalyst in a fluoroelastomer which has been dissolved in a suitable solvent.
  • a second pre-reaction method the hydropolysiloxane is crosslinked in a solvent in the presence of a catalyst and a fluoroelastomer is then added.
  • a fusing member having a fluoroelastomer and silicone blend surface prepared in accordance with the invention has advantages over conventional fusing members in fusing systems using dimethylpolysiloxane release fluids, by providing increased copy life and avoiding the need to use expensive mercapto functional active release agents to prevent offset. Accordingly, it is an object of the invention to provide an improved fluoroelastomer and silicone blend composition.
  • Another object of the invention is to provide an improved fuser member having a topcoat of fluoroelastomer and silicone blend for fixing toner to a recording medium.
  • a further object of the invention is to provide a fuser member having a fluoroelastomer and silicone blend topcoat for fusing without the need to use mercapto functional release agents.
  • the invention accordingly comprises the several steps and the relation of one or more of such steps with respect to each of the others, and the composition possessing the features, properties and the relation of constituents and the article possessing the features, properties, and the relation of elements, which are all exemplified in the following detailed disclosure, and the scope of the invention will be indicated in the claims.
  • FIG. 1 is a schematic cross-sectional view of a fuser roller test assembly
  • FIG. 2 is a cross-sectional view of a single layer fuser roller constructed in accordance with an embodiment of the invention
  • FIG. 3 is a cross-sectional view of a multi-layer fuser roller constructed in accordance with another embodiment of the invention.
  • FIG. 4 are the results of an X-ray analysis of the surface of a cut cross-section of a film of a fluoroelastomer and silicone blend prepared in accordance with the invention
  • FIG. 5 are the results of an X-ray analysis of an individual dispersed particle in the film analyzed in FIG. 4;
  • FIG. 6 is a Thermogram showing the Dynamic Mechanical Thermal Analysis of the film of FIG. 4 measured on a plastic backing, and measured by Differential Scanning Calorimetry.
  • a fusing member constructed in accordance with an embodiment of the invention includes a fluoroelastomer and silicone blend topcoat surface.
  • the fusing member can be a roller, a belt, a flat surface or another substrate having a suitable shape for fixing toner images to a recording medium, such as paper, at elevated temperatures under pressure.
  • a preferred fusing member is a fuser roller having a metal core that can be hollow, covered with the fluoroelastomer and silicone blend material.
  • a heating element can be included within the metal core to heat the fluoroelastomer and silicone blend surface.
  • the fuser roller can be used to fix toner powder to a recording medium, such as paper, without offset and without relying on the interaction between metal oxides in a fluoroelastomer and mercapto functional release agent fluids.
  • the outer layer of the fusing member is of a fluoroelastomer material having high molar content of HFP
  • the fluoroelastomer preferably is a copolymer of HFP and VF 2 (vinylidene fluoride) monomer, and includes more HFP monomer than VF 2 monomer, so that the weight ratio of VF 2 to HFP is less than about 1.40, and above about 0.70.
  • a copolymer of VF 2 and HFP based on the monomer content described would contain between about 65 to 71 percent total fluorine by weight.
  • Preferred silicone material for preparation of the composition are hydropolysiloxane oligomers having weight average molecular weights ranging from about 500 to 10,000 and preferably between about 500 and 2,000.
  • the hydropolysiloxane is preferably present in the composition between about 10 to 40% by weight.
  • the preferred polysiloxane phase is selected from dimethylpolysiloxane copolymers which can be described and specified as:
  • the weight average molecular weight of the aforementioned copolymers can vary from about 550 to 120,000, with the most preferred range being between about 2000 to 60,000.
  • the silicone copolymer phase can be insitu crosslinked in the presence of the fluoroelastomer phase, or crosslinked independently in solvent and added to the fluoroelastomer phase.
  • suitable crosslink agents must be present to crosslink the silicone copolymer.
  • Suitable crosslinking agents include water, vinyl silanes and hydrosilanes, plus catalysts appropriate to the chemistry, i.e. Sn (IV) salts for condensation reactions and Pt salts for addition systems.
  • the fluoroelastomer composition can also include cure additives, such as hexafluoropropylidine diphenol, triphenyl benzylphosphonium chloride/bromide and acid acceptors, including metal oxides in some.
  • cure additives such as hexafluoropropylidine diphenol, triphenyl benzylphosphonium chloride/bromide and acid acceptors, including metal oxides in some.
  • the effectiveness of compositions prepared in accordance with the invention are due to inclusion of the silicone phase and including higher amounts of HFP than is conventional.
  • the high HFP content relates to the associated reduction in surface energy at the expense of other properties conventionally considered to be more important.
  • the top coat compositions can be prepared in two ways.
  • the first, or "insitu” method follows a sequence whereby the fluoroelastomer is first put into solution by dissolving in an appropriate solvent, such as methyl ethyl ketone (MEK) , methyl isobutyl ketone (MIBK) , ethyl acetate, and the like.
  • MEK methyl ethyl ketone
  • MIBK methyl isobutyl ketone
  • ethyl acetate ethyl acetate
  • a typical solids by weight content ranges from about 10 to 40 percent of the solution.
  • a hydropolysiloxane and a platinum catalyst is then added to the fluoroelastomer solution and lightly agitated until thoroughly mixed. The mixture is allowed to stand until evolution of hydrogen is completed after which time the mixture is ready for use as coating material for fabrication of fusing members.
  • the second, or "pre-reaction” method follows a sequence whereby hydropolysiloxane in the presence of ketone base solvent, distilled water and platinum salt complex is first refluxed for about 1 to 2 hours at slightly above the boiling point of the solvent, allowed to cool after which time the fluoroelastomer components is added and agitated until the fluoroelastomer component is dissolved.
  • the "pre-reaction” method can also be prepared as a two component system whereby the fluoroelastomer component as in the in-situ method is first dissolved in solvent prior to blending with the pre-reacted silicone component. The latter method of preparation (pre- reaction) generally allows higher proportion of silicone component to be added in the composition.
  • a fuser roller test assembly 100 is shown generally in FIG. 1.
  • Roller 100 applies heat and pressure to fuse a quantity of toner particles 12 on a sheet of paper 13 between a fuser roller 20 and a pressure roller 30.
  • Fuser roll test assembly 100 also includes a release agent application unit 11 including a wick 15 for applying release agent to the surface of fuser roller 20.
  • a stripper finger 16 facilitates the separation of paper 13 from roller 20.
  • FIG. 2 is a cross-sectional view of a fuser roller 200 constructed in accordance with an embodiment of the invention.
  • Fuser roller 200 includes a hollow middle core 201 covered with a fluoroelastomer surface layer 202.
  • a second fuser roller 300 is shown in cross-sectional view in FIG. 3.
  • Fuser roller 300 includes an insert 302 covered with a base coat 303 having a tie coat 304 disposed thereon and a topcoat 302 disposed on tie coat 304.
  • Base coat 303 is preferably 0.5 to 5 mil thick and the overall coating (either surface layer 202 or combined layers 303, 304, and 302) should be between about 3 to 8 mils thick.
  • the following Examples describe fluoroelastomer and silicone blend compositions and fuser members having a topcoat of the composition prepared in accordance with the invention.
  • a composition containing 75% by weight of an incorporated cure copolymer of VF 2 and HFP having 37% mole percent HFP with a VF 2 /HFP mole ratio of 1.7, and 25% by weight hydropolysiloxane having molecular weight of 1610 was prepared by first dissolving the components in MEK. Using an appropriate amount of MEK to make a 10% solids mixture, the two solutions were blended with addition of approximately 0.1% chloroplatinic acid as a catalyst. The mixture was then allowed to stand at room temperature until evolution of hydrogen was completed prior to use as a coating material for fabrication of a fuser roller sample.
  • Fabrication of the fuser roller sample was made using a 38mm diameter aluminum insert that has been degreased, sandblasted, degreased and an epoxy based adhesive (Thixon 300/301) applied by spraying approximately 0.01 to 0.02mm thickness.
  • the fluoroelastomer silicone mixture was applied to the prepared insert by spraying to a thickness build-up of 0.30mm.
  • the sample was then allowed to dwell at room temperature for 12 to 24 hours after which it was then exposed to a curing cycle of 1 hour each at 100°C, 121°C, 149°C, 176°C, plus 16 hours @ 204°C. using an air circulating oven.
  • the cured sample was then ground to have a final coating thickness of 0.2mm.
  • roller prepared in the foregoing manner was placed in a fuser assembly shown in FIG. 1.
  • a linear polydimethysiloxane release fluid of 250 CSTKS viscosity the roller showed excellent release of thermoplastic resin toner and excellent copy life.
  • a fuser roller is prepared in accordance with Example 1, except that an inner layer of fluoroelastomer compound consisting of 100 parts of fluoroelastomer described in Example 1, 15 parts of MgO, 2 parts of Ca(OH) 2 and 20 parts of MT black was applied to the insert by similar spraying manner to a thickness build-up of 0.07mm before applying the top layer composition described in Example 1.
  • the roller was then placed in a fuser assembly shown in FIG. 1 and used with a linear polydimethysiloxane release fluid of 250 CSTKS viscosity.
  • the roller showed excellent release of thermoplastic toner resin, excellent copy life and no sign of coating delamination from the aluminum insert during the test period.
  • Example 3 A composition containing 75% by weight of an incorporated cure copolymer of VF 2 and HFP having 37% mole percent HFP with a VF 2 /HFP mole ratio of 1.7 and 25% by weight hydropolysiloxane having molecular weight of 1610 was prepared using the pre-reaction method. In this method, 77.8 g of hydropolysiloxane (M.W. 1610), 724.5 g of MEK, 6.6 g of distilled water and 3.3 cc of chloroplatinic acid (0.1% solution) was refluxed at about 80°C. for 2 hours then allowed to cool.
  • hydropolysiloxane M.W. 1610
  • Example 4 A composition containing 75% by weight of an incorporated cure polymer of VF 2 and HFP having 44 mole percent HFP with a VF 2 /HFP mole ratio of 1.2 and 25% by weight hydropolysiloxane having molecular weight of 1610 was prepared using the pre-reaction method described in Example 3. A fuser roll of this composition using the methods used in Example 3 showed excellent release from the thermoplastic toner with no hot offset observed when this roller is heated at 185°C. to fix toner to paper.
  • Example 5 A fuser roller was prepared in accordance with
  • Example 3 except that the outermost layer or topcoat composition was modified to include 4.2 percent by weight of dicinnamylidene - 1,6 hexanediamine to the fluoroelastomer component.
  • the roller prepared in the foregoing manner was placed in a fuser assembly shown in FIG. 1 and used with a linear polydimethysiloxane release fluid of 250 CSTKS viscosity.
  • the roller showed excellent toner release properties, absence of flat spots and no hot off-set observed when this roll was heated at 185°C. to fix toner to paper.
  • rollers prepared in Examples 1-5 were tested for roller life.
  • the materials utilized and the roller life results tested are set forth in the following Table II.
  • Fuser roller samples were formed by covering a 1.5 inch standard aluminum insert with a 4 mil thick fluoroelastomer base coat covered with a 2 mil thick topcoat of the materials shown below in Table II.
  • the sample fuser rollers were prepared by first mixing the base coat material and topcoat material in a two roll mixing mill.
  • the base coat compound was formulated by combining 100 parts VITON E-60
  • the mixed starting materials were dissolved in a 50:50 blend of methyl ethyl ketone (MEK) and methyl isobutyl ketone (MIBK) solvents to approximately a 15% solid concentration.
  • MEK methyl ethyl ketone
  • MIBK methyl isobutyl ketone
  • the aluminum insert was precured with a primer layer of THIXON 300/301 adhesive and then sprayed with the base coat solution to a thickness of about 5-6 mils.
  • the coated sample was maintained at room temperature to permit residual solvent to evaporate and then cured in a circulating oven for up to 24 hours at a temperature of 150 to 450° F.
  • the sample was then ground to a base coat thickness of 3-4 mils. After washing the sample with solvent, it was over sprayed with a 15% solid topcoat solution to yield a coating having a thickness of 4 to 5 mils. Residual solvent was permitted to evaporate and the sample was subjected to final curing in a hot air circulating oven
  • Fusing tests herein were carried out by passing an 8.5 x 11.5 inch 75g/m 2 sheet of paper having toner particles thereon between fuser roller 20 and pressure roll 30 to fuse toner 12 to paper 13.
  • Fuser roller life is indicated by the number of sheets of paper that can be successfully fused before failure by either offset, mechanical failure or some other difficulty.
  • Runs I and II By comparing Runs I and II, it can be seen that including a high HFP percentage is associated with 100% increase in roller life. Run IV having 70% F shows a further 75% increase in roller life compared to Run II and a 250% increase over Run I with 66% F. The most dramatic increase can be seen by comparing Runs III, V and VI. Elimination of metal oxide within the fuser roll surface material leads to a further significant increases in roller life. The increase in Runs III and V is due to use of a mercapto-functional polydimethylsiloxane release oil.
  • the blend prepared in accordance with the invention incorporates high concentrations of silicone dispersed in a matrix of fluoroelastomer vulcanizate. Analysis of the fluoroelastomer and polysiloxane blends prepared in accordance with the invention confirm they are physical mixture without any evidence of covalent bonding between the fluoroelastomer and polysiloxane.
  • Example 7 A cured fluoroelastomer of 75% copolymer of VF 2 and
  • HFP containing phosphonium salt accelerator and bisphenol cross linker with 70 weight percent fluorine, 25% polydimethylsiloxane (a hydropolysiloxane oligomer) as in Example 1 and a platinum catalyst was dissolved in MEK.
  • the solution was spray-coated on a substrate, air-dried overnight and subjected to a stepped post cure cycle ending with heating for 24 hours at 400°F.
  • the 100 micron film so prepared was a dry, pale tan, translucent elastomer which appeared to be under-cured.
  • Photomicrographs of both the film surface and a cut cross-section low magnification indicated mud-cracking. At higher magnification a grainy topography was visible with numerous particles under the surface appearing to be about 0.1 ⁇ m or less in diameter.
  • the cross-section featured voids and numerous particles ranging broadly in size from less than 0.1 ⁇ m to as much as 10 ⁇ m. Many were smoothly ovoid in shape. The appearance of the voids and particles suggested very poor interfacial adhesion.
  • X-ray analysis of the ovoid shaped particles showed the presence of C, 0 and Si as shown in FIG. 4.
  • FIG. 6 is a Thermogram showing the DMTA (Dynamic Mechanical Thermal Analysis) of the film supported by a plastic backing.
  • the lower tan ⁇ curve shows three thermal transitions centered at -80°, -3° and +17°C.
  • the first transition is very broad and is assigned to the mixture of polydisperse polysiloxanes derived from the hydropolysiloxane.
  • the transition at -3°C corresponds to the glass transition temperature (T g ) of the fluoroelastomer. This was the normal T g expected for this polymer.
  • the peak at +17°C may be a third order transition and is not believed to be significant because it was not confirmed in the DSC discussed below.
  • a Thermogram was measured on the plastic backing alone after removal of the film. This did not exhibit any feature showing that the backing did significantly affect the transitions observed in the Thermogram of FIG. 6.
  • a Thermogram obtained by Differential Scanning Calorimetry confirmed the normal fluoroelastomer T g at -2.3°C.
  • Sample films from the formulation utilized in Example 7 were prepared in both the un-cured and the fully-cured state and were coded Ex 8-A.
  • a second set of un-cured and fully cured films was prepared by a modified make-up procedure.
  • a solution of polydimethylsiloxane oligomer and Curative 50 was prepared and aged for 72 hours before mixing with a solution of the fluoroelastomer L of Example 7.
  • the Pt catalyst was then added to the combined solution which was sprayed immediately.
  • Sample films coded Ex 8-B were obtained in both the un-cured and fully-cured state. Extraction of the four films with boiling methylene chloride was performed. The amounts of extractable material were reported as follows:
  • Metal free fluoroelastomer compositions utilized in some aspects of the invention include sufficient sites for cross-linking, but not excessive sites which would oxidize, thereby increasing surface energy and impede toner release. Furthermore, without residual metal oxide particles, the compositions inherently yield a polymer surface having lower surface energy, making it well suited for fusing applications.
  • compositions prepared in accordance with the invention as a fusing material is a result of the complimenting properties of the two elastomers specific to fusing applications.
  • the fluoroelastomer segments provides a toughness to the coating while the silicone segments provides a desirable silicone rich surface best suited for fusing systems utilizing silicone oil as a release agent in the fusing process.
  • ingredients or compounds recited in the singular are intended to include compatible mixtures of such ingredients wherever the sense permits.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Fixing For Electrophotography (AREA)

Abstract

L'invention concerne un mélange de fluoroélastomère et de silicone polymérisés adaptés à la couche de surface extérieure d'un élément de fusion, lequel ne nécessite pas l'utilisation d'agents de libération actifs à fonctionnalité mercapto afin d'empêcher un décalage. Le constituant fluoroélastomère des compositions contient au moins 23,4 mole pour cent d'hexafluoropropylène, et de préférence il ne contient pas d'oxyde de métal. Le mélange peut être préparé par dissolution du fluoroélastomère dans un solvant, et addition d'un siloxane et d'un catalyseur, puis polymérisation du siloxane. Dans une variante, on peut ajouter le siloxane au fluoroélastomère dans le solvant, en présence d'un catalyseur, puis l'ajouter au fluoroélastomère dans le solvant.
PCT/US1996/002057 1995-02-16 1996-02-15 Compositions de melanges de fluoroelastomere et de silicone et agent de fusion les contenant WO1996025461A1 (fr)

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US08/389,495 1995-02-16

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1065573A1 (fr) * 1999-06-30 2001-01-03 Xerox Corporation Procédé de fabrication de revêtements superficiels adhésifs et mélanges de revêtements d'élastomères à un dispositif de fusion
CN103889077A (zh) * 2012-12-21 2014-06-25 富士施乐株式会社 片材加热元件的制造方法、定影装置和图像形成设备
JP2015071758A (ja) * 2013-10-02 2015-04-16 ゼロックス コーポレイションＸｅｒｏｘ Ｃｏｒｐｏｒａｔｉｏｎ グラフェンおよびフルオロポリマーコンポジット

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EP0441645A2 (fr) * 1990-02-09 1991-08-14 Ames Rubber Corporation Rouleau de fixage par fusion recouvert d'un élastomère fluoré
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US4942202A (en) * 1987-10-30 1990-07-17 Japan Synthetic Rubber Co., Ltd. Rubber composition and vulcanized rubber product
EP0441645A2 (fr) * 1990-02-09 1991-08-14 Ames Rubber Corporation Rouleau de fixage par fusion recouvert d'un élastomère fluoré
EP0582841A1 (fr) * 1992-07-24 1994-02-16 Bayer Ag Combinaisons de polyorganosiloxanes et de caoutchoucs en polymère fluoré contenant des liaisons doubles par l'addition Si-H
EP0617345A1 (fr) * 1993-03-22 1994-09-28 Xerox Corporation Revêtements pour éléments de transfert intermédiaires

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R.M. FERGUSON ET AL.: "Viton/RTV silicone fuser release overcoating", XEROX DISCLOSURE JOURNAL, vol. 11, no. 5, September 1986 (1986-09-01) - October 1986 (1986-10-01), STAMFORD, CONECTICUT, US, pages 207, XP002005483 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1065573A1 (fr) * 1999-06-30 2001-01-03 Xerox Corporation Procédé de fabrication de revêtements superficiels adhésifs et mélanges de revêtements d'élastomères à un dispositif de fusion
CN103889077A (zh) * 2012-12-21 2014-06-25 富士施乐株式会社 片材加热元件的制造方法、定影装置和图像形成设备
JP2015071758A (ja) * 2013-10-02 2015-04-16 ゼロックス コーポレイションＸｅｒｏｘ Ｃｏｒｐｏｒａｔｉｏｎ グラフェンおよびフルオロポリマーコンポジット

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