Classifications

• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
  • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
  • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
  • C07C29/1516—Multisteps
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
  • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
  • B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
  • B01J19/122—Incoherent waves
  • B01J19/127—Sunlight; Visible light
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
  • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
  • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
  • C07C29/1516—Multisteps
  • C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
  • Y02P20/00—Technologies relating to chemical industry
  • Y02P20/50—Improvements relating to the production of bulk chemicals

Definitions

• This invention relates to improvements in the production of energy-providing fuels. It relates particularly to methods and apparatus for the production of methanol or methanol-based derivatives as an energy-providing fuel.
• Hydrocarbon substances such as methanol are useful fuel sources, in that they can be combusted to generate heat from which electricity can be derived by gas or steam turbines.
• methanol can be compressed and ignited, with the expansion energy thus liberated utilised to provide a power source for rotating engines, such as might be used in motor vehicles.
• Methanol also has the advantage of being readily transportable since it is a liquid at ambient temperature and pressure, and is chemically stable.
• the transportation modes can be pipelines or bulk carriers such as road tankers or ships.
• Methanol conventionally can be produced by coal-based synthesis units, broadly comprising a coal gasification system, a gas treatment and purification system, a gas compression and methanol synthesis system, and a methanol recovery and methanol distillation system.
• Coal is constituted by elemental carbon and other carbon-based compounds, together with impurities such as sulphur and nitrogen and particulates such as ash.
• impurities such as sulphur and nitrogen and particulates such as ash.
• the production of methanol from coal generates large amounts of waste carbon dioxide gas which is generally exhausted to the atmosphere. This is an undesirable occurrence since carbon dioxide is known to be a contributor to the greenhouse effect.
• Kansai Electric It has been proposed by the company Kansai Electric of Japan that carbon dioxide recovered from the use of fossil fuels in the generation of power in Japan could be shipped from Japan to a country such as Canada where it can be processed together with hydrogen produced by the process of the electrolysis of water to generate methanol.
• the electrolysis process would be based upon hydro-electric power, for example.
• the system proposed by Kansai Electric has two major problems, firstly that the fossil fuel-based power generation systems in Japan would need to incorporate a further system for the recovery of the carbon dioxide. Conventional power stations require significant plant investment and power consumption to implement carbon dioxide recovery. Secondly, a significant portion of the carbon in the fossil fuel thus is shipped three times between its source and the source of the electrolitically derived hydrogen.
• Carbon dioxide also is a difficult substance to store and transport, as it must be pressurised and placed at a low temperature for it to enter the liquid state (or as a cryogenic solid) to increase its density and thus make it efficient to transport.
• methanol is relatively easy of transport.
• the present invention seeks to overcome or at least ameliorate one or more of the foregoing problems.
• the invention discloses a process for producing methanol or a methanol-based fuel, the method comprising the steps of: synthesizing methanol or a methanol-based fuel from a supply of coal and a first supply of oxygen, and whereby excess carbon dioxide also is produced; generating a DC power supply from photo-voltaic cells; electrolysing water by said DC power supply to generate a second supply of oxygen and a supply of hydrogen; and producing further methanol or methanol-based fuel from said hydrogen and said excess carbon dioxide.
• the process can further provide for transporting said second supply of oxygen for use in said methanol synthesis step to replace or supplement said first supply of oxygen.
• the process can include the step of transporting said supply of hydrogen and/ or said second supply of oxygen from a location remote from the location where said synthesizing and further production steps take place.
• the invention further discloses a system for the production of methanol or a methanol-based fuel, said system comprising: a methanol synthesis unit receiving a supply of coal and a first supply of oxygen from which methanol or a methanol-based fuel is synthesized and excess carbon dioxide is produced; a photo- voltaic cell system for the generation of a DC power supply; an electrolysis system for the generation of a second supply of oxygen and a supply of hydrogen from water by means of said DC power supply; means for transporting at least said supply of hydrogen from said electrolysis system to said methanol synthesis unit; and methanol production means receiving said excess carbon dioxide and the transported supply of hydrogen for the further production of methanol or a methanol- based fuel.
• the photo- voltaic cell system and the electrolysis system are located remote from said methanol synthesis unit and said methanol production means.
• the system can further comprise storage means for storing the methanol or methanol- based fuel produced by said synthesis unit and said further production unit.
• said transporting means comprises a pipeline or a bulk carrier.
• the system comprises further means for transporting said second supply of oxygen from said electrolysis system to said methanol synthesis unit to replace or supplement said first supply of oxygen.
• the invention further discloses methanol or methanol-based fuel produced in accordance with the above-described process or by the above-described system.
• FIG. 1 is a schematic block diagram of a methanol-producing process and apparatus in accordance with an embodiment of the invention.
• a known coal-based methanol synthesis unit 20 is constituted by three conventional process stages, generally represented by the reference numerals 10,12 and 14.
• the first stage 10 is a coal gasification system that receives a supply of coal 116 together with a supply of oxygen 114.
• the oxygen provided to the gasifier system 10 can be provided in bulk from a commercial supply of oxygen, or alternatively as an output product of an electrolysis process, as presently will be described.
• the coal gasification system 10 consists of coal grinding and feeding systems, a gasifier(s) such as those produced by Texaco, Shell Totzec, High Temperature Winkler, U-Gas or the like, ash removal systems, heat exchange system boilers and other such units normally required for coal gasification.
• an impure coal-based synthesis gas is output from the gasifier system 10 via a pipeline(s) 120 to pass to the subsequent gas treatment and purification system 12.
• Impurities such as coal ash and water condensate are removed by an extraction system and rejected by the process output 118.
• the gas treatment and purification system 12 consists of dust and particle removal systems, shift reaction and acid gas separation systems. Acidic gases consisting of hydrogen sulphide, carbon dioxide and other impurities are removed from the synthesis gas by such systems. A purified form of (excess) carbon dioxide is output by a pipeline(s) 122 for subsequent processing, as will be described. The carbon dioxide also can be stored so that a stand-by supply is available for the methanol synthesis unit 14. The hydrogen sulphide and other impurities are output by a further process output 124 to be rejected.
• Methanol synthesis gas consisting of hydrogen, carbon monoxide and carbon dioxide in the correct proportions for the synthesis of methanol are output from the gas treatment and purification system 12 on a pipeline(s) 126.
• the synthesis gas may contain low percentages of impurities such as methane, nitrogen, argon or the like, which may be formed in the gasification stage or be present in the oxygen fed to the gasifier 10.
• the synthesis gas is input to the methanol synthesis unit 14 that performs the sub-processes of gas compression and methanol synthesis, methanol recovery and distillation to produce synthesized methanol or methanol-based fuel output by the pipeline(s) 130.
• Gaseous impurities which are purged from the synthesis loop including methane, argon, nitrogen and the like, and further impurities removed from the impure methanol produced by synthesis such as higher alcohols and dimethyl ether and the like are rejected by a further process output 128.
• Transportation of the supply of hydrogen preferably will be by pipeline, however other forms of bulk carriage also fall within the meaning of the term, including tanker haulage by rail or road.
• the resulting further methanol or methanol-based fuel is output by a pipeline(s) 134, and together with the methanol or methanol-based fuel generated by the methanol synthesis unit 20 in the pipeline(s) 130 is either stored in storage means such as tanks (not shown) for subsequent use as a fuel, else transported by pipeline (for example) for immediate use.
• By-products of the secondary methanol production system 16 such as higher alcohols and dimethyl ether, are removed and rejected by a yet further process output 132.
• the source of hydrogen provided to the secondary methanol production system 16, in this embodiment, is transported by pipeline from a remotely located production source.
• the production source is constituted by an photo-voltaic cell array system 2 that converts solar radiation into a DC electrical power supply 102 provided to a known water electrolysis system 4, such as those manufactured by Lurgi of Germany or DeNora of Italy.
• the water electrolysis system 4 receives a supply of water 104 which is electrolysed and separately generates hydrogen gas and oxygen gas to be output upon respective gas conduits 106,108 to gas receivers or compression systems 8,6.
• the pressurised hydrogen gas is transported by the pipeline 110 to the secondary methanol generation system 16.
• the hydrogen gas generated by the electrolysis unit 4 is in the proportion 2:1 to the oxygen gas.
• the oxygen gas too optionally can also be transported by a pipeline 112 to the methanol synthesis plant 20, where it can be provided as the supply of oxygen gas, or by way of replacing or supplementing the bulk oxygen supply to the coal gasifier 10.
• the electrolysis unit 4 must be located proximate the cell array 2 which, in turn, is located in an area of high solar flux. Taking the example of New South Wales, Australia, the cell array 2 typically would be located in the north-west of that State, west of the Great Dividing Range. Specific locations could be
• the methanol synthesis plant would be located near the central coast of the State, that being a coal-bearing region.
• the hydrogen gas-transporting pipeline 110 thus would be of a length of at least 400 km.
• An alternative site in Australia would be at the northern end of the Bowen Basin in North Central Queensland, where there are substantial coal-bearing deposits.
• the photo-voltaic cell array 2 again could be located at least 400 km away and inland in a region of high solar flux.
• Photo-voltaic systems are of course dependent upon sunlight, and thus cannot generate electricity (or hydrogen as in the present embodiment) continuously. Even so, by appropriate sizing of the photo- voltaic array system 2, the amount of hydrogen generated can be in excess of the requirement of the secondary methanol generation plant 16, and can be appropriately stored (at either end of the interconnecting pipeline 110 for use on demand, and particularly during night periods. This has the further advantages of allowing continuous production of methanol, and avoiding the need for stand-by plant or costly supplies of bulk hydrogen.
• the hydrogen transported on the pipeline 110 typically would be compressed to 80 atmospheres and the pipeline 110 would have an internal diameter of 750 mm, which, over a 400 km distance, would result in the hydrogen being drawn off from the other end of the pipeline 110 at pressures of the order of 30 atmospheres.
• the oxygen derived by electrolysis would be compressed to 60 atmospheres and the pipeline 110, having an internal diameter of 600 mm, could during 8 hour periods of rated solar radiation per day provide in excess of 80% of the total oxygen requirements of the coal gasifier 10.
• receiving the volumes of carbon dioxide and hydrogen also is noted above, approximately 1,949 tonnes per day of fuel grade methanol can be produced.
• This 1949 tonnes per day of methanol, following transportation, can be utilised in a 50% efficient peak shaving gas turbine/methanol dissociator generation unit(s) to provide an intermediate or peak load equivalent to 1,800 MW for 4.16 hours per nominal working weekday equivalent to 240 days per year.
• the excess carbon dioxide and electrolytically- derived hydrogen can be combined in a secondary process stream in the methanol synthesis unit 14 in place of the secondary production unit 16.
• the methanol generated by the two processes described thus is in a form for easy transportation to a customer for use as an energy source. Transportation can be by way of pipeline, ship, tanker or the like. In particular, the methanol could be shipped to other countries as a competitive fuel source. Where the end use for energy (power) occurs in winter, methanol produced in the southern hemisphere during the southern summer can be generated and transported to the northern hemisphere to meet that demand. The converse situation equally applies for the opposed seasons.
• the secondary methanol generation plant 16 need not be located at the site of the methanol synthesis system 20, but at some other location, possibly intermediate of the methanol synthesis system 20 and the electrolysis system 4.
• the secondary methanol generation plant 16 can be located adjacent a power generation plant, with the stored methanol being used to supplement load requirements during peak periods.
• the excess carbon dioxide derived from the gas treatment and purification system 12 is readily transported by pipeline in the same manner as the electrolytic hydrogen.

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Physics & Mathematics (AREA)
• Electromagnetism (AREA)
• Health & Medical Sciences (AREA)
• General Health & Medical Sciences (AREA)
• Toxicology (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

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Cited By (13)

Citations (3)

• 1994
  • 1994-05-16 AU AUPM5615A patent/AUPM561594A0/en not_active Abandoned
• 1995
  • 1995-05-16 ZA ZA953982A patent/ZA953982B/xx unknown
  • 1995-05-16 WO PCT/AU1995/000284 patent/WO1995031423A1/en active Search and Examination
  • 1995-05-16 IN IN545CA1995 patent/IN184582B/en unknown

Patent Citations (3)

Non-Patent Citations (4)

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