WO1995015928B1 - Coating system for glass adhesion retention - Google Patents
Coating system for glass adhesion retentionInfo
- Publication number
- WO1995015928B1 WO1995015928B1 PCT/NL1994/000308 NL9400308W WO9515928B1 WO 1995015928 B1 WO1995015928 B1 WO 1995015928B1 NL 9400308 W NL9400308 W NL 9400308W WO 9515928 B1 WO9515928 B1 WO 9515928B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- optical fiber
- coating composition
- composition according
- tetrasubstituted compound
- Prior art date
Links
- 239000011521 glass Substances 0.000 title claims abstract 10
- 239000011248 coating agent Substances 0.000 title claims abstract 5
- 238000000576 coating method Methods 0.000 title claims abstract 5
- 230000014759 maintenance of location Effects 0.000 title claims 3
- 239000008199 coating composition Substances 0.000 claims abstract 13
- 150000001875 compounds Chemical class 0.000 claims abstract 13
- 239000003365 glass fiber Substances 0.000 claims abstract 11
- 239000011159 matrix material Substances 0.000 claims abstract 10
- 239000000758 substrate Substances 0.000 claims abstract 9
- 239000002253 acid Substances 0.000 claims abstract 6
- 239000000178 monomer Substances 0.000 claims abstract 6
- 239000000203 mixture Substances 0.000 claims 21
- -1 chloro) Chemical class 0.000 claims 6
- 125000003545 alkoxy group Chemical group 0.000 claims 3
- 229920000642 polymer Polymers 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- 125000004414 alkyl thio group Chemical group 0.000 claims 1
- 125000005336 allyloxy group Chemical group 0.000 claims 1
- 125000001231 benzoyloxy group Chemical group C(C1=CC=CC=C1)(=O)O* 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 1
- 150000003016 phosphoric acids Chemical class 0.000 claims 1
- 230000003247 decreasing Effects 0.000 abstract 1
- 239000011229 interlayer Substances 0.000 abstract 1
Abstract
This invention provides an improved coating composition for glass substrates that comprises a tetrasubstituted compound. The introduction of a tetrasubstituted compound in a coating composition for a glass substrate, and in particular an optical fiber, acts to delay the rate of deterioration of the glass or optical fiber due to moisture, and improves adhesion between the glass substrate and the coating composition. The introduction of a tetrasubstituted compound into a polymeric coating composition also improves the interlayer adhesion when more than one coating is applied to a glass substrate. This invention further relates to an outer primary coating composition or matrix material that comprises an acid functional ethylenically unsaturated monomer. This invention also provides an improved coated glass substrate having a decreased rate of deterioration due to moisture, improved adhesion between the glass substrate and the coating composition and between the various coatings, wherein the coating composition comprises a tetrasubstituted compound.
Claims
1. A radiation curable coating composition for a glass
substrate, said composition comprising at least one component selected from the group consisting of radiation curable polymers, oligomers and monomers, and said composition further comprising a tetrasubstituted
compound having the formula:
wherein A is Si, Ti or Zr, characterized in that X1, X2, X3 and X4 are hydrolyzable groups that can be hydrolyzed from the tetrasubstituted compound in the presence of water.
2. The composition according to claim 1, characterized in that the hydrolyzable groups X1, X2, X3 and X4 are
independently halogen (e.g. chloro), formyloxy, acetoxy, propyonyl-oxy, valeryloxy, steaoryloxy, benzoyloxy, naphtoyloxy, toluyloxy, maleoyloxy, alkoxy, alkyl-thio, vinyloxy, allyloxy, vinyletheroxy, methacryloxy or acryloxy.
3. The composition according to claim 1, characterized in that the hydrolyzable groups X1, X2, X3 and X4 are
independently an alkoxy group or a group containing an ethylenic unsaturation.
4. The composition according to claim 1, characterized in that the tetrasubstituted compound is present in an amount in the range of 0.1% to 30% by weight of the entire composition.
5. The composition according to claim 1, characterized in that the tetrasubstituted compound is present in an amount in the range of 0.5% to 10% by weight of the entire composition.
6. The composition according to claim 3, characterized in that the alkoxy groups are methoxy or ethoxy groups.
7. A radiation curable coating composition for a glass
substrate, said composition comprising at least one component selected from the group consisting of radiation curable polymers, oligomers and monomers, characterized in that said composition has an adhesion retention of at least 80%.
8. A composition according to claim 7 , characterized in that the composition has an adhesion retention of at least 95%.
9. An outer primary coating composition or matrix
composition characterized in that it comprises an acid functional ethylenically unsaturated monomer.
10. An outer primary coating composition or matrix
composition according to claim 9, characterized in that the composition, when cured, has a T9 above 0°C and a modulus in the range of about 10.0 to about 3,000 MPa.
11. An outer primary coating composition or matrix
composition according to claim 9 or 10, characaterized in that the acid functional ethylenically unsaturated monomer is present in an amount of 0.1 to 10% by weight of the composition.
12. An outer primary coating composition or matrix
composition according to any of claims 9-11,
characterized in that the acid functional ethylenically unsaturated monomer is an ethylenically unsaturated phosphoric acid.
13. A glass substrate characterized in that it is coated with at least one composition in accordance with claim 1 and/or claim 9.
14. A coated optical fiber having more than one layer of
coating, characterized in that the optical fiber has a dynamic fatigue value nd of at least 24.
15. A coated optical fiber coated with more than one layer of coating, characterized in that at least the innermost layer comprises the tetrasubstituted compound according to claim 1, and wherein at least one of the other layers comprises an acid functional monomer.
16. A coated optical fiber coated with more than one layer of coating, characterized in that the innermost layer comprises the tetrasubstituted compound according to claim 1, and wherein at least one of the other layers comprises the tetrasubstituted compound according to claim 1.
17. A matrix material characterized in that it comprises a composition according to claim 1.
18. An optical fiber ribbon comprising at least one coated optical fiber embedded in a cured matrix material, characterized in that the matrix material comprises a tetrasubstituted compound having the formula
wherein A is Si, Ti or Zr, and where X1, X2, X3 and X4 are hydrolyzable groups that can be hydrolyzed from the tetrasubstituted compound in the presence of water.
19. An optical fiber ribbon comprising at least one coated optical fiber embedded in a cured matrix material, characterized in that the matrix material before curing comprises an acid functional ethylenically unsaturated monomer.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DK95903031T DK0733027T3 (en) | 1993-12-07 | 1994-12-06 | System with increased permanent adhesion for coating glass |
| AU12037/95A AU704774B2 (en) | 1993-12-07 | 1994-12-06 | Coating system for glass adhesion retention |
| DE69417572T DE69417572T2 (en) | 1993-12-07 | 1994-12-06 | COATING SYSTEMS OF GLASS WITH HIGH, PERMANENT LIABILITY AFTER MOISTURE |
| EP95903031A EP0733027B1 (en) | 1993-12-07 | 1994-12-06 | Coating systems for glass with improved wet adhesion retention |
| JP51611595A JP3686082B2 (en) | 1993-12-07 | 1994-12-06 | Paint system for glass adhesion retention |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16316493A | 1993-12-07 | 1993-12-07 | |
| US08/163,164 | 1993-12-07 | ||
| US08/298,136 | 1994-08-30 | ||
| US08/298,136 US5664041A (en) | 1993-12-07 | 1994-08-30 | Coating system for glass adhesion retention |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| WO1995015928A2 WO1995015928A2 (en) | 1995-06-15 |
| WO1995015928A3 WO1995015928A3 (en) | 1995-07-27 |
| WO1995015928B1 true WO1995015928B1 (en) | 1995-08-17 |
Family
ID=26859402
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/NL1994/000308 WO1995015928A2 (en) | 1993-12-07 | 1994-12-06 | Coating system for glass adhesion retention |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US5664041A (en) |
| EP (2) | EP0733027B1 (en) |
| JP (2) | JP3686082B2 (en) |
| AU (1) | AU704774B2 (en) |
| CA (1) | CA2178338A1 (en) |
| DE (2) | DE69417572T2 (en) |
| DK (2) | DK0733027T3 (en) |
| WO (1) | WO1995015928A2 (en) |
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-
1994
- 1994-08-30 US US08/298,136 patent/US5664041A/en not_active Expired - Lifetime
- 1994-12-06 JP JP51611595A patent/JP3686082B2/en not_active Expired - Fee Related
- 1994-12-06 EP EP95903031A patent/EP0733027B1/en not_active Expired - Lifetime
- 1994-12-06 AU AU12037/95A patent/AU704774B2/en not_active Ceased
- 1994-12-06 CA CA002178338A patent/CA2178338A1/en not_active Abandoned
- 1994-12-06 EP EP97201989A patent/EP0801041B1/en not_active Expired - Lifetime
- 1994-12-06 DK DK95903031T patent/DK0733027T3/en active
- 1994-12-06 DE DE69417572T patent/DE69417572T2/en not_active Expired - Fee Related
- 1994-12-06 DE DE69431195T patent/DE69431195T2/en not_active Expired - Fee Related
- 1994-12-06 DK DK97201989T patent/DK0801041T3/en active
- 1994-12-06 WO PCT/NL1994/000308 patent/WO1995015928A2/en active Search and Examination
-
1998
- 1998-08-21 US US09/137,925 patent/US6306924B2/en not_active Expired - Fee Related
-
2004
- 2004-10-01 JP JP2004289464A patent/JP4279764B2/en not_active Expired - Fee Related
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