WO1995012704A1 - Procede de dosage d'un produit detersif - Google Patents

Procede de dosage d'un produit detersif Download PDF

Info

Publication number
WO1995012704A1
WO1995012704A1 PCT/EP1994/003493 EP9403493W WO9512704A1 WO 1995012704 A1 WO1995012704 A1 WO 1995012704A1 EP 9403493 W EP9403493 W EP 9403493W WO 9512704 A1 WO9512704 A1 WO 9512704A1
Authority
WO
WIPO (PCT)
Prior art keywords
detergent
measured
washing solution
conductivity
detergent product
Prior art date
Application number
PCT/EP1994/003493
Other languages
English (en)
Inventor
Klaas Der Kinderen
Original Assignee
Unilever N.V.
Unilever Plc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever N.V., Unilever Plc filed Critical Unilever N.V.
Priority to AU80599/94A priority Critical patent/AU679281B2/en
Priority to BR9407967A priority patent/BR9407967A/pt
Priority to DE69413246T priority patent/DE69413246T2/de
Priority to EP94931546A priority patent/EP0726978B1/fr
Publication of WO1995012704A1 publication Critical patent/WO1995012704A1/fr
Priority to FI961837A priority patent/FI108866B/fi

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F34/00—Details of control systems for washing machines, washer-dryers or laundry dryers
    • D06F34/14—Arrangements for detecting or measuring specific parameters
    • D06F34/22—Condition of the washing liquid, e.g. turbidity
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F2103/00—Parameters monitored or detected for the control of domestic laundry washing machines, washer-dryers or laundry dryers
    • D06F2103/20—Washing liquid condition, e.g. turbidity
    • D06F2103/22—Content of detergent or additives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F2105/00—Systems or parameters controlled or affected by the control systems of washing machines, washer-dryers or laundry dryers
    • D06F2105/42—Detergent or additive supply
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F2105/00—Systems or parameters controlled or affected by the control systems of washing machines, washer-dryers or laundry dryers
    • D06F2105/58—Indications or alarms to the control system or to the user
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F2105/00—Systems or parameters controlled or affected by the control systems of washing machines, washer-dryers or laundry dryers
    • D06F2105/58—Indications or alarms to the control system or to the user
    • D06F2105/60—Audible signals

Definitions

  • the present invention relates to a method of dosing deter- gent product into a washing solution present in an in ⁇ dustrial washing machine, in particular an institutional mechanical ware washing machine.
  • the detergent concentration of the washing solution is usually observed by measuring the electroconductivity of the washing solution between at least two electric electrodes immersed in the washing solution.
  • electroconductivity can be simply defined as the ability of a solution to pass an electrical current.
  • contact to the solution is made by two or more electrodes, and a small alternating current is passed between them. This current is related to the solution conductivity.
  • the conductivity measurement is generally carried out by means of the above-described electrodes and a conductivity amplifier which activates a detergent dosing pump whenever the electroconductivity of the washing solution (and, as a consequence, the detergent concentration) drops below a predetermined threshold value, until the theshold level has been regained. Since the conductivity amplifier may operate up to a high accuracy, it can be ensured under all cir- cumstances that the detergent concentration and washing effect are sufficient, i.e. that the detergent con ⁇ centration remains constantly above a predeterminede level. However, it has been observed that the detergent con ⁇ centration in prior art washing systems usually exceeds considerably the threshold level yielding complete clean ⁇ ness. This over-dosage of detergent product may amount to tens of percents, thus causing considerable extra operating costs.
  • the electrodes present in the measuring cell are subject to scumming. That is, the electrodes may be coated by a film when they are used to monitor a hard water solution, and, as a result, an accep ⁇ table conductivity level may be indicated when in fact the conductivity, and therefore the detergent concentration of the washing solution, is unacceptably high.
  • food soil in the washing solution is likely to cause con ⁇ tamination of the electrodes which may have a detrimental effect on the accuracy of the conductivity measurement.
  • the electrodes have been found to be sensitive to scale build-up resulting in erroneous measurements and, as a consequence, increasing product consumption and operating costs.
  • inductive measuring systems comprising electrodeless conductivity measuring sensors.
  • the type of sensor applied in these inductive systems usually comprises two toroidally wound coils, and when these sensors are immersed in the washing solution to be monitored, said solution provides an electrical coupling between the coils.
  • US-A-4,733,798 discloses an apparatus for controlling the concentration of a washing solution, wherein the conduc ⁇ tivity of said solution is measured using an inductive measuring system comprising an electrodeless sensor.
  • the present invention provides a method of dosing detergent product into a washing solution present in an industrial washing machine, comprising measuring, from a washing solution containing water and detergent material, a proper ⁇ ty which is proportional to the detergent concentration of said washing solution, and adding detergent product to the washing solution if the value of the measured property corresponds to a detergent concentration below a preset threshold value, whereby the measured property is the electroconductivity of the washing solution, said property being measured using a measuring cell including 1 or more electrodes, characterised by the steps of:
  • the method of the invention As a result of the method of the invention, a constant detergent concentration throughout the operating life of the electrodes and at a minimised detergent consumption could be attained. Further advantages of the method of the invention are guaranteed constant cleaning performance using a relatively cheap system including measurement cells containing one or more electrodes, and improved reliability resulting in a reduced number of service calls. Further ⁇ more, the applied system is usually fully automatised. In order to reduce hardware and installation costs, a measuring cell containing only one electrode is preferably applied. In that case, the other "counter" electrode is constituted by the internal wall of the container holding the washing solution to be monitored.
  • the mixing time before the conduc ⁇ tivity is measured is as short as possible.
  • this mixing time is generally less than 2 minutes, preferably less than 1 minute.
  • this mixing time is generally less than 1 minute, preferably less than 30 seconds, a mixing time of from 5 to 15 seconds being pre-ferred.
  • the steps according to the present invention are preferably repeated every time the washing machine is filled with clean water.
  • the correct amount of detergent product when filling the washing machine with clean water it is desirable to calculate this amount by determining the internal water volume of the washing machine to be applied.
  • the method of the invention turned out to be particularly suitable for controlling the detergent concentration of washing solutions present in institutional ware washing machines.
  • an alarm function can be included, indicating that the electrodes applied have been contaminated to such extent and that, consequently, their sensitivity has deteriorated so much, that suitable operation of these electrodes is not possible anymore.
  • This alarm function is usually adjustable such that it gives a visual or audible signal when the sensitivity of the electrodes has reduced to a level in the range of 50-70 % of the sensitivity value at the start of their operating life.
  • the specific adjustment of the alarm function depends on the accuracy of the concentration control required: when a higher accuracy is required the alarm will be adjusted to a higher percentage of the initial sensitivity. In other words: in that case, less fouling of the electrodes will be tolerated.
  • figure 1 schematically il ⁇ lustrates a system for carrying out the method of the invention.
  • This figure shows a block diagram of this system, including a conductivity amplifier/controller (1) which is connected to measuring electrodes (3) and (4) , one of which may be the internal wall of a container holding a washing solution to be monitored by said system.. These electrodes are immersed in the washing solution at a suitable location. This location is not critical; however, a measuring point positioned close to the detergent feeding point detects the effect of fed detergent product more rapidly.
  • the conduc ⁇ tivity amplifier/controller (1) measures the electroconduc- tivity of the washing solution between the measuring electrodes (3) and (4) and generates at its output an ac ⁇ tivating signal (AKT) when the measured conductivity drops below a preset threshold value.
  • AKT ac ⁇ tivating signal
  • This preset value is measured during the beginning of the wash cycle, and subse- quently stored in the memory (3) .
  • the output of the conductivity amplifier/controller (1) is connected to a control input of a control unit (2) for a detergent dosing pump. This control unit (2) switches on the dosing pump only if the signal AKT is generated.
  • Bayhibit AM Phosphono-1,2,4-butane-tricarboxylic acid
  • Norasol LMW 45 N Sodium salt of polyacrylic acid, ex Norsohaas.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
  • Washing And Drying Of Tableware (AREA)
  • Detergent Compositions (AREA)
  • Control Of Washing Machine And Dryer (AREA)

Abstract

L'invention se rapporte à un procédé permettant de doser un produit détersif dans une solution de lavage contenue dans un lave-ling industriel. Ce procédé consiste à mesurer, à partir d'une solution de lavage contenant de l'eau et une substance détersive, une caractéristique proportionnelle à la concentration de détergent dans ladite solution de lavage, et à ajouter du produit detersif à ladite solution si la valeur de la caractéristique mesurée correspond à une concentration de détergent inférieure à une valeur seuil prédéfinie. La caractéristique mesurée est l'électroconductivité de la solution de lavage, et elle est mesurée au moyen d'une cellule de mesure comprenant une ou plusieurs électrodes (3, 4). Ce procédé se caractérise en ce qu'il consiste à: (a) doser, au cours du remplissage du lave-linge avec de l'eau propre, une quantité suffisante du produit détersif pour atteindre une valeur seuil prédéfinie, après quoi ledit produit dosé est mélangé à l'eau; (b) mesurer la conductivité du liquide de lavage ainsi obtenu après avoir poursuivi le mélange pendant moins de 2 minutes; et (c) mémoriser la conductivité mesurée, ainsi que la valeur de concentration de détergent qui y correspond, sous forme de valeurs seuil prédéfinies, dans la mémoire (3) d'un contrôleur (1) qui est fixé à la cellule de mesure et qui régule le dosage du produit détersif en fonction de la conductivité mesurée.
PCT/EP1994/003493 1993-11-02 1994-10-24 Procede de dosage d'un produit detersif WO1995012704A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
AU80599/94A AU679281B2 (en) 1993-11-02 1994-10-24 Method of dosing detergent product
BR9407967A BR9407967A (pt) 1993-11-02 1994-10-24 Processo de dosar produto detergente
DE69413246T DE69413246T2 (de) 1993-11-02 1994-10-24 Verfahren zum dosieren eines waschmittelproduktes
EP94931546A EP0726978B1 (fr) 1993-11-02 1994-10-24 Procede de dosage d'un produit detersif
FI961837A FI108866B (fi) 1993-11-02 1996-04-30 Menetelmä pesuainetuotteen annostelemiseksi

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP93203065.3 1993-11-02
EP93203065 1993-11-02

Publications (1)

Publication Number Publication Date
WO1995012704A1 true WO1995012704A1 (fr) 1995-05-11

Family

ID=8214155

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1994/003493 WO1995012704A1 (fr) 1993-11-02 1994-10-24 Procede de dosage d'un produit detersif

Country Status (9)

Country Link
EP (1) EP0726978B1 (fr)
AU (1) AU679281B2 (fr)
BR (1) BR9407967A (fr)
CA (1) CA2172723C (fr)
DE (1) DE69413246T2 (fr)
ES (1) ES2123161T3 (fr)
FI (1) FI108866B (fr)
WO (1) WO1995012704A1 (fr)
ZA (1) ZA948468B (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001012892A1 (fr) * 1999-08-11 2001-02-22 BSH Bosch und Siemens Hausgeräte GmbH Procede pour commander, reguler un processus de nettoyage realise a l'aide d'un milieu de nettoyage et egalement pour etablir la documentation relative a ce processus
WO2004106616A1 (fr) * 2003-05-28 2004-12-09 Lg Electronics, Inc. Procede de commande d'une machine a laver
US6958693B2 (en) 2002-05-24 2005-10-25 Procter & Gamble Company Sensor device and methods for using same
EP1639176A1 (fr) * 2003-05-28 2006-03-29 LG Electronics, Inc. Machine a laver et procede de commande correspondant
WO2007117748A1 (fr) * 2006-04-07 2007-10-18 Masco Corporation Detecteur de conductivite permettant de determiner le niveau de granules dans une capsule remplie d'eau
WO2013087100A1 (fr) * 2011-12-14 2013-06-20 Ecolab Usa Inc. Procédure optimisée de dosage destinée à un lave-linge

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7571734B2 (en) 2005-01-20 2009-08-11 General Electric Company Fluid dispensing system for a washing device
US8056747B2 (en) 2007-10-12 2011-11-15 General Electric Company Removable tank for laundry bulk dispenser system
US8056374B2 (en) 2007-10-12 2011-11-15 General Electric Company Multiple compartments wash additives auto-dispenser in washer or dryer pedestal
US7802335B2 (en) 2007-10-12 2010-09-28 General Electric Company Bulk dispense user adjustable controls
US8388695B2 (en) 2008-07-01 2013-03-05 Whirlpool Corporation Apparatus and method for controlling laundering cycle by sensing wash aid concentration
US8266748B2 (en) 2008-07-01 2012-09-18 Whirlpool Corporation Apparatus and method for controlling bulk dispensing of wash aid by sensing wash aid concentration

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3645669A (en) * 1969-02-28 1972-02-29 Gerhard Rausch Method and arrangement for testing the liquid in washing machines
FR2412638A1 (fr) * 1977-12-20 1979-07-20 Asko Upo Oy Procede et dispositif pour commander le rincage dans une machine a laver
US4733798A (en) * 1986-02-05 1988-03-29 Ecolab Inc. Method and apparatus for controlling the concentration of a chemical solution
GB2217050A (en) * 1988-04-07 1989-10-18 Vesa Hakulinen Metering detergent
EP0506137A1 (fr) * 1991-03-29 1992-09-30 Hitachi, Ltd. Machine à laver

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3645669A (en) * 1969-02-28 1972-02-29 Gerhard Rausch Method and arrangement for testing the liquid in washing machines
FR2412638A1 (fr) * 1977-12-20 1979-07-20 Asko Upo Oy Procede et dispositif pour commander le rincage dans une machine a laver
US4733798A (en) * 1986-02-05 1988-03-29 Ecolab Inc. Method and apparatus for controlling the concentration of a chemical solution
GB2217050A (en) * 1988-04-07 1989-10-18 Vesa Hakulinen Metering detergent
EP0506137A1 (fr) * 1991-03-29 1992-09-30 Hitachi, Ltd. Machine à laver

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001012892A1 (fr) * 1999-08-11 2001-02-22 BSH Bosch und Siemens Hausgeräte GmbH Procede pour commander, reguler un processus de nettoyage realise a l'aide d'un milieu de nettoyage et egalement pour etablir la documentation relative a ce processus
US6881275B2 (en) 1999-08-11 2005-04-19 Bsh Bosch Und Siemens Hausgerate Gmbh Method for the open-loop and closed-loop control and documentation of a cleaning operation with a cleaning medium
US6958693B2 (en) 2002-05-24 2005-10-25 Procter & Gamble Company Sensor device and methods for using same
EP1639176A4 (fr) * 2003-05-28 2009-02-18 Lg Electronics Inc Machine a laver et procede de commande correspondant
EP1639176A1 (fr) * 2003-05-28 2006-03-29 LG Electronics, Inc. Machine a laver et procede de commande correspondant
WO2004106616A1 (fr) * 2003-05-28 2004-12-09 Lg Electronics, Inc. Procede de commande d'une machine a laver
US7971301B2 (en) 2003-05-28 2011-07-05 Lg Electronics Inc. Washing machine and the control method of the same
US8015645B2 (en) 2003-05-28 2011-09-13 Lg Electronics Inc. Washing machine and a method of controlling the same based on measured hardness of water
WO2007117748A1 (fr) * 2006-04-07 2007-10-18 Masco Corporation Detecteur de conductivite permettant de determiner le niveau de granules dans une capsule remplie d'eau
US7581437B2 (en) 2006-04-07 2009-09-01 Masco Corporation Level sensor for granules in water
WO2013087100A1 (fr) * 2011-12-14 2013-06-20 Ecolab Usa Inc. Procédure optimisée de dosage destinée à un lave-linge
US10004380B2 (en) 2011-12-14 2018-06-26 Ecolab Usa Inc. Optimized dosing procedure for a washing machine
EP3396052A1 (fr) * 2011-12-14 2018-10-31 Ecolab USA Inc. Procédure de dosage optimisé pour une machine à laver
US10182700B2 (en) 2011-12-14 2019-01-22 Ecolab Usa Inc. Optimized dosing procedure for a washing machine

Also Published As

Publication number Publication date
ES2123161T3 (es) 1999-01-01
AU8059994A (en) 1995-05-23
CA2172723C (fr) 1997-11-25
DE69413246T2 (de) 1999-02-18
FI961837A0 (fi) 1996-04-30
FI961837A (fi) 1996-04-30
BR9407967A (pt) 1996-12-03
CA2172723A1 (fr) 1995-05-11
FI108866B (fi) 2002-04-15
DE69413246D1 (de) 1998-10-15
EP0726978B1 (fr) 1998-09-09
EP0726978A1 (fr) 1996-08-21
AU679281B2 (en) 1997-06-26
ZA948468B (en) 1996-04-29

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