WO1995008829A1 - Composition de revetement conductrice coloree - Google Patents

Composition de revetement conductrice coloree Download PDF

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Publication number
WO1995008829A1
WO1995008829A1 PCT/US1994/010293 US9410293W WO9508829A1 WO 1995008829 A1 WO1995008829 A1 WO 1995008829A1 US 9410293 W US9410293 W US 9410293W WO 9508829 A1 WO9508829 A1 WO 9508829A1
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WIPO (PCT)
Prior art keywords
weight
percent
composition
recited
conductive particles
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PCT/US1994/010293
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English (en)
Inventor
Frank R. Russo
Adrian I. Rose
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Engelhard Corporation
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Publication of WO1995008829A1 publication Critical patent/WO1995008829A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24—Electrically-conducting paints
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/20—Conductive material dispersed in non-conductive organic material
    • H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/20—Conductive material dispersed in non-conductive organic material
    • H01B1/24—Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon or silicon

Definitions

  • the present invention relates to an electrically conductive coating composition comprising a colorant. More particularly, the invention relates to a conductive composition comprising a colorant which can be a pigment or dye.
  • US Patent No. 5,006,278 discloses an electrically conductive substituted and unsubstituted polyaniline composition having different colors.
  • the composition can also include various conductive polymers, graphite and metal conductors.
  • a polar organic solvent is disclosed for use to form a coating for conductive articles.
  • Other components can include conventional polymers, fillers and the like.
  • the polymer can be used as a coating or in the form of fibers and films of any desired thickness.
  • Conductive coating materials comprising vinyl resin, carbon black, conductive metal containing powder, epoxy compounds and/or organic stabilizers that can be colored into different colors are disclosed or as is for example to US Patent Nos. 5,006,278; 5,066,422 and 4,079,156.
  • US Patent No. 4,079,156 discloses conductive metal pigments which are useful in electrical devices.
  • US Patent No. 4,529,539 discloses electrically conductive high molecular weight compositions obtained by mixing high molecular weight compounds such as thermoplastic resin, synthetic resin, a rubber or the like with a water soluble electrolyte and a water soluble high molecular weight compound.
  • the electrolyte is a soluble salt which can include sodium, potassium chloride or sulfite, carbonate, phosphate, thiocyanate and the like.
  • the conductive high molecular weight composition can be transparent and colored to any desirable color.
  • the compounding ratio of the water soluble electrolyte and the water soluble high molecular weight compound respectively per hundred parts of the base high molecular weight compound is from 1 to 10 parts by weight.
  • the composition does not contain either carbon black or metallic powder. It can be colored to any desirable color by adding a colorant useful for ordinary thermoplastic resins or rubbers.
  • US Patent No. 4,052,256 and Reissue Patent No. 33,285 disclose articles having a transparent conductive polymeric coating body resistance to close a circuit. Such articles include watches and lamps. Conductive polymeric compositions are also disclosed in US Patent Nos. 4,264,477 and 4,518,833.
  • compositions are primarily compositions which are made of conductive polymers which can be colored.
  • the conductive particles are colored, or maintain the color inherent in the color of the particles such as the silvery color of silver or aluminum or the natural colors of copper, bronze, gold or the like.
  • Conductive coatings have been colored black using carbon black.
  • the present invention is directed to a colored conductive composition
  • a colored conductive composition comprising a colorant, conductive particles, a resin which can function as a binder, and optionally, a liquid which can be an organic liquid or water.
  • a colorant can be a dye or a pigment and provide a color in the range from violet to red. This includes all of the colors that are in the visual light wave length band including white.
  • a useful composition comprises from about 2 to 20% and preferably 5 to about 15% by weight of at least one binder.
  • the binder is preferably a resin which can be a thermoplastic or thermosetting resin.
  • the preferred composition useful for a coating further comprises from 15 to 50, preferably 25 to 45 and more preferably from 35 to 45% by weight of a liquid vehicle.
  • the liquid vehicle is selected from an organic solvent or water.
  • the composition can be a non-self-supported coating or a self supporting film, fiber or molding or the like.
  • the composition without the liquid comprises from about 5 to about 20 percent by weight of at least one resin; from about 3 to about 20 percent by weight of at least one colorant; and from about 40 to about 70 percent by weight of at least one conductive particle selected from metals, metal compounds and graphite.
  • the present invention includes articles of manufacture comprising coating compositions as recited.
  • the liquid can be removed by any suitable means leaving a conductive coating on the article.
  • Articles include textiles, film sheets, fibers and particles which support the coating.
  • the present invention further includes a method comprising a step of conducting an electric current through a layer of coating composition supported on a non ⁇ conducting substrate wherein the coating composition comprises the composition as recited wherein the liquid has been removed.
  • Figure 1 shows an article which includes the conductive coating composition of the present invention.
  • Figure 2 shows a typical silk screen testing sample of conductive composition of the type made using Example 28-35
  • a preferred coating composition of the present invention comprises from about 5 to about 20, preferably 5 to 15 and more preferably 9 to 12% by weight of at least one resin; from about 3 to about 15% by weight of at least one colorant; from about 40 to about 70 and preferably 50 to 55% by weight of at least one conductive particle comprising metals or metal compounds in graphite, and from 25 to 45 and preferably 35 to 45 of at least one liquid vehicle.
  • compositions not including the liquid, but including a coating, film or self-support articles comprises from about 5 to about 20, preferably 9 to 12% by weight of at least one resin; from about 3 to about 20 and preferably 5 to 10% by weight of at least one colorant; and from about 40 to about 70, and preferably 50 to about 55% by weight of at least one conductive particle comprising metals or metal compounds and graphite.
  • the conductive particles can include metals including pure metals and metal alloys.
  • Useful metals include silver, iron, copper, brass, gold, platinum, silver alloys, gold alloys, bronze, aluminum, nickel and copper, as well as metal coated non-conducting particle such as metal coated glass.
  • Useful conductive metals and metal pigments are disclosed in US Patent No. 4,079,156 hereby incorporated by reference.
  • Conductive metal pigments include the alloy of a non-noble conductive metal with at least one oxidizable metal selected from the group consisting of carbon, boron, silicon, aluminum, carbon-silica, and boron-silicon and nickel carbonyl.
  • the metal compounds can additionally include organo etalics such as metallocenes such iron carbonyl, also useful are graphite and carbon black particles.
  • the particles should have a morphology that permits electrical conductivity.
  • Useful particles can be spherical, flat, irregularly shaped or coated with the composition as recited above.
  • pure metals are flake or flat- like in shape.
  • the preferred particles are flakes which have an aspect ratio of less than 20 and preferably 10 to 20, with a thickness of less than 1 micrometer ( ⁇ ) .
  • Other useful particles have an effective spherical diameter range of from 0.1 ⁇ to 20 ⁇ and preferably 0.5 to 10 ⁇ .
  • the effective diameter is the diameter of a sphere having the same volume as the particle.
  • the metals and conductive materials are typically characterized as having an average effective diameter of 1 to 2 ⁇ .
  • Preferred particles are in flake form with silver flakes being most preferred.
  • Silver flakes can be a leafing or nonleafing type.
  • leafing-type silver flakes are believed to align with the coating.
  • a surface or plane of the coating is generally parallel to the major plane of the silver flakes.
  • the major plane through nonleafing silver plates are believed to be randomly oriented in the coating.
  • Useful leafing type silver flakes have particle sizes ranging from 1-15 ⁇ m determined by scanning electron micrographs. Apparent density ranges from 16.0-32.0 g/in 2 measuring using a Scott Volumeter, per ASTM B329-81. Tap density ranges from 2.0 to 3.0 measured using a Tap-Pak Volumeter, per ASTM B527-81.
  • Weight loss (%) at 110°C is about 0.10 and at 538°C about 0.85 to 0.90 maximum.
  • Useful nonleafing silver flakes have particle sizes ranging from 0.5-10 ⁇ m determined by scanning electron micrographs. Apparent density ranges from 20.0-40 g/in 3 measured using a Scott Volumeter, per ASTM B329-81. Tap density ranges from 2.5 to 4.5 measured using a Tap-Pak Volumeter, per ASTM B527-81. Weight loss (%) at 100°C is about 0.10 and at 538°C about 0.65 to 0.90 maximum.
  • Nonleafing impurities having a maximum of from 0.002 to 0.004% (Na + K) and 0.001 to 0.002 (CD .
  • certain metals such as silver
  • when formed into flat or flake-like particles also include a sufficient amount of lubricant such as an organic soap which can be oleic, stearic, lauric or acid or salt thereof to prevent agglomeration of the flakes during processing.
  • lubricant such as an organic soap which can be oleic, stearic, lauric or acid or salt thereof to prevent agglomeration of the flakes during processing.
  • organic soap typically, there is from 0.5 to 2% by weight of the organic soap in the flake-like materials.
  • Particular color quality and intensity and compositions can comprise a mixture of flake leafing and nonleafing metal particles in the following weight percent ranges (based on the leafing and nonleafing particles) of leafing range to nonleafing range particles: 1-99 to 99-1, 10-90 to 90-10, 25-75 to 75-25 and 40-60 to 60-40 weight percent.
  • a colorant is a substance that imparts color to another material. Colorants are either dyes or pigments. A colorant may either be naturally present, admixed with a material such as dried pigments and paints or applied in solution such as organic dyes. Typically, a distinction between dyes and pigments is difficult to draw. However, most pigments are considered to be insoluble dry powders.
  • Such powders are insoluble in both water and organic solvents.
  • the coloring effect of a pigment is considered to be the result of their dispersion in a solid or liquid medium.
  • Dyes on the other hand are soluble, synthetic organic products which are chemically bound to and actually become part of the material to which they are applied. Instruments for measuring, comparing and matching the hue, tone and depth of color are called colorometers.
  • Pigments are useful as colorants in a composition of the present invention.
  • useful pigments for the present invention include inorganic pigments such as metal oxides, including iron, titanium, zinc, cobalt and chromium oxides. Also included are metal powders suspension. Earth color pigments are provided as siennas, ocras, and umbras.
  • Organic pigments include animal-based compounds, including rhodopsin and melanin.
  • Organic vegetable derived pigments include chlorophyll, xanthophyll, litmus, flavon, and carotene.
  • Mineral pigments and finally synthetic pigments such as phthalocyanin, lithols, toluidine, para red toners, lakes and the like. Useful pigments are set forth in the Condensed Chemical Dictionary, Eighth Edition, Van Nostrand Rheinhold, p. 695 hereby incorporated by reference.
  • dyes which can be used with the present invention. Included in these dyes are metal dyes, natural dyes, synthetic dyes, and dispersed dyes.
  • Metal dyes are organic dyes suitable for use with a metal such as aluminum or steel. Such dyes include alizarin cyanin RR, alizarin green S, nigrosine 2Y and naphthalene blue RS.
  • Natural dyes are obtained from natural animal or tree sources. Among the best known are madder, cochineal, logwood and indigo.
  • Synthetic organic dyes are often derived from coal, tar and petroleum based intermediates. Dyes may either by acidic or basic and their effectiveness on the objects to be dyed may depend on this factor. Some dyes are soluble in water while others are soluble in organics. Synthetic dyes include acetate dyes, anthraquinone dye, acid dye, azo dye, alizarine analyn, eosin, stilbene dye and sulfide dye. Dispersed dyes fall into three defined chemical classes including nitrorylamine, azo and anthraquinone and almost all contain amino or substitute amino groups but not solubilizing sulfonic groups.
  • Useful colorants include various classes of dispersed dyes such as nitro dyes, amino ketone dyes, ketone-imine dyes, methine dyes, nitro diphenyl amine dyes, quinoline dyes, amino naphthoquinone dyes, coumarin dyes and anthraquinone dyes as well as azo dyes such as monoazo dye, disazo dyes.
  • Other dyes include indigoid dyes, anthraquinoid dyes for example indianthrene and also sulfur dyes.
  • Other useful dyes are listed in Webster's Third New International Dictionary of the English Language. Unabridged. pp. 706-710 (1986) .
  • Pigments are defined at Webster's, supra, page 1714, also incorporated herein by reference.
  • the composition including the colorant and conductive compound are held together by a binder composition, preferably comprising a polymeric binder which can be a thermoplastic or thermosetting polymer.
  • the resin is preferably chosen so that if the composition is to be used to cost a substrate, the resin adheres to the substrate.
  • a polyester binder can be used with a polyester (Mylar ) substrate.
  • thermoplastic polymers include but are not limited to polyethylene, polypropylene, polystyrene, polybutadiene, polyvinyl acetate, methacrylate resin, AS resin, ABS resin, AAS resin, ACS resin, AES resin, polyacetal, polyamide, polyphenylene oxide, polycarbonate, linear polyester, polyurethane, polyvinyl alcohol, ethylene vinyl alcohol copolymer, chlorinated polyethylene, chlorosulfonated polyethylene, polyisoprenes, chlorinated rubber, rubber hydrochloride, styrene butadiene rubber, polyacrylonitrile, polymethylmethacrylate, polymethylacrylate, polyacrylic acid, polymethycrylic acid, ethylene acrylic acid copolymer, ethylene methycrylic acid copolymer and salts thereof, methylcyanoacrylate monomer, polyacrylamide, copolymers of styrene and methylmethacrylate, rigid polyvinyl chloride, copolymers of poly
  • the thermoplastic polymer include both homopolymers or copolymers.
  • Other useful polymers include fluorinated polymers such as polyvinyl fluoride, polyvinylidine fluoride, polychlorotrifluoroethylene copolymer, polytetrafluoro- ethylene, polyvinylidine fluoride and fluorinated ethylene propylene copolymers.
  • Useful linear saturated polyesters include polyethyleneterephthalate and polybutyleneterephthalate.
  • Useful ionic copolymers include the salts of copolymers of ethylene and an alpha beta ethylinically unsaturated carboxylic acid including copolymers of ethylene and salts of acrylic or methacrylic acid.
  • the salts can include the Groups I and II metal salts with sodium, potassium, zinc and magnesium being preferred.
  • Polyamides include nylon 6, nylon 66, nylon 610, nylon 11, nylon 12 and polyamide copolymers.
  • Useful thermoplastic polymers for the present invention are disclosed in Bilmeyer, Jr. , Textbook of Polymer Science. Second Edition, Wiley into Science, pp. 379 to 462, p. 171 are hereby incorporated herein by reference.
  • Useful thermosetting resins include but are not limited to epoxy resins such as disclosed in Modern Plastics Encyclopedia. 1979-1980, Vol. 56, No. 10A at page 16-26 hereby incorporated by reference. Useful thermosetting resins also include thermosetting polyamides and thermosetting resins set forth in Bilmeyer, supra, page 468-487 hereby incorporated by reference.
  • phenolic resins including phenylphemaldehyde resins, amino resins, terpene resins, unsaturated polyester resins, including the product of dibasic acids such as phthalic anhydride, adipic acid, azelaic acid or isophthalic acid and a dihydric alcohol such as ethylene or propylene glycol, 1,3- and 2,3- butylene, diethylene and dipropylene glycols.
  • styrenic polymers including styrene, vinyl toluene, methylmethacrylate, diallyl phthalate and triallyl cyanurate.
  • Epoxy resins with a commonly used epoxy resin made by condensing an epoxy such as epichlorohydrin and an hydroxyl group containing compound such as bisphenol A,
  • Useful liquids include water wherein the composition is an aqueous solution dispersion or latex and organic liquids.
  • Useful organic liquids include a polar and nonpolar organic solvents.
  • Useful organic liquids depend on the resin and include alkanes, alkenes, aromatics, alcohols, ethers, acetones, ketones, halogenated hydrocarbons, acids, esters, monomeric epoxies, alcohol/ester and aromatics including toluene, benzene, xylene and organic salts. Where the vehicle is a solvent, useful solvents are disclosed in Doolittle, The Technology of Solvents and Plasticizers. J. Wiley & Sons, 1954.
  • alkyl alkanesulfonates such as methyl methanesulfonate, ethyl methanesulfonate, butyl methanesulfonate, propyl ethanesulfonate; nitriles such as acetonitrile, propionitrile, butyronitrile, benzonitrile and the like; aromatic solvents such as nitrobenzene and the like; carbonates such as propylene carbonate, dimethyl carbonate, ethylene carbonate and the like; nitroalkanes, such as nitromethane, nitroethane, nitropropane, and the like; amides such as dimethyl forma idedimethyl thioformamide, N,N-dimethylacetamide, N-methylpyrrolidinone and the like; organophosphorus compounds such as hexamethyl phosphoroamide, diethylphosphate, triethylphosphites, trimethyl
  • compositions of the present invention useful for coating is in the form of a liquid suspension of the conductive particles.
  • the suspension is in a solution, suspension or latex of resin with colorant. Where the colorant is in solution, it is considered a dye and where the colorant is in suspension or slurried, it is considered to be a pigment.
  • the composition can contain other additives such as suspending agents, light and/or heat stabilizers, flow control agents, fibrous and particulate fillers, reinforcing agents, polymeric nucleation agents, platicizers and impact modifiers and the like so long as the conductivity of the coating composition is maintained in a useful range.
  • additives such as suspending agents, light and/or heat stabilizers, flow control agents, fibrous and particulate fillers, reinforcing agents, polymeric nucleation agents, platicizers and impact modifiers and the like so long as the conductivity of the coating composition is maintained in a useful range.
  • the conductivity of the composition of the present invention is determined based on the coating composition after removal of the liquid vehicle.
  • the electric properties of the composition are characterized by sheet resistivity as follows: 0.1 to 10,000 ohms/square, and preferably 0.2 to 1000 ohms/square. Resistivity is defined in Del Toro, Principles of Electrical Engineering, pp. 14,77 Prentice-Hill Inc. (1965). In the case where a conductor has uniform cross-sectional areas where I is current flow (amps) , Vis
  • the p can be normalized by dividing by the sheet thickness.
  • the composition can be a non- self-supporting composition useful as a coating onto a substrate.
  • the composition can be formed into a self supporting structure and formed into films, fibers and formed articles (moldings extrusions) .
  • composition of the present invention can be coated by suitable means.
  • suitable means include the use of brushes, rollers and printing.
  • a preferred method of coating is by silk screen printing.
  • Coatings can be from at least about 5 micrometers thick with useful coatings being from 5 to 100, preferably 5 to 50, more preferably 5 to 25 and most preferably 5 to 15 ⁇ in thickness.
  • At least part of the conductive coating is in the shape of lines from 0.01 to 0.25, and preferably 0.025 to 0.1 inches wide.
  • the present invention includes an article coated with the composition.
  • the composition can be set out in a pattern as shown in the accompanying figure.
  • the accompanying figure is an article of clothing such as a T- shirt 10.
  • the article can have thereon a drawing and/or artwork woven, or dyed, or silk-screened onto the article.
  • there can be one or more conducting channels such as 14 and 16 of the coating of the present invention.
  • the coated channels can be coated directly onto the article such as an article of clothing or coated onto a coating already present on the article.
  • the subcoating is useful to prevent the conductive coating from being absorbed into the textile fibers.
  • there can be an energy source such as battery 18 having terminals 20 and 22.
  • a conducting means such as a strip of conducting coating or conducting wire 24 is connected from terminal 20 to coated channel 14.
  • Coated channel 14 can be connected to a light such as an LCD 26 which in turn is shown connected to a second LCD light 28 via conductor 30.
  • Light 28 is connected to channel 16 which is connected to terminal 22 of battery 18 through conductor 32.
  • the present invention also includes a method. The method comprises a step of conducting an electric current through a layer of coating composition supported on a non ⁇ conducting substrate wherein the coating composition comprises the above-recited composition.
  • the method comprises coating a non-conducting substrate with a coating composition of the present invention, removing the liquid vehicle and conducting an electric current through the coating composition.
  • the composition can be formed into film, fiber, molded or extruded by conventional means.
  • the conductive materials was silver flake produced by Handy & Harmon, Chemical Products Center, 1770 Kings Highway, Fairfield, CT 06430 and described in the brochure Silflake ® Silver Flakes, hereby incorporated by reference.
  • silver flake sold as Silflake ® 135 and 237 were used in the following examples.
  • Silflake ® 135, referred to as Type 1 is a leafing-type silver flake
  • Silflake ® 237, referred to as Type 237 is a nonleafing-type silver flake particle. The reported characteristics of these particles are summarized in Table 1. TABLE 1
  • Type 1 2-15 16.0-28.0 2.0-3.0 0.10 0.90
  • Type 2 0.5-10 20.0-36.0 2.5-4.0 0.10 0.65
  • the Type 2 is also characterized as having "low ionic impurities, a maximum of 0.004% (Na + K) and 0.001% (Cl) .
  • the colorants used included those listed from the Hoechst Celanese Co., Hostaperm Series; and the Sandoz Chemical Corporation, Savinyl Series.
  • the resin used was a thermoplastic copolyester resin and the vehicle was dibasic ester solvent substantially comprising glutaric and tartaric acid.
  • the thermoplastic copolyester is sold by the Goodyear Tire and Rubber Company of Akron, Ohio as Vitel ® 2200.
  • Vitel ® 2200 is reported to have a specific gravity of 1.27, an acid number of from 1 to 3, a hydroxyl number of from 3 to 5, a Tg at onset of 63°C, Tg at nflection of 66°C, a melt flow point of 156°C (ASTM E 28-67) , a tensile at break of 7400 pr and an elongation of 3% (modified ASTM-822A) using an Instron 4200 at 73.4 gleich ⁇ 3.6°F and a humidity of 50% + 5% with a cross level speed of 0.5 inches/minute, a Shore hardness at 74°F of 74D (ASTM-D2240- 81), a number average molecular weight of 32,000, a weight average molecular weight of 58,000 and a polydispersity (AR-949 Polystyrene Reference) of 1.82.
  • the compositions used contained 50 parts by weight of the silver flake, 10 parts by weight of the colored pigment, 12 parts by wei ⁇
  • the example compositions were pr- red in accordance with the following procedures at ambient temperatures and pressure.
  • the conductive material, colorant, resin and vehicle were mixed in a bowl to form a paste.
  • 10 gram batches were mixed and dispersed using Hoover-Muller rotating glass plates; larger batches of lOOg of paste for Examples 28-36 were dispersed on a three-roll paint mill where it was ground to a fineness of 3 micrometers or less.
  • the paste was applied to a clear Mylar ® polyester film 5 mils thick.
  • the paste was applied to the film by silk screen printing using a 150 mesh polyester screen to form a 3 inch square.
  • a serpentine pattern was formed 64 inches long by 0.025 inches wide (2560 squares) using the coating composition of Examples 1-27, and a serpentine pattern found 64 long by 0.04 inches wide (1566 squares) was formed using the coating compositions of Examples 28-35.
  • the coating on the film was then dried in a static oven at 100°C for ten minutes.
  • a silk screen sample pattern of the type made using the compositions of Examples 25-35 is shown in Figure 2. Sheet resistivity was measured using a digital multi- ohm meter and the units of resistivity were ohms per square.
  • Example 1 - 9 compositions were made using only silver flake Type 2 (non-leafing) . The results are summarized in Table 1 below:
  • Examples 10 - 18 compositions were made using silver flake Type 1 (leafing type) at 25 parts by weight, silver flake Type 2 (non-leafing type) at 25 parts by weight. Table 2 summarizes the results using various colorants.
  • Example 19 - 27 compositions were made using silver flake Type 1 (leafing type) .
  • the colorants used and the results are summarized in Table 3 below:
  • Example 28-35 compositions were made by mixing the 25 parts of silver flake Type 1, 25 parts of silver flakes Type 2, 10 parts of the listed colorant, 12 parts of the copolyester and 28 parts of the dibasic solvent as recited.
  • the resin and solvent were premixed and comprise a vehicle for the metal particles and colorant.
  • the compositions were dispersed on the three roll mill.
  • the colorants treated in Table 4 were Hostoperm ® colored pigments sold by Hoechst.
  • the composition was silk screen printed through a 325 mesh stainless steel stencil screen. The pattern was a 0.040 inch wide by 64 inch long serpentine line (Figure 2) resulting in about 1566 squares.
  • the prints were heated on the 5 mil Mylar ® film at 100°C for 10 minutes.
  • the coating thickness micrometers ( ⁇ ) was measured using a stylus profilo eter.
  • Table 4 The colorants and results are summarized in Table 4 below:

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Abstract

L'invention concerne une composition conductrice colorée comprenant un colorant, des particules conductrices, une résine et, éventuellement, un liquide. La proportion du ou des colorants est d'environ 1 à 20 % par rapport au poids des particules conductrices. Une composition utilisable comprend environ 2 à 20 % en poids d'au moins une résine thermoplastique ou thermodurcissable, 40 à 70 % en poids d'au moins une particule conductrice contenant un métal ou des composés métalliques, et du graphite. L'article selon l'invention comporte des substrats supportant lesdites compositions.
PCT/US1994/010293 1993-09-24 1994-09-13 Composition de revetement conductrice coloree WO1995008829A1 (fr)

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Cited By (7)

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WO1999058615A1 (fr) * 1998-05-11 1999-11-18 Union Carbide Chemicals & Plastics Technology Corporation Compositions de revetements conducteurs a forte teneur en solides pouvant etre utilisees dans des procedes d'application par atomisation electrostatique
DE10332374A1 (de) * 2003-07-17 2005-02-17 Aventis Pharma Deutschland Gmbh Pflanzenfarbstoffhaltige Leitlacke
CN101096470B (zh) * 2006-06-30 2010-07-28 比亚迪股份有限公司 一种导电涂料组合物
CN101875798A (zh) * 2010-05-31 2010-11-03 刘昆虎 一种仿金属面外墙漆
WO2016164626A1 (fr) * 2015-04-10 2016-10-13 Tyco Electronics Corporation Formulation composite conductrice et article au moins partiellement formé d'une formulation composite conductrice
ITUB20151080A1 (it) * 2015-05-27 2016-11-27 Barzaghi S R L Composizione elettrotermica di composti carboniosi base acquosa e metodi applicativi
US10763004B2 (en) 2014-03-12 2020-09-01 3M Innovative Properties Company Conductive polymeric material

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FR2662703A1 (fr) * 1990-06-01 1991-12-06 Protex Manuf Prod Chimiq Peinture conductrice de l'electricite, de couleur claire.

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FR2662703A1 (fr) * 1990-06-01 1991-12-06 Protex Manuf Prod Chimiq Peinture conductrice de l'electricite, de couleur claire.

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WO1999058615A1 (fr) * 1998-05-11 1999-11-18 Union Carbide Chemicals & Plastics Technology Corporation Compositions de revetements conducteurs a forte teneur en solides pouvant etre utilisees dans des procedes d'application par atomisation electrostatique
US6106742A (en) * 1998-05-11 2000-08-22 Union Carbide Chemicals & Plastics Technology Corporation High solids conductive coatings compositions suitable for electrostatic atomization application methods
DE10332374A1 (de) * 2003-07-17 2005-02-17 Aventis Pharma Deutschland Gmbh Pflanzenfarbstoffhaltige Leitlacke
WO2005017052A1 (fr) * 2003-07-17 2005-02-24 Sanofi-Aventis Deutschland Gmbh Vernis conducteur contenant du colorant vegetal
CN101096470B (zh) * 2006-06-30 2010-07-28 比亚迪股份有限公司 一种导电涂料组合物
CN101875798A (zh) * 2010-05-31 2010-11-03 刘昆虎 一种仿金属面外墙漆
US10763004B2 (en) 2014-03-12 2020-09-01 3M Innovative Properties Company Conductive polymeric material
WO2016164626A1 (fr) * 2015-04-10 2016-10-13 Tyco Electronics Corporation Formulation composite conductrice et article au moins partiellement formé d'une formulation composite conductrice
US20160300636A1 (en) * 2015-04-10 2016-10-13 Tyco Electronics Corporation Conductive Composite Formulation and Article At Least Partially Formed From a Conductive Composite Formulation
CN107580723A (zh) * 2015-04-10 2018-01-12 泰连公司 导电复合制剂和至少部分地由导电复合制剂形成的制品
ITUB20151080A1 (it) * 2015-05-27 2016-11-27 Barzaghi S R L Composizione elettrotermica di composti carboniosi base acquosa e metodi applicativi

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