WO1995002314A3 - A lithium-ion-conductive solid polymer electrolyte and method for its preparation - Google Patents

A lithium-ion-conductive solid polymer electrolyte and method for its preparation Download PDF

Info

Publication number
WO1995002314A3
WO1995002314A3 PCT/US1993/009859 US9309859W WO9502314A3 WO 1995002314 A3 WO1995002314 A3 WO 1995002314A3 US 9309859 W US9309859 W US 9309859W WO 9502314 A3 WO9502314 A3 WO 9502314A3
Authority
WO
WIPO (PCT)
Prior art keywords
solid polymer
lithium
polyacrylonitrile
polymer electrolyte
ion
Prior art date
Application number
PCT/US1993/009859
Other languages
French (fr)
Other versions
WO1995002314A2 (en
Inventor
Vladimir Mihailovit Zhukovskiy
Andrey Leonidovitc Kruglyashov
Irina Evgenievna Animitsa
Olga Victorovna Bushkova
Yaroslav Arturovitc Krasnobaev
Anna Isaakovna Suvorova
Original Assignee
Scient Dimensions U S A Inc
Vladimir Mihailovit Zhukovskiy
Andrey Leonidovitc Kruglyashov
Irina Evgenievna Animitsa
Olga Victorovna Bushkova
Yaroslav Arturovitc Krasnobaev
Anna Isaakovna Suvorova
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scient Dimensions U S A Inc, Vladimir Mihailovit Zhukovskiy, Andrey Leonidovitc Kruglyashov, Irina Evgenievna Animitsa, Olga Victorovna Bushkova, Yaroslav Arturovitc Krasnobaev, Anna Isaakovna Suvorova filed Critical Scient Dimensions U S A Inc
Priority to US08/583,001 priority Critical patent/US5693433A/en
Priority to AU54048/94A priority patent/AU5404894A/en
Publication of WO1995002314A2 publication Critical patent/WO1995002314A2/en
Publication of WO1995002314A3 publication Critical patent/WO1995002314A3/en

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/122—Ionic conductors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Electrochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Dispersion Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Secondary Cells (AREA)
  • Conductive Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

The subject invention relates to solvent-free, lithium-ion conductive, solid polymer electrolytes containing an amorphous polyacrylonitrile polymer and an ionizable lithium salt. Preferably, the polyacrylonitrile polymer is a polyacrylonitrile copolymer obtained from copolymerization of a mixture of monomers containing at least 90 % acrylonitrile monomer. The solid polymer electrolyte is prepared using a method that produces a solvent-free amorphous polyacrylonitrile copolymer without causing nitrile cyclization or cross-linking reactions to occur. The polymer electrolytes of the subject invention have an ionic conductivity of about 10-4 to about 10?-2 Ohm-1cm-1¿ at ambient temperature.
PCT/US1993/009859 1993-01-07 1993-10-14 A lithium-ion-conductive solid polymer electrolyte and method for its preparation WO1995002314A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US08/583,001 US5693433A (en) 1993-01-07 1993-10-14 Lithium-ion-conductive solid polymer electrolyte and method for its preparation
AU54048/94A AU5404894A (en) 1993-07-01 1993-10-14 A lithium-ion-conductive solid polymer electrolyte and method for its preparation

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU93034570 1993-07-01
RU93034570/07A RU2066901C1 (en) 1993-07-01 1993-07-01 Solid lithium-conducting electrolyte and its production method

Publications (2)

Publication Number Publication Date
WO1995002314A2 WO1995002314A2 (en) 1995-01-26
WO1995002314A3 true WO1995002314A3 (en) 2002-02-14

Family

ID=20144479

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1993/009859 WO1995002314A2 (en) 1993-01-07 1993-10-14 A lithium-ion-conductive solid polymer electrolyte and method for its preparation

Country Status (3)

Country Link
AU (1) AU5404894A (en)
RU (1) RU2066901C1 (en)
WO (1) WO1995002314A2 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2781932B1 (en) 1998-07-10 2000-09-01 Giat Ind Sa SOLID POLYMER ELECTROLYTE AND METHODS OF PREPARING THE SAME
WO2005078834A1 (en) * 2004-02-16 2005-08-25 Chebotarev Valery Panteleimono Chemical current source
TWI317752B (en) 2005-04-19 2009-12-01 Lg Chemical Ltd Safety-improved electrode by introducing crosslinkable polymer and electrochemical device comprising the same
RU2457587C1 (en) * 2011-01-11 2012-07-27 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Сибирский государственный технологический университет" (СибГТУ) Polymer electrolyte gel for lithium-ion battery
RU2503098C1 (en) * 2012-07-03 2013-12-27 Федеральное государственное бюджетное учреждение науки Институт элементоорганических соединений им. А.Н. Несмеянова Российской академии наук (ИНЭОС РАН) Solid polymer electrolyte for lithium sources of current
CN106463691A (en) 2014-03-25 2017-02-22 天普大学英联邦高等教育体系 Soft-solid crystalline electrolyte compositions
RU2714498C1 (en) * 2016-01-18 2020-02-18 Мицубиси Газ Кемикал Компани, Инк. Method of producing ion conductor
WO2018173940A1 (en) * 2017-03-22 2018-09-27 三菱瓦斯化学株式会社 PRODUCTION METHOD FOR SOLID ELECTROLYTE HAVING Li3PS4
RU2766576C2 (en) * 2017-09-01 2022-03-15 Мицубиси Гэс Кемикал Компани, Инк. Method of producing solid electrolyte based on lgps

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4609971A (en) * 1983-08-11 1986-09-02 North American Philips Corporation Electrolytic capacitor with polymer conductor
US4654279A (en) * 1986-07-10 1987-03-31 The United States Of America As Represented By The Secretary Of The Navy Interpenetrating-network polymeric electrolytes
US4886572A (en) * 1987-12-14 1989-12-12 Ricoh Company, Ltd. Composite electrode comprising a bonded body of aluminum and electroconductive polymer and electric cell using such a composite electrode
US4999263A (en) * 1987-04-15 1991-03-12 Ricoh Company, Ltd. Sheet-shaped electrode, method or producing the same, and secondary battery
JPH03210313A (en) * 1990-01-11 1991-09-13 Yuasa Battery Co Ltd Solid-state polyelectrolyte

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4609971A (en) * 1983-08-11 1986-09-02 North American Philips Corporation Electrolytic capacitor with polymer conductor
US4654279A (en) * 1986-07-10 1987-03-31 The United States Of America As Represented By The Secretary Of The Navy Interpenetrating-network polymeric electrolytes
US4999263A (en) * 1987-04-15 1991-03-12 Ricoh Company, Ltd. Sheet-shaped electrode, method or producing the same, and secondary battery
US4886572A (en) * 1987-12-14 1989-12-12 Ricoh Company, Ltd. Composite electrode comprising a bonded body of aluminum and electroconductive polymer and electric cell using such a composite electrode
JPH03210313A (en) * 1990-01-11 1991-09-13 Yuasa Battery Co Ltd Solid-state polyelectrolyte

Also Published As

Publication number Publication date
WO1995002314A2 (en) 1995-01-26
AU5404894A (en) 1995-02-13
RU2066901C1 (en) 1996-09-20

Similar Documents

Publication Publication Date Title
CA2212399A1 (en) Ionically conductive polymeric gel electrolyte and solid battery containing the same
EP0842216B1 (en) Rechargeable battery polymeric electrolyte
US6001509A (en) Solid polymer electrolytes
CA1307024C (en) Separator for lithium batteries and lithium batteries including the separator
KR100250855B1 (en) A hybrid polymeric electrolyte, a method of making the same and a lithium battery with the same
WO2000059052A8 (en) Alkaline cell separator
CA2156800A1 (en) Polymerizable aromatic additives for overcharge protection in non-aqueous rechargeable lithium batteries
EP0822608A3 (en) Polymeric solid electrolyte and lithium secondary cell adopting the same
KR960036170A (en) Polymeric electrodes and electrolyte products
EP0312160A3 (en) Solid polymeric electrolyte and electrochemical generators containing it
CA2114473A1 (en) Electrochemical cells using a polymer electrolyte
CA2163187A1 (en) Aromatic monomer gassing agents for protecting non-aqueous lithium batteries against overcharge
CA2171298A1 (en) Trifluorostyrene and Substituted Trifluorostyrene Copolymeric Compositions and Ion-Exchange Membranes Formed Therefrom
WO1995002314A3 (en) A lithium-ion-conductive solid polymer electrolyte and method for its preparation
EP1116769A3 (en) Electrolyte composition, electrochemical cell and ionic liquid crystal monomer
EP0999223B8 (en) Vinylidene fluoride copolymer for gel-form solid electrolyte formation, solid electrolyte, and battery
FR2677800B1 (en) SOLID ION CONDUCTIVE MATERIAL FROM A POLYMER AND AN ALKALINE CATION SALT, APPLICATION AS AN ELECTROLYTE.
KR20010113516A (en) Gel electrolyte and nonaqueous electrolyte battery
MY117035A (en) Non-aqueous electrolyte secondary cell.
CA2316299A1 (en) Polymer electrolyte and nonaqueous battery containing the same
WO1999034372A6 (en) Polymer electrolyte and nonaqueous battery containing the same
CA2294291A1 (en) Solid electrolytic secondary battery
IT1277374B1 (en) PROCEDURE FOR THE PREPARATION OF A CURRENT COLLECTOR IN CONTACT WITH THE CATHODIC MATERIAL
EP0411156A4 (en) Secondary lithium battery
EP0359524A3 (en) Electrolyte composition

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AT AU BB BG BR BY CA CH CZ DE DK ES FI GB HU JP KP KR KZ LK LU LV MG MN MW NL NO NZ PL PT RO RU SD SE SK UA US UZ VN

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
122 Ep: pct application non-entry in european phase
WWE Wipo information: entry into national phase

Ref document number: 08583001

Country of ref document: US

NENP Non-entry into the national phase

Ref country code: CA

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

AK Designated states

Kind code of ref document: A3

Designated state(s): AT AU BB BG BR BY CA CH CZ DE DK ES FI GB HU JP KP KR KZ LK LU LV MG MN MW NL NO NZ PL PT RO RU SD SE SK UA US UZ VN

AL Designated countries for regional patents

Kind code of ref document: A3

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG