WO1994021828A2 - Vacuum apparatus for multiple-bed industrial hide driers, and drier including the apparatus - Google Patents
Vacuum apparatus for multiple-bed industrial hide driers, and drier including the apparatus Download PDFInfo
- Publication number
- WO1994021828A2 WO1994021828A2 PCT/EP1994/000788 EP9400788W WO9421828A2 WO 1994021828 A2 WO1994021828 A2 WO 1994021828A2 EP 9400788 W EP9400788 W EP 9400788W WO 9421828 A2 WO9421828 A2 WO 9421828A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mbar
- circuit
- absolute pressure
- aspiration device
- hides
- Prior art date
Links
- 206010003504 Aspiration Diseases 0.000 claims abstract description 17
- 238000011144 upstream manufacturing Methods 0.000 claims abstract description 6
- 238000001704 evaporation Methods 0.000 claims description 17
- 230000008020 evaporation Effects 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 2
- 238000006073 displacement reaction Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims 1
- 238000001035 drying Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000012530 fluid Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000012809 cooling fluid Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14B—MECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
- C14B1/00—Manufacture of leather; Machines or devices therefor
- C14B1/58—Drying
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B5/00—Drying solid materials or objects by processes not involving the application of heat
- F26B5/04—Drying solid materials or objects by processes not involving the application of heat by evaporation or sublimation of moisture under reduced pressure, e.g. in a vacuum
- F26B5/045—Drying solid materials or objects by processes not involving the application of heat by evaporation or sublimation of moisture under reduced pressure, e.g. in a vacuum for drying thin, flat articles in a batch operation, e.g. leather, rugs, gels
Definitions
- the present invention relates to a vacuum apparatus for multiple-bed industrial hide driers, and to a drier that includes the apparatus.
- vacuum driers have the drawback of higher initial and running costs and of lower final hide quality, especially for thinner hides with finer grain, due to the considerable heat-induced stresses on the hides and to the depletion of fatty materials contained in their fibers.
- the hides are in fact arranged on beds which are heated to approximately 60-80°C, i.e. to temperatures that are considerably higher than the "body" temperature of the animals from which they are obtained, in order to make the residual moisture evaporate as quickly as possible.
- the beds are hermetically enclosed by airtight lids so as to form a series of evaporation chambers that are connected to a vacuum pump by means of a circuit along which one or more condensers and/or condensate separators are arranged.
- the vapor state diagram clearly shows that the higher the vacuum produced in the sealed chambers, the lower the evaporation temperature at equilibrium.
- a high vacuum is produced in the vapor circuit by means of vacuum pumps of the liquid-ring type or of the variable-chamber cylinder type, using water or oil as working fluids; these pumps can produce vacuum up to 95% with residual absolute pressures of less than 30 mbar.
- the pressure is gradually reduced down to a vacuum of more than 90%, which corresponds to an absolute pressure of approximately 80 mbar, with a vapor equilibrium temperature of approximately 45°C. Accordingly, the beds are heated to a temperature of at least 60-70°C to produce a thermal gradient that allows evaporation of the residual moisture of the hides in an acceptable time.
- the aim of the present invention is to eliminate the drawbacks described above by providing an apparatus with lower evaporation temperatures than in the conventional types, with obvious advantages from the point of view of production.
- An object of the invention is to drastically reduce the evaporation temperature and consequently the temperature of the beds, so as to avoid any damage to the hides and give them maximum grain softness, with obvious advantages from the point of view of quality.
- the invention achieves this aim and this object by means of a vacuum apparatus for industrial hide driers, including a circuit with an open end and having arranged in series: at least one manifold associated with each bed to collect the vapors released by the hides; a first condenser inserted in each manifold; a first condensate separator at the output of the various condensers; at least one main vacuum pump which is suitable to reduce the absolute pressure in the circuit to a first upper value which corresponds to a given vapor equilibrium temperature; characterized in that it has a secondary aspiration device which is arranged upstream of the main vacuum pump, said device operating in series to the vacuum pump when the first upper value of the absolute pressure is reached, said device being suitable to further reduce the absolute pressure to a second lower value that allows to instantly increase the evaporation and/or reduce the vapor equilibrium temperature to a second value which is lower than the first one.
- the upper value of the absolute pressure reached by the main vacuum pump in the steady state is 100 to 40 mbar.
- the lower value of the absolute pressure reached in the steady state by placing the secondary aspiration device in series to the main pump can be of 15 to 1 mbar.
- the secondary aspiration device is of the high-capacity, low-head type, with an average capacity of 300 to 1000 m 3 /h and a pressure differential of 30 to 100 mbar.
- the secondary aspiration device can be constituted by a positive-displacement compressor of the Roots or vane type or by a gas or steam ejector.
- the intake and delivery ducts of the secondary aspiration device are connected by a bypass circuit with a controlled electric valve interposed.
- the secondary aspiration device runs continuously: the electric valve of the bypass circuit is normally open when the absolute pressure in the circuit is higher than the first upper value and is closed for equal or lower values.
- the block 1 schematically designates a conventional drier with multiple beds which includes a series of stacked beds 2 that can move along vertical guides 3 of a frame which is anchored to the ground.
- Each bed includes a lower part 4 and an upper cover 6 that closes hermetically.
- the lower part 4 is for heating hides P by means of coils 5, through which a fluid flows at a temperature T s which is higher than the ambient temperature.
- At least one, preferably two steam manifolds 7 are associated with each bed.
- the humid and partially condensed vapors at the outlet of the condensers 8 are conveyed by means of a main pipe 9 toward a first condensate separator 10, for example of the centrifugal type, with a condensate collection tray 11.
- the vapor that leaves the separator 10 is conveyed along the line 12 to a second condenser 13 and then to a second condensate separator 14 with a collection tray 14'.
- the condenser 14 allows to almost entirely eliminate the residual humidity that is present in the circuit, where dry air flows almost exclusively from this point onward.
- the separator 14 is connected, by means of a pipe 15, to a main vacuum pump 16, for example of the liquid-ring type with one or two stages, marketed and manufactured by Robuschi SpA under the trademark RVM.
- the pump 16 has the purpose of drawing the fluid toward the open end 17 of the circuit and of gradually reducing the absolute pressure of the fluid to a first upper value P s which is between 100 mbar (75 Torr) and 40 mbar (30 Torr), for example equal to 80 mbar (60 Torr), which corresponds to a first vapor equilibrium temperature T ⁇ which is approximately equal to 45°C.
- An electric valve 18 for cutoff and for interrupting the vacuum is placed along the line 15 upstream of the pump 16.
- a secondary aspiration device which is suitable to work in series to the main pump 16 when the upper value P ⁇ of the absolute pressure is reached.
- the aspiration device 19 can be constituted by a vane or Roots-type blower, for example of the type manufactured and marketed by Robuschi SpA under the trademark RB/AV, with high capacities of approximately 300 to 1000 m 3 /h, and low heads, for example 80 mbar (60 torr) to 100 mbar (75 torr).
- a vane or Roots-type blower for example of the type manufactured and marketed by Robuschi SpA under the trademark RB/AV, with high capacities of approximately 300 to 1000 m 3 /h, and low heads, for example 80 mbar (60 torr) to 100 mbar (75 torr).
- the blower 19 is connected in series to the main pump so that its intake duct 20 and its delivery duct 21 are always open, and runs continuously in order to make its differential pressure immediately available.
- the intake and delivery ducts 20, 21 are connected by a bypass circuit with a normally-open electric valve 22.
- This electric valve is operatively connected to a pressure sensor 23 which is arranged on the line 15 and is set to act on the valve 23 so that the valve is open for absolute pressure values above P g , which is set for example to 80 mbar (60 Torr), and is closed when this value is reached.
- the beds can be heated with water at temperatures T r which are between 15°C and 30°C, are distinctly lower than those of the past, and are such as to leave the quality of the grain of the hide absolutely unchanged. Furthermore, by virtue of the extremely short evaporation times, the hide does not lose its fat content, which is essential in giving it a good texture and high softness to the touch.
- these devices are adequately insulated in order to function adiabatically with respect to the outside environment.
- the hides are laid on the lower parts of the beds 2, which are in turn closed hermetically with the covers 6.
- the beds 4 are then heated with water at a temperature T s which is lower than 30°C.
- the pump 16 is started, gradually decreasing the absolute pressure within a few minutes to a value P g between 100 and 40 mbar, for example 80 mbar, to which the pressure sensor 23 is set.
- P g between 100 and 40 mbar, for example 80 mbar
- the pressure sensor 23 activates the electric valve 22, closing the bypass circuit of the device 19.
- This device operates in series to the vacuum pump 16, further reducing the pressure until it reaches a degree of vacuum which is close to absolute, with residual absolute pressures of approximately 5-10 mbar.
- the vapor equilibrium temperature T 2 is below 10°C and thus produces a thermal gradient at the beds which is meant to promptly vaporize the residual moisture of the hides.
- the vapors are quickly condensed by virtue of the temperature of the condensers, which is approximately equal to 0°C, drastically reducing the drying time. If one wishes to give priority to low treatment temperatures, in order to dry particularly delicate and thin hides, it is possible to reduce the heating temperature T r , for example to less than 20°C, slightly reducing the thermal gradient and conversely increasing the drying time. By acting on these parameters it is possible to balance the two effects, obtaining optimum quality with considerably shorter drying times than in the past.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- General Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Drying Of Solid Materials (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Paper (AREA)
Abstract
Description
Claims
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE69404635T DE69404635T2 (en) | 1993-03-18 | 1994-03-14 | VACUUM DRYING DEVICE WITH SEVERAL PANELS FOR SKIN, AND DRYER WITH SUCH A DEVICE |
JP52062394A JP3605112B2 (en) | 1993-03-18 | 1994-03-14 | Vacuum device for multi-bed industrial skin dryer and dryer including the device |
US08/525,570 US6178659B1 (en) | 1993-03-18 | 1994-03-14 | Vacuum apparatus for multiple-bed industrial hide driers, and drier including the apparatus |
KR1019950703677A KR100318614B1 (en) | 1993-03-18 | 1994-03-14 | Vacuum dryer for multi-stage bed type leather dryer and dryer with its factory |
BR9406006A BR9406006A (en) | 1993-03-18 | 1994-03-14 | Vacuum device for industrial multi-bed skin dryers and vacuum dryer for industrial skins |
EP94911883A EP0689613B1 (en) | 1993-03-18 | 1994-03-14 | Vacuum apparatus for multiple-bed industrial hide driers, and drier including the apparatus |
AU64259/94A AU682501B2 (en) | 1993-03-18 | 1994-03-14 | Vacuum apparatus for multiple-bed industrial hide driers, and drier including the apparatus |
UA95094181A UA44241C2 (en) | 1993-03-18 | 1994-03-14 | VACUUM INSTALLATION FOR CASSETTE INDUSTRIAL LEATHER DRYERS AND DRYER WITH SUCH INSTALLATION |
PL94310674A PL173440B1 (en) | 1993-03-18 | 1994-03-14 | Vacuum apparatus for a multi-level leather dryer and leather dryer incorporating such apparatus |
CA002156844A CA2156844C (en) | 1993-03-18 | 1994-03-14 | Vacuum apparatus for multiple-bed industrial hide driers, and drier including the apparatus |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITVI930041A IT1270767B (en) | 1993-03-18 | 1993-03-18 | VACUUM PLANT FOR INDUSTRIAL LEATHER DRYERS WITH MULTIPLE TANKS AND DRYING BUILDING SUCH SYSTEM |
ITVI93A000041 | 1993-03-18 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1994021828A2 true WO1994021828A2 (en) | 1994-09-29 |
WO1994021828A3 WO1994021828A3 (en) | 1994-11-10 |
Family
ID=11425149
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1994/000788 WO1994021828A2 (en) | 1993-03-18 | 1994-03-14 | Vacuum apparatus for multiple-bed industrial hide driers, and drier including the apparatus |
Country Status (15)
Country | Link |
---|---|
US (1) | US6178659B1 (en) |
EP (1) | EP0689613B1 (en) |
JP (1) | JP3605112B2 (en) |
KR (1) | KR100318614B1 (en) |
AT (1) | ATE156195T1 (en) |
AU (1) | AU682501B2 (en) |
BR (1) | BR9406006A (en) |
CA (1) | CA2156844C (en) |
DE (1) | DE69404635T2 (en) |
ES (1) | ES2105676T3 (en) |
IT (1) | IT1270767B (en) |
PL (1) | PL173440B1 (en) |
RU (1) | RU2120091C1 (en) |
UA (1) | UA44241C2 (en) |
WO (1) | WO1994021828A2 (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998001583A1 (en) | 1996-07-08 | 1998-01-15 | Emilio Buttazzi | Thermal compression plant with heat recovery for vacuum dryers and dryer incorporating said plant |
WO2000000777A1 (en) * | 1998-06-29 | 2000-01-06 | Officine Di Cartigliano S.P.A. | Stabilized high vacuum drying installation for industrial hides and similar products |
WO2008011912A1 (en) * | 2006-07-27 | 2008-01-31 | Escomar Italia S.R.L. | System for creating a vacuum in a tanning dryer |
ITVE20080061A1 (en) * | 2008-07-18 | 2010-01-19 | Dal Lago S R L | IMPROVED PLANT FOR THE VACUUM GENERATION IN DRYER DRIERS. |
ITVI20110307A1 (en) * | 2011-11-25 | 2013-05-26 | Turato S R L Off | VACUUM PLANT FOR MULTIPLE FLOOR DRIERS |
ITVI20130009A1 (en) * | 2013-01-17 | 2014-07-18 | Cartigliano Off Spa | COMPACT SYSTEM FOR VACUUM DRYING IN INDUSTRIAL SKINS |
ITVI20130138A1 (en) * | 2013-05-17 | 2014-11-18 | Cartigliano Off Spa | IMPROVED VACUUM DRYER FOR INDUSTRIAL SKINS |
ITVI20130304A1 (en) * | 2013-12-19 | 2015-06-20 | Turato Srl Off | STABILIZED VACUUM PLANT FOR INDUSTRIAL LEATHER DRYER WITH MULTIPLE EVAPORATION PANELS |
IT201600070577A1 (en) * | 2016-07-06 | 2018-01-06 | Simtech S R L | PLANT FOR SKIN DRYING |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1174105C (en) * | 1999-12-14 | 2004-11-03 | 卡尔蒂格利诺·奥菲希恩公司 | Machine for conditioning laminar flexible products such as industrial hides and skins |
CN1618716B (en) * | 2003-11-12 | 2011-03-16 | 周星工程股份有限公司 | Loading lock and loading lock chamber therewith |
GB0502149D0 (en) | 2005-02-02 | 2005-03-09 | Boc Group Inc | Method of operating a pumping system |
GB0508872D0 (en) * | 2005-04-29 | 2005-06-08 | Boc Group Plc | Method of operating a pumping system |
CN101046351B (en) * | 2006-03-30 | 2010-06-30 | 如皋市斯普润机器制造厂 | Low temperature vacuum drier |
CN104630392B (en) * | 2015-01-28 | 2016-05-11 | 浙江格莱美服装有限公司 | A kind of humidity controlled steam warming and humidifying leather and lining cloth adhesion processing equipment |
IT202000007369A1 (en) * | 2020-04-07 | 2021-10-07 | Giuseppe Pozzan | VACUUM DRYER FOR DRYING LEATHER AND / OR FABRICS WITH ADDITIONAL PRESSURE |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3027651A (en) * | 1958-07-23 | 1962-04-03 | Leybold Hochvakuum Anlagen | Process and system for removing condensable vapors |
FR2557888A1 (en) * | 1984-01-11 | 1985-07-12 | Cartigliano Ind Metalmecc | TRAY FOR VACUUM DRYING OF TANNED SKIN |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1364603A (en) * | 1963-02-26 | 1964-06-26 | Vide Soc Gen Du | Vacuum drying device |
FR2182406A6 (en) * | 1972-04-26 | 1973-12-07 | Scaal | |
IT1204265B (en) * | 1986-03-24 | 1989-03-01 | Cartigliano Off Spa | VACUUM DRYING MACHINE WITH MULTIPLE WORKING PLATES FOR TANNED LEATHER |
IT1233807B (en) * | 1989-02-15 | 1992-04-17 | Cartigliano Off Spa | VACUUM DRYING MACHINE WITH MULTIPLE PLANES FOR INDUSTRIAL LEATHER AND SIMILAR PRODUCTS. |
IT1236376B (en) * | 1989-10-13 | 1993-02-25 | Cartigliano Off Spa | METHOD AND MACHINE FOR SOFTENING AND IRONING LAMINARY PRODUCTS, PARTICULARLY TANNED LEATHER. |
IT1247067B (en) * | 1991-01-14 | 1994-12-12 | Cartigliano Off Spa | Method and equipment for the treatment of biological products. |
-
1993
- 1993-03-18 IT ITVI930041A patent/IT1270767B/en active IP Right Grant
-
1994
- 1994-03-14 DE DE69404635T patent/DE69404635T2/en not_active Expired - Fee Related
- 1994-03-14 EP EP94911883A patent/EP0689613B1/en not_active Expired - Lifetime
- 1994-03-14 BR BR9406006A patent/BR9406006A/en not_active IP Right Cessation
- 1994-03-14 US US08/525,570 patent/US6178659B1/en not_active Expired - Fee Related
- 1994-03-14 PL PL94310674A patent/PL173440B1/en not_active IP Right Cessation
- 1994-03-14 RU RU95121736A patent/RU2120091C1/en active
- 1994-03-14 UA UA95094181A patent/UA44241C2/en unknown
- 1994-03-14 WO PCT/EP1994/000788 patent/WO1994021828A2/en active IP Right Grant
- 1994-03-14 CA CA002156844A patent/CA2156844C/en not_active Expired - Fee Related
- 1994-03-14 JP JP52062394A patent/JP3605112B2/en not_active Expired - Fee Related
- 1994-03-14 KR KR1019950703677A patent/KR100318614B1/en not_active IP Right Cessation
- 1994-03-14 ES ES94911883T patent/ES2105676T3/en not_active Expired - Lifetime
- 1994-03-14 AT AT94911883T patent/ATE156195T1/en active
- 1994-03-14 AU AU64259/94A patent/AU682501B2/en not_active Ceased
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3027651A (en) * | 1958-07-23 | 1962-04-03 | Leybold Hochvakuum Anlagen | Process and system for removing condensable vapors |
FR2557888A1 (en) * | 1984-01-11 | 1985-07-12 | Cartigliano Ind Metalmecc | TRAY FOR VACUUM DRYING OF TANNED SKIN |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998001583A1 (en) | 1996-07-08 | 1998-01-15 | Emilio Buttazzi | Thermal compression plant with heat recovery for vacuum dryers and dryer incorporating said plant |
US6112426A (en) * | 1996-07-08 | 2000-09-05 | Buttazzi; Emilio | Thermal compression plant with heat recovery for vacuum dryers and dryer incorporating said plant |
WO2000000777A1 (en) * | 1998-06-29 | 2000-01-06 | Officine Di Cartigliano S.P.A. | Stabilized high vacuum drying installation for industrial hides and similar products |
US6381867B1 (en) | 1998-06-29 | 2002-05-07 | Antonio Polato | Stabilized high vacuum drying installation for industrial hides and similar products |
WO2008011912A1 (en) * | 2006-07-27 | 2008-01-31 | Escomar Italia S.R.L. | System for creating a vacuum in a tanning dryer |
ITVE20080061A1 (en) * | 2008-07-18 | 2010-01-19 | Dal Lago S R L | IMPROVED PLANT FOR THE VACUUM GENERATION IN DRYER DRIERS. |
ITVI20110307A1 (en) * | 2011-11-25 | 2013-05-26 | Turato S R L Off | VACUUM PLANT FOR MULTIPLE FLOOR DRIERS |
ITVI20130009A1 (en) * | 2013-01-17 | 2014-07-18 | Cartigliano Off Spa | COMPACT SYSTEM FOR VACUUM DRYING IN INDUSTRIAL SKINS |
ITVI20130138A1 (en) * | 2013-05-17 | 2014-11-18 | Cartigliano Off Spa | IMPROVED VACUUM DRYER FOR INDUSTRIAL SKINS |
WO2014184621A1 (en) * | 2013-05-17 | 2014-11-20 | Officine Di Cartigliano Spa | Improved vacuum drier for industrial hides |
CN104321445A (en) * | 2013-05-17 | 2015-01-28 | 卡尔蒂格利诺·奥菲希恩公司 | Improved vacuum drier for industrial hides |
KR20160010282A (en) * | 2013-05-17 | 2016-01-27 | 오피시네 디 카르티글리아노 에스.피.에이. | Improved vaccum drier for industrial hides |
KR101950547B1 (en) * | 2013-05-17 | 2019-02-20 | 오피시네 디 카르티글리아노 에스.피.에이. | Improved vaccum drier for industrial hides |
CN104321445B (en) * | 2013-05-17 | 2019-07-12 | 卡尔蒂格利诺·奥菲希恩公司 | Improved vacuum drier for industrial hides |
ITVI20130304A1 (en) * | 2013-12-19 | 2015-06-20 | Turato Srl Off | STABILIZED VACUUM PLANT FOR INDUSTRIAL LEATHER DRYER WITH MULTIPLE EVAPORATION PANELS |
IT201600070577A1 (en) * | 2016-07-06 | 2018-01-06 | Simtech S R L | PLANT FOR SKIN DRYING |
Also Published As
Publication number | Publication date |
---|---|
ITVI930041A1 (en) | 1994-09-18 |
ITVI930041A0 (en) | 1993-03-18 |
ATE156195T1 (en) | 1997-08-15 |
CA2156844A1 (en) | 1994-09-29 |
US6178659B1 (en) | 2001-01-30 |
WO1994021828A3 (en) | 1994-11-10 |
RU2120091C1 (en) | 1998-10-10 |
JP3605112B2 (en) | 2004-12-22 |
IT1270767B (en) | 1997-05-07 |
BR9406006A (en) | 1996-01-02 |
JPH08507815A (en) | 1996-08-20 |
AU682501B2 (en) | 1997-10-09 |
AU6425994A (en) | 1994-10-11 |
DE69404635T2 (en) | 1998-01-08 |
PL310674A1 (en) | 1995-12-27 |
DE69404635D1 (en) | 1997-09-04 |
UA44241C2 (en) | 2002-02-15 |
ES2105676T3 (en) | 1997-10-16 |
EP0689613B1 (en) | 1997-07-30 |
CA2156844C (en) | 2004-10-12 |
KR100318614B1 (en) | 2002-04-22 |
EP0689613A1 (en) | 1996-01-03 |
PL173440B1 (en) | 1998-03-31 |
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