WO1994018934A1 - Compositions capillaires contenant un compose de silicone et un compose d'ammonium quaternaire - Google Patents
Compositions capillaires contenant un compose de silicone et un compose d'ammonium quaternaire Download PDFInfo
- Publication number
- WO1994018934A1 WO1994018934A1 PCT/EP1994/000551 EP9400551W WO9418934A1 WO 1994018934 A1 WO1994018934 A1 WO 1994018934A1 EP 9400551 W EP9400551 W EP 9400551W WO 9418934 A1 WO9418934 A1 WO 9418934A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- quaternary ammonium
- hair
- weight
- amount
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Definitions
- the present invention relates to a toiletries composition in the form of a hair care composition having conditioning properties , and to methods of manufacturing and using such a composition .
- hair care composition includes so-called “hot oil” treatments , shampoos , conditioners , hair dyes , mousses , foams , gels , creams , lotions and rinses , all suitable for use on the human head .
- Hair care compositions comprising water soluble quaternary ammonium compounds, as conditioning agents, are well known in the art.
- GB-A-1538768 (Alberto Culver) discloses a method of treating hair to improve its manageability, by contacting the hair with an aqueous composition comprising a water soluble quaternary ammonium compound (having one or two nitrogen atoms and at least one long chain alkyl group linked to one or both of the nitrogen atom(s)), and then shampooing the hair.
- a water soluble quaternary ammonium compound having one or two nitrogen atoms and at least one long chain alkyl group linked to one or both of the nitrogen atom(s)
- Silicone copolyols are also known for use in hair care compositions.
- P Union Carbide has described the use of dimethicone copolyols (available under the registered trade name "Silwet”) in hair sprays (as plasticisers and as wetting and levelling agents) , in shampoos (to give profoaming activity and improved wettability and lubricity) , in after shampoo preparations (to give improved wettability and lubricity) , and in hair fixatives/dressings (as wetting agents and pump valve lubricants) .
- Dimethicone copolyols available under the registered trade name "Silwet”
- hair sprays as plasticisers and as wetting and levelling agents
- shampoos to give profoaming activity and improved wettability and lubricity
- after shampoo preparations to give improved wettability and lubricity
- hair fixatives/dressings as wetting agents and pump valve lubricants
- Avon cosmetics have marketed a so-called "hot oil” conditioning treatment comprising a dimethicone copolyol.
- the product is in the form of a lotion which is designed to turn from cloudy to clear when immersed in hot water prior to use.
- the Boots Company PLC has marketed another so-called "hot oil" conditioning treatment comprising the agent available under the CTFA designation stearalkonium chloride.
- the packaged product is intended to be heated by immersion in hot water prior to use.
- the product turns from cloudy to clear at the optimum temperature for use and this transition indicates to the user that the product is at the correct temperature.
- GB-A-2205 747 (Colgate - Palmolive) discloses a stable easily removable hair rinse conditioner comprising a short chain quaternary ammonium compound, a c i4-22 alkanol and about 0.5 to 1.5% by weight of a cyclic or linear silicone.
- EP-A-0155806 (Procter and Gamble) discloses a hair conditioning composition comprising inter alia 0.01% to
- silicone copolyols having a cloud point (in water at 4% by weight) of between 20°C and 60°C provide improved substantivity in hair care compositions when included in an amount of at least about 4% by weight of the composition.
- a hair care composition comprising a cosmetically acceptable silicone copolyol having a cloud point (in water at 4% by weight) of between about 20°C and about 60°C, in an amount of at least about 4% by weight of the composition and a conditioning amount of a cosmetically acceptable quaternary ammonium compound.
- cloud point denotes the temperature at which there is a sudden change in solubility at a given concentration (typically about 4% w/w) .
- the silicone copolyol has a cloud point of between about 20°C and about 55°C, preferably between about 23°C and about 50°C, preferably between about 27°C and about 45°C.
- the silicone copolyol is present in an amount of from about 4% to about 20%, preferably about 5% to about 10%, preferably about 6% to about 7% by weight of the composition.
- the silicone copolyol is a dimethicone copolyol, such as those available commercially under the trade names "Abil” (from T H Goldschmidt) and "Silwet” (from Union Carbide) .
- the cosmetically acceptable quaternary ammonium compound has the formula + A-, wherein R- ⁇ is g.- ⁇ g alkyl; R2 is C- ] __ 18 alkyl; R3 is c l-18 a lky3- or benzyl; R4 is C- ] __3 alkyl or benzyl; and A is an anion.
- R- j _ is - ] _o_2o alkyl, suitably C 12 -i6 alkyl, suitably C ⁇ g alkyl; R 2 to R 4 are each methyl and A is a chloride ion or a bromide ion.
- the quaternary ammonium compound is cetyl trimethyl ammonium chloride (also known under the CTFA designation "cetrimonium chloride”) cetyl trimethyl ammonium bromide, lauryl trimethyl ammonium chloride or lauryl trimethyl ammonium bromide.
- the quaternary ammonium compound is present in an amount of from about 0.5% to about 5%, preferably from about 0.5% to about 3%, suitably about 0.5% to 1% by weight of the composition.
- the silicone copolyol is chosen such that the composition undergoes a transition from clear to cloudy at or around the optimum temperature for use, thereby indicating to the user that the optimum temperature for use has been reached.
- the optimum temperature for use is from about 20°C to about 45°C.
- the composition further comprises a polymeric quaternary ammonium salt of hydroxyethyl cellulose reacted with a trimethyl ammonium substituted epoxide (also known under the CTFA designation
- preservatives may be present, such as bronopol, benzyl alcohol, imidazolidinyl urea, methyl paraben and propyl paraben, suitably in an amount of from about 0.01% to about 2% by weight of the composition.
- Thickeners and viscosity modifying agents may be present, such as amine oxides, block polymers of ethylene oxide and propylene oxide (for example, those available from BASF Wyandotte under the trade name "Pluronic"), polyvinyl alcohols and fatty alcohols, suitably in an amount of from about 0.5% to about 10% by weight of the composition.
- Sequestering agents may be present, such as ethy enediamine tetraacetic acid and salts thereof, suitably in an amount of from about 0.005 % to about 0.5% by weight of the composition.
- Perfumes may be present suitably in an amount of from about 0.01% to about 2%, as may water soluble dyes such as tartrazine, suitably in an amount of from about 0.00001% to about 0.1% by weight of the composition.
- the composition may be buffered by means well known in the art, for example by use of buffer systems comprising succinic acid, citric acid, lactic acid, phosphoric acid, mono- or disodium phosphoric and sodium carbonate.
- buffer systems comprising succinic acid, citric acid, lactic acid, phosphoric acid, mono- or disodium phosphoric and sodium carbonate.
- the composition may have a pH between about 3 and about 10, preferably between about 4 and about 6.
- the composition may also include an antidandruff agent such as salicyclic acid or zinc pyrithione suitably in an amount of from about 0.1% to about 5% by weight.
- an antidandruff agent such as salicyclic acid or zinc pyrithione suitably in an amount of from about 0.1% to about 5% by weight.
- the composition is a conditioning treatment substantially free of shampoo surfactants such as soaps and/or sulphate detergents.
- the composition finds particular application as a so called “hot oil treatment” which may be heated to a desired temperature and applied to the hair either before or after shampooing.
- the invention further provides a method of treating the hair by heating a composition as defined above, and then applying the heated composition to the hair.
- the method includes treatment with a separate shampoo product either before or after treatment with the composition, preferably after treatment.
- the composition is heated at least to the cloud point of the silicone copolyol (in water at 4% w/w) which is suitably between about 20°C and about
- the present invention also provides the use of a silicone copolyol as defined above in a hair care composition to improve substantivity to the hair.
- Polyquaternium 10 1 (available from Union Carbide under the trade name "Polymer JR 400")
- Example 1 The above composition (Example 1) was compared with a sample (Example A) having exactly the same composition except that it did not include the dimethicone copolyol .
- the two products were evaluated in a half head trial. Each trialist had their hair assessed by 10 trained evaluators for shine, feel, and control after the treatment had been applied and the hair shampooed and dried. Each evaluator assessed each of the two formulations for "shine”, “feel” and “control”, and in each case either "voted” for whichever formulation gave the better result in respect of that characteristic, or reported that there was no difference.
- Example 1 The composition of Example 1 was also compared in similar manner with a sample (Example B) having exactly the same composition except that it did not include the quaternary ammonium compound (cetrimonium chloride) .
- the mean results were as follows:- EVALUATORS' SCORES
- the figures show (for each characteristic) the relative numbers of evaluators preferring each formula and those detecting no difference.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
Une composition capillaire comprend un copolyol de silicone cosmétiquement acceptable et possédant un point de trouble d'écoulement (dans de l'eau à 4 % en poids) situé entre 20 °C et 60 °C environ, en quantité d'au moins 4 % en poids de la composition environ, ainsi qu'une quantité de conditionnement d'un composé d'ammonium quarternaire cosmétiquement acceptable.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU62064/94A AU6206494A (en) | 1993-02-26 | 1994-02-24 | Hair care compositions containing a silicone compound and a quaternary ammonium compound |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB939303889A GB9303889D0 (en) | 1993-02-26 | 1993-02-26 | Toiletries composition |
GB9303889.1 | 1993-02-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994018934A1 true WO1994018934A1 (fr) | 1994-09-01 |
Family
ID=10731072
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1994/000551 WO1994018934A1 (fr) | 1993-02-26 | 1994-02-24 | Compositions capillaires contenant un compose de silicone et un compose d'ammonium quaternaire |
Country Status (3)
Country | Link |
---|---|
AU (1) | AU6206494A (fr) |
GB (1) | GB9303889D0 (fr) |
WO (1) | WO1994018934A1 (fr) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5759527A (en) * | 1996-10-02 | 1998-06-02 | Colgate-Palmolive Company | Hair conditioning composition |
WO2000000170A1 (fr) * | 1998-06-29 | 2000-01-06 | The Procter & Gamble Company | Systeme de shampooing et traitement des cheveux par conditionneur |
FR2785799A1 (fr) * | 1998-11-12 | 2000-05-19 | Oreal | Composition cosmetique conditionnante et detergente comprenant un tensioactif carboxylique, une silicone et un polymere cationique, utilisation et procede. |
US6495498B2 (en) | 1999-05-27 | 2002-12-17 | Johnson & Johnson Consumer Companies, Inc. | Detergent compositions with enhanced depositing, conditioning and softness capabilities |
WO2017165112A1 (fr) * | 2016-03-22 | 2017-09-28 | Kao Usa, Inc. | Composition de type après-shampooing transparente |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2066659A (en) * | 1980-01-09 | 1981-07-15 | Kao Corp | Hair rinse compositions |
JPS5756413A (en) * | 1980-09-24 | 1982-04-05 | Lion Corp | Hair cosmetic |
EP0155806A2 (fr) * | 1984-03-15 | 1985-09-25 | The Procter & Gamble Company | Compositions pour le conditionnement des cheveux |
US4658839A (en) * | 1985-10-04 | 1987-04-21 | Zotos International Inc. | Hair conditioning and enhancing applicator wrap, composition and method |
JPS63188617A (ja) * | 1987-01-29 | 1988-08-04 | Shiseido Co Ltd | 透明ゲル状毛髪処理剤組成物 |
GB2211192A (en) * | 1987-12-18 | 1989-06-28 | Oreal | Composition and process for the treatment and care of the hair |
US4950468A (en) * | 1987-03-11 | 1990-08-21 | Sunstar Kabushiki Kaisha | Hair treating composition |
-
1993
- 1993-02-26 GB GB939303889A patent/GB9303889D0/en active Pending
-
1994
- 1994-02-24 AU AU62064/94A patent/AU6206494A/en not_active Abandoned
- 1994-02-24 WO PCT/EP1994/000551 patent/WO1994018934A1/fr active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2066659A (en) * | 1980-01-09 | 1981-07-15 | Kao Corp | Hair rinse compositions |
JPS5756413A (en) * | 1980-09-24 | 1982-04-05 | Lion Corp | Hair cosmetic |
EP0155806A2 (fr) * | 1984-03-15 | 1985-09-25 | The Procter & Gamble Company | Compositions pour le conditionnement des cheveux |
US4658839A (en) * | 1985-10-04 | 1987-04-21 | Zotos International Inc. | Hair conditioning and enhancing applicator wrap, composition and method |
JPS63188617A (ja) * | 1987-01-29 | 1988-08-04 | Shiseido Co Ltd | 透明ゲル状毛髪処理剤組成物 |
US4950468A (en) * | 1987-03-11 | 1990-08-21 | Sunstar Kabushiki Kaisha | Hair treating composition |
GB2211192A (en) * | 1987-12-18 | 1989-06-28 | Oreal | Composition and process for the treatment and care of the hair |
Non-Patent Citations (3)
Title |
---|
DATABASE WPI Section Ch Week 8219, Derwent World Patents Index; Class A05, AN 82-38440E * |
DATABASE WPI Section Ch Week 8837, Derwent World Patents Index; Class A06, AN 88-260481 * |
PATENT ABSTRACTS OF JAPAN vol. 12, no. 467 (C - 550) 7 December 1988 (1988-12-07) * |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5759527A (en) * | 1996-10-02 | 1998-06-02 | Colgate-Palmolive Company | Hair conditioning composition |
WO2000000170A1 (fr) * | 1998-06-29 | 2000-01-06 | The Procter & Gamble Company | Systeme de shampooing et traitement des cheveux par conditionneur |
FR2785799A1 (fr) * | 1998-11-12 | 2000-05-19 | Oreal | Composition cosmetique conditionnante et detergente comprenant un tensioactif carboxylique, une silicone et un polymere cationique, utilisation et procede. |
EP1004291A1 (fr) * | 1998-11-12 | 2000-05-31 | L'oreal | Composition conditionnante et détergente et utilisation |
US6410493B1 (en) | 1998-11-12 | 2002-06-25 | L'oreal S.A. | Conditioning and detergent composition comprising an anionic surfactant, a silicone, and a cationic polymer |
US6495498B2 (en) | 1999-05-27 | 2002-12-17 | Johnson & Johnson Consumer Companies, Inc. | Detergent compositions with enhanced depositing, conditioning and softness capabilities |
US6858202B2 (en) | 1999-05-27 | 2005-02-22 | Johnson & Johnson Consumer Companies, Inc. | Detergent compositions with enhanced depositing, conditioning and softness capabilities |
US6908889B2 (en) | 1999-05-27 | 2005-06-21 | Johnson & Johnson Consumer Companies, Inc. | Detergent composition with enhanced depositing, conditioning and softness capabilities |
WO2017165112A1 (fr) * | 2016-03-22 | 2017-09-28 | Kao Usa, Inc. | Composition de type après-shampooing transparente |
US10624835B2 (en) | 2016-03-22 | 2020-04-21 | Kao Usa, Inc. | Clear hair conditioner composition |
Also Published As
Publication number | Publication date |
---|---|
GB9303889D0 (en) | 1993-04-14 |
AU6206494A (en) | 1994-09-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5776443A (en) | Hair care compositions | |
US5049377A (en) | Hair-care composition and methods of treating hair | |
US5077040A (en) | Hair-treating microemulsion composition and method of preparing and using the same | |
US5482703A (en) | Hair conditioning compositions | |
US5338541A (en) | Dual cationic terpolymers providing superior conditioning properties in hair, skin and nail care products | |
AU656295B2 (en) | Hair care products containing N-alkoxyalkylamides | |
CA1252726A (fr) | Compositions pour le soin des cheveux | |
WO1992013829A1 (fr) | Composes quaternaires de panthenol et utilisation desdits composes | |
US20040018164A1 (en) | Hair conditioning formulation | |
US6150311A (en) | Detergent cosmetic compositions and their use | |
US5449475A (en) | Compositions for conditioning keratinous substances based on alkyl polyglycosides and their use for the washing and conditioning of hair | |
US5935560A (en) | Composition and methods of imparting durable conditioning properties to hair | |
US5139772A (en) | Hair cosmetic composition | |
EP0406887B2 (fr) | Composition cosmétique pour les cheveux | |
US6627183B1 (en) | Hair care compositions | |
EP1487398B1 (fr) | Compositions comprenant des polysiloxanes non-reticules | |
US20030133899A1 (en) | Personal cleansing compositions that contain surfactants, co-surfactants, water insoluble solids and/or liquids and cationic conditioning polymers | |
WO1994018934A1 (fr) | Compositions capillaires contenant un compose de silicone et un compose d'ammonium quaternaire | |
CA2336471C (fr) | Compositions de soins capillaires contenant des resines de polysiloxane a electrons delocalises | |
JPH08510464A (ja) | 少なくとも1種のアルキルガラクトシドウロネート型アニオン界面活性剤および少なくとも1種のアルキルポリグリコシド型および/またはポリグリセロール型ノニオン界面活性剤を含有する化粧用組成物 | |
AU623588B2 (en) | Shampoo compositions | |
JPH06192045A (ja) | 毛髪化粧料 | |
JPH04230615A (ja) | 毛髪化粧料 | |
WO1997003640A1 (fr) | Methode de coiffure utilisant des sels metalliques | |
EP1100441A1 (fr) | Compositions de soins capillaires |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AT AU BB BG BR BY CA CH CN CZ DE DK ES FI GB HU JP KP KR KZ LK LU LV MG MN MW NL NO NZ PL PT RO RU SD SE SK UA US UZ VN |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
122 | Ep: pct application non-entry in european phase | ||
NENP | Non-entry into the national phase |
Ref country code: CA |