WO1994007984A1 - Composition de detergent contenant un dispersant de savon de chaux et des lipases - Google Patents

Composition de detergent contenant un dispersant de savon de chaux et des lipases Download PDF

Info

Publication number
WO1994007984A1
WO1994007984A1 PCT/US1993/008875 US9308875W WO9407984A1 WO 1994007984 A1 WO1994007984 A1 WO 1994007984A1 US 9308875 W US9308875 W US 9308875W WO 9407984 A1 WO9407984 A1 WO 9407984A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
alkyl
detergent composition
composition according
detergent
Prior art date
Application number
PCT/US1993/008875
Other languages
English (en)
Inventor
Beatrijs Lutgrade A. De Smet
Johan Gerwin L. Pluyter
Lynda Anne Jones
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB929220343A external-priority patent/GB9220343D0/en
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to AT93922706T priority Critical patent/ATE201228T1/de
Priority to CA002145176A priority patent/CA2145176C/fr
Priority to EP93922706A priority patent/EP0662118B1/fr
Priority to DE69330230T priority patent/DE69330230T2/de
Publication of WO1994007984A1 publication Critical patent/WO1994007984A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3907—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0026—Low foaming or foam regulating compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase

Definitions

  • machine dishwashing or rinsing detergent products are free from chlorine bleaches or phosphate builder compounds.
  • spotting and filming effects are known to be a particular problem for machine dishwashing and rinsing products containing no chlorine bleach and/or no phosphate builder compound.
  • the machine dishwashing or rinsing detergent compositions of the present invention are of particular value when formulated as compositions containing no chlorine bleach and no phosphate builder compound since they provide the abovementioned mitigation of spotting and filming effects for these formulations where spotting and filming is known to be a particular problem.
  • the aluminosilicate ion exchange materials can be naturally occurring materials, but are preferably synthetically derived. A method for producing aluminosilicate ion exchange materials is discussed in US Patent No. 3,985,669. Synthetic crystalline aluminosilicate ion exchange materials are available under the designations Zeolite A, Zeolite B, Zeolite P, Zeolite X, Zeolite HS and mixtures thereof. Zeolite A has the formula
  • a lipase unit is defined as the amound of lipase which produces l umol of titratable butyric acid per minute in a pH stat, where pH is 7.0, temperature is 30°C, and substrate is an emulsion of ributyrin and gum arabic in the presence of Ca ++ and NaCl in phosphate buffer.
  • Anionic sulfonate surfactants suitable for use herein include essentially any sulfonate surfactants including, for example, the salts (eg : alkali metal salts) of C5-C2 0 linear alkylbenzene sulfonates, C -C22 primary or secondary alkane sulfonates, C 6 -C 24 olefin sulfonates, sulfonated polycarboxylic acids, alkyl glycerol sulfonates, fatty acyl glycerol sulfonates, fatty oleyl glycerol sulfonates, paraffin sulfonates, and any mixtures thereof.
  • the salts eg : alkali metal salts
  • C5-C2 0 linear alkylbenzene sulfonates C -C22 primary or secondary alkane sulfonates
  • Anionic alkyl ethoxy carboxylate surfactant Anionic alkyl ethoxy carboxylate surfactant
  • the mixed ethoxylated/propoxylated fatty alcohols have an alkyl chain length of from 10 to 18 carbon atoms, a degree of ethoxylation of from 3 to 30 and a degree of propoxylation of from 1 to 10.
  • a pholytic surfactants can be incorporated into the detergent compositions herein. These surfactants can be broadly described as aliphatic derivatives of secondary or tertiary amines, or aliphatic derivatives of heterocyclic secondary and tertiary amines in which the aliphatic radical can be straight chain or branched.
  • One of the aliphatic substituents contains at least about 8 carbon atoms, typically from about 8 to about 18 carbon atoms, and at least one contains an anionic water-solubilizing group, e.g., carboxy, sulfonate, sulfate. See U.S. Patent No. 3,929,678 to Laughlin et al., issued December 30, 1975 at column 19, lines 18-35 for examples of ampholytic surfactants.
  • the complex betaines for use herein have the formula R - (A) n - [N - (CHR ⁇ ) x ] y - N - Q (I)
  • x can be O or an integer between 1 & 6.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Enzymes And Modification Thereof (AREA)

Abstract

Compositions de lavage et de rinçage pour lave-vaisselle contenant une enzyme lipolytique active obtenue à partir d'une souche productrice de lipase de pseudomonas pseudoalcaligenes, et un dispersant de savon de chaux. Le dispersant de savon de chaux a un pouvoir de dispersion du savon de chaux inférieur ou égal à 8.
PCT/US1993/008875 1992-09-25 1993-09-20 Composition de detergent contenant un dispersant de savon de chaux et des lipases WO1994007984A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AT93922706T ATE201228T1 (de) 1992-09-25 1993-09-20 Verwendung einer kalkseifendispergator und lipasehaltige waschmittelzusammensetzung
CA002145176A CA2145176C (fr) 1992-09-25 1993-09-20 Composition detergente renfermant un dispersant a base de savon de chaux et de la lipase
EP93922706A EP0662118B1 (fr) 1992-09-25 1993-09-20 Utilisation d'une composition de detergent contenant un dispersant de savon de chaux et des lipases
DE69330230T DE69330230T2 (de) 1992-09-25 1993-09-20 Verwendung einer kalkseifendispergator und lipasehaltige waschmittelzusammensetzung

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB929220343A GB9220343D0 (en) 1992-09-25 1992-09-25 Detergent compositions
GB9220343.9 1992-09-25
EP93870170.3 1993-08-13
EP93870170 1993-08-13

Publications (1)

Publication Number Publication Date
WO1994007984A1 true WO1994007984A1 (fr) 1994-04-14

Family

ID=26134995

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1993/008875 WO1994007984A1 (fr) 1992-09-25 1993-09-20 Composition de detergent contenant un dispersant de savon de chaux et des lipases

Country Status (5)

Country Link
AT (1) ATE201228T1 (fr)
CA (1) CA2145176C (fr)
DE (1) DE69330230T2 (fr)
ES (1) ES2156586T3 (fr)
WO (1) WO1994007984A1 (fr)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995004806A1 (fr) * 1993-08-10 1995-02-16 The Procter & Gamble Company Composition pour la vaisselle a la main comprenant des lipases et un dispersant des savons de chaux
WO1997043379A1 (fr) * 1996-05-15 1997-11-20 The Procter & Gamble Company Compositions detergentes comprenant une enzyme lipolytique specifique et un dispersant a base de savon de chaux
EP0835925A2 (fr) * 1996-09-09 1998-04-15 Unilever N.V. Compositions pour lave-vaisselle contenant des polymères amphotères
US5772786A (en) * 1993-08-13 1998-06-30 The Procter & Gamble Company Detergent composition comprising lime soap dispersant and lipase enzymes
US5963658A (en) * 1997-01-27 1999-10-05 University Of North Carolina Method and apparatus for detecting an abnormality within a host medium
EP1090978A1 (fr) * 1999-10-09 2001-04-11 Cognis Deutschland GmbH, Dep. Intellectual Properties Agent de lavage, de rinçage et nettoyage solide contenant des granulats antimousse
WO2007087258A3 (fr) * 2006-01-23 2008-12-04 Procter & Gamble Composition comprenant une lipase et un catalyseur de blanchiment
US7786067B2 (en) 2006-01-23 2010-08-31 The Procter & Gamble Company Composition comprising a lipase and a bleach catalyst
US9138393B2 (en) 2013-02-08 2015-09-22 The Procter & Gamble Company Cosmetic compositions containing substituted azole and methods for improving the appearance of aging skin
US9144538B2 (en) 2013-02-08 2015-09-29 The Procter & Gamble Company Cosmetic compositions containing substituted azole and methods for alleviating the signs of photoaged skin
WO2017220422A1 (fr) * 2016-06-23 2017-12-28 Novozymes A/S Utilisation d'enzymes, composition et procédé d'élimination de salissures

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1987000859A1 (fr) * 1985-08-09 1987-02-12 Gist-Brocades N.V. Nouveaux enzymes lipolytiques et leur utilisation dans des compositions de detergents
EP0271153A2 (fr) * 1986-12-10 1988-06-15 Unilever N.V. Composition détergente à base d'enzymes
US4797223A (en) * 1988-01-11 1989-01-10 Rohm And Haas Company Water soluble polymers for detergent compositions
EP0373850A1 (fr) * 1988-12-12 1990-06-20 Unilever Plc Compositions détergentes contenant des enzymes et leur utilisation
US4959179A (en) * 1989-01-30 1990-09-25 Lever Brothers Company Stabilized enzymes liquid detergent composition containing lipase and protease
US5069809A (en) * 1988-05-09 1991-12-03 Lever Brothers Company, Division Of Conopco, Inc. Enzymatic detergent and bleaching composition containing a specific rdna technique cloned lipase
US5078898A (en) * 1987-11-02 1992-01-07 Novo Nordisk A/S Detergent compositions comprising pseudomonas lipase and a specific protease

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1987000859A1 (fr) * 1985-08-09 1987-02-12 Gist-Brocades N.V. Nouveaux enzymes lipolytiques et leur utilisation dans des compositions de detergents
EP0271153A2 (fr) * 1986-12-10 1988-06-15 Unilever N.V. Composition détergente à base d'enzymes
US5078898A (en) * 1987-11-02 1992-01-07 Novo Nordisk A/S Detergent compositions comprising pseudomonas lipase and a specific protease
US4797223A (en) * 1988-01-11 1989-01-10 Rohm And Haas Company Water soluble polymers for detergent compositions
US5069809A (en) * 1988-05-09 1991-12-03 Lever Brothers Company, Division Of Conopco, Inc. Enzymatic detergent and bleaching composition containing a specific rdna technique cloned lipase
EP0373850A1 (fr) * 1988-12-12 1990-06-20 Unilever Plc Compositions détergentes contenant des enzymes et leur utilisation
US4959179A (en) * 1989-01-30 1990-09-25 Lever Brothers Company Stabilized enzymes liquid detergent composition containing lipase and protease

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
LINFIELD, Tenside Sust. Det., Volume 27, pages 159-161 (1990). *
NAGARAJAN and MASLER, Polymeric Lime Soap Dispersants, Cosmetic and Toiletries, Volume 104, pages 71-73 (1989). *

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995004806A1 (fr) * 1993-08-10 1995-02-16 The Procter & Gamble Company Composition pour la vaisselle a la main comprenant des lipases et un dispersant des savons de chaux
US5772786A (en) * 1993-08-13 1998-06-30 The Procter & Gamble Company Detergent composition comprising lime soap dispersant and lipase enzymes
WO1997043379A1 (fr) * 1996-05-15 1997-11-20 The Procter & Gamble Company Compositions detergentes comprenant une enzyme lipolytique specifique et un dispersant a base de savon de chaux
EP0835925A2 (fr) * 1996-09-09 1998-04-15 Unilever N.V. Compositions pour lave-vaisselle contenant des polymères amphotères
EP0835925A3 (fr) * 1996-09-09 1999-01-27 Unilever N.V. Compositions pour lave-vaisselle contenant des polymères amphotères
US5963658A (en) * 1997-01-27 1999-10-05 University Of North Carolina Method and apparatus for detecting an abnormality within a host medium
EP1090978A1 (fr) * 1999-10-09 2001-04-11 Cognis Deutschland GmbH, Dep. Intellectual Properties Agent de lavage, de rinçage et nettoyage solide contenant des granulats antimousse
WO2007087258A3 (fr) * 2006-01-23 2008-12-04 Procter & Gamble Composition comprenant une lipase et un catalyseur de blanchiment
US7786067B2 (en) 2006-01-23 2010-08-31 The Procter & Gamble Company Composition comprising a lipase and a bleach catalyst
US8022027B2 (en) 2006-01-23 2011-09-20 The Procter & Gamble Company Composition comprising a lipase and a bleach catalyst
US9138393B2 (en) 2013-02-08 2015-09-22 The Procter & Gamble Company Cosmetic compositions containing substituted azole and methods for improving the appearance of aging skin
US9144538B2 (en) 2013-02-08 2015-09-29 The Procter & Gamble Company Cosmetic compositions containing substituted azole and methods for alleviating the signs of photoaged skin
WO2017220422A1 (fr) * 2016-06-23 2017-12-28 Novozymes A/S Utilisation d'enzymes, composition et procédé d'élimination de salissures
US11001787B2 (en) 2016-06-23 2021-05-11 Novozymes A/S Use of enzymes, composition and method for removing soil

Also Published As

Publication number Publication date
ES2156586T3 (es) 2001-07-01
DE69330230D1 (de) 2001-06-21
ATE201228T1 (de) 2001-06-15
DE69330230T2 (de) 2002-02-28
CA2145176C (fr) 1999-07-13
CA2145176A1 (fr) 1994-04-14

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