WO1993023150A1 - Extraction liquide de solutions aqueuses - Google Patents

Extraction liquide de solutions aqueuses Download PDF

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Publication number
WO1993023150A1
WO1993023150A1 PCT/EP1993/001217 EP9301217W WO9323150A1 WO 1993023150 A1 WO1993023150 A1 WO 1993023150A1 EP 9301217 W EP9301217 W EP 9301217W WO 9323150 A1 WO9323150 A1 WO 9323150A1
Authority
WO
WIPO (PCT)
Prior art keywords
solution
receiver
solute
extraction
membrane
Prior art date
Application number
PCT/EP1993/001217
Other languages
English (en)
Inventor
Myron J. Coplan
Aharon M. Eyal
Avraham M. Baniel
Eyal Bressler
Original Assignee
Yissum Research Development Company Of The Hebrew University Of Jerusalem
Cohn, Michael
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yissum Research Development Company Of The Hebrew University Of Jerusalem, Cohn, Michael filed Critical Yissum Research Development Company Of The Hebrew University Of Jerusalem
Publication of WO1993023150A1 publication Critical patent/WO1993023150A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/24—Dialysis ; Membrane extraction
    • B01D61/246—Membrane extraction
    • B01D61/2461—Membrane extraction comprising multiple membrane extraction steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/24—Dialysis ; Membrane extraction
    • B01D61/246—Membrane extraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0415—Solvent extraction of solutions which are liquid in combination with membranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M23/00—Constructional details, e.g. recesses, hinges
    • C12M23/34—Internal compartments or partitions
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M29/00—Means for introduction, extraction or recirculation of materials, e.g. pumps
    • C12M29/06—Nozzles; Sprayers; Spargers; Diffusers
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2319/00—Membrane assemblies within one housing
    • B01D2319/06—Use of membranes of different materials or properties within one module

Definitions

  • Direct contact extraction a liquid-liquid extraction process of the kind in which an aqueous solution and an organic extractant are intimately mixed and then allowed to separate whereby solute is transferred from the aqueous to the organic phase.
  • Indirect contact extraction an extraction process in which a solute is withdrawn from an aqueous feed solution to a receiver solution across a semi-per ⁇ meable membrane of anv kind.
  • Extraction reagent a compound capable of forming an asso ⁇ ciation product with a solute and thereby to extract such solute from an aqueous feed into a receiver solution.
  • Receiver solution a solution containing an extraction re ⁇ agent.
  • Organic receiver solution a receiver solution in which the solvent is organic.
  • Aqueous receiver solution a receiver solution in which the solvent is water.
  • the present invention is in the field of indirect contact extraction of solutes from aqueous solutions.
  • solutes e.g. electrolytes
  • Extraction of solutes, e.g. electrolytes, from aqueous solutions is required for many technological purposes such as in chemical, biotechno- logical and hydrometallurgical production and processes; for decontamina ⁇ tion of water by the removal of noxious electrolytes therefrom; for the removal of acids from reaction mixtures in the course of on-going chemical reaction or fermentation processes; and the like.
  • solutes are extracted from aqueous solutions by direct contact extraction techniques using water-immiscible organic receiver solutions.
  • the direct extraction method has the further disadvantages of being uneconomic in case of a dilute aqueous feed solution, of leading to extractant losses in consequence of inevitable dissolution, entrainment and frequent emulsification of the extractant which represents heavy expense and additionally cause contamination of the product and pollution of the extraction raffinate.
  • the entrained organic phase may also interfere with on-going reactions, e.g. by adversely affecting and inhibiting microorganisms participating in biotechnological processes such as fermentation, by denaturating proteins present in the aqueous feed solution, and the like.
  • a relatively high molecular weight extraction reagent in the receiver solution on one side of the membrane would be barred from crossing its permselective layer while a solute in the feed solution on the opposite side of the selective layer is not so barred.
  • the prior art describes methods of metal ion separation from aqueous feed utilizing a combination of high molecular weight water soluble complexants and ultrafiltration membranes, in which the complexant is added to the feed and complexes the metal ion to be separated. The water and non-complexed species are driven through the membrane concentrating the complexed ion in the feed side of the membrane (Spivakov et al., Nature, 315, 313 (1985)).
  • the association product of the extracted solute and the extraction reagent has to decompose.
  • Such decomposition may be mediated by pH changes, by displacement with another reagent, through oxidation/reduction (as known for example for uranium or iron extraction), etc.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Zoology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Microbiology (AREA)
  • General Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Genetics & Genomics (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Urology & Nephrology (AREA)
  • Biomedical Technology (AREA)
  • Sustainable Development (AREA)
  • Water Supply & Treatment (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Clinical Laboratory Science (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

Procédé d'extraction par contact indirect du type dans lequel un soluté est extrait d'une solution d'alimentation aqueuse dans une solution réceptrice à travers une membrane à perméabilité sélective, laquelle est perméable audit soluté et imperméable audit réactif d'extraction et ses produits d'association. Selon l'invention, on utilise une solution réceptrice aqueuse pour l'extraction.
PCT/EP1993/001217 1992-05-18 1993-05-14 Extraction liquide de solutions aqueuses WO1993023150A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IL101906A IL101906A0 (en) 1992-05-18 1992-05-18 Extraction of electrolytes from aqueous solutions
IL101906 1992-05-18

Publications (1)

Publication Number Publication Date
WO1993023150A1 true WO1993023150A1 (fr) 1993-11-25

Family

ID=11063632

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1993/001217 WO1993023150A1 (fr) 1992-05-18 1993-05-14 Extraction liquide de solutions aqueuses

Country Status (2)

Country Link
IL (1) IL101906A0 (fr)
WO (1) WO1993023150A1 (fr)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0652203A1 (fr) * 1994-04-07 1995-05-10 Glitsch, Inc. Procédé et l'appareillage pour la récupération d'acides carboxyliques à partir de solutions diluées
EP0725847A1 (fr) * 1993-07-12 1996-08-14 Aharon Eyal Procede de production de sels hydrosolubles d'acides carboxyliques et amines
US6001255A (en) * 1993-07-12 1999-12-14 Eyal; Aharon Process for the production of water-soluble salts of carboxylic and amino acids
WO2000066253A1 (fr) * 1999-04-29 2000-11-09 Dsm Biotech Gmbh Procede de separation de substances organiques contenues dans un melange aqueux
WO2004082812A1 (fr) * 2003-03-13 2004-09-30 3M Innovative Properties Company Systeme et procede d'extraction liquide-liquide
WO2005113119A1 (fr) * 2004-05-21 2005-12-01 Wisconsin Alumni Research Foundation Separation en cascade par membrane
US7122709B2 (en) 2003-03-13 2006-10-17 3M Innovative Properties Company Method for obtaining ethanol
GB2442941A (en) * 2006-10-21 2008-04-23 Philip Peter Monro A method for the generation of water with reduced ionic solutes
KR20120092107A (ko) * 2009-09-02 2012-08-20 헌트스만 인터내셔날, 엘엘씨 수성 흐름으로부터 메틸렌-가교된 폴리페닐 폴리아민을 제거하는 방법
US9039899B2 (en) 2011-04-25 2015-05-26 Oasys Water, Inc. Osmotic separation systems and methods
US9044711B2 (en) 2009-10-28 2015-06-02 Oasys Water, Inc. Osmotically driven membrane processes and systems and methods for draw solute recovery
US9248405B2 (en) 2009-10-28 2016-02-02 Oasys Water, Inc. Forward osmosis separation processes
US9266065B2 (en) 2009-10-30 2016-02-23 Oasys Water, Inc. Osmotic separation systems and methods
US10427957B2 (en) 2013-02-08 2019-10-01 Oasys Water LLC Osmotic separation systems and methods

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3454490A (en) * 1966-08-10 1969-07-08 Atomic Energy Commission Concentration of ions using ion selective membranes
US4306946A (en) * 1980-08-18 1981-12-22 General Electric Company Process for acid recovery from waste water
US4476025A (en) * 1983-05-09 1984-10-09 The United States Of America As Represented By The United States Department Of Energy Separation of certain carboxylic acids utilizing cation exchange membranes
EP0250666A1 (fr) * 1985-06-10 1988-01-07 The Standard Oil Company Procédé pour dialyse sélective utilisant des adsorbants polymériques d'affinité et des membranes de dimension sélective
US4789468A (en) * 1984-08-28 1988-12-06 The Trustees Of The Stevens Institute Of Technology Immobilized-interface solute-transfer apparatus
EP0458241A2 (fr) * 1990-05-25 1991-11-27 Forschungszentrum Jülich Gmbh Procédé et appareil pour la séparation d'ammonium à partir de liquides aqueux
EP0480567A1 (fr) * 1990-10-09 1992-04-15 Bend Research, Inc. Extraction aqueuse sélective de fluides organiques combinée avec épuration au moyen de membranes de séparation

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3454490A (en) * 1966-08-10 1969-07-08 Atomic Energy Commission Concentration of ions using ion selective membranes
US4306946A (en) * 1980-08-18 1981-12-22 General Electric Company Process for acid recovery from waste water
US4476025A (en) * 1983-05-09 1984-10-09 The United States Of America As Represented By The United States Department Of Energy Separation of certain carboxylic acids utilizing cation exchange membranes
US4789468A (en) * 1984-08-28 1988-12-06 The Trustees Of The Stevens Institute Of Technology Immobilized-interface solute-transfer apparatus
EP0250666A1 (fr) * 1985-06-10 1988-01-07 The Standard Oil Company Procédé pour dialyse sélective utilisant des adsorbants polymériques d'affinité et des membranes de dimension sélective
EP0458241A2 (fr) * 1990-05-25 1991-11-27 Forschungszentrum Jülich Gmbh Procédé et appareil pour la séparation d'ammonium à partir de liquides aqueux
EP0480567A1 (fr) * 1990-10-09 1992-04-15 Bend Research, Inc. Extraction aqueuse sélective de fluides organiques combinée avec épuration au moyen de membranes de séparation

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH vol. 30, no. 6, June 1991, WASHINGTON, USA pages 1231 - 1239 XINMING SHAO 'Continuous Membrane Dialysis Using Ion-Exchange Resin Suspension for Extracting Metal Ions' *
PATENT ABSTRACTS OF JAPAN vol. 12, no. 181 (C-499)27 May 1988 *

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0725847A1 (fr) * 1993-07-12 1996-08-14 Aharon Eyal Procede de production de sels hydrosolubles d'acides carboxyliques et amines
EP0725847A4 (fr) * 1993-07-12 1997-03-19 Aharon Eyal Procede de production de sels hydrosolubles d'acides carboxyliques et amines
US6001255A (en) * 1993-07-12 1999-12-14 Eyal; Aharon Process for the production of water-soluble salts of carboxylic and amino acids
EP0652203A1 (fr) * 1994-04-07 1995-05-10 Glitsch, Inc. Procédé et l'appareillage pour la récupération d'acides carboxyliques à partir de solutions diluées
US5492625A (en) * 1994-04-07 1996-02-20 Glitsch, Inc. Method of recovering carboxylic acids from dilute solutions
US5624566A (en) * 1994-04-07 1997-04-29 Glitsch, Inc. Method and apparatus for recovering carboxylic acids from dilute solutions
WO2000066253A1 (fr) * 1999-04-29 2000-11-09 Dsm Biotech Gmbh Procede de separation de substances organiques contenues dans un melange aqueux
JP2002542925A (ja) * 1999-04-29 2002-12-17 ディーエスエム ビオテック ゲーエムベーハー 水性混合物から有機物質を分離する方法
WO2004082812A1 (fr) * 2003-03-13 2004-09-30 3M Innovative Properties Company Systeme et procede d'extraction liquide-liquide
EP2404663A1 (fr) * 2003-03-13 2012-01-11 3M Innovative Properties Co. Système et procédé d'extraction liquide-liquide
US7105089B2 (en) 2003-03-13 2006-09-12 3M Innovative Properties Company Liquid—liquid extraction system and method
US7122709B2 (en) 2003-03-13 2006-10-17 3M Innovative Properties Company Method for obtaining ethanol
US7517455B2 (en) 2003-03-13 2009-04-14 3M Innovative Properties Company Liquid-liquid extraction system and method
US7141171B2 (en) 2004-05-21 2006-11-28 Wisconsin Alumni Research Foundation Membrane cascade-based separation
WO2005113119A1 (fr) * 2004-05-21 2005-12-01 Wisconsin Alumni Research Foundation Separation en cascade par membrane
GB2442941A (en) * 2006-10-21 2008-04-23 Philip Peter Monro A method for the generation of water with reduced ionic solutes
KR20120092107A (ko) * 2009-09-02 2012-08-20 헌트스만 인터내셔날, 엘엘씨 수성 흐름으로부터 메틸렌-가교된 폴리페닐 폴리아민을 제거하는 방법
KR101687437B1 (ko) 2009-09-02 2016-12-19 헌트스만 인터내셔날, 엘엘씨 수성 흐름으로부터 메틸렌-가교된 폴리페닐 폴리아민을 제거하는 방법
US9044711B2 (en) 2009-10-28 2015-06-02 Oasys Water, Inc. Osmotically driven membrane processes and systems and methods for draw solute recovery
US9248405B2 (en) 2009-10-28 2016-02-02 Oasys Water, Inc. Forward osmosis separation processes
US10315936B2 (en) 2009-10-28 2019-06-11 Oasys Water LLC Forward osmosis separation processes
US9266065B2 (en) 2009-10-30 2016-02-23 Oasys Water, Inc. Osmotic separation systems and methods
US10315163B2 (en) 2009-10-30 2019-06-11 Oasys Water LLC Osmotic separation systems and methods
US9039899B2 (en) 2011-04-25 2015-05-26 Oasys Water, Inc. Osmotic separation systems and methods
US10280097B2 (en) 2011-04-25 2019-05-07 Oasys Water LLC Osmotic separation systems and methods
US10427957B2 (en) 2013-02-08 2019-10-01 Oasys Water LLC Osmotic separation systems and methods

Also Published As

Publication number Publication date
IL101906A0 (en) 1992-12-30

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