WO1993016345A1 - Preheater for preheating air for example in a blast-furnace plant - Google Patents

Preheater for preheating air for example in a blast-furnace plant Download PDF

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Publication number
WO1993016345A1
WO1993016345A1 PCT/FI1993/000044 FI9300044W WO9316345A1 WO 1993016345 A1 WO1993016345 A1 WO 1993016345A1 FI 9300044 W FI9300044 W FI 9300044W WO 9316345 A1 WO9316345 A1 WO 9316345A1
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WO
WIPO (PCT)
Prior art keywords
preheater
heat accumulating
shaft
gas
bed
Prior art date
Application number
PCT/FI1993/000044
Other languages
French (fr)
Inventor
Olli Arpalahti
Markku ITÄPELTO
Kim Westerlund
Kurt Westerlund
Original Assignee
A. Ahlstrom Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FI920619A external-priority patent/FI920619A/en
Priority claimed from FI922420A external-priority patent/FI922420A/en
Application filed by A. Ahlstrom Corporation filed Critical A. Ahlstrom Corporation
Publication of WO1993016345A1 publication Critical patent/WO1993016345A1/en

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D17/00—Regenerative heat-exchange apparatus in which a stationary intermediate heat-transfer medium or body is contacted successively by each heat-exchange medium, e.g. using granular particles
    • F28D17/005—Regenerative heat-exchange apparatus in which a stationary intermediate heat-transfer medium or body is contacted successively by each heat-exchange medium, e.g. using granular particles using granular particles
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B9/00—Stoves for heating the blast in blast furnaces

Definitions

  • the present invention relates to a regenerative preheater of a modernized blast-furnace plant or like hot process, such as a Cowper-type preheater, of which two or more are used intermittently in a process for preheating the blast- furnace gas or like gas to be fed in the process by heating gases.
  • the preheater of the present invention comprises first and second refractory lined shafts arranged in a shell interconnected with each other.
  • the first shaft (“combustion shaft”), is provided with a gas outlet for the heated blast furnace air or like gas heated in the preheater and a gas inlet for the blast furnace gas from the blast furnace or like heating gas; and the -second shaft (“heat accumulating shaft”), is filled with a pile of heat accumulating mass, which is alternately heated with heating gas and caused to release heat to the blast furnace air or like gas being heated in a preheater.
  • the heat accumulating shaft also has a conduit for passing the cold blast furnace air or like gas to the shaft, and for exhausting cooled heating gases from the shaft.
  • Preheaters are used, for example, in the heat recovery of hot flue gases of the industry or exhaust gases usable as fuel. Preheaters heat the inlet air to desired high temperatures. At such high temperatures conventional steel heat exchangers cannot be used, but other solutions must be found. At temperatures above 1000°C heat accumulating, regenerative heat exchangers are usually used; typically a pile of refractory bricks functions as the heat accumulating mass.
  • Cowpers are heat accumulating heat exchangers, which are used in blast furnace plants for preheating blast air, i.e. blast furnace air.
  • the Cowpers are typically 30 to 40 m high towers with a diameter of up to 10 . They include two adjacent vertical shafts mounted in the same or two separate, adjacent shells. The shafts are interconnected at the top via a shaft dome.
  • blast furnace gas flowing upwards in the shaft is combusted in a narrower, so called combustion shaft in order to obtain heating gases.
  • the heating gases thus generated are supplied from the upper part of the combustion shaft via the shaft dome downwards to the heat accumulating shaft, through which the gases when flowing release heat to the pile of brickwork filling the shaft.
  • the filler usually used in the Cowper heaters are shaped bricks, like- hexagonal bricks, which have channels and grooves through the brick.
  • the -bricks are thus laid on the furnace grate forming the bottom of the heat accumulating shaft in such a way that they allow the gas flow both through the bricks and between the adjacent bricks.
  • the bricks are heated in the combustion shaft by hot gases to about 1000-1500°C.
  • the flow of the blast furnace gases is cut off by closing the valve between the blast furnace and the Cowper.
  • the air inlet valve of the Cowper is opened and cold blast air, i.e. blast furnace air, is supplied upwards through the pile of bricks, flowing in a direction opposite to the flow of the heating gases of the previous stage.
  • the bricks release heat to the air, which becomes warmer.
  • the heated air flows from the heat accumulating shaft through the combustion shaft further to the flues of the blast furnace.
  • Blast air is heated in the Cowper to about 950 - 1300°C.
  • the blast furnace plants have 3 to 5 Cowpers for one blast furnace.
  • the Cowpers run intermittently in such a way that some of them are in the heating stage and some in the air preheating, i.e. utilization, stage.
  • the number of the Cowpers used is three, whereby two of them are in the heating stage and one in the preheating stage.
  • the duration of the heating stage is about 1 - 2 hours and the preheating of air, in other words the cooling stage of the brick layer, about 30 minutes to 1 hour.
  • the preheating process it may be preferable to cut down the duration of different stages, but this possibility is limited in view of the heat exchange by the ineffective dead time of about 2-10 minutes between the stages.
  • the dead time is essentially independent of utilization time duration.
  • the change in the directions of the gas flows in a high pile of bricks takes a long time.
  • the dead time is, however, mainly due to the exchange having to take place so that fluctuation in pressure is avoided in the blast furnace.
  • the blast air must be pressurized to an appropriate pressure prior to its being introduced into the blast furnace. Because the gas space in the Cowper is large (especially in the heat accumulating shaft), its pressurization as well as the release of the pressure takes a long time, e.g. 4 - 5 minutes. It also takes time to open and close the valves.
  • the Cowpers are expensive, large plants. The great size thereof is due to their relatively small effective heat exchange area compared with their total volume. The Cowpers usually achieve only about 30 - 40 m ⁇ /m3 heat exchange area compared with the total volume of the pile of bricks.
  • US Patent 2,272,108 discloses a preheater in which the heat accumulating mass is arranged in an annular space around the combustion shaft.
  • the heat accumulating mass in a pre- heater in accordance with this patent comprises large solids instead of bricks.
  • the arrangement in accordance with this patent does not reach the level set by modern reguirements .
  • the temperature differences between the heating gas and the blast gas that are achieved thereby are too large. Therefore, its teachings are likely impractical in the modern blast furnace plants, because the temperature of the heating gas remains relatively low (often only up to about 1200°C due to, for example, the heat value of the present blast furnace gas).
  • the temperature of the blast furnace air is 1200°C or preferably even higher.
  • the purpose of the present invention is to develop an improved apparatus for preheating gases.
  • the purpose of the present invention is especially to improve the existing Cowper-preheaters, so as decrease the dead time between the heating and preheating stages and to enable the use of more freguent stages.
  • Another purpose is to improve in the existing Cowper-preheaters so that the improved apparatus is more effective and less expensive in the regenerative use than the previously known apparatuses.
  • the preheater is arranged in the shell of an existing preheater, from which the old heat accumulating mass formed (e.g. bricks) has been at least partially removed, and that a heat accumulating bed of fine-grained material is arranged as a new heat accumulating bed.
  • the ratio of heat exchange area and volume of the heat accumulating bed is higher than that of a conventional regenerative system so that the volume of the heat accumulating bed required for preheating is less than 50% of the volume of the brick pile used prior to the modernization.
  • the previously used brick pile is no longer used as a filler in the modernized preheater in accordance w-rtTi the present invention, since the effective heat exchange area of the brick pile filler is small compared with the total volume and thus requires too much space.
  • a heat accumulating bed formed of fine ⁇ grained material is used as a heat accumulating mass, which due to good heat exchange properties requires considerably less space than the previously used brick filler.
  • the old, Cowper-type preheater becomes more effective and advantageous according to the present invention, when a heat exchange bed formed of fine-grained material is used as heat accumulating mass. Due to a greater heat exchange area - volume _ratio, a heat exchange bed formed of fine- grained material requires considerably less space than the old previously used brick filler.
  • the heat exchange bed and the gas space must be disposed in such a way that at least a portion of the increase of the gas space of the preheater in the new -heat exchange bed is outside the gas space being used in the preheating process; in other words separated in a gas-tight manner from the preheating process. In this way, the advantages of the more efficient heat exchange bed may be obtained.
  • the old Cowper-preheater may simply be moderni-red, " for example, in such a way that the brick bed operating as heat accumulating mass is removed completely, or (preferably) only partially, and replaced by a heat exchange bed formed of filler solids or other fine-grained material.
  • the filler solids or the grains are, for example, having a maximum dimension of about 2 - 50 mm, so that the space required for the new heat accumulating mass in the shaft diminishes considerably from that of the previously used mass.
  • the new heat accumulating bed may simply be formed on the horizontal grate operatively associated with the upper part of the heat accumulating shaft. If so required, the heat accumulating mass or bed may also be arranged between two vertical or inclined grates, whereby the grate surface area may be made larger than the cross-sectional area of the shaft. Also, a plurality of grates may be mounted one on top of the other to increase the grate area.
  • a Cowper may be modernized with relatively slight constructive changes and the old pile of bricks may be changed to a heat accumulating mass in accordance with the present invention.
  • the lower half' - ⁇ _. the shaft may be completely closed off. This considerably diminishes the harmful empty gas space in the portion of the heat accumulating shaft which is in use.
  • the new grate may be disposed at such a height that the only space remaining at the top of the preheater is that required by the heat exchange bed and the gas space of the shaft dome interconnecting the shafts of the Cowper.
  • the height required by the heat exchange bed depends on the size and the shape of the filler solids or grains.
  • the height of the new heat exchange bed may be 5 - 50 % of the height of the previous brick filler.
  • the grate may thus be associated with the uppermost quarter of the shaft.
  • Cowpers the pressurization and depressurization of a large gas space cause a lot of dead time, which again weakens the operation of the ⁇ Cowper and its efficiency.
  • the new grate and the heat exchange bed By disposing the new grate and the heat exchange bed at the upper end of the shaft, and by separating the portion of the shaft remaining below the new grate and the distribution chamber communicating with the new grate, in a gas-tight manner, from the rest of the gas chamber of the Cowper, it is possible to diminish the excessive empty space in the shaft, and thus also minimize the dead time required by preheating.
  • the construction by which the excessive gas space is separated may be utilized, if necessary, to support the . wall between the combustion shaft and the regeneration shaft.
  • Cold blast furnace air may be introduced by an inlet conduit directly Into the distribution chamber via an opening in the wall of the Cowper, or by an inlet conduit connected to lead to the new distribution chamber through the gas space separated from the old distribution chamber in the lower part of the shaft.
  • the inlet conduits for the blast furnace air may be utilized at the same time as outlet conduits for the cooled heating gas. If so desired separate inlet and outlet conduits for air may be provided.
  • a modernized preheater in accordance with the present invention thus preferably comprises a heat exchange shaft.
  • a bed On the grate disposed in the upper part of the heat exchange shaft or between the grates arranged in the upper part of the heat exchange shaft a bed has been formed of granular material, through which hot heating gas, and gas to be preheated, alternately flow.
  • Another vertical partition wall with openings parallel to the above mentioned partition wall is mounted to the heat accumulating shaft spaced from the first partition wall in such a way that it is possible to operatively dispose an amount of heat accumulating mass appropriate for the operation of the preheater in the space formed between the partitions.
  • This heat accumulating mass forms a heat accumulating bed in the space determined by the partitions, through which heating gas and inlet air to be heated alternately flow.
  • the second partition wall may thus be manufactured, for example, of steel, since the gases flowing therethrough are either inlet air, which is relatively cool, or cooled heating gases.
  • the old Cowper may also be modernized in such a way that the partition wall between the combustion shaft and the heat accumulating shaft is also substantially completely removed and a new combustion shaft ⁇ is formed to a Cowper shell with, a lining, the new shaft being preferably coaxial with the shell.
  • the partition wall limited by the combustion shaft must be formed of refractory material, such as refractory bricks, ceramic material or, for example, of steel coated with brickwork.
  • the thus-formed new combustion shaft is surrounded by a second partition wall, which is coaxial with the combustion shaft.
  • the second partition wall may be manufactured of a material appropriate for the conditions, e.g. steel.
  • An annular space is provided with a heat accumulating bed.
  • An annular gas space is generated between the annular space filled with heat accumulating mass and the Cowper shell, through which gas space heating gas is supplied from the burner, i.e. through the second partition wall into communication with the heat accumulating mass.
  • the heat exchange material used is granular material or small-sized filler solids, for example, of size 1-50 mm, a considerably smaller heat accumulating shaft is required than what had been used with the original Cowper.
  • a new heat accumulating shaft is formed in such a way that the height thereof is typically only 5 - 50 % of the previous heat accumulating shaft.
  • the heat accumulating mass By arranging the heat accumulating mass in an annular space around the combustion shaft a heat accumulating bed is obtained, the cross-sectional area of which is large, and the layer thickness thereof relatively small. By a small layer thickness it is possible to maintain the pressure loss over the bed relatively small. An efficient heat exchange from the gas to the heat accumulating mass and vice versa is on the other hand ensured by a great cross-section of the bed, regardless of the small layer thickness.
  • the thickness of the heat exchange bed depends on the size and shape of the filler solids or grains used therein.
  • the thickness of the new heat accumulating bed is typically 5 - 50% of the height of the earlier used brick layer.
  • a heat exchange area/total volume ratio of about 360m 2 /m 3 is achieved with a bed formed of 10 mm pebbles.
  • the heat exchange area depends on the size of the pebbles. The above mentioned ratio is 720m 2 /m 3 with 5 mm pebbles.
  • the heat accumulating bed in an apparatus in accordance with the present invention may be formed, for example, of pebbles, the diameter of which is preferably less than 10 mm.
  • the bed material may thus be manufactured, for example, of material used for the production of refractory bricks, which is also appropriate for heat exchange.
  • the amount heat accumulating mass volume required is — due to an advantageous heat exchange surface area/volume ratio — considerably smaller than when using a conventional high pile of bricks as a filler, although the capacity of the preheater remains the same.
  • the small granular size of the bed material enables a sufficiently efficient heat exchange also in a low bed.
  • the height of the bed is usually about 30 m.
  • the height of a bed in accordance with the present invention is on a horizontal 30m 2 grate typically 2 - 8 m.
  • a heat accumulating bed of less than 15 m is sufficient.
  • a bed formed of granular material or loose solids typically generates a higher flow resistance than, for example, a heat accumulating pile of bricks of the same height.
  • a higher flow resistance is easily avoided in the apparatus in accordance with the present invention, however, by forming the bed operating as the heat exchange medium with a relatively smaller height/diameter ratio than a pile of bricks with a corresponding efficiency, so that the flow resistance in the bed diminishes respectively.
  • a heat exchange area is achieved with a smaller bed mass, which is as large as that achieved with a great pile of bricks in the Cowper.
  • the pressure difference in the heat accumulating bed in accordance with the present invention easily becomes even smaller than in the conventional heat exchangers with a brick filler/layer.
  • the decrease of the pressure difference by 5 kPa in a gas flow of 100 000 m 3 n/h means about 300000 FIM annual savings.
  • the bed material in the apparatus may be heated as close to the temperature of the heated gases as possible and respectively, the gases to be preheated to a higher temperature than what is achieved with the same amount and content of fuel with the Cowper.
  • the gas to be preheated may be heated to a temperature, which is only about ten degrees for example 10-20 °C, from the temperature of the heating gas .
  • the preheater in accordance with the present invention enables a preferred method of modernizing an old Cowper by a small heat accumulating bed, which is readily cleaned.
  • the plant has, for example, four preheaters for blast furnace it is possible to run the blast furnace plant continuously in full power with three preheaters and contemporarily to arrange the modernization of one preheater according to the present invention without disturbing the main process.
  • the blast furnace dust may be removed from the preheater, for example, once a year, so that the beds of the pre- heaters are changed to a clean bed material one after another.
  • the fouled pebbles or other loose solids of the bed are removed from the apparatus, for example, to a truck and conveyed away to be cleaned.
  • the cleaned pebbles are used later in the next preheater when changing its bed material during maintenance. An efficient heat exchange and a small pressure loss is thus secured in the preheaters.
  • FIG. 1 is a schematic vertical sectional view of an exemplary modernized preheater in accordance with the present invention
  • Fig. 2 is a cross-sectional view of the apparatus of Fig. 1 taken along line AA thereof;
  • Fig. 3 is a cross-sectional view of the apparatus of Fig. 1 along line BB thereof;
  • Fig. 4 is a vertical sectional view of a second exemplary modernized preheater in accordance with the invention;
  • Fig. 5 is a cross-sectional view of the apparatus of Fig. 4 along line AA thereof;
  • Figs. 6 - 8 are vertical sectional views of other exemplary embodiments of moderninized preheaters in accordance with the invention.
  • Fig. 9 is a vertical sectional view of a modernized preheater in accordance with the present invention.
  • Figs. 1, 2 and 3 illustrate a Cowper-type modernized preheater 10 for air in a blast furnace plant, the pre ⁇ heater comprising a tower-like steel shell construction 12 with a brick work lining 14 on the inside.
  • the tower-like construction comprises two shafts, 16 and 18.
  • the lower part of the narrow shaft 16 is provided with an inlet conduit 20 for blast furnace gas and an inlet conduit 22 for combustion air.
  • a gas burner 24 is mounted to communicate with the gas conduits 20, 22, and to combust the blast furnace gas with the combustion air in order to raise the temperature of the gas and to form a heating gas.
  • An outlet conduit 26 for heated blast furnace air is disposed above the gas burner 24.
  • the narrow shaft 16 communicates at its upper part with a gas space 28 of a shaft dome, connecting the narrow shaft 16 to the wider heat accumulating shaft 18.
  • the heat accumulating shaft 18 has an old distribution chamber 32 and an old grate 34 as well as a conduit 38 connected to the opening 36 in the distribution chamber 32.
  • the conduit 38 operates as an outlet conduit for the heating gas from burner 24, and as an inlet conduit for the cold blast furnace air.
  • the heat accumulating shaft 18 is provided with a new grate 40 and with a new distribution chamber 42 therebelow in the uppermost quarter of shaft 18, above the old grate 34.
  • the grate 40 supports a granular heat accumula-tr ⁇ _g bed 44 operating as heat accumulating mass.
  • the upper surface of the heat accumulating bed 44 extends to within close proximity of the top 49 of the partition wall 50 between the shafts 16, 18.
  • the space 46 between the old grate 34 and the new distribution chamber 42 is provided with a gas-tight wall 48.
  • the wall 48 supports the wall 50 between the shafts 16, 18.
  • An opening 52 is formed to the new distribution chamber 42, the opening 52 communicating with a conduit 54 so that cold blast furnace air may be introduced into the distribution chamber 42, or so that cooled heating gases may be exhausted from the preheater 10. It is, of course, possible to use different conduits for feeding blast furnace air and removing cooled heating gases.
  • the wider shaft 18 is provided with a connecting pipe 56 for cold blast furnace air and cooled heating gas, connecting the old distribution chamber 32 to the new distribution chamber 42.
  • the connecting pipe 56 leads through the separated gas space 46.
  • a modernized preheater for a blast furnace plant in accordance with Fig. 1 operates in such a way that blast furnace air and combustion air are supplied via conduits 20 and 22 to the lower part of the narrow shaft 16, through which either atmospheric or pressurized gases are introduced into the gas burner 24.
  • the blast furnace gases burn and form a hot heating gas of 1200 - 1700°C, which flows to the top of the narrow shaft and further through gas space 28 to the heat accumulating shaft 18.
  • the heating gas flows through the heat accumulating bed 44, releasing heat to the heat accumulating mass formed of granular material.
  • the heating gases cooled to the temperature of 150-400°C through grate 40, flow to the distribution chamber 42, from which the gases flow out through conduit 54 or in the connecting pipe 56 to the old distribution chamber 32, and therefrom are discharged through opening 36 and conduit 38.
  • the heat accumulating mass 44 is heated with the heating gases for about 30 minutes, so that the upper surface of the bed material almost reaches the inlet temperature of about 1200 - 1700°C of the heating gas, after which the inlet 20 of blast furnace gas to said preheater 10 is closed.
  • the increase in temperature depends on the composition of the gas.
  • the feed of the cold blast furnace air to upper part of the heat accumulating shaft 18 begins at a temperature of about 50 - 200°C and at an overpressure of about 0.5 - 4 bar through conduits 54 and/or 38.
  • Cold blast furnace air flows through grate 40 and heat accumulating bed 44 to the top of the shaft 18, thereby heating almost to the temperature of the heat accumulating material 44.
  • the heated blast furnace air which may be for example oxygen-enriched air, flows from the gas space 28 connecting the shafts 16, 18 downwardly in the narrow shaft 16 towards the discharge conduit 26, from which -- after about a minute so that the pressure has increased sufficiently that it may be supplied as blast air to the flues of the blast furnace (not shown) -- it is discharged.
  • the heat accumulating bed may be postioned between two vertical grates. Even very large vertical grates may be disposed in the old heat accumulating shaft 18.
  • Figs. 4 and 5 illustrate a preheater 110 modernized with vertical grat-es ..according to the present invention, in which the flow of the heating gas and the air to be heated through the heat accumulating bed 144 located between two vertical grates is horizontal.
  • Figs. 4 and 5 use three-digit reference numbers, in which the first digit is one and the last two digits correspond to the reference numbers used for the corresponding parts of the apparatus in Figs. 1 - 3, when possible.
  • the heat accumulating bed 144 in the preheater in accordance with Fig. 4 is provided in the upper part 119 of the heat accumulating shaft 118 between the grates 140 and 41.
  • the grate 41 on the hot side is manufactured of perforated ceramic mass, which endures the temperature of the heating gases.
  • the grate 41 on the hot side is built preferably on the old partition wall 150, which in the Cowper unit separates the gas combustion shaft 116 and the heat accumulating shaft 118 from each other.
  • the second grate 140 mounted on the cold side may be manufactured, for example, of perforated steel plate.
  • the heat accumulating bed 144 is formed in the upper part of the Cowper . . in a volume from which the old heat accumulating pile of bricks is removed.
  • the old grate 134 and a portion of the old brick pile 133 thereon are left below the upper part 119 of the heat accumulating shaft 118.
  • the remaining pile of bricks is separated by an inter ⁇ mediary floor 35, which separates the upper part 119 of the operating heat accumulating shaft from the. pile 133 in a gas-tight manner.
  • a ceiling plate 51 extending over the cross-section of the whole old Cowper is mounted above the heat accumulating bed 144, so that the flow from above from the heat accumulating shaft 118 past the bed 144 to the combustion shaft 116 is prevented.
  • the ceiling plate 51 is preferably mounted in such a way that the empty space 53 thereabove is separated in a gas-tight manner from the space below it. In addition to being gas-tight, the ceiling 51 also must be pressure resistant over long periods of time.
  • Fig. 6 illustrates a third modernized preheater 210 in accordance with the present invention.
  • the reference numbers in the drawing correspond to the two digit numbers, only preceded by a "2" in Figs. 4 and 5.
  • the heat accumulating bed 244 is also arranged between two grates 240 and 241.
  • the grate 240 is inclined in such a way that the horizontal cross-sectional area of the bed 244 is larger in the upper part of the bed than in the lower part thereof.
  • the thickness of the bed may thus be utilized to affect the distribution of the gas flowing through the heat accumulating bed 244.
  • the characteristics of the heat accumulating bed 244 may also be affected by forming the bed 244 of two or more different materials, for example, grains of different size and shape.
  • two separate zones 244 and 45 in which the shapes and quality of the solids are different, are provided between the grates 240, 241.
  • the lower zone 244 is formed of solids A and the higher zone 24 of solids B.
  • Different zones in the heat accumulating bed may also be provided in the other embodiments.
  • two vertical zones may be formed, if required, between the grates.
  • a bed material may be chosen on the hot side, in which the pressure difference becomes higher than on the cold side, the effect of which material on the growth of the pressure difference is smaller than that of the bed material chosen on the cold side.
  • Fig. 7 illustrates a fourth modernized preheater 310 in accordance with the invention.
  • Two digit reference numbers in accordance with the previous drawings are used in Fig. 7, preceded by a "3".
  • the embodiment in accordance with Fig. 7 the embodiment of Fig. 1 (in which the heat accumulating bed is arranged on a horizontal grate) is supplemented with a vertically positioned bed portion in accordance with Fig. 4, so that the total flow cross-sectional surface" of the bed may be increased and at the same time the thickness and pressure loss thereof diminished according to the dimensioning requirements of any given situation.
  • the upper part of the heat accumulating shaft 318 is provided on the one hand with a horizontal grate 340 and a horizontal heat accumulating bed 344 on top of the-grate 340, and on the other hand with two vertical grates 341 and 39, with a vertical heat accumulating bed 43 therebetween.
  • a portion of the gas flowing into the distribution chamber 342 is supplied through the horizontal grate 340 into contact with a horizontal heat accumulating bed 344 and further through the gas space 328 of the shaft dome 328 downwardly to the combustion shaft 316.
  • a second portion of the gas flowing to the distribution chamber 342 is supplied through the first vertical grate 39 into contact with the vertical heat accumulating bed 43 and further thorough the second vertical grate 341 to the narrow shaft 316, in which both preheated gas flows are joined.
  • the cross-sectional area of the heat accumulating bed may be increased compared with the embodiment in accordance with Fig. 1, which is advantageous when striving for a small pressure loss.
  • a ceiling plate e.g. 51 in Fig. 4
  • the same two digit reference numerals are used as in the other embodiments, and preceded by a "4".
  • the aim is to increase the cross-sectional area of the heat accumulating bed by dividing the bed using two grates 439 and 440 positioned on two different levels.
  • the gas flowing through the upper grate 440 and bed 444 flows through shaft dome 428 to the combustion shaft 416.
  • the gas flowing through the lower grate 439 and bed 443 flows through opening 451 formed in the wall 450 to the combustion shaft 416.
  • Gas may be supplied from the lower bed also through a separate channel, not shown in the drawing, via the upper distribution chamber 442, grate 440 and bed 444 to the shaft dome 428, whereby an opening in the partition wall 450 is no longer necessary.
  • Fig. 9 illustrates a fifth modernized preheater 510 in accordance with the invention.
  • the same two digit reference numbers have been used as in Fig. 4, and then preceded by a "5".
  • Fig. 9 illustrates a modernized Cowper-type preheater 510 for air, comprising a tower-like steel shell construction 512 with a brick work lining 514 on the inside.
  • the partition wall, which the preheater previously had, has been removed and the pile of brick filler has also been removed.
  • the tower-like construction has been divided in the mod- ernization by an intermediary floor 61 into an upper part 62 and a lower part 63.
  • the upper part 62 is left empty, and it may be pressurized, if necessary, to a desired pressure, so that the construction of the intermediary floor 61 does not have to be as strong as in the case when the separated upper part is maintained at the pressure of the surroundings.
  • the walls 512 of the upper part 61 may be supported by an additional brickwork, for example, with a sprayable mass.
  • the empty upper part 61 may also be completely removed.
  • the lower part 63 of the preheater 510 is provided with a cylindrical combustion shaft 64 and a heat accumulating shaft 65 therearound, which consists of two annular spaces 66 and 67.
  • the innermost annular space 66 is provided with a heat accumulating bed 544 formed of granular material.
  • the combustion shaft 64 is essentially coaxial with the steel shell 512 and the cylindrical middle part thereof is limited to a vertical cylindrical wall 69, which is provided with openings 70.
  • the wall 69 thus forms a grate construction.
  • the wall 69 is formed of refractory, for example ceramic, material.
  • the lower.part of the combustion shaft 64 is provided with a gas burner 524, communicating with an inlet conduit 520 for blast furnace gas and an inlet conduit 522 for air.
  • the upper part of the combustion shaft 64 is provided with an outlet conduit 552.
  • Each of the inlet conduits 520, 522 for blast furnace gas and air, and the outlet conduit 552 for the preheated air, are provided with a valve for opening and closing the conduits (the valves are not shown in the drawings) .
  • the annular space 66 closest to the combustion shaft 64 of the heat accumulating shaft 65 is determined by a first wall 69 and a second wall 72.
  • the second wall 72 is manufactured, for example, of a perforated steel plate, strong fine steel mesh, or like heat-resisting material appropriate for a grate plate.
  • the perforations 73 in the steel plate may typically be round or of the shape of a narrow slot, of the size, e.g. 2x200 mm.
  • a heat accumulating bed 544 of granular material or, for example, of small pebbles, is arranged between the grates formed by grates/walls 69 and 72.
  • the maximum dimensions of the grains may be only about 2 - 10 mm, and the openings/perforations of the grates are, of course, to be dimensioned such that the heat accumulating mass 544 does not pass through them.
  • the heat accumulating bed 544 may be formed, on the other hand, also of larger solids, for example, of steel balls, the diameter of which may be up to about 50 mm.
  • the outlet conduit 526 for cooled blast furnace gas and the inlet conduit 74 for cold air or air to be preheated are mounted to the outermost annular space 67 of the heat accumulating shaft 65.
  • the conduits 74, 526 are also provided with valves for opening and closing the conduits, (the valves are not shown in the drawing) .
  • the preheater 510 of the blast furnace plant in accordance with Fig. 9 operates in such a way that blast furnace gas and combustion air are supplied by conduits 520 and 522 to the gas burner 524, by which heating gas of about 1200 - 1700°C is generated. Heating gas flows to the combustion shaft 64.
  • the valve of outlet conduit 552 is closed, so that hot gases flow through the openings 70 of the first partition wall 69 to the annular space 66 of the heat accumulating shaft 65 releasing heat to the heat accumulating mass 544.
  • the valves for the blast furnace gas and combustion gas conduits 520, 522 as well as the valve of the gas outlet conduit 552, are closed and the valve in the inlet conduit 74 for air is opened, from which the pressurized inlet air of about 50 - 200°C is admitted, at an overpressure of about 0.5 - 4 bar to the outermost part of the preheater 510.
  • the inlet air may be oxygen-enriched gas.
  • the valve of the outlet conduit 552 for preheated air is opened, so that air begins to flow through the openings of the second partition wall 72, heat accumulating ⁇ bed 544 and the openings 70 of the first partition wall 69 to the combustion shaft 64 and further to the flues of the blast furnace.
  • the temperature of the air almost reaches " that of the heat accumulating bed.
  • the inlet and outlet conduits 74, 552 for air are closed and the inlet conduits 520, 522 for blast furnace gas and combustion air are reopened and heating gas is formed to reheat the heat accumulating bed 544.
  • the apparatus in accordance with the present invention may be pressurized, and it is preferably used continuously pressurized. Thereby the blast furnace gases are supplied pressurized to the burner and further therefrom as heating gases to the pressurized heat accumulating shaft without a need to decrease the pressure in the preheater between the blast stage and the heating stage.
  • the heat exchange from the blast furnace gases to the bed is intensified considerably.
  • a pressurized heat exchange to the blast is efficient.
  • the pressure of the blast may be 3 - 5 bar. Due to this pressurization, the duration of both the heating and preheating stages may be shortened. Moreover, the dead times diminish considerably when the pressurization and the pressure relief stages are completely left out or at least shortened considerably. Also, by pressurizing the heating stage also pressure strokes, which are common in conventional preheaters due to the pressure fluctuation, are avoided in the blast furnace.
  • the invention may be applied to such preheaters, in which the combustion shaft and the heat accumulating shaft are mounted into separate, adjacent shell constructions interconnected at the top.

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Abstract

The present invention relates to a regenerative preheater of a modernized blast-furnace plant or like hot process, such as a Cowper-type preheater. The inventive preheater is mounted to the shell of the old preheater from which the old heat accumulating mass (e.g. bricks) is at least partially removed. The heat accumulating shaft is provided with a heat accumulating bed formed of fine-grained material, the ratio of heat exchange area and volume of which is greater than that of a conventional regenerative preheater. The modernized preheater in accordance with the invention no longer has the previously used brick filler, so that the gas space is disposed in such a way that at least a portion of the increase of the gas space in the preheater gained in the removal of the old brick filler, and replacement to new heat exchange bed, is outside the gas space utilized in the preheating process (e.g. separated in a gas-tight manner from the preheating process).

Description

PREHEATER FOR PREHEATING AIR FOR EXAMPLE IN A BLAST-FURNACE PLANT
BACKGROUND & SUMMARY
The present invention relates to a regenerative preheater of a modernized blast-furnace plant or like hot process, such as a Cowper-type preheater, of which two or more are used intermittently in a process for preheating the blast- furnace gas or like gas to be fed in the process by heating gases. The preheater of the present invention comprises first and second refractory lined shafts arranged in a shell interconnected with each other. The first shaft ("combustion shaft"), is provided with a gas outlet for the heated blast furnace air or like gas heated in the preheater and a gas inlet for the blast furnace gas from the blast furnace or like heating gas; and the -second shaft ("heat accumulating shaft"), is filled with a pile of heat accumulating mass, which is alternately heated with heating gas and caused to release heat to the blast furnace air or like gas being heated in a preheater. The heat accumulating shaft also has a conduit for passing the cold blast furnace air or like gas to the shaft, and for exhausting cooled heating gases from the shaft.
Preheaters are used, for example, in the heat recovery of hot flue gases of the industry or exhaust gases usable as fuel. Preheaters heat the inlet air to desired high temperatures. At such high temperatures conventional steel heat exchangers cannot be used, but other solutions must be found. At temperatures above 1000°C heat accumulating, regenerative heat exchangers are usually used; typically a pile of refractory bricks functions as the heat accumulating mass.
For example, Cowpers are heat accumulating heat exchangers, which are used in blast furnace plants for preheating blast air, i.e. blast furnace air. The Cowpers are typically 30 to 40 m high towers with a diameter of up to 10 . They include two adjacent vertical shafts mounted in the same or two separate, adjacent shells. The shafts are interconnected at the top via a shaft dome. In the heating stage blast furnace gas flowing upwards in the shaft is combusted in a narrower, so called combustion shaft in order to obtain heating gases. The heating gases thus generated are supplied from the upper part of the combustion shaft via the shaft dome downwards to the heat accumulating shaft, through which the gases when flowing release heat to the pile of brickwork filling the shaft. There may be hundreds, even thousands of tons of bricks in the shaft.
The filler usually used in the Cowper heaters are shaped bricks, like- hexagonal bricks, which have channels and grooves through the brick. The -bricks are thus laid on the furnace grate forming the bottom of the heat accumulating shaft in such a way that they allow the gas flow both through the bricks and between the adjacent bricks.
In the heating stage the bricks are heated in the combustion shaft by hot gases to about 1000-1500°C. After the heating stage the flow of the blast furnace gases is cut off by closing the valve between the blast furnace and the Cowper. In the next stage (called the "preheating" or "utilization" stage), the air inlet valve of the Cowper is opened and cold blast air, i.e. blast furnace air, is supplied upwards through the pile of bricks, flowing in a direction opposite to the flow of the heating gases of the previous stage. The bricks release heat to the air, which becomes warmer. The heated air flows from the heat accumulating shaft through the combustion shaft further to the flues of the blast furnace. Blast air is heated in the Cowper to about 950 - 1300°C.
Usually the blast furnace plants have 3 to 5 Cowpers for one blast furnace. The Cowpers run intermittently in such a way that some of them are in the heating stage and some in the air preheating, i.e. utilization, stage. Often the number of the Cowpers used is three, whereby two of them are in the heating stage and one in the preheating stage. The duration of the heating stage is about 1 - 2 hours and the preheating of air, in other words the cooling stage of the brick layer, about 30 minutes to 1 hour. For the preheating process it may be preferable to cut down the duration of different stages, but this possibility is limited in view of the heat exchange by the ineffective dead time of about 2-10 minutes between the stages. The dead time is essentially independent of utilization time duration.
The change in the directions of the gas flows in a high pile of bricks takes a long time. The dead time is, however, mainly due to the exchange having to take place so that fluctuation in pressure is avoided in the blast furnace. The blast air must be pressurized to an appropriate pressure prior to its being introduced into the blast furnace. Because the gas space in the Cowper is large (especially in the heat accumulating shaft), its pressurization as well as the release of the pressure takes a long time, e.g. 4 - 5 minutes. It also takes time to open and close the valves.
The Cowpers are expensive, large plants. The great size thereof is due to their relatively small effective heat exchange area compared with their total volume. The Cowpers usually achieve only about 30 - 40 m}/m3 heat exchange area compared with the total volume of the pile of bricks.
US Patent 2,272,108 discloses a preheater in which the heat accumulating mass is arranged in an annular space around the combustion shaft. The heat accumulating mass in a pre- heater in accordance with this patent comprises large solids instead of bricks. However, the arrangement in accordance with this patent does not reach the level set by modern reguirements . For example, the temperature differences between the heating gas and the blast gas that are achieved thereby are too large. Therefore, its teachings are likely impractical in the modern blast furnace plants, because the temperature of the heating gas remains relatively low (often only up to about 1200°C due to, for example, the heat value of the present blast furnace gas). On the other hand, the temperature of the blast furnace air is 1200°C or preferably even higher. This leads to even smaller temperature differences between heating gas and blast gas. By using the method given in this patent the temperature" difference remains too high and by using the suggested apparatus it might be necessary to utilize an even bigger construction than a Cowper-preheater. Sufficient blast air temperatures are not achieved by an arrangement in accordance with US 2,272,108 by using a heat accumulating mass of a reasonable amount.
The purpose of the present invention is to develop an improved apparatus for preheating gases.
The purpose of the present invention is especially to improve the existing Cowper-preheaters, so as decrease the dead time between the heating and preheating stages and to enable the use of more freguent stages.
Furthermore, another purpose is to improve in the existing Cowper-preheaters so that the improved apparatus is more effective and less expensive in the regenerative use than the previously known apparatuses.
In achieving the above mentioned objects, it is characteristic of the modernized preheater in accordance with the present invention that the preheater is arranged in the shell of an existing preheater, from which the old heat accumulating mass formed (e.g. bricks) has been at least partially removed, and that a heat accumulating bed of fine-grained material is arranged as a new heat accumulating bed. The ratio of heat exchange area and volume of the heat accumulating bed is higher than that of a conventional regenerative system so that the volume of the heat accumulating bed required for preheating is less than 50% of the volume of the brick pile used prior to the modernization.
The previously used brick pile is no longer used as a filler in the modernized preheater in accordance w-rtTi the present invention, since the effective heat exchange area of the brick pile filler is small compared with the total volume and thus requires too much space. According to the present invention a heat accumulating bed formed of fine¬ grained material is used as a heat accumulating mass, which due to good heat exchange properties requires considerably less space than the previously used brick filler. By utilizing a preheater in accordance with the present invention it may be possible to more advantageously gain heat from the hot gases, such as blast furnace gases, for preheating inlet air [for example, blast air of the blast furnace plant] .
Considerable savings in energy are obtained by the invention compared with the conventional Cowper since the total pressure difference over the preheater decreases decisively due to the thin heat accumulating bed having a large cross- sectional area.
The old, Cowper-type preheater becomes more effective and advantageous according to the present invention, when a heat exchange bed formed of fine-grained material is used as heat accumulating mass. Due to a greater heat exchange area - volume _ratio, a heat exchange bed formed of fine- grained material requires considerably less space than the old previously used brick filler. However, in order to be able to utilize the advantages gained by such an enhanced efficiency heat exchange bed, the heat exchange bed and the gas space must be disposed in such a way that at least a portion of the increase of the gas space of the preheater in the new -heat exchange bed is outside the gas space being used in the preheating process; in other words separated in a gas-tight manner from the preheating process. In this way, the advantages of the more efficient heat exchange bed may be obtained.
According to a preferred embodiment of the present invention the old Cowper-preheater may simply be moderni-red," for example, in such a way that the brick bed operating as heat accumulating mass is removed completely, or (preferably) only partially, and replaced by a heat exchange bed formed of filler solids or other fine-grained material. In this heat exchange bed the filler solids or the grains are, for example, having a maximum dimension of about 2 - 50 mm, so that the space required for the new heat accumulating mass in the shaft diminishes considerably from that of the previously used mass.
The new heat accumulating bed may simply be formed on the horizontal grate operatively associated with the upper part of the heat accumulating shaft. If so required, the heat accumulating mass or bed may also be arranged between two vertical or inclined grates, whereby the grate surface area may be made larger than the cross-sectional area of the shaft. Also, a plurality of grates may be mounted one on top of the other to increase the grate area.
In the old Cowpers the pile of bricks must be renewed every now and then due to the impurities accumulated therein which decrease the permeability of the gas and increase the pressure loss. According to the invention, a Cowper may be modernized with relatively slight constructive changes and the old pile of bricks may be changed to a heat accumulating mass in accordance with the present invention.
When a new grate, on which a layer of new heat accumulating mass, which is considerably thinner than the brick filler layer, is mounted to the upper half of the old shaft, the lower half' -©_. the shaft may be completely closed off. This considerably diminishes the harmful empty gas space in the portion of the heat accumulating shaft which is in use. The new grate may be disposed at such a height that the only space remaining at the top of the preheater is that required by the heat exchange bed and the gas space of the shaft dome interconnecting the shafts of the Cowper. The height required by the heat exchange bed depends on the size and the shape of the filler solids or grains. The height of the new heat exchange bed may be 5 - 50 % of the height of the previous brick filler. The grate may thus be associated with the uppermost quarter of the shaft. In the presently' used Cowpers the pressurization and depressurization of a large gas space cause a lot of dead time, which again weakens the operation of the~Cowper and its efficiency.
In the modernized Cowpers shorter heat exchange cycles may be reached -- due to the new heat exchange mass -- and thus the relative amount of the harmful dead time increases, unless the empty space is eliminated by arranging the heat exchange bed into an as small space as possible (for example, in the upper part of the heat exchange shaft) .
By disposing the new grate and the heat exchange bed at the upper end of the shaft, and by separating the portion of the shaft remaining below the new grate and the distribution chamber communicating with the new grate, in a gas-tight manner, from the rest of the gas chamber of the Cowper, it is possible to diminish the excessive empty space in the shaft, and thus also minimize the dead time required by preheating. Thus according to the- present invention it is possible, for example, to separate the entire gas space which remains between the old grate and the new distribution chamber. The construction by which the excessive gas space is separated may be utilized, if necessary, to support the. wall between the combustion shaft and the regeneration shaft. If so desired it is possible to leave a portion of the old bricks of the regeneration shaft to support the new distribution chamber, the new grate, and the new heat exchange bed. Consequently it is necessary to remove only the upper layers of the brick material in the modernization, in other words only to the extent required by the distribution chamber, the grate, and the heat exchange bed. This procedure is often the simplest practical procedure.
Cold blast furnace air may be introduced by an inlet conduit directly Into the distribution chamber via an opening in the wall of the Cowper, or by an inlet conduit connected to lead to the new distribution chamber through the gas space separated from the old distribution chamber in the lower part of the shaft. The inlet conduits for the blast furnace air may be utilized at the same time as outlet conduits for the cooled heating gas. If so desired separate inlet and outlet conduits for air may be provided.
A modernized preheater in accordance with the present invention thus preferably comprises a heat exchange shaft. On the grate disposed in the upper part of the heat exchange shaft or between the grates arranged in the upper part of the heat exchange shaft a bed has been formed of granular material, through which hot heating gas, and gas to be preheated, alternately flow.
According to another embodiment of the invention it is possible to modernize an old Cowper-type preheater simply in such a way that the pile of bricks operating as a heat accumulating mass therein is, practically speaking, removed completely, and the upper part of the preheater is separated by a horizontal gas-tight ceiling from the lower part of the preheater. The old partition wall between the lower parts of the combustion and heat accumulating shafts is provided, with openings, thus providing a gas communication between the shafts. The openings must be small enough to prevent the heat accumulating mass from being conveyed to the combustion shaft. Another vertical partition wall with openings parallel to the above mentioned partition wall is mounted to the heat accumulating shaft spaced from the first partition wall in such a way that it is possible to operatively dispose an amount of heat accumulating mass appropriate for the operation of the preheater in the space formed between the partitions. This heat accumulating mass forms a heat accumulating bed in the space determined by the partitions, through which heating gas and inlet air to be heated alternately flow. The second partition wall may thus be manufactured, for example, of steel, since the gases flowing therethrough are either inlet air, which is relatively cool, or cooled heating gases.
The old Cowper may also be modernized in such a way that the partition wall between the combustion shaft and the heat accumulating shaft is also substantially completely removed and a new combustion shaft~is formed to a Cowper shell with, a lining, the new shaft being preferably coaxial with the shell. The partition wall limited by the combustion shaft must be formed of refractory material, such as refractory bricks, ceramic material or, for example, of steel coated with brickwork. The thus-formed new combustion shaft is surrounded by a second partition wall, which is coaxial with the combustion shaft. The second partition wall may be manufactured of a material appropriate for the conditions, e.g. steel. An annular space is provided with a heat accumulating bed. An annular gas space is generated between the annular space filled with heat accumulating mass and the Cowper shell, through which gas space heating gas is supplied from the burner, i.e. through the second partition wall into communication with the heat accumulating mass. In this arrangement, in which the heat exchange material used is granular material or small-sized filler solids, for example, of size 1-50 mm, a considerably smaller heat accumulating shaft is required than what had been used with the original Cowper.
Further, a new heat accumulating shaft is formed in such a way that the height thereof is typically only 5 - 50 % of the previous heat accumulating shaft. When the new grates, between which the new, considerably thinner layer of, heat accumulating mass is provided at the lower part of the old Cowper shell, it is possible to completely close off the upper part of the shell so that the upper part is left empty. It may, if so required, be pressurized so that the structure forming the intermediate floor does not have to be as strong as in the case when the separated upper part is maintained at the pressure of the surroundings. The upper part now remaining empty may, of course, also be removed completely. This again considerably decreases the harmful empty gas space in the heat accumulating shaft portion being used. In the modernized Cowpers, in which shorter heat exchange cycles are possible due to the new heat exchange mass, the relative share of the harmful dead time would increase, if it was not possible to eliminate the empty space by arranging the heat exchange bed in as small a volume as possible in the remaining space. The construction, by which the upper part of the Cowper is separated from the lower part thereof, may -- if required — be utilized to support new partition walls from the upper part thereof.
By arranging the heat accumulating mass in an annular space around the combustion shaft a heat accumulating bed is obtained, the cross-sectional area of which is large, and the layer thickness thereof relatively small. By a small layer thickness it is possible to maintain the pressure loss over the bed relatively small. An efficient heat exchange from the gas to the heat accumulating mass and vice versa is on the other hand ensured by a great cross-section of the bed, regardless of the small layer thickness. The thickness of the heat exchange bed depends on the size and shape of the filler solids or grains used therein. The thickness of the new heat accumulating bed is typically 5 - 50% of the height of the earlier used brick layer. By using a bed formed of granular material, for example ceramic pebbles, it is possible to achieve a considerably larger heat exchange area relative to the total volume or total weight of the bed. A heat exchange area/total volume ratio of about 360m2/m3 is achieved with a bed formed of 10 mm pebbles. The heat exchange area depends on the size of the pebbles. The above mentioned ratio is 720m2/m3 with 5 mm pebbles. The heat accumulating bed in an apparatus in accordance with the present invention may be formed, for example, of pebbles, the diameter of which is preferably less than 10 mm. The bed material may thus be manufactured, for example, of material used for the production of refractory bricks, which is also appropriate for heat exchange.
When using granular material or small loose solids instead of bricks, the amount heat accumulating mass volume required is — due to an advantageous heat exchange surface area/volume ratio — considerably smaller than when using a conventional high pile of bricks as a filler, although the capacity of the preheater remains the same. The small granular size of the bed material enables a sufficiently efficient heat exchange also in a low bed. The bed material m_rSt,' -however, be such that it forms a fixed bed and not a fluidized bed. According to the present invention it is possible to use a considerably low heat accumulating bed, which may be much lower than the conventional brick layer used in the Cowpers. In the conventional Cowper, in which the cross-sectional area is about 30m2, the height of the bed is usually about 30 m. The height of a bed in accordance with the present invention, which is as efficient, is on a horizontal 30m2 grate typically 2 - 8 m. Depending on the size and shape of the filler solids sometimes thicker bed layers may be necessary. Usually, however, a heat accumulating bed of less than 15 m is sufficient.
A bed formed of granular material or loose solids typically generates a higher flow resistance than, for example, a heat accumulating pile of bricks of the same height. A higher flow resistance is easily avoided in the apparatus in accordance with the present invention, however, by forming the bed operating as the heat exchange medium with a relatively smaller height/diameter ratio than a pile of bricks with a corresponding efficiency, so that the flow resistance in the bed diminishes respectively. By utilizing the apparatus in accordance with the present invention a heat exchange area is achieved with a smaller bed mass, which is as large as that achieved with a great pile of bricks in the Cowper.
The pressure difference in the heat accumulating bed in accordance with the present invention easily becomes even smaller than in the conventional heat exchangers with a brick filler/layer. The decrease of the pressure difference by 5 kPa in a gas flow of 100 000 m3n/h means about 300000 FIM annual savings.
When utilizing a modernized Cowper in accordance with the present invention, in which apparatus a small bed provides approximately as much heat exchange surface area in order to transfer a certain amount of power as a conventional massive pile of bricks filler, it is possible to decisively shorten the duration of the actual heating and preheating stages. With shorter heating and preheating times the apparatus on the other hand also operates with a smaller bed than before. Because also the dead time periods are shorter with the apparatus in accordance with the present invention than with the conventional Cowper, it is possible to shorten the duration of the heating and preheating stages, which again improves the efficiency of the heating process. Due to the high heat exchange ratio smaller temperature differences between the gases and bed material are also achieved in the modernized apparatus in accordance with the present invention. The bed material in the apparatus may be heated as close to the temperature of the heated gases as possible and respectively, the gases to be preheated to a higher temperature than what is achieved with the same amount and content of fuel with the Cowper. The gas to be preheated may be heated to a temperature, which is only about ten degrees for example 10-20 °C, from the temperature of the heating gas .
The preheater in accordance with the present invention enables a preferred method of modernizing an old Cowper by a small heat accumulating bed, which is readily cleaned. When the plant has, for example, four preheaters for blast furnace it is possible to run the blast furnace plant continuously in full power with three preheaters and contemporarily to arrange the modernization of one preheater according to the present invention without disturbing the main process.
The blast furnace dust may be removed from the preheater, for example, once a year, so that the beds of the pre- heaters are changed to a clean bed material one after another. The fouled pebbles or other loose solids of the bed are removed from the apparatus, for example, to a truck and conveyed away to be cleaned. The cleaned pebbles are used later in the next preheater when changing its bed material during maintenance. An efficient heat exchange and a small pressure loss is thus secured in the preheaters.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. 1 is a schematic vertical sectional view of an exemplary modernized preheater in accordance with the present invention; Fig. 2 is a cross-sectional view of the apparatus of Fig. 1 taken along line AA thereof;
Fig. 3 is a cross-sectional view of the apparatus of Fig. 1 along line BB thereof; Fig. 4 is a vertical sectional view of a second exemplary modernized preheater in accordance with the invention; Fig. 5 is a cross-sectional view of the apparatus of Fig. 4 along line AA thereof;
Figs. 6 - 8 are vertical sectional views of other exemplary embodiments of moderninized preheaters in accordance with the invention; and
Fig. 9 is a vertical sectional view of a modernized preheater in accordance with the present invention.
DETAILED DESCRIPTION OF THE INVENTION
Figs. 1, 2 and 3 illustrate a Cowper-type modernized preheater 10 for air in a blast furnace plant, the pre¬ heater comprising a tower-like steel shell construction 12 with a brick work lining 14 on the inside. The tower-like construction comprises two shafts, 16 and 18.
The lower part of the narrow shaft 16 is provided with an inlet conduit 20 for blast furnace gas and an inlet conduit 22 for combustion air. A gas burner 24 is mounted to communicate with the gas conduits 20, 22, and to combust the blast furnace gas with the combustion air in order to raise the temperature of the gas and to form a heating gas. An outlet conduit 26 for heated blast furnace air is disposed above the gas burner 24. The narrow shaft 16 communicates at its upper part with a gas space 28 of a shaft dome, connecting the narrow shaft 16 to the wider heat accumulating shaft 18.
In the lower part thereof the heat accumulating shaft 18 has an old distribution chamber 32 and an old grate 34 as well as a conduit 38 connected to the opening 36 in the distribution chamber 32. The conduit 38 operates as an outlet conduit for the heating gas from burner 24, and as an inlet conduit for the cold blast furnace air.
The heat accumulating shaft 18 is provided with a new grate 40 and with a new distribution chamber 42 therebelow in the uppermost quarter of shaft 18, above the old grate 34. The grate 40 supports a granular heat accumula-trϊ_g bed 44 operating as heat accumulating mass. The upper surface of the heat accumulating bed 44 extends to within close proximity of the top 49 of the partition wall 50 between the shafts 16, 18. The space 46 between the old grate 34 and the new distribution chamber 42 is provided with a gas-tight wall 48. The wall 48 supports the wall 50 between the shafts 16, 18. An opening 52 is formed to the new distribution chamber 42, the opening 52 communicating with a conduit 54 so that cold blast furnace air may be introduced into the distribution chamber 42, or so that cooled heating gases may be exhausted from the preheater 10. It is, of course, possible to use different conduits for feeding blast furnace air and removing cooled heating gases. The wider shaft 18 is provided with a connecting pipe 56 for cold blast furnace air and cooled heating gas, connecting the old distribution chamber 32 to the new distribution chamber 42. The connecting pipe 56 leads through the separated gas space 46.
A modernized preheater for a blast furnace plant in accordance with Fig. 1 operates in such a way that blast furnace air and combustion air are supplied via conduits 20 and 22 to the lower part of the narrow shaft 16, through which either atmospheric or pressurized gases are introduced into the gas burner 24. The blast furnace gases burn and form a hot heating gas of 1200 - 1700°C, which flows to the top of the narrow shaft and further through gas space 28 to the heat accumulating shaft 18. The heating gas flows through the heat accumulating bed 44, releasing heat to the heat accumulating mass formed of granular material. The heating gases, cooled to the temperature of 150-400°C through grate 40, flow to the distribution chamber 42, from which the gases flow out through conduit 54 or in the connecting pipe 56 to the old distribution chamber 32, and therefrom are discharged through opening 36 and conduit 38. The heat accumulating mass 44 is heated with the heating gases for about 30 minutes, so that the upper surface of the bed material almost reaches the inlet temperature of about 1200 - 1700°C of the heating gas, after which the inlet 20 of blast furnace gas to said preheater 10 is closed. The increase in temperature depends on the composition of the gas.
After the feed of the heating gas ends, the feed of the cold blast furnace air to upper part of the heat accumulating shaft 18 begins at a temperature of about 50 - 200°C and at an overpressure of about 0.5 - 4 bar through conduits 54 and/or 38. Cold blast furnace air flows through grate 40 and heat accumulating bed 44 to the top of the shaft 18, thereby heating almost to the temperature of the heat accumulating material 44. The heated blast furnace air, which may be for example oxygen-enriched air, flows from the gas space 28 connecting the shafts 16, 18 downwardly in the narrow shaft 16 towards the discharge conduit 26, from which -- after about a minute so that the pressure has increased sufficiently that it may be supplied as blast air to the flues of the blast furnace (not shown) -- it is discharged.
If it is not possible to fit a grate 40 which is large enough, and a horizontal heat accumulating bed 44, in the preheater 10 to be modernized, the heat accumulating bed may be postioned between two vertical grates. Even very large vertical grates may be disposed in the old heat accumulating shaft 18.
Figs. 4 and 5 illustrate a preheater 110 modernized with vertical grat-es ..according to the present invention, in which the flow of the heating gas and the air to be heated through the heat accumulating bed 144 located between two vertical grates is horizontal. Figs. 4 and 5 use three-digit reference numbers, in which the first digit is one and the last two digits correspond to the reference numbers used for the corresponding parts of the apparatus in Figs. 1 - 3, when possible.
The heat accumulating bed 144 in the preheater in accordance with Fig. 4 is provided in the upper part 119 of the heat accumulating shaft 118 between the grates 140 and 41. The grate 41 on the hot side is manufactured of perforated ceramic mass, which endures the temperature of the heating gases. The grate 41 on the hot side is built preferably on the old partition wall 150, which in the Cowper unit separates the gas combustion shaft 116 and the heat accumulating shaft 118 from each other. The second grate 140 mounted on the cold side may be manufactured, for example, of perforated steel plate.
The heat accumulating bed 144 is formed in the upper part of the Cowper ..in a volume from which the old heat accumulating pile of bricks is removed. The old grate 134 and a portion of the old brick pile 133 thereon are left below the upper part 119 of the heat accumulating shaft 118. The remaining pile of bricks is separated by an inter¬ mediary floor 35, which separates the upper part 119 of the operating heat accumulating shaft from the. pile 133 in a gas-tight manner.
A ceiling plate 51 extending over the cross-section of the whole old Cowper is mounted above the heat accumulating bed 144, so that the flow from above from the heat accumulating shaft 118 past the bed 144 to the combustion shaft 116 is prevented. The ceiling plate 51 is preferably mounted in such a way that the empty space 53 thereabove is separated in a gas-tight manner from the space below it. In addition to being gas-tight, the ceiling 51 also must be pressure resistant over long periods of time.
Fig. 6 illustrates a third modernized preheater 210 in accordance with the present invention. The reference numbers in the drawing correspond to the two digit numbers, only preceded by a "2" in Figs. 4 and 5.
In the embodiment of to Fig. 6 the heat accumulating bed 244 is also arranged between two grates 240 and 241. The grate 240 is inclined in such a way that the horizontal cross-sectional area of the bed 244 is larger in the upper part of the bed than in the lower part thereof. The thickness of the bed may thus be utilized to affect the distribution of the gas flowing through the heat accumulating bed 244.
The characteristics of the heat accumulating bed 244 -- for example the total loss of pressure or heat exchange characteristics -- may also be affected by forming the bed 244 of two or more different materials, for example, grains of different size and shape. In the arrangement in accordance with Fig. 6 two separate zones 244 and 45, in which the shapes and quality of the solids are different, are provided between the grates 240, 241. The lower zone 244 is formed of solids A and the higher zone 24 of solids B. By adjusting the size of the different zones it is possible to adjust the operation of the entire bed.
Different zones in the heat accumulating bed may also be provided in the other embodiments. For example, in the embodiment of Fig. 4, two vertical zones may be formed, if required, between the grates. In order to gain a uniform increase of the total pressure difference a bed material may be chosen on the hot side, in which the pressure difference becomes higher than on the cold side, the effect of which material on the growth of the pressure difference is smaller than that of the bed material chosen on the cold side.
Fig. 7 illustrates a fourth modernized preheater 310 in accordance with the invention. Two digit reference numbers in accordance with the previous drawings are used in Fig. 7, preceded by a "3". In the embodiment in accordance with Fig. 7 the embodiment of Fig. 1 (in which the heat accumulating bed is arranged on a horizontal grate) is supplemented with a vertically positioned bed portion in accordance with Fig. 4, so that the total flow cross-sectional surface" of the bed may be increased and at the same time the thickness and pressure loss thereof diminished according to the dimensioning requirements of any given situation.
In the embodiment in accordance with Fig. 7 the upper part of the heat accumulating shaft 318 is provided on the one hand with a horizontal grate 340 and a horizontal heat accumulating bed 344 on top of the-grate 340, and on the other hand with two vertical grates 341 and 39, with a vertical heat accumulating bed 43 therebetween. A portion of the gas flowing into the distribution chamber 342 is supplied through the horizontal grate 340 into contact with a horizontal heat accumulating bed 344 and further through the gas space 328 of the shaft dome 328 downwardly to the combustion shaft 316. A second portion of the gas flowing to the distribution chamber 342 is supplied through the first vertical grate 39 into contact with the vertical heat accumulating bed 43 and further thorough the second vertical grate 341 to the narrow shaft 316, in which both preheated gas flows are joined.
By utilizing the embodiment in accordance with Fig. 7 the cross-sectional area of the heat accumulating bed may be increased compared with the embodiment in accordance with Fig. 1, which is advantageous when striving for a small pressure loss. In the embodiment of Fig. 7 a ceiling plate (e.g. 51 in Fig. 4) is not necessary, however, as it is in the embodiments with vertical grates in accordance with Figs. 4 and 6, in which all the air/gas is supplied through the vertical grates.
In the embodiment in accordance with Fig. 8 the same two digit reference numerals are used as in the other embodiments, and preceded by a "4". Here the aim is to increase the cross-sectional area of the heat accumulating bed by dividing the bed using two grates 439 and 440 positioned on two different levels. The gas flowing through the upper grate 440 and bed 444 flows through shaft dome 428 to the combustion shaft 416. The gas flowing through the lower grate 439 and bed 443 flows through opening 451 formed in the wall 450 to the combustion shaft 416. Gas may be supplied from the lower bed also through a separate channel, not shown in the drawing, via the upper distribution chamber 442, grate 440 and bed 444 to the shaft dome 428, whereby an opening in the partition wall 450 is no longer necessary.
Fig. 9 illustrates a fifth modernized preheater 510 in accordance with the invention. When possible the same two digit reference numbers have been used as in Fig. 4, and then preceded by a "5".
Fig. 9 illustrates a modernized Cowper-type preheater 510 for air, comprising a tower-like steel shell construction 512 with a brick work lining 514 on the inside. The partition wall, which the preheater previously had, has been removed and the pile of brick filler has also been removed.
The tower-like construction has been divided in the mod- ernization by an intermediary floor 61 into an upper part 62 and a lower part 63. The upper part 62 is left empty, and it may be pressurized, if necessary, to a desired pressure, so that the construction of the intermediary floor 61 does not have to be as strong as in the case when the separated upper part is maintained at the pressure of the surroundings. If required, the walls 512 of the upper part 61 may be supported by an additional brickwork, for example, with a sprayable mass. The empty upper part 61 may also be completely removed.
The lower part 63 of the preheater 510 is provided with a cylindrical combustion shaft 64 and a heat accumulating shaft 65 therearound, which consists of two annular spaces 66 and 67. The innermost annular space 66 is provided with a heat accumulating bed 544 formed of granular material.
The combustion shaft 64 is essentially coaxial with the steel shell 512 and the cylindrical middle part thereof is limited to a vertical cylindrical wall 69, which is provided with openings 70. The wall 69 thus forms a grate construction. The wall 69 is formed of refractory, for example ceramic, material.
The lower.part of the combustion shaft 64 is provided with a gas burner 524, communicating with an inlet conduit 520 for blast furnace gas and an inlet conduit 522 for air. The upper part of the combustion shaft 64 is provided with an outlet conduit 552. Each of the inlet conduits 520, 522 for blast furnace gas and air, and the outlet conduit 552 for the preheated air, are provided with a valve for opening and closing the conduits (the valves are not shown in the drawings) .
The annular space 66 closest to the combustion shaft 64 of the heat accumulating shaft 65 is determined by a first wall 69 and a second wall 72. The second wall 72 is manufactured, for example, of a perforated steel plate, strong fine steel mesh, or like heat-resisting material appropriate for a grate plate. The perforations 73 in the steel plate may typically be round or of the shape of a narrow slot, of the size, e.g. 2x200 mm. A heat accumulating bed 544 of granular material or, for example, of small pebbles, is arranged between the grates formed by grates/walls 69 and 72. The maximum dimensions of the grains may be only about 2 - 10 mm, and the openings/perforations of the grates are, of course, to be dimensioned such that the heat accumulating mass 544 does not pass through them. The heat accumulating bed 544 may be formed, on the other hand, also of larger solids, for example, of steel balls, the diameter of which may be up to about 50 mm.
The outlet conduit 526 for cooled blast furnace gas and the inlet conduit 74 for cold air or air to be preheated are mounted to the outermost annular space 67 of the heat accumulating shaft 65. The conduits 74, 526 are also provided with valves for opening and closing the conduits, (the valves are not shown in the drawing) .
The preheater 510 of the blast furnace plant in accordance with Fig. 9 operates in such a way that blast furnace gas and combustion air are supplied by conduits 520 and 522 to the gas burner 524, by which heating gas of about 1200 - 1700°C is generated. Heating gas flows to the combustion shaft 64. The valve of outlet conduit 552 is closed, so that hot gases flow through the openings 70 of the first partition wall 69 to the annular space 66 of the heat accumulating shaft 65 releasing heat to the heat accumulating mass 544. Gases, which have cooled to the temperature of about 150-400°C, flow through the second partition wall 72 to the outermost annular space 67 and further via outlet conduit 526 for gas, for example, to a chimney. After about 30 minutes, when the heat accumulating mass 544 has typically heated almost to the temperature of the heating gas (e.g. about 10 - 20°C lower), the valves for the blast furnace gas and combustion gas conduits 520, 522 as well as the valve of the gas outlet conduit 552, are closed and the valve in the inlet conduit 74 for air is opened, from which the pressurized inlet air of about 50 - 200°C is admitted, at an overpressure of about 0.5 - 4 bar to the outermost part of the preheater 510. The inlet air may be oxygen-enriched gas. When the pressure has increased sufficiently, typically after a minute, the valve of the outlet conduit 552 for preheated air is opened, so that air begins to flow through the openings of the second partition wall 72, heat accumulating ■ bed 544 and the openings 70 of the first partition wall 69 to the combustion shaft 64 and further to the flues of the blast furnace. When flowing through the heat accumulating bed 544 the temperature of the air almost reaches "that of the heat accumulating bed. When the temperature of the bed 544 decreases below a preset temperature, the inlet and outlet conduits 74, 552 for air are closed and the inlet conduits 520, 522 for blast furnace gas and combustion air are reopened and heating gas is formed to reheat the heat accumulating bed 544.
The apparatus in accordance with the present invention may be pressurized, and it is preferably used continuously pressurized. Thereby the blast furnace gases are supplied pressurized to the burner and further therefrom as heating gases to the pressurized heat accumulating shaft without a need to decrease the pressure in the preheater between the blast stage and the heating stage.
At an overpressure of 1 - 3 bar the heat exchange from the blast furnace gases to the bed is intensified considerably. Also a pressurized heat exchange to the blast is efficient. The pressure of the blast may be 3 - 5 bar. Due to this pressurization, the duration of both the heating and preheating stages may be shortened. Moreover, the dead times diminish considerably when the pressurization and the pressure relief stages are completely left out or at least shortened considerably. Also, by pressurizing the heating stage also pressure strokes, which are common in conventional preheaters due to the pressure fluctuation, are avoided in the blast furnace.
The present invention is not intended to be limited to the above illustrated embodiments, but it may be modified within the inventive concept defined in the attached claims.
Thus the invention may be applied to such preheaters, in which the combustion shaft and the heat accumulating shaft are mounted into separate, adjacent shell constructions interconnected at the top.

Claims

1. In a modernized regenerative preheater for feed gas of a blast furnace plant or like heat process, two or more of said preheaters being used intermittently for a process for preheating blast furnace air or like gas with heating gases and which preheater comprises two shafts (16, 116, 216, 316, 416, 64; 18, 218, 318, 418, 65) arranged in a lined shell and communicating with each other, comprising: - a first shaft (16, 116, 216, 316, 416, 64) provided with an outlet conduit (26, 226, 326, 426) for blast furnace air or like gas heated in the preheater and an inlet conduit (20, 120, 220, 320, 420) for blast furnace gas from the blast furnace or like gas; - a second shaft (18, 218, 318, 418, 65) provided with heat accumulating mass (44, 144, 244, 344, 343, 444, 443, 544), which is alternately heated with heating gases and made to release heat to blast furnace air or like gas being heated in the preheater, and which heat accumulating shaft is provided with a conduit (38, 138, 238, 338, 438) to supply cold blast furnace air or like gas to a shaft and to exhaust cooled heating gases from the shaft, characterized in that
- the preheater is mounted to the shell (12, 112, 212, 312, 412, 512) of the old preheater, from which the old heat accumulating mass is at least partially removed; and
- the heat accumulating mass is provided with a heat accumulating bed (44, 144, 244, 45, 344, 343, 444, 443, 544) formed of fine-grained material, the ratio of the heat exchange area and the volume being greater than the corresponding ratio of the old regenerative preheater, and the volume of which required for the preheating is less than 50% of the volume of the heat accumulating filler layer used prior to the modernization.
2. A modernized preheater in accordance with claim 1, further characterized in that - a heat accumulating bed (44, 344, 444) is mou-nted in the blast furnace plant on a .substantially horizontal grate (40, 340, 439, 440) to the heat accumulating shaft (18, 318, 418); and further characterized by - a distribution chamber (42, 342, 442), communicating with a conduit (38, 338, 438; 54, 354, 454) for feeding the blast furnace air to the distribution chamber and exhausting the heating gases from the distribution chamber is mounted below the grate (40, 340, 439, 440).
3. A modernized preheater in accordance with claim 1, characterized in that the heat accumulating bed is mounted in the heat accumulating shaft between two substantially vertical grates (140, 141, 240, 241, 339, 341).
4. A modernized preheater in accordance with claim 3, characterized in that one of the vertical grates is mounted as an extension from the partition wall (150, 250, 350) between the combustion shaft and the heat accumulating shaft.
5. - A modernized preheater in accordance with claim 2 or 3, characterized in that the portion (46) of the gas space of the old heat accumulating remaining below the distribution chamber (42) is separated by a gas-tight wall (48) from the rest of the gas space.
6. A modernized preheater in accordance with claim 5, characterized in that the inlet conduit of cold blast furnace air and the outlet conduit for cooled heating gases are joined to form a connecting pipe (56) leading in a gas-tight manner from the distribution chamber (42) through a separated gas space (46) to below the grate (34) in the lower part of the shaft.
7. A modernized preheater in accordance with claim 2 or 3, characterized in that the grate is arranged to the heat accumulating shaft to- the upper half thereof.
8. A modernized preheater in accordance with claim 2 or 3, characterized in that the grate is mounted to the heat accumulating shaft to the lower half thereof.
9. A preheater in accordance with claim 1, characterized in that
- the combustion shaft 64 and the heat accumulation shaft 65 are separated from each other by a first partition wall 69, which is provided with openings 70, through which the shaft communicate with each other;
- a second partition wall 72 substantially parallel to the first partition wall is mounted to the heat accumulating shaft 65, which partition wall 72 is provided with openings 73 and which divides the heat accumulating shaft into two portions 66, 67; and
- heat accumulating mass 544 is formed of granular material or pieces and arranged as heat accumulating bed between the first and second partition wall in the heat accumulating shaft.
10. A preheater in accordance with claim 9, characterized in that the connection between the heat accumulating shaft and the combustion shaft in the upper part of the preheater is closed; the partition wall 69 between the combustion and heat accumulating shafts is provided with openings in order to form a communication between the shafts; and that a new partition wall 72 with perforations/openings is provided in the heat accumulating shaft, which wall 72 is substantially parallel to the partition wall 69 between the shafts.
11. A preheater in accordance with claim 9, characterized in that the combustion shaft 64 is mainly mounted in the middle part of the shell coaxially with the shell.
12. A preheater in accordance with claim 11, characterized in that the heat accumulating shaft forms an annular space 66, 67 around the combustion shaft.
13. A preheater in accordance with claim 12, characterized in that the heat accumulating bed is mounted in an annular space 66 between two coaxial partition walls 69, 72 in the combustion shaft.
14. A preheater in accordance with claim 12, characterized in that the heat accumulating bed of fine-grained material is arranged in the heat accumulating shaft, the ratio of the heat exchange area and the volume of said heat accumulating bed being higher than 300 m2/m3.
15. A preheater in accordance with claim 1, characterized in that the heat accumulating bed is formed of solids, the specific surface area of which corresponds to that of spherical solids having a diameter lower than 10 mm.
16. A preheater in accordance with claim 1, characterized in that the heat accumulating bed is formed of solids of two or more type.
17. A preheater in accordance with claim 1, characterized in that the material used for forming the solids or grains of the heat accumulating bed is ceramic material .
18. A preheater in accordance with claim 8 or 9 , characterized in that the preheater is formed to the lower part of the old Cowper-type preheater, so that
- the gas space in the upper part of the old preheater is separated by gas-tight pressure-resisting structure from the lower part of the preheater; and
- the pressure prevailing in the upper part of the gas space is equal to or higher than the pressure in the surrounding space.
PCT/FI1993/000044 1992-02-13 1993-02-12 Preheater for preheating air for example in a blast-furnace plant WO1993016345A1 (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
FI920619 1992-02-13
FI920619A FI920619A (en) 1992-02-13 1992-02-13 FOERVAERMARE FOER FOERVAERMNING AV LUFT
FI922420A FI922420A (en) 1992-02-13 1992-05-27 MODERNIZED FOERVAERMARE FOER FOERVARMNING AV LUFT I T.EX. MASUGNSANLAEGGNINGAR
FI922420 1992-05-27
FI923160 1992-07-09
FI923160A FI90284C (en) 1992-02-13 1992-07-09 Modernized preheater for preheating air, eg in a blast furnace plant

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996023188A2 (en) * 1995-01-24 1996-08-01 Nederlandse Organisatie Voor Toegepast- Natuurwetenschappelijk Onderzoek Tno Apparatus and method for the transfer of heat with the aid of air
WO2001069155A3 (en) * 2000-03-14 2002-04-18 Air Liquide Regenerative heat exchanger and method for heating a gas therewith
EP4012319A1 (en) * 2020-12-14 2022-06-15 Commissariat à l'énergie atomique et aux énergies alternatives Regenerative storage device

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Publication number Priority date Publication date Assignee Title
US1257524A (en) * 1913-08-26 1918-02-26 Stumm G M B H Geb Operation of checker-brick heaters.
US1278173A (en) * 1916-11-07 1918-09-10 James I Larimer Four-pass hot-blast stove.
US1825259A (en) * 1926-11-26 1931-09-29 Herman A Brassert Apparatus for heating air and other gases for industrial uses
US1845253A (en) * 1929-09-09 1932-02-16 Freyn Engineering Co Hot blast stove
DE658404C (en) * 1935-11-12 1938-04-05 Otto Lellep Dr Ing Method and device for regenerative heat exchange, especially for wind heating for blast furnace operation
US3378244A (en) * 1966-01-12 1968-04-16 Dresser Ind Pebble heat exchanger
US3401921A (en) * 1965-10-04 1968-09-17 Comte Jean Gaseous heat exchanger
US4398590A (en) * 1980-01-09 1983-08-16 Aluminum Pechiney Heat exchanger with reversing flow cycle for the recovery of heat from furnace smoke

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1257524A (en) * 1913-08-26 1918-02-26 Stumm G M B H Geb Operation of checker-brick heaters.
US1278173A (en) * 1916-11-07 1918-09-10 James I Larimer Four-pass hot-blast stove.
US1825259A (en) * 1926-11-26 1931-09-29 Herman A Brassert Apparatus for heating air and other gases for industrial uses
US1845253A (en) * 1929-09-09 1932-02-16 Freyn Engineering Co Hot blast stove
DE658404C (en) * 1935-11-12 1938-04-05 Otto Lellep Dr Ing Method and device for regenerative heat exchange, especially for wind heating for blast furnace operation
US3401921A (en) * 1965-10-04 1968-09-17 Comte Jean Gaseous heat exchanger
US3378244A (en) * 1966-01-12 1968-04-16 Dresser Ind Pebble heat exchanger
US4398590A (en) * 1980-01-09 1983-08-16 Aluminum Pechiney Heat exchanger with reversing flow cycle for the recovery of heat from furnace smoke

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996023188A2 (en) * 1995-01-24 1996-08-01 Nederlandse Organisatie Voor Toegepast- Natuurwetenschappelijk Onderzoek Tno Apparatus and method for the transfer of heat with the aid of air
NL9500130A (en) * 1995-01-24 1996-09-02 Tno Regenerative heat exchanger; heat pump and cooling device with regenerative heat exchanger; heat exchange method; cooling method; method of heating.
WO1996023188A3 (en) * 1995-01-24 1996-09-26 Tno Apparatus and method for the transfer of heat with the aid of air
WO2001069155A3 (en) * 2000-03-14 2002-04-18 Air Liquide Regenerative heat exchanger and method for heating a gas therewith
AU2001252175B2 (en) * 2000-03-14 2004-08-19 Primetals Technologies Austria GmbH Regenerative heat exchanger and method for heating a gas therewith
EP4012319A1 (en) * 2020-12-14 2022-06-15 Commissariat à l'énergie atomique et aux énergies alternatives Regenerative storage device
FR3117580A1 (en) * 2020-12-14 2022-06-17 Commissariat A L'energie Atomique Et Aux Energies Alternatives REGENERATIVE STORAGE DEVICE

Also Published As

Publication number Publication date
FI90284B (en) 1993-09-30
AU3500593A (en) 1993-09-03
FI923160A (en) 1993-08-14
FI923160A0 (en) 1992-07-09
FI90284C (en) 1994-01-10

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