WO1993012283A1 - Process for producing flocked decorative floor coverings from recycled rubber granulates - Google Patents

Process for producing flocked decorative floor coverings from recycled rubber granulates Download PDF

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Publication number
WO1993012283A1
WO1993012283A1 PCT/DE1991/000969 DE9100969W WO9312283A1 WO 1993012283 A1 WO1993012283 A1 WO 1993012283A1 DE 9100969 W DE9100969 W DE 9100969W WO 9312283 A1 WO9312283 A1 WO 9312283A1
Authority
WO
WIPO (PCT)
Prior art keywords
adhesive
flocking
mats
white
mat
Prior art date
Application number
PCT/DE1991/000969
Other languages
German (de)
French (fr)
Inventor
Alletto Rothhaar
Original Assignee
Alletto Rothhaar
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alletto Rothhaar filed Critical Alletto Rothhaar
Priority to PCT/DE1991/000969 priority Critical patent/WO1993012283A1/en
Publication of WO1993012283A1 publication Critical patent/WO1993012283A1/en

Links

Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H11/00—Non-woven pile fabrics
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/06—Recovery or working-up of waste materials of polymers without chemical reactions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0005—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface
    • D06N7/0039—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by the physical or chemical aspects of the layers
    • D06N7/0052—Compounding ingredients, e.g. rigid elements
    • D06N7/0055—Particulate material such as cork, rubber particles, reclaimed resin particles, magnetic particles, metal particles, glass beads
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00—Characterised by the use of unspecified rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

Definitions

  • the invention relates exclusively to a method which enables waste rubber and plastic in a refined form to be returned to the economic and industrial cycle. As a result, contaminated sites are reduced in this area, and environmental damage caused by the rubber and plastic combustion is restricted or largely avoided.
  • the use of recycling material enables the moderate and careful use of our resources.
  • the patent claim is preferably in the area of flooring, mats and sheets made from waste rubber, rubber granulate or regrind from e.g. Used tires, EPDM parts from the automotive or other industry, as well as in the area of wall, floor, or ceiling panels made from synthetic resin-bonded plastic granules, preferably from shredded plastic (e.g. from vehicles, household and packaging, etc.) in plate form or as a shaped body.
  • the subsequent flocking or lamination gives us e.g. a high-quality carpet for all areas of life, e.g. Household, office, exhibition stand, cars, buses, trains etc.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

A process is disclosed for producing floor coverings, mats and webs from recycled rubber granulates. For that purpose mats composed of a binder and of the granulate are produced, a pigmented adhesive is applied thereon and the coated substrate is electrostatically flocked with dyed fibers. If necessary, the substrate is coated with a phosphorescent enamel. To improve the adhesive anchorage, the surface of the substrate is milled or hollowed out.

Description

Verfahren zur Herstellung von dekorativen beflockten Fussbodenbelägen AI tgumml -Recycl 1 nggranul atProcess for the production of decorative flocked floor coverings AI tgumml -Recycl 1 nggranul at
Verfahren zur Herstellung von dekorativen und technisch nutzbaren Fußbodenbelägen, Matten und Bahnen, sowie Wand-, Boden- und Deckenplatten aus Recyclinggranulat oder Regenerat. Process for the production of decorative and technically usable floor coverings, mats and sheets, as well as wall, floor and ceiling panels made from recycled granulate or regenerated material.
Beschreibungdescription
Die Erfindung bezieht sich ausschließlich auf ein Verfahren welches ermöglicht Altgummi sowie Altplastik in veredelter Form dem Wirtschafts- und Industriekreislauf zurückzu- führen. Dadurch werden in diesem Bereich Altlasten ab¬ gebaut, sowie Umweltschäden durch die Gummi- und Kunst¬ stoffVerbrennung eingeschränkt oder weitgehend vermieden. Durch den Einsatz von Recyclingmaterial wird die Möglich¬ keit eines maßvollen und behutsamen Umganges mit unseren Ressourcen ermöglicht.The invention relates exclusively to a method which enables waste rubber and plastic in a refined form to be returned to the economic and industrial cycle. As a result, contaminated sites are reduced in this area, and environmental damage caused by the rubber and plastic combustion is restricted or largely avoided. The use of recycling material enables the moderate and careful use of our resources.
Der Patentanspruch liegt vorzugsweise im Bereich Fußboden¬ belag, Matten und Bahnen aus Altgummi-, Kautschukgranulat oder Regenerat von z.B. Altreifen, EPDM-Teilen aus der KFZ- oder sonstigen Industrie, sowie im Bereich Wand-, Boden-, oder Deckenplatten aus Kunstharzgebundenem Alt¬ kunststoffgranulat hergestellt, vorzugsweise aus ge- schredderte Altplastik (z.B. aus KFZ, Haushalt und Ver¬ packung etc.) in Plattenform oder auch als Formkörper. Durch die anschließende Beflockung oder Kaschierung er- halten wir z.B. einen hochwertigen Teppichboden für alle Lebensbereiche wie z.B. Haushalt, Büro, Messestand, PKW, Busse, Züge etc.The patent claim is preferably in the area of flooring, mats and sheets made from waste rubber, rubber granulate or regrind from e.g. Used tires, EPDM parts from the automotive or other industry, as well as in the area of wall, floor, or ceiling panels made from synthetic resin-bonded plastic granules, preferably from shredded plastic (e.g. from vehicles, household and packaging, etc.) in plate form or as a shaped body. The subsequent flocking or lamination gives us e.g. a high-quality carpet for all areas of life, e.g. Household, office, exhibition stand, cars, buses, trains etc.
Alle im Patentanspruch beschriebenen Produkte sind wie¬ derum Recyclingfähig und müssen nicht deponiegelagert oder verbrannt werden. All of the products described in the patent claim are in turn recyclable and do not have to be stored in landfills or incinerated.

Claims

3. PATENTANSPRÜCHE 3. PATENT CLAIMS
3.1. Herstellen eines unifarbenen Fußbodenbelages aus Altgummi3.1. Manufacture of a plain-colored floor covering from used rubber
Hierzu werden Matten, bestehend aus einem Bindemittel, z.B. Polyurethan, Melaminharz oder anderem, mit einem bis zu 90 %-tigem Altgummimehl oder Granulatanteil als Subs¬ trat verwendet. Diese Matten können eine Stärke von 0,5 - 50 mm aufweisen.For this purpose, mats consisting of a binder, e.g. Polyurethane, melamine resin or other, with up to 90% waste rubber powder or granulate content as Subs¬ used. These mats can have a thickness of 0.5 - 50 mm.
Gegebenenfalls notwendige Vorbehandlungen können z.B. sein: a)physikalisch (Corona, Beflammen, Plasmabehandlung) b)chemisch (Fluor, vorprimern, vorbeschichten z.B. Vulkanisation) Darauf wird im Walz-, Gieß-, Spritz-, Siebdruck- oder an¬ deren Verfahren, ein in der gewünschten Farbe pigmentierter reaktiver Beflockungsklebstoff aufgebracht. Wie z. B. inAny necessary pretreatments can e.g. be: a) physical (corona, flame treatment, plasma treatment) b) chemical (fluorine, pre-priming, pre-coating, for example vulcanization) Then, in the rolling, casting, spraying, screen printing or other processes, a pigmented in the desired color reactive flocking adhesive applied. Such as B. in
DE 33 22 695 A 1DE 33 22 695 A 1
'DE 34 00 340 A 1 beschrieben. Anschließend wird in die KlebstoffSchicht ein entsprechend eingefärbtes Flockmaterial elektrostatisch aufgebracht um ein textiles Äußeres zu erhalten. Die verwendeten Flock¬ fasern können jede Länge, vorzugsweise 1 - 4mm und jeden Titer, vorzugsweise 10 - 50 dtex aufweisen. Sie sind in der Regel aus Polyester, Polyamid ( 6 oder 6,6 ), Polyurethan, Kunstseide, Baumwolle, Trilobal oder Zellulosefasern. ' DE 34 00 340 A1 described. A correspondingly colored flock material is then electrostatically applied to the adhesive layer in order to obtain a textile exterior. The flock fibers used can have any length, preferably 1-4 mm and each titer, preferably 10-50 dtex. They are usually made of polyester, polyamide (6 or 6.6), polyurethane, rayon, cotton, trilobal or cellulose fibers.
Die anschließende Trocknung wird bei 120 - 150 C während ca. 10 Minuten vorgenommen. Nach dem Reinigen (z.B. Bürsten , Waschen und oder Vakuumabsaugung) erhält man einen Fußboden- belag' wie z . B . inThe subsequent drying is carried out at 120-150 C for approx. 10 minutes. After cleaning (e.g. brushing, washing and or vacuum extraction) you get a floor covering 'such. B. in
DD 230 033 A 1 beschrieben, t~ h ohne Verwendung von PVC.DD 230 033 A 1, t ~ h without the use of PVC.
3.2.1. Herstellen eines mehrfarbigen Fußbodenbelages oder Teppichbodens aus Altgummi3.2.1. Manufacture of a multi-colored floor covering or carpet from waste rubber
Hierzu wird das Substrat(wie unter 3.1. beschrieben) beschichtet, jedoch ist der Klebstoff weiß eingefärbt. Die hierbei verwendeten Flockfasern sind vorzugsweise aus Polyamid oder Polyester (weiß oder farblos ) . Nach der Trocknung oder Reinigung der beflockten Bahn oder Matte, wird im Thermoumdruckverfahren (Sublimation) jedes gewünschte Design, Emblem oder Schriftzug, bei einer Tempe¬ ratur von 160° - 220° C auf die Oberfläche aufgedampft. Dadurch ist es möglich, ohne Verlußt des textilen Charak- ters, Teppichböden für faßt alle Bereiche herzustellen z.B. für Haushalt, Messestände, Büroräume, Ämter, öffentlichFor this purpose, the substrate is coated (as described under 3.1.), But the adhesive is colored white. The flock fibers used here are preferably made of polyamide or polyester (white or colorless). After the flocked web or mat has been dried or cleaned, any desired design, emblem or lettering is evaporated onto the surface at a temperature of 160 ° -220 ° C. using the thermal transfer printing process (sublimation). This makes it possible to produce carpets for almost all areas without losing the textile character, e.g. for household, exhibition stands, offices, offices, public
Verkehrsmittel, PKW etc. )Means of transport, cars etc.)
Für die Beurteilung in Betracht zu ziehende Druckschriften:Publications to be considered for assessment:
DE 27 32 576 C 2 DE PS 4518DE 27 32 576 C 2 DE PS 4518
DE 23 21 592 B 2DE 23 21 592 B 2
DE 26 51 392 A 1DE 26 51 392 A 1
GB 20 84 931GB 20 84 931
GB 15 18 252 GB 14 52 130GB 15 18 252 GB 14 52 130
DE 39 08 142 A 1 3.2.21 Bei Verwendung von z.B Baumwoll- oder Viskoseflocken kann die Einfärbung auch mittels eines direkten Druck¬ verfahrens ( z.B. Siebdruck ) vorgenommen werden.DE 39 08 142 A 1 3.2.21 When using, for example, cotton or viscose flakes, the coloring can also be carried out by means of a direct printing process (for example screen printing).
3.3. Herstellen einer Fußmatte für den Haushalt, die Indus trie oder das KFZ3.3. Manufacture of a doormat for the household, industry or the car
3.3.1.Hierzu wird eine gestanzte oder geschnittene Recyclingmatte im Siebdruck, RSD, Prägedruck oder mit Spritztechnik (Spritzmaske) im gewünschten Design mit Kleb¬ stoff versehen und anschließend beflockt. Nach dem Trocknen und Reinigen erhält man eine hochwertige Fußmatte aus Alt¬ material, die selbst wieder Recyclingfähig ist.3.3.1 For this purpose, a punched or cut recycling mat is screen-printed, RSD, embossed or sprayed (spray mask) in the desired design with adhesive and then flocked. After drying and cleaning, a high-quality floor mat made of old material is obtained, which is itself recyclable.
3.3.2.Bei Verwendung von weißpigmentiertem Klebstoff, sowie weißem oder farblosen Flockmaterial, ist es möglich Fu߬ matten für Haushalt, Industrie oder KFZ in allen Farben ode Designs herzustellen. Das dazu gebräuchliche Verfahren wurde unter Punkt 3.3.3.2. When using white pigmented adhesive, as well as white or colorless flock material, it is possible to manufacture floor mats for household, industrial or automotive in all colors or designs. The procedure used for this was described under point 3.
2.1. angesprochen. (Termoumdruckverfahren oder Sublimation)2.1. addressed. (Thermal transfer printing or sublimation)
3.4. Herstellen eines nachleuchtenden Teppichbodens für Notausgänge, Kinos, Hotels, Kaufhäuser, Flughäfen, öffentliche Gebäude, Schutzräume, Keller etc. z. B. als Fluchtwegmarkierung3.4. Manufacture of an afterglow carpet for emergency exits, cinemas, hotels, department stores, airports, public buildings, shelters, cellars etc. z. B. as an escape route marker
Dazu wird eine Recyclingmatte mit einem transparentem, flexi¬ blen, jedoch pigmentierten (Nachleuchtpigment ) Lack vor¬ lackiert. Anschließend wird ein transparenter Beflockungs- klebstoff (2-komponentig oder 1 K reaktiv) aufgebracht und elektrostatisch weiß oder transparent beflockt. Nach dem Trocknen und Reinigen der Matte erhält man einen Teppichboden der flächig oder partiell verlegt den gängigen Sicherheitsvorschriften genügt. Das Nachleuchtpigment kann vollflächig, in SchriftformFor this purpose, a recycling mat is pre-coated with a transparent, flexible, but pigmented (afterglow pigment) lacquer. Then a transparent flocking adhesive (2-component or 1-component reactive) is applied and flocked electrostatically white or transparent. After drying and cleaning the mat, you get a carpet that is flat or partially laid and meets the current safety regulations. The afterglow pigment can cover the entire surface, in writing
(z.B. Notausgang) oder in graphischer Form (z.B. Pfeile)(e.g. emergency exit) or in graphic form (e.g. arrows)
aufgebracht sein. Patentliteratur hierzu:be upset. Patent literature on this:
EP 0 173 762 A 1 FR A - 2-176 559EP 0 173 762 A1 FR A - 2-176 559
FR A - 2-384 836FR A - 2-384 836
DE A - 2 949 901DE A - 2 949 901
US A - 2 838 762US A - 2,838,762
3.5. Alle Recyclingmatten aus Altgummi können anstatt einer Beflockung, auch durch jedweder Art von Kaschierung veredelt werden(z.B. Textil, Leder, Kuststoff etc) , ebenso durch Beschichtung mit Glimmer, Kork, Quarzsand,3.5. Instead of flocking, all recycled mats made from waste rubber can also be refined by any type of lamination (e.g. textile, leather, plastic, etc.), as well as by coating with mica, cork, quartz sand,
Kiesel etc.Pebbles etc.
3.6. s ellen be^^ Wand. Boden oder Deckenplatten.3.6. s e llen be ^^ wall. Floor or ceiling tiles.
3.6.1. Hierzu werden die Recyclinggranulat bestehenden Platten mit einer entsprechenden Oberfläche versehen, die es einem Klebstoff erlaubt auch bei schlechter Haftung zum Substrat eine. Planen mechanisch verankerten Klebstoffilm zu bilden.Hierzu wird die Oberfläche z.B. in geringen Abständen längs und/oder quer gefräßt oder hohlgebohrt, um einem caJ00% Festkörperklebstoff festen Halt zu geben.3.6.1. For this purpose, the existing granules of recycling granules are provided with a corresponding surface, which allows an adhesive even with poor adhesion to the substrate. Plan to form mechanically anchored adhesive film by using e.g. milled or drilled longitudinally and / or transversely at short intervals to give a caJ00% solid adhesive a firm hold.
( siehe Zeichnung, Blatt 8 )(see drawing, sheet 8)
Damit wird ereicht, das nach dem Beflocken und Trocknen ein statisch, sowie dynamisch stabiles Sandwichelement vorliegt, welches durch die Beflockung einen dekorativen Charakter aufweist und als Bauelement eingesetzt werden kann. Alle von 3.1. bis 3.5. beschriebenen Verfahren können angewendet werden.This is achieved after flocking and drying there is a statically and dynamically stable sandwich element, which has a decorative character due to the flocking and can be used as a structural element. All from 3.1. until 3.5. described methods can be applied.
3.7. Alle vorstehend benannten Produkte können auch im sogenannten MC-Verfahren dekorativ gestalltet werden. (Erfinder: Firma Maag 4* Schenk, Reutlingen) 3.7. All of the products mentioned above can also be decoratively designed using the so-called MC process. (Inventor: Maag 4 * Schenk company, Reutlingen)
PCT/DE1991/000969 1991-12-12 1991-12-12 Process for producing flocked decorative floor coverings from recycled rubber granulates WO1993012283A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/DE1991/000969 WO1993012283A1 (en) 1991-12-12 1991-12-12 Process for producing flocked decorative floor coverings from recycled rubber granulates

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/DE1991/000969 WO1993012283A1 (en) 1991-12-12 1991-12-12 Process for producing flocked decorative floor coverings from recycled rubber granulates

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996022413A1 (en) * 1995-01-19 1996-07-25 Ekotex S.R.O. Self-adhering floor covering and process for its manufacture
EP1551629A1 (en) * 2002-07-03 2005-07-13 High Voltage Graphics, Inc. Process for printing and molding a flocked article
EP1598463A1 (en) * 2004-05-21 2005-11-23 Rafael Pascual Bernabeu Procedure to obtain flocked surfaces with white and coloured flocking during the carrying out of the process, with one, two or more colours in the hair/flocking material, and the final product
USRE41945E1 (en) 2001-08-16 2010-11-23 Ecore International Inc. Impact sound insulation
US9175436B2 (en) 2010-03-12 2015-11-03 High Voltage Graphics, Inc. Flocked articles having a resistance to splitting and methods for making the same
USRE45802E1 (en) 2005-07-28 2015-11-17 High Voltage Graphics, Inc. Flocked articles having noncompatible insert and porous film
US9193214B2 (en) 2012-10-12 2015-11-24 High Voltage Graphics, Inc. Flexible heat sealable decorative articles and method for making the same
US9914011B2 (en) 2015-06-25 2018-03-13 Pliteq Inc. Impact damping mat, equipment accessory and flooring system
CN108456984A (en) * 2018-02-27 2018-08-28 浙江富润印染有限公司 Thermal fabric dyeing and printing process with mercerising flocking effect

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB995390A (en) * 1962-02-26 1965-06-16 Hans Joachim Roth Device for the production of unicoloured and/or multicoloured tufted materials
GB1120827A (en) * 1964-12-22 1968-07-24 Dunlop Co Ltd Process for making carpets
GB1156352A (en) * 1965-10-11 1969-06-25 West Point Pepperell Inc Method of and Apparatus for use in applying Flock Fiber to a Base Fabric
FR2303136A1 (en) * 1975-03-07 1976-10-01 Metzeler Schaum Gmbh Fibre covered supported sheet foam insulation - esp. for acoustic insulation of buildings (SW041076)
EP0173762A1 (en) * 1984-09-04 1986-03-12 Peter Kollmer After-illuminating flocked substrate, process and apparatus for its manufacture
US4895748A (en) * 1989-04-03 1990-01-23 Squires William J Flocked foam fabric with flattened fibers which are color printed

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB995390A (en) * 1962-02-26 1965-06-16 Hans Joachim Roth Device for the production of unicoloured and/or multicoloured tufted materials
GB1120827A (en) * 1964-12-22 1968-07-24 Dunlop Co Ltd Process for making carpets
GB1156352A (en) * 1965-10-11 1969-06-25 West Point Pepperell Inc Method of and Apparatus for use in applying Flock Fiber to a Base Fabric
FR2303136A1 (en) * 1975-03-07 1976-10-01 Metzeler Schaum Gmbh Fibre covered supported sheet foam insulation - esp. for acoustic insulation of buildings (SW041076)
EP0173762A1 (en) * 1984-09-04 1986-03-12 Peter Kollmer After-illuminating flocked substrate, process and apparatus for its manufacture
US4895748A (en) * 1989-04-03 1990-01-23 Squires William J Flocked foam fabric with flattened fibers which are color printed

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996022413A1 (en) * 1995-01-19 1996-07-25 Ekotex S.R.O. Self-adhering floor covering and process for its manufacture
USRE41945E1 (en) 2001-08-16 2010-11-23 Ecore International Inc. Impact sound insulation
EP1551629A1 (en) * 2002-07-03 2005-07-13 High Voltage Graphics, Inc. Process for printing and molding a flocked article
EP1551629A4 (en) * 2002-07-03 2009-07-22 High Voltage Graphics Inc Process for printing and molding a flocked article
EP1598463A1 (en) * 2004-05-21 2005-11-23 Rafael Pascual Bernabeu Procedure to obtain flocked surfaces with white and coloured flocking during the carrying out of the process, with one, two or more colours in the hair/flocking material, and the final product
ES2246141A1 (en) * 2004-05-21 2006-02-01 Rafael Pascual Bernabeu Procedure to obtain flocked surfaces with white and coloured flocking during the carrying out of the process, with one, two or more colours in the hair/flocking material, and the final product
USRE45802E1 (en) 2005-07-28 2015-11-17 High Voltage Graphics, Inc. Flocked articles having noncompatible insert and porous film
US9175436B2 (en) 2010-03-12 2015-11-03 High Voltage Graphics, Inc. Flocked articles having a resistance to splitting and methods for making the same
US9193214B2 (en) 2012-10-12 2015-11-24 High Voltage Graphics, Inc. Flexible heat sealable decorative articles and method for making the same
US9914011B2 (en) 2015-06-25 2018-03-13 Pliteq Inc. Impact damping mat, equipment accessory and flooring system
CN108456984A (en) * 2018-02-27 2018-08-28 浙江富润印染有限公司 Thermal fabric dyeing and printing process with mercerising flocking effect
CN108456984B (en) * 2018-02-27 2020-01-31 浙江富润印染有限公司 Warm fabric printing and dyeing process with mercerized flocking effect

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