WO1993006204A1 - Compositions de solvant et procede de nettoyage semi-aqueux - Google Patents

Compositions de solvant et procede de nettoyage semi-aqueux Download PDF

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Publication number
WO1993006204A1
WO1993006204A1 PCT/US1992/008126 US9208126W WO9306204A1 WO 1993006204 A1 WO1993006204 A1 WO 1993006204A1 US 9208126 W US9208126 W US 9208126W WO 9306204 A1 WO9306204 A1 WO 9306204A1
Authority
WO
WIPO (PCT)
Prior art keywords
volume percent
composition
glycol
ether
less
Prior art date
Application number
PCT/US1992/008126
Other languages
English (en)
Inventor
Felipe A. Donate
James G. Papajesk
Joanna M. Farella
Laurence W. Lee
Nancy H. Morris
Original Assignee
The Dow Chemical Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Dow Chemical Company filed Critical The Dow Chemical Company
Priority to EP92920868A priority Critical patent/EP0605605A1/fr
Publication of WO1993006204A1 publication Critical patent/WO1993006204A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50—Solvents
    • C11D7/5004—Organic solvents
    • C11D7/5022—Organic solvents containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
    • C23G5/024—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
    • C23G5/032—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/24—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/263—Ethers

Definitions

  • the present invention is related to semi-aqueous cleaning processes and compositions useful therein.
  • Cleaning is required in the metal working and electronics industries to remove oils, greases, coolants, fluxes and various particuiates such as metal fines and shop soils.
  • chlorocarbon and chlorofluorocarbon solvents have been used m vapor ⁇ egreasmg equipment to provide the needed cleaning.
  • environmental concerns and regulations nave been directed toward the jse of these solvents in recent years.
  • Semi-aqueous cleaners are hydrocarbon formulations containing emulsifying agents to ennance their abil ity to be rinsed Generally the formulations are not bulk liquid flammable, put nave vapors that can ignite under certai n conditions whicn results in potential problems n processing and equipment design. Semi- aqueous cleaners typically use their affinity to organic contaminants to solvate the
  • the present invention is a cleaning composition consisting essentially of
  • C 12-13 hydrocarbons having a flash point greater than about 200°F, a viscosity of less than 3.0 cP at 25°C and a surface tension of less than 30.0 dynes/cm at 25°C;
  • HLB hydrophile/lipophile balance
  • tne composition (4) zero to 5 volume percent of one or more innibitors, perfumes or dyes
  • the various components of tne composition are selected so that the compositior has a boiling point greater than 200°C ana a freezing point less than 5°C; a flash point greater tnan 95oC, ana water solubility of less tnan 1 g/100g
  • the present invention is a semi-aqueous cleaning process using the above described composition.
  • the part to be cleaned is typically (1) subjected to a solvent wash; (2) brown with air to control solvent carryover; (3) rinsed witn water: and (4) driec in a modification of this system, an emulsion stage 5 used in the modified system, the part is subjected to a solvent wasn and then mmersed emulsion of solvent and water prior to being blown with air, rinsed ana dried. Solvents are kept at a minimum in the emulsion stage and the water is continuously recycled by
  • the emulsion must readily separate - the static tank to permit the recycling of the water and/or solvent.
  • the cleaning process may be conducted at room temperature or at elevated temperatures to accelerate cleaning and separation of emulsion.
  • elevated temperatures will be maintained below the rasn point for safety purposes
  • the semi-aqueous cleaner of the present invention includes the grycol ether one or more hydrocarbons, optionally one or more surfactants are optionally one or more
  • a hydrocarbon or a blend of hydrocarbons may be used in the practice of the invention.
  • the hydrocarbon may be linear, branched or cyclic with linear being preferred. Typically, the hydrocarbon will have from from 12 to 18 carbon atoms, with C 14-16 linear paraffins being preferred.
  • the cyclic hydrocarbons may contain inert substituents such as alkyi groups.
  • Surfactants useful in the composition of the present invention are non-ionic surfactants having an HLB of 1 to 8.5 or 12 to 16.
  • the surfactants will typically comprise a C 8-1 5 linear, branched or cyclic aliphatic hydrophilic chain and a hydrophobic chain containing between 2 and 10 mole percent degree of alkoxylation.
  • Preferred surfactants are Cs-i 5 alkyoxylated alcohols having from 1 to 8 alkylene oxide units wherein the alkylene oxide 15 ethylene oxide, propylene oxide or butylene oxide with ethylene oxide being preferred More preferred surfactants are C 9- 1 1 alkyoxylated alcohols having 5-7 ethyiene oxide units.
  • the semi-aqueous cleaner may also include inhibitors to prevent corrosion of metals such as steel.
  • inhibitors to prevent corrosion of metals such as steel. Examples of useful inhibitors inciude amines, phosphates,
  • polyphosphates polyphosphates, nitrides, molybdates, suifonates and quarternary ammonium salts
  • Antioxidants such as butylated hydroxy toluene are also useful in some applications, it may also be necessary or desirable to add perfumes, dyes or other additives.
  • the relative amounts of the various components of the cleaning formulation are any which results in a composition having tne desired properties.
  • the glycol etner comprises from 30 to 70 volume percent of the comoosition, preferably from 30 to 60 volume percert, more preferably from 40 to 50 ana most preferably 40 to 45 volume percent.
  • the hyarocarbon comp rises from 30 to 70 volume percent of the composition, preferably from 40 to 70 volume percent, more preferably from 50 to 65 and most preferably 50-55 volume percent
  • the surfactant comprises from 0 to 10 volume percent of the composition, preferably from 1 to 5 volume percent.
  • An inhibitor or inhibitors, perfumes, dyes or other additives comprises from 0 to 5 volume percent of the composition, preferably from 0 1 to 1 .5 volume oercent Of course, the total volume of components in the composition totals 100.
  • the semi-aqueous cleaner 's prepared by mixing the components in a suitable vessel typically used oy those witn the art Order of mixing s not critical the cleaner composition s tormulated to have a flash point of 95oC or greater. point. of 200oC or greater and a freezing point at or below 5°C; and to have water 100g the cieaner composition also nas certain soil oa ⁇ ing capac.ty. the ability to break an
  • the cleaning composition has soil loading capacity of at least 15 weignt percent at 60°C.
  • This soil loading capacity is the weight percent of soil , i.e. grease or oii, wmcn when present in the cleaning composition causes the cleaning performance of the formuiation to decrease below 90 percent.
  • Aprocedure foUowec to measure soil loading capacity is to soil a series of 2" x 1/2" x 1/16" 1010 steel coupons with grease or oil (soil) . The oil is applied by dipping the coupons in the oil, and then allowing the excess oil drip off before weighing the coupons. These coupons are placed in 1 -ounce bottles containing solutions of the ⁇ eaner containing various weight percentages of grease or oil, i. e. soil loading.
  • compositions when emulsified with water, .vill preferably separate from water in five, more preferably three, minutes or less at temperatures of 60°C or above.
  • the ability to separate from water is determined bymixing, at room temperature, thirty ml of the cleaning composition and 70 mi of deionize ⁇ water in a graduated cylinder. Location of the initial meniscus is noted and the cylinder is inverted several times to insure mixing The cylinder's left undisturbed for a set period of time then the appearance of each layer and the location of the meniscus are noted. The same tests are repeated at 6C°C.
  • Rinsing capabil ties are determined by mmersing a cou pon in a cleaner to which has been added a dye and then immersing the coupon into a container of
  • Example 1 Semi-aqueous Cleaning with No Emulsion Stage
  • the 1010 steel coupons were greased as described in Example 1 with Prestige 74' Lithium Grease and placed in 1-ounce flint bottles containing 15 ml of an emulsion made by mixing 4.5 ml of the formulation with 10.5 mi deionized water (30/70 ratio).
  • Each formulation contained dipropylene glycol n-butyl ether (DPnB), a C,. _.. linear hydrocarbon and the various surfactants shown in the amounts listed in Table 2
  • the bottles were placed in an Eberpach snakerand shaken at 180 oscillations per minute. The shaker was stopped every 1 minute so that the coupons could be visually inspected for cleanliness. The test was discontinued when grease could no longer be seen on the coupon.
  • Each formulation was tested in tripilcate and the results averaged.
  • Example 3 The procedure in Example 3 was followed with the exception that the test composition was varied as shown in Table 3 below
  • the coupons were greased as described previously with each of the commercial greases and placed in 1-ounce flint bottles containing 20 ml of an emulsion made by mixing 6 ml of heat solvent or formulation with 14 ml delonized water (30/70 ratio)

Abstract

Composition et procédé de nettoyage semi-aqueux comportant certains éthers de glycol, notamment l'éther n-butylique de dipropylène-glycol; un hydrocarbure; et éventuellement un tensio-actif et des inhibiteurs.
PCT/US1992/008126 1991-09-24 1992-09-24 Compositions de solvant et procede de nettoyage semi-aqueux WO1993006204A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP92920868A EP0605605A1 (fr) 1991-09-24 1992-09-24 Compositions de solvant et procede de nettoyage semi-aqueux

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US76475991A 1991-09-24 1991-09-24
US07/764,759 1991-09-24

Publications (1)

Publication Number Publication Date
WO1993006204A1 true WO1993006204A1 (fr) 1993-04-01

Family

ID=25071688

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1992/008126 WO1993006204A1 (fr) 1991-09-24 1992-09-24 Compositions de solvant et procede de nettoyage semi-aqueux

Country Status (4)

Country Link
EP (1) EP0605605A1 (fr)
AU (1) AU2678292A (fr)
CA (1) CA2119646A1 (fr)
WO (1) WO1993006204A1 (fr)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0620270A2 (fr) * 1993-04-12 1994-10-19 Colgate-Palmolive Company Compositions de nettoyage
EP0636710A1 (fr) * 1993-07-27 1995-02-01 Dr. O.K. WACK CHEMIE GmbH Procédé pour le nettoyage d'objects
WO1995010593A1 (fr) * 1993-10-12 1995-04-20 Munford Finance S.A. Composition nettoyante, anti-adhesive, liquide
WO1995017244A1 (fr) * 1993-12-22 1995-06-29 Union Oil Company Of California Savons dissolvants et procedes d'utilisation de ces derniers
US5435936A (en) * 1993-09-01 1995-07-25 Colgate Palmolive Co. Nonaqueous liquid microemulsion compositions
EP0676488A1 (fr) * 1994-04-05 1995-10-11 Mtu Motoren- Und Turbinen-Union MàœNchen Gmbh Procédé pour enlever des matériause organiques de composants de machines
US5486314A (en) * 1992-08-07 1996-01-23 O. K. Wack Chemie Gmbh Cleaning agent containing glycol ethers
WO1996033260A1 (fr) * 1995-04-20 1996-10-24 Elf Atochem S.A. Agent de nettoyage a base de cycloalcanes
US5597792A (en) * 1993-04-02 1997-01-28 The Dow Chemical Company High water content, low viscosity, oil continuous microemulsions and emulsions, and their use in cleaning applications
FR2737219A1 (fr) * 1995-07-28 1997-01-31 Philippe Lutringer Composition nettoyante liquide
US20150052689A1 (en) * 2013-08-23 2015-02-26 Dow Global Technologies Llc Adhesive remover compositions and methods of use
WO2016029103A1 (fr) * 2014-08-21 2016-02-25 Nelson John J Compositions aqueuses et procédés pour les utiliser dans l'évaluation histopathologique d'échantillons de tissu

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107541741A (zh) * 2017-08-29 2018-01-05 天津普罗米新材料有限公司 一种替代水洗的烷烃清洗剂
CN110408943B (zh) * 2019-07-09 2021-07-23 江西瑞思博新材料有限公司 硬表面清洗后替代水漂洗的清洗液切除剂及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1450079A (fr) * 1964-10-10 1966-05-06 Hoechst Ag Agent de nettoyage et de passivation de surfaces métalliques
US4983224A (en) * 1988-10-28 1991-01-08 Rd Chemical Company Cleaning compositions and methods for removing soldering flux
WO1991006690A1 (fr) * 1989-11-01 1991-05-16 Henkel Kommanditgesellschaft Auf Aktien Melange pour le nettoyage de cartes imprimees
US5145523A (en) * 1991-01-22 1992-09-08 Van Waters And Rogers, Inc. Solutions for cleaning plastic and metallic surfaces

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1450079A (fr) * 1964-10-10 1966-05-06 Hoechst Ag Agent de nettoyage et de passivation de surfaces métalliques
US4983224A (en) * 1988-10-28 1991-01-08 Rd Chemical Company Cleaning compositions and methods for removing soldering flux
WO1991006690A1 (fr) * 1989-11-01 1991-05-16 Henkel Kommanditgesellschaft Auf Aktien Melange pour le nettoyage de cartes imprimees
US5145523A (en) * 1991-01-22 1992-09-08 Van Waters And Rogers, Inc. Solutions for cleaning plastic and metallic surfaces

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE WPIL Derwent Publications Ltd., London, GB; AN 92-120580 & JP,A,4 065 495 (ARAKAWA KAGAKU) 2 March 1992 *
Derwent Publications Ltd., London, GB; AN 92-093067 & JP,A,4 036 395 (NIPPON BARS KK) 6 February 1992 *

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5486314A (en) * 1992-08-07 1996-01-23 O. K. Wack Chemie Gmbh Cleaning agent containing glycol ethers
US5811383A (en) * 1993-04-02 1998-09-22 The Dow Chemical Company High water content, low viscosity, oil continuous microemulsions and emulsions, and their use in cleaning applications
US5597792A (en) * 1993-04-02 1997-01-28 The Dow Chemical Company High water content, low viscosity, oil continuous microemulsions and emulsions, and their use in cleaning applications
EP0620270A3 (fr) * 1993-04-12 1995-07-26 Colgate Palmolive Co Compositions de nettoyage.
EP0620270A2 (fr) * 1993-04-12 1994-10-19 Colgate-Palmolive Company Compositions de nettoyage
EP0636710A1 (fr) * 1993-07-27 1995-02-01 Dr. O.K. WACK CHEMIE GmbH Procédé pour le nettoyage d'objects
US5435936A (en) * 1993-09-01 1995-07-25 Colgate Palmolive Co. Nonaqueous liquid microemulsion compositions
WO1995010593A1 (fr) * 1993-10-12 1995-04-20 Munford Finance S.A. Composition nettoyante, anti-adhesive, liquide
WO1995017244A1 (fr) * 1993-12-22 1995-06-29 Union Oil Company Of California Savons dissolvants et procedes d'utilisation de ces derniers
US5788781A (en) * 1993-12-22 1998-08-04 Union Oil Company Of California Method for cleaning an oil-coated substrate
AU684309B2 (en) * 1993-12-22 1997-12-11 Union Oil Company Of California Solvent soaps and methods employing same
US5780407A (en) * 1993-12-22 1998-07-14 Union Oil Company Of California Solvent soaps and methods employing same
US5723423A (en) * 1993-12-22 1998-03-03 Union Oil Company Of California, Dba Unocal Solvent soaps and methods employing same
US5634984A (en) * 1993-12-22 1997-06-03 Union Oil Company Of California Method for cleaning an oil-coated substrate
EP0676488A1 (fr) * 1994-04-05 1995-10-11 Mtu Motoren- Und Turbinen-Union MàœNchen Gmbh Procédé pour enlever des matériause organiques de composants de machines
FR2733247A1 (fr) * 1995-04-20 1996-10-25 Atochem Elf Sa Agent de nettoyage a base de cycloalcanes
WO1996033260A1 (fr) * 1995-04-20 1996-10-24 Elf Atochem S.A. Agent de nettoyage a base de cycloalcanes
US5954886A (en) * 1995-04-20 1999-09-21 Elf Atochem S.A. Cleaning agent based on cycloalkanes
WO1997005230A1 (fr) * 1995-07-28 1997-02-13 Philippe Lutringer Composition nettoyante liquide
FR2737219A1 (fr) * 1995-07-28 1997-01-31 Philippe Lutringer Composition nettoyante liquide
US20150052689A1 (en) * 2013-08-23 2015-02-26 Dow Global Technologies Llc Adhesive remover compositions and methods of use
US11851637B2 (en) * 2013-08-23 2023-12-26 Ecolab Usa Inc. Adhesive remover compositions and methods of use
WO2016029103A1 (fr) * 2014-08-21 2016-02-25 Nelson John J Compositions aqueuses et procédés pour les utiliser dans l'évaluation histopathologique d'échantillons de tissu
US9562834B2 (en) 2014-08-21 2017-02-07 John J. Nelson Aqueous compositions and methods of using the same for histopathological evaluation of tissue samples

Also Published As

Publication number Publication date
AU2678292A (en) 1993-04-27
EP0605605A1 (fr) 1994-07-13
CA2119646A1 (fr) 1993-04-01

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