WO1993000316A1 - Catalyseur d'alkylation a acide liquide et procede d'alkylation a reaction isoparaffine/olefine ameliores - Google Patents

Catalyseur d'alkylation a acide liquide et procede d'alkylation a reaction isoparaffine/olefine ameliores Download PDF

Info

Publication number
WO1993000316A1
WO1993000316A1 PCT/US1992/005201 US9205201W WO9300316A1 WO 1993000316 A1 WO1993000316 A1 WO 1993000316A1 US 9205201 W US9205201 W US 9205201W WO 9300316 A1 WO9300316 A1 WO 9300316A1
Authority
WO
WIPO (PCT)
Prior art keywords
solvent
catalyst composition
isoparaffin
alkylation
weight percent
Prior art date
Application number
PCT/US1992/005201
Other languages
English (en)
Inventor
Kenneth Joseph Del Rossi
Albin Huss, Jr.
Original Assignee
Mobil Oil Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corporation filed Critical Mobil Oil Corporation
Publication of WO1993000316A1 publication Critical patent/WO1993000316A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/62—Catalytic processes with acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/03—Acids of sulfur other than sulfhydric acid or sulfuric acid, e.g. halosulfonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/12—Fluorides
    • C07C2527/1206—Hydrogen fluoride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025—Sulfonic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

L'invention se rapporte à une composition catalytique d'alkylation à réaction isoparaffine/oléfine, qui comprend environ 10 à environ 90 % en poids d'au moins un acide choisi dans le groupe constitué par l'acide fluorhydrique et par les acides sulfoniques halogénés, conjointement avec environ 10 à environ 90 % en poids d'un solvant présentant un nombre donneur inférieur à environ 40, en l'absence d'halogénure de métal ajouté intentionnellement. Un procédé d'alkylation à réaction isoparaffine/oléfine qui utilise cette composition catalytique est également décrit.
PCT/US1992/005201 1991-06-21 1992-06-18 Catalyseur d'alkylation a acide liquide et procede d'alkylation a reaction isoparaffine/olefine ameliores WO1993000316A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US71927491A 1991-06-21 1991-06-21
US719,274 1991-06-21

Publications (1)

Publication Number Publication Date
WO1993000316A1 true WO1993000316A1 (fr) 1993-01-07

Family

ID=24889433

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1992/005201 WO1993000316A1 (fr) 1991-06-21 1992-06-18 Catalyseur d'alkylation a acide liquide et procede d'alkylation a reaction isoparaffine/olefine ameliores

Country Status (2)

Country Link
AU (1) AU2252992A (fr)
WO (1) WO1993000316A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0601599A1 (fr) * 1992-12-11 1994-06-15 Phillips Petroleum Company Procédé pour l'alkylation isoparaffine/oléfine
EP0663377A1 (fr) * 1994-01-13 1995-07-19 Haldor Topsoe A/S Procédé d'alkylation
FR2736911A1 (fr) * 1995-07-20 1997-01-24 Inst Francais Du Petrole Catalyseur liquide d'alkylation aliphatique
EP0839781A1 (fr) * 1996-11-05 1998-05-06 Haldor Topsoe A/S Procédé pour la préparation d'un produit hydrocarboné riche en fraction de distillat moyen
US5906957A (en) * 1995-09-11 1999-05-25 Institut Francais Du Petrole Solid aliphatic alkylation catalyst

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2406954A (en) * 1943-09-20 1946-09-03 Universal Oil Prod Co Alkylation of isoparaffinic hydrocarbons
US3778489A (en) * 1971-12-16 1973-12-11 Exxon Research Engineering Co Alkylation with separate olefin streams including isobutylene
US3795712A (en) * 1969-11-24 1974-03-05 Inst Francais Du Petrole Alkylation of hydrocarbons with olefins in the presence of an acid catalyst
US3865896A (en) * 1973-11-05 1975-02-11 Texaco Inc Alkylation catalyst additive
DD243923A1 (de) * 1985-12-07 1987-03-18 Petrolchemisches Kombinat Verfahren zur hf-katalysierten alkylierung von butenen mit isobutan
DD271322A1 (de) * 1988-04-05 1989-08-30 Petrolchemisches Kombinat Verfahren zur hf-katalysierten alkylierung von butenen oder buten-propen-gemischen mit isobutan
US5073674A (en) * 1990-04-20 1991-12-17 Olah George A Environmentally safe catalytic alkyation using liquid onium poly (hydrogen fluorides)

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2406954A (en) * 1943-09-20 1946-09-03 Universal Oil Prod Co Alkylation of isoparaffinic hydrocarbons
US3795712A (en) * 1969-11-24 1974-03-05 Inst Francais Du Petrole Alkylation of hydrocarbons with olefins in the presence of an acid catalyst
US3778489A (en) * 1971-12-16 1973-12-11 Exxon Research Engineering Co Alkylation with separate olefin streams including isobutylene
US3865896A (en) * 1973-11-05 1975-02-11 Texaco Inc Alkylation catalyst additive
DD243923A1 (de) * 1985-12-07 1987-03-18 Petrolchemisches Kombinat Verfahren zur hf-katalysierten alkylierung von butenen mit isobutan
DD271322A1 (de) * 1988-04-05 1989-08-30 Petrolchemisches Kombinat Verfahren zur hf-katalysierten alkylierung von butenen oder buten-propen-gemischen mit isobutan
US5073674A (en) * 1990-04-20 1991-12-17 Olah George A Environmentally safe catalytic alkyation using liquid onium poly (hydrogen fluorides)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0601599A1 (fr) * 1992-12-11 1994-06-15 Phillips Petroleum Company Procédé pour l'alkylation isoparaffine/oléfine
TR28194A (tr) * 1992-12-11 1996-02-13 Phillips Petroleum Co Izoparafin-olefin alkilasyon prosesi.
US5792896A (en) * 1992-12-11 1998-08-11 Phillips Petroleum Company Isoparaffin-olefin alkylation
CN1041624C (zh) * 1992-12-11 1999-01-13 菲利浦石油公司 异链烷烃－烯烃烷基化
EP0663377A1 (fr) * 1994-01-13 1995-07-19 Haldor Topsoe A/S Procédé d'alkylation
FR2736911A1 (fr) * 1995-07-20 1997-01-24 Inst Francais Du Petrole Catalyseur liquide d'alkylation aliphatique
EP0755906A1 (fr) * 1995-07-20 1997-01-29 Institut Francais Du Petrole Procédé d'alyklation catalytique d'hydrocarbures aliphatiques
US5849978A (en) * 1995-07-20 1998-12-15 Institut Francais Du Petrole Liquid catalyst for aliphatic alkylation
US6096939A (en) * 1995-07-20 2000-08-01 Institut Francais Du Petrole Aliphatic alkylation utilizing a liquid catalyst
US5906957A (en) * 1995-09-11 1999-05-25 Institut Francais Du Petrole Solid aliphatic alkylation catalyst
EP0839781A1 (fr) * 1996-11-05 1998-05-06 Haldor Topsoe A/S Procédé pour la préparation d'un produit hydrocarboné riche en fraction de distillat moyen

Also Published As

Publication number Publication date
AU2252992A (en) 1993-01-25

Similar Documents

Publication Publication Date Title
US3778489A (en) Alkylation with separate olefin streams including isobutylene
EP0568089B1 (fr) Procédé d'alkylation d'une isoparaffine avec une oléfine et composition catalytique contenant haloacide et sulfone
EP0584760B1 (fr) Régénération d'un catalyseur d'alkylation
US5292986A (en) Isoparaffin-olefin alkylation catalyst composition and process
KR100272030B1 (ko) 탄화수소의 알킬화를 위한 촉매 및 탄화수소 알킬화 방법
WO1993000316A1 (fr) Catalyseur d'alkylation a acide liquide et procede d'alkylation a reaction isoparaffine/olefine ameliores
EP0593614B1 (fr) Procede pour accroitre la transformation en pluie de nuages de vapeur auto-refrigeree contenant de l'acide fluoridrique
US3922319A (en) Isoparaffin-olefin alkylation utilizing fluorosulfonic acid and sulfuric acid catalyst
US3970721A (en) Alkylation process for production of motor fuels utilizing sulfuric acid catalyst with trifluoromethane sulfonic acid
US5202518A (en) Liquid acid alkylation catalyst and isoparaffin:olefin alkylation process
US5292982A (en) Liquid acid alkylation catalyst and isoparaffin-olefin alkylation process
US4038212A (en) Alkylation process for production of motor fuels
US5220096A (en) Liquid acid alkylation catalyst composition and isoparaffin:olefin alkylation process
US5414186A (en) Liquid acid alkylation catalyst and isoparaffin-olefin alkylation process
US5196628A (en) Liquid acid alkylation catalyst and isoparaffin:olefin alkylation process
US5371314A (en) Catalytic isoparaffin-olefin alkylation with HF and a low donicity solvent
US3928486A (en) Alkylation process with fluorination step utilizing HF catalyst and hydrocarbon polymer
US3888935A (en) Process for producing alkyl fluorides from mono-olefins
US5196629A (en) Isoparaffin:olefin alkylation process and reactor apparatus
US5723715A (en) Isoparaffin-olefin alkylation
US5324699A (en) Alkylation catalyst complex
EP0632795B1 (fr) Catalyseur d'alkylation d'une isoparaffine avec une olefine comprenant hf, sulfone et eau
WO1993006068A1 (fr) Catalyseur acide liquide ameliore d'alkylation et procede d'alkylation d'isoparaffine:olefine
USRE28724E (en) Isoparaffin alkylation with a lighter olefin and subsequently with a heavier olefin

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AU CA JP

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IT LU MC NL SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: CA