WO1992019903A1 - Multilayer fire protective coating - Google Patents

Multilayer fire protective coating Download PDF

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Publication number
WO1992019903A1
WO1992019903A1 PCT/NO1992/000087 NO9200087W WO9219903A1 WO 1992019903 A1 WO1992019903 A1 WO 1992019903A1 NO 9200087 W NO9200087 W NO 9200087W WO 9219903 A1 WO9219903 A1 WO 9219903A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
layers
fire
rubber
outside
Prior art date
Application number
PCT/NO1992/000087
Other languages
English (en)
French (fr)
Inventor
Øystein HILDEN
Original Assignee
Viking Mjøndalen A.S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Viking Mjøndalen A.S filed Critical Viking Mjøndalen A.S
Publication of WO1992019903A1 publication Critical patent/WO1992019903A1/en

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B17/00Drilling rods or pipes; Flexible drill strings; Kellies; Drill collars; Sucker rods; Cables; Casings; Tubings
    • E21B17/01Risers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/06Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of natural rubber or synthetic rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/18Layered products comprising a layer of metal comprising iron or steel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/042Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of natural rubber or synthetic rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/10Layered products comprising a layer of natural or synthetic rubber next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/16Layered products comprising a layer of natural or synthetic rubber comprising polydienes homopolymers or poly-halodienes homopolymers
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B35/00Methods or apparatus for preventing or extinguishing fires
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L57/00Protection of pipes or objects of similar shape against external or internal damage or wear
    • F16L57/04Protection of pipes or objects of similar shape against external or internal damage or wear against fire or other external sources of extreme heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L57/00Protection of pipes or objects of similar shape against external or internal damage or wear
    • F16L57/06Protection of pipes or objects of similar shape against external or internal damage or wear against wear
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L58/00Protection of pipes or pipe fittings against corrosion or incrustation
    • F16L58/02Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
    • F16L58/04Coatings characterised by the materials used
    • F16L58/10Coatings characterised by the materials used by rubber or plastics
    • F16L58/1009Coatings characterised by the materials used by rubber or plastics the coating being placed inside the pipe
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00Thermal insulation in general
    • F16L59/02Shape or form of insulating materials, with or without coverings integral with the insulating materials
    • F16L59/029Shape or form of insulating materials, with or without coverings integral with the insulating materials layered
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00Thermal insulation in general
    • F16L59/14Arrangements for the insulation of pipes or pipe systems
    • F16L59/145Arrangements for the insulation of pipes or pipe systems providing fire-resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/304Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/71Resistive to light or to UV
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • B32B2307/7265Non-permeable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/752Corrosion inhibitor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2597/00Tubular articles, e.g. hoses, pipes

Definitions

  • the present invention relates to fire safety coatings for structures, particularly for steel line pipes for hydrocarbons in offshore activities, possibly for plastic material conduits for e.g. fire extinguishing installations in the oil industry, but also as a coating on e.g. flat or profiled structures of steel or other materials.
  • the risers mentioned are constructed of steel, and are often provided with a rubber cladding vulcanized thereon for corrosion protection and mechanical protection in the splash zone.
  • a rubber cladding vulcanized thereon for corrosion protection and mechanical protection in the splash zone.
  • Fire protecting combination coatings i.e. multilayer coatings, are per se previously known.
  • the outer layer is a composite material with a mineral matrix surrounding structural reinforcement elements.
  • the outer layer may be inorganic, since the mineral matrix can be a material similar to a ceramic, and the reinforcement elements are metal fibres or mineral fibres.
  • the function of the outer layer is to provide structural solidity for the coating, and to provide resistance against flames and "thermal shocks".
  • An intermediate layer consists of a felt of refractory fibres, and this layer is intended to constitute a fire-retarding shield for the material inside.
  • the inner layer is a thermally insulating layer with a cell structure, preferably of an organic type, i.e. cork or resin of a heat curable or thermoplastic type.
  • EP 283.385 corresponds to the particular fire safety functions for the inner and outer layers in accordance with the present invention in its general form, even though these functions are preferably obtained using other types of materials than in EP 283.385.
  • the intermediate layer of EP 283.385 suffers from the substantial drawback that oxygen may find its way therethrough, and hence lead to oxidation of the inner layer, thereafter leading to alteration of properties in an unfavourable direction, i.e. the thermal insulating property of the inner layer may in such a case be substantially impaired.
  • the present invention provides a coating where the drawbacks of the prior art regarding mechanical strength, corrosion retarding effect and oxygen barrier effect are remedied.
  • Steel pipe 1 which conducts hydrocarbons (not shown) in the center thereof, is to be protected.
  • a layer 5 of natural rubber, synthetic rubber or plastic to constitute a mechanical protection layer.
  • An inside layer 4 is provided to stop flame attacks, and is of an inorganic type.
  • layer 4 consists of inorganic fibres, e.g. wound glass fibre ribbons.
  • a layer 3 of a thermally highly insulating material preferably of rubber or plastic, and with great mechanical '* strength.
  • This layer 3 provides delay of the heat transport in toward steel pipe 1.
  • a corrosion inhibiting layer 2 of rubber or plastic which possibly also may exhibit good heat insula-tion properties.
  • a specially developed neoprene rubber material may constitute this layer 2 which has special corrosion inhibiting properties and is a mechanically strong layer 2 which is vulcanized directly on to steel pipe 1.
  • Thermally insulating layer 3 has special qualities in connection with a fire.
  • this material which preferably is made of a special rubber compound or of a special type of plastic, works as a heat insulator.
  • the layer 3 When this layer 3 is heated due to the fire, the layer develops reactive gases which draw outwards and react with the outside layers 4 and 5, converting these layers to a hard shell during the fire. The surplus thereafter remaining of the gases is combustible, and causes a counterfire on the outer surface of layer 5, against the actual fire.
  • intermediate layer 3 Due to the overpressure from the gases formed, or actually due to the outwards migration of the gases, oxygen wil not be able to penetrate from the outside to cause a combustion of intermediate layer 3 itself. However, intermediate layer 3 will all the time be subject to pyrolysis, i.e. degradation without any supply of oxygen. This pyrolysis process leads to the formation of a new material structure inside layer 3, but this new structure also exhibits very good heat insulating characteristics, and takes care of keeping away the fire heat from the underlying structure 1 to be protected.
  • inorganic layer 4 works as a flame shield, consisting of a non-combustible material, which thus prevents the flames from reaching the underlying rubber or plastic.
  • the material of layer 5 shall also be a rubber or plastic material which is impervious to water, and additio ⁇ nally it protects the rest of the materials from degradation due to influence from the sun or chemical substances like e.g. ozone.
  • layer 9 is a mechanically protective layer, preferably of chloroprene rubber
  • layer 8 i ⁇ an inorganic flame inhibiting/flame stopping layer, preferably of inorganic fibres
  • layer 7 is a new mechanically protecting layer of chloroprene rubber and layer 6 an inorganic fibre layer.
  • the gas barrier which is formed has the effect that no undesired oxidation occurs in the insulating intermediate layer 3, which therefore maintains its favourable properties for a long time during a fire.
  • the coating i ⁇ not in any manner intended to be used merely for protecting pipes, but also other constructions situated in a harsh climatic milieu, for instance construction parts, profile ⁇ and walls.

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Mining & Mineral Resources (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Fluid Mechanics (AREA)
  • Physics & Mathematics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Environmental & Geological Engineering (AREA)
  • Laminated Bodies (AREA)
  • Building Environments (AREA)
  • Thermal Insulation (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
PCT/NO1992/000087 1991-05-06 1992-05-06 Multilayer fire protective coating WO1992019903A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NO911764A NO175391C (no) 1991-05-06 1991-05-06 Brann-, korrosjonsbeskyttet og mekanisk beskyttet gjenstand omfattende en indre struktur og et flerlags belegg med brannbeskyttende egenskaper
NO91.1764 1991-05-06

Publications (1)

Publication Number Publication Date
WO1992019903A1 true WO1992019903A1 (en) 1992-11-12

Family

ID=19894129

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/NO1992/000087 WO1992019903A1 (en) 1991-05-06 1992-05-06 Multilayer fire protective coating

Country Status (2)

Country Link
NO (1) NO175391C (no)
WO (1) WO1992019903A1 (no)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994010497A1 (en) * 1992-11-05 1994-05-11 Viking-Mjøndalen A.S Multilayer fire protective coating
WO1998059193A1 (en) * 1997-06-23 1998-12-30 British Steel Limited Insulated pipework systems
US6382259B1 (en) 1998-06-22 2002-05-07 Corus Uk Limited Insulated pipework systems
US7100694B2 (en) 2001-01-08 2006-09-05 Stolt Offshore S.A. Marine riser tower
US7104330B2 (en) 2001-01-08 2006-09-12 Stolt Offshore S.A. Marine riser tower
EP2753789A4 (en) * 2011-09-06 2015-03-11 Ashwan Murdhi B Aldosari SELF-DISSOLVING ROOM FOR DELETING OIL AND GAS DRILLING HOLES
CN108397640A (zh) * 2018-06-07 2018-08-14 苏州赛易特环保科技有限公司 一种柔性螺旋状导风筒

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113803567A (zh) * 2021-09-24 2021-12-17 海南中盛旭鑫低碳科技有限公司 一种防腐结构、输送连接件及制备方法和应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2050041A (en) * 1979-05-30 1980-12-31 Pirelli General Cable Works Fire resistant cable
EP0240072A1 (en) * 1986-04-02 1987-10-07 Shell Internationale Researchmaatschappij B.V. Fire resistant plastic pipe
WO1988005885A1 (en) * 1987-01-29 1988-08-11 Eb Norsk Kabel A.S Method and device for fire and corrosion protected objects

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2050041A (en) * 1979-05-30 1980-12-31 Pirelli General Cable Works Fire resistant cable
EP0240072A1 (en) * 1986-04-02 1987-10-07 Shell Internationale Researchmaatschappij B.V. Fire resistant plastic pipe
WO1988005885A1 (en) * 1987-01-29 1988-08-11 Eb Norsk Kabel A.S Method and device for fire and corrosion protected objects

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994010497A1 (en) * 1992-11-05 1994-05-11 Viking-Mjøndalen A.S Multilayer fire protective coating
US5562957A (en) * 1992-11-05 1996-10-08 Trelleborg Viking As Multilayer fire protective coating
WO1998059193A1 (en) * 1997-06-23 1998-12-30 British Steel Limited Insulated pipework systems
AU734228B2 (en) * 1997-06-23 2001-06-07 Corus Uk Limited Insulated pipework systems
US6382259B1 (en) 1998-06-22 2002-05-07 Corus Uk Limited Insulated pipework systems
US7100694B2 (en) 2001-01-08 2006-09-05 Stolt Offshore S.A. Marine riser tower
US7104330B2 (en) 2001-01-08 2006-09-12 Stolt Offshore S.A. Marine riser tower
EP2753789A4 (en) * 2011-09-06 2015-03-11 Ashwan Murdhi B Aldosari SELF-DISSOLVING ROOM FOR DELETING OIL AND GAS DRILLING HOLES
CN108397640A (zh) * 2018-06-07 2018-08-14 苏州赛易特环保科技有限公司 一种柔性螺旋状导风筒

Also Published As

Publication number Publication date
NO175391C (no) 1994-10-05
NO911764L (no) 1992-11-09
NO911764D0 (no) 1991-05-06
NO175391B (no) 1994-06-27

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