WO1992014282A1 - Conductors material for electrical switching applications - Google Patents

Conductors material for electrical switching applications Download PDF

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Publication number
WO1992014282A1
WO1992014282A1 PCT/GB1992/000185 GB9200185W WO9214282A1 WO 1992014282 A1 WO1992014282 A1 WO 1992014282A1 GB 9200185 W GB9200185 W GB 9200185W WO 9214282 A1 WO9214282 A1 WO 9214282A1
Authority
WO
WIPO (PCT)
Prior art keywords
electrical
conductor
antimony
silver
copper
Prior art date
Application number
PCT/GB1992/000185
Other languages
French (fr)
Inventor
Robin Bose
Original Assignee
Otter Controls Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Otter Controls Limited filed Critical Otter Controls Limited
Priority to AU12018/92A priority Critical patent/AU659436B2/en
Publication of WO1992014282A1 publication Critical patent/WO1992014282A1/en

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00Contacts
    • H01H1/02Contacts characterised by the material thereof
    • H01H1/021Composite material
    • H01H1/023Composite material having a noble metal as the basic material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01RELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
    • H01R13/00Details of coupling devices of the kinds covered by groups H01R12/70 or H01R24/00 - H01R33/00
    • H01R13/02Contact members
    • H01R13/03Contact members characterised by the material, e.g. plating, or coating materials

Definitions

  • This invention generally concerns improvements relating to conductors for electrical switching applications.
  • a preferred form of electrical conductor for electrical switching applications in which electrical contact to the conductor is repeatedly made and broken in use, such conductor providing excellent electrical characteristics in combination with superior wear characteristics and comprising a member formed of copper or of a copper alloy having a thermal conductivity approaching (eg. at least 90%) that of copper, said member being provided with a thick plating layer of silver and antimony.
  • an electrical conductor for electrical switching applications in which electrical contact to the conductor is repeatedly made and broken, said conductor being formed of brass and having a thick plating layer thereon of silver and antimony.
  • Figure 1 is a schematic side view, partly in section, showing an X12 element protector control as manufactured by Otter Controls Limited fitted to a water heating vessel, and showing a co-operating CS2 connector part also as manufactured by Otter Controls Limited for incorporation into the base unit of a cordless appliance, the X12 control and the CS2 connector part of the base unit being shown spaced apart from each other one above the other; and
  • Figure 2 shows the X12 control and the CS2 connector part shown in engaged condition.
  • an X12 device is designated 1 and a co-operating CS2 base unit connector part is designated 2.
  • the X12 device l is substantially as described in GB-A-2194099 with reference to Figures 3A, 3B and 3C thereof, and as shown in Figure 1 hereof is attached in conventional manner to a side wall of a schematically-illustrated water heating vessel 3.
  • the X12 device has the function of interrupting the supply of electrical power to a heating element within the vessel 3 in the event of an element overtemperature condition occurring, for example as a result of the vessel being powered without there being any water in it.
  • the X12 device 1 has live, neutral and earth terminal pins 4, 5 and 6 within a hooded or open-based socket inlet shroud 7 and incorporates within the body of the device thermally- responsive switch means for interrupting the electric circuit from the live and neutral pins 4, 5 to the vessel heating element in the event of an element overtemperature condition.
  • the physical arrangement of the terminal pins of the X12 device and of the socket inlet shroud is fully conventional and enables the vessel 3 to be used in a corded manner, if desired, with a standard 10 amp kettle type connector plug (not shown) plugged into the socket inlet shroud 7 and making contact with the terminal pins.
  • This arrangement is adapted also to enable the vessel to be used in a cordless manner with a base unit incorporating the illustrated connector part 2 as will now be described.
  • the connector part 2 comprises a moulded plastics upstand from the base part of the appliance which is shaped to mate with the socket inlet shroud 7 of the X12 device 1 when the vessel part of the appliance is set down onto the base.
  • the vessel and/or the base part of the appliance may include formations designed to ensure proper mating cf the connector part 2 with the socket inlet shroud 7 of the X12 device 1 when the vessel part is seated on the base.
  • a moulded plastics shutter 8 which is spring biassed towards a closed position by means of a coil spring 9, and three leaf-spring terminals 10, 11 and 12 which couple within the base unit 2 to the live, neutral and earth conductors of a power supply cord and are adapted to contact the live, neutral and earth terminal pins 4, 5 and 6 respectively when the vessel part 3 is seated upon the base and the shutter 8 is displaced to an open position as shown in Figure 2.
  • a preferred form of terminal pin providing excellent electrical characteristics in combination with superior wear characteristics comprises a copper pin, or a pin formed from a copper alloy having a thermal conductivity at least 90% that of copper, provided with a thick plating layer of silver and antimony, and the terminal pins 4, 5 and 6 can advantageously have this construction. If a common brass pin with a 5 micron layer of essentially pure silver plating were to be used then the life of the contact effected by the pin to the base unit connector springs would be around 1000 cycles of connection and disconnection. This may be increased to around 5000 cycles by use of a plating of 40 microns of essentially pure silver.
  • This life may further be increased by use of a pin made from copper or a high thermal conductivity copper alloy, but a side effect would be the formation of silver powder caused by abrasion of the contact surfaces which could lead to premature electrical breakdown.
  • a thick plating e.g. at least 30 microns and preferably 40 microns thickness
  • antimony typically about 1% and particularly between 0.3% and 0.7%
  • a silver antimony plating may be used to improve the performance of a brass pin, and a copper or high thermal conductivity copper alloy pin also obtains improved performance as compared to a brass pin, but the best results are obtained in accordance with the teachings of the present invention when these two improvements are combined.
  • the preferred form of terminal pin for co-operation with a base unit connector as herein described is a pin formed of copper or of a copper alloy having a thermal conductivity at least 95% and preferably 99% that of 99.95% pure copper, and having a plating layer of at least 30 microns and more preferably 40 microns thickness comprising fine silver (99.9% purity) with the addition of about 1% and more preferably between 0.3% and 0.7% of antimony.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Contacts (AREA)
  • Insulated Conductors (AREA)
  • Coupling Device And Connection With Printed Circuit (AREA)
  • Connector Housings Or Holding Contact Members (AREA)

Abstract

The electrical terminal pins of a cordless electrical appliance may be implicated in electrical switching operations and, to increase their longevity, they are formed of copper or a copper alloy having a thermal conductivity approaching that of copper and are provided with a plating of from 30 to 40 $g(m)m thickness of silver containing from 0.3 to 0.7 % antimony.

Description

CONDUCTORS MATERIALFORELECTRICALSWITCHINGAPPLICATIONS
Field of the Invention:
This invention generally concerns improvements relating to conductors for electrical switching applications. Background of the Invention;
In many electrical switching applications, discrete contacts formed for example of silver or a silver alloy are utilized to provide reliability and longevity in the switching operation. However such an approach is frequently inconvenient from a manufacturing viewpoint and can give rise to unacceptable cost. Electrical appliances, for example electrically heated water boiling vessels, particularly of the cordless type, are also known in which the power supply terminal pins of the appliance are implicated in switching operations. Commonly such terminal pins are formed as brass stampings, but brass pins are susceptible to excessive wear in applications involving frequent or relatively frequent switching operations, such wear arising on account particularly of arc erosion. To reduce this problem it is known to silver plate the brass stampings but this does not provide a satisfactory solution. Summary of the Invention:
According to one aspect of the the present invention there is provided a preferred form of electrical conductor for electrical switching applications in which electrical contact to the conductor is repeatedly made and broken in use, such conductor providing excellent electrical characteristics in combination with superior wear characteristics and comprising a member formed of copper or of a copper alloy having a thermal conductivity approaching (eg. at least 90%) that of copper, said member being provided with a thick plating layer of silver and antimony. According to another aspect of the present invention there is provided an electrical conductor for electrical switching applications in which electrical contact to the conductor is repeatedly made and broken, said conductor being formed of brass and having a thick plating layer thereon of silver and antimony.
The above and additional features of the invention are set forth with particularity in the appended claims- and will be best understood from consideration of the following detailed description of an exemplary embodiment which is given with reference to the accompanying drawing. Brief Description of the Drawing:
Figure 1 is a schematic side view, partly in section, showing an X12 element protector control as manufactured by Otter Controls Limited fitted to a water heating vessel, and showing a co-operating CS2 connector part also as manufactured by Otter Controls Limited for incorporation into the base unit of a cordless appliance, the X12 control and the CS2 connector part of the base unit being shown spaced apart from each other one above the other; and
Figure 2 shows the X12 control and the CS2 connector part shown in engaged condition.
Detailed Description of the Embodiment: A description will first be given of an exemplary cordless connection system to which the present invention may advantageously be applied, the system in question being described and illustrated in greater detail in European Patent Application No. 91300780.3 (published as EP-A-0441536) of Otter Controls Limited.
Referring first to Figure 1, an X12 device is designated 1 and a co-operating CS2 base unit connector part is designated 2. The X12 device l is substantially as described in GB-A-2194099 with reference to Figures 3A, 3B and 3C thereof, and as shown in Figure 1 hereof is attached in conventional manner to a side wall of a schematically-illustrated water heating vessel 3. As is described in GB-A- 2194099, the X12 device has the function of interrupting the supply of electrical power to a heating element within the vessel 3 in the event of an element overtemperature condition occurring, for example as a result of the vessel being powered without there being any water in it. The means whereby this protective function is achieved is not especially material to the present invention and will not be described further herein. All that need be said in this regard is that the X12 device 1 has live, neutral and earth terminal pins 4, 5 and 6 within a hooded or open-based socket inlet shroud 7 and incorporates within the body of the device thermally- responsive switch means for interrupting the electric circuit from the live and neutral pins 4, 5 to the vessel heating element in the event of an element overtemperature condition. The physical arrangement of the terminal pins of the X12 device and of the socket inlet shroud is fully conventional and enables the vessel 3 to be used in a corded manner, if desired, with a standard 10 amp kettle type connector plug (not shown) plugged into the socket inlet shroud 7 and making contact with the terminal pins. This arrangement is adapted also to enable the vessel to be used in a cordless manner with a base unit incorporating the illustrated connector part 2 as will now be described.
The connector part 2 comprises a moulded plastics upstand from the base part of the appliance which is shaped to mate with the socket inlet shroud 7 of the X12 device 1 when the vessel part of the appliance is set down onto the base. Although not illustrated in the drawing, it will be understood that the vessel and/or the base part of the appliance may include formations designed to ensure proper mating cf the connector part 2 with the socket inlet shroud 7 of the X12 device 1 when the vessel part is seated on the base. Within the connector part 2 there is provided a moulded plastics shutter 8 which is spring biassed towards a closed position by means of a coil spring 9, and three leaf-spring terminals 10, 11 and 12 which couple within the base unit 2 to the live, neutral and earth conductors of a power supply cord and are adapted to contact the live, neutral and earth terminal pins 4, 5 and 6 respectively when the vessel part 3 is seated upon the base and the shutter 8 is displaced to an open position as shown in Figure 2. In accordance with the teachings of the present invention, a preferred form of terminal pin providing excellent electrical characteristics in combination with superior wear characteristics comprises a copper pin, or a pin formed from a copper alloy having a thermal conductivity at least 90% that of copper, provided with a thick plating layer of silver and antimony, and the terminal pins 4, 5 and 6 can advantageously have this construction. If a common brass pin with a 5 micron layer of essentially pure silver plating were to be used then the life of the contact effected by the pin to the base unit connector springs would be around 1000 cycles of connection and disconnection. This may be increased to around 5000 cycles by use of a plating of 40 microns of essentially pure silver. This life may further be increased by use of a pin made from copper or a high thermal conductivity copper alloy, but a side effect would be the formation of silver powder caused by abrasion of the contact surfaces which could lead to premature electrical breakdown. By the use of a thick plating (e.g. at least 30 microns and preferably 40 microns thickness) comprising silver with a small amount of antimony, typically about 1% and particularly between 0.3% and 0.7%, on a pin formed of copper or a high thermal conductivity copper alloy, the formation of silver powder is inhibited and a life of about 70,000 cycles may be obtained.
A silver antimony plating may be used to improve the performance of a brass pin, and a copper or high thermal conductivity copper alloy pin also obtains improved performance as compared to a brass pin, but the best results are obtained in accordance with the teachings of the present invention when these two improvements are combined. Accordingly the preferred form of terminal pin for co-operation with a base unit connector as herein described is a pin formed of copper or of a copper alloy having a thermal conductivity at least 95% and preferably 99% that of 99.95% pure copper, and having a plating layer of at least 30 microns and more preferably 40 microns thickness comprising fine silver (99.9% purity) with the addition of about 1% and more preferably between 0.3% and 0.7% of antimony.
The invention having been described in the foregoing with reference to an exemplary application, it is to be well appreciated that other applications for the invention are possible. Furthermore, modifications could be made to the described arrangement, for example by providing the leaf spring terminals 10, 11 and 12 in the connector part 2 with a thick silver-antimony plating in accordance with the invention or with silver contact pads.

Claims

CLAIMS :
1. An electrical conductor for electrical switching applications in which electrical contact to the conductor is repeatedly made and broken, said conductor comprising a member formed of copper or of a copper alloy having a thermal conductivity approaching that of copper and said member being provided with a thick plating layer of silver and antimony.
2. An electrical conductor as claimed in claim 1 wherein the thickness of said plating layer is at least 30 microns.
3. An electrical conductor as claimed in claim 1 or 2 wherein the silver antimony plating contains about 1% antimony.
4. An electrical conductor as claimed in claim 3 wherein the silver antimony plating contains between 0.3% and 0.7% antimony.
5. An electrical conductor as claimed in any of the preceding claims configured as a terminal pin. *\
6. An electrical switch incorporating at least one electrical conductor as claimed in any of the preceding claims.
7. An electrical appliance incorporating an electrical switch as claimed in claim 6.
8. An electrical appliance as claimed in claim 7 and wherein a power supply terminal pin of the appliance is implicated in switching operations and said power supply terminal pin constitutes said electrical conductor.
9. An electrical conductor for electrical switching applications in which electrical contact to the conductor is repeatedly made and broken, said conductor being formed of brass and having a thick plating layer thereon of silver and antimony.
PCT/GB1992/000185 1991-01-31 1992-01-31 Conductors material for electrical switching applications WO1992014282A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU12018/92A AU659436B2 (en) 1991-01-31 1992-01-31 Improvements relating to conductors for electrical connection applications

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB919102062A GB9102062D0 (en) 1991-01-31 1991-01-31 Improvements relating to conductors for switching applications
GB9102062.8 1991-01-31

Publications (1)

Publication Number Publication Date
WO1992014282A1 true WO1992014282A1 (en) 1992-08-20

Family

ID=10689285

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1992/000185 WO1992014282A1 (en) 1991-01-31 1992-01-31 Conductors material for electrical switching applications

Country Status (5)

Country Link
EP (1) EP0569433A1 (en)
AU (1) AU659436B2 (en)
CA (1) CA2101558A1 (en)
GB (2) GB9102062D0 (en)
WO (1) WO1992014282A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011158023A2 (en) 2010-06-17 2011-12-22 Otter Controls Limited Thermally responsive electric switches
WO2013142765A1 (en) * 2012-03-23 2013-09-26 Technic, Inc. Silver antimony coatings and connectors
EP2978076A4 (en) * 2013-03-21 2016-11-02 Enplas Corp Electrical connector, and socket for electric component

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR950703219A (en) 1992-09-02 1995-08-23 제이, 더블유, 뀌, 프리소 Charger for Wireless Products
US6463446B1 (en) 1998-02-26 2002-10-08 Sun Microsystems, Inc. Method and apparatus for transporting behavior in an event-based distributed system
GB0218138D0 (en) * 2002-08-05 2002-09-11 Strix Ltd Electrical terminals

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2131615A (en) * 1982-11-23 1984-06-20 Gunter Merten Electrical switch for actuation by motor vehicle doors
US4513183A (en) * 1983-05-04 1985-04-23 U.S. Plastics Corporation Gravity switch
DE3932536C1 (en) * 1989-09-29 1990-08-09 W.C. Heraeus Gmbh, 6450 Hanau, De Wear resistant contact material - in which is applied to support comprising copper alloy and non-noble metal contg. silver, palladium or palladium-silver alloy

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1065886A (en) * 1963-10-11 1967-04-19 Ass Elect Ind Improvements relating to vacuum-switch contacts
CH519775A (en) * 1970-03-26 1972-02-29 Siemens Ag Process for producing a heterogeneous interpenetrating composite metal as a contact material for vacuum switches
DE2014638A1 (en) * 1970-03-26 1971-10-14 Siemens Ag Process for the production of a two-layer contact piece
JPS57177988A (en) * 1981-04-24 1982-11-01 Furukawa Electric Co Ltd:The Manufacture of silver plated copper material
JPS63221517A (en) * 1987-03-09 1988-09-14 古河電気工業株式会社 Electric contact material and manufacture thereof
CA2035419C (en) * 1990-01-31 2002-01-01 Robert Andrew O'neill Electrical appliances
DE4005836C2 (en) * 1990-02-23 1999-10-28 Stolberger Metallwerke Gmbh Electrical connector pair

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2131615A (en) * 1982-11-23 1984-06-20 Gunter Merten Electrical switch for actuation by motor vehicle doors
US4513183A (en) * 1983-05-04 1985-04-23 U.S. Plastics Corporation Gravity switch
DE3932536C1 (en) * 1989-09-29 1990-08-09 W.C. Heraeus Gmbh, 6450 Hanau, De Wear resistant contact material - in which is applied to support comprising copper alloy and non-noble metal contg. silver, palladium or palladium-silver alloy

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011158023A2 (en) 2010-06-17 2011-12-22 Otter Controls Limited Thermally responsive electric switches
WO2013142765A1 (en) * 2012-03-23 2013-09-26 Technic, Inc. Silver antimony coatings and connectors
EP2978076A4 (en) * 2013-03-21 2016-11-02 Enplas Corp Electrical connector, and socket for electric component

Also Published As

Publication number Publication date
CA2101558A1 (en) 1992-08-01
GB9102062D0 (en) 1991-03-13
GB9202055D0 (en) 1992-03-18
AU1201892A (en) 1992-09-07
AU659436B2 (en) 1995-05-18
GB2253097A (en) 1992-08-26
GB2253097B (en) 1995-01-18
EP0569433A1 (en) 1993-11-18

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