WO1991014747A1 - Coating composition - Google Patents

Coating composition Download PDF

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Publication number
WO1991014747A1
WO1991014747A1 PCT/GB1991/000454 GB9100454W WO9114747A1 WO 1991014747 A1 WO1991014747 A1 WO 1991014747A1 GB 9100454 W GB9100454 W GB 9100454W WO 9114747 A1 WO9114747 A1 WO 9114747A1
Authority
WO
WIPO (PCT)
Prior art keywords
polydiorganosiloxane
room
primer composition
temperature
carbon atoms
Prior art date
Application number
PCT/GB1991/000454
Other languages
French (fr)
Inventor
Rodney Ralph Brooks
Michael John Winter
Original Assignee
Courtaulds Coatings (Holdings) Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB909006840A external-priority patent/GB9006840D0/en
Priority to BR919106209A priority Critical patent/BR9106209A/en
Priority to EP91906926A priority patent/EP0521983B1/en
Priority to DK91906926.0T priority patent/DK0521983T3/en
Priority to CA002078144A priority patent/CA2078144C/en
Priority to AU75773/91A priority patent/AU651096B2/en
Application filed by Courtaulds Coatings (Holdings) Limited filed Critical Courtaulds Coatings (Holdings) Limited
Priority to DE69102535T priority patent/DE69102535T2/en
Priority to KR1019920702339A priority patent/KR0175648B1/en
Publication of WO1991014747A1 publication Critical patent/WO1991014747A1/en
Priority to NO923660A priority patent/NO303643B1/en
Priority to FI924303A priority patent/FI101717B1/en
Priority to HK134794A priority patent/HK134794A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C09D5/1675—Polyorganosiloxane-containing compositions
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/26—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
    • C09D123/28—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen

Definitions

  • This invention relates to a primer composition for application to a substrate to promote adhesion of a room-temperature-vulcanisable (RTV) silicone rubber coating.
  • RTV room-temperature-vulcanisable
  • RTV silicone rubber coatings are applied to underwater surfaces, for example ships' hulls. the cooling water inlets and outlets of power stations, fish-farming equipment and the underwater and splash-zone surfaces of oil production platforms, to inhibit fouling by aquatic organisms such as algae and barnacles.
  • Silicone rubber fouling-resistant coatings are described for example in GB-A-1307001, GB-A-1470465, GB-A- 1581727, GB-A-2141436, EP-A-16195 and US-A-3702773.
  • RTV silicone rubber coatings have also been suggested as coatings inhibiting the adhesion of ice, for example on the superstructure and topsides of ships.
  • a problem in the use of such RTV silicone rubber coatings is that it is difficult to make them adhere well to substrates. This problem is discussed in EP-A-16195 which proposes applying the RTV silicone rubber as a cladding on a fabric backing.
  • Various primer compositions have been suggested for room-temperature-vulcanisable silicone rubber antifoulings.
  • US-A-3702778 proposes a crosslinkable silicone paste.
  • EP- A-89066 proposes a mixture of an epoxysilane and a silane containing an unsaturated hydrocarbon group.
  • JP-A-53- 137231, JP-A-53-137233 and JP-A-53-137234 propose various elastomeric materials such as polyurethane, natural rubber, chloroprene or neoprene rubber or butyral/silicone rubber.
  • EP-A-323906 and EP-A-329375 propose a silicone resin containing an aminosilane.
  • US-A-4070421 describes the use of chlorinated polyethylene as a primer for improving adhesion of coatings on polyolefin surfaces.
  • a primer composition according to the invention for application to a substrate to promote adhesion of an RTV silicone rubber coating comprises: (A) an aminosilane material which is
  • R (RO) x R (3-x) SiR 1 NHR 2 (I)
  • R 1 is an alkylene radical having 2 to 4 carbon atoms or a divalent aliphatic ether radical having 3 to 8 carbon atoms
  • R 2 is hydrogen or an alkylene radical of 2 to 4 carbon atoms tipped with a primary amine group
  • x is
  • the radicals R are preferably alkyl, for example methyl, ethyl, hexy l or octyl, aryl, for example phenyl, or aralkyl, for example benzyl.
  • the alkylene radical R 1 is preferably -(CH 2 ) 3 -, -(CH 2 ) 4 - or methyl-substituted trimethylene, or can be -(CH 2 ) 3 -O-(CH 2 ) 2 , -(CH 2 ) 3 -O-(CH 2 ) 3 - or -CH 2 -O-(CH 2 ) 2 -.
  • R 2 is preferably hydrogen or -CH 2 CH 2 NH 2 . It may be preferred to seoarate any ether oxygen atom in R and R 1 by at least two carbon atoms from the nearest heteroatom.
  • Examples of primary amine-functional silanes of formula (I) are: (CH 3 O) 3 Si(CH 2 ) 3 NH(CH 2 ) 2 NH 2 ; (CH 3 CH 2 OCH 2 CH 2 O) 3 Si(CH 2 ) 2 NH 2 ;
  • the primary amine-functional silane (I) is preferably used as such in the primer composition. It can however be replaced wholly or in part by a reaction product of the primary amine-functional silane (I) and an epoxy-functional silane ( I I ) .
  • the group A i n the epoxy-functi onal si l ane ( I I ) i s p referabl y a gl yci doxy-substi tuted alkyl group, for example 3-glycidoxypropyl.
  • the epoxy-functional silane (II) can for example be 3-glycidoxypropyl trimethoxy silane, 3-glycidoxypropyl diethoxy methoxy silane, 2- glycidoxypropyl trimethoxy silane, 3-(3,4-epoxycyclohexyl)- propyl trimethoxy silane or 2-(3,4-epoxy-4-methylcyclohexyl)-ethyl trimethoxy silane.
  • Examples of preferred reaction products of an amine-functional silane (I) and an epoxy-functional silane (II) are:
  • the aminosilane (I) and the epoxysilane (II) can be reacted at 20-80°C, preferably using 0.4-1.2 primary amine groups of aminosilane (I) per epoxide group in (II).
  • the primary amine-functional silane (I) is replaced wholly or in part by a reaction product of the primary amine-functional silane (I) and an alpha, omega-dihydroxypolydimethylsiloxane (III).
  • (I) and (III) can be reacted at 20-80°C, preferably using 0.4-1.2 alkoxy groups of aminosilane (I) per silanol group in (III).
  • the chlorinated polyolefin (B) preferably has a molecular weight of 5.000 to 50,000 and a chlorine content of 15 to 75%, most preferably 17 to 40%. by weight.
  • Chlorinated polyolefins are commercially available. They can be prepared by treating a polyolefin with chlorine in the presence of a peroxide catalyst. The chlorinatior. reaction is preferably carried out in a solvent for the polyolefin starting material.
  • the polyolefin is preferably a poly(alpha-olefin) such as polyethylene or polypropylene.
  • the polyolefin can be of high or low density, amorphous or crystalline.
  • It can be a copolymer of two or more olefins, preferably alpha-olefins.
  • Suitable chlorinated polyolefins are described for example in US-A-3561965 and US-A-4070421.
  • the chlorinated polyolefin (B) car be used in conjunction with another chlorinated hydrocarbon resin, for example a chlorinated polyterpene resin or chlorinated polystyrene.
  • the polystyrene is preferably of low molecular weight (less than 5000).
  • Such a chlorinated hydrocarbon resin preferably has a similar degree of chlorination to the chlorinated polyolefin.
  • the chlorinated hydrocarbon resin can for example be used in an amount of from 1 to 100% by weight based on the chlorinated polyolefin (B).
  • the aminosilane material (A) is generally used at 0.1 to 50% by weight based on the chlorinated material (chlorinated polyolefin (B) plus any other chlorinated hydrocarbon resin), most oreferably 1 to 20% by weight.
  • the room-temperature-curable polydiorganosiloxane (C) is preferably a polydiorganosiloxane of viscosity 700 to 1,000,000 m Pa s at 25°C. It preferably contains siliconbonded hydroxyl groups, for example an aloha, omega- dihydroxypolydiorganosiloxane, or silicon-bonded hydrolysable groups, for example a polydiorganosiloxane tipped with silicon-bonded hydrolysable groups. More preferably. it is formed of recurring diorgancsiloxy units of the formula
  • radicals R 4 which can be the same or different, represent hydrocarbon radicals having 1 to 10 carbon atoms. It is preferred that at least 50% of the radicals R 4 are methyl groups.
  • the dihydroxyoolydiorganosiloxane may further contain monoorganosiloxy groups of the formula R 4 SiO 1.5 and/or siloxy groups of the formula
  • the hydrocarbon radicals represented by the symbol R 4 in the di- and mono-organosiloxy units may suitably be selected from alkyl radicals such as methyl, ethyl, n- propyl, isopropyl, n-butyl, n-pentyl, n-hexyl, 2-ethyl hexyl or n-octyl, cycloalkyl radicals having from 4 to 8 carbon atoms such as cyclopentyl, cyclohexyl or methyl- cyclohexyl, alkenyl radicals having from 2 to 4 carbon atoms such as vinyl, allyl or buten-2-yl, and aryl radicals having from 6 to 8 carbon atoms such as phenyl, tolyl or xylyl.
  • alkyl radicals such as methyl, ethyl, n- propyl, isopropyl, n-butyl, n-pentyl
  • Alpha, omega-dihydroxypolydiorganosiloxanes can readily be prepared by well-known techni ⁇ ues described, for example, in FR-A-1134005, FR-A-1198749 and FR-A-1226745.
  • the polydiorganosiloxanes are preferably separated from volatile by-products before use, for example by the devolatilisation process described in US-A-4356116.
  • Preferred alpha, omega-dihydroxypolydimethylsiloxanes consist of successive groups of the formula (CH 3 ) 2 SiO or contain up to 10%, for example 2-10%, by mole of their groups R 4 as phenyl groups, for example in the form of
  • Alpha, omega-dihydroxypolydiorganosiloxanes are generally used with a curing agent, for example a compound containing at least two silicon-bonded hydrolysable groups per molecule.
  • a curing agent for example a compound containing at least two silicon-bonded hydrolysable groups per molecule.
  • suitable curing agents are ketiminoxysilanes, acyloxysilanes and alkoxysilanes, tetraalkyl titanates and aluminium alcoholates.
  • a ketiminoxysilane curing agent preferably contains at least two silicon-bonded hydrolysable ketiminoxy groups per molecule. Such a curing agent is preferably used at 1 to 18 parts by weight per 100 parts of alpha, omega-dihycroxy- polydiorganosiloxane.
  • the ketiminoxysilane curing agent may have the general formula:
  • Y 1 represents a hydrocarbon radical having 1 to 10 carbon atoms, which may be substituted by halogen or cyano:
  • Z represents a hydrolysable radical of the formula:
  • C 4 -C 8 alkylene radical the groups Z 1 can be the same or different: and f represents 0 or 1.
  • group Y are those listed above as examples of group R 4 in the diorganosiloxy units.
  • ketiminoxysilane curing agents are those of the formulae:
  • An acyloxysilane curing agent can for example have the formula:
  • R 5 a Si(OCOR 6 ) 4-a where R 5 is defined as for group R 4 mentioned above, R 6 is a monovalent hydrocarbon radical, e.g. of up to 8 carbon atoms, without aliphatic unsaturation and a is 0 or 1.
  • the radicals R 6 can for example be alkyl such as methyl, ethyl, n-propyl, n-butyl or n-hexyl, cycloalky! such as cyclopentyl or cyclohexyl, or aryl such as phenyl, tolyl or xylyl.
  • Examples of acyloxysi lane curing agents are: CH 3 Si ( OCOCH 3 ) 3 C 2 H 5 Si ( OCOCH 3 ) 3
  • An acyloxysilane curing agent can for example be used at 2-20 % by weight based on the alpha, omega- dihydroxypolydiorganosiloxane.
  • An alkoxysilane curing agent can for example be a tetraalkyl orthosilicate (tetraalkoxysilane) such as tetraethyl orthosilicate or an alkyl trialkoxysilane such as methyl trimethoxysilane, ethyl trimethoxysilane or methyl triethoxysilane.
  • Alkoxysilane curing agents such as tetraethyl orthosilicate are particularly preferred for use with moisture-curable polydiorganosiloxanes.
  • the room-temoerature-curable polydiorganosiloxane (C) can be moisture-curable because atmospheric moisture is usually present when coating a marine surface.
  • a moisture- curable polydiorganosiloxane can for example have hydrolysable end groups.
  • the polydiorganosiloxane (3) containing silicon-bonded hydrolysable groups is preferaply formed by combining an alpha, omega-dihydroxypolydiorganosiloxane with a compound containing at least two silicon- bonded hydrolysable groups per molecule. Examples of suitable compounds of this type are the ketiminoxysilanes anc acyloxysilanes described above as curing agents, for example methyl triacetoxy silane.
  • An alternative polydiorganosiloxane (C) tipped with silicon-bonded hydrolysable groups is an amine-tipped polydiorganosiloxane, for example an alpha, omega-diamino- polydiorganosiloxane of the formula:
  • n is an integer such that the polydiorganosiloxane has a viscosity of 700-1,000,000 m Pa s at 25°C. and R 7 and R 8 each represent hydrogen or a monovalent hydrocarbon group having 1 to 10 carbon atoms.
  • R 7 represents hydrogen and R 8 represents an alkyl group having 2 to 6 carbon atoms.
  • R 8 represents an alkyl group having 2 to 6 carbon atoms. for example ethyl. propyl, isopropyl, n-butyl or sec-butyl (but-2-yl).
  • the room-temperature-curable polydiorganosiloxane (C) is preferably used at 0.1 to 100 parts by weight, more preferably 1 to 50 parts by weight, per part by weight of the chlorinated material (chlorinated polyolefin (B) plus any other chlorinated hydrocarbon resin).
  • the primer composition may contain a catalyst for the room-temperature curing of the polydiorganosiloxane.
  • catalysts are metallic and organometallic salts of carboxylic acids.
  • Metallic salts may be salts of tin, lead, nickel, cobalt, iron, chromium, zinc or manganese, for example stannous octoate.
  • Preferred organometallic salts are diorganotin carboxylate compounds such as dibutyltin dilaurate or dibutyltin acetate.
  • Organic titanium derivatives containing at least one -Ti-O-Si- or -Ti-O-C- linkage, e.g. an alkanol amine titanate, and organic zirconium derivatives can be used as catalyst, as described in US-A-4525565.
  • the primer compositions preferably contain an organic diluent which can for example be an aliphatic, cycloaliphatic or aromatic hydrocarbon which is optionally halogenated such as n-heptane, n-octane, cyclohexane, methylcyclohexane, toluene, xylene, mesitylene, cumene, tetrahydronaphthalene, perchloroethylene, trichloroethane, tetrachloroethane, chlorobenzene or orthodichlorobenzene, an aliphatic or cycloal iphatic ketone such as methylethylketone, methylisobutylketone, methylisoamylketone, cyclohexanone or isophorone: an ether such as a dialkyl ether of ethylene glycol or propylene glycol, or an ester such as ethyl acetate, butyl
  • the diluent is preferably a solvent for the chlorinated polyolefin (B), including any other chlorinated hydrocarbon resin present.
  • the weight ratio of diluent to chlorinated polyolefin plus any other chlorinated hydrocarbon resin is preferably in the range 1:3 to 20:1, more preferably 2:3 to 10:1.
  • the weight ratio of diluent to room-temoerature- curable polydiorganosiloxane is usually 1:50 to 20:1, preferably 1:10 to 3:1.
  • the primer composition can be prepared by mixing the aminosilane material (A) and the chlorinated polyolefin (B) with the room-temperature-curable polydiorganosiloxane (C).
  • the chlorinated polyolefin (B) and any other chlorinated hydrocarbon resin present are preferably dissolved in an organic solvent before mixing with the aminosilane material (A) and the polydiorganosiloxane (C).
  • the primer composition can also contain additives selected from pigments, mineral fillers, thixotropic agents, stabilisers, surfactants, antioxidants and plasticisers. It may be preferred to include colouring pigments in the primer composition so that it can be overcoated by a fouling-resistant layer of clear RTV silicone rubber. When incorporating pigments, it may be necessary to take precautionary steps to avoid any moisture present in the pigment from instigating premature curing of the room-temperature-curable polydiorganosiloxane (C). The simplest precaution is to ensure that any pigments used are thoroughly dry.
  • the pigments can be dispersed in a diluent, preferably a polydiorganosiloxane, which inhibits reaction of any moisture present in the pigment with the room-temperature-curable polydiorganosiloxane (C).
  • the pigment can for example be dispersed in a non-reactive polydiorganosiloxane oil such as a methyltipped polydimethylsiloxane oil before the pigment contacts the room-temperature-curable polydiorganosiloxane (C) (including any curing agent therefor) and preferably also before the pigment contacts the aminosilane material (A).
  • the pigment is dispersed in a liquid hydroxyl-tipped polydiorganosiloxane before the pigment contacts the aminosilane material (A) or any curing agent or material containing silicon-bonded hydrolysable groups which forms part of the room-temperature-curable polydidrganosiloxane (C).
  • the liquid hydroxyl-tipped polydiorganosiloxane used as dispersion medium will generally become co-cured with the room-temperature-curable polydiorganosiloxane (C). It can itself be used as the room-temperature-curable polydiorganosiloxane (C), in conjunction with a curing agent added later.
  • a liquid hydroxyl-tipped polydiorganosiloxane used as dispersion medium for the pigment forms only part of the polydiorganosiloxane (C); for example it can be used with a later-added moisture-curable polydiorganosiloxane (C) tipped with hydrolysable groups.
  • the primer composition is particularly effective in promoting adhesion to organic resin substrates such as neoprene rubber, chlorinated rubber, block copolymer rubbers such as polystyrene/polybutadiene or polystyrene/poly(ethylene-butylene) rubbers, polyurethanes, (both elastomers and thermoplastic resins), epoxy coatings, vinyl resins such as vinyl chloride polymers or alkyd resins.
  • organic resin substrates such as neoprene rubber, chlorinated rubber, block copolymer rubbers such as polystyrene/polybutadiene or polystyrene/poly(ethylene-butylene) rubbers, polyurethanes, (both elastomers and thermoplastic resins), epoxy coatings, vinyl resins such as vinyl chloride polymers or alkyd resins.
  • These resins may for example be in the form of cladding in the case of neoprene and similar rubbers, or may be previously-applied coatings, for example anticorrosive coatings which are to be covered by a silicone rubber antifouling paint, or old antifouling coatings which are to be overcoated.
  • the primer composition also promotes adhesion to metal substrates such as aluminium or steel.
  • the primer composition can be applied to the substrate by any known coating technique. Usually it is applied by spray, brush or roller.
  • the RTV silicone rubber fouling-resistant coating which is applied over the primer composition can for example be based on an alpha, omega-dihydroxypolydiorganosiloxane as described above, used with a curing agent selected from those described above and optionally a catalyst selected from those described above.
  • the RTV silicone rubber can be a polydiorganosiloxane tipped with silicon-bonded hydrolysable groups as described above, for example silicon-bonded ketiminoxy or acyloxy groups.
  • the RTV silicone rubber coating preferably includes a non-reactive silicone oil, for example of the formula: Q 3 Si-O-(SiQ 2 -
  • each group Q represents a hydrocarbon radical having 1-10 carbon atoms and n is an integer such that the silicone oil has a viscosity of 20 to 5000 m Pa s.
  • At least 10% of the groups Q are generally methyl groups and at least 2% of the groups Q are preferably phenyl groups.
  • At least 25% of the -SiQ 2 -O- units are methylphenylsiloxane units.
  • the non-reactive silicone oil is a methyl-terminated poly(- methylphenylsiloxane).
  • the oil preferably has a viscosity of 20 to 1000 m Pa s and is preferably used at 1 to 50%, most preferably 2 to 20%, by weight based on the RTV silicone rubber.
  • An example of a preferred non-reactive silicone oil is that sold under the Trade Mark "Rhodorsil Huile 550". The non-reactive silicone oil improves the resistance of the composition to aquatic fouling.
  • the RTV silicone rubber composition can contain a non-reactive fluid organic hydrocarbon, for example a lubricating mineral oil such as white oil, a low molecular weight polybutene or petrolatum or a liquid paraffin/petrolatum mixture.
  • a non-reactive fluid organic hydrocarbon is preferably absent from the primer composition.
  • the primer composition improves the overall adhesion of the RTV silicone rubber to the substrate to a greater extent than can be achieved in the absence of any of the essential components (A), (B) and (C).
  • the aminosilane material (A) and chlorinated polyolefin (B) ensure strong adhesion of the primer to the RTV silicone rubber and to the organic resin substrate respectively.
  • a composition comprising aminosilane material (A), chlorinated polyolefin (B) and solvent is applied to many organic resin substrates it is rapidly absorbed by the substrate, so that adhesion of a subsequently applied RTV silicone rubber coating is poor unless it is applied very soon.
  • the room-temperature-curable polydiorganosi loxane (C) counteracts the tendency for the primer composition to be absorbed by the substrate, allowing a much longer time period, for example up to a week or even longer, within which overcoating with an RTV silicone rubber composition can be achieved with good adhesion.
  • the primer composition according to the invention has much greater adhesion to many substrates, in particular neoprene, chloroprene or hydrocarbon rubbers, than a composition which does not contain chlorinated polyolefin.
  • substrates including those such as epoxy resin where the simple combination of room-temperature-curable polydiorganosiloxane and aminosilane material gives good adhesion
  • the chlorinated polyolefin improves the resistance to sea water immersion: good adhesion of the primer composition to the substrate and of the RTV silicone rubber top coat to the primer composition is maintained even after 18 months or more of immersion in sea water.
  • Example 1 The invention is illustrated by the following Examples in which parts and percentages are by weight.
  • Example 1 The invention is illustrated by the following Examples in which parts and percentages are by weight.
  • the room-temperature-curable polydiorganosiloxane composition comprised an alpha, omega-dihydroxypoly- dimethylsiloxane used with a ketiminoxysilane curing agent.
  • the resulting primer composition was applied to a neoprene rubber substrate, and also to substrates coated with epoxy resin, polyurethane, vinyl resin and alkyd resin anticorrosive paints, and to a substrate having the residue of an old antifouling paint based on rosin, a vinyl chloride copolymer and cuprous oxide.
  • primer composition could be overcoated with an RTV silicone rubber fouling-resistant composition based on an alpha, omega-dihydroxypolydiorganosiloxane with a ketiminoxysilane curing agent and a non-reactive poly(- methyl phenyl siloxane) oil about 10 minutes after application of the primer composition with good adhesion of the RTV composition, and could also be overcoated with the RTV composition 24 hours later with good adhesion.
  • RTV silicone rubber fouling-resistant composition based on an alpha, omega-dihydroxypolydiorganosiloxane with a ketiminoxysilane curing agent and a non-reactive poly(- methyl phenyl siloxane) oil about 10 minutes after application of the primer composition with good adhesion of the RTV composition, and could also be overcoated with the RTV composition 24 hours later with good adhesion.
  • the overcoated materials were immersed in sea water.
  • the resulting pigment dispersion was mixed with 36.4 parts of room-temperature-curable polydimethylsiloxane tipped with ketiminoxy groups, 8.3 parts of the solution of chlorinated polyethylene and N-(2-aminoethyl)-3-aminopropyl trimethoxy silane described in Example 1 and 8.2 parts of methyl isoamyl ketone.
  • the resulting primer composition was applied to epoxy resin, neoprene rubber and urethane rubber substrates. These samples were overcoated after 16 to 48 hours with the RTV silicone rubber of Example 1. The overcoated materials were immersed in sea water. Adhesion between the primer composition and the substrates, and between the RTV silicone rubber fouling-resistant coating and the primer composition, remained strong after 16 months' immersion in sea water.
  • Example 3
  • pigments and fillers titanium dioxide, barytes, black iron oxide and fumed silica
  • the resulting pigment dispersion was mixed with 7.6 parts of the solution of chlorinated polyethylene and N-(2-aminoethyl)-3-aminopropyl trimethoxy silane described in Example 1, 30.9 parts of room-temperature-curable polydimethylsiloxane tipped with ketiminoxy groups, 0.03 part of dibutyltin dilaurate and 10.0 parts of methyl isoamyl ketone.
  • the resulting primer composition was applied to substrates of epoxy resin, aluminium, urethane rubber, neoprene rubber, a substrate having a residue of old antifouling paint as described in Example 1, polystyrene/polybutadiene block copolymer rubber and polystyrene/poly(ethylene-butylene) block copolymer rubber. These samples were overcoated after 16 to 48 hours with the RTV silicone rubber of Example 1.
  • the overcoated materials were immersed in sea water.

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Abstract

A primer composition for application to a substrate to promote adhesion of a room-temperature-vulcanisable silicone rubber coating comprises (A) an aminosilane material, (B) a chlorinated polyolefin and (C) a room-temperature-curable polydiorganosiloxane. The aminosilane material (A) is a primary amine-functional silane or the reaction product of a primary amine-functional silane with an epoxy-functional silane or an alpha, omega-dihydroxypolydimethylsiloxane oil.

Description

COATING COMPOSITION
Field of the invention
This invention relates to a primer composition for application to a substrate to promote adhesion of a room-temperature-vulcanisable (RTV) silicone rubber coating.
RTV silicone rubber coatings are applied to underwater surfaces, for example ships' hulls. the cooling water inlets and outlets of power stations, fish-farming equipment and the underwater and splash-zone surfaces of oil production platforms, to inhibit fouling by aquatic organisms such as algae and barnacles.
Background of the invention
Silicone rubber fouling-resistant coatings are described for example in GB-A-1307001, GB-A-1470465, GB-A- 1581727, GB-A-2141436, EP-A-16195 and US-A-3702773. RTV silicone rubber coatings have also been suggested as coatings inhibiting the adhesion of ice, for example on the superstructure and topsides of ships. A problem in the use of such RTV silicone rubber coatings is that it is difficult to make them adhere well to substrates. This problem is discussed in EP-A-16195 which proposes applying the RTV silicone rubber as a cladding on a fabric backing. Various primer compositions have been suggested for room-temperature-vulcanisable silicone rubber antifoulings. US-A-3702778 proposes a crosslinkable silicone paste. EP- A-89066 proposes a mixture of an epoxysilane and a silane containing an unsaturated hydrocarbon group. JP-A-53- 137231, JP-A-53-137233 and JP-A-53-137234 propose various elastomeric materials such as polyurethane, natural rubber, chloroprene or neoprene rubber or butyral/silicone rubber. EP-A-323906 and EP-A-329375 propose a silicone resin containing an aminosilane.
US-A-4070421 describes the use of chlorinated polyethylene as a primer for improving adhesion of coatings on polyolefin surfaces.
Summary of the invention
A primer composition according to the invention for application to a substrate to promote adhesion of an RTV silicone rubber coating comprises: (A) an aminosilane material which is
(i) a primary amine-functional silane of the formula:
(RO)xR(3-x)SiR1NHR2 (I) where the radicals R, which can be the same or different, are monovalent hydrocarbon radicals having 1 to 12 carbon atoms and optionally containing an ether linkage: R1 is an alkylene radical having 2 to 4 carbon atoms or a divalent aliphatic ether radical having 3 to 8 carbon atoms; R2 is hydrogen or an alkylene radical of 2 to 4 carbon atoms tipped with a primary amine group; and x is
2 or 3: or
(ii) the reaction product of a primary amine-functional silane of the formula (I) with an epoxy-functional silane of the formula: A - Si(B)a(OB)(3-a) (II) where A is an epoxide-substituted monovalent hydrocarbon radical having 4 to 12 carbon atoms; the radicals B, which can be the same or different, are alkyl radicals having 1 to 4 carbon atoms; and a is 0 or 1; or (iii) the reaction product of a primary amine-functional silane of the formula (I) with an alpha, omega- dihydroxypolydimethylsiloxane oil of the formula:
HO(Si(CH3)2O)yH (III) in which y is 2 to 60;
(B) a chlorinated polyolefin: and
(C) a room-temperature-curable polydiorganosiloxane.
Detailed disclosure
In the pri mary amine-functional silane of formula (I) the radicals R are preferably alkyl, for example methyl, ethyl, hexy l or octyl, aryl, for example phenyl, or aralkyl, for example benzyl. The alkylene radical R1 is preferably -(CH2)3-, -(CH2)4- or methyl-substituted trimethylene, or can be -(CH2)3-O-(CH2)2, -(CH2)3-O-(CH2)3- or -CH2-O-(CH2)2-. R2 is preferably hydrogen or -CH2CH2NH2. It may be preferred to seoarate any ether oxygen atom in R and R1 by at least two carbon atoms from the nearest heteroatom. Examples of primary amine-functional silanes of formula (I) are: (CH3O)3Si(CH2)3NH(CH2)2NH2; (CH3CH2OCH2CH2O)3Si(CH2)2NH2;
(C2H5O)3Si (CH2)3NH2; (CH3OCH2CH2O)3Si(CH2)3NH2;
(C2H5O)3Si(CH2)3O(CH2)3NH2; (C2H5O)2C6H5Si(CH2)3NH2;
(C2H5O)3SiCH2O(CH2)2NH2; (C2H5O)3Si(CH2)3O(CH2)2NH ; and
(C2H5O)2CH3Si(CH2)3NH2. Mixtures of two or more primary amine-functional silanes (I) may be used if desired.
The primary amine-functional silane (I) is preferably used as such in the primer composition. It can however be replaced wholly or in part by a reaction product of the primary amine-functional silane (I) and an epoxy-functional silane ( I I ) . The group A i n the epoxy-functi onal si l ane ( I I ) i s p referabl y a gl yci doxy-substi tuted alkyl group, for example 3-glycidoxypropyl. The epoxy-functional silane (II) can for example be 3-glycidoxypropyl trimethoxy silane, 3-glycidoxypropyl diethoxy methoxy silane, 2- glycidoxypropyl trimethoxy silane, 3-(3,4-epoxycyclohexyl)- propyl trimethoxy silane or 2-(3,4-epoxy-4-methylcyclohexyl)-ethyl trimethoxy silane. Examples of preferred reaction products of an amine-functional silane (I) and an epoxy-functional silane (II) are:
(C2H5O)3Si(CH2)3 - NH - CH2 - CH - CH2 - O(CH2)3Si(OCH3)3
Figure imgf000006_0002
(CH3O)3Si(CH2)3 - NH - CH2 - CH - CH2 - O(CH2)3Si(OCH3)3
Figure imgf000006_0001
(CH3O)3Si(CH2)3 - NH-(CH2)2-NH-CH2-CH-CH2-O(CH2)3Si(OCH3)3
Figure imgf000006_0003
The aminosilane (I) and the epoxysilane (II) can be reacted at 20-80°C, preferably using 0.4-1.2 primary amine groups of aminosilane (I) per epoxide group in (II).
In a further alternative, the primary amine-functional silane (I) is replaced wholly or in part by a reaction product of the primary amine-functional silane (I) and an alpha, omega-dihydroxypolydimethylsiloxane (III). (I) and (III) can be reacted at 20-80°C, preferably using 0.4-1.2 alkoxy groups of aminosilane (I) per silanol group in (III).
The chlorinated polyolefin (B) preferably has a molecular weight of 5.000 to 50,000 and a chlorine content of 15 to 75%, most preferably 17 to 40%. by weight. Chlorinated polyolefins are commercially available. They can be prepared by treating a polyolefin with chlorine in the presence of a peroxide catalyst. The chlorinatior. reaction is preferably carried out in a solvent for the polyolefin starting material. The polyolefin is preferably a poly(alpha-olefin) such as polyethylene or polypropylene. The polyolefin can be of high or low density, amorphous or crystalline. It can be a copolymer of two or more olefins, preferably alpha-olefins. Suitable chlorinated polyolefins are described for example in US-A-3561965 and US-A-4070421. The chlorinated polyolefin (B) car, be used in conjunction with another chlorinated hydrocarbon resin, for example a chlorinated polyterpene resin or chlorinated polystyrene. The polystyrene is preferably of low molecular weight (less than 5000). Such a chlorinated hydrocarbon resin preferably has a similar degree of chlorination to the chlorinated polyolefin. The chlorinated hydrocarbon resin can for example be used in an amount of from 1 to 100% by weight based on the chlorinated polyolefin (B). The aminosilane material (A) is generally used at 0.1 to 50% by weight based on the chlorinated material (chlorinated polyolefin (B) plus any other chlorinated hydrocarbon resin), most oreferably 1 to 20% by weight.
The room-temperature-curable polydiorganosiloxane (C) is preferably a polydiorganosiloxane of viscosity 700 to 1,000,000 m Pa s at 25°C. It preferably contains siliconbonded hydroxyl groups, for example an aloha, omega- dihydroxypolydiorganosiloxane, or silicon-bonded hydrolysable groups, for example a polydiorganosiloxane tipped with silicon-bonded hydrolysable groups. More preferably. it is formed of recurring diorgancsiloxy units of the formula
- R4 2SiO - where the radicals R4, which can be the same or different, represent hydrocarbon radicals having 1 to 10 carbon atoms. It is preferred that at least 50% of the radicals R4 are methyl groups. The dihydroxyoolydiorganosiloxane may further contain monoorganosiloxy groups of the formula R4SiO1.5 and/or siloxy groups of the formula
SiO2 in a maximum proportion of 2% with respect to the number of diorganosiloxy groups R4 2SiO. The hydrocarbon radicals represented by the symbol R4 in the di- and mono-organosiloxy units may suitably be selected from alkyl radicals such as methyl, ethyl, n- propyl, isopropyl, n-butyl, n-pentyl, n-hexyl, 2-ethyl hexyl or n-octyl, cycloalkyl radicals having from 4 to 8 carbon atoms such as cyclopentyl, cyclohexyl or methyl- cyclohexyl, alkenyl radicals having from 2 to 4 carbon atoms such as vinyl, allyl or buten-2-yl, and aryl radicals having from 6 to 8 carbon atoms such as phenyl, tolyl or xylyl.
As preferred examples cf the groups represented by R4 2SiO the following formulae are noted:
(CH3)2SiO CH3(CH2=CH)SiO
CH3(C6H5)SiO (C6H5)2SiO One example of a suitable alpha, omega-dihydroxy polydimethylsiloxane is that sold by Rhone Poulenc under the trade name "48V 3500".
Alpha, omega-dihydroxypolydiorganosiloxanes can readily be prepared by well-known techniαues described, for example, in FR-A-1134005, FR-A-1198749 and FR-A-1226745. The polydiorganosiloxanes are preferably separated from volatile by-products before use, for example by the devolatilisation process described in US-A-4356116.
Preferred alpha, omega-dihydroxypolydimethylsiloxanes consist of successive groups of the formula (CH3)2SiO or contain up to 10%, for example 2-10%, by mole of their groups R4 as phenyl groups, for example in the form of
(C6H5)2SiO units.
Alpha, omega-dihydroxypolydiorganosiloxanes are generally used with a curing agent, for example a compound containing at least two silicon-bonded hydrolysable groups per molecule. Examples of suitable curing agents are ketiminoxysilanes, acyloxysilanes and alkoxysilanes, tetraalkyl titanates and aluminium alcoholates.
A ketiminoxysilane curing agent preferably contains at least two silicon-bonded hydrolysable ketiminoxy groups per molecule. Such a curing agent is preferably used at 1 to 18 parts by weight per 100 parts of alpha, omega-dihycroxy- polydiorganosiloxane. The ketiminoxysilane curing agent may have the general formula:
Y1 fSlZ1 (4-f) in which:
Y1 represents a hydrocarbon radical having 1 to 10 carbon atoms, which may be substituted by halogen or cyano:
Z represents a hydrolysable radical of the formula:
(Z2)2C = NO- or
Figure imgf000009_0001
in which the groups Z2, which can be the same or difrerent, represent C1-C8 hydrocarbon radicals and E1 represents a
C4-C8 alkylene radical: the groups Z1 can be the same or different: and f represents 0 or 1. Examples of group Y are those listed above as examples of group R4 in the diorganosiloxy units.
Examples of ketiminoxysilane curing agents are those of the formulae:
CH3Si [ON = C(CH3)2]3, CH3Si [ON = C(CH3)C2H5]3,
(CH2 = CH)Si [ON = C(CH3)C2H5]3, C6H5Si [ON = C(CH3)2]3,
CH3Si [ON = C (C2H5)(CH2)3CH3]3,
(CH3)2C = NOSi [ON = C(CH3)C2H5]3. CH3Si [ON =
CH3Si [ON = 5]3
Figure imgf000010_0001
Si[ON = C(C2H5)(CH3)]4 or Si [ON = C(CH3)2]4 and their mixtures. An acyloxysilane curing agent can for example have the formula:
R5 aSi(OCOR6)4-a where R5 is defined as for group R4 mentioned above, R6 is a monovalent hydrocarbon radical, e.g. of up to 8 carbon atoms, without aliphatic unsaturation and a is 0 or 1. The radicals R6 can for example be alkyl such as methyl, ethyl, n-propyl, n-butyl or n-hexyl, cycloalky! such as cyclopentyl or cyclohexyl, or aryl such as phenyl, tolyl or xylyl. Examples of acyloxysi lane curing agents are: CH3 Si ( OCOCH3 )3 C2H5Si ( OCOCH 3 ) 3
CH 2 = CHS i ( OCOCH3 ) 3 C6H5 Si ( OCOCH3 ) 3
CH3Si(OCOCH(C2H5)(CH2)3CH3)3 CF3CH2CH2Si(OCOC6H5)3
An acyloxysilane curing agent can for example be used at 2-20 % by weight based on the alpha, omega- dihydroxypolydiorganosiloxane.
An alkoxysilane curing agent can for example be a tetraalkyl orthosilicate (tetraalkoxysilane) such as tetraethyl orthosilicate or an alkyl trialkoxysilane such as methyl trimethoxysilane, ethyl trimethoxysilane or methyl triethoxysilane. Alkoxysilane curing agents such as tetraethyl orthosilicate are particularly preferred for use with moisture-curable polydiorganosiloxanes.
The room-temoerature-curable polydiorganosiloxane (C) can be moisture-curable because atmospheric moisture is usually present when coating a marine surface. A moisture- curable polydiorganosiloxane can for example have hydrolysable end groups. The polydiorganosiloxane (3) containing silicon-bonded hydrolysable groups is preferaply formed by combining an alpha, omega-dihydroxypolydiorganosiloxane with a compound containing at least two silicon- bonded hydrolysable groups per molecule. Examples of suitable compounds of this type are the ketiminoxysilanes anc acyloxysilanes described above as curing agents, for example methyl triacetoxy silane. which form polydiorganosiloxanes tipped with silicon-bonded hydrolysable ketirmnoxy or acyloxy groups. Reaction between the silicon-bonded hydroxyl groups of the alpha, omega-dihydroxy- polydiorganosiloxane and the silicon-bonded hydrolysable groups of the said compound generally takes place as these materials are combined, so that the polydiorganosiloxane (C) is at least partially tipped with silicon-bonded hydroxyl groups. An alternative polydiorganosiloxane (C) tipped with silicon-bonded hydrolysable groups is an amine-tipped polydiorganosiloxane, for example an alpha, omega-diamino- polydiorganosiloxane of the formula:
Figure imgf000011_0001
where R4 is defined as above, n is an integer such that the polydiorganosiloxane has a viscosity of 700-1,000,000 m Pa s at 25°C. and R7 and R8 each represent hydrogen or a monovalent hydrocarbon group having 1 to 10 carbon atoms.
Most preferably R7 represents hydrogen and R8 represents an alkyl group having 2 to 6 carbon atoms. for example ethyl. propyl, isopropyl, n-butyl or sec-butyl (but-2-yl).
Examples of amine-tioped polydiorganosiloxanes are sold under the Trade Marks "Silgan 500" and "Silgan 501J".
The room-temperature-curable polydiorganosiloxane (C) is preferably used at 0.1 to 100 parts by weight, more preferably 1 to 50 parts by weight, per part by weight of the chlorinated material (chlorinated polyolefin (B) plus any other chlorinated hydrocarbon resin).
The primer composition may contain a catalyst for the room-temperature curing of the polydiorganosiloxane. Examples of catalysts are metallic and organometallic salts of carboxylic acids. Metallic salts may be salts of tin, lead, nickel, cobalt, iron, chromium, zinc or manganese, for example stannous octoate. Preferred organometallic salts are diorganotin carboxylate compounds such as dibutyltin dilaurate or dibutyltin acetate. Organic titanium derivatives containing at least one -Ti-O-Si- or -Ti-O-C- linkage, e.g. an alkanol amine titanate, and organic zirconium derivatives can be used as catalyst, as described in US-A-4525565.
The primer compositions preferably contain an organic diluent which can for example be an aliphatic, cycloaliphatic or aromatic hydrocarbon which is optionally halogenated such as n-heptane, n-octane, cyclohexane, methylcyclohexane, toluene, xylene, mesitylene, cumene, tetrahydronaphthalene, perchloroethylene, trichloroethane, tetrachloroethane, chlorobenzene or orthodichlorobenzene, an aliphatic or cycloal iphatic ketone such as methylethylketone, methylisobutylketone, methylisoamylketone, cyclohexanone or isophorone: an ether such as a dialkyl ether of ethylene glycol or propylene glycol, or an ester such as ethyl acetate, butyl acetate or ethoxyethyl acetate. The diluent is preferably a solvent for the chlorinated polyolefin (B), including any other chlorinated hydrocarbon resin present. The weight ratio of diluent to chlorinated polyolefin plus any other chlorinated hydrocarbon resin is preferably in the range 1:3 to 20:1, more preferably 2:3 to 10:1. The weight ratio of diluent to room-temoerature- curable polydiorganosiloxane is usually 1:50 to 20:1, preferably 1:10 to 3:1.
The primer composition can be prepared by mixing the aminosilane material (A) and the chlorinated polyolefin (B) with the room-temperature-curable polydiorganosiloxane (C). The chlorinated polyolefin (B) and any other chlorinated hydrocarbon resin present are preferably dissolved in an organic solvent before mixing with the aminosilane material (A) and the polydiorganosiloxane (C).
The primer composition can also contain additives selected from pigments, mineral fillers, thixotropic agents, stabilisers, surfactants, antioxidants and plasticisers. It may be preferred to include colouring pigments in the primer composition so that it can be overcoated by a fouling-resistant layer of clear RTV silicone rubber. When incorporating pigments, it may be necessary to take precautionary steps to avoid any moisture present in the pigment from instigating premature curing of the room-temperature-curable polydiorganosiloxane (C). The simplest precaution is to ensure that any pigments used are thoroughly dry. Alternatively, the pigments can be dispersed in a diluent, preferably a polydiorganosiloxane, which inhibits reaction of any moisture present in the pigment with the room-temperature-curable polydiorganosiloxane (C). The pigment can for example be dispersed in a non-reactive polydiorganosiloxane oil such as a methyltipped polydimethylsiloxane oil before the pigment contacts the room-temperature-curable polydiorganosiloxane (C) (including any curing agent therefor) and preferably also before the pigment contacts the aminosilane material (A). In an alternative procedure the pigment is dispersed in a liquid hydroxyl-tipped polydiorganosiloxane before the pigment contacts the aminosilane material (A) or any curing agent or material containing silicon-bonded hydrolysable groups which forms part of the room-temperature-curable polydidrganosiloxane (C). When this alternative procedure is used, the liquid hydroxyl-tipped polydiorganosiloxane used as dispersion medium will generally become co-cured with the room-temperature-curable polydiorganosiloxane (C). It can itself be used as the room-temperature-curable polydiorganosiloxane (C), in conjunction with a curing agent added later. It is generally preferred however that a liquid hydroxyl-tipped polydiorganosiloxane used as dispersion medium for the pigment forms only part of the polydiorganosiloxane (C); for example it can be used with a later-added moisture-curable polydiorganosiloxane (C) tipped with hydrolysable groups.
The primer composition is particularly effective in promoting adhesion to organic resin substrates such as neoprene rubber, chlorinated rubber, block copolymer rubbers such as polystyrene/polybutadiene or polystyrene/poly(ethylene-butylene) rubbers, polyurethanes, (both elastomers and thermoplastic resins), epoxy coatings, vinyl resins such as vinyl chloride polymers or alkyd resins. These resins may for example be in the form of cladding in the case of neoprene and similar rubbers, or may be previously-applied coatings, for example anticorrosive coatings which are to be covered by a silicone rubber antifouling paint, or old antifouling coatings which are to be overcoated. The primer composition also promotes adhesion to metal substrates such as aluminium or steel.
The primer composition can be applied to the substrate by any known coating technique. Usually it is applied by spray, brush or roller. The RTV silicone rubber fouling-resistant coating which is applied over the primer composition can for example be based on an alpha, omega-dihydroxypolydiorganosiloxane as described above, used with a curing agent selected from those described above and optionally a catalyst selected from those described above. Alternative ly, the RTV silicone rubber can be a polydiorganosiloxane tipped with silicon-bonded hydrolysable groups as described above, for example silicon-bonded ketiminoxy or acyloxy groups. It may be preferred that the curing agent or silicon-bonded hydrolysable groups in the room-temoerature- curable diorganopolysiloxane (C) in the primer composition and the curing agent or silicon-bonded hydrolysable groups in the RTV silicone rubber coating are the same. The RTV silicone rubber coating preferably includes a non-reactive silicone oil, for example of the formula: Q3Si-O-(SiQ2-
O-)nSiQ3, wherein each group Q represents a hydrocarbon radical having 1-10 carbon atoms and n is an integer such that the silicone oil has a viscosity of 20 to 5000 m Pa s. At least 10% of the groups Q are generally methyl groups and at least 2% of the groups Q are preferably phenyl groups. Most preferably, at least 25% of the -SiQ2-O- units are methylphenylsiloxane units. Most preferably the non-reactive silicone oil is a methyl-terminated poly(- methylphenylsiloxane). The oil preferably has a viscosity of 20 to 1000 m Pa s and is preferably used at 1 to 50%, most preferably 2 to 20%, by weight based on the RTV silicone rubber. An example of a preferred non-reactive silicone oil is that sold under the Trade Mark "Rhodorsil Huile 550". The non-reactive silicone oil improves the resistance of the composition to aquatic fouling.
Instead of, or in addition to, the non-reactive silicone oil, the RTV silicone rubber composition can contain a non-reactive fluid organic hydrocarbon, for example a lubricating mineral oil such as white oil, a low molecular weight polybutene or petrolatum or a liquid paraffin/petrolatum mixture. Such a non-reactive fluid organic hydrocarbon is preferably absent from the primer composition.
The primer composition improves the overall adhesion of the RTV silicone rubber to the substrate to a greater extent than can be achieved in the absence of any of the essential components (A), (B) and (C). The aminosilane material (A) and chlorinated polyolefin (B) ensure strong adhesion of the primer to the RTV silicone rubber and to the organic resin substrate respectively. We have however found that when a composition comprising aminosilane material (A), chlorinated polyolefin (B) and solvent is applied to many organic resin substrates it is rapidly absorbed by the substrate, so that adhesion of a subsequently applied RTV silicone rubber coating is poor unless it is applied very soon. The room-temperature-curable polydiorganosi loxane (C) counteracts the tendency for the primer composition to be absorbed by the substrate, allowing a much longer time period, for example up to a week or even longer, within which overcoating with an RTV silicone rubber composition can be achieved with good adhesion.
The primer composition according to the invention has much greater adhesion to many substrates, in particular neoprene, chloroprene or hydrocarbon rubbers, than a composition which does not contain chlorinated polyolefin. On all substrates, including those such as epoxy resin where the simple combination of room-temperature-curable polydiorganosiloxane and aminosilane material gives good adhesion, the chlorinated polyolefin improves the resistance to sea water immersion: good adhesion of the primer composition to the substrate and of the RTV silicone rubber top coat to the primer composition is maintained even after 18 months or more of immersion in sea water.
The invention is illustrated by the following Examples in which parts and percentages are by weight. Example 1
25 parts of a 40% solution in xylene of a chlorinated polyethylene (chlorine content 22%) was mixed with 2 parts
N-(2-aminoethyl)-3-aminopropyl trimethoxy silane and diluted with 73 parts xylene. 14 parts of the resulting composition was mixed with 61 parts of a room-temperature-curable polydiorganosiloxane composition and 25 parts methyl isoamyl ketone solvent. The room-temperature-curable polydiorganosiloxane composition comprised an alpha, omega-dihydroxypoly- dimethylsiloxane used with a ketiminoxysilane curing agent.
The resulting primer composition was applied to a neoprene rubber substrate, and also to substrates coated with epoxy resin, polyurethane, vinyl resin and alkyd resin anticorrosive paints, and to a substrate having the residue of an old antifouling paint based on rosin, a vinyl chloride copolymer and cuprous oxide. In all cases the coating of primer composition could be overcoated with an RTV silicone rubber fouling-resistant composition based on an alpha, omega-dihydroxypolydiorganosiloxane with a ketiminoxysilane curing agent and a non-reactive poly(- methyl phenyl siloxane) oil about 10 minutes after application of the primer composition with good adhesion of the RTV composition, and could also be overcoated with the RTV composition 24 hours later with good adhesion.
The overcoated materials were immersed in sea water.
Adhesion between the primer composition and the substrates, and between the RTV silicone rubber fouling-resistant coating and the primer composition, remained strong after
18 months immersion in sea water.
Example 2
29.7 parts of pigments and fillears (barytes, titanium dioxide, fumed silica and black iron oxide) and 0.1 cart of dibutyltin dilaurate curing catalyst were dispersed by milling in 6.7 parts of non-reactive methyl-tipped polydimethylsiloxane oil and 10.6 parts of methyl isoamyl ketone solvent. The resulting pigment dispersion was mixed with 36.4 parts of room-temperature-curable polydimethylsiloxane tipped with ketiminoxy groups, 8.3 parts of the solution of chlorinated polyethylene and N-(2-aminoethyl)-3-aminopropyl trimethoxy silane described in Example 1 and 8.2 parts of methyl isoamyl ketone.
The resulting primer composition was applied to epoxy resin, neoprene rubber and urethane rubber substrates. These samples were overcoated after 16 to 48 hours with the RTV silicone rubber of Example 1. The overcoated materials were immersed in sea water. Adhesion between the primer composition and the substrates, and between the RTV silicone rubber fouling-resistant coating and the primer composition, remained strong after 16 months' immersion in sea water. Example 3
28.1 parts of pigments and fillers (titanium dioxide, barytes, black iron oxide and fumed silica) were dispersed by milling in 11.5 parts of liquid hydroxyl-tipped polydimethylsiloxane with 0.5 part of wetting aid and 11.4 parts of methyl isoamyl ketone. The resulting pigment dispersion was mixed with 7.6 parts of the solution of chlorinated polyethylene and N-(2-aminoethyl)-3-aminopropyl trimethoxy silane described in Example 1, 30.9 parts of room-temperature-curable polydimethylsiloxane tipped with ketiminoxy groups, 0.03 part of dibutyltin dilaurate and 10.0 parts of methyl isoamyl ketone.
The resulting primer composition was applied to substrates of epoxy resin, aluminium, urethane rubber, neoprene rubber, a substrate having a residue of old antifouling paint as described in Example 1, polystyrene/polybutadiene block copolymer rubber and polystyrene/poly(ethylene-butylene) block copolymer rubber. These samples were overcoated after 16 to 48 hours with the RTV silicone rubber of Example 1.
The overcoated materials were immersed in sea water.
Adhesion between the primer composition and the substrates, and between the RTV silicone rubber fouling-resistant coating and the primer composition, remained strong after 6 months' immersion in sea water.

Claims

1. A primer composition for application to a substrate to promote adhesion of a room-temperature-vulcanisable silicone rubber coating, which primer composition comprises:
(A) an aminosilane material which is
(i) a primary amine-functional silane of the formula:
(RO)xR(3-x)SiR1NHR2 (I) where the radicals R, which can be the same or different, are monovalent hydrocarbon radicals having 1 to 12 carbon atoms and optionally containing an ether linkage; R1 is an alkylene radical having 2 to 4 carbon atoms or a divalent aliphatic ether radical having 3 to 8 carbon atoms: R2 is hydrogen or an alkylene radical of 2 to 4 carbon atoms tipped with a primary amino group: and x is 2 or 3: or
(ii) the reaction product of a primary amine-functional silane of the formula (I) with an epoxy-functional silane of the formula:
A- Si(B)a(OB)(3-a) (II) where A is an epoxide-substituted monovalent hydrocarbon radical having 4 to 12 carbon atoms; the radicals B, which can be the same or different, are alkyl radicals having 1 to 4 carbon atoms; and a is 0 or 1; or
(iii) the reaction product of a primary amine-functional silane of the formula (I) with an alpha, omegadihydroxypolydimethylsiloxane oil of the formula:
HO(Si(CH3)2O)yH (III) in which v is 2 to 60; (B) a chlorinated polyolefin; and
(C) a room-temperature-curable polydiorganosiloxane.
2. A primer composition according to claim 1, characterised in that the room-temperature-curable polydiorganosiloxane (C) is an alpha, omega-dihydroxypolydiorganosiloxane used in conjunction with a ketiminoxysilane curing agent.
3. A primer composition according to claim 1, characterised in that the room-temperature-curable polydiorganosiloxane (C) is an alpha, omega-dihydroxypolydiorganosiloxane used in conjunction with an acyloxysilane curing agent.
4. A primer composition according to claim 1, characterised in that the room-temperature-curable polydiorganosiloxane (C) is an alpha, omega-dihydroxypolydiorganosiloxane used in conjunction with an alkoxysilane curing agent.
5. A primer composition according to claim 1, characterised in that the room-temperature-curable polydiorganosiloxane (C) is a polydiorganosiloxane tipped with silicon-bonded hydrolysable groups.
6. A primer composition according to claim 5, characterised in that the silicon-bonded hydrolysable groups are ketiminoxy, acyloxy or amine groups.
7. A primer composition according to any of claims 1 to 6, characterised in that the chlorinated polyolefin (B) has a chlorine content of 17 to 40% by weight.
8. A primer composition according to any of claims 1 to 7, characterised in that the composition contains another chlorinated hydrocarbon resin in an amount of 1 to 100% by weight based on the chlorinated polyolefin (B).
9. A primer composition according to any of claims 1 to 8, characterised in that the aminosilane material (A) is used at 1 to 20% by weight based on the weight of chlorinated polyolefin (B) plus any other chlorinated hydrocarbon resin present in the composition.
10. A primer composition according to any of claims 1 to 9, characterised in that the weight ratio of the room- temperature-curable polydiorganosiloxane (C) to the chlorinated polyolefin (B) plus any other chlorinated hydrocarbon resin present in the composition is 1:1 to 50:1.
11. A primer composition according to any of claims 1 to 10, characterised in that a pigment is dispersed in the composition.
12. A process for preparing a primer composition in which
(A) an aminosilane material which is
(i) a primary amine-functional silane of the formula: (RO)xR(3-x)SiR1NHR2 (I) where the radicals R, which can be the same or different, are monovalent hydrocarbon radicals having 1 to 12 carbon atoms and optionally containing an ether linkage; R1 is an alkylene radical having 2 to 4 carbon atoms or a divalent aliphatic ether radical having 3 to 8 carbon atoms; R2 is hydrogen or an alkylene radical of 2 to 4 carbon atoms tipped with a primary amino group; and x is
2 or 3; or
(ii) the reaction product of a primary amine-functional silane of the formula (I) with an epoxy-functional silane of the formula:
A - Si(B)a(OB)(3-a) (II) where A is an epoxide-substituted monovalent hydrocarbon radical having 4 to 12 carbon atoms; the radicals B, which can be the same or different, are alkyl radicals having 1 to 4 carbon atoms; and a is 0 or 1; or
(iii) the reaction product of a primary amine-functional silane of the formula (I) with an alpha, omega- dihydroxypolydimethylsiloxane oil of the formula:
HO(Si(CH3)2O)yH (III) in which y is 2 to 60; and (B) a chlorinated polyolefin;
are mixed with
(C) a room-temperature-curable polydiorganosiloxane.
13. A process according to claim 12, characterised in that a pigmented primer composition is prepared by dispersing a pigment in a non-reactive polydiorganosiloxane oil and mixing with the aminosilane material (A), the chlorinated polyolefin (B) and the room-temperature-curable polydiorganosiloxane (C), said step of dispersing the pigment in polydiorganosiloxane oil being carried out before the pigment contacts the aminosilane material (A) or the room-temperature-curable polydiorganosiloxane (C).
14. A process according to claim 12, characterised in that a pigmented primer composition is prepared by dispersing a pigment in a liquid hydroxyl-tipped polydiorganosiloxane and mixing it with the aminosilane material (A), the chlorinated polyolefin (B) and the room-temperature- curable polydiorganosiloxane (C), said step of dispersing the pigment in a liquid polydiorganosiloxane being carried out before the pigment contacts the aminosilane material (A) or any curing agent or material containing silicon- bonded hydrolysable groups which forms part of the room- temperature-curable polydiorganosiloxane (C).
15. A process according to claim 12, characterised in that a pigmented primer composition is formed by dispersing a pigment in a liquid hydroxyl-tipped polydiorganosiloxane and mixing it with the aminosilane material (A), the chlorinated polyolefin (B) and a curing agent which together with the liquid hydroxyl-tipped polydiorganosiloxane forms the room-temperature-curable polydiorganosiloxane (C), said step of dispersing the pigment in a liquid polydiorganosiloxane being carried out before the pigment contacts the aminosilane material (A) or the said curing agent.
16. A process for coating a substrate with a room- temperature-vulcanisable silicone rubber, characterised in that the substrate is coated with a primer composition according to any of claims 1 to 11 and the room-temperature-vulcanisable silicone rubber composition is applied over the said primer composition.
17. A process according to claim 16, characterised in that the primer composition is as defined in any of claims 2 to 4 and the room-temperature-vulcanisable silicone rubber composition comprises an alpha, omega-dihydroxypolydiorganosiloxane used in conjunction with a curing agent of the same type as is used in the primer composition.
18. A process according to claim 16, characterised in that the primer composition is as defined in claim 5 or claim 6 and the room-temperature-vulcanisable silicone rubber composition comprises a polydiorganosiloxane tipped with silicon-bonded hydrolysable groups of the same type as those in the room-temperature-curable polydiorganosiloxane (C).
PCT/GB1991/000454 1990-03-27 1991-03-26 Coating composition WO1991014747A1 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
KR1019920702339A KR0175648B1 (en) 1990-03-27 1991-03-26 Coating composition
EP91906926A EP0521983B1 (en) 1990-03-27 1991-03-26 Coating composition
DK91906926.0T DK0521983T3 (en) 1990-03-27 1991-03-26 coating Material
CA002078144A CA2078144C (en) 1990-03-27 1991-03-26 Coating composition
AU75773/91A AU651096B2 (en) 1990-03-27 1991-03-26 Coating composition
BR919106209A BR9106209A (en) 1990-03-27 1991-03-26 COATING COMPOSITION
DE69102535T DE69102535T2 (en) 1990-03-27 1991-03-26 COATING COMPOSITION.
NO923660A NO303643B1 (en) 1990-03-27 1992-09-21 Primer for better adhesion of a silicone rubber coating to the substrate and its use
FI924303A FI101717B1 (en) 1990-03-27 1992-09-25 Primer composition and method for coating a substrate
HK134794A HK134794A (en) 1990-03-27 1994-12-01 Coating composition

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB9006840.4 1990-03-27
GB909006840A GB9006840D0 (en) 1990-03-27 1990-03-27 Coating compositions
SG152094A SG152094G (en) 1990-03-27 1994-10-18 Coating composition

Publications (1)

Publication Number Publication Date
WO1991014747A1 true WO1991014747A1 (en) 1991-10-03

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US (1) US5290601A (en)
EP (1) EP0521983B1 (en)
AU (1) AU651096B2 (en)
DE (1) DE69102535T2 (en)
DK (1) DK0521983T3 (en)
ES (1) ES2056645T3 (en)
HK (1) HK134794A (en)
SG (1) SG152094G (en)
WO (1) WO1991014747A1 (en)

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GB2300370A (en) * 1995-05-01 1996-11-06 Gen Electric Anti-fouling coating with anti-corrosive layer
EP1063270A3 (en) * 1999-06-21 2002-02-13 General Electric Company Adhesion primer for use with RTV silicones
RU2382063C2 (en) * 2005-04-05 2010-02-20 Чугоку Марин Пейнтс, Лтд. Binding coating for antifouling film based on organopolysiloxane, composite coating film and ship and submarine structure coated with said film

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US8067066B2 (en) 2003-10-03 2011-11-29 Hempel A/S Tie-coat composition comprising at least two types of functional polysiloxane compounds and a method for using the same for establishing a coating on a substrate
WO2007037483A1 (en) * 2005-09-30 2007-04-05 Kaneka Corporation Curable composition
KR100965739B1 (en) * 2006-02-17 2010-06-24 주고꾸 도료 가부시키가이샤 Curable Organopolysiloxane Compositions and Antifouling Composite Coatings
EP2723821A1 (en) 2011-06-21 2014-04-30 Akzo Nobel Coatings International B.V. Biocidal foul release coating systems
WO2015131032A1 (en) * 2014-02-28 2015-09-03 Momentive Performance Materials Inc. Tie coat composition and antifouling system
PL3048141T3 (en) 2015-01-26 2018-05-30 Avery Dennison Corporation Self adhesive fouling release coating composition
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WO1994029390A1 (en) * 1993-06-03 1994-12-22 Essex Specialty Products, Inc. Primer composition for improving the bonding of a urethane adhesive to non-porous substrates
US5466727A (en) * 1993-06-03 1995-11-14 Essex Specialty Products, Inc. Primer composition for improving the bonding of a urethane adhesive to non-porous substrates
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AU678261B2 (en) * 1993-06-03 1997-05-22 Essex Specialty Products Inc. Primer composition for improving the bonding of a urethane adhesive to non-porous substrates
GB2300370A (en) * 1995-05-01 1996-11-06 Gen Electric Anti-fouling coating with anti-corrosive layer
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EP1063270A3 (en) * 1999-06-21 2002-02-13 General Electric Company Adhesion primer for use with RTV silicones
RU2382063C2 (en) * 2005-04-05 2010-02-20 Чугоку Марин Пейнтс, Лтд. Binding coating for antifouling film based on organopolysiloxane, composite coating film and ship and submarine structure coated with said film

Also Published As

Publication number Publication date
AU651096B2 (en) 1994-07-14
EP0521983B1 (en) 1994-06-15
US5290601A (en) 1994-03-01
SG152094G (en) 1995-03-17
DK0521983T3 (en) 1994-11-14
EP0521983A1 (en) 1993-01-13
DE69102535T2 (en) 1995-01-05
AU7577391A (en) 1991-10-21
HK134794A (en) 1994-12-09
ES2056645T3 (en) 1994-10-01
DE69102535D1 (en) 1994-07-21

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