WO1991003149A1 - Water retentive matrix incorporating plastic for growing seeds and plants - Google Patents

Water retentive matrix incorporating plastic for growing seeds and plants Download PDF

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Publication number
WO1991003149A1
WO1991003149A1 PCT/US1990/004816 US9004816W WO9103149A1 WO 1991003149 A1 WO1991003149 A1 WO 1991003149A1 US 9004816 W US9004816 W US 9004816W WO 9103149 A1 WO9103149 A1 WO 9103149A1
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Prior art keywords
percent
matrix
composition
water
seed
Prior art date
Application number
PCT/US1990/004816
Other languages
French (fr)
Inventor
George Wyatt Prejean
Timothy Claud Sharp
Original Assignee
E.I. Du Pont De Nemours And Company
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Filing date
Publication date
Application filed by E.I. Du Pont De Nemours And Company filed Critical E.I. Du Pont De Nemours And Company
Publication of WO1991003149A1 publication Critical patent/WO1991003149A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C1/00Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/06Coating or dressing seed
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G24/00Growth substrates; Culture media; Apparatus or methods therefor
    • A01G24/20Growth substrates; Culture media; Apparatus or methods therefor based on or containing natural organic material
    • A01G24/28Growth substrates; Culture media; Apparatus or methods therefor based on or containing natural organic material containing peat, moss or sphagnum
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G24/00Growth substrates; Culture media; Apparatus or methods therefor
    • A01G24/30Growth substrates; Culture media; Apparatus or methods therefor based on or containing synthetic organic compounds
    • A01G24/35Growth substrates; Culture media; Apparatus or methods therefor based on or containing synthetic organic compounds containing water-absorbing polymers
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G24/00Growth substrates; Culture media; Apparatus or methods therefor
    • A01G24/40Growth substrates; Culture media; Apparatus or methods therefor characterised by their structure
    • A01G24/44Growth substrates; Culture media; Apparatus or methods therefor characterised by their structure in block, mat or sheet form

Definitions

  • This invention relates to a water retentive matrix composition for improving germination rates, retaining water, and, when used as an encapsulating material, may protect seeds from predation and mechanical injury with application in the fields of forestry, agronomy, and commercial and amateur horticulture.
  • Seeding directly into fields would be preferred in the forestry industry, but to date this has proved ineffective due to the high seed mortality from
  • a protective material to encapsulate the seed is a means of protecting the seed from these dangers and of improving germination rates.
  • encapsulated seeds do not experience the transplant shock found in bare-root seedlings. Misplanting, resulting in "J"- or "L”-shaped root seedlings which are unable to produce a desirable tree, is eliminated. The better protected encapsulated seed is plantable during a longer window of time, permitting coordination with herbicide
  • An improved matrix for encapsulating seeds is needed to better protect the seed and so to improve germination and survival rates above the industry average of 17% after twenty-eight days.
  • the improved matrix must reflect a balance between the water
  • the matrix should accommodate the addition of nutrients, fungicides, fertilizers and dyes. Under proper conditions, it should permit the aerial planting of seeds. In addition, the matrix may be substituted for conventional potting soil.
  • Applicants' invention includes a matrix composition for protecting seeds against injury and enhancing the conditions for germination and growth of seeds and plants.
  • the matrix comprises about 55 to 80 percent by dry weight of a hydrophilic fibrous bulking agent, about 0.001 to 0.35 percent by dry weight of a non-ionic surfactant, about 0 to 40 percent by dry weight of a substantially fully hydrolyzed (90-100%) poly (vinyl alcohol) of a molecular weight between 10,000 and
  • Applicants' invention is a matrix composition comprising about 70-75 percent by dry weight of peat, 0.2 to 0.35 percent by dry weight of polyoxypropylene-polyoxyethylene block copolymer, 10 to 15 percent by dry weight of a
  • substantially fully hydrolyzed poly (vinyl alcohol) with a molecular weight of approximately 50,000, 10 to 20 percent by dry weight of potassium acrylate acrylamide co-polymer and a seed. Water is added in an amount of 10 to 15 percent as measured against the dry elements to activate the polymer.
  • Applicants have invented a water retentive matrix that permits improved germination rates in seedlings and can be used advantageously as a potting soil substitute for plants.
  • the instant invention by use of a matrix, solves the problems inherent in bare-root seedling transplantation methods described above.
  • the matrix material provides an environment that balances (1) sufficient retention of water in the matrix to sustain the germinating seedling and (2) sufficient structural integrity of the matrix to protect the seedling from mechanical injury and predation.
  • the matrix when wetted yields a gel that bonds to the sowing surface,
  • the invention uses a water soluble polymer, a water
  • the matrix permits the passage of oxygen to the seedling and can include nutrients, dyes, fertilizers, and fungicides.
  • the matrix of the invention can be shaped to accommodate a seed of any size for forestry, agronomic or horticultural purposes. It is envisioned that Applicants' invention will be used to replant stands of longleaf pine, slash pine, white pine, red pine, jack pine, spruce, and other commercial tree crops.
  • Factors influencing the way in which the instant invention is used in the forestry industry include the amount and type of rainfall received in a planting area. Where rainfall varies from very intense to long drought periods as in the southeastern United States, insertion in a small hole formed in the soil is preferable. Where rainfall is less intense and more consistent as in the northwestern United States, England and Canada, aerial dispersion would achieve the greatest cost savings in labor and time.
  • the potted house plant market will obtain great benefit from the water retentive properties of the matrix when used as a replacement for conventional potting soil. Used as a potting medium, the matrix will not need watering for up to a full month after initial watering. It releases water over time on an as-needed basis helping to prevent over- or under-watering of the plant.
  • the components of Applicants' invention include:
  • a hydrophilic fibrous bulking agent forms the majority of the total matrix.
  • the bulking agent include peat, cotton, mineral wool, paper pulp, wool and hair.
  • the grind size of the bulking agent is important to the matrix retaining its structural
  • the bulking agent is peat that can pass through a 1/8" screen.
  • Substantially fully-hydrolyzed poly (vinyl alcohol) is the preferred water soluble binder material.
  • the invention requires that whatever water soluble binder material used is soluble in hot water to solution impregnate the peat or other bulking material, but is largely insoluble in cold water to maintain binding of the matrix under field conditions. Cold water soluble PVA would be unacceptable for seed encapsulation since it would leach from the matrix when wet; however, it would function effectively for preparation of the potting soil substitute.
  • the PVA is chosen from a broad molecular weight range, so that when wet the PVA
  • a number average for the molecular weight of the water soluble binder is approximately 10,000 to 150,000.
  • the PVA is used in an amount of 5 to 40% by dry weight of the total matrix depending on expected climatic conditions. Applicants used approximately 12% PVA (ElvanolTM 7130,
  • PVA polyvinylpyrrolidone
  • Non-ionic surfactant or emulsifier serves to wet the dry hydrophilic bulking agent and allows it to blend with substantially fully-hydrolyzed PVA in solution.
  • surfactant decreases surface tension otherwise preventing water uptake and thus increases the rate at which the bulking agent absorbs water.
  • Surfactants include polyoxypropylene-polyoxyethylene block copolymers; alkanol amides, betamol derivatives; block copolymers include a series of condensates of ethylene oxide with hydrophobic bases formed by condensing propylene oxide with propylene glycol; ethoxylated compounds comprising alcohols, alkyl phenols, amines and amides, alkylphenol ethoxylates, fatty alcohol
  • polyglycol ethers oxo-alcohol polyethyleneglycol ethers, alkylphenol-ethoxylates, fatty or oxo-alcohol polyethylene glycol ethers, and hydrophilic and
  • hydrophobic block copolymers hydrophobic block copolymers.
  • Applicant's preferred non-ionic surfactant is polyoxypropylene-polyoxyethylene block copolymer (Pluronic L-92, BASF). D. Moisture Content
  • the materials including the bulking agent, the water soluble polymer, and the non-ionic surfactant, are blended with a roller drum and dried to approximately 10 to 25% moisture content in a 95°C air circulating oven. Moisture content of the matrix at the point of
  • the amount of water needed to trigger the activation of the water soluble polymer to sufficiently allow encapsulation was surprisingly small.
  • the moisture activates the binding agent to form the matrix network which assists in maintaining the structural integrity of the matrix during transport and handling. It is understood that climatic conditions after production may affect the moisture content and appropriate packaging may be required to prevent this while the invention is in storage or transit.
  • Water-retentive polymers also called
  • SAP's superabsorbing polymers
  • hydrophilic materials which can absorb fluid and retain it under pressure without dissolution in the fluid
  • a water soluble polymer is cross-linked so that it can swell between cross-links but not dissolve.
  • a water-soluble monomer is co-polymerized with a waterinsoluble monomer into blocks.
  • Synthetic superabsorbers include polyacrylic acid, polymaleic anhydride-vinyl monomer superabsorbents, starch-polyacrylic acid grafts, polyacrylonitrile-based polymers, cross-linked polyacrylamide, cross-linked sulfonated polystyrene, cross-linked n-vinyl pyrrolidone or vinyl pyrrolidone-acrylamide copolymer, and polyvinyl alcohol superabsorbents.
  • the water retentive polymer chosen for seed encapsulation should have a water absorbtivity of between 50 and 600 times its weight. At such absorption levels, the entire composition upon exposure to rainfall is converted to a wet, gas-permeable gel which protects and bonds said seed to the ground during germination.
  • Additional water-retentive polymers include sodium propionate-acrylamide, poly (vinyl pyridine),
  • poly (ethylene imine), polyphosphates, poly (ethylene oxide), vinyl alcohol copolymer with acrylamide, and vinyl alcohol copolymer with acrylic acid acrylate are examples of poly (ethylene imine), polyphosphates, poly (ethylene oxide), vinyl alcohol copolymer with acrylamide, and vinyl alcohol copolymer with acrylic acid acrylate.
  • Applicants is 1 to 25% by dry weight of potassium acrylate acrylamide copolymer, preferably in an amount of 13 to 16% by dry weight of the matrix.
  • the material is commercially available under the tradename "Viterra” from the Nepera Chemical Company.
  • the matrix is compressed at room temperature to form a seed encapsulating product.
  • the matrix may be compressed while containing the seed, but this requires a lower pressure to prevent injury to the seed.
  • the matrix may be pressed at high
  • the size of the cavity to hold the seed is determined by the size of the particular seed type used. Once the seed is placed in the cavity, the cavity opening is plugged with a
  • a paste composed of 50% by dry weight dry peat and 50% by dry weight of an aqueous solution containing 11.25% by dry weight PVA (ElvanolTM
  • non-ionic surfactant Pluronic L-92, BASF.
  • Other material may be used to plug the cavity including silicate clays.
  • the blended material When the blended material is wetted after seeding by hand, by machine, or by air, it becomes gel-like, expands, and bonds to the soil localizing the seedling's growth at the point the seed capsule is deposited.
  • the resulting gel-like structure permits the exchange of oxygen and the retention of water which are essential for the germination of the seeds. It also forms a mechanical barrier to predators.
  • the encapsulating process permits the optional inclusion of nutrients, fertilizers and
  • fungicides selected to address local conditions.
  • BenlateTM at levels to 5000 ppm
  • RidamilTM at levels to 50 ppm
  • ThiaramTM at levels up to 25 ppm to the matrix without toxic effect to the seeds.
  • component characteristics in the matrix yield a product that has qualities of performance, convenience and costeffectiveness.
  • the resulting material was then dry blended in a bag with 14.32 g of the water retentive polymer, potassium acrylate acrylamide copolymer (ViterraTM, Nepera Chemical Co.).
  • the resulting blend thus had the following dry weight percentages of each component of the total non-aqueous ingredients, by calculation: 12% poly (vinyl alcohol) (ElvanolTM 7130, E. I. du Pont de Nemours and Company), 0.2% surfactant (PluronicTM L- 92, BASF), 11.0% water retentive polymer (ViterraTM, Nepera Chemical Company) and 76.8% peat.
  • compositions were made varying the amounts of
  • compositions were prepared. Quantities refer to weight percent of total non-aqueous ingredients:
  • ViterraTM grade 360E has an average grind size of 0.3 mm.
  • ViterraTM grade 375 has an average grind size of 1 mm.
  • the matrix number refers to the polymer from the corresponding matrix-preparation
  • the germination conditions varied.
  • the germination methods (Methods A, B and Control) are
  • Method A About 4 g of matrix was pressed in a conventional platten type compression molding machine at room temperature, using a pressure of 7500 psi per capsule. A cylindrical mold cavity was used resulting in capsule dimensions of 0.5 in. deep and 0.75 in.
  • the mold had a concentric stud resulting in a hole in the capsule 5/16 in. deep with a diameter of 3/16 in.
  • the seed was placed in the hole, which was then plugged with ground up peat moistened with
  • Method B About 2 g of peat was placed in the mold and a seed carefully placed as centrally as possible in the mold. About 2 g more of peat was then added to the mold. The peat and seed were then compressed at room temperature with a pressure of only 263 psi, in order to minimize damage to the seed during encapsulation.
  • Method C The same procedure as that described in method B was used, except that the pressure was only 188 psi.
  • Method A Several capsules were wetted in the numbers of specimens indicated by the Table I and placed in a pan on the soil surface and brought to field capacity. "Field capacity” refers to the saturation point or the amount of water that the soil will hold at equilibrium. The pans were then covered with a clear acrylic sheet to maintain field capacity, providing sufficient moisture for encapsulated seeds to germinate. The pans were then placed in a greenhouse and maintained at 65-75°F. Method B. Several capsules were wetted and placed in a pan on the soil surface. The pans were not covered but were subjected to 0.5 inches of simulated rainfall every other day. This provided sufficient moisture to germinate the encapsulated seeds.
  • Germination data in the accompanying Tables include the number of seeds germinated after the indicated number of days. Values are given in percentages. Thus 1 out of 8 is shown as 13%; 3 out of 8 as 38%; etc.
  • capsules allow seeds to grow as well as seeds planted directly. That is to say, the capsules do not have a phytotoxic effect on the seeds.
  • the data suggest that there may be some damage to the seed resulting in slightly reduced germination when the seed is in place before pressing the capsule.
  • the greenhouse studies described above do not show
  • Matrix 6 was used in this EXAMPLE 24. This Example used the encapsulating method A described above. The data shown in Table III were obtained from greenhouse tests. Seeds or capsules were placed on the surface of a sandy loam soil contained in pans with holes drilled in the bottom. The soil was wetted to field capacity initially. The pans were then placed on rubber sponge pads that were kept saturated with water. The
  • non-ionic surfactant PluronicTM
  • the matrix wafers were then moistened to fully activate the water retentive polymer and the resulting matrix used as potting soil in which to plant house plants.
  • the size of the wafer was determined by
  • Applicants' matrix showed a more healthy appearance than those planted in conventional potting soil.
  • Evidence of advantageous effects included glossier leaves, no wilting, more growth, and no browning of leaves.

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  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Soil Sciences (AREA)
  • Pretreatment Of Seeds And Plants (AREA)

Abstract

There is provided a matrix composition for use in germinating, growing, and protecting a variety of seeds or plants under different conditions. The composition provides protection from predation and mechanical injury, and upon exposure to moisture is converted to a water-retentive, gas-permeable gel which bonds the seed to the ground and establishes a nurturing habitat facilitating plant growth. The composition is of use in forestry and agronomy and for specialty crops. In addition, the matrix may be substituted for conventional potting soil.

Description

TITLE
WATER RETENTIVE MATRIX INCORPORATING PLASTIC FOR GROWING SEEDS AND PLANTS
CROSS-REFERENCE TO RELATED APPLICATION
This application is a continuation-in-part of
U.S.S.N. 07/404,812 filed September 8, 1989 entitled "Water Retentive Matrix Incorporating Plastic for
Growing Seeds and Plants."
TECHNICAL FIELD
This invention relates to a water retentive matrix composition for improving germination rates, retaining water, and, when used as an encapsulating material, may protect seeds from predation and mechanical injury with application in the fields of forestry, agronomy, and commercial and amateur horticulture. BACKGROUND OF THE INVENTION
Currently, the replanting of harvested commercial forest acreage requires labor-intensive planting methods. Year-old nursery-raised, bare-root tree seedlings are transplanted by hand or semi-mechanized equipment to open woodlands. This is a costly and timeconsuming procedure necessitated by the delicacy of the plants. Light and water needs of bare-root seedlings require very careful handling with specialized
environmental controls such as refrigeration or misters to prevent overheating or drying out while in transit. The seedlings are bulky, often become root-bound and have limited periods for transplantation. Survival rates of only 70% are considered the best obtainable with current practices and under optimum conditions. Other agricultural markets face similar limitations of pre-grown seedlings. Commercial vegetable farming relies on pre-grown seedlings of tomatoes, tobacco, and cabbage. Home gardeners also make heavy use of pregrown seedlings.
Seeding directly into fields would be preferred in the forestry industry, but to date this has proved ineffective due to the high seed mortality from
predation and the lack of predictable moisture and light. A protective material to encapsulate the seed is a means of protecting the seed from these dangers and of improving germination rates.
The idea of encapsulating seeds to improve
germination is known. For instance, in U.S. Patent No. 4,628,633 a method is taught which uses compressed peat moss enclosing the seed to absorb water to form a loose, partially light-transmitting structure. Planting is simplified since the encapsulated seeds will dry out less quickly and can be shipped more cheaply and
conveniently in less space than pre-grown seedlings. The rounded shape of encapsulated seeds permits bulk handling methods.
However, there are additional qualities not possessed in peat alone that can be achieved by a novel composition of materials. Total mechanization of planting would be possible through use of improved encapsulated seeds. The semi-mechanized planting of bare-root timber seedlings, for example, require a deepshank plow to plant the seedlings deep enough into the soil. In contrast, encapsulated seeds need a shallow planting depth, which reduces the horsepower needed for the machine, increases the speed of the operation, and permits machine planting on otherwise unsuitable sites: Hand planting, the most expensive method in time and cost, is faster with encapsulated seeds than with bare-root seedlings. Encapsulated seeds are easier to handle and more can be carried by the hand-planter than can bare-root seedlings. In addition, encapsulated seeds will not dry out as quickly.
Whether planted by machine or by hand, encapsulated seeds do not experience the transplant shock found in bare-root seedlings. Misplanting, resulting in "J"- or "L"-shaped root seedlings which are unable to produce a desirable tree, is eliminated. The better protected encapsulated seed is plantable during a longer window of time, permitting coordination with herbicide
application, a cost-savings not now available. However, known matrices have not produced the advantages cited to the degree needed by the industry.
An improved matrix for encapsulating seeds is needed to better protect the seed and so to improve germination and survival rates above the industry average of 17% after twenty-eight days. The improved matrix must reflect a balance between the water
absorbance capacity of the encapsulating matrix and its structural integrity. The matrix should accommodate the addition of nutrients, fungicides, fertilizers and dyes. Under proper conditions, it should permit the aerial planting of seeds. In addition, the matrix may be substituted for conventional potting soil.
SUMMARY OF THE INVENTION
Applicants' invention includes a matrix composition for protecting seeds against injury and enhancing the conditions for germination and growth of seeds and plants. The matrix comprises about 55 to 80 percent by dry weight of a hydrophilic fibrous bulking agent, about 0.001 to 0.35 percent by dry weight of a non-ionic surfactant, about 0 to 40 percent by dry weight of a substantially fully hydrolyzed (90-100%) poly (vinyl alcohol) of a molecular weight between 10,000 and
150,000, water in an amount of between about 10 and 25 percent by weight of the composition, about 5 to 20 percent by dry weight of a water retentive polymer with a water absorbtivity of between 50 and 600 times its weight and optionally a seed. Preferably, Applicants' invention is a matrix composition comprising about 70-75 percent by dry weight of peat, 0.2 to 0.35 percent by dry weight of polyoxypropylene-polyoxyethylene block copolymer, 10 to 15 percent by dry weight of a
substantially fully hydrolyzed poly (vinyl alcohol) with a molecular weight of approximately 50,000, 10 to 20 percent by dry weight of potassium acrylate acrylamide co-polymer and a seed. Water is added in an amount of 10 to 15 percent as measured against the dry elements to activate the polymer.
DETAILED DESCRIPTION OF THE INVENTION
Applicants have invented a water retentive matrix that permits improved germination rates in seedlings and can be used advantageously as a potting soil substitute for plants. The instant invention, by use of a matrix, solves the problems inherent in bare-root seedling transplantation methods described above. The matrix material provides an environment that balances (1) sufficient retention of water in the matrix to sustain the germinating seedling and (2) sufficient structural integrity of the matrix to protect the seedling from mechanical injury and predation. The matrix when wetted yields a gel that bonds to the sowing surface,
localizing the seedling to grow at that point. The invention uses a water soluble polymer, a water
retentive polymer in combination with a bulking
material, and other components described below to achieve the desired protection.
The matrix permits the passage of oxygen to the seedling and can include nutrients, dyes, fertilizers, and fungicides. The matrix of the invention can be shaped to accommodate a seed of any size for forestry, agronomic or horticultural purposes. It is envisioned that Applicants' invention will be used to replant stands of longleaf pine, slash pine, white pine, red pine, jack pine, spruce, and other commercial tree crops.
Factors influencing the way in which the instant invention is used in the forestry industry include the amount and type of rainfall received in a planting area. Where rainfall varies from very intense to long drought periods as in the southeastern United States, insertion in a small hole formed in the soil is preferable. Where rainfall is less intense and more consistent as in the northwestern United States, England and Canada, aerial dispersion would achieve the greatest cost savings in labor and time.
Additional important uses for the matrix are with commercial vegetable crops, in the commercial greenhouse trade, and by the significant number of amateur
gardeners. In particular, it is envisioned that the potted house plant market will obtain great benefit from the water retentive properties of the matrix when used as a replacement for conventional potting soil. Used as a potting medium, the matrix will not need watering for up to a full month after initial watering. It releases water over time on an as-needed basis helping to prevent over- or under-watering of the plant. The components of Applicants' invention include:
A. Hydrophilic Fibrous Bulking Agent
A hydrophilic fibrous bulking agent forms the majority of the total matrix. Examples of the bulking agent include peat, cotton, mineral wool, paper pulp, wool and hair. The grind size of the bulking agent is important to the matrix retaining its structural
integrity even when wet. In its preferred form, the bulking agent is peat that can pass through a 1/8" screen.
B. Water Soluble Binder Material
Substantially fully-hydrolyzed poly (vinyl alcohol) (PVA) is the preferred water soluble binder material. The invention requires that whatever water soluble binder material used is soluble in hot water to solution impregnate the peat or other bulking material, but is largely insoluble in cold water to maintain binding of the matrix under field conditions. Cold water soluble PVA would be unacceptable for seed encapsulation since it would leach from the matrix when wet; however, it would function effectively for preparation of the potting soil substitute. The PVA is chosen from a broad molecular weight range, so that when wet the PVA
continues to bind the matrix together. A number average for the molecular weight of the water soluble binder is approximately 10,000 to 150,000. The PVA is used in an amount of 5 to 40% by dry weight of the total matrix depending on expected climatic conditions. Applicants used approximately 12% PVA (Elvanol™ 7130,
E. I. du Pont de Nemours and Company). The particular PVA used has a molecular weight of approximately 50,000. Additional water soluble binders can be used in the invention including polyvinylpyrrolidone.
C. Non-ionic Surfactant
Non-ionic surfactant or emulsifier serves to wet the dry hydrophilic bulking agent and allows it to blend with substantially fully-hydrolyzed PVA in solution.
The surfactant decreases surface tension otherwise preventing water uptake and thus increases the rate at which the bulking agent absorbs water. Surfactants include polyoxypropylene-polyoxyethylene block copolymers; alkanol amides, betamol derivatives; block copolymers include a series of condensates of ethylene oxide with hydrophobic bases formed by condensing propylene oxide with propylene glycol; ethoxylated compounds comprising alcohols, alkyl phenols, amines and amides, alkylphenol ethoxylates, fatty alcohol
polyglycol ethers, oxo-alcohol polyethyleneglycol ethers, alkylphenol-ethoxylates, fatty or oxo-alcohol polyethylene glycol ethers, and hydrophilic and
hydrophobic block copolymers. Applicant's preferred non-ionic surfactant is polyoxypropylene-polyoxyethylene block copolymer (Pluronic L-92, BASF). D. Moisture Content
The materials, including the bulking agent, the water soluble polymer, and the non-ionic surfactant, are blended with a roller drum and dried to approximately 10 to 25% moisture content in a 95°C air circulating oven. Moisture content of the matrix at the point of
production is a critical feature to, maintain the relative qualities of the water soluble material and the water-retentive polymer described below. The amount of water needed to trigger the activation of the water soluble polymer to sufficiently allow encapsulation was surprisingly small. The moisture activates the binding agent to form the matrix network which assists in maintaining the structural integrity of the matrix during transport and handling. It is understood that climatic conditions after production may affect the moisture content and appropriate packaging may be required to prevent this while the invention is in storage or transit.
E. Water-Retentive Polymer
Water-retentive polymers, also called
superabsorbing polymers or SAP's, are hydrophilic materials which can absorb fluid and retain it under pressure without dissolution in the fluid being
absorbed. The materials used are generally all
synthesized by one of two routes. In the first, a water soluble polymer is cross-linked so that it can swell between cross-links but not dissolve. In the second, a water-soluble monomer is co-polymerized with a waterinsoluble monomer into blocks.
The earliest superabsorbent materials were
saponified starch graft polyacrylonitrile copolymers. Synthetic superabsorbers include polyacrylic acid, polymaleic anhydride-vinyl monomer superabsorbents, starch-polyacrylic acid grafts, polyacrylonitrile-based polymers, cross-linked polyacrylamide, cross-linked sulfonated polystyrene, cross-linked n-vinyl pyrrolidone or vinyl pyrrolidone-acrylamide copolymer, and polyvinyl alcohol superabsorbents.
These polymers absorb many times their own weight in aqueous fluid. The water retentive polymer chosen for seed encapsulation should have a water absorbtivity of between 50 and 600 times its weight. At such absorption levels, the entire composition upon exposure to rainfall is converted to a wet, gas-permeable gel which protects and bonds said seed to the ground during germination.
Additional water-retentive polymers include sodium propionate-acrylamide, poly (vinyl pyridine),
poly (ethylene imine), polyphosphates, poly (ethylene oxide), vinyl alcohol copolymer with acrylamide, and vinyl alcohol copolymer with acrylic acid acrylate.
The preferred water-retentive polymer used by
Applicants is 1 to 25% by dry weight of potassium acrylate acrylamide copolymer, preferably in an amount of 13 to 16% by dry weight of the matrix. The material is commercially available under the tradename "Viterra" from the Nepera Chemical Company.
Formation of Compressed Matrix Product
The matrix is compressed at room temperature to form a seed encapsulating product. The matrix may be compressed while containing the seed, but this requires a lower pressure to prevent injury to the seed.
Alternatively, the matrix may be pressed at high
pressures (approximately 7500 psi) before the seed is inserted into the matrix unit. The size of the cavity to hold the seed is determined by the size of the particular seed type used. Once the seed is placed in the cavity, the cavity opening is plugged with a
suitable material that will remain in place once dried and that is not toxic to the seed or germinating plant. For example, Applicants used a paste composed of 50% by dry weight dry peat and 50% by dry weight of an aqueous solution containing 11.25% by dry weight PVA (Elvanol™
7130, E. I du Pont de Nemours and Company) and 0.125% by dry weight non-ionic surfactant (Pluronic L-92, BASF). Other material may be used to plug the cavity including silicate clays.
Functioning of the Encapsulated Seed
When the blended material is wetted after seeding by hand, by machine, or by air, it becomes gel-like, expands, and bonds to the soil localizing the seedling's growth at the point the seed capsule is deposited.
Approximately one inch of rain is required to activate the preferred capsule matrix; however, water
requirements can be varied in light of local climate conditions, seed requirements, and resulting proportions of matrix components. The resulting gel-like structure permits the exchange of oxygen and the retention of water which are essential for the germination of the seeds. It also forms a mechanical barrier to predators. In addition, the encapsulating process permits the optional inclusion of nutrients, fertilizers and
fungicides selected to address local conditions.
Applicants have added commercial fungicides such as
Benlate™ at levels to 5000 ppm, Ridamil™ at levels to 50 ppm, and Thiaram™ at levels up to 25 ppm to the matrix without toxic effect to the seeds.
Precise ratios of ingredients are important to obtain the most advantageous characteristics of the matrix. The particular use made of the matrix and local growing conditions will dictate the ratios chosen. For instance, it is essential that the matrix, when wetted, holds sufficient water to supply the needs of the germinating seeds, bedding plant, or house plant, but not hold so much to subject the seed or plant to a deleterious amount of water. The combination of
component characteristics in the matrix yield a product that has qualities of performance, convenience and costeffectiveness.
EXAMPLES EXAMPLE 1
Preparation of Encapsulating Matrix
Commercial peat moss was dried in an air oven to less than 1% water content, ground in a Wiley mill, and screened through a 1/8" holed screen. Two hundred grams of a distilled water solution containing 15.62 g of poly (vinyl alcohol), (Elvanol™ 7130, E. I. du Pont de Nemours and Company), and 0.260 g of surfactant, polyoxypropylene-polyoxyethylene block copolymer
(Pluronic™ L-92, BASF), were added to 100 g of the above dried peat moss and hand blended in a plastic bag. The blend was then placed in an 85°C oven and dried to a moisture content of between 10 and 25%, as ascertained using an Ohaus Moisture Analyser, Model 6010PC. The moisture content was ascertained but not recorded, since subsequent handling and storage before seed
encapsulation resulted in minor changes in the water content. The resulting material was then dry blended in a bag with 14.32 g of the water retentive polymer, potassium acrylate acrylamide copolymer (Viterra™, Nepera Chemical Co.). The resulting blend thus had the following dry weight percentages of each component of the total non-aqueous ingredients, by calculation: 12% poly (vinyl alcohol) (Elvanol™ 7130, E. I. du Pont de Nemours and Company), 0.2% surfactant (Pluronic™ L- 92, BASF), 11.0% water retentive polymer (Viterra™, Nepera Chemical Company) and 76.8% peat. EXAMPLES 2 to 7
Using the same procedure as in EXAMPLE 1,
compositions were made varying the amounts of
ingredients added to 100 g of dried peat to give the following calculated weight by percent compositions (on a dry basis, as in EXAMPLE 1):
Ex.# Poly (vinyl alc.) Pluronic L -92 Viterra/grade Peat
2 16% 0.2% 11/360E 72.8%
3 24 0.2 11/360E 64.8
4 24 0.2 5/360E 70.8
5 24 0.2 16/360E 59.8
6 18 0.2 11/360E 70.8
7 14 0.2 11/360E 74.8
EXAMPLES 8 to 11
These examples use the same procedure as in Example 1, except that in Examples 9 and 11, a small amount of methyl 1-(butylcarbamoyl)-2-benzimidazolecarbamate fungicide (Benlate™, E. I. du Pont de Nemours and
Company) was added at the same time the aqueous solution was added to the dried peat moss. The following
compositions were prepared. Quantities refer to weight percent of total non-aqueous ingredients:
Ex. # Poly (vinyl, alc.) Pluronic L-92 Viterra/grade Peat Fungicide 8 12 0.2 7.5/360E 74.8 0
+7.5/375
9 12 0.2 7.5/360E 74.55
25
+7.5/375
10 18 0.2 11/360E 70.8 0
11 18 0.2 11/360E 70.3 .5
Viterra™ grade 360E has an average grind size of 0.3 mm. Viterra™ grade 375 has an average grind size of 1 mm.
EXAMPLES 12 to 19 and EXAMPLE 20
Encapsulation, Greenhouse Germination, and Control
In Table I, below, the matrix number refers to the polymer from the corresponding matrix-preparation
Examples above. Table I also indicates the
encapsulation procedure and gives the results of
germination studies. The encapsulation method varied depending on whether the seed was inserted within the matrix after (Method A) or before (Method B) pressing.
In addition, the germination conditions varied. The germination methods (Methods A, B and Control) are
described below.
TAB LE I
LOB LOLLY P INE SEED ENCAP SULATION AND GERMINATION STUDIES
NO. OF %GERMINATION
TEST PRESSING WETTING (DAYS)
EX. # MATRIX # SPECIMENS METHOD METHOD 7 14 21 28 12 1 8 A A 0 13 25 38
8 A A 0 25 50 50 8 A B 0 25 38 100 8 A B 13 25 25 75 13 2 8 A B 0 13 63 75
8 A B 0 13 63 75 8 A A 0 13 25 63 8 A A 0 25 75 88 14 3 8 A B 0 50 63 88
8 A B 0 0 38 75 8 A A 0 0 25 88 8 A A 0 25 50 63 15 4 8 A B 0 38 63 75
8 A B 0 25 50 75 8 A A 0 75 75 75
16 5 8 A B 0 25 38 38
8 A B 0 0 38 50 8 A A 0 13 25 38
17 6 8 B B 0 13 13 13
8 B B 0 13 13 13 8 B A 0 63 63 75 8 B A 0 75 75 75
18 6 8 C B 0 25 25 25
8 C B 0 13 13 13 8 C A 0 50 50 50 8 C A 0 13 25 38
19 7 8 B B 0 25 63 75
8 B B 0 38 50 63 8 B A 13 63 63 63
20 39 - B 33 41 59 64
(Bare Seed
Control) 48 - A 31 63 75 79
48 - B 0 38 65 85 Encapsulation :
Method A. About 4 g of matrix was pressed in a conventional platten type compression molding machine at room temperature, using a pressure of 7500 psi per capsule. A cylindrical mold cavity was used resulting in capsule dimensions of 0.5 in. deep and 0.75 in.
diameter. The mold had a concentric stud resulting in a hole in the capsule 5/16 in. deep with a diameter of 3/16 in. The seed was placed in the hole, which was then plugged with ground up peat moistened with
surfactant.
Method B. About 2 g of peat was placed in the mold and a seed carefully placed as centrally as possible in the mold. About 2 g more of peat was then added to the mold. The peat and seed were then compressed at room temperature with a pressure of only 263 psi, in order to minimize damage to the seed during encapsulation. Method C. The same procedure as that described in method B was used, except that the pressure was only 188 psi.
Germination :
Method A. Several capsules were wetted in the numbers of specimens indicated by the Table I and placed in a pan on the soil surface and brought to field capacity. "Field capacity" refers to the saturation point or the amount of water that the soil will hold at equilibrium. The pans were then covered with a clear acrylic sheet to maintain field capacity, providing sufficient moisture for encapsulated seeds to germinate. The pans were then placed in a greenhouse and maintained at 65-75°F. Method B. Several capsules were wetted and placed in a pan on the soil surface. The pans were not covered but were subjected to 0.5 inches of simulated rainfall every other day. This provided sufficient moisture to germinate the encapsulated seeds.
Control Method. Bare seeds were placed directly on the soil surface and their germination time recorded.
Germination data in the accompanying Tables include the number of seeds germinated after the indicated number of days. Values are given in percentages. Thus 1 out of 8 is shown as 13%; 3 out of 8 as 38%; etc.
The Examples show that capsules allow seeds to grow as well as seeds planted directly. That is to say, the capsules do not have a phytotoxic effect on the seeds. The data suggest that there may be some damage to the seed resulting in slightly reduced germination when the seed is in place before pressing the capsule. The greenhouse studies described above do not show
superiority of the capsule over bare seeds, since this would only be expected under field conditions where predation and other adverse conditions would be expected to adversely affect bare seeds. Such field tests are described below.
EXAMPLES 21, 22, and Control EXAMPLE 23 These Examples used the encapsulating Method A described above. In Table II below, the initial number refers to the matrix of the corresponding matrix
preparation examples. The capsules were placed in holes 1.5 inches in diameter and 1.25 inches deep. Germination studies were carried out in the fall in Buna, Texas. Data are shown in Table II giving number of specimens and germination after 28 days. Rainfall measured during the period is given. These tests show the superiority in percent germination of the capsules over bare seeds under real growing conditions. They also indicate that the presence of a fungicide further increases the germination rate. TABLE II
ENCAPSULATES LOBLOLLY PINE SEED FALL FIELD TEST DATA
(Buna, Texas)
% GERMINATION
EXAMPLE # MATRIX # NO. OF SPECIMENS (AFTER 28 DAYS)
21 8 50 56
22 9 50 66
23 - 50 36
(Bare Seed Control) Rainfall during 28 day period = 1.55 inches
7th day = 1.10 inches
9th day = 0.25 inches
12th day = 0.10 inches
17th day = 0.10 inches
EXAMPLE 24 AND CONTROL EXAMPLE 25
Matrix 6 was used in this EXAMPLE 24. This Example used the encapsulating method A described above. The data shown in Table III were obtained from greenhouse tests. Seeds or capsules were placed on the surface of a sandy loam soil contained in pans with holes drilled in the bottom. The soil was wetted to field capacity initially. The pans were then placed on rubber sponge pads that were kept saturated with water. The
greenhouse was kept between 65 and 75 deg F and a relative humidity of 45 to 70%.
These tests were designed to show the effects where only a limited amount of water was present, or the conditions placed the seeds 'under stress.' Once again, the results shown in Table III, indicate the clear advantage of encapsulation.
TABLE III
GERMINATION DATA FOR LOBLOLLY PINE SEEDS
(Stress Test)
% GERMINATION
(DAYS)
EXAMPLE # MATRIX # NO. OF SPECIMENS 7 14 21 28
24 6 32 0 32 57 64
24 0 25 45 63
128 4 30 50 67
25 (Bare Seed - 72 0 25 25 25 Control)
24 0 8 29 38 24 0 21 25 33
EXAMPLES 26, 27 and 28
These Examples used the encapsulating Method A described above. In Table IV, the initial number refers to the matrix of the corresponding matrix preparation examples. The capsules were placed on the soil surface. Germination studies were carried out in the spring in Buna, Texas. Data are shown in Table IV giving the number of specimens and germination after 28 days.
Total rainfall measured during the period is given.
These tests show the superiority in percent germination of the capsules over bare seeds under real growing conditions. They also indicate that the presence of a fungicide further increases the germination rate.
TABLE TV
ENCAPSULATED LOBLOLLY PINE SEED SPRING FIELD TEST DATA
(Buna, Texas)
% GERMINATION EXAMPLE # MATRIX # NO. OF SPECIMENS (AFTER 28 DAYS)
26 10 50 44
(without
Benlate™)
27 11 50 58
(with
Benlate™)
28 50 41 (Bare Seed
Control )
Rainfall during 28 day period = 8 . 46 inches
EXAMPLE 12
Applicants compressed the following matrix composition into 2 " X 3/8 " chip-like wafers with 7500 psi :
12% by dry weight PVA (Elvanol™ 7130,
E . I . du Pont de Nemours and Company) 15% by dry weight water retentive polymer (Viterra™, Nepera Chemical Company) ,
7 . 5% 360E grade/7 . 5% 375 grade
0 .35% non-ionic surfactant (Pluronic™
L-92 , BASF)
72.65% hydrophilic bulking agent (peat) Sufficient water is added to trigger the water retentive polymer enough to bind the wafer together during production.
The matrix wafers were then moistened to fully activate the water retentive polymer and the resulting matrix used as potting soil in which to plant house plants. The size of the wafer was determined by
reference to the standard size flower pot the matrix would expand to fill. Preliminary growing trials were run with squash, watermelon, cantaloupe, bell pepper and okra plants over a two month period. No deleterious effects were noted from use of the matrix and water retention of the matrix was considered a convenience and advantage.
A variety of house plants were potted in the matrix including Pathos, Aglaonema, "China Doll", Rex Begonia, Calathea, Draconia, Diffenbachia, Boston fern. Aloe, Croton, and "Peace Lily". No deleterious effects from use of the matrix were noted. Comparable specimens of Pathos, Aglaonema, "China Doll", and Rex Begonia were planted in the matrix and in conventional potting soil. Each was watered once to saturation at the outset of the trial period and like species were compared after 20 days (Pathos, Aglaonema) and 10 days ("China Doll", Rex Begonia). All of the house plants planted in
Applicants' matrix showed a more healthy appearance than those planted in conventional potting soil. Evidence of advantageous effects included glossier leaves, no wilting, more growth, and no browning of leaves.
Applicants believe that the matrix's ability to release water on an as-needed basis accounts for the superior results of these trials. Applicants have also used the following matrix as a potting soil substitute without any deleterious effects to potted plants noted:
15% by dry weight water retentive polymer (Viterra™, Nepera Chemical Company),
7.5% 360E grade/7.5% 375 grade
0.35% non-ionic surfactant (Pluronic™
L-92, BASF)
84.65% hydrophilic bulking agent (peat)
It will be apparent that the instant specification and the examples are set forth by way of illustration and not limitation, and that various modifications and changes may be made without departing from the spirit and scope of the present invention.

Claims

CLAIMS We claim:
1. A matrix composition for protecting seeds against injury and enhancing the conditions for
germination and growth of seeds and plants, comprising:
about 55 to 80 percent by dry weight of a hydrophilic fibrous bulking agent;
about 0.001 to 0.35 percent by dry weight of a non-ionic surfactant;
0 to 40 percent by dry weight of a substantially fully hydrolyzed poly (vinyl alcohol) of a molecular weight between 10,000 and 150,000;
about 5 to 20 percent by dry weight of a water-retentive polymer with a water absorbtivity of between 50 and 600 times its weight;
water in an amount of between about 10 and 25 percent by weight as measured against all other
components of the composition; and
a seed or plant.
2. The composition of Claim 1 wherein the hydrophilic fibrous bulking material is selected from the group consisting of peat, cotton, mineral wool, paperpulp, wool and hair.
3. The composition of Claim 2 wherein the hydrophilic fibrous bulking agent is peat in an amount of between about 70 and 75 percent by dry weight of the matrix composition and having a grind size that will pass through a 1/8 inch screen.
4. The composition of Claim 1 wherein the nonionic surfactant is selected from the group consisting of polyoxypropylene-polyoxyethylene block co-polymers; alkanol amides, betamol derivatives; block copolymers comprising a series of condensates of ethylene oxide with hydrophobic bases formed by condensing propylene oxide with propylene glycol; ethoxylated compounds comprising alcohols, alkyl phenols, amines and amides, alkylphenol ethoxylates, fatty alcohol polyglycol ethers, oxo-alcohol polyethyleneglycol ethers.
5. The composition of Claim 4 wherein the nonionic surfactant is a polyoxypropylene-polyoxyethylene block co-polymer in an amount between about 0.001 and 0.35 percent of the composition.
6. The composition of Claim 1 wherein the water retentive polymer is selected from the group consisting of cross-linked poly(acrylamide), cross-linked
poly (acrylic acid) copolymers and ionomers, cross-linked poly (ethylene oxide), saponified acrylonitrile grafted starch, cellulose and cellulose derivatives, acrylic acid grafted starch, poly(maleic acid) copolymers, cross-linked poly (vinyl alcohol) and copolymers, potassium acrylate acrylamide co-polymer, vinyl alcohol copolymer with methyl acrylate, vinyl alcohol copolymer with acrylic acid acrylate, vinyl alcohol copolymer with acrylamide, poly (ethylene oxide), poly(vinyl
pyrollidone), sulfonated polystyrene, polyphosphates, polyethylene imine, poly (vinyl pyridine) and sodium propionate-acrylamide.
7. The composition of Claim 6 wherein the water retentive polymer is potassium acrylate acrylamide co polymer in an amount between 14 and 16 percent by dry weight of the matrix composition.
8. The composition of Claim 1 wherein the seed encapsulating matrix optionally comprises a pesticide, a fungicide, a dye, a fertilizer, or nutrient.
9. A matrix composition for protecting seeds against injury and enhancing the conditions for
germination and growth of seeds and plants, preferably comprising the following solids:
73 percent by dry weight of peat;
0.2 to 0.35 percent by dry weight of polyoxypropylene-polyoxyethylene block co-polymer;
11 to 13 percent by dry weight of a substantially fully hydrolyzed poly (vinyl alcohol) with a molecular weight of approximately 50,000;
14 to 16 percent by dry weight of potassium acrylate acrylamide co-polymer;
water in an amount of between 10 and 11 percent by weight as measured against all other
components; and
a seed.
10. The matrix composition of Claim 9 optionally comprising a pesticide, a fungicide, or a nutrient.
11. The matrix composition of Claim 9 wherein the seed is a vegetable seed or a tree seed.
PCT/US1990/004816 1989-09-08 1990-08-29 Water retentive matrix incorporating plastic for growing seeds and plants WO1991003149A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US40481289A 1989-09-08 1989-09-08
US404,812 1989-09-08
US56781690A 1990-08-15 1990-08-15
US567,816 1990-08-15

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FR2705191A1 (en) * 1993-05-13 1994-11-25 Hortifrance Process for the preparation of a product used as substrate (support) or ameliorator (fertilizer) for crops
US5382269A (en) * 1990-12-10 1995-01-17 Rhone-Poulenc Agrochimie Artificial seeds
US8256160B2 (en) * 2004-11-19 2012-09-04 Rubin Patti D Compressed growing medium
US8381439B2 (en) 2007-05-18 2013-02-26 Patti D. Rubin Compressed growing medium including castings
WO2013044266A1 (en) * 2011-09-23 2013-03-28 Zynnovation Llc Disposable diaper recycling and applications thereof
WO2014186305A1 (en) * 2013-05-13 2014-11-20 Owens Luther Vernon Plant hydration method and composition
WO2015195687A1 (en) * 2014-06-16 2015-12-23 Aquatrols Corporation Of America Seed composition and method to improve germination and emergence under adverse soil conditions
US9756798B2 (en) 2004-11-19 2017-09-12 Patti D. Rubin Burrow filling compressed growing medium
CN114207058A (en) * 2019-08-01 2022-03-18 佩瓦斯有限股份公司 Superabsorbent-based suspension suitable for hydration-stimulated coating of seeds and method for coating seeds with said suspension

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US3947996A (en) * 1974-01-21 1976-04-06 The Dow Chemical Company Method of coating seeds to control germination and the resultant coated seeds
US4250660A (en) * 1978-07-12 1981-02-17 Sumitomo Chemical Company, Limited Process for producing coated seed
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WO1985001736A1 (en) * 1983-10-13 1985-04-25 Agrisorb Pty. Ltd. Seed coating
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5382269A (en) * 1990-12-10 1995-01-17 Rhone-Poulenc Agrochimie Artificial seeds
FR2705191A1 (en) * 1993-05-13 1994-11-25 Hortifrance Process for the preparation of a product used as substrate (support) or ameliorator (fertilizer) for crops
US9756798B2 (en) 2004-11-19 2017-09-12 Patti D. Rubin Burrow filling compressed growing medium
US8256160B2 (en) * 2004-11-19 2012-09-04 Rubin Patti D Compressed growing medium
US8381439B2 (en) 2007-05-18 2013-02-26 Patti D. Rubin Compressed growing medium including castings
US9565809B2 (en) 2011-09-23 2017-02-14 Zynnovation Llc Tree or plant protection mat
WO2013044266A1 (en) * 2011-09-23 2013-03-28 Zynnovation Llc Disposable diaper recycling and applications thereof
US10178834B2 (en) 2011-09-23 2019-01-15 Zynnovation Llc Tree or plant protection mat
WO2014186305A1 (en) * 2013-05-13 2014-11-20 Owens Luther Vernon Plant hydration method and composition
CN105392360A (en) * 2013-05-13 2016-03-09 路德·弗农·欧文斯 Plant hydration method and composition
WO2015195687A1 (en) * 2014-06-16 2015-12-23 Aquatrols Corporation Of America Seed composition and method to improve germination and emergence under adverse soil conditions
CN114207058A (en) * 2019-08-01 2022-03-18 佩瓦斯有限股份公司 Superabsorbent-based suspension suitable for hydration-stimulated coating of seeds and method for coating seeds with said suspension
EP4007796B1 (en) * 2019-08-01 2023-04-12 P E W A S S.R.O. Superabsorbent-based suspension suitable for hydrostimulatory coating of seeds and a method of coating seeds with the suspension
CN114207058B (en) * 2019-08-01 2023-07-28 佩瓦斯有限股份公司 Superabsorbent-based suspension suitable for hydration-stimulated coating of seeds and method for coating seeds with said suspension

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