WO1989011739A2

WO1989011739A2 - Solid compositions for fuel cell electrolytes

Info

Publication number: WO1989011739A2
Application number: PCT/US1989/002156
Authority: WO
Inventors: Marc J. Madou; Takaaki Otagawa; Arden Sher
Original assignee: Sri International
Priority date: 1988-05-20
Filing date: 1989-05-18
Publication date: 1989-11-30
Also published as: JPH02504445A; WO1989011739A3; EP0372069A1; GB9000121D0; KR900702589A; GB2232293A

Abstract

A solid O2- conducting material for use as an electrolyte (152) for a fuel cell, comprising: a monocrystal or polycrystal structure of the formula: A1-xBxZ, wherein, A is independently selected from lanthanum, cerium, neodymium, praseodymium, scandium or mixtures thereof; B is independently selected form strontium, calcium, barium or magnesium; x is between about 0 and 0.9999; Z is selected from the group consisting of F3-x and OcFd where F is fluorine, O is oxygen, x is between about 0 and 0.9999 and 2c+d = 3-x, wherein c is between 0.0001 and 1.5 and d is between 0.0001 and less than or equal to 3, with the proviso when A is lanthanum, Z is F3-x and x is 0, the solid material is only a monocrystal. Composite fuel cell of thin lanthanum strontium fluoride having a laminate (composite)-type structure (151, 152, 153, 154). In another aspect, the solid electrolyte for a fuel cell is a monocrystal or polycrystal structure of PbeSnfFg, where Pb is lead and Sn is tin. The use of the solid electrolyte fuel cells disclosed to generate electricity.

Description

SOLID COMPOSITIONS FOR FUEL CELL ELECTROLYTES

BACKGROUND OF THE INVENTION Field of the Invention

The present invention relates to materials and processes to prepare polycrystal and monocrystal forms for use as solid electrolytes in fuel cells. In specifi embodiments, a fuel cell having oxygen or air/solid O^2- (oxide ion) conducting lanthanum fluoride (as a single crystal) hydrogen configuration produces about 1 volt of open circuit potential at moderately low temperatures. In other specific embodiments, a fuel cell having oxygen or air/specific substituted alkaline earth lanthanide fluorides (either as a single crystal or poly crystal) that conduct O^2-/hydrogen configuration also produce electricity at moderately low temperatures compared to the present art.

DESCRIPTION OF THE RELEVANT ART

Fuel cells convert chemical energy to electrical energy directly, without having a Carnot-cycle efficiency limitation, through electrochemical oxidation-reduction reactions of fuels. Several types of fuel cells have been or are being investigated at the present time. These may generally be classified as shown in Figure 1A and 1B, as Table 1, depending upon the kinds of electrolyte used and the operation temperature.

The solid electrolyte fuel cell which can be considered as the third generation fuel cell technology, is essentially an oxygen-hydrogen (or H₂-CO mixture) fuel cell operated at high temperature (ca. 1000º C) with a solid ceramic oxide material used as the electrolyte. At present, yttrium- or calcium-stabilized zirconium oxides have been used as the electrolyte. The mechanism of ionic conduction is oxygen ion transport via O^2- anion in the solid oxide crystal lattice.

References of interest regarding fuel cells include the following:

B.V. Tilak, R.S. Yeo, and S. Srinivasan (1981), "Electrochemical Energy Conversion-Principals", in

"Comprehensive Treatise of Electrochemistry" Vol. 3:

Electrochemical Energy Conversion and Storage (J.O'M.

Bockris et al., editors), pp. 39-122, Plenum Press, New

York. K. K. Ushiba, (1984), "Fuel Cells", Chemtech, May, pp.

300-307.

A. McDougall (1976), "Fuel Cells", Energy Alternatives

Series (CA. McAuliffe, series editor), The Macmillan

Press Ltd., London. T. Takahashi (1984), "Fuel Cells (Japanese)",

Chemistry One Point Series 8 (M. Taniguchi, editor),

Kyoritsu-shuppan, Tokyo, Japan. J.D. Canaday, et al. (1987), "A Polarization Model for Protonic Solid Electrolyte Fuel Cells," Int. J. Hvdroσen Energy. Vol. 12, No. 3, pp. 151-157.

A.O. Isenberg (1981), "Energy Conversion via Solid Oxide Electrochemical Cells at High Temperatures," Solid State Ionics, Vols. 3/4, pp. 431-437.

Additional general information is found in "Fuel Cells" by E. J. Cairns et al in Kirk-Othmer: Encyclopedia of Chemical Technology. (3rd Ed.), Vol. 3, pp. 545-568; and in "Fuel Cells" by O.J. Adlhart in Van Nostrand's Scientific Encyclopedia, 6th ed., D. M. Considine (ed), Van Nostrand Reinhold Co., New York, pp. 1296-1299, 1986, which are both incorporated herein by reference.

Lyall in U.S. Patent No. 3,625,769 and Fouletier in U.S. Patent No. 4,526,674 each disclose lithium/oxygen fuel cells.

Raleigh in U.S. Patent No. 4,118,194 and Weininger in U.S. Patent No. 3,565,692, each disclose halogen electrochemical cells or the like. Solid electrolyte fuel cells have several advantages over the other types of fuel cells:

1. There are no liquids involved and, hence, the problems associated with pore flooding, maintenance of a stable three-phase interface, and corrosion are totally avoided.

2. Being a pure solid-state device, it poses virtually no maintenance problems. For example, the electrolyte composition is invariant and independent of the composition of the fuel and oxidant streams.

3. Inexpensive metallic oxides (ceramics) rather than expensive platinum can be used as the electrode catalysts. 4. The solid electrolyte fuels cells demand less feed gas preparation than the phosphoric acid cell (see Figure 1), which requires a conversion of CO to H₂ via the water-gas shift reaction, or the molten carbonate cell (see Figure 1), which requires a carbon dioxide loop due to the use of carbonate ions for ionic transport.

The attraction of developing a solid electrolyte fuel cell is its simplicity. However, a high operation temperature (ca. 1000ºC) is by far the most critical aspect of this type of fuel cell. Although high operation temperature produces high-quality exhaust heat that can generate additional electrical power, leading to a high overall system efficiency, maintaining the integrity of the cell components such as the interconnector is the most difficult challenge. It is therefore desirable to develop alternative low temperature solid materials and composites for use as solid electrolytes in fuel cells that can be operated in a range of 25-600ºC or lower (preferably about 200-400ºC, especially at ambient temperature). The present invention relates to the design of such low temperature solid electrolyte fuel cells based on non-oxide solid electrolytes, such as solid solutions of lanthanide fluorides (e.g. La_1-xSr_xF_3-x).

References of interest regarding such lanthanide fluorides include:

B. C. LaRoy et al., in the Journal of the Electrochemical Society: Electrochemical Science and

Technology, Vol. 120, No. 12 pp. 1668-1673, published in December 1973, disclose some electrical properties of solid-state electrochemical oxygen sensors using vapor deposited thin films. Polycrystalline thin films of lanthanum fluoride solid electrolytes were investigated at ambient temperature.

In U.S. Patent No. 3,698,955 and 3,719,564, Lilly discloses the use of rare earth fluorides such as lanthanum fluoride as solid electrolytes which are deposited as their films in a battery and a gas sensor respectively.

G. W. Mellors in European Patent Application No. 055,135 discloses a composition which can be used as a solid state electrolyte comprising at least 70 mole percent of cerium trifluoride and/or lanthanum trifluoride an alkaline earth metal compound, e.g. fluoride, and an alkali metal compound, e.g. lithium fluoride.

A. Sher, R. Solomon, K. Lee, and M.W. Muller (1967), "Fluorine Motion in LaF₃", in "Lattice Defects and Their Interactions", R.R. Hasiguti, Editor, pp. 363-405, Gordon and Breach Science Publishers, New York.

A. Yamaguchi and T. Matsuo (1981), "Fabrication of Room Temperature Oxygen Sensor Using Solid Electrolyte LaF₃ (Japanese)", Keisoku-Jidoseigyo-Gakkai Ronbunshu, Vol. 17(3), pp. 434-439.

M.A. Arnold and M.E. Meyerhoff (1984), "Ion-Selective Electrodes," Anal. Chem., Vol. 56, 20R-48R. S. Kuwata, N. Miura, N. Yamazoe, and T. Seiyama (1984), "Potentiometric Oxygen Sensor with Fluoride Ion Conductors Operating at Lower-Temperatures (Japanese)", J. Chem. Soc. Japan, 1984(8), pp. 1232-1236, and "Response of A Solid-State Potentiometric Sensor Using LaF₃ to A Small Amount of H₂ or CO in Air at Lower Temperatures", Chemistry Letters, pp. 1295-1296, 1984.

M. Madou, S. Gaisford, and A. Sher (1986), "A Multifunctional Sensor for Humidity, Temperature, and Oxygen", Proc. of the 2nd International Meeting on Chemical Sensors, Bordeaux, France, pp. 376-379.

N. Yamazoe, N. , J. Hisamoto, N. Miura, S. Kuwata (1986) , "Solid State Oxygen Sensor Operative at Room Temperature", in Proc. of the 2nd Int. Meeting on Chemical Sensors, Bordeaux, France. J. Meuldijk, J. and H.W. den Hartog (1983), "Charge Transport in Sr_1-xLa_xF_2+x solid solutions. An Ionic Thermocurrent Study", Physical Review B, 28(2), PP. 1036- 1047.

H.W. den Hartog, K.F. Pen, and J. Meuldijk (1983), "Defect Structure and Charge Transport in Solid Solutions Ba_1-xLa_xF_2+x", Physical Review B, 28(10), pp. 6031-6040.

J. Schoonman, J., G. Oversluizen, and K.E.D. Wapenaar (1980), "Solid Electrolyte Properties of LaF₃", Solid State Ionics, Vol. 1, pp. 211-221.

A.F. Aalders, A. Polman, A.F.M. Arts and H.W. de Wijn (1983), "Fluorine Mobility in La_1-xBa_xF_3-x (0<×<0.1) Studied by Nuclear Magnetic Resonance", Solid State Ionics, Vol. 9 & 10, pp. 539-542.

A. K. Ivanovshits, N.I. Sorokin, P.P. Fedorov, and B.P. Sobolev (1983), "Conductivity of Sr_1-xBa_xF_3-x Solid Solutions with Compositions in the Range 0.03<x<0.40, "SOV. Phys. Solid State, 25(6), pp. 1007-1010.

H. Geiger, et al (1985), "Ion Conductivity of Single Crystals of the Non-Stoichiometric Tysonite Phase La_1-xSr_xF_3-x (0 < × < 0.14)," Solid State Ionics. Vol. 15, pp. 155-158. A.C. Lilly, et al. (1973), "Transport Properties of La₃F Thin Films," J. Electrochem Soc., Vol. 120, No. 12, pp. 1673-1973.

N. Miura, et al. (1987), "Development of Solid State Oxygen Sensor Operation at Room Temperature," Proc. 4th Int. Conf. Solid-State Sensors and Actuators, Toyko, Japan, pp. 681-684 (June).

Some of the structures described herein have been examined for usefulness as battery electrolytes. However, none of the references cited hereinabove, individually or collectively, disclose or suggest the present invention as described herein. All of the references cited above are incorporated herein by reference. SUMMARY OF THE INVENTION The present invention relates to a solid O^2- (oxide ion) conducting material for use as an electrolyte for a fuel cell, comprising: (a) a monocrystal or polycrystal structure of the formula:

A_1-xB_xZ (AA) wherein

A is independently selected from lanthanum, cerium, neodymium, praseodymium, scandium or mixtures thereof;

B is independently selected from strontium, calcium, barium or magnesium, and x is between about 0 and 0.9999,

Z is selected from the group consisting of F_3-x and O_cF_d where F is fluorine, O is oxygen, x is between about 0 and 0.9999 and 2c+d = 3-x, wherein c is between 0.0001 and 1.5 and d is between 0.0001 and less than or equal to 3, with the proviso when A is lanthanum, Z is F_3-x and x is 0, the solid material is only a monocrystal.

In another aspect, the present invention relates to a solid electrolyte fuel cell comprising a structure:

C - E - A - S wherein a first electrode material (C) , which is only in contact with a thin film solid electrolyte (E) which is also separately in contact with a second electrode material A which is also separately in contact with a porous mechanical support material (S), wherein the thin film solid electrolyte has the structure:

A_1-xB_xZ (AA) wherein A is independently selected from lanthanum, cerium, neodymium, praseodymium, scandium or mixtures thereof;

B is independently selected from strontium, calcium, barium, or magnesium, x is between about 0 and 0.9999,

Z is selected from the group consisting of F_3-x and O_cF_d wnere F is fluorine, 0 is oxygen, x is between about 0 and 0.9999 and 2c+d = 3-x, wherein c is between 0.0001 and 1.5 and d is between 0.0001 and less than or equal to 3, with the proviso when A is lanthanum, Z is F_3-χ and x is 0, the solid material is only a monocrystal.

In a preferred embodiment, the second electrode material is in contact with a porous metallic support (e.g. stainless steel, nickel) that also operates as a current collector. In yet another aspect the present invention relates to a solid material for use as an electrolyte for a fuel cell comprising: a monocrystal or polycrystal structure of the formula:

Pb_eSn_fF_g wherein Pb is lead, Sn is tin, with the proviso that when f is 1, e is 1 and g is 4 and with the additional proviso that when e is 1, f is 0, and g is 2.

BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 (as Figures 1A and IB) shows Table 1 as a comparison of various types of fuel cells.

Figure 2 shows a representative schematic diagram of the experimental set up to test the solid electrolyte fuel cell.

Figure 3 shows a representative schematic diagram of the solid electrolyte fuel cell assembly for testing.

Figure 4 shows a graph of a solid electrolyte fuel cell of dependence of V_oc on temperature.

Figure 5 shows a typical chart recorder response of an open circuit voltage of a single crystal lanthanum fluoride disk upon an On/Off cycle of hydrogen/argon as a function of time.

Figure 6 (as Figures 6A to 6F) shows a set of hydrogen/oxygen fuel cell current and power vs. cell voltage of single crystal lanthanum fluoride disks (0.64 mm thickness) as a function of temperature and pretreatment with oxygen.

Figure 7 is a phase diagram of the SrF₂-LaF₃ system. Figure 8 is an X-ray defraction (XRD) pattern from a sample with the nominal composition of

La_0.974Sr_0.026F_2.974

Figure 9 (as Figures 9A to 9E) shows a set of data concerning the H₂/O₂ fuel cell current and power-cell voltage relationship of La_0.92Sr_0.08F_2.92 Pellets.

Figure 10 shows a scanning electron micrograph of a cross-sectional view of the platinum catalyst view of the platinum catalyst/polished La_0.92Sr_0.08F_2.92 Pellet interface.

Figure 11 (as Figures 11A to HE) shows a set of data concerning H₂/O₂ fuel-cell current and power versus cell voltage related to the roughened surface of a

La_0.904Sr_0.096F_2.904 Pellet at five different operating temperatures.

Figure 12 shows a scanning electron micrographs of a cross-sectional view of the platinum catalyst/roughened

La_0.904Sr_0.096F_2.904 Pellet interface.

Figure 13 illustrates a typical response of a short-circuit current (I_sc) of a roughened surface

La_0.90.4Sr_0.096F2.904 pcellet (xused) as a function of time at approximately 200ºC at an ON/OFF cycle of H₂/Ar.

Figure 14 shows the Isc at 200°C as a function of time for 100 hours (6,000 minutes) for a pellet of

La_0.938Sr_0.062F_2.938.

Figure 15 shows a schematic cross-sectional representation of a thin-film solid-electrolyte fuel cell.

Figures 16A and 16B show a graph of the projected performance of a thin film polycrystalline La_1-xSr_xF_3-x solid electrolyte fuel cell. Figure 16A is conducted at 300ºC, and Figure 16B is conducted at 400ºC.

Figures 17A, B and C show depth profiles of virgin and used polycrystalline LaF₃ pellets by Auger electron spectroscopy.

Figure 18A is a photograph of the original surface of PALL P05 porous stainless steel substrate (0.5 micrometer nominal pore size). Figure 18B is the surface of the PALL

P05 substrate coated with platinum electrochemically deposited at -679 mV for 2.5 hours.

Figure 19 is an illustration of the vacuum deposition station used to deposit a thin film of La_1-xSr_xF_3-x on a porous substrate (e.g., stainless steel).

Figure 20 is a cut away exploded view of the sample placement within the vacuum deposition station of Figure 19. Figure 21 is a photograph of lanthanum fluoride film (about 10μm) deposited on an uncoated (i.e. no sample deposition) SSI (S-2930, 2 micrometer nomimal pore size) porous stainless steel substrate.

Figure 22 is a cross section of a solid material composite useful as a solid electrode having a catalyst support, a platinum contact, a solid coating of an electrolyte (e.g. La_0.7Sr_0.3F_2.7) with a solid discontinuous coating of a perovskite-type (e.g. La_0.7Sr_0.3CoCO₃) electrode.

Figure 22A is an enlarged cross section showing the discontinuous nature of the electrolyte in contact with the electrode on the solid support.

DETAILED DESCRIPTION OF THE INVENTION AND PREFERRED EMBODIMENTS Definitions

As used herein: "Contact" refers to the laminate structure of Figure 15. It refers not only to physical contact but also may refer to a new phase between layer 151 and 152 or between layer 152 and 153 (or i.e., C and E or E and A, respectively), which is produced during formation or afterward having different chemical properties and/or physical properties than the immediately adjacent phase (e.g., a mixed conduction - electron or ion - phase). See Figure 15 and Figures 22 and 22A.

"Fuel gases" refer to oxygen (as defined herein) and hydrogen (as defined herein) or liquids or gases which contain carbon, such as carbon dioxide, carbon monoxide, methane, ethane, natural gas, reformed natural gas or mixtures thereof. Liquids such as methanol, ethanol or mixtures thereof are also useful. "Hydrogen electrode" or "hydrogen" refers to hydrogen and as used herein may refer to carbon containing fuel gases. "Oxygen electrode" or "oxygen" refers to the oxidizing electrode side of the fuel cell, and may be oxygen or oxygen mixed with air, or air itself.

In the present invention, O^2- (oxide ion) conducting lanthanum fluoride (either in its pure form or its substituted form) is the solid electrolyte of choice for a fuel cell. The basic properties of LaF₃ are shown below in

Table 2.

Table 2 PROPERTIES OF LaF₃

-Crystal structure: hexagonal space group is P6₃/mcm

-D³ _6h -with twelve formula units per cell,

-Melting Point: 1493ºC, -Density: 5.936,

-Dielectric constant: 14 (at 10MHz), -Thermal conductivity: 0.025 (W cm~¹deg^-1), -Electrical conductivity about 10^-7 Ω^-1cm^-1 (at 25ºC) -Transmits light from the vacuum ultraviolet into the infrared,

-The effective Debye temperature is: +360ºK,

-The activation energy for fluorine ion diffusion is about 0.45 eV, -Activation energy for the formation of defects: about 0.07eV,

-Birefringence: n=0.006,

-Thermal expansion coefficient: 11×10^-6 cm/cm/ºC (c-axis, 25°C), a good match is Cu,

LaF₃ has unique physicochemical properties such as high electrical conductivity and high polorizability at room temperature. The Debye temperature of LaF₃ is only 360ºK, while its melting point is high at 1766ºK. The observed phenomena appear to be associated with the formation of Schottky defects and with the activation energy for the diffusion of defects having the unusually low value of about 0.42 eV, and the room temperature Schottky defect density is about 10¹⁹/cm³.

Fluorine in LaF₃ usually exists in three magnetically non-equivalent sites . Covalent bonding predominates in two of the sites. In the third site, the fluorines make up a layered array with approximately 60% ionic bonding and about 40% π-bonding. The high polarizability and high conductivity of LaF₃ at room temperature is primarily due to the motion of F- ions through the latter sites. The relatively small radius of F-(1.19A) is almost identical with that of the oxide O ^2- ion (1.25A); therefore oxide ions (O ^2- ions) can substitute for the F ions in LaF₃.

The oxygen ion is transported through the bulk of a single crystal LaF₃ as measured by Auger electron spectroscopy. In other words, the solid electrolyte LaF₃ serves as a supporting electrolyte analogous to liquid phase in which oxygen ions can move freely.

Our solid solutions with the formula A_1-xB_xZ (e.g. where A is lanthanum and B is strontium or barium and Z is F and x is defined herein) exhibit a much higher ionic conductivity that pure LaF₃. Moreover, this type of solid solution contain a large amount of F- ion vacancies in which oxygen ions can be sited. Therefore, the solid solutions A_1-xB_xZ (where A is lanthanum, B = strontium or barium, Z is F and x is as defined herein) are very attractive as solid electrolytes for lower temperature, solid electrolyte fuel cells.

In practice, Z can also be O_cF_d (where 2c+d = 3-x) due to small impurity oxygen that may be present during the preparation of A_1-xB_xF_3-x. Alternatively, the mobile oxygen ions sitting in the vacant F~ sites may be viewed as O_cF_d instead of pure F or Z (for both monocrystal and polycrystal forms). Lanthanum Fluoride (Single Crystal) as a Solid Electrolyte for Fuel Cell

Traditionally, LaF₃ has been extensively used as a F- ion selective electrode in electroanalytical chemistry. Recently LaF₃ has been applied to a room temperature potentiometric oxygen sensor and to a multifunctional sensor for humidity, temperature, oxygen gas, and dissolved oxygen. However, no disclosure exists concerning the use of LaF₃ material as a single crystal as a solid electrolyte in a fuel cell; nor the use of A_1-xB_xZ (e.g. La_1-xB_xF_3-x (where 0 < x ≤0.5) as a single crystal or as a polycrystal for a solid electrolyte in a fuel cell. Experimental Setup

Figure 2 depicts a block diagram of the experimental setup 20 used to evaluate various La_1-xB_xF_3-x soli electrolytes (e.g., single crystal LaF₃ disk) for the fuel cell application. The temperature of the cell 21 is maintained at a desired value (about 25-300°C) using a heating tape 22 (coiled around the cell), whose voltage is controlled by a transformer. Cell voltages are measured by a high-input impedance electrometer 23 (e.g. Keithley Model 617). A strip chart recorder 26 (e.g., Soltec Model 1243; with three channels) is used to measure currents, cell emf

(electromotive forces), or both as a function of time. The measurements are carried out under gentle streams of oxygen

24 (99.99 percent purity) and hydrogen 25 (99.99 percent purity) that are controlled by flowmeters 27A and 27B and are passed through each compartment of the cell at a flow rate of about 20 cc/min. The oxygen may be replaced by air. The hydrogen may be replaced by a fuel gas as defined herein. Current cell-voltage (IV) curves are obtained by controlling the potential difference between two platinum electrodes by means of a PAR Model 173 potentiostat from Princeton Applied Research or a BAS Model CV 37 voltammograph from Bioanalytical Systems. Currents are measured typically 3 min after changing the cell voltages. Experimental Fuel Assembly

Figure 3 illustrates the design for the experimental fuel cell assembly 30 in detail. A circle about 4 mm in diameter of Pt mesh 31 (or 31A) (mesh size: 50) is used as a current collector. An ohmic contact is made by mechanically pressing a stainless steel mesh 32 (mesh size: about 60) against the Pt catalyst/Pt mesh using a stainless steel rod 33, which also serves as an electrical lead and is fixed in a rubber stopper 34 (or 34A). A pair of electrode holders made of Teflon (35A, 35B) to hold the disk (e.g., La_1-xSr_xF_3-x) 36, Pt meshes (30, 30A), and stainless steel meshes (32, 32A) together. A pair of stainless steel tubes 37A, 37B with appropriate gas inlet 38A, 38B and outlet 39A, 39B form the main body of the fuel cell 30. The Teflon electrode holder system (35A and 35B) is inserted between the two stainless steel tubes, and the entire assembly is held together tightly by stainless steel screws 40A, 40B.

Dependence of V_oc on Temperature

Figure 4 graphically presents the open-circuit cell voltages (V_oc) of a single crystal LaF₃ disk 0.64 mm thick as a function of temperature (0 to 300°C) when the cathode and anode were exposed to oxygen and hydrogen, respectively. The LaF₃ disk is equilibrated with each new temperature for about 60 min before a steady-state reading of the V_oc was taken. The V_oc appears to increase almost linearly with an increase of the cell temperature and saturates around 1.07 V at temperatures about 250ºC. The saturated value of 1.07 V obtained is in fair agreement with the theoretical value of V_oc for a hydrogen/oxygen fuel cell, i.e. 1.13V at 227ºC. A slight hysteresis was observed in the V_oc vs. temperature relation when the measurements are made in the direction of decreasing temperature, indicating that the reaction that determines V_oc is not completely reversible.

The large deviation of V_oc values from the theoretical values observed at lower temperatures ( 25 ° C to 200 º C) , gradually diminishes as the temperature increases. Possible explanations are either that the electrochemical reactions at the electrodes are slow or that the resistance of the solid electrolyte is extremely high (ohmic over potential). An ohmic over potential would most likely be associated with a slow transport of O^2- ions in such pure (unpretreated) LaF₃ at these low temperatures. Figure 5 illustrates a typical response of an open-circuit cell voltage (V_oc) of an untreated single crystal LaF₃ disk as a function of time at about 175ºC. When hydrogen is switched to argon in the anodic compartment (while oxygen is passed through the cathodic compartment), the V_oc decays to nearly 0 volts within about 10 min; this slow decay is most likely due to residual H₂ and H⁺ ions in the lattice in the vicinity of the anode. The V_oc goes back to its original value (about 1 V) within about 10 seconds upon switching back to hydrogen. The recorder saturated at the point shown by the dotted line. This observation supports the idea that an oxygen/hydrogen fuel-cell reaction is taking place on the single crystal LaF₃ disk. These response times become longer as the operating temperature drops .

In the present invention certain combinations of materials, thickness and operating temperatures for the fuel cell are preferred.

In preferred embodiments, the solid material electrolyte described as (AA) in the Summary is one where A is lanthanum, and/or where B is strontium.

In another embodiment, the electrolyte of structure (AA) is one where Z is F_3-x.

In yet another embodiment, the electrolyte (AA) is one where Z is O_cF_d and where the oxygen is an integral part of the crystal lattice, especially where A is lanthanum, Z is F_3-x, and x is 0, and the solid material is a monocrystal. In still another embodiment, the solid material electrolyte (AA) is one where the solid material as a monocrystal has a thickness between about 1 and 300 micrometers, or as a polycrystal has a thickness between about 1 and 100 micrometers. Preferred temperatures of operation for the fuel cell of structure (AA) to generate an electrical current at a temperature of between about 20 and 600ºC, especially between about 200 and 400ºC. Current-Cell Voltage (l-V) Characteristics Figure 6 (6A to 6F) presents a set of data concerning the H₂/O₂ fuel cell current (I) and power (P) vs. cell voltage relations of a single crystal LaF₃ disks 0.64 mm thick with or without a pretreatment as a function of operating temperature. Figures 6A, 6C and 6E have no pretreatment. Figures 6B, 6D and 6F are pretreated in oxygen at 600 'C for 1 hour. Generally speaking, the electromotive forces (cell voltages) show a good reproducibility, while the current densities do not, probably because of a variation in the morphology of the electrocatalyst/electrolyte interface (i.e., Pt black/LaF₃ disk) of each sample. The current density increases with operating temperature, and the I_sc of the LaF₃ disk becomes about 20 μA/cm² at 204ºC (see Figure 6E), which is about 10 times that at room temperature. When the single-crystal LaF₃ disks are pretreated by annealing in an oxygen atmosphere for 1 hr at 600ºC, current densities increased dramatically. The fuel cell short-circuit current density becomes as high as 2 × 10^-4 A/cm² at 206°C. The observed positive influence of the pretreatment of O₂ of the LaF₃ disk on the current density is most likely due to the formation and/or impregnation of O^2- ions into the lattice of LaF₃.

In the present invention, certain combinations, material thicknesses of electrolytes, temperature of operation, etc. are preferred. These include the following:

In a preferred embodiment, the solid electrolyte fuel cell is one where the first electrode material is in contact with an oxidizing gas and the second electrode material is in contact with a reducing gas.

In a preferred embodiment, the solid electrolyte fuel cell is one where the anode material is in contact with a reducing gas and the second electrode material is in contact with an oxidizing gas.

In a preferred embodiment, the solid electrolyte fuel cell is one where the porous support is colloidal alumina. In a preferred embodiment, the solid electrolyte fuel cell is one where the thin film solid electrolyte is between about 1 and 300 micrometers in thickness.

In a preferred embodiment, the solid electrolyte fuel cell is one where in the thin film solid electrolyte B is strontium. In a preferred embodiment, the solid electrolyte fuel cell is one where in the thin film solid electrolyte A is lanthanum.

In a preferred embodiment, the solid electrolyte fuel cell is one where x is between about 0.001 and 0.2, especially about 0.1.

In a preferred embodiment, the solid electrolyte fuel cell is one where the thin film has a thickness of about 10 micrometers.

In a preferred embodiment, the use of the solid material of Claim 1 as an electrolyte (AA) for a fuel cell is conducted at a temperature of between about 200 and 500ºC, especially at a temperature of between about 300 to

500ºC.

Thermodynamic Considerations

The probable fuel-cell electrochemical reactions taking place at each electrode are: Cathode (positive electrode):

O₂ + 4e-→ 2 O^2- (1)

Anode (negative) :

2 H₂ + 2 O^2- → 2 H₂O + 4e-. (2) These lead to the well-known fuel-cell overall reaction: O₂ + 2H₂ → 2 H₂O, which has a Gibbs free energy change, ΔGº, of -56.8 kcal/mol at room temperature and is thermodynamically very favorable.

In using a LaF₃ crystal as a solid electrolyte in a fuel cell, it is reasonable to ask whether or not the formation of HF or F₂ is likely in addition to Reaction (2) . The thermodynamic considerations governing the formation of these chemical are as follows: Cathode:

3/2 O₂ + 2LaF₃ + 6e- →La₂O₃ + 6F- (3)

Anode:

3H₂ + 6F- → 6HF + 6e- (4)

Overall:

3/2 O₂ + 2LaF₃ + 3H₂ → La₂O₃ + 6HF (5)

ΔGº = + 40.2 kcal/mol at 25ºC Cathode:

3/2 O₂ + 2LaF₃ + 6_e- →La₂O₃ + 6F- (3)

Anode: 6F- → 3F₂ + 6e- (6) Overall:

3/2 0₂ + 2LaF₃ → La₂O₃ + 3F₂ (7)

ΔGº = + 432 kcal/mol at 25ºC

Therefore, Reactions (5) and (7) above, are thermodynamically unfavorable and quite unlikely. It is noted, however, that the product of the cathodic reaction in Eq. (3) may be a lanthanum oxyfluoride that can be written as LaO_xF_3-2x (for which no thermodynamic data are available), rather than La₂O₃ (at least at the LaF₃ surface). It is likely that the formation of LaO_xF_3-2x is thermodynamically more favored than that of La₂O₃, which might lead to the production of a very small amount of HF. Polycrystalline La_1-xB_xF_{3 -x} Materials The basic method we have chosen for preparing polycrystalline pellets is as follows:

- Mix LaCl₃·7H₂O and SrCl₂·6H₂O Dissolve mixture in dilute HCl - Add HF solution for coprecipitation

- Decant and settle (three times)

- Filter

Dry at about 120ºC (overnight)

- Calcinate (overnight at about 950ºC in argon) Press and sinter (hot press) Coprecipitation of the fluorides form a slightly acidic solution of the chlorides is the most efficient means of ensuring a homogeneous mixture. The salts are dissolved in deionized water with a small amount of HCl added to ensure that the pH is sufficiently low as to prevent formation of the insoluble hydroxides. A commercial NH₄F:HF solution with a ratio of 7:1, sold to the semiconductor industry as buffered oxide etch (BOE) , has been used as the precipitant because it is the most chemically pure fluoride source available; in addition, because it is buffered, it is less hazardous than pure HF. See Example 7. The resulting power samples of La_1-χB_xF_3-x (B = strontium or barium) as pressed into rods (approximately 1 cm in diameter by approximately 2 cm long) by conventional hot-pressing process. Individual pellets with approximately 1 mm thickness are prepared by slicing the rods using a mechanical saw. Alternatively, some of the powders are first pressed hydrostatically into disks, which are subsequently sintered.

A phase diagram of the system SrF₂-LaF₃ is presented in Figure 7 (Yoshimoto, Kim and Somiya, 1985, 1986), together with our data points (shown as solid or open diamonds). According to this phase diagram, solubility limits in the system SrF₂-LaF₃ to form a single phase solid solution are a function of temperature as follows:

Therefore, one is able to synthesize single-phase A_1-xB_xF_3-x solid solutions using temperatures below 1400° C only when strontium concentrations are below 15 percent.

Figure 8 is an XRD pattern from a sample with the nominal composition of La_0.974Sr_0.026F_2.974, which is single phase, showing a substantially identical XRD pattern as the one for LaF₃. However, there is a very small peak at about d = 3.35 A, indicated by the arrow in Figure 8, which is most probably due to LaOF.

The formation of a single phase with minor peak due to the presence of LaOF is confirmed with polycrystalline strontium (or barium) substituted (i.e. B is strontium or barium) substituted A_1-xB_xF_3-x pellets in the range where x is greater than or equal to O and less than or equal to 0.15.

Fuel Cell Performance Data Obtained with La_1-xM_xF_3-x Polycrystalline Pellets Figure 9 (9A to 9E) presents a set of data concerning the H₂/O₂ fuel cell current (I) and power (P) cell voltage relations of La_0.92Sr_0.08F_2.92 pellets (approximately 1 mm thick) with and without a physical pretreatment of polishing both sides of the pellets by an emery paper (#120) as a function of operating temperature. (Figures 9A and 9C are as prepared; Figures 9B, 9D and 9E are polished). The polished pellet with the surface layer removed by polishing gives a much higher current density (by about a factor of 10) than the unpolished pellet with as-prepared surface. The observed increase of reaction rate (i.e. current density) of the fuel cell is due to an increase the "real" electrochemical surface area, i.e. number of the triple contact points, where the gas reactions can take place.

A scanning electron micrograph (SEM) of a cross-sectional view of the platinum catalyst/polished La_0.92Sr_0.08F_2.92 pellet interface is shown in Figure 10. An array of submicron-size "ridges" is visible at the platinum/solid electrolyte interface. The observed enhancement of Isc on the polished surface could be also partly due to the removal of the surface layer that may contain some "undesirable" materials (e.g. LaOF). It therefore would be still possible to enhance the current density further, say by another factor of 10, by carefully optimizing the microstructure of the interface.

The effect of operation temperature was studied using the same polished La_0.92Sr_0.08F_2.92 pellet. When the temperature was increased from 215ºC to 287ºC, the short-circuit current density was increased: from 165 μA/cm² to 674 μA/cm² i.e., a factor of 4. An almost linear decrease of the current density with the cell voltage in the low cell voltage region of the I-V plot at 287ºC is indicative of a high electrolyte resistance (a total of approximately 400Ω) still existing at this temperature. This situation can be improved by making the electrolyte much thinner.

High current density is observed with an approximately 2-mm thick La_0.904Sr_0.096F_2.904 pellet with a roughened surface, which produced approximately 1.2 mA/cm² at 214ºC. This value should be compared with the performance of a typical hydrogen/oxygen solid electrolyte fuel cell based on (for example) a calcia-stablized zirconia (ZrO₂)_0.85 (CaO)_0.15 0.4 mιn thick, which exhibit an Isc of approximately 60 mA/cm² at 900ºC (McDougall, 1976). Figure 11 (11A to HE) presents a set of data concerning H₂/O₂ fuel-cell current and power vs. cell voltage relations of the roughened surface La_0.904Sr_0.096F_2.904 pellet at five different operating temperatures. Two thin layers of commercial fuel-cell grade platinum black power, which serve as "grinding" powder, are first pressed together with powder of the electrolyte placed in between. The platinum black came off after sintering, and the platinum catalyst is applied using H₂PtCl₆ solution. A scanning electron micrograph of a cross-secitonal view of the platinum catalyst/roughened La_0.904Sr_0.096F_2.904 pellet interface is shown in Figure 12. Indeed, the interface presents a very rough surface on which highly porous platinum catalysts are densely deposited and uniformly distributed over the surface with few voids.

The same magnitude of high current density (on the order of 1 mA/cm²) was also observed when a composite was used as an electrode; a 50%/50% mixture by weight of the platinum black powder catalyst and the powder of La_0.904Sr_0.096F_2.904 were pressed and inserted together with the electrolyte powder of La_0.904Sr_0.096F_2.904 in between; and used as an electrode. In conclusion, a further improvement of current densities by one or two orders of magnitude should be possible when an ultra-thin film of La_1-xSr_xF_3-x is used in conjunction with proper electrocatalysts and an optimized electrolyte/electrode interface.

Figure 13 illustrates a typical response of a short-circuit current (I_sc) of a roughened surface La_0.904Sr_0.096F2.904 pelled (used) as a function of time at approximately 200ºC. When oxygen is switched to argon in the cathodic compartment (while hydrogen is passed through the anodic compartment), the Isc rapidly decays to around 0 within 20 s. The Isc goes back to its original value within 20 s upon switching back to oxygen. This observation strongly' supports the observation that an oxygen/hydrogen fuel-cell reaction is taking place on the pellet of La_0.904Sr_0.096F_2.904. The residual current observed in argon is most likely due to oxide ions (O^2-) remaining in the lattice.

A long term "fuel-cell" performance test was carried out at approximately 200°C using a pellet of La_0.904Sr_0.096F_2.904, which was pretreated in oxygen at 600ºC for 20 hours. Figure 14 shows the I_sc as a function of time for 100 hr. (6000 minutes); as observed with the LaF₃ single crystal disk the Isc gradually decreased and became a quasi-steady state. The precise mechanism for this degradation is not fully understood. It would be reasonable to attribute a part of this degradation to a gradual deterioration of the morphological stability of the catalyst/solid electrolyte interface under the operating condtions. However, our independent experimental data suggests that the degradation could be, to a larger extent, due to rather "poor" gas sealing conditions provided by the Teflon electrolyte holder/gasket. Thin-Film Polycrystalline La_1-xSr_xF_3-x Solid Electrolyte Fuel Cell

Figure 15 shows an idealized schematic cross section of a laminate of a thin-film La_1-xSr_xF_3-x solid-electrolyte fuel cell. The cell is arranged in a multilayer structure on a porous support 154. A similar basic structure but on a porous support "tube" has been used for Westinghouse thin-film zirconia solid-electrolyte fuel cell (Isenberg, 1981). The porous support 154, such as porous sintered glass (e.g. Vycor glass) and porous alumina, provides mechanical integrity for the multilayer structure and also serves as conduit for one of the reactants, e.g. hydrogen. Alternatively, an electronically conductive (e.g., metallic substrate such as porous stainless steel or a nickel disk and porous sintered nickel plaque) could be used as the mechanical support 154 which also serves as a current collector, and as an electrocatalyst (e.g. nickel). Figure 15 shows cathode (C) as 151, electrolyte (E) as 152, anode (A) as 153 and support (S) as 154. The anode A and cathode (C) may be reversed when the gases O₂ and H₂ are also reversed.

Figures 22 and 22A present a more realistic view of the discontinuous surface of the solid electrolyte fuel cell of Figure 15. Figure 22 shows the configuration of a supported composite for use in a fuel cell. The perovskite substrate 71 is spray dried onto an inorganic or metal support 70 (or 154) such as silica, thoria, zirconia, magnesia, stainless steel or the like having mechanical stability. The fluoride electrolyte (E) 72 is then vapor deposited on the surface of the perovskite 71. As shown in Figure 22A the fluoride electrolyte 72 as a vapor enters the pores of the perovskite 71 and the substrate 70 in a discontinuous manner. In this way, millions of two-material catalytic surfaces 74 are created to facilitate the electrochemical reaction at the intersection of the perovskite 71 and fluoride 72.

The overall performances of the low-temperature thin-film La_1-xSr_xF_3-x solid-electrolyte fuel cell are reasonably predicted as follows using a mathematical overall cell voltage, Vcell/current density, J, relation (Canady et al., 1987):

where V is the reversible thermodynamic electromotive force (emf), R is gas constant, T is absolute temperature, F is Faraday's constant, L is electrolyte thickness, is the specific resistance of the solid electrolyte, J_L,a and J_L,c are limiting current densities at anode and at cathode, and J_o,a and J_o,c are exchange current densities at anode and cathode, respectively. The second and fourth terms in Eq. (8) represent the concentration polarization of the electrodes (which depends on the electrode morphological parameters, porosity and thichness); the third and fifth terms in Eq. (8) represent activation polarization at the three-phase point of the electrode-electrolyte interface, and the last (sixth) term in Eq. (8) represents ohmic polarization (which solely depends on electrolyte resistivity and thickness).

Table 2 lists values of thermodynamic emf and resistively used in the calculations. In these calculations, values are used (as a first approximation) for exchange current density for electrodes J_0,a and J_o,c data that were experimentally determined for the case of zirconia-and ceria-based fuel cells, viz. approximately 1 mA/cm2 for both electrodes (Canaday, et al., 1987). The anode and cathode limiting current densities, J_L,a and J_L,c, associated with an interdiffusion of hydrogen and oxygen, have been estimated as 82.9 and 44.3 A/cm² at 300ºC and 1 atm, respectively, assuming bulk electrode thickness of 10 μm with a porosity of 10 percent (Canaday, et al.,

1987 ) .

Figures 16A and 16B show the calculated cell voltages plotted against current density (I-V curves) for the polycrystalline films of La_1-xSr_xF_3-x as a function of operating temperature (300 and 400ºC) for the film thickness 10 μm; in each case, three different concentrations of strontium substitution (viz. x = 0, 0.026, and 0.1) are considered. When the LaF₃ polycrystals are doped with strontium (2.6 or 10 molpercent), a cell voltage of approximately 0.6 V or 0.8 V is found, which generates a current density of 200 mA/cm² when the fuel cell is operated at 300°C or 400°C, respectively. The effect of strontium concentration (x = 0.026 or 0.1) appears to be minimal. Similar performance levels may be obtained by highly nonstoichiometric films of LaF_3-x (made by e.g., electron-beam evaporation) that exhibit comparable ionic conductivity. A further increase in operating temperature to 500ºC does not seem to improve the fuel-cell performance in terms of the I-V curves, so long as the strontium concentration is maintained between 2.6 and 10 mol-percent. On the other hand, the fuel-cell maximum power density dramatically increases almost linearly with an increase of operating temperature; especially when the strontium content is 10 mol-percent, and reaches approximately 0.55 W/cm² at 500ºC. The set of I-V curves shown in Figure 16A and 16B may represent rather a modest case, because the calculations were made on the basis of highly resistive polycrystalline La_1-xSr_xF_3-x films [it was assumed that the resistivity of polycrystalline La_1-xSr_xF_3-x thin films is two orders of magnitude greater than the resistiveity of the single crystal, following the data given by Lilly et al. (1983) on thin films of LaF3]. Fuel-cell performance could be further significantly improved if we could reduce the resistivity of polycrystalline films by carefully optimizing a thin-film deposition process. For example, if the resistivity of polycrystalline La_1-xSr_xF_3-x films is reduced by two orders of magnitude (thus approaching the resistivity values of single crystals), a cell voltage of approximately 0.9 V (which generates a current density of 200 mA/cm²) can be obtained by 10-μm thick La_1-xSr_xF_3-x films with x = 0, 0.026, or 0.1 at only 300ºC. Thin Film Deposition Techniques

Table 3 compares three physical thin-film deposition techniques that might be used to fabricate thin films (e.g. 5 to 50 -μm (preferred 5 to 15 μm) thick of polycrystalline La_1-xSr_xF_3-x for the fuel-cell application.

In vacuum evaporation - the best established thin- film deposition process for LaF₃--the source compound is evaporated by heating with a thermal or electron-beam heater and deposited on the substrate. Areas are delineated either by a shadow mask or by photolithography. Electron beam evaporation is a particularly attractive method for depositing polycrystalline La_1-xSr_xF_3-x films for the fuel-cell application, because the film deposition rate can be as fast as 10 μm/h and highly nonstoichiometric, conductive films of LaF_3-x (for which strontium-doping might not be necessary) can be formed.

Magnetron sputtering is a process that is similar to (but faster than) diode sputtering and is primarily useful for films that are thicker than 5 μm. However, the film deposition rate of magnetron sputtering is still slower than vacuum evaporation methods.

In addition to the physical methods described above, chemical processes, such as chemical vapor deposition and screen printing, may be used to prepare thin films of polycrystalline La_1-xSr_xF_3-x films. Screen printing is widely used in electronic manufacturing (e.g. ceramic capacitors). Screen-printed deposits are thicker than sputtered and evaporated layers, usually in the range of 10 to 50 μm. The deposits are made from a paint-like suspension of particles and binders that, after application through a patterned screen, are dried and sintered to form a coherent (but often porous) mass. The resultant deposit can be similar to the pressed materials. Screen printing is particularly suited for volume production techniques, because manufacturing equipment is available and printing precision is relatively high. However, it is expected that this method is applicable to the deposition of polycrystalline LaF_3-x or La_1-xSr_xF_3-x films.

Plasma enhanced chemical vapor deposition (PECVD) uses an RF glow discharge to generate highly reactive species, and is attractive for a large-scale production, although PECVD has not been used to fabricate LaF_3-x or La_1-xSr_xF_3-x films.

In another aspect, the present invention relates to a process [BB] for preparing a composite comprising:

A_1-xB_xQO₃ having a perovskite or perovskite-type structure as an electrode catalyst in combination with:

A_1-xB_xZ as a discontinuous polycrystalline surface coating solid electrolyte wherein A is independently selected from lanthanum, cerium, neodymium, praseodymium, or scandium, B is independently selected from strontium, calcium, barium or magnesium, Q is independently selected from nickel, cobalt, iron or manganese, and x is between about 0 and

0.9999, Z is selected from the group consisting of F_3-x and

O_cF_d where F is fluorine, 0 is oxygen, x is between about

0 and 0.9999 and 2c+d = 3-x, wherein c is between 0.0001 and 1.5 and d is between 0.0001 and less than or equal to 3, which process comprises:

(a) obtaining a particulate of: A_1-xB_xQO₃ wherein A, B, Z and x are defined hereinabove, having an average crystal size distribution of between about 50 and

200 Angstroms in diameter and a surface area of between about 10 and 100 meters ²/grams and formed into a film-like or pellet-like shape having a general thickness of between about 1 and 5mm, a pore size of between about 25 and 200

Angstrom; and

(b) reacting the particulate of step (a) with a vapor comprising: A_1-xB_xZ wherein A, B, Z and x are defined hereinabove, at about ambient pressure at between about 0 and 1000ºC: for between about 10 and 30 hr. obtain the composite of between 25 to 1000 microns in thickness; and (c) recovering the composite of step (b) having multiple interfaces between:

A_1-xB_xQO₃ and A_1-xB_xZ said composite having a pore size of between about 25 and

200 Angstroms and a surface area of between about 10 and 100 meters ²/gram.

A preferred embodiment in this process [BB] is wherein

A is lanthanum, B is strontium, Q is cobalt, and especially where x is about 0.3. Another preferred embodiment of process [BB] is wherein A is selected from cerium or scandium, B is selected from strontium or magnesium, Q is selected from nickel, cobalt or manganese and x is between about 0.2 and 0.4.

The perovskites useful in this invention may be purchased or may be formed according to the procedures described in the literature, e.g., T. Kudo, et al., U.S.

Patent No. 3,804,674, which is incorporated herein by reference.

The following Examples are meant to be illustrative and descriptive only. They are not to be construed as being limiting in any way.

EXAMPLE 1 (a) Single Crystal Lanthanum Fluoride Solid

Electrolyte Fuel Cell LaF₃ single crystals (purity 99.99 percent; diameter; 10 mm) were purchased from Optovac, Incorporated, North Brookfield, Massachusetts 01535, and were sliced into disks 25 mil (0.64 mm) thick. The nominal ionic conductivity of the LaF₃ single crystals is about 10^-7 S/cm at room temperature. Platinum black that is made by a thermal decomposition of a Pt salt is used as an electrocatalyst for both oxygen cathode and hydrogen anode. A typical catalyst loading is about 25-30 mg/cm². The procedure for depositing Pt black catalyst onto the LaF₃ single-crystal disk is as follows: (1) Place a tiny drop (about 0.002-0.005 mL) of a concentrated (about 2M) H₂PtCl₆ aqueous solution on one side of a LaF₃ disk (previously cleaned with methanol), and using a metal rod, spread the solution into a circular spot with a diameter of about 4 or 5 mm.

(2) Place the above sample into an electric furnace. Increase the temperature of the furnace very slowly at a rate of about 4ºC/min so as not to break the LaF₃ disk by a thermal shock, and maintain the temperature of the furnace at 200ºC for about 20 min for the termal decomposition of the Pt salt in a gentle mixed-gas stream (flow rate: 30-50 mL/min) consisiting of 10 percent H₂ and 90 percent N₂.

(3) Cool the furnace extremely slowly at a rate of 2ºC/min. Then carefully remove the sample from the furnace.

(4) Repeat the above procedure several times until a desired catalyst loading is obtained; then, repeat the entire procedure for the other side of the LaF₃ disk.

(b) Test for Formation of HF or F₂

The exhausted gas from the anodic compartment of the H₂/O₂ fuel-cell of Part (a) based on a single crystal LaF₃ pellet under a short-circuit operating condition is introduced into a beaker containing 30 mL of a 5 percent CaCl₂ aqueous solution (about 1.4 × 10^-2 mol/30 mL or about 0.45 M). If HF, F₂, or both are produced at the anode, white colloids of CaF₂ precipitates will be formed according to the following reaction: CaCl₂ + 2F-(or F₂) CaF₂(s.) + 2Cl- (or Cl₂) (9)

Reaction (9) has a solubility constant K_sp of 1.6 × 10^-10 for CaF₂ (K_sp(CaF₂) = [Ca²⁺] [F-]²). Therefore, 30 mL of 5 percent CaCl₂ aqueous solution is sensitive enough to detect the presence of F- ions in a concentration greater than 1.8 × 10⁵ M or 5.5 × 10^-7 moles. The test was continued for 120 hours with an average I_sc of 20 μA, which corresponds to 8.6 Coulombs, and 9 × 10^-5 mols of F- ions should be produced if HF (or F₂) is produced at 100 percent efficiency. The solution remained clear after this prolonged test, indicating no evidence for the formation of HF or F₂.

EXAMPLE 2 Preparation of Polycrystalline La_g.94Sr_0.06F_2.94 50 g of LaCl₃·H₂O (Reacton-M; 99.99 percent, Alpha Products, Danvers, Massachusetts; Stock 500062) and 2.38 g of SrCl₂·6H₂O (Puratronic; 99.9965 percent Alpha Products, Danvers, Massachusetts; Stock 400267) are dissolved in 500 mL of deionized water with 1 mL of concentrated reagentgrade HCl on a magnetic εtirrer until free of solids. A solution of 80 mL of buffered oxide etch (prepared by KTI Chemicals of Sunnyvale, California, by mixing 8.01 g of 42 percent NH₄F with 1.31 g of 49 percent HF) in 400 mL deionized water is added as rapidly as possible with brisk stirring to encourage the maximum degree of coprecipitation. After about two minutes of vigorous stirring, the suspension is allowed to settle and a few drops of buffered oxide etch are added to check for complete precipitation. The material is washed three times by decantation and settling. Further washing results in peptization (i.e. formation of a colloidal suspension in the ion-free water), as indicated by a haze in the supernatant liquid.

The mixture is filtered through Whatman No. 1 filter paper with limited washing with deionized water to aid in the transfer. The solids and paper were dried overnight ot 120ºC or until visibly dry. The solid is removed from the filter paper and trasferred to a quartz boat and calcined in argon in a tube furnace at 950ºC overnight so as to drive off the residual H₂O, NH₄Cl, and NH₄F. The calcined material is ground to pass a 100-mesh screen. The particles are then all much less than 0.01 inch (250 μm) in diameter. The pressed and sintered pellets are prepared by hot pressing in a heated graphite die at 1100°C and 15,000 pounds for 15 minutes. The resultant 0.5 inch-diameter rod is sliced to 1-mm thick disks.

EXAMPLE 3 DEPTH PROFILE BY AUGER ELECTRON SPECTROSCOPY

Auger electron spectroscopy (AES) analysis was employed to obtain the depth profile of the polycrystalline LaF₃ pellet that was used in a long-term fuel-cell test. In high-energy Auger spectra, characteristic peaks are obtained for the elements of our concern, viz. oxygen, lanthanum, and fluorine at 503, 625, and 647 eV, respectively. Figures 17 A, B and C show the Auger depth profile of the used sample as well as of a virgin LaF₃ pellet for comparison. Unfortunately, it is not known which end is anode or cathode. The y axis corresponds to the concentrations of these elements on arbitrary scale. No substantial difference was observed in the depth profile of lanthanum. A major redistribution of elemental fluorine is seen in the used sample; however, no substantial net decrese of fluorine concentration is noted. A most encouraging finding is an apparent dramatic increase in the oxygen concentration in the used sample. The AES results strongly indicate that oxide ion (O^2-) are, indeed, generated at the cathode by the H₂/O₂ fuel-cell operation and transported to the anode, where they are consumed by a reaction with hydrogen with little production of such side products as HF and F₂.

EXAMPLE 4 STAINLESS STEEL POROUS SUBSTRATES Porous stainless-steel materials are most preferred as the substrates on which thin films of La_1-xSr_xF_3-x can be deposited for the following reasons:

* Thermal coefficient of expansion of stainless steel (#316: 16×10^-6/ºC; #304: 17.3 × 10^-6/ºC) is close to that of LaF₃ materials (about 17.2 × 10^-6/ºC).

* Stainless steel is relatively inert.

* A porous stainless steel serves not only as a substrate but also as a current collector.

Porous stainless steel substrates are purchased from Pall Porous Metals Filter Corporation (PALL), East Hills, New York 11548, and from Sintered Specialities, Incorporated (SSI), Janesville, Wisconsin 53547. Table 4 summarizes their physical properties. These porous stainless steel materials are originally designed as filters for fluid clarification in high temperature, high pressure, and corrosive environments.

The Pall materials are rougher and have higher porosity; thus, they are attractive for our fuel-cell application because they potentially can provide a large number of triple-interface reaction sites. However, the deposition of LaF₃ films on the PALL materials is not easy because of their wide open structures. Indeed, the PALL

P09 (nominal pore size 2 μm) was found to be too coarse to use. So far, the PALL material with nominal pore size of

0.5 μm (see Figure 18A) has been identified as the best substrate for experiments. One difficulty associated with this material is, however, that although the manufacturer states (nominal) pore size to be 0.5 μm, the actual size of individual pores varies from 0.2 μm to as high as 40 μm, which makes the deposition of LaF₃ films difficult. The SSI materials are substantially flatter and have pores much closer to the state 2 and 3 μm, with a concomitant lowering in the porosity. The deposition of LaF₃ films should be easier with the SSI materials; however, their porosity is too low to provide enough triple interface reaction sites. EXAMPLE 5

Preparation Method of Platinum-Based Hydrogen Oxidation Electrocatalvst on a Porous Stainless Steel Substrate The deposition of a hydrogen electrocatalyεt is one of the key steps for the successful fabrication of the thin- film La_1-xB_xF_3-x solid electrolyte fuel-cell. The electrocatalyst is deposited on the porous stainless-steel substrate in such a way that the resulted coating provides not only an ideal triple-interface but also a "smooth" surface necessary for the deposition of LaF₃ layer. In the first set of experiments, PALL PO5 (0.5 μm nominal pore size) as the substrate and platinum as the hydrogen oxidation electrode material are examined:

Method 1: Thermal Decomposition of a Platinum Salt

(a) Drop concentrated hydrous hexaplatinic acid solution (1M) on a substrate.

(b) Dry it in a furnace at 450°C for about 1 hr in H₂/Ar mixture gas.

Method 2: Physical Deposition of Platinum Black Power Powder. followed by Thermal Decomposition of a Platinum Salt

(a) Mix platinum black powder into xylene (some of the platinum black dissolves into the solvent while most of the platinum black remains as powder at the bottom of the container). (b) Put stainless steel into the solution and pick up the bottom solution by a squeezer so that this solution contains much Pt black powder.

(c) Put this solution on top of the stainless steel under the agitation of an ultrasonic bath. Platinum powder will spread out on the whole surface of porous stainless steel which partly encloses the cavities.

(d) Pick up the substrate and dry it until the xylene evaporates.

(e) Drop H₂PtCl₆ solution on the substrate and dry it in a furnace as described in Method 1.

Method 3 Electrochemical Deposition of Platinum

In An Alkaline Solution

(a) Make up the solution of the following composition: platinum as H₂PtCl₆ 10 g/L ammonium phosphate 60 g/L ammonium hydroxide to pH 7.5- 9

(b) Deposit platinum by applying a constant potential of -550 to about -700 mV versus SCE at about 70°C under the stirring condition for 20-30 minutes to several hours, depending upon a desired catalyst loading.

Method 1 produces a very rough surface with cracked PtO_x layers, which is not favorable for the LaF₃ deposition. It is thought that the application of platinum black powder onto the substrate would result in the pores that are partly filled with" the platinum black, and the successive Pt deposition by the thermal decomposition method would completely fill the pores with Pt (Method 2). The resultant surface is much smoother than the one made by Method 1, however, there are still some unfilled, big cavities, and the deposited Pt is very flaky. Therefore, the surface made by Method 2 is not ideal either for the deposition of LaF₃. Because the first two methods did not turn out to be effective for our purpose, an electroplating method (Method 3), i.e. a constant potential method, was introduced for the deposition of Pt catalyst layers. Figure 18B shows the surface morphology of the platinum layers formed at about -670 mV versus SCE for 2.5 hours. The surface morphology of the electroplated platinum depends strongly upon the applied potential; a platinum "black" film is obtained when the applied potential is in the range of about -600 mV to about -700 mV versus SCE, while the potential of about -500 mV to about -600 mV versus SCE produces a more metallic- looking Pt film. The cut-off potential appears to be related to the competing hydrogen evolution reaction which initiates around -600 mV. In the case of metallic Pt, the pores appear to be totally clogged with Pt and few gas molecules can go through. Therefore, PALL PO5 porous stainless steel (0.5 μm nominal pore size) substrates that are electrochemically plated with Pt catalyst layer at about -670 mV for 2.5 hours are found to be the most desirable for the LaF₃ depositions. The estimated Pt catalyst loading is in the range of 20-30 mg/cm². The surface consists of small clusters of platinum and exhibits more compact, "smooth" morphology, compared to the surfaces made by other Methods 1 and 2. EXAMPLE 6

Preparation of Perovskite Powder La_1-xSr_xCoO₃ by

Freeze-Drving Method

(a) Four aqueous solutions of La_1-xSr_xCoO₃ with x = 0.1, 0.2, 0.4 and 0.94 are made using acetates of lanthanum, strontium and cobalt. Each solution is diluted using distilled water to 0.13 molality in cobalt.

(b) The solutions are then ultrasonically sprayed into stainless steel pans containing liquid nitrogen. The pans of frozen droplets were then placed into the freeze- dryer.

(c) After the liquid nitrogen evaporates, the vacuum is switched on and the dryer program is engaged.

(d) After the droplets are dried for 3 days, they are removed from the dryer and placed in Al₂O₃ crucibles for calcining.

(e) Calcining is done at 600°C for 10 hours and then at 800ºC for 4 hours in flowing oxygen.

(f) Samples are removed from crucibles and placed directly into vials without any attempts to break up any agglomerates formed.

The perovskite powder is first mixed with a binder material-water glass (about 10 weight percent) made of sodium meta silicate. The slurry is coated onto the lanthanum fluoride film followed by a sintering treatment in air of 450ºC to 500ºC for 1 hour. The perovskite forms a physical combination with the electrolyte on the support. EXAMPLE 7

Deposition of Thin-Films of La_1-xSr_xF_3-x on Porous Substrates by Thermal Evaporation

Figures 19 and 20 illustrate the vacuum deposition station 19 used to deposit a thin film of La_1-xSr_xF_3-x on a porous stainless steel substrate ("sample"). The samples are placed into the sample holder 51, which holds up to four samples. The vacuum system is prepared for the deposition by replacing the thickness monitor crystal 58 and by filling the evaporation boats 53 with source material 54. The thickness monitor 58 calculates the thickness by measuring the amount of material evaporated onto the crystal and calculates the thickness from the density. If microcracks occur on the crystal, it ceases to function; and having a finite lifetime, it must be changed before each series of depositions. The tantalum evaporation boats 53 are filled with source material 54.

The source material is either optical grade 99.999% crystalline LaF₃, 99.999% crystalline SrF₂, or a mixture of 99.999% LaF₃ powder and 99.994% SrF₂. Two evaporation source boats 53 are used to maximize the amount of material that can be deposited during one pump-down cycle of the vacuum chamber 55. The samples are placed in the chamber with the surface for the deposition perpendicular to the gas stream from the evaporation. In what follows, a typical deposition procedure is given:

(a) The chamber 55 is first flooded with N₂ for several minutes to remove O₂ and water vapor from the chamber.

(b) The pump 56 (turbo) and backing pump 57 are switched on and the chamber 55 is pumped down to 10^-7 torr. Before deposition, the source material needs to be outgassed for approximately 1 hour with a current of 40 amps through the boat.

(c) Turn on Inficon Xtal monitor that measures deposition rate and start water flow to cool the monitor crystal. Normally, the substrate temperature is around 175ºC without water cooling. Increase the current through the boat to approximately 75A until the monitor reads the desired deposition rate, i.e. 3-5 A/s, which depends on resistances due to the boat geometry, source material, and pressure. At this rate, deposition of about 10 μm film takes approximately 5 hours.

(d) Open shutter to expose substrates to gas stream and monitor the deposition parameters, i.e. time, rate, thickness, and pressure. Adjust current to keep constant deposition parameters, as needed.

(e) Repeat outgas and deposition (i.e. steps a through d) with second boat, if a thicker film is desired.

(f) Allow samples to cool. Remove and characterize. Additional features of Figures 19 and 20 include the apparatus support 59. The thickness monitor crystal 58, which is connected to wire 60 which exits vaccum chamber 61 and is referred to as the thickness monitor outlet. The tube support 62, shutter 63 and shield 64 are seen in both Figures 19 and 20.

Figure 21 shows a typical example of the deposited LaF₃ films with or without platinum catalyst layer. A LaF₃ film was directly deposited on an SSI S-2930 porous stainless steel substrate. It can be seen that crystallites of LaF₃ grow almost perpendicular to the substrate plane, i.e. the direction to the evaporation source. The deposited LaF₃ film, unfortunately, exactly reflects the surface "roughness" of the substrate; viz. the film consists of many small islands surrounded with cracks, which may lower the energy density of the fuel cell through the possible cross-talk of gases.

While some embodiments of the invention have been shown and described herein, it will become apparent to those skilled in the art that various modifications and changes can be made in the present invention regarding solid materials for use as electrodes solid electrolytes in fuel cell applications, without departing from its spirit and scope. All such modifications and changes coming within the scope of the appended claims are intended to be covered thereby.

Claims

WE CLAIM :

1. A solid O^2- (oxide ion) conducting material for use as an electrolyte for a fuel-cell, comprising: a monocrystal or polycrystal structure of the formula: A_1-xB_xZ (AA) wherein

Z is selected from the group consisting of F_3-x and O_cF_d where F is fluorine, 0 is oxygen, x is between about 0 and 0.9999 and 2c+d = 3-x, wherein c is between 0.0001 and 1.5 and d is between 0.0001 and less than or equal to 3, with the proviso when A is lanthanum, Z is F_3-x and x is 0, the solid material is only a monocrystal.

2. The solid material of Claim 1 wherein A is lanthanum.

3. The solid material of Claim 2 wherein B is strontium.

4. The solid material of Claim 3 wherein Z is F_3-x.

5. The solid material of Claim 3 wherein Z is O_cF_d and where the oxygen is an integral part of the crystal lattice.

6. The solid material of Claim 4 wherein A is lanthanum, Z is F_3-x, and x is 0, and the solid material is a monocrystal.

7. The solid material of Claim 1 wherein the solid material as a monocrystal has a thickness between about 1 and 300 micrometers.

8. The solid material of Claim 7 wherein the solid material as a polycrystal has a thickness between about 1 and 100 micrometers.

9. The use of the solid material of Claim 1 as a fuel cell to generate an electrical current at a temperature of between about 20 and 300°C.

10. The use of the solid material of Claim 8 as a fuel cell to generate an electrical current at a temperature of between about 20 and 300°C.

11. A solid electrolyte fuel cell comprising a structure:

C - E - A - S wherein a first electrode material (C), which is only in contact with a thin film solid electrolyte (E) which is also separately in contact with a second electrode material (A) which is also separately in contact with a porous mechanical support material (s). wherein the thin film solid electrolyte has the structure:

A_1-xB_xZ wherein A is independently selected from lanthanum, cerium, neodymium, praseodymium, scandium or mixtures thereof;

12. The solid electrolyte fuel cell of Claim 11 wherein the first electrode material is in contact with an oxidizing gas and the second electrode material is in contact with a reducing gas.

13. The solid electrolyte fuel cell of Claim 11 wherein the first electrode material is in contact with a reducing gas and the second electrode material is in contact with an oxidizing gas.

14. The solid electrolyte fuel cell of Claim 11 wherein the porous support is colloidal alumina.

15. The solid electrolyte fuel cell of Claim 11 wherein the thin film solid electrolyte is between about 1 and 300 micrometers.

16. The solid electrolyte fuel cell of Claim 15 wherein in the thin film solid electrolyte B is strontium.

17. The solid electrolyte fuel cell of Claim 16 wherein in the thin film solid electrolyte A is lanthanum.

18. The solid electrolyte fuel cell of Claim 17 wherein x is between about 0.001 and 0.2.

19. The solid electrolyte fuel cell of Claim 18 wherein x is about 0.1.

20. The solid electrolyte fuel cell of Claim 19 wherein the thin film has a thickness of about 10 micrometers.

21. The use of the solid material of Claim 1 an electrolyte for a fuel cell at a temperature of between about 200 and 500ºC.

22. The use of the solid electrolyte fuel cell of Claim 11 at a temperature of between about 300 to 500ºC.

23. The solid electrolyte fuel cell of Claim 11 wherein the second electrode material is in contact with a porous metallic mechanical support which also functions as a current collector.

24. The solid electrolyte to fuel cell of Claim 23 wherein the porous metallic support is selected from stainless steel or nickel.

25. The solid electrolyte fuel cell of Claim 11 wherein either first or second electrode material comprises

A_1-xB_xQO₃ having a perovskite or a perovskite-type structure as an electrode catalyst in combination with

A_1-xB_xZ as a polycrystalline solid electrolyte wherein

A is independently selected from lanthanum, cerium, neodymium, praseodymium or scandium, B is independently selected from strontium, calcium, barium, or magnesium,

Q is independently selected from nickel, cobalt, iron or manganese and x is between about 0 and 0.9999,

Z is selected from the group consisting of F_3-x and O_cF_d where F is fluorine, 0 is oxygen, x is between about 0 and 0.9999 and 2c+d = 3-x, wherein c is between 0.0001 and 1.5 and d is between 0.0001 and less than or equal to 3.

26. The solid electrolyte fuel cell of Claim 25 wherein A is lanthanum, B is strontium, Q is cobalt, Z is F_3-x and x is greater than 0 and less than 0.5.

27. The solid electrolyte fuel cell of Claim 11 wherein the cathode material is A_1-xB_xQO₃ : wherein 0 is oxygen, A is independently selected from lanthanum, cerium, neodymium, praseodymium, scandium or mixtures thereof;

B is independently selected from calcium, barium or magnesium;

Q is selected from manganese, iron, cobalt or nickel, and x is between about 0 and 0.8.

28. The solid electrolyte fuel cell of Claim 11 wherein A in the porous mechanical support material (S) is selected from electrically conducting metallic material or non-electrically conducting material.

29. The solid electrolyte of Claim 28 wherein S has a pore size of between about 0.05 - 5μm, a porosity between about 40-80% and a thickness of between about 200 micrometers and 5 millimeters.

30. A solid material for use as an electrolyte for a fuel cell comprising: a monocrystal or polycrystal structure of the formula: wherein Pb_eSn_fF_g

Pb is lead,

Sn is tin, with the proviso that f is 1, e is 1 and g is 4 , and when e is 1, f is 0, and g is 2.

31. The solid material of Claim 30 wherein Pb_eSn_fF_g is PbSn₄.

32. The solid material of Claim 30 wherein Pb_eSn_fF_g is PbF₂.