WO1989005832A3 - Polymere de condensation contenant le residu d'un compose de benzodioxylmethine et articles façonnes avec ce polymere - Google Patents

Polymere de condensation contenant le residu d'un compose de benzodioxylmethine et articles façonnes avec ce polymere Download PDF

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Publication number
WO1989005832A3
WO1989005832A3 PCT/US1988/004554 US8804554W WO8905832A3 WO 1989005832 A3 WO1989005832 A3 WO 1989005832A3 US 8804554 W US8804554 W US 8804554W WO 8905832 A3 WO8905832 A3 WO 8905832A3
Authority
WO
WIPO (PCT)
Prior art keywords
polymer
benzodioxylmethine
residue
unsubstituted
substituted
Prior art date
Application number
PCT/US1988/004554
Other languages
English (en)
Other versions
WO1989005832A2 (fr
Inventor
Max Allen Weaver
Wayne Payton Pruett
Samuel David Hilbert
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Priority to JP89500918A priority Critical patent/JPH03501745A/ja
Publication of WO1989005832A2 publication Critical patent/WO1989005832A2/fr
Publication of WO1989005832A3 publication Critical patent/WO1989005832A3/fr
Priority to KR1019890701556A priority patent/KR900700522A/ko

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/685Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen
    • C08G63/6854Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6858Polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C08G63/54Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/04Aromatic polycarbonates
    • C08G64/045Aromatic polycarbonates containing aliphatic unsaturation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Une composition utile pour le moulage d'articles tels que récipients de produits alimentaires, bouteilles de boissons, plastiques structurels durcis et similaires comprend du polyester ou du polycarbonate linéaire ou insaturé propre au moulage entré en réaction avec le résidu d'un ou plusieurs composés de benzodioxylméthine ayant la formule (I) ou contenant un copolymère de ce résidu. Dans la formule, R1 est cyano, carboxyle, alkényloxycarbonyle ou un radical alkoxycarbonyle, cycloalkoxycarbonyle ou aryloxycarbonyle substitué ou non, R2 est un des groupes décrits dans le cas de R1 ou un radical aryle, carbamoyle, alkanoyle, cycloalkanoyle, aroyle, alkylsulfonyle, cycloalkylsulfonyle, arylsulfonyle ou aryle hétérocyclique substitué ou non; R3 est hydrogène ou un radical alkyle, cycloalkyle ou aryle substitué ou non; R4 est hydrogène, alkyle, alkoxyle ou halogène; n est égal à 1 ou 2; et X est un radical méthylène ou éthylène substitué ou non; à condition que le composé de benzodioxolylméthine porte au moins un substituant susceptible de réagir avec un ou plusieurs monomères à partir desquels le polymère de condensation est dérivé. Le résidu de benzodioxylméthine absorbe des rayonnements compris entre 250 nm et 390 nm, ne peut pas être extrait dudit polymère et reste stable dans des conditions de traitement du polymère. Les résidus benzodioxylméthine présents dans le polymère forment une partie intégrante de la chaîne polymère et absorbent des rayonnements ultra-violets dans une plage comprise entre 250 et 390 nm environ. Ces résidus ne peuvent pas être extraits du polymère et restent stables dans les conditions de préparation et de traitement des polymères.
PCT/US1988/004554 1987-12-21 1988-12-20 Polymere de condensation contenant le residu d'un compose de benzodioxylmethine et articles façonnes avec ce polymere WO1989005832A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP89500918A JPH03501745A (ja) 1987-12-21 1988-12-20 ベンゾジオキシルメチン化合物残基を含有する縮合ポリマー及びそれから製造される造形品
KR1019890701556A KR900700522A (ko) 1987-12-21 1989-08-21 벤조디옥실메틴 화합물의 잔사를 함유하는 축합 중합체 및 이것으로 만든 성형제품

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/135,425 US4791188A (en) 1987-12-21 1987-12-21 Condensation polymer containing the residue of a benzodioxylmethine compound and shaped articles produced therefrom
US135,425 1987-12-21

Publications (2)

Publication Number Publication Date
WO1989005832A2 WO1989005832A2 (fr) 1989-06-29
WO1989005832A3 true WO1989005832A3 (fr) 1989-07-27

Family

ID=22468051

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1988/004554 WO1989005832A2 (fr) 1987-12-21 1988-12-20 Polymere de condensation contenant le residu d'un compose de benzodioxylmethine et articles façonnes avec ce polymere

Country Status (8)

Country Link
US (1) US4791188A (fr)
EP (2) EP0322187A3 (fr)
JP (1) JPH03501745A (fr)
KR (1) KR900700522A (fr)
CN (1) CN1036218A (fr)
AU (1) AU2906989A (fr)
TR (1) TR23986A (fr)
WO (1) WO1989005832A2 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4845188A (en) * 1988-08-19 1989-07-04 Eastman Kodak Company Condensation polymers containing methine ultraviolet radiation-absorbing residues and shaped articles produced therefrom
US5030708A (en) * 1990-12-17 1991-07-09 Eastman Kodak Company Colored polyester compositions
US5459224A (en) * 1994-07-18 1995-10-17 Eastman Chemical Company Copolyesters having improved weatherability

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4551420A (en) * 1982-10-12 1985-11-05 Fuji Photo Film Co., Ltd. Silver halide photographic light-sensitive material
WO1986004903A1 (fr) * 1985-02-15 1986-08-28 Eastman Kodak Company Compositions de polymeres de condensation absorbant les rayons uv; produits de ces compositions
US4645735A (en) * 1982-08-05 1987-02-24 Fuji Photo Film Co., Ltd. Silver halide photographic light-sensitive material containing ultraviolet ray absorbing polymer latex

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4340718A (en) * 1980-06-02 1982-07-20 Eastman Kodak Company Stabilized copolyester material
US4338247A (en) * 1980-06-02 1982-07-06 Eastman Kodak Company Polyester compositions having improved resistance to radiation deterioration
US4305719A (en) * 1980-06-25 1981-12-15 Eastman Kodak Company Stable dyed polyester material
US4617373A (en) * 1985-02-15 1986-10-14 Eastman Kodak Company Condensation polymers and products therefrom
US4661566A (en) * 1986-02-06 1987-04-28 Eastman Kodak Company UV-absorbing condensation polymeric composition
US4707537A (en) * 1986-09-30 1987-11-17 Eastman Kodak Company UV-absorbing condensation polymeric compositions and products therefrom
US4749774A (en) * 1986-12-29 1988-06-07 Eastman Kodak Company Condensation polymer containing the residue of a poly-methine compound and shaped articles produced therefrom
US4749772A (en) * 1987-07-20 1988-06-07 Eastman Kodak Company Condensation copolymers containing methine ultraviolet radiation-absorbing residues and shaped articles produced therefrom
US4749773A (en) * 1987-07-27 1988-06-07 Eastman Kodak Company Condensation polymers containing methine ultraviolet radiation-absorbing residues and shaped articles produced therefrom

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4645735A (en) * 1982-08-05 1987-02-24 Fuji Photo Film Co., Ltd. Silver halide photographic light-sensitive material containing ultraviolet ray absorbing polymer latex
US4551420A (en) * 1982-10-12 1985-11-05 Fuji Photo Film Co., Ltd. Silver halide photographic light-sensitive material
WO1986004903A1 (fr) * 1985-02-15 1986-08-28 Eastman Kodak Company Compositions de polymeres de condensation absorbant les rayons uv; produits de ces compositions

Also Published As

Publication number Publication date
KR900700522A (ko) 1990-08-16
US4791188A (en) 1988-12-13
AU2906989A (en) 1989-07-19
CN1036218A (zh) 1989-10-11
TR23986A (tr) 1991-01-14
EP0322187A2 (fr) 1989-06-28
JPH03501745A (ja) 1991-04-18
EP0322187A3 (fr) 1989-08-09
WO1989005832A2 (fr) 1989-06-29
EP0393131A1 (fr) 1990-10-24

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