WO1988002737A1 - Procede de production de l'ammoniac - Google Patents
Procede de production de l'ammoniac Download PDFInfo
- Publication number
- WO1988002737A1 WO1988002737A1 PCT/SU1987/000106 SU8700106W WO8802737A1 WO 1988002737 A1 WO1988002737 A1 WO 1988002737A1 SU 8700106 W SU8700106 W SU 8700106W WO 8802737 A1 WO8802737 A1 WO 8802737A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mixture
- ammonia
- κaτalizaτορa
- catalyst
- ammiaκa
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/04—Preparation of ammonia by synthesis
- C01C1/0405—Preparation of ammonia by synthesis from N2 and H2 in presence of a catalyst
- C01C1/0411—Preparation of ammonia by synthesis from N2 and H2 in presence of a catalyst characterised by the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/04—Preparation of ammonia by synthesis
- C01C1/0405—Preparation of ammonia by synthesis from N2 and H2 in presence of a catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Definitions
- the inventive invention is related to chemical technology, and more specifically, to the production of ammonia
- 10 ammonia has an elevated pressure of 10-35 PSa and a temperature of up to 600 ° C from nitrogen and hydrogen at the following reaction:
- a ' disadvantageous disadvantage is the reduction of the mode of the accelerated mode.
- ⁇ process ⁇ '. ge ⁇ e ⁇ ichee ⁇ i ⁇ sh-imaln ⁇ mu - ch ⁇ ⁇ iv ⁇ di ⁇ ⁇ ned ⁇ s ⁇ a ⁇ chn ⁇ vys ⁇ im s ⁇ e ⁇ enyam / ⁇ 16% ⁇ bema / ⁇ ev ⁇ ascheniya is ⁇ dn ⁇ y
- the catalyst is preliminarily heated for a reaction corresponding to a reaction temperature of 120-5 0 ° C.-.
- the basic present invention has been set up to enable the operation of the transmitter to the process to be dispensed with.
- the processes for the production of ammonia are carried out, using as a source of the raw gas product, the gaseous mixture is used for the production of gas, the
- catalyses they have the appearance of a granular or subsidiary site.
- the size of the fractions is 1-3 mm, 3-5 mm, 5-7 ' mm, 7-10 mm, 10-15 mm.
- the inventive method was implemented by using a catalyst that uses the indicated sizes of fractions, dimensions and sizes of 15-50 mm. Due to the use of the catalysts of the indicated fractions, the intensity of the process is reduced between the filtered sources. a day ago
- the catalyst needs to significantly increase the quantity of catalytic converter, there is to be a reduction in the volume of exhaust gas.
- the process of the synthesis of ammonia is in the case of catalysis, a section of which is by a little less than two parts, a little more than a half of it.
- the synthesis process is carried out in the case of a galvanizing unit, and it is pre-heated to a temperature of 20-590 ° ⁇ .
- the named system with a blood pressure of 20 to 250 ° C is used.
- the operational changes to the effective direction of the payment in the case of the commercialization of the aforementioned nitrogen.
- Pe ⁇ i ⁇ d ⁇ a ⁇ - g ⁇ Changes are s ⁇ s ⁇ avlyae ⁇ , ⁇ a ⁇ ⁇ avil ⁇ '1-30 minutes the.
- Equalization of the hemorrhagic non-uniform one-sys- tem by means of intercalation is associated with pressure reduction.
- the catalytic liquid emanating from the first part of the catalyst has a high hemisphere, which differs in cross section, because of the low gas consumption.
- the conditioned non-uniformity of the catalyst layer - 8 - za ⁇ a, b ⁇ lshe than ⁇ emya between changes na ⁇ av ⁇ e Nia ⁇ dachi is ⁇ dn ⁇ y az ⁇ d ⁇ dn ⁇ y smeei, ⁇ edlagaem ⁇ e ⁇ e ⁇ e- mixing of e ⁇ y az ⁇ v ⁇ d ⁇ dn ⁇ y mixture ⁇ iv ⁇ di ⁇ ⁇ -zy ⁇ avni- vaniyu ⁇ em ⁇ e ⁇ a ⁇ u ⁇ y in lyub ⁇ m sectional sl ⁇ ya ⁇ a ⁇ aliza ⁇ a 5 ⁇ e ⁇ endi ⁇ ulya ⁇ n ⁇ m ⁇ u is ⁇ dn ⁇ g ⁇ gas and haem thus ⁇ zv ⁇ lyae ⁇
- the optimal mode is the whole process of ammonia blasting.
- Variation of the flow direction of the feed of the aqueous mixture in the catalyst layer is, in fact, said: from the beginning
- ⁇ dna ⁇ pressure is ⁇ dn ⁇ y az ⁇ v ⁇ d ⁇ dn ⁇ y mixture ⁇ Pa 10, ⁇ em ⁇ e ⁇ a ⁇ u ⁇ a az ⁇ v ⁇ d ⁇ dn ⁇ y mixture on v ⁇ de in sl ⁇ y ⁇ a ⁇ alizag ⁇ ra ⁇ 00 ⁇ C .
- the average output of ammonia is $ 10; the average ammonia output is $ 8.
- the combination of the ammonia is subject to the conditions similar to that shown in Example 2.
- the same size is measured at 50 mm.
- the average output of amshaka is $ 16, and ammonia is 5 $ 14 $.
- ammonia occurs under conditions similar to those indicated in Example I. However, the 15 catalytic converter is divided into two parts with a separation of a little more than 0.6. Medium: ammonia output 15.9, ammonia output $ 13.9. _Note ⁇ 10
- the synthesis of agglomerate is subject to conditions similar to the 20 indicated in Example I.
- the one-layer catalytic converter is divided into two parts with a difference in parts! catalytic layer 0.71.
- the synthesis of ammonia is in the CONDITIONS ⁇ , similar to those indicated in Example I. However, the catalytic conversion is divided into two parts with a separation of at least 1. The average ammonia output is $ 35.16.1, pripyst 14.1. EXAMPLE 13 The synthesis of ammonia is carried out under conditions similar - II - ny ⁇ u ⁇ azannym in ⁇ ime ⁇ e I.
- ammonia The synthesis of ammonia is subject to conditions similar to those indicated in Example I.
- the same and basic mixture is contained in bulk: nitrogen - 20; ⁇ Play ⁇ Play- 60; Southern gases - 15; ammonia - 5.
- the change in the direction of delivery of the original mixture to the positive is effective after every 2 minutes.
- the average output of ammonia is 16.6, the amount of ammonia is $ 11.6.
- the intended use of 15 ummiak is used for the use of nitric acid, nitric acid, urea, and salt. Hydrate of the United Nations, hydrocyanic acid, fertilizers, diazo-typed light materials.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HU875776A HUT46594A (en) | 1986-10-17 | 1987-09-23 | Process for producing ammonia |
| GB8811619A GB2205561B (en) | 1986-10-17 | 1987-09-23 | Process for producing ammonia. |
| DK327888A DK327888D0 (da) | 1986-10-17 | 1988-06-15 | Fremgangsmaade til fremstilling af ammoniak |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU864131458A SU1696387A1 (ru) | 1986-10-17 | 1986-10-17 | Способ синтеза аммиака |
| SU4131458/23 | 1986-10-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1988002737A1 true WO1988002737A1 (fr) | 1988-04-21 |
Family
ID=21261751
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/SU1987/000106 Ceased WO1988002737A1 (fr) | 1986-10-17 | 1987-09-23 | Procede de production de l'ammoniac |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPH01501141A (https=) |
| DE (1) | DE3790631T1 (https=) |
| FR (1) | FR2605305B1 (https=) |
| GB (1) | GB2205561B (https=) |
| HU (1) | HUT46594A (https=) |
| PL (1) | PL268264A1 (https=) |
| SU (1) | SU1696387A1 (https=) |
| WO (1) | WO1988002737A1 (https=) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK173917B1 (da) * | 1998-07-02 | 2002-02-18 | Topsoe Haldor As | Fremgangsmåde til fremstilling af ammoniak |
| DK173814B1 (da) * | 1999-03-15 | 2001-11-12 | Topsoe Haldor As | Fremgangsmåde til fremstilling af ammoniak og katalysator til syntese af ammoniak |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4423022A (en) * | 1979-05-22 | 1983-12-27 | The Lummus Company | Processes for carrying out catalytic exothermic and endothermic high-pressure gas reactions |
| US4510123A (en) * | 1982-11-26 | 1985-04-09 | C F Braun & Co. | Temperature controlled ammonia synthesis process |
-
1986
- 1986-10-17 SU SU864131458A patent/SU1696387A1/ru active
-
1987
- 1987-09-23 GB GB8811619A patent/GB2205561B/en not_active Expired - Lifetime
- 1987-09-23 HU HU875776A patent/HUT46594A/hu unknown
- 1987-09-23 DE DE19873790631 patent/DE3790631T1/de not_active Withdrawn
- 1987-09-23 JP JP62506696A patent/JPH01501141A/ja active Pending
- 1987-09-23 WO PCT/SU1987/000106 patent/WO1988002737A1/ru not_active Ceased
- 1987-10-16 PL PL1987268264A patent/PL268264A1/xx unknown
- 1987-10-16 FR FR878714279A patent/FR2605305B1/fr not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4423022A (en) * | 1979-05-22 | 1983-12-27 | The Lummus Company | Processes for carrying out catalytic exothermic and endothermic high-pressure gas reactions |
| US4510123A (en) * | 1982-11-26 | 1985-04-09 | C F Braun & Co. | Temperature controlled ammonia synthesis process |
Non-Patent Citations (1)
| Title |
|---|
| A.G. KASATKIN, "Osuovnye Protsessy I Apparaty Khimicheskoi Tekhnologii", 1973, Khimia Moscow, page 246. * |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2605305B1 (fr) | 1990-07-20 |
| GB8811619D0 (en) | 1988-07-13 |
| FR2605305A1 (fr) | 1988-04-22 |
| GB2205561A (en) | 1988-12-14 |
| SU1696387A1 (ru) | 1991-12-07 |
| JPH01501141A (ja) | 1989-04-20 |
| GB2205561B (en) | 1990-12-19 |
| PL268264A1 (en) | 1988-08-18 |
| HUT46594A (en) | 1988-11-28 |
| DE3790631T1 (https=) | 1988-10-06 |
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