WO1988002737A1 - Procede de production de l'ammoniac - Google Patents

Procede de production de l'ammoniac Download PDF

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Publication number
WO1988002737A1
WO1988002737A1 PCT/SU1987/000106 SU8700106W WO8802737A1 WO 1988002737 A1 WO1988002737 A1 WO 1988002737A1 SU 8700106 W SU8700106 W SU 8700106W WO 8802737 A1 WO8802737 A1 WO 8802737A1
Authority
WO
WIPO (PCT)
Prior art keywords
mixture
ammonia
κaτalizaτορa
catalyst
ammiaκa
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/SU1987/000106
Other languages
English (en)
French (fr)
Russian (ru)
Inventor
Jury Shaevich Matros
Alexandr Petrovich Gerasev
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boreskov Institute of Catalysis Siberian Branch of Russian Academy of Sciences
Original Assignee
Boreskov Institute of Catalysis Siberian Branch of Russian Academy of Sciences
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boreskov Institute of Catalysis Siberian Branch of Russian Academy of Sciences filed Critical Boreskov Institute of Catalysis Siberian Branch of Russian Academy of Sciences
Priority to HU875776A priority Critical patent/HUT46594A/hu
Priority to GB8811619A priority patent/GB2205561B/en
Publication of WO1988002737A1 publication Critical patent/WO1988002737A1/ru
Priority to DK327888A priority patent/DK327888D0/da
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01CAMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00Ammonia; Compounds thereof
    • C01C1/02Preparation, purification or separation of ammonia
    • C01C1/04Preparation of ammonia by synthesis
    • C01C1/0405Preparation of ammonia by synthesis from N2 and H2 in presence of a catalyst
    • C01C1/0411Preparation of ammonia by synthesis from N2 and H2 in presence of a catalyst characterised by the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01CAMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00Ammonia; Compounds thereof
    • C01C1/02Preparation, purification or separation of ammonia
    • C01C1/04Preparation of ammonia by synthesis
    • C01C1/0405Preparation of ammonia by synthesis from N2 and H2 in presence of a catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Definitions

  • the inventive invention is related to chemical technology, and more specifically, to the production of ammonia
  • 10 ammonia has an elevated pressure of 10-35 PSa and a temperature of up to 600 ° C from nitrogen and hydrogen at the following reaction:
  • a ' disadvantageous disadvantage is the reduction of the mode of the accelerated mode.
  • ⁇ process ⁇ '. ge ⁇ e ⁇ ichee ⁇ i ⁇ sh-imaln ⁇ mu - ch ⁇ ⁇ iv ⁇ di ⁇ ⁇ ned ⁇ s ⁇ a ⁇ chn ⁇ vys ⁇ im s ⁇ e ⁇ enyam / ⁇ 16% ⁇ bema / ⁇ ev ⁇ ascheniya is ⁇ dn ⁇ y
  • the catalyst is preliminarily heated for a reaction corresponding to a reaction temperature of 120-5 0 ° C.-.
  • the basic present invention has been set up to enable the operation of the transmitter to the process to be dispensed with.
  • the processes for the production of ammonia are carried out, using as a source of the raw gas product, the gaseous mixture is used for the production of gas, the
  • catalyses they have the appearance of a granular or subsidiary site.
  • the size of the fractions is 1-3 mm, 3-5 mm, 5-7 ' mm, 7-10 mm, 10-15 mm.
  • the inventive method was implemented by using a catalyst that uses the indicated sizes of fractions, dimensions and sizes of 15-50 mm. Due to the use of the catalysts of the indicated fractions, the intensity of the process is reduced between the filtered sources. a day ago
  • the catalyst needs to significantly increase the quantity of catalytic converter, there is to be a reduction in the volume of exhaust gas.
  • the process of the synthesis of ammonia is in the case of catalysis, a section of which is by a little less than two parts, a little more than a half of it.
  • the synthesis process is carried out in the case of a galvanizing unit, and it is pre-heated to a temperature of 20-590 ° ⁇ .
  • the named system with a blood pressure of 20 to 250 ° C is used.
  • the operational changes to the effective direction of the payment in the case of the commercialization of the aforementioned nitrogen.
  • Pe ⁇ i ⁇ d ⁇ a ⁇ - g ⁇ Changes are s ⁇ s ⁇ avlyae ⁇ , ⁇ a ⁇ ⁇ avil ⁇ '1-30 minutes the.
  • Equalization of the hemorrhagic non-uniform one-sys- tem by means of intercalation is associated with pressure reduction.
  • the catalytic liquid emanating from the first part of the catalyst has a high hemisphere, which differs in cross section, because of the low gas consumption.
  • the conditioned non-uniformity of the catalyst layer - 8 - za ⁇ a, b ⁇ lshe than ⁇ emya between changes na ⁇ av ⁇ e Nia ⁇ dachi is ⁇ dn ⁇ y az ⁇ d ⁇ dn ⁇ y smeei, ⁇ edlagaem ⁇ e ⁇ e ⁇ e- mixing of e ⁇ y az ⁇ v ⁇ d ⁇ dn ⁇ y mixture ⁇ iv ⁇ di ⁇ ⁇ -zy ⁇ avni- vaniyu ⁇ em ⁇ e ⁇ a ⁇ u ⁇ y in lyub ⁇ m sectional sl ⁇ ya ⁇ a ⁇ aliza ⁇ a 5 ⁇ e ⁇ endi ⁇ ulya ⁇ n ⁇ m ⁇ u is ⁇ dn ⁇ g ⁇ gas and haem thus ⁇ zv ⁇ lyae ⁇
  • the optimal mode is the whole process of ammonia blasting.
  • Variation of the flow direction of the feed of the aqueous mixture in the catalyst layer is, in fact, said: from the beginning
  • ⁇ dna ⁇ pressure is ⁇ dn ⁇ y az ⁇ v ⁇ d ⁇ dn ⁇ y mixture ⁇ Pa 10, ⁇ em ⁇ e ⁇ a ⁇ u ⁇ a az ⁇ v ⁇ d ⁇ dn ⁇ y mixture on v ⁇ de in sl ⁇ y ⁇ a ⁇ alizag ⁇ ra ⁇ 00 ⁇ C .
  • the average output of ammonia is $ 10; the average ammonia output is $ 8.
  • the combination of the ammonia is subject to the conditions similar to that shown in Example 2.
  • the same size is measured at 50 mm.
  • the average output of amshaka is $ 16, and ammonia is 5 $ 14 $.
  • ammonia occurs under conditions similar to those indicated in Example I. However, the 15 catalytic converter is divided into two parts with a separation of a little more than 0.6. Medium: ammonia output 15.9, ammonia output $ 13.9. _Note ⁇ 10
  • the synthesis of agglomerate is subject to conditions similar to the 20 indicated in Example I.
  • the one-layer catalytic converter is divided into two parts with a difference in parts! catalytic layer 0.71.
  • the synthesis of ammonia is in the CONDITIONS ⁇ , similar to those indicated in Example I. However, the catalytic conversion is divided into two parts with a separation of at least 1. The average ammonia output is $ 35.16.1, pripyst 14.1. EXAMPLE 13 The synthesis of ammonia is carried out under conditions similar - II - ny ⁇ u ⁇ azannym in ⁇ ime ⁇ e I.
  • ammonia The synthesis of ammonia is subject to conditions similar to those indicated in Example I.
  • the same and basic mixture is contained in bulk: nitrogen - 20; ⁇ Play ⁇ Play- 60; Southern gases - 15; ammonia - 5.
  • the change in the direction of delivery of the original mixture to the positive is effective after every 2 minutes.
  • the average output of ammonia is 16.6, the amount of ammonia is $ 11.6.
  • the intended use of 15 ummiak is used for the use of nitric acid, nitric acid, urea, and salt. Hydrate of the United Nations, hydrocyanic acid, fertilizers, diazo-typed light materials.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
PCT/SU1987/000106 1986-10-17 1987-09-23 Procede de production de l'ammoniac Ceased WO1988002737A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
HU875776A HUT46594A (en) 1986-10-17 1987-09-23 Process for producing ammonia
GB8811619A GB2205561B (en) 1986-10-17 1987-09-23 Process for producing ammonia.
DK327888A DK327888D0 (da) 1986-10-17 1988-06-15 Fremgangsmaade til fremstilling af ammoniak

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SU864131458A SU1696387A1 (ru) 1986-10-17 1986-10-17 Способ синтеза аммиака
SU4131458/23 1986-10-17

Publications (1)

Publication Number Publication Date
WO1988002737A1 true WO1988002737A1 (fr) 1988-04-21

Family

ID=21261751

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SU1987/000106 Ceased WO1988002737A1 (fr) 1986-10-17 1987-09-23 Procede de production de l'ammoniac

Country Status (8)

Country Link
JP (1) JPH01501141A (https=)
DE (1) DE3790631T1 (https=)
FR (1) FR2605305B1 (https=)
GB (1) GB2205561B (https=)
HU (1) HUT46594A (https=)
PL (1) PL268264A1 (https=)
SU (1) SU1696387A1 (https=)
WO (1) WO1988002737A1 (https=)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK173917B1 (da) * 1998-07-02 2002-02-18 Topsoe Haldor As Fremgangsmåde til fremstilling af ammoniak
DK173814B1 (da) * 1999-03-15 2001-11-12 Topsoe Haldor As Fremgangsmåde til fremstilling af ammoniak og katalysator til syntese af ammoniak

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4423022A (en) * 1979-05-22 1983-12-27 The Lummus Company Processes for carrying out catalytic exothermic and endothermic high-pressure gas reactions
US4510123A (en) * 1982-11-26 1985-04-09 C F Braun & Co. Temperature controlled ammonia synthesis process

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4423022A (en) * 1979-05-22 1983-12-27 The Lummus Company Processes for carrying out catalytic exothermic and endothermic high-pressure gas reactions
US4510123A (en) * 1982-11-26 1985-04-09 C F Braun & Co. Temperature controlled ammonia synthesis process

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
A.G. KASATKIN, "Osuovnye Protsessy I Apparaty Khimicheskoi Tekhnologii", 1973, Khimia Moscow, page 246. *

Also Published As

Publication number Publication date
FR2605305B1 (fr) 1990-07-20
GB8811619D0 (en) 1988-07-13
FR2605305A1 (fr) 1988-04-22
GB2205561A (en) 1988-12-14
SU1696387A1 (ru) 1991-12-07
JPH01501141A (ja) 1989-04-20
GB2205561B (en) 1990-12-19
PL268264A1 (en) 1988-08-18
HUT46594A (en) 1988-11-28
DE3790631T1 (https=) 1988-10-06

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