WO1987007602A3 - N-(5-substituted methylene) phenyl herbicides - Google Patents

N-(5-substituted methylene) phenyl herbicides Download PDF

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Publication number
WO1987007602A3
WO1987007602A3 PCT/EP1987/000279 EP8700279W WO8707602A3 WO 1987007602 A3 WO1987007602 A3 WO 1987007602A3 EP 8700279 W EP8700279 W EP 8700279W WO 8707602 A3 WO8707602 A3 WO 8707602A3
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WO
WIPO (PCT)
Prior art keywords
halogen
alkyl
low
hydrogen
control
Prior art date
Application number
PCT/EP1987/000279
Other languages
French (fr)
Other versions
WO1987007602A2 (en
Inventor
Thomas Neil Wheeler
Robert Benton Morland
Todd Alexander Craig
Original Assignee
Rhone Poulenc Agrochimie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Agrochimie filed Critical Rhone Poulenc Agrochimie
Publication of WO1987007602A2 publication Critical patent/WO1987007602A2/en
Publication of WO1987007602A3 publication Critical patent/WO1987007602A3/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/44—Iso-indoles; Hydrogenated iso-indoles
    • C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/44—Iso-indoles; Hydrogenated iso-indoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/44—Iso-indoles; Hydrogenated iso-indoles
    • C07D209/46—Iso-indoles; Hydrogenated iso-indoles with an oxygen atom in position 1
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/18—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
    • C07D295/182—Radicals derived from carboxylic acids
    • C07D295/185—Radicals derived from carboxylic acids from aliphatic carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/14—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/12—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains three hetero rings
    • C07D493/14—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/5537—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom the heteroring containing the structure -C(=O)-N-C(=O)- (both carbon atoms belong to the heteroring)

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Aniline herbicides of formula (I), wherein R1 and R2 are hydrogen, halogen, alkyl, alkoxy or trifluoromethyl, phenoxy or benzyloxy, R3 and R4 are hydrogen, alkyl, alkenyl, alkynyl or halogen, Y represents hydrogen, halogen, cyano, nitrate, alkyl, alkenyl, alkynyl and various other substituents and Z is a heterocyclic group attached to the phenyl ring via a nitrogen atom which forms part of the ring system, or a carbocyclic or heterocyclic group attached via a nitrogen atom which does not form part of the ring system, exhibit excellent pre-emergent control of broadleaf weeds and grasses at rates as low as 0.25 lb/A with good safety to soybeans, cotton, corn and wheat. In post-emergent treatments these compounds show excellent and rapid control of broadleaf weeds with low (0-20 %) injury to soybeans, corn, wheat, and rice at rates as low as 0.015 lb/A. The compounds of this invention afford improved crop safety and control of grassy weeds. Novel aniline intermediates are used to make the anilides.
PCT/EP1987/000279 1986-06-03 1987-05-29 N-(5-substituted methylene) phenyl herbicides WO1987007602A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US86991486A 1986-06-03 1986-06-03
US869,914 1986-06-03

Publications (2)

Publication Number Publication Date
WO1987007602A2 WO1987007602A2 (en) 1987-12-17
WO1987007602A3 true WO1987007602A3 (en) 1988-03-24

Family

ID=25354450

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1987/000279 WO1987007602A2 (en) 1986-06-03 1987-05-29 N-(5-substituted methylene) phenyl herbicides

Country Status (7)

Country Link
AU (1) AU7512587A (en)
DD (1) DD257573A5 (en)
GR (1) GR870854B (en)
IL (1) IL82657A0 (en)
MA (1) MA20993A1 (en)
WO (1) WO1987007602A2 (en)
ZA (1) ZA873933B (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1986000072A1 (en) * 1984-06-12 1986-01-03 Fmc Corporation Herbicidal 2-aryl-1,2,4-triazine-3,5(2h,4h)-diones and sulfur analogs thereof
US4804400A (en) * 1986-09-12 1989-02-14 Ciba-Geigy Corporation N-phenyl-maleimides and herbicidal and plant growth regulating methods of use thereof
JPH0778047B2 (en) * 1987-03-10 1995-08-23 呉羽化学工業株式会社 1,5-Diphenyl-1H-1,2,4-triazol-3-carboxylic acid amide derivative and herbicide containing the derivative
DE3724395A1 (en) * 1987-07-23 1989-02-02 Basf Ag 3-phenylpropionic acid derivatives
DE3736297A1 (en) * 1987-10-27 1989-05-11 Basf Ag N-PHENYLTETRAHYDROPHTHALIMIDVERBINDUNGEN
DE3741272A1 (en) * 1987-12-05 1989-06-15 Basf Ag N-3- (1,3-dioxolan-2-YL) -PHENYLTETRAHYDROPHTHALIMIDE
DE3741273A1 (en) * 1987-12-05 1989-06-15 Basf Ag N-PHENYLTETRAHYDROPHTHALIMIDVERBINDUNGEN
US5169428A (en) * 1987-12-30 1992-12-08 Tosoh Corporation Tetrahydrophthalimide derivative and herbicide composition containing same
EP0323271A1 (en) * 1987-12-30 1989-07-05 Tosoh Corporation Tetrahydrophthalimide derivative and herbicide composition containing the same
DE3815042A1 (en) * 1988-05-04 1989-11-16 Basf Ag N- (5-FORMYL) -PHENYL-3,4,5,6-TETRAHYDROPHTHALIMIDE COMPOUNDS, 5-AMINOBENZALDEHYDACETALS, PROCESS FOR THEIR PRODUCTION AND THEIR USE AS INTERMEDIATE PRODUCTS
DE3819464A1 (en) * 1988-06-08 1989-12-14 Basf Ag SUBSTITUTED N- (HETEROCYLYLIDENETHYL) PENTYL-3,4,5,6-TETRAHYDROPHTHALIMIDES, PROCESS FOR THE PREPARATION THEREOF AND HERBICIDES CONTAINING THEM
EP0834503B1 (en) * 1992-04-25 2001-06-27 Basf Aktiengesellschaft Tetrahydrophthalimides, their preparation and use
DE4236880A1 (en) * 1992-10-31 1994-05-05 Basf Ag N-phenyl-substituted glutarimides and N-phenylglutaric acid amides, their preparation and use
DE19517597A1 (en) * 1994-06-03 1995-12-07 Basf Ag New 3-(tetra:hydro-phthalimido)cinnamyl alcohol derivs.
US7449481B2 (en) 2004-04-13 2008-11-11 Cephalon, Inc. Thio-substituted biaryl-methanesulfinyl derivatives
ITMI20050275A1 (en) * 2005-02-22 2006-08-23 Miteni Spa PROCEDURE FOR THE PREPARATION OF BENZOIC ACID DERIVATIVES THROUGH A NEW INTERMEDIATE SYNTHESIS

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0068822A2 (en) * 1981-06-29 1983-01-05 Rohm And Haas Company Novel heterocyclic substituted benzenes, herbicidal compositions containing them and the use thereof for combating weeds
EP0083055A2 (en) * 1981-12-25 1983-07-06 Sumitomo Chemical Company, Limited Tetrahydrophthalimide compounds, and their production and use
EP0095192A2 (en) * 1982-05-26 1983-11-30 Sumitomo Chemical Company, Limited Tetrahydrophthalimides, and their production and use
EP0126419A1 (en) * 1983-05-16 1984-11-28 Sumitomo Chemical Company, Limited 2-Substituted phenyl-4,5,6,7-tetrahydro-2H-isoindole-1,3-diones, and their production and use

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0068822A2 (en) * 1981-06-29 1983-01-05 Rohm And Haas Company Novel heterocyclic substituted benzenes, herbicidal compositions containing them and the use thereof for combating weeds
EP0083055A2 (en) * 1981-12-25 1983-07-06 Sumitomo Chemical Company, Limited Tetrahydrophthalimide compounds, and their production and use
EP0095192A2 (en) * 1982-05-26 1983-11-30 Sumitomo Chemical Company, Limited Tetrahydrophthalimides, and their production and use
EP0126419A1 (en) * 1983-05-16 1984-11-28 Sumitomo Chemical Company, Limited 2-Substituted phenyl-4,5,6,7-tetrahydro-2H-isoindole-1,3-diones, and their production and use

Also Published As

Publication number Publication date
IL82657A0 (en) 1987-11-30
DD257573A5 (en) 1988-06-22
ZA873933B (en) 1987-12-02
WO1987007602A2 (en) 1987-12-17
AU7512587A (en) 1988-01-11
GR870854B (en) 1987-10-02
MA20993A1 (en) 1987-12-31

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