WO1986000389A1 - Process for combustion or decomposition of pollutants and equipment therefor - Google Patents
Process for combustion or decomposition of pollutants and equipment therefor Download PDFInfo
- Publication number
- WO1986000389A1 WO1986000389A1 PCT/SE1985/000257 SE8500257W WO8600389A1 WO 1986000389 A1 WO1986000389 A1 WO 1986000389A1 SE 8500257 W SE8500257 W SE 8500257W WO 8600389 A1 WO8600389 A1 WO 8600389A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- gas
- bed
- combustion
- pollutants
- changing
- Prior art date
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/06—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
- F23G7/061—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating
- F23G7/065—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating using gaseous or liquid fuel
- F23G7/066—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating using gaseous or liquid fuel preheating the waste gas by the heat of the combustion, e.g. recuperation type incinerator
- F23G7/068—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating using gaseous or liquid fuel preheating the waste gas by the heat of the combustion, e.g. recuperation type incinerator using regenerative heat recovery means
Definitions
- the rate of a combustion reaction is very sensitive to temperature and the rate increases strongly with increasing temperature. In a combustion process it is necessary that the temperature of the flame or combustion zone is high enough to make the reaction proceed with rea ⁇ sonable speed.
- the method has some drawbacks, for instance: a) Catalysts are expensive. . b) Catalysts are easily destroyed by certain impurities in the gas even if their concentration is low (catalyst poisons) . c) Catalysts usually are sensitive to tempe ⁇ rature and destroyed at too high temperatures. Consequently, gas mixtures with too high concentrations of burnables cannot be treated and the whole process is sensitive to variations of concentration of burnables.
- the present invention relates to a process for the establishment of combustion and/or decomposition of pollutants in the form of gas or particles carried by air or other gas.
- the main object of this invention is to bring about a process of the above mentioned kind which makes possible an effective and reliable combustion and/or decom- position of pollutants for instance obtained in industry such as air evacuated from paint spraying booths or nitrogen oxides and thereby prevent harmful gases and particles from entering the environment.
- a second object of the invention is to present an apparatus by means of which the above mentioned process can be practised. Said second object is accomplished by an apparatus according to the present invention characterized by said apparatus incorporating a bed filled with sand, stone or the like having the ability to store heat and exchange heat and having means for heating of the inner portion of said bed to self decomposition temperature and/ or self combustion temperature for instance by means of an electric heater in the bed or by means of gaseous fuel.
- a "combustor" 1 which preferably is suited to be used effectively according to the invention comprises a bed of sand, stone or other material which has the ability to store and exchange heat and to combust and/or decompose gaseous or particulate pollutants carried by air or other gas in the bed.
- air evacuated from paint spray ⁇ ing booths or other gases which contain burnable gases etc. and/or for instance nitrogen oxides or other gases possible to decompose can be combusted and/or decomposed in said bed 1. This is only due to the high temperature, i.e. without the bed participating in the reaction otherwise than as a means to establish the high temperature.
- a conduit 2 communicating with the two ends 1A and IB respectively of the combustor 1 also communicates with a device 3 for periodic changing of the direction of flow .which can be manually and/or automatically operated.
- the intention is to preferably let the pollutants in question be fed into it by means of conduit 2 in order to drive the apparatus 1, but mainly to ascertain a complete combustion of said pollutants which may be harmful or odorous like paint gases.
- the feeding of pollutants to the device 3 for changing of flow direction is done through a duct 4 from the inlet 5.
- Said duct 2 also works as outlet for air and/or gas from the combustor 1 to an exhaust duct 11 which leads from the flow direction changer 3 to an exhaust 12.
- the counter current regenerative heat ex ⁇ change occurring in the bed makes it possible to use the heat contents of the treated gas which leaves through the bed 1* of the combustor 1 to heat the gas and/or air or of other gas carried particulate pollutants which are being fed inwards through said bed 1* .
- this is done so that maximum temperature and combustion and/or decompo- sition occurs in the central parts of the bed 1'.
- This is accomplished by changing of the direction of gas flow through the combustor 1 and its bed l 1 at suitable time intervals by means of the gas flow direction changer 3.
- the combustion and/or decomposition of the pollutants can often proceed by influence from the heat of the bed 1* without having any extra energy supplied by the heating means. This is the case when heat produced by the reaction in the bed is enough to compensate for unavoidable heat losses from for instance incomplete heat exchange in the bed. In cases when the pollutants are rich in energy, produced excess heat could be utilized by extraction at desired temperature level by means of cooling tubes installed at suitable positions in the bed.
- a storing device M which makes possible a safe reception of pollutants which are fed from the inlet 5 to the changing device 3 during the time said changing de ⁇ vice 3 is being switched over for the reversal of the flow direction in the conduit 2 to the combustor 1 is connected to the outlet duct 11 after the direction changer 3, as seen in the direction of the flow. This is done to prevent pollu ⁇ tants to escape in connection with the above described inter ⁇ change of point of feed and point of outlet of gas/air.
- said storing device M comprises a comparatively long duct 13 which makes it possible to temporarily store air/gas of said kind.
- a circuit 14 which comprises an ent ⁇ rance duct 15 which is connected to•the exhaust duct 11 before an incorporated valve 16 or the like and an outlet 17 which is connected to the inlet duct 4 is connected to said long duct 13 or the like in store M incorporated recep- tion reservoir.
- One way valves 18 and 19 which make it possible to convey air and/or gas in the direction of the arrows 20 and 21 on the drawing to and from the store M, but are designed to automatically shut off flow in the opposite direction, are incorporated in the inlet and outlet ducts 15 and 17, respectively.
- a valve 22 is incorporated in a duct 23 leading for instance outside from the store M and a fan 24 or some other type of blowing machinery is connected to the store M.
- This fan can preferably be run continuously while the device is operating. Changing of flow is made possible according to the following: Positions of the valve 6 at the switching device 3 according to the continuous line in the drawing will convey the pollutants in the direction 7 in the conduit 2 into the combustor 1 and convey treated gas to the outlet 12 from the combustor 1 in the direction 25. Reversal of the valve 6 according to the dashed line on the drawing will convey the pollu ⁇ tants from the entrance 5 to the combustor 1 in the direct ⁇ ion 8 and thus treated gas by means of the circuit 9 to the exhaust 12 in the direction 26. When opening valve 22 the one way valve 19 is automatically shut so that possible gas flowing towards exhaust 12 is instead conveyed into the store M when valve 16 has been shut off and the one way valve 18 opened.
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Incineration Of Waste (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60502928A JPH0733905B2 (ja) | 1984-06-21 | 1985-06-19 | 汚染物質の燃焼または分解方法およびその装置 |
AT85903427T ATE41052T1 (de) | 1984-06-21 | 1985-06-19 | Verfahren zum verbrennen oder vernichten von schadstoffen und anlage dazu. |
DE8585903427T DE3568483D1 (en) | 1984-06-21 | 1985-06-19 | Process for combustion or decomposition of pollutants and equipment therefor |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE8403330A SE441623B (sv) | 1984-06-21 | 1984-06-21 | Forfarande och anordning for forbrenning och/eller sonderdelning av fororeningar |
SE8403330-7 | 1984-06-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1986000389A1 true WO1986000389A1 (en) | 1986-01-16 |
Family
ID=20356317
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/SE1985/000257 WO1986000389A1 (en) | 1984-06-21 | 1985-06-19 | Process for combustion or decomposition of pollutants and equipment therefor |
Country Status (7)
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0365262A1 (en) * | 1988-10-17 | 1990-04-25 | Haldor Topsoe A/S | A method and an apparatus for continuously purifying an oxygen-containing gas of its combustible contaminants |
WO1991000477A1 (en) * | 1989-06-28 | 1991-01-10 | Adtec Ab | A method and a device in gas purifying installations for preventing discharge of unpurified gas upon changes of the gas-flow direction |
WO1993012381A1 (en) * | 1991-12-19 | 1993-06-24 | Heed Bjoern | A gas treatment installation |
EP0587064A1 (en) * | 1992-09-07 | 1994-03-16 | O.R.V. OVATTIFICIO RESINATURA VALPADANA S.p.A. | Improved thermal disposal unit |
WO1997022835A1 (de) * | 1995-12-15 | 1997-06-26 | Bwt Aktiengesellschaft | Verfahren und anlage zum reinigen von verschmutzten abgasen |
WO2000034569A1 (en) * | 1998-11-26 | 2000-06-15 | Excelentec Holding Ab | A method of cleaning sulfide contaminated condensates |
Families Citing this family (70)
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US5229071A (en) * | 1988-08-19 | 1993-07-20 | Meo Iii Dominic | Catalytic oxidizer for treating fixed quantities of gases |
SE466433B (sv) * | 1989-10-26 | 1992-02-17 | Bjoern Heed | Saett och anordning att rena luft fraan braennbara foeroreningar |
CA2031367C (en) * | 1989-12-04 | 1996-06-04 | Craig Edward Bayer | Regenerative bed incinerator system with gas doping |
US5186901A (en) * | 1989-12-04 | 1993-02-16 | The Air Preheater Company, Inc. | Regenerative bed incinerator system |
US5024817A (en) * | 1989-12-18 | 1991-06-18 | The Air Preheater Company, Inc. | Twin bed regenerative incinerator system |
US5188804A (en) * | 1989-12-26 | 1993-02-23 | The Air Preheater Company, Inc. | Regenerative bed incinerator and method of operating same |
US5165884A (en) * | 1991-07-05 | 1992-11-24 | Thermatrix, Inc. | Method and apparatus for controlled reaction in a reaction matrix |
DK0524736T3 (da) * | 1991-07-05 | 1998-09-23 | Thermatrix Inc A Delaware Corp | Fremgangsmåde og apparat til styret reaktion i en reaktionsmatrix |
SE468156B (sv) * | 1991-10-16 | 1992-11-16 | Bjoern Heed | Foerfarande foer eliminering av kvaeveoxider ur en gasstroem med anvaendning av en foerbraenningsvaexlare |
US6168770B1 (en) | 1991-10-16 | 2001-01-02 | Bjorn Heed | Method of removing nitrogen oxides from a gas flow by using a combustion engine |
SE500521C2 (sv) * | 1991-12-09 | 1994-07-11 | Bjoern Heed | Förbränningsanordning innefattande en stationär bädd med värmeackumulerande och värmeväxlande egenskaper |
DE4234080A1 (de) * | 1992-10-09 | 1994-04-14 | Kirchner Reinhardt Robert Dr I | Verfahren zur Aufkonzentrierung gering mit Schadstoffen belasteter Abluftströme |
US5366708A (en) * | 1992-12-28 | 1994-11-22 | Monsanto Eviro-Chem Systems, Inc. | Process for catalytic reaction of gases |
US5376340A (en) * | 1993-04-15 | 1994-12-27 | Abb Air Preheater, Inc. | Regenerative thermal oxidizer |
US5538693A (en) * | 1994-08-04 | 1996-07-23 | Tellkamp Systems, Inc. | Varying switching temperature set-point method for bed flow reversal for regenerative incinerator systems |
ES2182921T3 (es) * | 1995-12-08 | 2003-03-16 | Megtec Systems Ab | Un metodo y un dispositovo para recuperacion de energia de medios que contienen substancias combustibles, incluso bajas concentraciones. |
DE19611226C1 (de) * | 1996-03-21 | 1997-10-02 | Fhw Brenntechnik Gmbh | Vorrichtung zur thermischen Abgasbehandlung, insbesondere von oxidierbaren Schwelgasen |
US5921763A (en) * | 1996-05-02 | 1999-07-13 | Thermatrix, Inc. | Methods for destroying colliery methane and system for practicing same |
US5833938A (en) * | 1996-05-20 | 1998-11-10 | Megtec Systems, Inc. | Integrated VOC entrapment system for regenerative oxidation |
US5692893A (en) * | 1996-08-16 | 1997-12-02 | Houston; Reagan | Rotary valve for 2-bed regenerative fume incinerator |
FR2756753B1 (fr) * | 1996-12-05 | 1998-12-31 | Inst Francais Du Petrole | Dispositif rotatif perfectionne d'epuration catalytique d'effluents gazeux |
US5823770A (en) * | 1997-02-26 | 1998-10-20 | Monsanto Company | Process and apparatus for oxidizing components of a feed gas mixture in a heat regenerative reactor |
US5931663A (en) * | 1997-02-27 | 1999-08-03 | Process Combustion Corporation | Purge system for regenerative thermal oxidizer |
US6015540A (en) * | 1997-09-02 | 2000-01-18 | Thermatrix, Inc. | Method and apparatus for thermally reacting chemicals in a matrix bed |
US5989010A (en) * | 1997-09-02 | 1999-11-23 | Thermatrix, Inc. | Matrix bed for generating non-planar reaction wave fronts, and method thereof |
US6003305A (en) | 1997-09-02 | 1999-12-21 | Thermatrix, Inc. | Method of reducing internal combustion engine emissions, and system for same |
SE518812C2 (sv) * | 1998-03-17 | 2002-11-26 | Bjoern Heed | Katalytisk regenerativ anordning för rening av gaser |
WO1999057492A1 (en) | 1998-05-05 | 1999-11-11 | Thermatrix, Inc. | A device for thermally processing a gas stream, and method for same |
US6282371B1 (en) | 1998-07-02 | 2001-08-28 | Richard J. Martin | Devices for reducing emissions, and methods for same |
EP1222015A1 (de) * | 1999-10-21 | 2002-07-17 | Kronospan AG | Verfahren zur reinigung von mit organischen verbindungen und staubpartikeln beladenen abgasen |
SE515710C2 (sv) | 2000-02-11 | 2001-10-01 | Bjoern Heed | Luftskåp vid en regenerativ förbränningsanordning |
US6261092B1 (en) | 2000-05-17 | 2001-07-17 | Megtec Systems, Inc. | Switching valve |
US6749815B2 (en) | 2001-05-04 | 2004-06-15 | Megtec Systems, Inc. | Switching valve seal |
US7325562B2 (en) | 2002-05-07 | 2008-02-05 | Meggec Systems, Inc. | Heated seal air for valve and regenerative thermal oxidizer containing same |
US6669472B1 (en) | 2002-08-28 | 2003-12-30 | Megtec Systems, Inc. | Dual lift system |
US7150446B1 (en) | 2002-08-28 | 2006-12-19 | Megtec Systems, Inc. | Dual lift system |
DE102004038730B3 (de) * | 2004-08-10 | 2006-02-23 | Probat-Werke Von Gimborn Maschinenfabrik Gmbh | Röstvorrichtung für pflanzliches Schüttgut sowie Verfahren zum Betreiben einer Röstvorrichtung für pflanzliches Schüttgut |
US8671658B2 (en) | 2007-10-23 | 2014-03-18 | Ener-Core Power, Inc. | Oxidizing fuel |
US8393160B2 (en) | 2007-10-23 | 2013-03-12 | Flex Power Generation, Inc. | Managing leaks in a gas turbine system |
US8701413B2 (en) * | 2008-12-08 | 2014-04-22 | Ener-Core Power, Inc. | Oxidizing fuel in multiple operating modes |
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US8621869B2 (en) | 2009-05-01 | 2014-01-07 | Ener-Core Power, Inc. | Heating a reaction chamber |
US20100275611A1 (en) * | 2009-05-01 | 2010-11-04 | Edan Prabhu | Distributing Fuel Flow in a Reaction Chamber |
US8893468B2 (en) | 2010-03-15 | 2014-11-25 | Ener-Core Power, Inc. | Processing fuel and water |
US9057028B2 (en) | 2011-05-25 | 2015-06-16 | Ener-Core Power, Inc. | Gasifier power plant and management of wastes |
US9279364B2 (en) | 2011-11-04 | 2016-03-08 | Ener-Core Power, Inc. | Multi-combustor turbine |
US9273606B2 (en) | 2011-11-04 | 2016-03-01 | Ener-Core Power, Inc. | Controls for multi-combustor turbine |
US8671917B2 (en) | 2012-03-09 | 2014-03-18 | Ener-Core Power, Inc. | Gradual oxidation with reciprocating engine |
US9353946B2 (en) | 2012-03-09 | 2016-05-31 | Ener-Core Power, Inc. | Gradual oxidation with heat transfer |
US8926917B2 (en) | 2012-03-09 | 2015-01-06 | Ener-Core Power, Inc. | Gradual oxidation with adiabatic temperature above flameout temperature |
US9267432B2 (en) | 2012-03-09 | 2016-02-23 | Ener-Core Power, Inc. | Staged gradual oxidation |
US9273608B2 (en) | 2012-03-09 | 2016-03-01 | Ener-Core Power, Inc. | Gradual oxidation and autoignition temperature controls |
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US9359947B2 (en) | 2012-03-09 | 2016-06-07 | Ener-Core Power, Inc. | Gradual oxidation with heat control |
US8980192B2 (en) | 2012-03-09 | 2015-03-17 | Ener-Core Power, Inc. | Gradual oxidation below flameout temperature |
US9567903B2 (en) | 2012-03-09 | 2017-02-14 | Ener-Core Power, Inc. | Gradual oxidation with heat transfer |
US9371993B2 (en) | 2012-03-09 | 2016-06-21 | Ener-Core Power, Inc. | Gradual oxidation below flameout temperature |
US8980193B2 (en) | 2012-03-09 | 2015-03-17 | Ener-Core Power, Inc. | Gradual oxidation and multiple flow paths |
US9234660B2 (en) | 2012-03-09 | 2016-01-12 | Ener-Core Power, Inc. | Gradual oxidation with heat transfer |
US9726374B2 (en) | 2012-03-09 | 2017-08-08 | Ener-Core Power, Inc. | Gradual oxidation with flue gas |
US9359948B2 (en) | 2012-03-09 | 2016-06-07 | Ener-Core Power, Inc. | Gradual oxidation with heat control |
US8807989B2 (en) | 2012-03-09 | 2014-08-19 | Ener-Core Power, Inc. | Staged gradual oxidation |
US9206980B2 (en) | 2012-03-09 | 2015-12-08 | Ener-Core Power, Inc. | Gradual oxidation and autoignition temperature controls |
US9328916B2 (en) | 2012-03-09 | 2016-05-03 | Ener-Core Power, Inc. | Gradual oxidation with heat control |
US9381484B2 (en) | 2012-03-09 | 2016-07-05 | Ener-Core Power, Inc. | Gradual oxidation with adiabatic temperature above flameout temperature |
US9534780B2 (en) | 2012-03-09 | 2017-01-03 | Ener-Core Power, Inc. | Hybrid gradual oxidation |
US9017618B2 (en) | 2012-03-09 | 2015-04-28 | Ener-Core Power, Inc. | Gradual oxidation with heat exchange media |
US9347664B2 (en) | 2012-03-09 | 2016-05-24 | Ener-Core Power, Inc. | Gradual oxidation with heat control |
US8844473B2 (en) | 2012-03-09 | 2014-09-30 | Ener-Core Power, Inc. | Gradual oxidation with reciprocating engine |
CN108980867A (zh) * | 2018-10-15 | 2018-12-11 | 上海环境工程设计研究院有限公司 | 立式rto焚烧系统 |
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DE2127687A1 (de) * | 1971-06-04 | 1972-12-14 | Daimler-Benz Ag, 7000 Stuttgart | Verfahren zum Verbrennen von Lackschlamm |
US3942264A (en) * | 1972-11-09 | 1976-03-09 | Kurt Zenkner | Method for thermal afterburning of exhaust air from industrial working plants and device for carrying out this method |
DE2652474A1 (de) * | 1976-11-18 | 1978-05-24 | Udo Dipl Ing Jodeit | Verfahren zur schadlosen verfeuerung von bindemittelhaltigem holzschleifstaub |
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-
1984
- 1984-06-21 SE SE8403330A patent/SE441623B/sv unknown
-
1985
- 1985-06-19 EP EP85903427A patent/EP0218590B1/en not_active Expired
- 1985-06-19 DE DE8585903427T patent/DE3568483D1/de not_active Expired
- 1985-06-19 DE DE19853590307 patent/DE3590307T1/de not_active Withdrawn
- 1985-06-19 JP JP60502928A patent/JPH0733905B2/ja not_active Expired - Fee Related
- 1985-06-19 US US06/848,397 patent/US4741690A/en not_active Expired - Lifetime
- 1985-06-19 WO PCT/SE1985/000257 patent/WO1986000389A1/en active IP Right Grant
- 1985-06-20 CA CA000484668A patent/CA1249213A/en not_active Expired
Patent Citations (3)
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DE2127687A1 (de) * | 1971-06-04 | 1972-12-14 | Daimler-Benz Ag, 7000 Stuttgart | Verfahren zum Verbrennen von Lackschlamm |
US3942264A (en) * | 1972-11-09 | 1976-03-09 | Kurt Zenkner | Method for thermal afterburning of exhaust air from industrial working plants and device for carrying out this method |
DE2652474A1 (de) * | 1976-11-18 | 1978-05-24 | Udo Dipl Ing Jodeit | Verfahren zur schadlosen verfeuerung von bindemittelhaltigem holzschleifstaub |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0365262A1 (en) * | 1988-10-17 | 1990-04-25 | Haldor Topsoe A/S | A method and an apparatus for continuously purifying an oxygen-containing gas of its combustible contaminants |
WO1990004742A1 (en) | 1988-10-17 | 1990-05-03 | Haldor Topsøe A/S | A method and an apparatus for continuously purifying an oxygen-containing gas for combustible contaminants |
US5145363A (en) * | 1988-10-17 | 1992-09-08 | Haldor Topsoe A/S | Method and an apparatus for continuously purifying an oxygen-containing gas for combustible contaminants |
WO1991000477A1 (en) * | 1989-06-28 | 1991-01-10 | Adtec Ab | A method and a device in gas purifying installations for preventing discharge of unpurified gas upon changes of the gas-flow direction |
WO1993012381A1 (en) * | 1991-12-19 | 1993-06-24 | Heed Bjoern | A gas treatment installation |
EP0587064A1 (en) * | 1992-09-07 | 1994-03-16 | O.R.V. OVATTIFICIO RESINATURA VALPADANA S.p.A. | Improved thermal disposal unit |
WO1997022835A1 (de) * | 1995-12-15 | 1997-06-26 | Bwt Aktiengesellschaft | Verfahren und anlage zum reinigen von verschmutzten abgasen |
WO2000034569A1 (en) * | 1998-11-26 | 2000-06-15 | Excelentec Holding Ab | A method of cleaning sulfide contaminated condensates |
US6790313B1 (en) | 1998-11-26 | 2004-09-14 | Excelentec Holding Ab | Method of cleaning sulfide contaminated condensates |
Also Published As
Publication number | Publication date |
---|---|
JPH0733905B2 (ja) | 1995-04-12 |
DE3568483D1 (en) | 1989-04-06 |
JPS61502484A (ja) | 1986-10-30 |
DE3590307T1 (US20100170793A1-20100708-C00006.png) | 1987-06-04 |
EP0218590B1 (en) | 1989-03-01 |
US4741690A (en) | 1988-05-03 |
SE8403330D0 (sv) | 1984-06-21 |
SE441623B (sv) | 1985-10-21 |
EP0218590A1 (en) | 1987-04-22 |
CA1249213A (en) | 1989-01-24 |
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