WO1983000374A1 - Heater with sensor - Google Patents

Heater with sensor Download PDF

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Publication number
WO1983000374A1
WO1983000374A1 PCT/JP1982/000272 JP8200272W WO8300374A1 WO 1983000374 A1 WO1983000374 A1 WO 1983000374A1 JP 8200272 W JP8200272 W JP 8200272W WO 8300374 A1 WO8300374 A1 WO 8300374A1
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WO
WIPO (PCT)
Prior art keywords
sensor
heating
temperature
heating chamber
control unit
Prior art date
Application number
PCT/JP1982/000272
Other languages
French (fr)
Japanese (ja)
Inventor
Ltd. Matsushita Electric Industrial Co.
Original Assignee
Watanabe, Kenji
Akiyoshi, Mitsuo
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Watanabe, Kenji, Akiyoshi, Mitsuo filed Critical Watanabe, Kenji
Priority to AU86866/82A priority Critical patent/AU8686682A/en
Publication of WO1983000374A1 publication Critical patent/WO1983000374A1/en

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Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B6/00Heating by electric, magnetic or electromagnetic fields
    • H05B6/64Heating using microwaves
    • H05B6/6447Method of operation or details of the microwave heating apparatus related to the use of detectors or sensors
    • H05B6/6458Method of operation or details of the microwave heating apparatus related to the use of detectors or sensors using humidity or vapor sensors

Definitions

  • the present invention relates to an improvement in means for detecting a heating state and means for determining a total heating time in an automatic heating device provided with a sensor.
  • heating devices such as electric ovens, electronic rangers, gas ovens, or composite products of these, have been rapidly becoming intelligent based on this electronic control.
  • a particularly troublesome problem with the heating device is that the automatic heating device, which detects the heating state of the powder to be heated by means of various sensors and automatically controls the heating, quickly penetrated. . -'This is because, even if the user does not set the heating time, output, heating temperature, etc. as in the past, the control unit automatically ends the heating using the sensor.
  • an electronic range that requires consideration of the quantity of the material and the initial temperature, etc., it has been made possible to perform a simple soldering operation and to perform heating with few failures.
  • This is an example of automatic heating control using a so-called humidity sensor, but is also an effective control method for a so-called gas sensor that reacts to steam, alcohol, and carbon dioxide. Just in this method
  • FIG. 1 Figure 3 is an example showing plainly such situations.
  • [ 1 ] in the case where heating is started when the heating chamber is at room temperature will be described.
  • the temperature inside the heating chamber gradually increases depending on the heating source, so that the relative humidity RH in the heating chamber decreases. Rollers increases the temperature of the heated object is eventually the generation of steam actively 3 ⁇ 4 connection is rather that the (P 1 point), overcoming the reduced convex 'Ku of RH relative humidity to the temperature rise of the heating chamber
  • the relative humidity RH shows an increasing tendency.
  • the point at which the humidity rises above a certain threshold, ⁇ 2 is defined as the steam generation point, and the sum of the heating time required to reach that point and the separately determined picking coefficient ⁇ specific to the heated object
  • ⁇ 2 The concept of Japanese Patent Application Laid-Open No. Sho 51-13495 is to set the total heating time to zero.
  • the relative humidity R ⁇ has dropped considerably from the beginning of the heating, that is, the end is dry. Even if the same amount of water vapor as that of D is generated from the object to be heated, the relative humidity is as large as [ 1 ].
  • the relative humidity in the heating chamber will drop to 1 o%. In this state, it is assumed that 1 O ⁇ water vapor is generated from the object to be heated. At this time, if the temperature in the heating chamber is 2 o e c, which is the same as the temperature, the relative humidity will be 1 oo%, that is, it will reach a saturated state, but if it rises to 50 ° C
  • the remainder of the total change with respect to the threshold value the degree is small, and the sensitivity is high.
  • the present invention provides an automatic heating device that realizes stable and reliable automatic heating without the presence of a temperature in a heating chamber.
  • the present invention relates to the following: (1) When the initial temperature of the heat chamber is high, the amount detected by the sensor in the sensor reacting to steam is reduced, and thus the amount detected by the sensor is reduced. In this configuration, a predetermined value for judging the heating state by comparison and a constant for determining the total heating time are changed according to the initial temperature of the heating chamber. Therefore, regardless of the temperature at the start of heating in the heating chamber, the humidity sensor can detect the slight amount of water vapor generated from the object to be heated, preventing the failure of automatic ripening cooking. Then, it is possible to perform automatic heating cooking with a good finish. — —
  • FIG. 1 is an external perspective view of an automatic heating device according to an embodiment of the present invention
  • FIG. 2 is a block diagram of the same configuration
  • FIG. 3 shows a change in relative humidity in a heating chamber in a conventional heating device.
  • Fig. 4 schematically shows the control method
  • Fig. 4 is a diagram showing a control method which is an example of the present invention
  • Fig. 5 shows a control method which is another embodiment of the present invention.
  • Figure 6 shows the actual sensor! 5
  • Diagrams showing detected voltage waveforms where (a) shows a humidity sensor and (b) shows a gas sensor.
  • FIG. 3 is a functional block diagram of the control unit.
  • FIG. 1 is a perspective view of the main body of the automatic heating device according to the present invention.
  • a door 2 is attached to the front of the main body 1 so as to be openable and closable, and an operation panel 3 is provided.
  • the operation panel 3 is provided with at least a keyboard 4 for selecting a heating sequence in accordance with an object to be heated, and a display unit 5 for performing various notifications.
  • - Figure 2 shows a control block diagram of such a heating device.
  • An object 7 to be heated is placed in the heating chamber 6, and a magnetron 8 is connected as a heating source.
  • the power of the magnetron B is controlled by the control unit 9. Details of the control unit 9 3 ⁇ 4 The configuration will be described later.
  • C 1 O is a humidity sensor or a gas sensor, and the water vapor and the air discharged from the object to be heated exhausted by the fan 11 Gas, charcoal gas, etc. which gas 12 is detected.
  • 13 is a temperature detecting means such as a thermistor for measuring the temperature in the heating chamber.
  • the enemy unit 9 controls the power supply to the magnetron 8 and sends some data to the display city 5. Display various warnings and warnings with a synthesized voice or a buzzer sound using the speaker or buzzer 14.
  • Fig. 3 of the conventional method has already been described.
  • the point is that even when the same amount of water vapor is generated from the same object to be heated, the amount of change in the relative humidity varies greatly depending on the temperature in the heating chamber at that time.
  • the present invention monitors the temperature in the heating chamber, thereby stably and surely ascertaining the point at which steam or gas is generated, and realizes automatic heating by a sensor that depends on the temperature in the heating chamber.
  • FIG. 4 is a diagram showing a method for detecting a steam generation point based on the present invention.
  • the control unit 9 first measures the temperature in the heating chamber using the thermistor 13. By performing through such measurements are total heating time, the but of course that it is precisely 3 ⁇ 4 control, also measured at any single point of heating start point or P 1 point, or vapor generated point P 2 points even rather small 3 ⁇ 4 The purpose of the explanation can be reached. -Now, based on the temperature measured in this way, the control unit 9 resets a threshold value corresponding to the temperature in the system. In other words, in the case of [ 1 ], the threshold value “2” is smaller than that in the case of the higher temperature [ 2 ].
  • the steam detection points ⁇ 2 and The P 2 'point can be matched, so that the total heating time can be determined stably irrespective of the temperature, and there is sufficient margin between the threshold value and the amount of change at high temperature, and the sensor You can prevent insensitivity.
  • the total heating time can be determined stably by the amount of, the object to be heated is supplied with heat energy from this ambient temperature if the temperature inside the heating chamber is high. For this reason, the total heating time is rather short. This can be achieved by setting ⁇ 2 less than ⁇ . That is, the point of D vapor generation point P 2 'point in Fig. 4] is also taken earlier, so that the time can be shortened and the total heating time can be shortened and corrected.
  • Constant B is a constant peculiar to food. JD. It can be selected even when the heating chamber is at high temperature.
  • the total heating time can be more stable.
  • the temperature in the heating chamber immediately after the use of a heater flight is 2 5 0 to 3 0 Q e is reached in C, but the threshold is g Umate small value DOO Ru in such a state. If the sensor or its detection circuit receives noise, — T —
  • the temperature at which the sensor or its detection circuit becomes ineffective is determined as a hot level, and the hot level at the time of temperature measurement by a thermistor is detected. If a heating circuit is started, or if heating is in progress, a power supply to the heating source is stopped, and a safety circuit is provided to stop ripening. The inability of the sensor is notified to the user by a display on the display means or a notification of the synthesized voice to the speaker 14 by the voice synthesis means.
  • FIG. 6 shows the voltage waveform of the sensor detection voltage S 1 actually detected by the sensor, where (a) shows the humidity sensor and (b) shows the gas sensor.
  • the relative humidity R H detected by the humidity sensor is
  • this graph is a direct reading of the change in sensor impedance, but at high temperatures the change in the detected value is small because the change in relative humidity is small. You can see that it is small. Therefore, if the threshold value is controlled according to the temperature of the heating chamber as in the present invention, good automatic heating can be realized.
  • the threshold value may be an absolute value as in this embodiment,
  • It may be a relative value such as a voltage ratio between ⁇ 1 point and ⁇ 2 point.
  • FIG. 4 is a block diagram showing a functional configuration of the control unit 9.
  • Se emissions Sa 1 Anal port grayed amount I detected in ⁇ is converted to Dejitanore amount by the AZD converter 1 5, is input to the V 1 detector 1 6 and leveled Noreko damper rater 1 7.
  • V 1 detector 1 6 is a block to detect the leveling Norre of P 1 point, humidity • Detects the minimum value from the temperature sensor and the maximum value from the gas sensor.
  • V 1 holding register 1 S is restored.
  • V 1 holding register 1 S responsible for the update of the p V 1 value to the V 1 holds Les Soo data 1 8 by a comparison of the new data.
  • the thermistor 13 measures the temperature in the heating chamber, and the AZD converter 19 is used for the measurement! ? Input as the amount of data.
  • the converter 19 converts this into a digital storage amount TMP, reads out the corresponding useful n from the register 21 by means of the selector 20 and reads the corresponding useful n from the register 21, and reads the value from the register 21. Enter 7
  • the controller 19 also has a function of detecting an unsensorable level and outputs a HOT signal.
  • the level comparator 1 is
  • the value corresponding to the combination of the menu selected by the keyboard 4 and the value TMP obtained by converting the temperature in the heating chamber into a digital amount is stored in the R register 26 by the R selector 25.
  • the signal is extracted and input to the multiplier 23.
  • Reference numeral 28 denotes a drive circuit for operating the magnetron 8.
  • the flip-flop 27 shifts to the additional heating mode, and when the content of the down counter 24 is detected at the outlet: 5: Detachment is detected by the decoder 29].
  • i 5 Chi P 2 points by Rn -. when the T i time has elapsed, terminate the heating is Bok by re set to ZERO signal.
  • the time of AZD co Nba over data 1 9, I H 0 T signal is output, even when the temperature of the to Wachi heating chamber exceeds the sensor impossible level, full re Tsu Pufu Lock flop 2 7 Resets and prohibits or interrupts heating.
  • the HOT signal is also input to the display unit 5 and the synthesizer S0 as a voice synthesizing unit, and a warning is issued to the user in the form of a display and a synthesized voice.
  • each function block in Fig. 7 can be replaced by software-based software logic, and most of the functions are implemented by a micro-computer female storage logic controller. 3 ⁇ 4It is natural that we can do it.
  • an automatic heating apparatus having a stable and reliable sensor independent of the temperature in the heating chamber can be realized. Also, even at high temperatures, the margin between the threshold value and the total variation can be sufficiently provided, and sensor confusing can be prevented. Therefore, it can be widely used in heating cookers such as microwave ovens and electric ovens.

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  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Electric Ovens (AREA)
  • Control Of High-Frequency Heating Circuits (AREA)

Abstract

When the initial temperature of a heating chamber is high, the variations in the relative moisture detected by a moisture sensor (10) are reduced, by, for example, the reaction with vapor from food, if the sensor (10) reacts with the vapor. Accordingly, there is a problem of providing a sufficiently high sensitivity when steam is produced from the food being heated. This heater with a sensor varies the value which determines whether the food has been heated by comparison with the value detected by the sensor (10), and a constant for determining the total heating time according to the initial temperature of the heating chamber, thereby enabling an effective automatic cooking of food even regardless of the atmosphere in the kitchen.

Description

明 細 書  Specification
発明の名称 '  Title of invention ''
セ ンサを備えた加熱装置  Heating device with sensor
技術分野  Technical field
本発明はセ ン サを備えた自動加熱装置において、 加熱状態の 検出手段と、 全加熱時間の決定手段の改良に関するものである。 背景技術  The present invention relates to an improvement in means for detecting a heating state and means for determining a total heating time in an automatic heating device provided with a sensor. Background art
近年、 半導体技術の著しい進展は制御回路の高機能化 ,高集 債度による小型化、 量産効果による低価格化に成功し、 家庭用 電気機器にもこれら電子制御回路が汎用されるに至った。  In recent years, remarkable progress in semiconductor technology has succeeded in increasing the functionality of control circuits, reducing the size due to a high degree of bond collection, and reducing the price due to mass production effects, and these electronic control circuits have become widely used in home electric appliances. .
電気オ ーブ ンや電子 レ ン ジ , ガ スオ ーブ ンあるいはこれらの 複合商品 ¾ど、 種々の加熱装置においても、 この電子制御に基 く イ ンテ リ ジ- ンス化は急速に進んだ。 特に加熱装置にあって 顕著 煩向は、 糧々のセ ンサによ 被加熱粉の加熱状態を検出 し、 自動的に加熱を制御する自動加熱装置が、 またたく間に浸 透したこ とであろう。 -' これは従来のよ うに加熱時間や出力 , 加熱温度 どをュ ザ が自身で設定し く とも、 制御部がセ ンサを用いて自動的に加 熱を終了させてくれるもので、 被加熱物の分量や初期温度 ¾ど を考慮し ければ ら い電子レ ンジ どでは、 は ¾はだ操作 が簡便で、 しかも失敗の少¾い加熱が行 ¾える よ うに つた。  Various heating devices, such as electric ovens, electronic rangers, gas ovens, or composite products of these, have been rapidly becoming intelligent based on this electronic control. A particularly troublesome problem with the heating device is that the automatic heating device, which detects the heating state of the powder to be heated by means of various sensors and automatically controls the heating, quickly penetrated. . -'This is because, even if the user does not set the heating time, output, heating temperature, etc. as in the past, the control unit automatically ends the heating using the sensor. With an electronic range that requires consideration of the quantity of the material and the initial temperature, etc., it has been made possible to perform a simple soldering operation and to perform heating with few failures.
このよ う 先行技術と しては、 特開昭 5 1 — 1 3 4 9 5 1 号 がある。 これは被加熱物から発生する湿度の変化を検出し、 そ れがある設定値に達した時点を蒸気発生点とする。 そこに到達 するまでの加熱時間 T1と、 別に定めた被加熱物固有の係数 R と • の漬 R T1 との和を全加熱時間とするものである。 As such prior art, there is Japanese Patent Application Laid-Open No. 51-34995. This detects a change in humidity generated from the object to be heated, and the point when the change reaches a certain set value is defined as a steam generation point. And heating time T 1 of the to reach there, the heated object-specific coefficients R are separately prescribed • the sum of the pickles RT 1 of it is an total heating time.
これはいわゆる湿度セ ンサを用いた自動加熱の制御例である が、 蒸気 , ア コ ーノレ ,炭酸ガスに反応するいわゆるガ スセ ン サにおいても、 ^めて有効 制御方式である。 ただこの方式に This is an example of automatic heating control using a so-called humidity sensor, but is also an effective control method for a so-called gas sensor that reacts to steam, alcohol, and carbon dioxide. Just in this method
5 も次のよ う 難点はあった。 するわち加熱室内の温度が高く ると、 相対湿度が低下して乾燥状態と るため、 蒸気に反応す る湿度セ ンサおよびガスセ ンサでは、 検出レべノレが低下してし まい、 被加熱物から蒸気が出始めても、 ,低温時に比して充分る 感度をと にくかった。 5 also had the following difficulties. In other words, if the temperature in the heating chamber increases, the relative humidity decreases and the drying chamber becomes dry, so that the humidity sensor and gas sensor that react to steam will have lower detection levels and will be heated. Even when vapors began to come out of the object, the sensitivity was low enough compared to low temperatures.
10 第 3図はかかる状況を端的に示す例である。一まず加熱室内が 室温のときに加熱を開始した場合の〔1〕について説明する。 加 熱の初期には加熱室内の温度は加熱源によつて徐々に上畀して いくため、 加熱室内.の相対湿度 R Hは低下していぐ。 と ころが やがて被加熱物の温度が上昇し、 水蒸気の発生が活発に ¾つて i s く ると ( P1点)、 加熱室の温度上昇にもとつ'く相対湿度 R Hの 低下に打ち勝って、 相対湿度 R Hは上昇煩向を示すよ うにるる。 そしてかかる湿度の上昇傾向があるしきい値 を越えた時点 Ρ2 を蒸気発生点と し、 そこに到達するまでの加熱時間 と、 別に 定めた被加熱称固有の係数 Εとの漬 との和を全加熱時間と 0 するのが、 特開昭 5 1 — 1 3 4 9 5 1 号の考え方である。 1 0 Figure 3 is an example showing plainly such situations. First, [ 1 ] in the case where heating is started when the heating chamber is at room temperature will be described. In the initial stage of heating, the temperature inside the heating chamber gradually increases depending on the heating source, so that the relative humidity RH in the heating chamber decreases. Rollers increases the temperature of the heated object is eventually the generation of steam actively ¾ connexion is rather that the (P 1 point), overcoming the reduced convex 'Ku of RH relative humidity to the temperature rise of the heating chamber However, the relative humidity RH shows an increasing tendency. The point at which the humidity rises above a certain threshold, Ρ2, is defined as the steam generation point, and the sum of the heating time required to reach that point and the separately determined picking coefficient 称 specific to the heated object The concept of Japanese Patent Application Laid-Open No. Sho 51-13495 is to set the total heating time to zero.
ところ'が加熱室内が 5 0でを越えるよ う 高温のときに加熱 を開始すると ( 〔2〕 )、 加熱の冒頭から相対湿度 R Ηは相当に 低下してお 、 するわち檯端 乾燥状態にあ D 、 と全く同 量の水蒸気が被加熱物よ 発生しても、 〔1〕ほど大き くは相対However, when heating is started at a high temperature so that the temperature in the heating chamber exceeds 50 ([ 2 ]), the relative humidity RΗ has dropped considerably from the beginning of the heating, that is, the end is dry. Even if the same amount of water vapor as that of D is generated from the object to be heated, the relative humidity is as large as [ 1 ].
25 湿度が変化しない。 湿度通籙によると室温 2 0 °C、 相対湿度 25 Humidity does not change. Room temperature 20 ° C, relative humidity according to humidity
BUf? 4 0%のとき、 加熱室内の温度が 5 0 °Cまで上昇していれば、 このとき加熱室内の相対湿度は 1 o%にまで低下する。 かかる 状態で被加熱物から 1 O ^の水蒸気が発生したとする。 このと き加熱室内が寧温と同じ 2 oecであれば 相対湿共は 1 o o%、 す わち飽和状態にまで達するが、 5 0 °Cに上昇していれば BUf? At 40%, if the temperature in the heating chamber has risen to 50 ° C, then the relative humidity in the heating chamber will drop to 1 o%. In this state, it is assumed that 1 O ^ water vapor is generated from the object to be heated. At this time, if the temperature in the heating chamber is 2 o e c, which is the same as the temperature, the relative humidity will be 1 oo%, that is, it will reach a saturated state, but if it rises to 50 ° C
2 0%までにしか至ら い。 つま り 〔1〕では 6 0%も変化した 相対湿度が、 〔2〕では 1 o%しか変化してい ¾い。 従ってある —定のしきい値 で蒸気発生点 P2' を検出すると、 Ρ2点に比し て遅れてしま う。 そこで加熱時間 が長くる すぎ、 過加熱を 招く 。 Only up to 20%. That is, in [ 1 ], the relative humidity changed by as much as 60%, and in [ 2 ], the relative humidity changed only by 1%. Therefore, if the steam generation point P 2 'is detected at a certain threshold value, it will be delayed compared to the point Ρ2. Therefore, the heating time is too long, resulting in overheating.
しきい値 に対する総変化量の余: ^度も小さく 、 感度が とれ く ¾る危険も高い。  The remainder of the total change with respect to the threshold value: the degree is small, and the sensitivity is high.
発明の開示 - 本発明はかかる背景に鑑みて、 加爇室内の温度に俵存せず安 定で確実な自動加熱を実現する自動加熱装置を提供するもので DISCLOSURE OF THE INVENTION-In view of such a background, the present invention provides an automatic heating device that realizes stable and reliable automatic heating without the presence of a temperature in a heating chamber.
¾)る ¾)
上記目的を達するため、 本発明は ¾熱室の初期温度が高い場 合、 蒸気に反応するセ ンサではセ ンサによ 検出される量が抵 下するため、 セ ンサによ 検出される量と比較して加熱状態を 判定する所定値と、 全加熱時間を決定する定数とを加熱室の初 期温度によ って変化させる構成である。 したがって加熱室内の 加熱開始時の温度がどのよ う ¾温度であつても例え 湿度セ ン サは被加熱物から発生するわずか 水蒸気量を検出することがで き、 自動加熟調理の失敗を防止し、 ^に仕上 ]?のよい自動加熱 調理をすることができ る。 — — In order to achieve the above object, the present invention relates to the following: (1) When the initial temperature of the heat chamber is high, the amount detected by the sensor in the sensor reacting to steam is reduced, and thus the amount detected by the sensor is reduced. In this configuration, a predetermined value for judging the heating state by comparison and a constant for determining the total heating time are changed according to the initial temperature of the heating chamber. Therefore, regardless of the temperature at the start of heating in the heating chamber, the humidity sensor can detect the slight amount of water vapor generated from the object to be heated, preventing the failure of automatic ripening cooking. Then, it is possible to perform automatic heating cooking with a good finish. — —
図面の簡単 ¾説明 Brief description of drawings
第 1 図は本発明の一実施例である自動加熱装置の外観斜視図、 第 2図は同構成プロ ッ ク図、 第 3図は従来の加熱装置における 加熱室内の相対湿度の変化を示し、 その制御方式を模式的に示 した鎳図、 第 4図は本発明の一実旌例である制御方式を示した 線図、 第 5図は本発明の他の実施例である制御方式を示した線 図、 第 6図は実際のセ ンサによ!)検出される電圧波形を示す図 で、 (a)は湿度セ ンサを、 (b)はガスセ ンサをそれぞれ示している。 第ァ図は制御部の機能ブロ ッ ク図である。  FIG. 1 is an external perspective view of an automatic heating device according to an embodiment of the present invention, FIG. 2 is a block diagram of the same configuration, and FIG. 3 shows a change in relative humidity in a heating chamber in a conventional heating device. Fig. 4 schematically shows the control method, Fig. 4 is a diagram showing a control method which is an example of the present invention, and Fig. 5 shows a control method which is another embodiment of the present invention. Figure 6 shows the actual sensor! 5) Diagrams showing detected voltage waveforms, where (a) shows a humidity sensor and (b) shows a gas sensor. FIG. 3 is a functional block diagram of the control unit.
発明を実施するための最良の形態 BEST MODE FOR CARRYING OUT THE INVENTION
以下、 図面に従って本発明の構成を説明する  Hereinafter, the configuration of the present invention will be described with reference to the drawings.
第 1 図は本発明に係る自動加熱装置の本体斜視図である。 本 体 1の前面には扉体 2が開閉自在に装着され、 操作パネ 3が 配されている。 この操作パネ 3上には、 被加熱物に応じた加 熱シーケンスを選択するためのキーボー ド 4 と、 種々の報知を 行うための表示部 5とが少る ぐ とも設けられている。 -- 第 2図はかかる加熱装置の制御プロ ブ ク図を示す。 加熱室 6 内には被加熱物 7が載置され、 加熱源としてマグネ ト ロ ン 8が 結合されている。 マグネ ト ロ ン Bは制御部 9によ 耠電を制御 される。 制御部 9の詳釉 ¾構成については後述する c 1 Oは湿 度セ ンサもしくはガ ス セ ンサであ 、 フ ァ ン 1 1 によ 排気さ れた被加熱物了よ の水蒸気 ,ア コ ール ,炭羧ガ ス どの気 体 1 2を検出する。 1 3はサ ー ミ スタの如き温度検知手段で、 加熱室内の温度を測定する。 剞衝部 9はかかる検出データをも とに、 マグネ ト ロ ン 8への給電を制御し、 表示都 5へ種 のデ ータを表示させ、 ス ピーカ も しくはブザー 1 4によつて合成音 声あるいはブザー音でさまざま 報知 ,警告を発する。 FIG. 1 is a perspective view of the main body of the automatic heating device according to the present invention. A door 2 is attached to the front of the main body 1 so as to be openable and closable, and an operation panel 3 is provided. The operation panel 3 is provided with at least a keyboard 4 for selecting a heating sequence in accordance with an object to be heated, and a display unit 5 for performing various notifications. -Figure 2 shows a control block diagram of such a heating device. An object 7 to be heated is placed in the heating chamber 6, and a magnetron 8 is connected as a heating source. The power of the magnetron B is controlled by the control unit 9. Details of the control unit 9 ¾ The configuration will be described later. C 1 O is a humidity sensor or a gas sensor, and the water vapor and the air discharged from the object to be heated exhausted by the fan 11 Gas, charcoal gas, etc. which gas 12 is detected. 13 is a temperature detecting means such as a thermistor for measuring the temperature in the heating chamber. Based on the detected data, the enemy unit 9 controls the power supply to the magnetron 8 and sends some data to the display city 5. Display various warnings and warnings with a synthesized voice or a buzzer sound using the speaker or buzzer 14.
さてかかる構成によ 制御部 9がいかるる動作をするかにつ いて述べる。 従来方式の第 3図についてはすでに記述した。 要 は同じ被加熱物から同量の水蒸気が発生したとしても、 そのと きの加熱室内の温度によつて相対湿度の変化量は大き く異¾つ てくる、 ということであった。 本発明は加熱室内の温度をモニ タすることによって、 蒸,気発生点を安定かつ確実にとらえ、 加 熱室内の温度に依存し ¾いセ ンサによる自動如熱を実現するも のである。  Now, the operation of the control unit 9 with such a configuration will be described. Fig. 3 of the conventional method has already been described. The point is that even when the same amount of water vapor is generated from the same object to be heated, the amount of change in the relative humidity varies greatly depending on the temperature in the heating chamber at that time. The present invention monitors the temperature in the heating chamber, thereby stably and surely ascertaining the point at which steam or gas is generated, and realizes automatic heating by a sensor that depends on the temperature in the heating chamber.
第 4図は本発明にもとづく蒸気髡生点の検出方式を示す線図 である。 制御部 9はまずサ — ミ スタ 1 3によ 加熱室内の温度 を測.定する。 かかる測定は全加熱時間を通して行えば、 正確 ¾ 制御ができることはもちろんであるが、 少¾ く とも加熱開始時 点あるいは P1点、 もしくは蒸気発生点 P2点のいずれか一点での 測定でも本髡明の目的は達しう る。 -- さてこの.ようにして測定された温度をも とに制御部 9はその 温度に対応するしきい値 をシ ス テ ム内にブリ セッ トする。 す ¾わち〔1〕の場合には が、 これよ 高温の〔2〕の場合には よ 小さ しきい値 " 2 がブリ セ 'ノ トされる。 このことによ 蒸気検出点 Ρ 2 および P 2 ' 点を一致させることができる。 よつ て全加熱時間を温度によらず安定に決定しうる。 また高温時の しきい値と篛変化量との余裕度も十分にとれ、 セ ンサ不感を防 止でき る。 FIG. 4 is a diagram showing a method for detecting a steam generation point based on the present invention. The control unit 9 first measures the temperature in the heating chamber using the thermistor 13. By performing through such measurements are total heating time, the but of course that it is precisely ¾ control, also measured at any single point of heating start point or P 1 point, or vapor generated point P 2 points even rather small ¾ The purpose of the explanation can be reached. -Now, based on the temperature measured in this way, the control unit 9 resets a threshold value corresponding to the temperature in the system. In other words, in the case of [ 1 ], the threshold value “2” is smaller than that in the case of the higher temperature [ 2 ]. As a result, the steam detection points Ρ2 and The P 2 'point can be matched, so that the total heating time can be determined stably irrespective of the temperature, and there is sufficient margin between the threshold value and the amount of change at high temperature, and the sensor You can prevent insensitivity.
お本実 ¾例は加熱室内の温度にかかわ く、 被加熱物 • の分量によ 安定した全加熱時間が決定できる搆成を示したが、 実際には加熱室内の温度が高ければ被加熱物はこの雰囲気温度 からも熱エネルギーを供耠される。 このため全加熱時間はむし ろ若干短かくて い。 これ 《2 をよ ^小さく設定することで 5 実現できる。 つま D蒸気発生点 P 2' 点を第 4図よ ]? もさらに前 にとるわけで、 時間を短かくでき、 つて全加熱時間を短縮 補正できる。 In this example, regardless of the temperature inside the heating chamber, • Although the total heating time can be determined stably by the amount of, the object to be heated is supplied with heat energy from this ambient temperature if the temperature inside the heating chamber is high. For this reason, the total heating time is rather short. This can be achieved by setting 《 2 less than ^^. That is, the point of D vapor generation point P 2 'point in Fig. 4] is also taken earlier, so that the time can be shortened and the total heating time can be shortened and corrected.
ところが、 セ ンサの特性が高温において接端に感度が低下す るものであった場合、 第 5図に示すよ うに、 相対湿度の変化が t o 非常に少るぐ る。 しきい値 は小さくするにも限度があ i?、 な 3 とした場合、 P2点と P 点を一致させることは不可能と るる。 従 て、 T1時間は長ぐ 過ぎ逼加熱と る。 そこで、 全加熱時間を決定する定数 Hを小さく してやれぱ過加熱を防止 することができる。 However, when the sensor characteristics are such that the sensitivity decreases at the contact end at high temperatures, the change in relative humidity is very small as shown in Fig. 5. Is there a limit to reducing the threshold i? In the case of 3, it is impossible to match point P 2 with point P. Therefore, T 1 hour is too long and the heating is tight. Therefore, the constant H that determines the total heating time can be reduced, and overheating can be prevented.
15 他の実施例を次に示す。 加熱室の温度がしきい値と綏変化量 との余裕度が十分にある領域においては、 しきい値なを変化さ せる必要は く、 全加熱時間を決定する定数 Rを変化させて全 加熱時間の補正を行っても良い。 定数 Bは食品固有の定数であ JD . 加熱室が高温の場合でもきめ弒かく選択することが可能と15 Another embodiment is shown below. In a region where the temperature of the heating chamber has a sufficient margin between the threshold value and the amount of change, it is not necessary to change the threshold value. The time may be corrected. Constant B is a constant peculiar to food. JD. It can be selected even when the heating chamber is at high temperature.
20 ¾ 1)全加熱時間をよ 安定することができる。 20 ¾ 1) The total heating time can be more stable.
さ らに加熱室内が高温に ¾ると、 例えば電熟ヒータ とマイク 口波との複合型の加熱装置、 いわゆるオ ー ブン レン ジ どでは、 ヒ一タ便用直後の加熱室内の温度は 2 5 0〜3 0 Q eCにも達す るが、 かかる状態ではしきい値 が gめて小さ 値と る。 よ 25 つてセ ンサあるいはその検出回路にノィ ズが乗ると誤検出しゃ — T — Furthermore, when the temperature in the heating chamber becomes high, for example, in a combined heating device of an electro-mature heater and a microphone mouthpiece, so-called oven range, the temperature in the heating chamber immediately after the use of a heater flight is 2 5 0 to 3 0 Q e is reached in C, but the threshold is g Umate small value DOO Ru in such a state. If the sensor or its detection circuit receives noise, — T —
• すく る。 そこで本発明ではセ ンサあるいはその検出回路が不 能と る温度をホ ッ ト レべノレと して定め、 サ ー ミ スタによる温 度測定の際にかかるホ つ ト レべノレが検出されれば加熱を開始し い、 あるいは加熱中であれば加熱源への^電を停止させて加 熟を中断する安全回路を備えている。 かかるセ ン サの不能は表 示手段への表示、 あるいは音声合成手段によるス ピ ー カ 1 4へ の合成音声報知などによ 、 使用者に知らしめられる。 • Get it. Therefore, in the present invention, the temperature at which the sensor or its detection circuit becomes ineffective is determined as a hot level, and the hot level at the time of temperature measurement by a thermistor is detected. If a heating circuit is started, or if heating is in progress, a power supply to the heating source is stopped, and a safety circuit is provided to stop ripening. The inability of the sensor is notified to the user by a display on the display means or a notification of the synthesized voice to the speaker 14 by the voice synthesis means.
第 6図は実際にセ ンサによ 1?検出されるセ ンサ検出電圧 S Ε の電圧波形を示し、 (a)は湿度セ ンサを、 (b)はガス セ ンサを各 表わしている。 湿度セ ンサによ 検出される相対湿度 R Hは第 FIG. 6 shows the voltage waveform of the sensor detection voltage S 1 actually detected by the sensor, where (a) shows the humidity sensor and (b) shows the gas sensor. The relative humidity R H detected by the humidity sensor is
4図で説明したものと同じ変化を見せてお |) 、 つけ加えるべき ものは い。 ガ スセ ンサについては、 このグラ フはセ ンサのィ ンビーダ ン スの変化を直読するものであるが、 やは 高温に ると相対湿度の変化が小さ く ¾るため、 検出値の変化量が小さ くるっていることがわかる。 よって本発明のごと く しきい値 を加熱室の温度に応じて制御すれば、 良好 ¾自動加熱を実現し うる。 Showing the same changes as described in Figure 4) |), there is nothing to add. For gas sensors, this graph is a direct reading of the change in sensor impedance, but at high temperatures the change in the detected value is small because the change in relative humidity is small. You can see that it is small. Therefore, if the threshold value is controlled according to the temperature of the heating chamber as in the present invention, good automatic heating can be realized.
おしきい値 は本実施例の如く絶対値であつてもよいし、 The threshold value may be an absolute value as in this embodiment,
Ρ1点と Ρ2点 の電圧比の如く相対値であってもよい。 It may be a relative value such as a voltage ratio between Ρ 1 point and Ρ 2 point.
さて以上のよう 制御方式をいかに実現するか、 その制御部 の具体的 構成について次に詳述する。 第ァ図は制御部 9の機 能的る構成を示すブロ ック図である。 セ ン サ 1 Οによ 検出さ れたア ナ口グ量は A Z D コ ンバータ 1 5によ デジタノレ量に変 換され、 V1検出器 1 6およびレべ ノレコ ンパ レータ 1 7に入力さ れる。 V1検出器 1 6は P1点のレ べノレを検出するブロ ックで、 湿 • 度セ ンサな ら最小値を、 ガスセ ンサ ら最大値を各 検出し、 Now, how to implement the control method as described above, the specific configuration of the control unit will be described in detail below. FIG. 4 is a block diagram showing a functional configuration of the control unit 9. Se emissions Sa 1 Anal port grayed amount I detected in Ο is converted to Dejitanore amount by the AZD converter 1 5, is input to the V 1 detector 1 6 and leveled Noreko damper rater 1 7. V 1 detector 1 6 is a block to detect the leveling Norre of P 1 point, humidity • Detects the minimum value from the temperature sensor and the maximum value from the gas sensor.
V1保持レ ジスタ 1 Sヘス ト ァする。 具体的には 検出器 1 6は V 1 holding register 1 S is restored. Specifically, detector 16
V1保持レジスタ 1 Sの値をまず読み出し、 新デ ータとの比較を して V1保持レ ジス タ 1 8へ p V1値の更新を司る。 Read First, the value of V 1 holding register 1 S, responsible for the update of the p V 1 value to the V 1 holds Les Soo data 1 8 by a comparison of the new data.
—方、 サ ーミ スタ 1 3は加熱室内の温度を測定し、 A ZDコ ン バータ 1 9へア ナ!?グ量として入力する。 コ ンノ 一タ 1 9はこれをデジタ ノレ量 T M Pに変換し、 な セ レ ク タ 2 0によ i?対応するしき い慷 n を レジス タ 2 1 よ 読み出して、 レ ベノレコ ンゾく レータ 1 7へと入力する。 コ ンノ ータ 1 9は セ ン サ不能レべ ノレを検知する機能をも有し、 H O T信号を出力 する。 On the other hand, the thermistor 13 measures the temperature in the heating chamber, and the AZD converter 19 is used for the measurement! ? Input as the amount of data. The converter 19 converts this into a digital storage amount TMP, reads out the corresponding useful n from the register 21 by means of the selector 20 and reads the corresponding useful n from the register 21, and reads the value from the register 21. Enter 7 The controller 19 also has a function of detecting an unsensorable level and outputs a HOT signal.
さてレベ ル コ ン パ レータ 1 了は コ ンノくータょ ^入力さ By the way, the level comparator 1 is
' れたセ ンサ情報を前述の V1値と比較し、 セ レク タ 2 0よ 入 力された所定のしきい値 η を越えたかどうかの判定をする。'Compare the obtained sensor information with the above-mentioned V 1 value, and determine whether or not the predetermined threshold value η input from the selector 20 has been exceeded .
5 す わち Ρ2点の検出を行う。 Ρ2点に達すれぱ H D Τ信号を出 5 That is, Ρ two points are detected.ぱ When 2 points are reached ぱ HD signal
力する。  Power.
H D Τ信号が出力されるとァ ッブカ ウ ン タ 2 2によるク ロ ッ クの計数は停止する。 そしてァ ッ ブカ ウ ンタ 2 2によ つて計数 された 時間は、 乗算器 2 3へ入力さ 追加加熱時間 Rn'T1When the HD Τ signal is output, clock counting by the web counter 22 stops. And § Tsu Buka cormorant printer 2 2 by connexion counted time, the multiplier 2 3 input of additional heating time Rn'T 1 to
0 算出されてダウ ンカ ウ ン タ 2 4ヘプ セッ トされる。 0 Calculated and set 24 downcounters.
定数 Rn はキーボー ド4によ 選択されたメニューと加熱室 内の温度をデジタ ノレ量に変換した値 T M P との組み合せに対応 した値が Rセ レ ク タ 2 5によ R レジス タ 2 6内よ |¾み出さ れ、 乗算器 2 3へと入力される。The value corresponding to the combination of the menu selected by the keyboard 4 and the value TMP obtained by converting the temperature in the heating chamber into a digital amount is stored in the R register 26 by the R selector 25. The signal is extracted and input to the multiplier 23.
5 さて一方、 マグネ ト ロ ン Sへの耠電はス ター トキーが押され _ 5 On the other hand, the power supply to the magnetron S is pressed by the start key _
OMPI • た直後からフ リ ッ プフ ロ ッ プ 2 ァによ 開始される。 2 8はマ グネ ト ロ ン 8を動作させる駆動回路である。 フ リ ッ ブフ 口 ッブ 2 7は追加熱モ ー ドに移行し、 ダウ ンカ ウ ンタ 2 4の内容がゼ 口に: 5:つたことがデコーダ 2 9によ ]?検出された時点、 す わ 5 ち P 2. 点よ Rn - T i時間が経過したとき、 Z E R O信号によ リ セッ 卜されて加熱を終了させる。 また A Z D コ ンバ ータ 1 9 , によ H 0 T信号が出力された時点、 す わち加熱室の温度が セ ンサ不能レベ を越えたときにも、 フ リ ッ プフ ロ ッ プ 2 7は リ セ ッ 卜され、 加熱を禁止も しくは中断させる。 OMPI • Immediately after being started by a flip-flop. Reference numeral 28 denotes a drive circuit for operating the magnetron 8. The flip-flop 27 shifts to the additional heating mode, and when the content of the down counter 24 is detected at the outlet: 5: Detachment is detected by the decoder 29]. i 5 Chi P 2 points by Rn -. when the T i time has elapsed, terminate the heating is Bok by re set to ZERO signal. The time of AZD co Nba over data 1 9, I H 0 T signal is output, even when the temperature of the to Wachi heating chamber exceeds the sensor impossible level, full re Tsu Pufu Lock flop 2 7 Resets and prohibits or interrupts heating.
かかる H O T信号は表示部 5および音声合成手段たるシ ンセ サ イザ S Oにも入力され、 表示および合成音声の形で使用者に 警告が行われる。  The HOT signal is also input to the display unit 5 and the synthesizer S0 as a voice synthesizing unit, and a warning is issued to the user in the form of a display and a synthesized voice.
以上述べたよ うに第 7図に示す制御部によ 本発明を実現で きる。 また第 7図の各機能ブロ ッ クはプロ グラ ムによるソ フ ト 口 ジックに置換でき、 その大半をマイク ロコ ン ビュ一タの女口き ス トア ドロジッ ク ' コ ン ト口 ラによ 実 ¾できることは当然 である。  As described above, the present invention can be realized by the control unit shown in FIG. In addition, each function block in Fig. 7 can be replaced by software-based software logic, and most of the functions are implemented by a micro-computer female storage logic controller. ¾It is natural that we can do it.
産業上の利用可能性  Industrial applicability
さて以上説明したよ うに本発明によれば、 加熱室内の温度に 依存せず安定で確実 セ ンサを備えた自動加熱装置が実現でき る。 また高温時にもしきい値と総変化量との余裕度を十分にと れ、 セ ンサ不惑を防止できる。 従って、 電子レンジ , 電気ォ— ブン どの加熱調理器に広ぐ利用することができるものである。  As described above, according to the present invention, an automatic heating apparatus having a stable and reliable sensor independent of the temperature in the heating chamber can be realized. Also, even at high temperatures, the margin between the threshold value and the total variation can be sufficiently provided, and sensor confusing can be prevented. Therefore, it can be widely used in heating cookers such as microwave ovens and electric ovens.
0Λ1ΡΙ 0Λ1ΡΙ

Claims

請 求 の 範 囲  The scope of the claims
被加熱物を載置する加熱室と、 前記加熱室に結合された加 熱源と、 前記加熱源への給電を制御する制御部と、 前記被加 熱物が発する水蒸気 , ァノレコ一ノレあるいは炭酸ガスるどを検 出するセ ンサと、 前記加熱室の温度を測定する温度検知手段 と、 前記センサによ!?検出される量をある所定値と比較する 比較手段と、 前記セ ンサによ 検出される量がある所定値に 達した後連続して加熱される時間をある定数によ 決定する 時間制御手段とによ 1?構成され、 前記制御部は前記温度検知 手段によ 直接もしくは間接的に検出された前記加熱室の温 度に応じて、 前記比較部の基準と る所定値と、 前記時間制 御部で加熱時間を決定する定数とを変化することを特徵とす るセ ンサを備えた加熱装置。  A heating chamber on which the object to be heated is placed; a heating source coupled to the heating chamber; a control unit for controlling power supply to the heating source; water vapor generated by the object to be heated; A sensor for detecting a throat, temperature detecting means for measuring the temperature of the heating chamber, and the sensor! ? Comparison means for comparing the detected amount with a certain predetermined value; and time control means for determining the time for continuous heating after the amount detected by the sensor reaches a certain predetermined value by a certain constant. The control unit is configured to determine a reference value of the comparison unit and the time control in accordance with the temperature of the heating chamber detected directly or indirectly by the temperature detection unit. A heating device provided with a sensor characterized in that a constant that determines a heating time is changed in a section.
請求の範囲第 1 項において、 比較部の基準と ¾る所定値の みを変化させることを特徴とするセンサを備えた加熱装置。  2. The heating device according to claim 1, further comprising a sensor that changes only a predetermined value that is a reference of the comparison unit.
請求 範 ffl第 1 項において、 時間制御部で加熱時間を決定 する定数のみを変化させることを特徵とするセ ンサを備えた 加熱装置。  Claim 1. The heating device according to claim 1, further comprising a sensor characterized in that only the constant for determining the heating time is changed by the time control unit.
請求の範囲第 1項において、 温度検知手段によ 加熱室の 温度が高いことが測定された際には、 前記制御部は前記比較 部の基準と る所定値をよ 小さく変化させること 特羧と するセ ンサを備えた加熱装置。  In claim 1, when the temperature detecting means measures that the temperature of the heating chamber is high, the control unit changes the reference value of the comparison unit to a smaller value. A heating device equipped with a sensor.
請求の範囲第 1項において、 温度検知手段によ ]3制御部は 加熱室の温度を少 くと も 3 レベルに分別し、 最高レベルの しきい値をセ ンサが不能と るレベルに略一致させ、 前記温 度 レべノレが検出された折には、 前記制御部が加熱源への耠電 を禁止あるいは中断することを特徵とするセ ンサを備えた加 請求の範囲第 4項において、 セ ンサの不能を報知せしめる 表示手段、 あるいは音声合成手段等の ¾知手段を備えること を特徵とするセ ンサを備えた加熟装置。 In claim 1, according to the temperature detecting means] 3 The control unit classifies the temperature of the heating chamber into at least three levels, and the highest level threshold substantially matches the level at which the sensor cannot be used. Let the temperature 5. The sensor according to claim 4, further comprising a sensor characterized in that the control unit prohibits or interrupts the supply of electric power to the heating source when a level is detected. A ripening apparatus provided with a sensor that is provided with a display means for notifying the user or a notification means such as a voice synthesis means.
WiPo WiPo
PCT/JP1982/000272 1981-07-20 1982-07-16 Heater with sensor WO1983000374A1 (en)

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Application Number Priority Date Filing Date Title
AU86866/82A AU8686682A (en) 1981-07-20 1982-07-16 Heater with sensor

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP11399681A JPS5813925A (en) 1981-07-20 1981-07-20 Composite heater
JP56/113996810720 1981-07-20

Publications (1)

Publication Number Publication Date
WO1983000374A1 true WO1983000374A1 (en) 1983-02-03

Family

ID=14626441

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1982/000272 WO1983000374A1 (en) 1981-07-20 1982-07-16 Heater with sensor

Country Status (2)

Country Link
JP (1) JPS5813925A (en)
WO (1) WO1983000374A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0375148A2 (en) * 1988-11-17 1990-06-27 Praxair S.T. Technology, Inc. Production of molded refractory shapes
US5078048A (en) * 1988-08-03 1992-01-07 Matsushita Electric Industrial Co., Ltd. Cooking apparatus including a pyroelectric vapor sensor

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0833206B2 (en) * 1987-01-09 1996-03-29 株式会社東芝 Cooking device

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52101743A (en) * 1976-02-20 1977-08-26 Matsushita Electric Ind Co Ltd Cooking voen
JPS5472538A (en) * 1977-11-21 1979-06-11 Matsushita Electric Ind Co Ltd Heating cooker
JPS55111096A (en) * 1979-02-21 1980-08-27 Matsushita Electric Ind Co Ltd High freouency heater with oven

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5483148A (en) * 1977-12-15 1979-07-03 Matsushita Electric Ind Co Ltd Cooking oven
JPS5495041A (en) * 1978-01-13 1979-07-27 Matsushita Electric Ind Co Ltd Heat controlling device
JPS5640029A (en) * 1979-09-07 1981-04-16 Matsushita Electric Ind Co Ltd Method and apparatus for controlling food heating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52101743A (en) * 1976-02-20 1977-08-26 Matsushita Electric Ind Co Ltd Cooking voen
JPS5472538A (en) * 1977-11-21 1979-06-11 Matsushita Electric Ind Co Ltd Heating cooker
JPS55111096A (en) * 1979-02-21 1980-08-27 Matsushita Electric Ind Co Ltd High freouency heater with oven

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5078048A (en) * 1988-08-03 1992-01-07 Matsushita Electric Industrial Co., Ltd. Cooking apparatus including a pyroelectric vapor sensor
EP0375148A2 (en) * 1988-11-17 1990-06-27 Praxair S.T. Technology, Inc. Production of molded refractory shapes
EP0375148A3 (en) * 1988-11-17 1991-05-08 Praxair S.T. Technology, Inc. Production of molded refractory shapes

Also Published As

Publication number Publication date
JPS5813925A (en) 1983-01-26

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