WO1982001737A1 - Method of treating oil-contaminated drill muds or cuttings prior to reuse or disposal - Google Patents

Method of treating oil-contaminated drill muds or cuttings prior to reuse or disposal Download PDF

Info

Publication number
WO1982001737A1
WO1982001737A1 PCT/GB1981/000252 GB8100252W WO8201737A1 WO 1982001737 A1 WO1982001737 A1 WO 1982001737A1 GB 8100252 W GB8100252 W GB 8100252W WO 8201737 A1 WO8201737 A1 WO 8201737A1
Authority
WO
WIPO (PCT)
Prior art keywords
oil
solvent
solids
stream
contaminated
Prior art date
Application number
PCT/GB1981/000252
Other languages
French (fr)
Inventor
Ltd Harpsound
Original Assignee
Moir James A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Moir James A filed Critical Moir James A
Publication of WO1982001737A1 publication Critical patent/WO1982001737A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B9/00General arrangement of separating plant, e.g. flow sheets
    • B03B9/02General arrangement of separating plant, e.g. flow sheets specially adapted for oil-sand, oil-chalk, oil-shales, ozokerite, bitumen, or the like
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B21/00Methods or apparatus for flushing boreholes, e.g. by use of exhaust air from motor
    • E21B21/06Arrangements for treating drilling fluids outside the borehole
    • E21B21/063Arrangements for treating drilling fluids outside the borehole by separating components
    • E21B21/065Separating solids from drilling fluids
    • E21B21/066Separating solids from drilling fluids with further treatment of the solids, e.g. for disposal
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B21/00Methods or apparatus for flushing boreholes, e.g. by use of exhaust air from motor
    • E21B21/06Arrangements for treating drilling fluids outside the borehole
    • E21B21/068Arrangements for treating drilling fluids outside the borehole using chemical treatment
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B41/00Equipment or details not covered by groups E21B15/00 - E21B40/00
    • E21B41/005Waste disposal systems

Definitions

  • This invention relates to the treatment of oil-contaminated drill solids, e.g. drilling muds or drill cuttings prior to reuse or disposal.
  • Oil-based muds are also preferred since, in general, they permit higher drilling rates, and also they facilitate drilling at an angle to the vertical, for example, when drilling inclined well bores which may be at anything up to 50° or 60° from the vertical or more.
  • the drill cuttings from such operations present a disposal problem because of the oil contamination.
  • the hydrocarbon values in such oil-contaminated drill cuttings are proposed to be removed by a combination of vacuum distillation and grinding by heating the cuttings under reduced pressure in a pressure vessel equipped with means for milling or shearing the drill cuttings during the heating process.
  • oil contaminated drill cuttings are passed on a conveyor belt through a preheater for partial drying and then to a high-intensity infrared heating chamber in which the volatile hydrocarbons are expelled from the cuttings at a surface temperature higher than the combustion point of petroleum.
  • the oil content of oil-contaminated drill cuttings can be economically and efficiently reduced to permitted levels by washing the oil-contaminated drill cuttings, preferably after screening to remove fines and supernatant drilling mud which can be re-used, with a single solvent system consisting of a haiogenated hydrocarbon such as carbon tetrachloride or 1,1,1-trichioroethane, and centrifuging the washed cuttings to remove the oil-solvent solution, which can be recycled to the washing process and/or distilled to recover the washing solvent and an oil residue which can be recycled to the drilling process.
  • a haiogenated hydrocarbon such as carbon tetrachloride or 1,1,1-trichioroethane
  • the method of the invention is also applicable to the recovery of the drilling mud itself, particularly drilling muds which are weighted with barytes. Because of the cost element, the recovery of the barytes for reuse can be an important factor in the economics of subterranean and submarine drilling operations, and the present invention provides a simple efficient and economic way in which this can be done.
  • the separated drilling mud can be treated in essentially the same way, for example, by initial screening or centrifuging to separate out the mud solids, and removing from the separated mud solids decontaminating oil by washing with the halohydrocarbon and centrifuging in the manner described.
  • oil-contaminated drill cuttings which have been screened to remove surplus oil-based fluids and fines for re-use in the drilling operation are passed via line 1 to a mixing tank 2. If desired a portion of the separated fines may also be passed to the tank.
  • the cuttings are contacted with an organic haiohydrocarbon solvent washing liquid, preferably 1,1,1-trichloroethane, fed from a storage tank 12.
  • an organic haiohydrocarbon solvent washing liquid preferably 1,1,1-trichloroethane
  • a recycle stream of macerated slurry is fed via line 4 from the macerator 3 to the tank 2 to maintain a desirable solids concentration in the tank.
  • the main stream of macerated slurry is fed from macerator 3 via line 5 to a continuously running decanter centrifuge 6.
  • Substantially oil-free cuttings are withdrawn from the centrifuge 6 via line 7 for disposal whilst separated oil/solvent washing liquid is withdrawn via line 8. This may be recycled via line 9 to the washing tank 2 whilst a slip stream is taken off via line 10 to a distillation unit II for recovery of the solvent which is returned to the solvent storage tank 12 for re-use and separation of the oil residue via line 13.
  • the oil residue separated via line 13 will contain a proportion of fines and also substantial amounts of the chemical additives added to the original drilling mud and can either be collected for disposal, treated for further recovery of one or more components and/or returned to the drilling operation for use as recycle oilbased drilling mud.
  • the decontaminated drill cuttings withdrawn via line 7 are in a dry, non-sticky friable powder form suitable for pneumatic transportation in a carrier gas, e.g. air stream, to a disposal point.
  • a carrier gas e.g. air stream
  • the decontaminated cuttings can simply be dumped overboard since oil-contamination levels of cuttings treated in accordance with the present invention is well below the minimum standards imposed by government regulations.
  • the preferred embodiment of the invention at least, provides a substantially closed cycle for the recovery and reprocessing of the oil-based drilling mud, whilst at the same time substantially solving the disposal problems of the oil-contaminated drill cuttings.
  • the above described method and apparatus can readily be adapted for the recovery of the mud solids themselves, e.g. the barytes used in weighied drilling muds.

Landscapes

  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Mining & Mineral Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • Physics & Mathematics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

Oil contaminated drilling solids, e.g. drilling muds and drill-cuttings, are decontaminated prior to reuse or disposal by washing with a halohydrocarbon e.g. 1,1,1-trichloroethane.

Description

Method of treating oil-contaminated drill muds or cuttings prior to reuse or disposal.
This invention relates to the treatment of oil-contaminated drill solids, e.g. drilling muds or drill cuttings prior to reuse or disposal.
In subterranean and marine drilling operations using water-based drilling mud, the disposal of the driil cuttings presents little problem from the environmental or ecological point of view. In land-based operations they can be dumped or used as land in-fill at any convenient site, and in marine operations they can be dumped overboard from the drill platform for distribution over the sea bed by tidal currents. However, in many drilling operations, for example, in drilling through shale high in montmoriilonite, which undergoes expansion when contacted by an aqueous drilling mud, it is preferred to use an oil-based drilling mud, containing for example, a substantial amount of diesel oil. Oil-based muds are also preferred since, in general, they permit higher drilling rates, and also they facilitate drilling at an angle to the vertical, for example, when drilling inclined well bores which may be at anything up to 50° or 60° from the vertical or more. However, the drill cuttings from such operations present a disposal problem because of the oil contamination.
Various proposals have been made for the treatment of such oilcontaminated drill cuttings prior to disposal ranging from incineration, which is costly, and detergent washing, which is often not sufficiently effective to meet statutory requirements governing the disposal of oil-contaminated waste, or at least not at economic levels of operation.
In one such method, disclosed in European Patent Application Publication No. 0005273, the hydrocarbon values in such oil-contaminated drill cuttings are proposed to be removed by a combination of vacuum distillation and grinding by heating the cuttings under reduced pressure in a pressure vessel equipped with means for milling or shearing the drill cuttings during the heating process. In another method disclosed in U.S. Patent No. 3 693 951 oil contaminated drill cuttings are passed on a conveyor belt through a preheater for partial drying and then to a high-intensity infrared heating chamber in which the volatile hydrocarbons are expelled from the cuttings at a surface temperature higher than the combustion point of petroleum.
The detergent washing of drilling cuttings is disclosed in U.S. Patents 3 693 733 and 3 860 019.
Yet another approach is adopted in U.5. Patent No. 4 040 866. In this proposal oil-contaminated drill cuttings are processed to remove the contaminating oil by contacting the cuttings with a mixed solvent system consisting of ethylenegiycoi monoisobutyl ether, diethylenegiycol monobutyi ether acetate, ethyl butyl ketone, ethylenegiycoi monobutylether, ethylenegiycol monom ethyl ether acetate, diethylene giycol diethyl ether or diethylene giycol mono-n-hexyl ether as the first component and paraffin oil as the second component in relative proportions of from 10:90 to 80:20. The resultant oil-solvent mixture which forms on the cuttings is readily removable by centrifuging or washing, e.g. with sea water, or a combination of the two.
In accordance with the present invention it has been found that the oil content of oil-contaminated drill cuttings can be economically and efficiently reduced to permitted levels by washing the oil-contaminated drill cuttings, preferably after screening to remove fines and supernatant drilling mud which can be re-used, with a single solvent system consisting of a haiogenated hydrocarbon such as carbon tetrachloride or 1,1,1-trichioroethane, and centrifuging the washed cuttings to remove the oil-solvent solution, which can be recycled to the washing process and/or distilled to recover the washing solvent and an oil residue which can be recycled to the drilling process.
Moreover, it has been found that washing with a single haiogenated hydrocarbon solvent, particularly, 1,1,1-trichloroethane, reduces the drill cuttings to a dry non-sticky, easily friable form which greatly facilitates subsquent transportation and dumping of the decontaminating cuttings. Thus, for example, it has been found that such decontaminated cuttings can be readily transported pneumatically by entrainment in a carrier gas stream, e.g. air. Such cuttings can therefore be readily and easily pipelined away from the drilling platform for dumping at a location remote from the drilling operation. Whilst the invention is particularly described with reference to the decontamination of oil-contaminated drill cuttings prior to disposal, the method of the invention is also applicable to the recovery of the drilling mud itself, particularly drilling muds which are weighted with barytes. Because of the cost element, the recovery of the barytes for reuse can be an important factor in the economics of subterranean and submarine drilling operations, and the present invention provides a simple efficient and economic way in which this can be done. Thus, after screening to remove the cuttings for further decontamination treatment as described, the separated drilling mud can be treated in essentially the same way, for example, by initial screening or centrifuging to separate out the mud solids, and removing from the separated mud solids decontaminating oil by washing with the halohydrocarbon and centrifuging in the manner described.
The invention will be further described with reference to the accompanying drawing in which the single figure represents a diagrammatic flow sheet of a preferred method of treating oil-contaminated drill cuttings in accordance with this invention.
Referring to the drawings, oil-contaminated drill cuttings which have been screened to remove surplus oil-based fluids and fines for re-use in the drilling operation are passed via line 1 to a mixing tank 2. If desired a portion of the separated fines may also be passed to the tank. In the tank 2, the cuttings are contacted with an organic haiohydrocarbon solvent washing liquid, preferably 1,1,1-trichloroethane, fed from a storage tank 12. From the tank 2, the cuttings/solvent slurry is fed to a macerator and pump 3 which reduce the particle size of the cuttings to improve washing contact with the solvent. A recycle stream of macerated slurry is fed via line 4 from the macerator 3 to the tank 2 to maintain a desirable solids concentration in the tank. The main stream of macerated slurry is fed from macerator 3 via line 5 to a continuously running decanter centrifuge 6. Substantially oil-free cuttings are withdrawn from the centrifuge 6 via line 7 for disposal whilst separated oil/solvent washing liquid is withdrawn via line 8. This may be recycled via line 9 to the washing tank 2 whilst a slip stream is taken off via line 10 to a distillation unit II for recovery of the solvent which is returned to the solvent storage tank 12 for re-use and separation of the oil residue via line 13. The oil residue separated via line 13 will contain a proportion of fines and also substantial amounts of the chemical additives added to the original drilling mud and can either be collected for disposal, treated for further recovery of one or more components and/or returned to the drilling operation for use as recycle oilbased drilling mud.
The decontaminated drill cuttings withdrawn via line 7 are in a dry, non-sticky friable powder form suitable for pneumatic transportation in a carrier gas, e.g. air stream, to a disposal point. Alternatively, in submarine operations the decontaminated cuttings can simply be dumped overboard since oil-contamination levels of cuttings treated in accordance with the present invention is well below the minimum standards imposed by government regulations.
It will be seen therefore that the preferred embodiment of the invention, at least, provides a substantially closed cycle for the recovery and reprocessing of the oil-based drilling mud, whilst at the same time substantially solving the disposal problems of the oil-contaminated drill cuttings.
As has already been stated, the above described method and apparatus can readily be adapted for the recovery of the mud solids themselves, e.g. the barytes used in weighied drilling muds.

Claims

1. A method for the treatment of oil-contaminated solids resulting from submarine and subterranean drilling operations using oil-based drilling fluids to remove oil contamination prior to disposal or reuse of those solids which comprises washing the contaminated solids with an organic solvent to remove said oil and centrifugally separating the washed solids from the solvent, characterised in that the solvent is a haiogenated hydrocarbon.
2. A method according to claim 1, characterised in that the solvent is 1,1,1- trichloroethane.
3. A method according to claim 1 or 2, which comprises agitating the oil-contaminated solids with said solvent in a closed vessel; continuously withdrawing from said vessel a first stream comprising a slurry of said solids in said solvent and a second stream of oil-contaminated solvent; feeding said slurry to a continuously running centrifuge to separate the solids from the solvent; recycling the recovered solvent stream from the centrifuge to the agitation vessel; air drying the separated solids to remove final solvent traces; fractionating the oil-solvent stream from the agitation vessel to recover an oil stream and a solvent stream; and recycling the solvent stream to the agitation vessel.
4. A method according to claim 1, 2 or 3, characterised in that the oilcontaminated solids are oil-contaminated drill cuttings.
5.. A method according to claim 1, 2 or 3, characterised in that the oilcontaminated solids are drill mud solids.
6. A method according to claim 5, characterised in that the drill mud solids is or comprise barytes.
PCT/GB1981/000252 1980-11-21 1981-11-20 Method of treating oil-contaminated drill muds or cuttings prior to reuse or disposal WO1982001737A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8037377801121 1980-11-21
GB8037377 1980-11-21

Publications (1)

Publication Number Publication Date
WO1982001737A1 true WO1982001737A1 (en) 1982-05-27

Family

ID=10517469

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1981/000252 WO1982001737A1 (en) 1980-11-21 1981-11-20 Method of treating oil-contaminated drill muds or cuttings prior to reuse or disposal

Country Status (3)

Country Link
EP (1) EP0065532A1 (en)
AU (1) AU7808881A (en)
WO (1) WO1982001737A1 (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0136373A1 (en) * 1983-10-06 1985-04-10 FLOTTWEG-WERK DR. GEORG BRUCKMAYER GMBH & CO. KT Process for washing drill cuttings
EP0334944A1 (en) * 1987-10-05 1989-10-04 Conoco Specialty Products Inc. Apparatus and method for removing and recovering oil and/or other oil-based drilling mud additives from drill cuttings
WO1989009091A1 (en) * 1988-03-25 1989-10-05 Mellgren Steinar E Process and arrangement for treating recirculated drilling mud in drilling for oil and gas
WO1991008375A1 (en) * 1989-11-28 1991-06-13 Rig Technology Limited Method and apparatus for cleaning drill cuttings
GB2239470A (en) * 1989-11-28 1991-07-03 Rig Technology Ltd Cleaning of cuttings from drilling operations
WO1991013232A2 (en) * 1990-02-28 1991-09-05 Conoco Inc. Process and apparatus for cleaning particulate solids
WO1991014075A1 (en) * 1990-02-28 1991-09-19 Conoco Inc. Process and apparatus for cleaning particulate solids
US5107874A (en) * 1990-02-28 1992-04-28 Conoco Inc. Apparatus for cleaning particulate solids
WO1993013882A1 (en) * 1992-01-13 1993-07-22 Henkel Kommanditgesellschaft Auf Aktien Improved method of disposal of contaminated cuttings
US7867399B2 (en) 2008-11-24 2011-01-11 Arkansas Reclamation Company, Llc Method for treating waste drilling mud
US7935261B2 (en) 2008-11-24 2011-05-03 Arkansas Reclamation Company, Llc Process for treating waste drilling mud
WO2013037978A1 (en) * 2011-09-16 2013-03-21 Montanuniversität Leoben Recycling of borehole solids in polymers
CN103899262A (en) * 2012-12-28 2014-07-02 中国石油化工股份有限公司 Treating-while-drilling method for drilling cuttings of oil base of borehole

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB456422A (en) * 1934-07-14 1936-11-09 Standard Oil Dev Co Improvements relating to the treatment of hydrocarbon oils with selective solvents
US2189844A (en) * 1933-10-18 1940-02-13 Standard Oil Dev Co Treating mineral oil
FR1586065A (en) * 1967-10-24 1970-02-06
US3811614A (en) * 1973-06-05 1974-05-21 Atlantic Richfield Co Method for centrifuging of tar sands froth
US3813030A (en) * 1973-05-24 1974-05-28 Atlantic Richfield Co Method for tar sands bitumen froth treatment
US4040866A (en) * 1973-10-05 1977-08-09 N L Industries, Inc. Laundering of oil base mud cuttings
US4120775A (en) * 1977-07-18 1978-10-17 Natomas Company Process and apparatus for separating coarse sand particles and recovering bitumen from tar sands

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2189844A (en) * 1933-10-18 1940-02-13 Standard Oil Dev Co Treating mineral oil
GB456422A (en) * 1934-07-14 1936-11-09 Standard Oil Dev Co Improvements relating to the treatment of hydrocarbon oils with selective solvents
FR1586065A (en) * 1967-10-24 1970-02-06
US3813030A (en) * 1973-05-24 1974-05-28 Atlantic Richfield Co Method for tar sands bitumen froth treatment
US3811614A (en) * 1973-06-05 1974-05-21 Atlantic Richfield Co Method for centrifuging of tar sands froth
US4040866A (en) * 1973-10-05 1977-08-09 N L Industries, Inc. Laundering of oil base mud cuttings
US4120775A (en) * 1977-07-18 1978-10-17 Natomas Company Process and apparatus for separating coarse sand particles and recovering bitumen from tar sands

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0136373A1 (en) * 1983-10-06 1985-04-10 FLOTTWEG-WERK DR. GEORG BRUCKMAYER GMBH & CO. KT Process for washing drill cuttings
EP0334944A4 (en) * 1987-10-05 1991-10-09 Novatec, Inc. Apparatus and method for removing and recovering oil and/or other oil-based drilling mud additives from drill cuttings
EP0334944A1 (en) * 1987-10-05 1989-10-04 Conoco Specialty Products Inc. Apparatus and method for removing and recovering oil and/or other oil-based drilling mud additives from drill cuttings
WO1989009091A1 (en) * 1988-03-25 1989-10-05 Mellgren Steinar E Process and arrangement for treating recirculated drilling mud in drilling for oil and gas
WO1991008375A1 (en) * 1989-11-28 1991-06-13 Rig Technology Limited Method and apparatus for cleaning drill cuttings
GB2239470A (en) * 1989-11-28 1991-07-03 Rig Technology Ltd Cleaning of cuttings from drilling operations
GB2239470B (en) * 1989-11-28 1993-12-15 Rig Technology Ltd Cleaning of cuttings from drilling operations
AU644120B2 (en) * 1989-11-28 1993-12-02 Varco I/P Inc. Method and apparatus for cleaning drill cuttings
US5080721A (en) * 1990-02-28 1992-01-14 Conoco Inc. Process for cleaning particulate solids
WO1991013232A2 (en) * 1990-02-28 1991-09-05 Conoco Inc. Process and apparatus for cleaning particulate solids
US5053082A (en) * 1990-02-28 1991-10-01 Conoco Inc. Process and apparatus for cleaning particulate solids
US5107874A (en) * 1990-02-28 1992-04-28 Conoco Inc. Apparatus for cleaning particulate solids
WO1991013232A3 (en) * 1990-02-28 1991-10-03 Conoco Inc Process and apparatus for cleaning particulate solids
WO1991014075A1 (en) * 1990-02-28 1991-09-19 Conoco Inc. Process and apparatus for cleaning particulate solids
AU665050B2 (en) * 1992-01-13 1995-12-14 Baroid Limited Disposal of contaminated cuttings
WO1993013882A1 (en) * 1992-01-13 1993-07-22 Henkel Kommanditgesellschaft Auf Aktien Improved method of disposal of contaminated cuttings
US5755892A (en) * 1992-01-13 1998-05-26 Henkel Kommanditgesellschaft Auf Aktien Waste disposal of contaminated drill cuttings from geological drilling using drilling fluid systems containing mineral oil
US7867399B2 (en) 2008-11-24 2011-01-11 Arkansas Reclamation Company, Llc Method for treating waste drilling mud
US7935261B2 (en) 2008-11-24 2011-05-03 Arkansas Reclamation Company, Llc Process for treating waste drilling mud
WO2013037978A1 (en) * 2011-09-16 2013-03-21 Montanuniversität Leoben Recycling of borehole solids in polymers
US9464180B2 (en) 2011-09-16 2016-10-11 Montanuniversität Leoben Recycling of borehole solids in polymers
EA029152B1 (en) * 2011-09-16 2018-02-28 Монтануниверзитет Леобен Method of fabricating a composite material
CN103899262A (en) * 2012-12-28 2014-07-02 中国石油化工股份有限公司 Treating-while-drilling method for drilling cuttings of oil base of borehole

Also Published As

Publication number Publication date
AU7808881A (en) 1982-06-07
EP0065532A1 (en) 1982-12-01

Similar Documents

Publication Publication Date Title
US5107874A (en) Apparatus for cleaning particulate solids
US5080721A (en) Process for cleaning particulate solids
US4836302A (en) Apparatus and method for removing and recovering oil and/or other oil-based drilling mud additives from drill cuttings
US5570749A (en) Drilling fluid remediation system
US6576145B2 (en) Method of separating hydrocarbons from mineral substrates
US5199997A (en) Treatment of hydrocarbon-contaminated particulate materials
US4683963A (en) Drilling cuttings treatment
US5005655A (en) Partially halogenated ethane solvent removal of oleophylic materials from mineral particles
WO1982001737A1 (en) Method of treating oil-contaminated drill muds or cuttings prior to reuse or disposal
MXPA06006426A (en) Oil contaminated substrate treatment method and apparatus.
US5207532A (en) Process for conditioning material for disposal
US20060004236A1 (en) Method of separating and converting hydrocarbon composites and polymer materials
US11566159B2 (en) Base oil for re-use
CA1329319C (en) Oil removal from hydrocarbon contaminated cuttings
EP1214497B1 (en) Absorbent materials and production thereof
JPH05502279A (en) Method and apparatus for cleaning excavation cuttings
EP0323649B1 (en) A method for decontaminating a material and an assembly for carrying out said method
Akinnuli et al. RECLAMATION OF BASE OIL FROM OIL WELLS DRILL CUTTINGS AND ITS DISPOSAL ECOLOGICAL HAZARD CONTROL
EP1404466A1 (en) Process for the remediation of soil polluted by organic compounds
MXPA01006071A (en) Removal of oil and chloride from oil contaminated material.
RU2092518C1 (en) Method of recovering petroleum derivatives from sludges and polluted ground
WO2023018742A1 (en) Process for remediation of articles contaminated with radioactive materials
CA2091507A1 (en) Process for separating mixtures of solids or sludges which contain non-volatile hydrocarbons and other accompanying substances
Hayward et al. Prevention of Offshore Pollution from Drilling Fluids
JPT staff Invert-Fluid Flocculation: A Method for Recycling Drilling Fluid

Legal Events

Date Code Title Description
AK Designated states

Designated state(s): AU BR JP NO US

AL Designated countries for regional patents

Designated state(s): DE FR GB NL SE