AU644120B2 - Method and apparatus for cleaning drill cuttings - Google Patents

Method and apparatus for cleaning drill cuttings

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Publication number
AU644120B2
AU644120B2 AU67557/90A AU6755790A AU644120B2 AU 644120 B2 AU644120 B2 AU 644120B2 AU 67557/90 A AU67557/90 A AU 67557/90A AU 6755790 A AU6755790 A AU 6755790A AU 644120 B2 AU644120 B2 AU 644120B2
Authority
AU
Australia
Prior art keywords
solvent
cuttings
oil
solids
extractor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU67557/90A
Other versions
AU6755790A (en
Inventor
Marshall Graham Bailey
Derek Tyldsley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Varco IP Inc
Original Assignee
Rig Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB898926893A external-priority patent/GB8926893D0/en
Priority claimed from GB909013964A external-priority patent/GB9013964D0/en
Priority claimed from GB9019592A external-priority patent/GB2239470B/en
Application filed by Rig Technology Ltd filed Critical Rig Technology Ltd
Publication of AU6755790A publication Critical patent/AU6755790A/en
Application granted granted Critical
Publication of AU644120B2 publication Critical patent/AU644120B2/en
Assigned to VARCO I/P INC. reassignment VARCO I/P INC. Alteration of Name(s) in Register under S187 Assignors: RIG TECHNOLOGY LIMITED
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D11/00Solvent extraction
    • B01D11/02Solvent extraction of solids
    • B01D11/028Flow sheets
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B21/00Methods or apparatus for flushing boreholes, e.g. by use of exhaust air from motor
    • E21B21/06Arrangements for treating drilling fluids outside the borehole
    • E21B21/063Arrangements for treating drilling fluids outside the borehole by separating components
    • E21B21/065Separating solids from drilling fluids
    • E21B21/066Separating solids from drilling fluids with further treatment of the solids, e.g. for disposal

Landscapes

  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • Geology (AREA)
  • Physics & Mathematics (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
  • Lubricants (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Treatment Of Sludge (AREA)
  • Fats And Perfumes (AREA)

Description

Title: Method and apparatus for cleaning drill cuttings.
Field of the Invention
This invention relates to the cleaning of oil contaminated cuttings arising from drilling operations.
Background to the Invention
During the drilling of oil and gas wells large quantities of rock particles are produced from the bore hole. The rock particles, typically referred to as cuttings, are carried to the surface of the hole by a continuously circulating fluid, referred to as the drilling fluid or drilling mud. At the surface the cuttings are separated from the bulk of the fluid by various units of mechanical equipment, typically vibrating screen shakers, hydrocyclones, and centrifuges. Separated cuttings are, however, still wetted by the drilling fluid.
In cases where the drilling fluid is an oil based mud, which typically consists of an emulsion of aqueous salt solution in a light mineral oil base, the separated cuttings may have a considerable quantity of oil associated with them.
Oil is retained on cuttings in three ways: as oil mud in a viscous layer on the surface of the cuttings; as oil mud in "free" form trapped in agglomerates of cuttings; and as free oil absorbed into rock pores. Excluding accidental oil spills, the largest source of oil discharge from oil field operations is in the form of oil mud associated with drill cuttings. To combat this, legislation has been introduced which limits the concentration of oil on cuttings which can lawfully be discharged. For example, countries bordering the North Sea are working to standardise and improve current legislation, and it is expected that oil discharge levels will be made more stringent in the future.
To meet current legislative requirements, cleaning systems have been developed for offshore application which, under most circumstances, will reduce the oil content on discharged cuttings to below 10% by weight. All of these systems employ an initial washing technique followed by centrifugal separation and discharge of cleaned solids, and limited recycling of the wash fluid. One known system employs mud based oil as the washing fluid but this suffers from the disadvantage of leaving a coating of oil on the solids and therefore limits the degree to which the cuttings can be cleaned. Another known method utilises a water/surfactant wash solution which, whilst theoretically producing cleaner solids, results in the secondary problem of producing large volumes of oil contaminated wash water for disposal.
Several other thermal methods have been attempted which employ either thermal destruction of the hydrocarbons associated with the cuttings, or thermal evaporation of the oil followed by condensation and recovery of oil values. Such systems have suffered the disadvantages of high mechanical wear, corrosion, and difficulty in process control due to the variability in properties of the cuttings. In particular, such systems have also had a high energy demand due, in large part, to the necessity to evaporate all water associated with the cuttings.
The present invention aims to provide a novel method of and apparatus for cleaning cuttings which meets the more stringent cleaning requirements shortly to be imposed and which is capable of overcoming the disadvantages of known cleaning systems.
Summary of the Invention
According to the invention a method of removing oil from oily cuttings obtained from a drilling operation comprises
- exposing the oily cuttings to a solvent for oil and thereby dissolving the oil in the solvent, and separating the cuttings from the solvent with the oil dissolved therein.
The solvent (eg toluene) and the oily cuttings are preferably exposed to the solvent in an extractor chamber through which the cuttings and solvent pass in opposite directions in a continuous process, the cuttings being fed into an inlet end of the extractor chamber and exiting from an outlet end thereof, with the solvent discharge being collected at the inlet end of the extractor chamber, cleaned and then recirculated back to the outlet end of the extractor chamber. This ensures that the cleanest solvent contacts the cuttings at the outlet end of the extractor chamber.
The cuttings are conveniently fed through the extractor chamber by means of a conveyor belt and the solvent may be sprayed into the extractor chamber at the outlet end thereof. The extractor chamber is conveniently divided into a plurality of compartments through which the cuttings are transported in succession by the belt, the solvent being extracted at the base of each compartment and being pumped to the adjacent compartment into which the solvent is sprayed. In each compartment, the solvent is preferably allowed to filter through the cuttings and belt and is then collected in a sump at the base of the compartment.
The cuttings obtained from the outlet end of the extractor chamber will retain a certain amount of solvent and absorbed water. To remove these, the cuttings thus obtained are preferably fed to a dryer unit which removes the solvent, leaving clean cuttings in the form of solids having an oil content typically not greater than 1% by weight.
The solvent discharge from the extractor chamber normally contains fine solids, in addition to oil/solvent and water. For solvents such as toluene, the oil/solvent and water are in the form of an emulsion. In one method, the fine solids are separated from the emulsion which is then delivered to an evaporator in which the emulsion is broken down into an oil component and a solvent plus water vapour component. Fine solids may be extracted, as by gravity separation, either upstream or downstream of the evaporator. However, the high latent heat of the evaporated water demands a great deal of energy for this process. To overcome this problem, in another preferred method, the emulsion is broken down by a demulsification process in which the fine solids and the emulsion are exposed to a demulsifying agent which effects separation into a fine solids component, an oil/solvent component and a water component. In both methods the solvent is preferably recovered, together with solvent from the dryer unit, and recirculated to be fed into the extractor chamber.
In a modification of the method, an alternative extracting means is employed, comprising an agitated vessel to which the oily cuttings and the solvent are added, and the resultant solids/solvent slurry is then fed, for example by a positive displacement pump, to a centrifuge, preferably a solid bowl decanting centrifuge.
According to a further feature of the invention, water is added to the solids/solvent slurry prior to centrifugation. This reduces the amount of oil carried through with the solids, and avoids any requirement to heat the solids phase prior to its discharge.
The invention also includes within its scope apparatus for removing oil from oily cuttings obtained from a drilling operation, the apparatus comprising an extractor in which the oily cuttings are exposed to an organic solvent for oil and in which the oil is dissolved in the solvent, the extractor having separate outlets for the cuttings and for the solvent and oil dissolved therein.
Description of Embodiments
Eight methods according to the invention will now be described, by way of example only, with reference to the accompanying drawings, in which:
Figure 1 is a block diagram illustrating a first method. Figure 2 is a block diagram illustrating a second method, and
Figures 3 to 8 are block diagrams illustrating six further methods.
Referring first to Figure 1, drill cuttings from a drilling operation are fed as indicated by arrow 10 into an extractor in which oil is extracted (as indicated at 12) by the application of a solvent, eg toluene. Instead of being fed directly into the extractor, the cuttings may optionally be pre-mixed with the solvent to present a slurry feed to the extractor, as shown at 14.
The extractor consists of a closed chamber, separated into a plurality of compartments. A continuous fine mesh belt conveys the cuttings from an inlet end of the extractor, through the compartments in turn and discharges the solids from an outlet end of the extractor into a hopper. Clean solvent is sprayed onto the cuttings in the compartment at the outlet end of the extractor, the solvent filtering through the cuttings and belt and being collected in a sump at the base of the compartment. This solvent is then re-circulated by means of a pump to the adjacent compartment immediately upstream (in relation to the direction of movement of the cuttings through the extractor) and the process repeated. Solvent and cuttings are therefore transported in mutually opposite directions through the extractor, with the cleanest solvent contacting the cleanest cuttings at the outlet end of the extractor.
The bulk solids discharged from the extractor at 16 will still be wet, ie they will contain solvent and any water absorbed into the particles of the cuttings. These solids are therefore transferred to a dryer 18 where the solvent is evaporated at 20 and the clean dry solids discharged at 22, where the oil content of the solids is typically not greater than about 1% by weight.
The fluid discharge 24 from the extractor consists of fine solids plus a solution of water in an oil emulsion dissolved in the solvent. Fine solids are removed at 26 by, for example, a decanting centrifuge and are fed at 28 into t; e bulk solids which are supplied to the dryer 18. The liquid phase 30 from the centrifuge is transferred to an evaporator 32 where the solvent and water are evaporated from the oil. The oil is recovered at 34 as a useable product and the solvent plus water vapour 36 is combined with the solvent and water vapour 20 from the dryer unit 18 and fed into a condenser/separator 38 where the vapours are conder ed. Condensed water and solvents separate by gravity, the water being discharged at 40 and the solvent being re-cycled at 42 back to the extractor at 12.
In the modified process shown in Figure 2, equivalent process steps bear the same reference numerals as used in Figure 1. The process is similar except that the fluid discharge 24 from the extractor is subjected to demulsification in order to separate water from the oil/solvent. Hence, the fine solids plus the oil/solvent and water are fed to a demulsification unit 44 where they are exposed to a demulsifying agent. The fluid mixture is then transferred to a three phase separator unit 46, for example a disc stacked centrifuge, where wet solids, oil/solvent and water are separated. As before, the fine solids 28 are reunited with the bulk solids which are fed to the dryer 18, and water is discharged at 48 via a separate treatment system if required. The oil/solvent solution 50 is transferred to the evaporater 32, but this will require less energy than in the evaporator 32 of Figure 1 because a large amount of water has been removed at 48 as a result of the demulsification and subsequent separation.
In the methods illustrated in Figures 3 to 8, the same reference numerals are again used for the process steps equivalent to those of Figures 1 and 2.
Referring to the drawings collectively, drill cuttings from a drilling operation are fed as indicated by arrow 10 into an extracting means, in which oil is extracted (as indicated at 12A, 12B) by the application of a solvent, eg toluene or other suitable stabilised gasoline fraction.
The solids discharged from the extracting means at 16 will be wet, ie they will contain solvent and any water absorbed into the cuttings particles. These solids, possibly after second stage washing, are transferred to a dryer 18 where the solvent is evaporated (at 20) and the clean cuttings discharged at 22.
The fluid discharge 24 from the extracting means again consists of fine solids plus a solution of water in oil emulsion dissolved in the solvent. Fine solids may be removed at 26 by, for example, a decanting centrifuge. After optional fine solids removal, the fluid discharge 24 is transferred to an evaporator 32 where the solvent and water are evaporated from the oil. The oil is recovered at 34 as a usable product and the solvent plus water vapour 36, possibly combined with the solvent and water vapour 20 from the dryer unit 18, is fed into a condenser/separator 38 where the vapours are condensed. Condensed water and solvents separate by gravity, the water being discharged at 40 and the solvent being re¬ cycled at 42 back to the extractor.
Two examples of the invention, practised in accordance with the methods of any one of Figures 3 to 8, are as follows:-
EXAMP E 1
In one series of tests oil contaminated drill cuttings of average composition 80.6% w/w solids, 10.0% w/w water, and
9.4% w/w oil were added at the rate of 6.2 tonnes per hour to an agitated vessel 12A into which was also added a
3 solvent at the rate 7.0 m per hour. The solvent used in this case was a stabilised gasoline fraction ex BP
Refinery, Grangemouth.
The average residence time of the cuttings in the vessel was 1 minute, and the temperature was 21°C.
The resultant solids/solvent slurry was fed at the rate of 10 m 3, via a positive displacement pump, into a solid bowl decanting centrifuge 12B. The centrifuge effected solids/liquid separation to yield a centrate (solvent) phase of average composition 88.3% w/w solvent, 10.4% w/w oil, and 1.1% w/w water. Solids phase exiting the centrifuge had an average composition of 84.9% w/w dry solids, 0.9% w/w oil, 9.2% w/w water, and 5.0% w/w solvent.
The oil dissolved in the solvent phase was recovered by evaporation of the solvent which was subsequently condensed and recovered for re-use. The resultant oil phase, containing 5.1% w/w water and 1.0% w/w residual solvent was considered suitable for re-use in oil based mud preparations.
Solids exiting from the centrifuge were heated to effect evaporation of associated solvent, which was subsequently recovered by condensation. Solids discharged from the dryer unit had an average composition of 89.36% w/w dry solids, 0.95% w/w oil, 9.48% w/w water, and 0.21% w/w solvent.
EXAMPLE 2
The procedure as described in Example 1 above was repeated, using the same ratios and composition of oil contaminated drill cuttings and solvent, but with the addition of water at the rate of 500 litres per hour to the cuttings/solvent slurry immediately prior to centrifugation, as indicated at 12C in Figures 3 to 8.
The resultant centrate (solvent) phase from the centrifuge 12B had a composition of 86.5% w/w solvent, 9.7% w/w oil, and 3.8% w/w water. Water was allowed to separate by gravity in an intermediate tank and discharged to drain. Solvent was removed by evaporation and subsequently recondensed to yield a fluid of composition of 99.6% w/w solvent and 0.4% w/w water, which was recycled back to the process. Residual oil phase remaining in the evaporator had a composition of 97.0% w/w oil, 2.1% w/w water, and 0.9% w/w solvent, and was considered suitable for re-use in oil based mud preparations. Solids phase exiting from the centrifuge had an average composition of 82.9% w/w solids, 14.8% w/w water, 0.8% w/w oil, and 1.5% w/w solvent indicating that the addition of water to the centrifuge feed slurry had resulted in a significant lowering of solvent carry through with solids. In this case it was considered that no further solvent removal by heating of the solids phase was necessary prior to discharge.

Claims (18)

Claims
1. A method of removing oil from oily cuttings obtained from a drilling operation comprising exposing the oily cuttings to a solvent for oil and thereby dissolving the oil in the solvent, and separating the cuttings from the solvent with the oil dissolved therein.
2. A method according to claim 1 in which the oily cuttings are exposed to the solvent in an extractor chamber through which the cuttings and solvent pass in opposite directions in a continuous process, the cuttings being fed into an inlet end of the extractor chamber and exiting from an outlet end thereof, with the solvent discharge being collected at the inlet end of the extractor chamber, being cleaned and then recirculated back to the outlet end of the extractor chamber.
3. A method according to claim 2 in which the cuttings are fed through the extractor chamber by means of a conveyor belt and the solvent is sprayed into the chamber at the outlet end thereof.
4. A method according to claim 3 in which the chamber is divided into a plurality of compartments through which the cuttings are transported in succession by the belt, the solvent being extracted at the base of each compartment and being pumped to the adjacent compartment into which the solvent is sprayed.
5. A method according to claim 4 in which the solvent in each compartment is allowed to filter through the cuttings and belt and is then collected in a sump at the base of the compartment.
6. A method according to any one of claims 2 to 5 in which the cuttings obtained from the outlet end of the extractor chamber are fed to a dryer unit which removes the solvent and leaves clean cuttings in the form of solids.
7. A method according to claim 6 in which the clean cuttings are left with an oil content not greater than 1% by weight.
8. A method according to any one of claims 2 to 7 in which the solvent discharge contains oil/solvent and water in the form of an emulsion in addition to fine solids.
9. A method according to claim 8 in which the fine solids are separated from the emulsion which is delivered to an evaporator in which the emulsion is broken down into an oil component and a solvent plus water vapour component.
10. A method according to claim 9 in which the fine solids are separated, as by gravity separation, either upstream or downstream of the evaporator.
11. A method according to claim 9 in which the emulsion is broken down by a demulsification process in which the fine solids and the emulsion are exposed to a demulsifying agent which effects separation into a fine solids component, an oil/solvent component and a water component.
12. A method according to any one of claims 6 to 11 in which the solvent is recovered, together with solvent from the dryer unit, and recirculated to be fed into the extractor chamber.
13. A method according to claim 1 in which the solids of oily cuttings are exposed to the solvent in any agitating vessel from which the resultant slurry of solids and solvent is pumped to a centrifuge.
14. A method according to claim 13 in which the slurry is pumped by a positive displacement pump.
15. A method according to claim 13 or claim 14 in which the centrifuge is a solid bowl decanting centrifuge.
16. A method according to any one of claims 13 to 15 in which water is added to the solids/solvent slurry prior to centrifugation.
17. A method according to any one preceding claim in which the solvent is toluene or a stabilised gasoline fraction.
18. Apparatus for removing oil from oily cuttings obtained from a drilling operation, the apparatus comprising an extractor in which the oily cuttings are exposed to an organic solvent for oil and in which the oil is dissolved in the solvent, the extractor having separate outlets for the cuttings and for the solvent and oil dissolved therein.
AU67557/90A 1989-11-28 1990-11-23 Method and apparatus for cleaning drill cuttings Ceased AU644120B2 (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
GB898926893A GB8926893D0 (en) 1989-11-28 1989-11-28 Cleaning of cuttings from drilling operations
GB8926893 1989-11-28
GB909013964A GB9013964D0 (en) 1990-06-22 1990-06-22 Cleaning of cuttings from drilling operations
GB9013964 1990-06-22
GB9019592 1990-09-07
GB9019592A GB2239470B (en) 1989-11-28 1990-09-07 Cleaning of cuttings from drilling operations

Publications (2)

Publication Number Publication Date
AU6755790A AU6755790A (en) 1991-06-26
AU644120B2 true AU644120B2 (en) 1993-12-02

Family

ID=27264816

Family Applications (1)

Application Number Title Priority Date Filing Date
AU67557/90A Ceased AU644120B2 (en) 1989-11-28 1990-11-23 Method and apparatus for cleaning drill cuttings

Country Status (9)

Country Link
EP (1) EP0502882B1 (en)
JP (1) JPH05502279A (en)
AU (1) AU644120B2 (en)
CA (1) CA2068997A1 (en)
DE (1) DE69033535T2 (en)
DK (1) DK0502882T3 (en)
ES (1) ES2145734T3 (en)
NO (1) NO304443B1 (en)
WO (1) WO1991008375A1 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2319016A1 (en) * 1998-02-03 1999-08-12 Inge Brun Henriksen Cleaning of drill cuttings and apparatus therefor
US6936092B2 (en) 2003-03-19 2005-08-30 Varco I/P, Inc. Positive pressure drilled cuttings movement systems and methods
WO2004083597A1 (en) 2003-03-19 2004-09-30 Varco I/P, Inc. Apparatus and method for moving drilled cuttings
US7493969B2 (en) 2003-03-19 2009-02-24 Varco I/P, Inc. Drill cuttings conveyance systems and methods
US20150300108A1 (en) * 2012-11-29 2015-10-22 M-I L.L.C. Vapor displacement method for hydrocarbon removal and recovery from drill cuttings
WO2016044485A1 (en) * 2014-09-17 2016-03-24 Oxr, Llc Oil extraction from drilling mud and cuttings
WO2017037569A1 (en) * 2015-09-01 2017-03-09 Recover Energy Services Inc. Gas-tight centrifuge for voc separation
CA2959849C (en) 2016-03-03 2023-08-22 Recover Energy Services Inc. Diluent treated drilling waste material recovery process and system
CA3016380C (en) 2016-03-03 2023-03-21 Recover Energy Services Inc. Gas tight horizontal decanter for drilling waste solids washing
CA2959851A1 (en) 2016-03-03 2017-09-03 Recover Energy Services Inc. Gas tight shale shaker for enhanced drilling fluid recovery and drilled solids washing
CA3021262A1 (en) 2016-04-19 2017-10-26 Recover Energy Services Inc. Oilfield centrifuge decanter for drilling waste drying method and apparatus
WO2019157040A1 (en) 2018-02-06 2019-08-15 Astec, Inc. Apparatus and method for a remediation plant

Citations (1)

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Publication number Priority date Publication date Assignee Title
WO1982001737A1 (en) * 1980-11-21 1982-05-27 Moir James A Method of treating oil-contaminated drill muds or cuttings prior to reuse or disposal

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Publication number Priority date Publication date Assignee Title
DE1053470B (en) * 1958-02-21 1959-03-26 Metallgesellschaft Ag Procedure for extraction in horizontal bucket elevator extractors
US3693951A (en) * 1970-12-30 1972-09-26 Nl Industries Inc Process and apparatus for the treatment of well cuttings
US4040866A (en) * 1973-10-05 1977-08-09 N L Industries, Inc. Laundering of oil base mud cuttings
US4434028A (en) * 1981-04-17 1984-02-28 Critical Fluid Systems, Inc. Apparatus for removing organic contaminants from inorganic-rich mineral solids
US4836302A (en) * 1986-12-03 1989-06-06 Heilhecker Joe K Apparatus and method for removing and recovering oil and/or other oil-based drilling mud additives from drill cuttings

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1982001737A1 (en) * 1980-11-21 1982-05-27 Moir James A Method of treating oil-contaminated drill muds or cuttings prior to reuse or disposal

Also Published As

Publication number Publication date
EP0502882A1 (en) 1992-09-16
EP0502882B1 (en) 2000-05-03
NO922103D0 (en) 1992-05-27
JPH05502279A (en) 1993-04-22
NO304443B1 (en) 1998-12-14
DE69033535T2 (en) 2001-01-11
DK0502882T3 (en) 2000-08-07
DE69033535D1 (en) 2000-06-08
NO922103L (en) 1992-05-27
CA2068997A1 (en) 1991-05-29
WO1991008375A1 (en) 1991-06-13
ES2145734T3 (en) 2000-07-16
AU6755790A (en) 1991-06-26

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Owner name: VARCO I/P, INC.

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