UST888016I4 - Defensive publication - Google Patents
Defensive publication Download PDFInfo
- Publication number
- UST888016I4 UST888016I4 US888016DH UST888016I4 US T888016 I4 UST888016 I4 US T888016I4 US 888016D H US888016D H US 888016DH US T888016 I4 UST888016 I4 US T888016I4
- Authority
- US
- United States
- Prior art keywords
- group
- pyridine
- ethyl
- heterocyclic
- nitrogen containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract description 8
- -1 SILVER HALIDE Chemical class 0.000 abstract description 5
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 abstract description 4
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 abstract description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract description 4
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract description 2
- 230000002378 acidificating effect Effects 0.000 abstract description 2
- 150000001450 anions Chemical class 0.000 abstract description 2
- 239000000975 dye Substances 0.000 abstract description 2
- 239000000839 emulsion Substances 0.000 abstract description 2
- 229910052711 selenium Inorganic materials 0.000 abstract description 2
- 230000001235 sensitizing effect Effects 0.000 abstract description 2
- 229910052709 silver Inorganic materials 0.000 abstract description 2
- 239000004332 silver Substances 0.000 abstract description 2
- 229910052717 sulfur Inorganic materials 0.000 abstract description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 125000004391 aryl sulfonyl group Chemical group 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/10—Organic substances
- G03C1/12—Methine and polymethine dyes
Definitions
- Photographic silver halide emulsions contain a sensitizing combination comprising a merocyanine dye having an imino group on the acidic nucleus thereof, and a pyridine and/ or a quinoline base.
- the preferred merocyanine dyes have one of the following formulas:
- a preferred combination comprises 3 ethyl-5-
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyridine Compounds (AREA)
Abstract
PHOTOGRAPHIC SILVER HALIDE EMULSIONS CONTAIN A SENSITIZING COMBINATION COMPRISING A MEROCYANINE DYE HAVING AN IMINO GROUP ON THE ACIDIC NUCLEUS THEREOF, AND A PYRIDINE AND-OR A QUINOLINE BASE. THE PREFERRED MEROCYANINE DYES HAVE ONE OF THE FOLLOWING FORMULAS:
WHEREIN N AND M EACH REPRESENTS A POSITIVE INTEGER OF FROM 1 TO 2; L REPRESENTS A METHINE LINKAGE; D REPRESENTS AND OXYGEN ATOM, A SULFUR ATOM, A SELENIUM ATOM OR THE GROUP =N-R; R1, R2 AND R4 EACH REPRESENTS AN ALKYL GROUP OR AN ARYL GROUP; R3 REPRESENTS AN AMINO GROUP, AN ALKYL GROUP, AN ARYL GROUP, AN ACYL GROUP, AN ARYLSULFONYL GROUP, AN ALKOXYCARBONYL GROUP, A CARBOXYALKYLCARBONYL GROUP, A 5- TO 6-MEMBERED NITROGEN CONTAINING HETEROCYCLIC GROUP, AND THE GROUP
WHEREIN Z1, M, D, R1 AND R2 ARE AS ABOVE DEFINED; X REPRESENTS AN ACID ANION; AND Z1 AND Z2 EACH REPRESENTS THE NON-METALLIC ATOMS NECESSARY TO COMPLETE A NITROGEN CONTAINING THE HETEROCYCLIC NUCLEUS CONTAINING FROM 5 TO 6 ATOMS IN THE HETEROCYCLIC RING. A PREFERRED COMBINATION COMPRISES 3 - ETHYL-5((3-ETHYL-2-BENZOTHIAZOLINYLIDENE)ETHYLIDIENE)-2-P-CARBOXYPHENYLIMINO-4-THIAZOLIDINONE AND PYRIDINE.
WHEREIN N AND M EACH REPRESENTS A POSITIVE INTEGER OF FROM 1 TO 2; L REPRESENTS A METHINE LINKAGE; D REPRESENTS AND OXYGEN ATOM, A SULFUR ATOM, A SELENIUM ATOM OR THE GROUP =N-R; R1, R2 AND R4 EACH REPRESENTS AN ALKYL GROUP OR AN ARYL GROUP; R3 REPRESENTS AN AMINO GROUP, AN ALKYL GROUP, AN ARYL GROUP, AN ACYL GROUP, AN ARYLSULFONYL GROUP, AN ALKOXYCARBONYL GROUP, A CARBOXYALKYLCARBONYL GROUP, A 5- TO 6-MEMBERED NITROGEN CONTAINING HETEROCYCLIC GROUP, AND THE GROUP
WHEREIN Z1, M, D, R1 AND R2 ARE AS ABOVE DEFINED; X REPRESENTS AN ACID ANION; AND Z1 AND Z2 EACH REPRESENTS THE NON-METALLIC ATOMS NECESSARY TO COMPLETE A NITROGEN CONTAINING THE HETEROCYCLIC NUCLEUS CONTAINING FROM 5 TO 6 ATOMS IN THE HETEROCYCLIC RING. A PREFERRED COMBINATION COMPRISES 3 - ETHYL-5((3-ETHYL-2-BENZOTHIAZOLINYLIDENE)ETHYLIDIENE)-2-P-CARBOXYPHENYLIMINO-4-THIAZOLIDINONE AND PYRIDINE.
Description
DEFENSIVE PUBMCATTQN UNITED STATES PATENT OFFICE Published at the request of the applicant or owner in accordance with the Notice of Dec. 16, 1969, 869 O.G. 687. The abstracts of Defensive Publication applications are identified by distinctly numbered series and are arranged chronologically. The heading of each abstract indicates the number of pages of specification, including claims and sheets of drawings contained in the application as originally filed. The files of these applications are available to the public for inspection and reproduction may be purchased for 30 cents a sheet.
Defensive Publication applications have not been examined as to the merits of alleged invention. The Patent Ofiice makes no assertion as to the novelty of the disclosed subject matter.
PUBLISHED JULY 20, 1971 T888,0l6 PHOTOGRAPHIC MATERIALS Norman W. Kalenda, Kodak Park, Rochester, NY. 14650 Filed Dec. 4, 1970, Ser. No. 95,419 Int. Cl. G03c N10 US. Cl. 96-126 No Drawing. 27 Pages Specification Photographic silver halide emulsions contain a sensitizing combination comprising a merocyanine dye having an imino group on the acidic nucleus thereof, and a pyridine and/ or a quinoline base. The preferred merocyanine dyes have one of the following formulas:
L=-(ort=oH-).. 11 :-R, wherein n and m each represents a positive integer of from 1 to 2; L represents a methine linkage; D represents an oxygen atom, a sulfur atom, a selenium atom or the group =N-R; R, R R and R each represents an alkyl group or an aryl group; R represents an amino group, an al-kyl group, an aryl group, an acyl group, an arylsulfonyl group, an alkoxycarbonyl group, a carboxyalkylcarbonyl group, a 5- to 6-membered nitrogen containing heterocyclic group, and the group wherein Z m, D, R and R are as above defined; X represents an acid anion; and Z and Z each represents the non-metallic atoms necessary to complete a nitrogen containing heterocyclic nucleus containing from 5 to 6 atoms in the heterocyclic ring. A preferred combination comprises 3 ethyl-5-[(3-ethyl-Z-benzothiazolinylidene)ethylidiene]-2p-carboxyphenylimino-4-thiazolidinone and pyridine.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9541970A | 1970-12-04 | 1970-12-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UST888016I4 true UST888016I4 (en) | 1971-07-20 |
Family
ID=22251922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US888016D Pending UST888016I4 (en) | 1970-12-04 | 1970-12-04 | Defensive publication |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | UST888016I4 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5077191A (en) * | 1989-12-26 | 1991-12-31 | Eastman Kodak Company | Photographic sensitizing dyes |
-
1970
- 1970-12-04 US US888016D patent/UST888016I4/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5077191A (en) * | 1989-12-26 | 1991-12-31 | Eastman Kodak Company | Photographic sensitizing dyes |
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