UST861031I4 - Defensive publication - Google Patents
Defensive publication Download PDFInfo
- Publication number
- UST861031I4 UST861031I4 US861031DH UST861031I4 US T861031 I4 UST861031 I4 US T861031I4 US 861031D H US861031D H US 861031DH US T861031 I4 UST861031 I4 US T861031I4
- Authority
- US
- United States
- Prior art keywords
- defensive publication
- borane
- defensive
- published
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical class B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 6
- 229910000085 borane Inorganic materials 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- -1 Trioctylamine borane Chemical compound 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- RBFQJDQYXXHULB-UHFFFAOYSA-N arsane Chemical class [AsH3] RBFQJDQYXXHULB-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000002541 furyl group Chemical group 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 125000001544 thienyl group Chemical group 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
Definitions
- Ethylenically unsaturated, elastomeric, sulfur curable hydrocarbon polymers are reacted in bulk (optionally containing 150 parts per 100 parts of petroleum oil) or solution at room temperature to 250 0., preferably 50-225 C., with boranes EH B H or RBH (R is C C alkyl, aryl, or substituted aryl, to reduce the cold flow of the elastomer while maintaining sulfur-curability and not effecting significant gelation.
- the borane supplies about 0.002 to 0.1 gramatoms of B per kilogram of polymer.
- Trioctylamine borane is representative.
- the borane can be supplied as a solution in petrolatum, decalin, or high boiling oil (preferably less than 10% by Weight of the polymer). If the polymer is treated in an extruder, the extrudate should be cooled in a protective atmosphere.
- the treated polymers can be returned partly or Wholly to their original state by mixing them with 1-5 moles of a carboxylic acid, e.g., stearic acid, per gram-atom of B. ZnO or CdO will prevent this change if added ahead of the acid.
- a carboxylic acid e.g., stearic acid
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
DEFENSIVE PUBLICATIONT UNITED STATES PATENT OFFICE Published at the request of the applicant or owner in accordance with the Notice of Apr. 11, 1968, 849 0.G. 1221. Identification is by serial number of the application and the heading indicates the number of pages of specification, including claims. and of sheets of drawing contained in the application as originally filed. The file of this application is available to the public for inspection; reproduction may be purchased for 30 cents per sheet.
Applications published under the Defensive Publication Program have not been examined as to the merits of alleged invention. The Patent Ofiice makes no assertion as to the novelty of the disclosed subject matter.
PUBLISHED APRIL 15, 1969 743 029 ETHYLENICALLY UNSATURATED HYDRO- CARBON POLYMERS TREATED WITH BORON COMPOUNDS Anestis Leonidas Logothetis, Wilmington, Del., assignor to E. I. du Pont de Nemours and Company, Wilmington, Del., a corporation of Delaware Filed July 8, 1968. Published Apr. 15, 1969 Class 260-8058 No Drawing. 16 Pages Specification Ethylenically unsaturated, elastomeric, sulfur curable hydrocarbon polymers, particularly copolymers of at least one lalpha-monoolefin and at least one non-conjugated diene, are reacted in bulk (optionally containing 150 parts per 100 parts of petroleum oil) or solution at room temperature to 250 0., preferably 50-225 C., with boranes EH B H or RBH (R is C C alkyl, aryl, or substituted aryl, to reduce the cold flow of the elastomer while maintaining sulfur-curability and not effecting significant gelation. The borane supplies about 0.002 to 0.1 gramatoms of B per kilogram of polymer. The borane can be derived from complexes with ethers, ammonia, amines (R' NH phosphines (R' P), and arsines (R' As) where R is H, C -C alkyl, cycloalkyl, aryl, alkaryl, pyridyl, furyl, and thienyl, n=03, m=dn. Trioctylamine borane is representative. Optionally, the borane can be supplied as a solution in petrolatum, decalin, or high boiling oil (preferably less than 10% by Weight of the polymer). If the polymer is treated in an extruder, the extrudate should be cooled in a protective atmosphere.
The treated polymers can be returned partly or Wholly to their original state by mixing them with 1-5 moles of a carboxylic acid, e.g., stearic acid, per gram-atom of B. ZnO or CdO will prevent this change if added ahead of the acid.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US74302968A | 1968-07-08 | 1968-07-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UST861031I4 true UST861031I4 (en) | 1969-04-15 |
Family
ID=24987238
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US861031D Pending UST861031I4 (en) | 1968-07-08 | 1968-07-08 | Defensive publication |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | UST861031I4 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5741870A (en) * | 1993-03-15 | 1998-04-21 | Kuraray Co., Ltd. | Resin composition |
-
1968
- 1968-07-08 US US861031D patent/UST861031I4/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5741870A (en) * | 1993-03-15 | 1998-04-21 | Kuraray Co., Ltd. | Resin composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3380978A (en) | Process for producing hydrocarbon polymers | |
| ES392021A2 (en) | Catalysts and process for the polymerization and copolymerization of olefins | |
| UST861031I4 (en) | Defensive publication | |
| US2997456A (en) | Stabilization of polymers of 1-olefins | |
| US1983949A (en) | Method of polymerizing vinyl chloride | |
| US3361709A (en) | Polyolefins stabilized with a nickel complex of a benzophenone | |
| US2580695A (en) | Alpha, alpha'-dithiodialdehydes | |
| US3513152A (en) | Thermally stable olefin polymer | |
| Tuskaev et al. | Binuclear Ti (IV) complex with new compartmental ligand 2, 6‐(bis‐CF3‐carbinol)‐4‐tert‐butylphenol as precatalysts for ethylene polymerization and its copolymerization with propylene and 5‐ethylidene‐norbornene | |
| GB870425A (en) | Improvements in and relating to organic phosphorus compounds | |
| ES247016A1 (en) | Polymerization catalyst | |
| US3117952A (en) | Method of improving certain catalysts | |
| US3264253A (en) | Polymer compositions | |
| ES295989A1 (en) | A procedure for preparing a composition of polyol (Machine-translation by Google Translate, not legally binding) | |
| US3342854A (en) | Method for the preparation of acrylate dimers and trimers | |
| GB1104211A (en) | Improvements in elastomeric copolymers | |
| ES298331A1 (en) | Copolymers of 1, 3-butadiene and a norbornadiene | |
| ES386497A1 (en) | Process for polymerizing alpha-olefins | |
| US3227689A (en) | Process for the preparation of high molecular-weight formaldehyde polymers | |
| US2883367A (en) | Adducts of polyethylene and fumarates | |
| US2775594A (en) | Stabilization of polymerizable heterocyclic nitrogen compounds | |
| US3248375A (en) | Ethylene/vinyl chloride copolymerization using triethylborane and oxygen as cocatalysts at high pressure | |
| ES399408A1 (en) | Procedure for (co) polymerizing olefins. (Machine-translation by Google Translate, not legally binding) | |
| GB1079246A (en) | Process for the polymerization of ª-olefinic hydrocarbon material and catalyst compositions for effecting such polymerization | |
| UST875006I4 (en) | Defensive publication |