USRE43387E1 - Anchored oxide coatings on hard metal cutting tools - Google Patents

Anchored oxide coatings on hard metal cutting tools Download PDF

Info

Publication number
USRE43387E1
USRE43387E1 US12/511,394 US51139496A USRE43387E US RE43387 E1 USRE43387 E1 US RE43387E1 US 51139496 A US51139496 A US 51139496A US RE43387 E USRE43387 E US RE43387E
Authority
US
United States
Prior art keywords
coating
cutting tool
carbonitride
metal
tool insert
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US12/511,394
Other languages
English (en)
Inventor
Roy V. Leverenz
John Bost
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kennametal Inc
Original Assignee
TDY Industries LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TDY Industries LLC filed Critical TDY Industries LLC
Priority to US12/511,394 priority Critical patent/USRE43387E1/en
Assigned to TELEDYNE INDUSTRIES, INC. reassignment TELEDYNE INDUSTRIES, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BOST, JOHN, LEVERENZ, ROY V.
Assigned to TDY INDUSTRIES, INC. reassignment TDY INDUSTRIES, INC. CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). Assignors: TELEDYNE INDUSTRIES, INC.
Assigned to TDY Industries, LLC reassignment TDY Industries, LLC CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). Assignors: TDY INDUSTRIES, INC.
Application granted granted Critical
Publication of USRE43387E1 publication Critical patent/USRE43387E1/en
Assigned to KENNAMETAL INC. reassignment KENNAMETAL INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: TDY Industries, LLC
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/34—Nitrides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/36—Carbonitrides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/40—Oxides
    • C23C16/403—Oxides of aluminium, magnesium or beryllium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495—Thickness [relative or absolute]
    • Y10T428/24967—Absolute thicknesses specified
    • Y10T428/24975—No layer or component greater than 5 mils thick
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
    • Y10T428/264—Up to 3 mils
    • Y10T428/265—1 mil or less

Definitions

  • the present invention relates to the field of cutting tools and particularly to coatings for ceramic coated hard metal cutting tool inserts used for cutting, milling, drilling and other applications such as boring, trepanning, threading and grooving.
  • Coatings improve the performance of cutting tools, especially ceramic or oxide coatings on carbide or hard metal cutting tools.
  • carbide cutting tool inserts have been ceramic coated with, for example, aluminum oxide (Al 2 O 3 )
  • Al 2 O 3 aluminum oxide
  • the oxygen in the aluminum oxide reacted with the substrate which reduced the adherence.
  • TiCN titanium carbonitride
  • the ceramic coating (Al 2 O 3 ) does not adhere well enough to the TiC and many TiCN intermediate coatings when used to enhance the adhesion of the coating to the cemented carbide substrate. Due to thermal expansion differences, there is a tendency to delaminate. With the stress caused by the thermal expansion difference, coatings tend to perform inconsistently. These intermediate coatings are mostly characterized by a straight line interface between the intermediate coating and the oxide coating as shown in FIG. 1 . This results in a weak bond. Adhesion may be increased some by making the substrate rough but the projections provided by the roughening are spaced too far apart to perform consistently.
  • coatings according to the present invention, increased wear resistance as well as adhesion strength are provided in ceramic coatings on hard metal cutting tools.
  • a cutting tool insert comprising a hard metal substrate having at least two wear-resistant coatings.
  • One of the coatings is a ceramic coating.
  • An intermediate coating under the ceramic coating is comprised of carbonitride having a nitrogen to carbon-plus-nitrogen atomic ratio between about 0.7 and about 0.95 whereby the carbonitride coating forms fingers interlocking the ceramic coating, thus improving the adherence and fatigue strength of the ceramic coating.
  • the nitrogen to carbon-plus-nitrogen atomic ratio in the carbonitride coating lies between about 0.75 and 0.95 as determined by X-ray diffraction.
  • the hard metal cutting tool insert has two intermediate coatings between the hard metal substrate and the aluminum oxide surface coating.
  • the coating adjacent the substrate is a 1 to 4 micron layer of titanium nitride.
  • the coating over the titanium nitride layer is a 2 to 4 micron thick titanium carbonitride layer and the aluminum oxide coating is a 1 to 10 micron layer.
  • the hard metal substrate of the cutting tool insert has four coatings as follows: a 2 micron titanium nitride interior coating, a 3 micron titanium carbonitride intermediate coating, a 6 micron aluminum oxide intermediate coating, and a 2 micron Ti (C,N), i.e., TiC, TiN, TiC x N y exterior coating.
  • Titanium is not the only suitable metal for use in the carbonitride coating.
  • the metal may be comprised of, in addition to titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten.
  • the cutting tool insert substrate typically comprises 3% to 30% of a binder metal from the iron group including, in addition to iron, nickel and cobalt and mixtures thereof and between 70% and 97% of a carbide selected from the group tungsten carbide, titanium carbide, tantalum carbide, niobium carbide, molybdenum carbide, zirconium carbide and hafnium carbide.
  • a carbide selected from the group tungsten carbide, titanium carbide, tantalum carbide, niobium carbide, molybdenum carbide, zirconium carbide and hafnium carbide.
  • the cutting tool insert substrate may also include nitrides.
  • the cutting tool insert substrate has a binder phase enriched surface layer, that is, a surface layer enriched with a higher percentage of cobalt or other binder.
  • a method of making a coated cutting tool insert having a wear-resistant coating comprising the steps of depositing a metal carbonitride coating having a nitrogen to carbon-plus-nitrogen atomic ratio between about 0.7 and about 0.95 by adjusting the reactants used for chemical vapor deposition of said coating and depositing a ceramic coating directly over said carbonitride coating whereby said carbonitride coating and ceramic coating have interlocking microscopic fingers.
  • FIG. 1 is a photomicrograph of a polished section of a hard metal cutting tool insert having an oxide coating and an intermediate coating according to the prior art
  • FIGS. 2-4 are photomicrographs of polished sections of hard metal cutting tool inserts, according to this invention, having an intermediate coating and an oxide coating.
  • hard metal cutting tools with a ceramic or oxide wear-resistant coating have a novel reinforcing intermediate coating.
  • the hard metal substrate has a thin metal nitride coating overlaid with a titanium carbonitride coating.
  • the wear-resistant ceramic coating overlays the metal carbonitride coating.
  • the metal carbonitride intermediate layer is provided with a nitrogen to carbon-plus-nitrogen atomic ratio that results in superior adherence of the oxide coating due to the development of interlocking fingers between the oxide coating and the metal carbonitride coating.
  • the test is performed on a turning machine.
  • the stock is a cylindrical bar having a diameter greater than about 4 inches.
  • the bar has four axial slots 3 ⁇ 4 inch wide and 11 ⁇ 2 inches deep extending the length of the bar.
  • the bar is medium carbon steel AISI-SAE 1045 having a hardness of 25-30 HRC.
  • the tools to be tested were used to reduce the diameter of the stock as follows.
  • Feed Rate Speed (inches per Depth of Cut (surface feet per revolution or IPR) (inches) minute or SFM) .020 .050 500
  • the cutting tool insert impacts the edge of a slot.
  • the cutting tool insert is run until it breaks through the coating or another failure is observed. Failures were observed in the following described test and were of the fretting type which is a precursor to the greater wear and cutting failure type.
  • the nitrogen to carbon atomic ratio in the titanium carbonitride intermediate layer or coating was determined by use of X-ray diffraction to first detect the lattice spacing of the carbonitride layer and then to calculate the atomic ratio of nitrogen to carbon or the atomic percentage of nitrogen based upon nitrogen and carbon.
  • the lattice spacing of titanium carbide is known to be 1.53 Angstroms and the lattice spacing for titanium nitride is known to be 1.5 Angstroms. The range or difference is 0.03 Angstroms.
  • a titanium carbonitride layer found to have a lattice spacing of 1.5073 Angstroms is 0.0227 Angstroms between the spacing for titanium nitride and titanium carbide.
  • the atomic ratio of nitrogen to carbon-plus-nitrogen is 0.0227 divided by 0.03 or 75.7% nitrogen based on total carbon and nitrogen in the carbonitride layer.
  • a tungsten carbide based substrate (94% tungsten carbide, 6% cobalt) of K20 material (K20 is a designation of the type of hard cutting material for machining as set forth in ISO Standard IS0513:1991(E) classified according to the materials and working conditions for which the hard metal cutting material can appropriately be used) was coated according to well-known procedures in a Bernex Programmat 250 coating furnace.
  • the coating process known as chemical vapor deposition (CVD) was used where gasses and liquids (converted to gas) are passed over substrates to be coated at 800° to 1,100° C. and reduced pressures from 50 to 900 mBAR.
  • CVD chemical vapor deposition
  • the reactions used to coat the hard metal substrate were as follows: CVD of TiN ⁇ uses H 2 +N 2 +Titanium Tetrachloride (TiCl 4 ) CVD of TiCN ⁇ uses H 2 +N 2 +TiCl 4 +Acetonitrile (CH 3 CN) or CH 4 CVD of Al 2 O 3 ⁇ uses H 2 +HCl+Aluminum Chloride (AlCl 2 )+CO 2 +H 2 S
  • the essential coating periods and atmospheres used to apply the titanium nitride layer, the titanium carbonitride layer and the oxide layer are set forth in the following Tables I, II and III.
  • the gas reactants, the product of the AlCl 3 reactor and the liquid reactions are introduced to the furnace.
  • X-ray analysis of the titanium carbonitride layer demonstrated a lattice spacing of 1.516 Angstroms which, based on the analysis explained above, represents a nitrogen to carbon-plus-nitrogen atomic ratio of 14:30 or a nitrogen content of 46.7% based on the total carbon and nitrogen in the carbonitride layer.
  • the coated tool according to this example was submitted to the above-described machining test. After only 14.5 seconds, fretting was displayed.
  • FIG. 1 is a photomicrograph of a polished section showing the layers or coatings over the substrate. Notice that the interface between the titanium carbonitride and oxide layer is almost a straight line, that is, there are no interlocking fingers.
  • Tables IV, V and VI in addition to showing the run times, reaction pressures and temperatures, show the rate of gas reactants, aluminum chloride generator reactants and the liquid reactants.
  • the gas reactants introduced into the aluminum chloride generator flow over aluminum metal chips producing a quantity of aluminum chloride which is passed into the coating furnace.
  • X-ray analysis of the titanium carbonitride layer demonstrated a lattice spacing of 1.5073 which, based on the analysis explained above, represents a nitrogen to carbon-plus-nitrogen atomic ratio of 23:30 or a nitrogen content of 75.7% based upon the total carbon and nitrogen in the carbonitride layer.
  • FIG. 2 is a photomicrograph of a polished section showing the layers of coating over the substrate. The photomicrograph illustrates fingers or anchors of the titanium carbonitride layer penetrating the oxide layer and anchoring it in place.
  • Example III was prepared the same as Example II except the nitrogen was lower in the coating furnace during the deposition of the carbonitride layer.
  • the lattice spacing in the titanium carbonitride layer was found to be 1.509 which represents a nitrogen to carbon-plus-nitrogen atomic ratio of 21:30 or a nitrogen content of 70%.
  • Example IV was prepared the same as Example II except with increased nitrogen flow.
  • the lattice spacing of the titanium carbonitride layer was 1.503 Angstroms which represents a nitrogen to carbon-plus-nitrogen atomic ratio of 27:30 or 90% nitrogen.
  • the tool insert displayed no fretting after 120 seconds.
  • the microstructure of Example IV is shown in FIG. 4 and illustrates prominent fingers or anchors extending between the carbonitride layer and the oxide layer.
  • tool inserts coated according to this invention were machine tested with the following cutting conditions.
  • the stock was 3,000 gray cast iron 200 BHN.
  • the tools tested were used to reduce the diameter of the stock as follows.
  • Feed Rate Speed (inches per Depth of Cut (surface feet per revolution or IPR) (inches) minute or SFM) .022 .100 950
  • the stock for the machining test was ARMA steel 250 BHN.
  • the machining conditions were as follows.
  • Feed Rate Speed (inches per Depth of Cut (surface feet per revolution or IPR) (inches) minute or SFM) .010 .100 1,200

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Chemical Vapour Deposition (AREA)
  • Physical Vapour Deposition (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Ceramic Products (AREA)
  • Scissors And Nippers (AREA)
  • Dowels (AREA)
US12/511,394 1995-10-27 1996-10-23 Anchored oxide coatings on hard metal cutting tools Expired - Lifetime USRE43387E1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US12/511,394 USRE43387E1 (en) 1995-10-27 1996-10-23 Anchored oxide coatings on hard metal cutting tools

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US595295P 1995-10-27 1995-10-27
US08/860,163 US5958569A (en) 1995-10-27 1996-10-23 Anchored oxide coatings on hard metal cutting tools
PCT/US1996/017107 WO1997015411A1 (fr) 1995-10-27 1996-10-23 Revetements en oxide ancres pour outils coupants en metal dur
US12/511,394 USRE43387E1 (en) 1995-10-27 1996-10-23 Anchored oxide coatings on hard metal cutting tools

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US08/860,163 Reissue US5958569A (en) 1995-10-27 1996-10-23 Anchored oxide coatings on hard metal cutting tools

Publications (1)

Publication Number Publication Date
USRE43387E1 true USRE43387E1 (en) 2012-05-15

Family

ID=21718533

Family Applications (2)

Application Number Title Priority Date Filing Date
US12/511,394 Expired - Lifetime USRE43387E1 (en) 1995-10-27 1996-10-23 Anchored oxide coatings on hard metal cutting tools
US08/860,163 Ceased US5958569A (en) 1995-10-27 1996-10-23 Anchored oxide coatings on hard metal cutting tools

Family Applications After (1)

Application Number Title Priority Date Filing Date
US08/860,163 Ceased US5958569A (en) 1995-10-27 1996-10-23 Anchored oxide coatings on hard metal cutting tools

Country Status (14)

Country Link
US (2) USRE43387E1 (fr)
EP (1) EP0857095B1 (fr)
CN (1) CN1101287C (fr)
AT (1) ATE258834T1 (fr)
BR (1) BR9611817A (fr)
CA (1) CA2235807C (fr)
DE (1) DE69631484T2 (fr)
DK (1) DK0857095T3 (fr)
ES (1) ES2215198T3 (fr)
HK (1) HK1016524A1 (fr)
PT (1) PT857095E (fr)
TW (1) TW429181B (fr)
WO (1) WO1997015411A1 (fr)
ZA (1) ZA968986B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9627500B2 (en) 2015-01-29 2017-04-18 Samsung Electronics Co., Ltd. Semiconductor device having work-function metal and method of forming the same

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6447890B1 (en) * 1997-06-16 2002-09-10 Ati Properties, Inc. Coatings for cutting tools
US6086953A (en) * 1997-07-01 2000-07-11 Raghavan; Srimathy Ceramic-coated metal guide pin
US6764255B1 (en) 1999-10-15 2004-07-20 Seagate Technology Llc Cutting tool for precision machining a hydrodynamic bearing bore in stainless steel sleeve
DE10002861A1 (de) * 2000-01-24 2001-08-09 Walter Ag Zerspannungswerkzeug mit Carbonitrid-Beschichtung
SE520253C2 (sv) 2000-12-19 2003-06-17 Sandvik Ab Belagt hårdmetallskär
SE526602C2 (sv) * 2003-10-27 2005-10-18 Seco Tools Ab Belagt skär för grovsvarvning
US7455918B2 (en) * 2004-03-12 2008-11-25 Kennametal Inc. Alumina coating, coated product and method of making the same
US7581906B2 (en) * 2004-05-19 2009-09-01 Tdy Industries, Inc. Al2O3 ceramic tools with diffusion bonding enhanced layer
SE533972C2 (sv) 2009-07-27 2011-03-15 Seco Tools Ab Finkornigt belagt hårdmetallskärverktygsskär för svarvning i härdat stål och verktygsstål
JP5569739B2 (ja) * 2009-10-30 2014-08-13 三菱マテリアル株式会社 耐チッピング性にすぐれた表面被覆切削工具
JP5569740B2 (ja) * 2010-03-23 2014-08-13 三菱マテリアル株式会社 耐チッピング性にすぐれた表面被覆切削工具
JP6041160B2 (ja) * 2012-04-19 2016-12-07 住友電工ハードメタル株式会社 表面被覆切削工具
CN103334041B (zh) * 2013-06-21 2015-11-18 上海工程技术大学 一种具有表面涂层的硬质合金及其制备工艺
JP6831448B2 (ja) * 2017-02-28 2021-02-17 住友電工ハードメタル株式会社 表面被覆切削工具およびその製造方法
KR102431159B1 (ko) * 2018-03-20 2022-08-10 교세라 가부시키가이샤 인서트 및 이것을 구비한 절삭공구
CN108478259A (zh) * 2018-05-01 2018-09-04 雷霆 一种组合式耐用型手术刀及其制备方法
US20220205109A1 (en) * 2019-05-27 2022-06-30 Ab Sandvik Coromant Coated cutting tool
US20220250163A1 (en) * 2019-07-29 2022-08-11 Kyocera Corporation Coated tool and cutting tool including the same
WO2021020367A1 (fr) * 2019-07-29 2021-02-04 京セラ株式会社 Outil revêtu et outil de coupe comprenant un tel outil revêtu
JP7337168B2 (ja) * 2019-07-29 2023-09-01 京セラ株式会社 被覆工具およびそれを備えた切削工具
JP7301971B2 (ja) * 2019-07-29 2023-07-03 京セラ株式会社 被覆工具およびそれを備えた切削工具

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4101703A (en) * 1972-02-04 1978-07-18 Schwarzkopf Development Corporation Coated cemented carbide elements
US4610931A (en) * 1981-03-27 1986-09-09 Kennametal Inc. Preferentially binder enriched cemented carbide bodies and method of manufacture
US5372873A (en) * 1992-10-22 1994-12-13 Mitsubishi Materials Corporation Multilayer coated hard alloy cutting tool

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5296911A (en) * 1976-02-10 1977-08-15 Mitsubishi Metal Corp Coated cutting chip made of hard alloy
JPS5952703B2 (ja) * 1979-07-02 1984-12-21 三菱マテリアル株式会社 表面被覆超硬合金部材
JPH07122139B2 (ja) * 1989-08-29 1995-12-25 日立ツール株式会社 被覆超硬合金工具の製造方法
JP2932853B2 (ja) * 1992-08-11 1999-08-09 三菱マテリアル株式会社 耐チッピング性にすぐれた表面被覆炭窒化チタン基サーメット製切削工具
US5436071A (en) * 1990-01-31 1995-07-25 Mitsubishi Materials Corporation Cermet cutting tool and process for producing the same
JP3161088B2 (ja) * 1992-09-28 2001-04-25 三菱マテリアル株式会社 表面被覆ｗｃ基超硬合金製切削工具
SE514737C2 (sv) * 1994-03-22 2001-04-09 Sandvik Ab Belagt skärverktyg av hårdmetall

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4101703A (en) * 1972-02-04 1978-07-18 Schwarzkopf Development Corporation Coated cemented carbide elements
US4101703B1 (fr) * 1972-02-04 1989-01-24
US4610931A (en) * 1981-03-27 1986-09-09 Kennametal Inc. Preferentially binder enriched cemented carbide bodies and method of manufacture
US5372873A (en) * 1992-10-22 1994-12-13 Mitsubishi Materials Corporation Multilayer coated hard alloy cutting tool

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9627500B2 (en) 2015-01-29 2017-04-18 Samsung Electronics Co., Ltd. Semiconductor device having work-function metal and method of forming the same
US10388574B2 (en) 2015-01-29 2019-08-20 Samsung Electronics Co., Ltd. Semiconductor device having work-function metal and method of forming the same
US10734288B2 (en) 2015-01-29 2020-08-04 Samsung Electronics Co., Ltd. Semiconductor device having work-function metal and method of forming the same
US11043430B2 (en) 2015-01-29 2021-06-22 Samsung Electronics Co., Ltd. Semiconductor device having work-function metal and method of forming the same
US11462442B2 (en) 2015-01-29 2022-10-04 Samsung Electronics Co., Ltd. Semiconductor device having work-function metal and method of forming the same
US11929289B2 (en) 2015-01-29 2024-03-12 Samsung Electronics Co., Ltd. Semiconductor device having work-function metal and method of forming the same

Also Published As

Publication number Publication date
DE69631484T2 (de) 2004-12-16
CA2235807A1 (fr) 1997-05-01
CN1101287C (zh) 2003-02-12
EP0857095A4 (fr) 2001-02-14
EP0857095B1 (fr) 2004-02-04
US5958569A (en) 1999-09-28
TW429181B (en) 2001-04-11
CN1202845A (zh) 1998-12-23
HK1016524A1 (en) 1999-11-05
PT857095E (pt) 2004-06-30
DK0857095T3 (da) 2004-03-08
BR9611817A (pt) 1999-12-28
CA2235807C (fr) 2001-07-24
ES2215198T3 (es) 2004-10-01
ATE258834T1 (de) 2004-02-15
WO1997015411A1 (fr) 1997-05-01
EP0857095A1 (fr) 1998-08-12
DE69631484D1 (de) 2004-03-11
ZA968986B (en) 1997-04-25

Similar Documents

Publication Publication Date Title
USRE43387E1 (en) Anchored oxide coatings on hard metal cutting tools
US6827975B2 (en) Method of coating cutting tools
US6214247B1 (en) Substrate treatment method
US5750247A (en) Coated cutting tool having an outer layer of TiC
US7648736B2 (en) Coated cutting tool for turning of steel
US4686156A (en) Coated cemented carbide cutting tool
US4268582A (en) Boride coated cemented carbide
US4357382A (en) Coated cemented carbide bodies
US4525415A (en) Sintered hard metal products having a multi-layer wear-resistant coating
USRE32111E (en) Coated cemented carbide bodies
EP0149024B2 (fr) Corps composite revêtu résistant à l'usure et procédé de sa fabrication
GB2048960A (en) Coating Articles With Layers of Hard Materials
US20170356091A1 (en) Multilayer structured coatings for cutting tools
CA1327277C (fr) Outil de coupe a mises rapportees en carbure dote d'un revetement multicouche
US20030022029A1 (en) Surface coated sintered alloy member
EP0792390B1 (fr) Insert en carbure fritte revetu pour applications de coupe de metal
Kübel New developments in chemically vapour-deposited coatings from an industrial point of view
JPH0364469A (ja) 被覆超硬質合金工具
AU761003B2 (en) Substrate treatment method
RU2173241C2 (ru) Пластина режущего инструмента и способ ее изготовления
KR100534293B1 (ko) 경금속 절삭공구의 고정 산화물 코팅제
JPS5952704B2 (ja) 切削工具用表面被覆サ−メツト部材

Legal Events

Date Code Title Description
AS Assignment

Owner name: TDY INDUSTRIES, INC., PENNSYLVANIA

Free format text: CHANGE OF NAME;ASSIGNOR:TELEDYNE INDUSTRIES, INC.;REEL/FRAME:028018/0728

Effective date: 19991223

Owner name: TDY INDUSTRIES, LLC, PENNSYLVANIA

Free format text: CHANGE OF NAME;ASSIGNOR:TDY INDUSTRIES, INC.;REEL/FRAME:028018/0737

Effective date: 20120102

Owner name: TELEDYNE INDUSTRIES, INC., TENNESSEE

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:LEVERENZ, ROY V.;BOST, JOHN;REEL/FRAME:028016/0768

Effective date: 19970528

AS Assignment

Owner name: KENNAMETAL INC., PENNSYLVANIA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:TDY INDUSTRIES, LLC;REEL/FRAME:032108/0389

Effective date: 20131104