USRE42004E1 - Method for fabricating a semiconductor storage device having an increased dielectric film area - Google Patents
Method for fabricating a semiconductor storage device having an increased dielectric film area Download PDFInfo
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- USRE42004E1 USRE42004E1 US11/655,744 US65574407A USRE42004E US RE42004 E1 USRE42004 E1 US RE42004E1 US 65574407 A US65574407 A US 65574407A US RE42004 E USRE42004 E US RE42004E
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Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L28/00—Passive two-terminal components without a potential-jump or surface barrier for integrated circuits; Details thereof; Multistep manufacturing processes therefor
- H01L28/40—Capacitors
- H01L28/60—Electrodes
- H01L28/82—Electrodes with an enlarged surface, e.g. formed by texturisation
- H01L28/90—Electrodes with an enlarged surface, e.g. formed by texturisation having vertical extensions
- H01L28/92—Electrodes with an enlarged surface, e.g. formed by texturisation having vertical extensions made by patterning layers, e.g. by etching conductive layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/401—Multistep manufacturing processes
- H01L29/4011—Multistep manufacturing processes for data storage electrodes
- H01L29/40114—Multistep manufacturing processes for data storage electrodes the electrodes comprising a conductor-insulator-conductor-insulator-semiconductor structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/41—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
- H01L29/423—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions not carrying the current to be rectified, amplified or switched
- H01L29/42312—Gate electrodes for field effect devices
- H01L29/42316—Gate electrodes for field effect devices for field-effect transistors
- H01L29/4232—Gate electrodes for field effect devices for field-effect transistors with insulated gate
- H01L29/42324—Gate electrodes for transistors with a floating gate
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B41/00—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
- H10B41/30—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the memory core region
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/30—EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B12/00—Dynamic random access memory [DRAM] devices
- H10B12/01—Manufacture or treatment
- H10B12/02—Manufacture or treatment for one transistor one-capacitor [1T-1C] memory cells
- H10B12/03—Making the capacitor or connections thereto
- H10B12/033—Making the capacitor or connections thereto the capacitor extending over the transistor
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B53/00—Ferroelectric RAM [FeRAM] devices comprising ferroelectric memory capacitors
- H10B53/30—Ferroelectric RAM [FeRAM] devices comprising ferroelectric memory capacitors characterised by the memory core region
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S438/00—Semiconductor device manufacturing: process
- Y10S438/942—Masking
- Y10S438/947—Subphotolithographic processing
Definitions
- the present invention relates to a semiconductor device including a memory cell having a composite gate structure or a semiconductor device including a stacked memory cell capacitor and a method of fabricating the same.
- At least a portion of a polysilicon film as a floating gate electrode is formed by CVD under conditions by which a larger number of fine undulations are formed on the surface of the floating gate electrode, and an insulating interlayer and a control gate electrode are formed along the undulations on the surface of the floating gate electrode.
- a recess is formed in substantially the center of a floating gate electrode to increase the capacitance between the floating gate electrode and a control gate electrode. Consequently, an effect similar to the effect of the above prior art is achieved.
- the capacitance of a memory cell capacitor can also be increased by forming undulations on the surface of a lower electrode.
- Japanese Patent Laid-Open No. 5-243515 has described a method of increasing the charge storage amount by forming a rectangular or cylindrical trench in a lower electrode of a stacked memory cell capacitor.
- the recess is formed in substantially the center of the floating gate electrode after a polysilicon film serving as the floating gate electrode is formed. Therefore, it is unavoidable to complicate the fabrication steps and increase the number of the fabrication steps. Also, the end point of etching for forming the recess is difficult to determine. Accordingly, the recess may sometimes extend through the polysilicon film to separate the floating gate electrode.
- the trench is formed by etching after stacked polysilicon serving as the lower electrode is formed. Accordingly, the fabrication steps are complicated and the number of the fabrication steps is increased. Furthermore, the end point of the etching cannot be easily determined.
- a semiconductor device of the present invention is a semiconductor device including an element active region defined by forming an element isolation structure on a semiconductor substrate, comprising an island-like charge storage film formed across the element isolation structure and the element active region so as to be formed on the element active region through an insulating film, the charge storage film having a recess in a surface on the element active region and a hole formed on the element isolation structure to reach the element isolation structure, a dielectric film so formed as to cover the surface of the charge storage film including inner surfaces of the hole, and a conductive film formed on the dielectric film and capacitively coupled with the charge storage film.
- Another aspect of the semiconductor device of the present invention is a semiconductor device including an element active region defined by forming an element isolation structure on a semiconductor substrate, comprising an island-like charge storage film formed across the element isolation structure and the element active region so as to be formed on the element active region through an insulating film, the charge storage film having a recess in a surface on the element active region and a hole formed on the element isolation structure to reach the element isolation structure, and a conductive film formed on the charge storage film.
- Still another aspect of the semiconductor device of the present invention is a semiconductor device including an element active region defined by forming an element isolation structure on a semiconductor substrate and having a transistor constituted by a gate electrode and a pair of impurity diffusion layers in the element active region, comprising an insulating interlayer formed on the semiconductor substrate including the transistor, a first hole formed in the insulating interlayer and having a surface layer of the impurity diffusion layer as a bottom surface, an island-like charge storage film electrically connected to one of the impurity diffusion layers through the first hole, a second hole formed in the charge storage film and having a surface layer of the insulating interlayer as a bottom surface, a dielectric film so formed as to cover a surface of the charge storage film including inner surfaces of the second hole, and a conductive film formed on the dielectric film and capacitively coupled with the charge storage film, wherein the charge storage film, the dielectric film, and the conductive film constitute a capacitor.
- Still another aspect of the semiconductor device of the present invention is a semiconductor device including an element active region defined by forming an element isolation structure on a semiconductor substrate, comprising an insulating film formed on the semiconductor substrate in the element active region, and a charge storage film patterned on the insulating film, wherein the charge storage film is formed across the element isolation structure and has a hole on the element isolation structure, and at least a portion of a bottom surface of the hole reaches a surface layer of the element isolation structure.
- Still another aspect of the semiconductor device of the present invention is a semiconductor device including a plurality of element isolation regions defined by forming an element isolation structure on a semiconductor substrate, comprising an island-like charge storage film formed across the element isolation structure and the element active regions and having a recess, a dielectric film so formed as to cover a surface of the charge storage film, and a conductive film formed on the dielectric film and capacitively coupled with the charge storage film, wherein the charge storage film is formed in each of the element active regions, and an upper surface of each of the charge storage films is planarized by CMP and flush with an upper surface of an adjacent charge storage film.
- a method of fabricating a semiconductor device comprises the first step of defining an element active region by forming an element isolation structure on a semiconductor substrate, the second step of forming an insulating film on the semiconductor substrate in the element active region, the third step of forming a first conductive film on an entire surface of the semiconductor substrate including the insulating film and the element isolation structure, the fourth step of forming a mask pattern having first and second openings on the first conductive film, the fifth step of etching the first conductive film until the element isolation structure is exposed in the first opening by using the mask pattern as a mask, thereby dividing the first conductive film, and simultaneously forming a recess in the second opening having the first conductive film on a bottom of the recess, the sixth step of forming a dielectric film so as to cover a surface of the first conductive film, and the seventh step of forming a second conductive film on the dielectric film opposite the first conductive film and separated by the dielectric film.
- Another aspect of the method of fabricating a semiconductor device comprises the first step of defining an element active region by forming an element isolation structure on a semiconductor substrate, the second step of forming a gate insulating film and a gate electrode in the element active region, the third step of doping an impurity into the second substrate to form a pair of impurity diffusion layers in surface regions of the semiconductor substrate on two sides of the gate electrode, the fourth step of forming a first conductive film electrically connected to one of the impurity diffusion layers, the fifth step of forming a mask pattern having at least first and second openings on the first conductive film, the sixth step of etching the first conductive film by using the mask pattern as a mask, thereby dividing the first conductive film in the first opening, and simultaneously forming a recess in the second opening where the first conductive film is on a bottom of the recess, the seventh step of forming a dielectric film so as to cover a surface of the first conductive film, and the eighth step of forming a
- Still another aspect of the method of fabricating a semiconductor device comprises the first step of forming a first conductive film in an insulating film region on a semiconductor substrate, the second step of forming a mask pattern having two types of openings on the first conductive film, the third step of etching the first conductive film by using the mask pattern as a mask, thereby dividing the first conductive film conforming to a shape of one of the openings, and simultaneously forming at least one recess in a surface of the divided first conductive film conforming to a shape of the other opening, the fourth step of forming an insulating film so as to cover a surface of the first conductive film, and the fifth step of forming a second conductive film so as to cover a surface of the insulating film and opposing the second conductive film to the first conductive film through the insulating film.
- Still another aspect of the method of fabricating a semiconductor device comprises the first step of defining an element active region by forming an element isolation structure on a semiconductor substrate, the second step of forming an insulating film on the semiconductor substrate in the element active region, the third step of forming a first conductive film on an entire surface including the insulating film and the element isolation structure, the fourth step of forming a mask pattern having at least first and second openings on the first conductive film, the fifth step of etching the first conductive film until the element isolation structure is exposed in the first and second openings by using the mask pattern as a mask, thereby dividing the first conductive film below the first opening, and simultaneously forming a hole extending through the first conductive film below the second opening, the sixth step of forming a dielectric film so as to cover the first conductive film, and the seventh step of forming a second conductive film on the dielectric film opposite the first conductive film and separated by the dielectric film.
- Still another aspect of the method of fabricating a semiconductor device comprises the first step of defining an element active region by forming an element isolation structure on a semiconductor substrate, the second step of forming a gate oxide film and a gate electrode on the semiconductor substrate in the element active region, the third step of doping an impurity into the semiconductor substrate in the element active region to form a pair of impurity diffusion layers in surface regions of the semiconductor substrate on two sides of the gate electrode, the fourth step of forming a first conductive film electrically connected to one of the impurity diffusion layers, the fifth step of forming a mask pattern having at least first and second openings on the first conductive film, the sixth step of etching the first conductive film by using the mask pattern as a mask, thereby dividing the first conductive film below the first opening, and simultaneously forming a hole extending through the first conductive film below the second opening, the seventh step of forming a dielectric film so as to cover a surface of the first conductive film, and the eighth step of forming a second
- a recess or a hole is formed in the charge storage film. Therefore, the area of the dielectric film can be increased to increase the charge storage amount. Especially when a hole is formed, the charge storage film and the conductive film can be opposite to each other and separated by the dielectric film within the range from the lower surface to the upper surface of the hole. Consequently, the charge storage amount can be effectively increased.
- the first conductive film (charge storage film) is divided by etching along the first opening in a mask pattern.
- a recess or hole can be formed by self-alignment along the second opening in the mask pattern.
- the width of the first opening is twice or more the width of the second opening, it is possible to decrease the etching rate in the second opening by a micro-loading effect and reliably form the recess without dividing the first conductive film.
- the first conductive film is formed across the step between the element isolation structure and the element active region, the first conductive film is etched after its surface is planarized by polishing. Accordingly, even when etching is performed until the element isolation structure is exposed along the first opening, a recess can be formed without dividing the first conductive film in the second opening formed above the element active region.
- the first conductive film is etched until the underlying stacked film is exposed in the first and second openings. Consequently, it is possible to divide the first conductive film along the first opening and form a hole along the second opening.
- the present invention can provide a semiconductor device which includes a composite gate structure memory cell or a stacked memory cell capacitor and in which the capacitance of the floating gate or the memory cell capacitor is effectively increased, and a method of stably and reliably fabricating this semiconductor device.
- the present invention contributes to further development of these semiconductor devices.
- FIGS. 1A to 1 G are schematic sectional views showing a method of fabricating an EEPROM according to the first embodiment in order of steps;
- FIGS. 2A to 2 J are schematic sectional views showing the method of fabricating the EEPROM according to the first embodiment in order of steps;
- FIG. 3 is a schematic plan view showing the EEPROM according to the first embodiment
- FIGS. 4A to 4 C are schematic sectional views showing a method of fabricating an EEPROM according to a modification of the first embodiment in order of steps;
- FIG. 5 is a schematic plan view showing the EEPROM according to the modification of the first embodiment shown in FIGS. 4A to 4 C;
- FIGS. 6A to 6 C are schematic views showing a method of fabricating an EEPROM according to another modification of the first embodiment in order of steps;
- FIG. 7 is a schematic view showing the EEPROM according to the modification of the first embodiment shown in FIGS. 6A to 6 C;
- FIGS. 8A to 8 D are schematic sectional views showing a method of fabricating an EEPROM according to the second embodiment in order of steps;
- FIG. 9 is a schematic plan view showing the EEPROM according to the second embodiment.
- FIGS. 10A to 10 K are schematic sectional views showing a method of fabricating a stacked capacitor cell structure DRAM according to the third embodiment in order of steps;
- FIG. 11 is a schematic plan view showing the stacked capacitor cell structure DRAM according to the third embodiment.
- FIGS. 12A to 12 E are schematic sectional views showing a method of fabricating a stacked capacitor cell structure DRAM according to a modification of the third embodiment in order of steps;
- FIG. 13 is a schematic plan view showing the stacked capacitor cell structure DRAM according to the modification of the third embodiment shown in FIGS. 12A to 12 E;
- FIGS. 14A to 14 E are schematic sectional views showing a method of fabricating a stacked capacitor cell structure DRAM according to another modification of the third embodiment in order of steps;
- FIG. 15 is a schematic plan view showing the stacked capacitor cell structure DRAM according to the modification of the third embodiment shown in FIGS. 14A to 14 E;
- FIG. 16 is a schematic plan view showing the EEPROM according to the first embodiment.
- FIG. 17 is a flow chart showing a read method of the EEPROM according to the first embodiment.
- FIGS. 1A to 1 G and 2 A to 2 J are side sectional views showing the fabrication steps of the EEPROM memory cell according to the first embodiment.
- FIG. 3 is a schematic plan view showing a memory cell region of the EEPROM. A section I—I in FIG. 3 corresponds to FIGS. 1A to 1 G; and a section II—II, to FIGS. 2A to 2 J.
- the surface of a p-type silicon semiconductor substrate 1 is selectively oxidized by a so-called LOCOS process to form a field oxide film 2 . Consequently, element isolation is achieved on the p-type silicon semiconductor substrate 1 to define element formation regions 3 .
- the element formation regions on the p-type silicon semiconductor substrate 1 are thermally oxidized to form a tunnel oxide film 4 having a thickness of about 100 ⁇ , thereby obtaining the state shown in FIGS. 1A and 2A .
- a polysilicon film 5 having a thickness of about 5,000 ⁇ is formed on the entire surface of the field oxide film 2 and the tunnel oxide film 4 by adding a dopant gas by low-pressure CVD.
- an undoped polysilicon film 5 may be formed and given conductivity by ion-implanting an impurity such as arsenic. This state is shown in FIG. 2 B.
- a photoresist 6 is formed on the polysilicon film 5 by photolithography.
- a photoresist opening 7 is formed by forming an opening about 0.6 ⁇ m wide in a region for isolating floating gate electrodes 9 to be formed later.
- photoresist openings 8 are formed by forming openings about 0.25 ⁇ m wide in regions corresponding to substantially the center of the width of the tunnel oxide film 4 .
- the polysilicon film 5 is selectively removed by dry etching until the surface of the field oxide film 2 below the photoresist opening 7 is exposed. Since the width of the photoresist openings 8 is smaller than the half width of the photoresist opening 7 , the supply of the etchant is reduced by a microloading effect when the polysilicon film 5 exposed in the photoresist openings 8 is etched. As a consequence, the etching rate is decreased in these portions.
- the progress in etching the polysilicon film 5 exposed in the photoresist opening 7 is faster than the progress in etching the polysilicon film 5 exposed in the photoresist openings 8 . Accordingly, the polysilicon film 5 exposed in the photoresist opening 7 is removed first, and the underlying field oxide film 2 is exposed.
- a silicon oxide film about 50 ⁇ thick, a silicon nitride film about 40 ⁇ thick, and a silicon oxide film about 50 ⁇ thick are deposited in this order on the entire surface by LPCVD, thereby forming a dielectric film 10 made from an ONO film.
- a polysilicon film 11 having a thickness of about 1,500 ⁇ is formed on the dielectric film 10 by CVD and patterned together with the floating gate electrodes 9 and the dielectric film 10 , thereby completing composite gate electrodes 12 .
- This state is shown in FIGS. 1E and 2F .
- the floating gate electrodes 9 have the function of a charge storage film which stores electric charge in accordance with the voltage applied to the polysilicon film 11 .
- arsenic is ion-implanted into the surface region of the p-type silicon semiconductor substrate 1 to form a source region 13 and a drain region 14 as n-type impurity diffusion layers.
- Appropriate ion-implantation conditions are an acceleration energy of about 70 kev and a dose of about 5 ⁇ 10 15 /cm 2 .
- annealing is performed at 900° C. for about 30 min to activate the implanted arsenic, obtaining the state shown in FIG. 2 G.
- a BPSG film 15 as an insulating interlayer is deposited on the entire surface by CVD, and the surface is planarized by reflow. Thereafter, contact holes 16 , 17 , and 18 are formed in the BPSG film 15 to expose portions of the source region 13 , the polysilicon film 11 , and the drain region 14 , respectively. The result is the state shown in FIG. 2 I.
- a wiring pattern is formed by photolithography and subsequent dry etching to complete a memory cell of an EEPROM as shown in FIGS. 1F , 2 J, and 3 .
- the element formation regions 3 defined in the first step can also be defined by a method other than LOCOS.
- a shield gate oxide film is first formed on the p-type semiconductor substrate 1 , and a thin polysilicon film and a CVD oxide film are formed in this order on top of the shield gate oxide film.
- FIG. 1G shows a memory cell of an EEPROM having a field shield element isolation structure thus formed.
- a thin polysilicon film 24 covered with a CVD oxide film 23 is equivalent to a shield plate electrode.
- the width of the photoresist openings 8 is made smaller than the half width of the photoresist opening 7 . Consequently, even when the polysilicon film 5 exposed in the photoresist opening 7 is etched away to expose the underlying field oxide film 2 , the polysilicon film 5 is left behind on the bottom surfaces of the photoresist openings 8 by the microloading effect, forming the recesses 20 in these portions.
- the bottom surfaces of the recesses 20 are reliably positioned above the surface of the field oxide film 2 by the microloading effect. This prevents the polysilicon film 5 from being divided by the recesses 20 . Accordingly, the floating gate electrodes 9 having the recesses 20 can be stably formed.
- the recesses 20 are formed by self-alignment at the same time the floating gate electrodes 9 are separated. Therefore, the recesses 20 can be formed without increasing the number of fabrication steps.
- the capacitance of the dielectric film 10 is increased by the recess 20 .
- the write and erase characteristics of the memory cell can be improved.
- FIGS. 4A to 4 C are side sectional views showing the steps in fabricating a memory cell of an EEPROM according to this modification.
- FIG. 5 is a schematic plan view showing a memory cell region of this EEPROM.
- a section I—I in FIG. 5 corresponds to FIGS. 4A to 4 C.
- the same reference numerals as in the EEPROM of the first embodiment denote the same parts, and a detailed description thereof will be omitted.
- FIG. 4A corresponds to the step shown in FIG. 1B of the first embodiment.
- the steps up to the state shown in FIG. 4A are the same as in the first embodiment.
- the number of openings in the photoresist 6 formed on the polysilicon film 5 is larger than in the first embodiment.
- substantially cylindrical photoresist openings 21 are formed between the photoresist openings 7 and the photoresist opening 8 in this modification.
- the polysilicon film 5 is selectively removed by dry etching. The etching is performed until the underlying field oxide film 2 is exposed in the photoresist opening 8 and the photoresist openings 21 . Consequently, as shown in FIG. 4B , substantially cylindrical openings 22 are formed, and the recesses 20 are formed in the photoresist openings 7 .
- the dielectric film 10 made from an ONO film is formed on the entire surface.
- the polysilicon film 11 is then formed by CVD and patterned to form the composite gate electrodes 12 .
- arsenic is ion-implanted to form the source and drain regions 13 and 14 (not shown), the BPSG film 15 is deposited and subjected to reflow, the contact holes 16 , 17 , and 18 are formed, and the aluminum alloy film 19 is deposited and patterned to complete a memory cell of an EEPROM as shown in FIGS. 4C and 5 .
- the substantially cylindrical openings 22 are additionally formed on the floating gate electrodes 9 . Accordingly, the capacitance of the dielectric film 10 can be further increased compared to the first embodiment. As a consequence, the write and erase characteristics of the memory cell can be further improved.
- the etching rate controlled by the microloading effect can be increased or decreased by properly changing the diameter of the photoresist openings 21 in the above modification.
- the diameter may be made smaller than in the above modification to set the same etching rate as the photoresist openings 7 , and the polysilicon film 5 may be removed to the extent to which the underlying field oxide film 2 is not exposed.
- substantially cylindrical photoresist openings 26 having a smaller diameter are formed between the photoresist openings 7 and 8 as shown in FIG. 6 A.
- the polysilicon film 5 is selectively removed by dry etching. In this etching, the polysilicon film 5 exposed in the photoresist openings 26 is also removed to form substantially cylindrical recesses 25 as shown in FIG. 6 B.
- the polysilicon film 11 is formed by CVD and patterned to form the composite gate electrodes 12 .
- arsenic is ion-implanted to form the source and drain regions 13 and 14 , the BPSG film 15 is deposited on the entire surface and subjected to reflow, the contact holes 16 , 17 , and 18 are formed, and the aluminum alloy film 19 is deposited and patterned to complete a memory cell of an EEPROM as shown in FIG. 6 C and the schematic plan view of FIG. 7 .
- the capacitance of the dielectric film 10 can be increased compared to the first embodiment. Consequently, the write and erase characteristics of the memory cell can be improved.
- FIGS. 8A to 8 D are side sectional views showing the steps in fabricating a memory cell of the EEPROM according to the second embodiment.
- FIG. 9 is a schematic plan view showing a memory cell region of this EEPROM. A section I—I in FIG. 9 corresponds to FIGS. 8A to 8 D.
- the same reference numerals as in the EEPROM of the first embodiment denote the same parts, and a detailed description thereof will be omitted.
- This second embodiment differs from the first embodiment in that after a polysilicon film 5 is formed, the surface of the polysilicon film 5 is planarized by chemical mechanical polishing (CMP) before the step of forming a photoresist 6 .
- CMP chemical mechanical polishing
- FIG. 8A is a view corresponding to the step shown in FIG. 2B of the first embodiment.
- the polysilicon film 5 having a thickness of about 1,000 ⁇ is formed by LPCVD on a field oxide film 2 and a gate oxide film 4 .
- the steps up to the state shown in FIG. 8A are the same as in the first embodiment.
- the surface of the polysilicon film 5 is planarized by chemical mechanical polishing (CMP).
- the photoresist 6 is formed on the polysilicon film 5 .
- a photoresist opening 7 is formed by forming an opening about 0.6 ⁇ m wide in a region for isolating floating gate electrodes 9 to be formed later.
- photoresist openings 8 are formed by forming openings about 0.6 ⁇ m wide in portions above regions corresponding to the centers of the floating gate electrodes 9 .
- the polysilicon film 5 is dry-etched by using the photoresist 6 as a mask, and the etching is stopped when the field oxide film 2 is exposed in the photoresist opening 7 .
- the surface of the polysilicon film 5 is previously planarized by chemical mechanical polishing described above. Therefore, when etching is stopped at the time the field oxide film 2 is exposed, the tunnel oxide film 4 is not exposed and recesses 20 are formed in the photoresist openings 8 due to the step between the surfaces of the field oxide film 2 and the tunnel oxide film 4 .
- the recesses 20 can be formed with high controllability at the same time the floating gate electrodes 9 are isolated. This state is shown in FIGS. 8D and 9 .
- a dielectric film 10 made from an ONO film (not shown) is formed, a polysilicon film 11 is formed by CVD, and these films are patterned to form composite gate electrodes 12 .
- a BPSG film 15 (not shown) is formed, and reflow is performed. Finally, contact holes 16 , 17 , and 18 are formed, and an aluminum alloy film 19 is formed and patterned to complete a memory cell of an EEPROM.
- the surface of the polysilicon film 5 is planarized before the photoresist 6 is formed. Therefore, even when etching is performed until the field oxide film 2 is exposed in the photoresist opening 7 , the recesses 20 can be reliably formed in the photoresist openings 8 without exposing the underlying tunnel oxide film 4 .
- the recesses 20 can be formed by leaving the polysilicon film 5 behind on the bottom surfaces with higher controllability.
- the recesses 20 can also be formed by self-alignment when the floating gate electrodes 9 are isolated.
- the photoresist 6 is formed on the planarized polysilicon film 5 and patterned by lithography. Therefore, the widths of the photoresist openings 7 and 8 can be set with high controllability during lithography.
- a nonvolatile memory such as an EEPROM or an EPROM using the floating gate electrodes 9 made from polysilicon as a charge storage film
- a stacked film of a silicon oxide film, a silicon nitride film, and a silicon oxide film may be used as a charge storage film
- the present invention may be applied to an MONOS type nonvolatile memory including this charge storage film, a control gate, a source, and a drain.
- the present invention may also be applied to an MNOS type nonvolatile memory including a charge storage film made from a stacked film of a silicon oxide film and a silicon nitride film, a control gate, a source, and a drain.
- the dielectric film 10 need not be formed. If this is the case, electric charge is stored in the interface of the silicon oxide film or the silicon nitride film.
- FIG. 16 is a schematic plan view showing an embodiment in which the source region 13 is formed by a diffusion layer commonly to the unit memory cells, and the gate electrode 22 of the access transister is formed commonly to the unit memory cells, over the first and second embodiments above described.
- the EEPROM can also be constituted as a so-called multi-valued memory by setting a predetermined value of two bits or more as a storage state. That is, if the storage state is n bits (2n values, n is an integer of 2 or more), it is only necessary to set 2n different threshold voltages. For example, if the storage state is two bits (four values), four different reference voltages (threshold voltages) are used in a one-to-one correspondence with storage states “00”, “01”, “10”, and “11”. In a read, one storage state of each memory cell of the EEPROM is specified from the four threshold voltages by a predetermined determining operation.
- the storage state is three bits (eight values)
- eight different reference voltages threshold voltages
- this multi-valued EEPROM greatly increases the storage density of each memory cell. Therefore, the EEPROM can well meet demands for a higher integration degree and a finer structure.
- storage information is not binary data but information constituted by 0, 1, and 2, it is also possible to use “0”, “1”, and “2”, or “00”, “01”, “02”, “10”, “11”, “12”, “20”, “21”, and “22” as storage states.
- the storage state is expressed by three values in the former case and nine values in the latter case.
- This multi-valued structure is also applicable to a DRAM (to be described later) and other various semiconductor memories as well as to the EEPROM.
- a method of writing storage information when the EEPROM described above is a multi-valued memory capable of storing 2-bit information in each memory cell will be described below.
- the drain region 14 of a memory cell is connected to the ground potential, the source region 13 is opened, and a voltage of about 22 V is applied to the polysilicon film 11 . Consequently, electrons are injected from the drain region 14 into the floating gate electrode 9 through the tunnel oxide film 4 , and the threshold voltage (V T ) goes positive. Accordingly, the threshold voltage of the memory cell rises to about 4 V.
- This storage state is “11”.
- the drain region 14 of the memory cell is connected to the ground potential, the source region 13 is opened, and a voltage of about 20 V is applied to the polysilicon film 11 . Consequently, electrons are injected from the drain region 14 into the floating gate electrode 9 through the tunnel oxide film 4 , and the threshold voltage of the memory cell changes to about 3 V. This storage state is “10”.
- the drain region 14 of the memory cell is connected to the ground potential, the source region 13 is opened, and a voltage of about 18 V is applied to the polysilicon film 11 . Consequently, electrons are injected from the drain region 14 into the floating gate .electrode 9 .through the tunnel oxide film 4 , and the threshold voltage of the memory cell changes to about 2 V. This storage state is “01”.
- the drain region 14 of the memory cell is connected to the ground potential, the source region 13 is opened, and a voltage of about 10 V is applied to the polysilicon film 11 . Consequently, the electrons injected into the floating gate electrode 9 are cleared from the drain region 14 , and the threshold voltage of the memory cell changes to about 1 V. This storage state is “00”.
- step S 1 whether the upper bit of storage information stored in a memory cell is “0” or “1” is checked.
- a voltage of about 5 V is applied to the source region 13 and the drain region 14 and the polysilicon film 11 (step S 1 ).
- the drain current is detected by a sense amplifier, and the threshold voltage V T is compared with the threshold voltage of a comparative transistor Tr 1 (step S 2 ). If the threshold voltage V T is larger than the threshold voltage of the transistor Tr 1 , it is determined that the upper bit is “1”. If the current of the transistor Tr 1 is smaller, it is determined that the upper bit is “0”.
- threshold voltage V T is larger than the threshold voltage of the transistor Tr 1 , a similar read is performed by using a transistor Tr 2 , and the current flowing through the memory cell is compared with the current flowing through the transistor Tr 2 (step S 3 ). If the threshold voltage V T is smaller than the threshold voltage of the transistor Tr 1 , a similar read is performed by using a transistor Tr 3 (step S 4 ).
- step S 5 If the threshold voltage V T is larger than the threshold voltage of the transistor Tr 2 in the read performed in step S 3 , it is determined that the storage information stored in the memory cell is “11” (step S 5 ), and the information is read out from the memory cell on the other hand, if the threshold voltage V T is smaller than the threshold voltage of the transistor Tr 2 in step S 3 , it is determined that the storage information stored in the memory cell is “10” (step S 6 ), and the information is read out from the memory cell.
- step S 7 If the threshold voltage of the memory cell is larger than the threshold voltage of the transistor Tr 3 in step S 4 , it is determined that the storage information stored in the memory cell is “01” (step S 7 ), and the information is read out from the memory cell. If the threshold voltage V T is smaller than the threshold voltage of the transistor Tr 3 in step S 4 , it is determined that the storage information stored in the memory cell is “00” (step S 8 ), and the information is read out from the memory cell.
- FIGS. 10A to 10 K are side sectional views showing the steps in fabricating two adjacent DRAM memory cells in the third embodiment.
- FIG. 11 is a schematic plan view showing these DRAM memory cell regions. A section I—I in FIG. 11 corresponds to FIGS. 10A to 10 K.
- the surface of a p-type silicon semiconductor substrate 31 is selectively oxidized by a so-called LOCOS process to form a field oxide film 32 . Consequently, element isolation is achieved on the p-type silicon semiconductor substrate 31 to define two element formation regions 32 .
- the surface of the element formation regions 32 is thermally oxidized to form a gate oxide film 34 having a thickness of about 130 ⁇ .
- a polysilicon film 35 is formed on the entire surface by CVD.
- the gate oxide film 34 and the polysilicon film 35 are then patterned by photolithography and subsequent dry etching, thereby forming gate electrodes 36 . This state is shown in FIG. 10 B.
- arsenic is ion-implanted to form source regions 37 and drain regions 38 as n-type impurity diffusion layers.
- Annealing is then performed to activate the arsenic ions.
- Appropriate ion-implantation conditions are an acceleration energy of about 70 kev and a dose of about 5 ⁇ 10 15 /cm 2 .
- Appropriate annealing conditions are a temperature of 900° C. and an annealing time of about 30 min. Consequently, n-type MOS transistors are formed on the p-type silicon substrate 31 as shown in FIG. 10 C.
- a BPSG film 39 as an insulating interlayer is formed on the entire surface of the p-type silicon semiconductor substrate 31 by CVD, and the surface is planarized by reflow.
- holes 40 for exposing portions of the source regions 27 are formed in the BPSG film 39 .
- a polysilicon film 41 is formed in the holes 40 and on the BPSG film 39 by adding a dopant gas by low-pressure CVD.
- an undoped polysilicon film 41 may be formed on the BPSG film 39 and given conductivity by ion-implanting an impurity such as arsenic. This state is shown in FIG. 10 F.
- a photoresist 42 is formed on the polysilicon film 41 by photolithography.
- a photoresist opening 43 is formed by forming an opening about 0.6 ⁇ m wide in a region for isolating lower electrodes 48 of adjacent stacked capacitor cells to be formed later.
- photoresist openings 44 are formed by forming openings about 0.25 ⁇ m wide in regions near the centers of the lower electrodes 48 to be formed.
- the polysilicon film 41 is selectively removed by dry etching. Since the width of the photoresist openings 44 is smaller than the half width of the photoresist opening 43 , the supply of the etchant is reduced by a microloading effect when the polysilicon film 41 exposed in the photoresist openings 44 is etched. As a consequence, the etching rate is decreased in these portions.
- the progress in etching polysilicon film 41 exposed in the photoresist opening 43 is faster than the progress in etching the polysilicon film 41 exposed in the photoresist openings 44 . Accordingly, the polysilicon film 41 exposed in the photoresist opening 43 is removed first, and the underlying BPSG film 39 is exposed.
- a silicon nitride film about 30 ⁇ thick is deposited on the entire surface by LPCVD and oxidized in an oxygen atmosphere at about 850° C., thereby forming a dielectric film 45 made from an ONO film.
- a polysilicon film 46 having a thickness of about 1,500 ⁇ and serving as an upper electrode of the stacked capacitor cells is formed on the dielectric film 45 by CVD and patterned together with the dielectric film 45 , thereby completing a stacked capacitor cell structure including the lower electrodes 48 , the dielectric film 45 , and the polysilicon film 46 as an upper electrode as shown in FIG. 10 I.
- the lower electrodes 48 achieve the function of charge storage films which capacitively couple with the polysilicon film 46 through the dielectric film 45 .
- a BPSG film 50 is formed on the entire surface and subjected to reflow, and contact holes 47 are formed to expose portions of the drain regions 38 .
- an aluminum alloy film 51 as a bit line is filled in the contact holes 47 and deposited on the BPSG film by sputtering.
- the aluminum alloy film 51 is patterned to complete a stacked capacitor cell structure DRAM as shown in FIGS. 10K and 11 .
- the width of the photoresist openings 44 is made smaller than the half width of the photoresist opening 43 . Consequently, even when the polysilicon film 41 exposed in the photoresist opening 43 is etched away until the underlying BPSG film 39 is exposed, the polysilicon film 41 is left behind on the bottom surfaces of the photoresist openings 44 by the microloading effect, forming the recesses 49 in these portions.
- the bottom surfaces of the recesses 49 are reliably positioned above the surface of the BPSG film 39 by the microloading effect. This prevents the polysilicon film 41 from being separated by the recesses 20 . Accordingly, the lower electrodes 48 having the recesses 49 can be stably formed.
- the recesses 49 are formed by self-alignment at the same time the lower electrodes 48 are isolated. Therefore, the recesses 49 can be formed without increasing the number of fabrication steps.
- each stacked capacitor cell including the lower electrode 48 having the recess 49 , the dielectric film 45 made from the ONO film, and the polysilicon film 46 as the upper electrode, the capacitance of the dielectric film 45 is increased by the recess 49 . As a consequence, the write and erase characteristics of the memory cell can be improved.
- FIGS. 12A to 12 E are side sectional views showing the steps in fabricating two adjacent DRAM memory cell capacitors according to this modification.
- FIG. 13 is a schematic plan view showing the memory cell capacitors.
- a section I—I in FIG. 13 corresponds to FIGS. 12A to 12 E.
- the same reference numerals as in the DRAM of the third embodiment denote the same parts, and a detailed description thereof will be omitted.
- FIG. 12A corresponds to the step shown in FIG. 10G of the third embodiment.
- the steps up to the state shown in FIG. 12A are the same as in the third embodiment.
- the number of openings in the photoresist 42 formed on the polysilicon film 41 is larger than in the third embodiment.
- the photoresist opening 43 is formed by forming an opening about 0.6 ⁇ m wide in a region for isolating the lower electrodes 48 of adjacent stacked capacitor cells to be described later.
- the photoresist openings 44 are formed by forming openings about 0.25 ⁇ m wide in regions near the centers of the lower electrodes 48 to be formed.
- substantially cylindrical photoresist openings 53 are formed between the photoresist openings 43 and 44 .
- the polysilicon film 41 is selectively removed by dry etching. Since the width of the photoresist openings 44 is made smaller than the half width of the photoresist openings 43 and 53 , the supply of the etchant is reduced by a microloading effect when the polysilicon film 41 exposed in the photoresist openings 44 is etched. As a consequence, the etching rate is decreased in these portions.
- the progress in etching the polysilicon film 41 exposed in the photoresist openings 43 and 53 is faster than the progress in etching the polysilicon film 41 exposed in the photoresist openings 44 . Accordingly, the polysilicon film 41 exposed in the photoresist openings 43 and 53 is removed first, and the underlying BPSG film 39 is exposed.
- a silicon nitride film about 30 ⁇ thick is deposited on the entire surface by LPCVD and oxidized in an oxygen atmosphere at about 850° C., thereby forming the dielectric film 45 made from an ONO film.
- the polysilicon film 46 having a thickness of about 1,500 ⁇ and serving as an upper electrode of the stacked capacitor cells is formed on the dielectric film 45 by CVD and patterned together with the dielectric film 45 , thereby completing a stacked capacitor cell structure including the lower electrodes 48 , the dielectric film 45 , and the polysilicon film 46 as an upper electrode as shown in FIG. 12 C.
- the BPSG film 50 is formed on the entire surface and subjected to reflow, and the contact holes 47 are formed to expose portions of the drain regions 38 .
- the aluminum alloy film 51 as a bit line is filled in the contact holes 47 and deposited on the BPSG film by sputtering.
- the aluminum alloy film 51 is patterned to complete a stacked capacitor cell structure DRAM as shown in FIGS. 12E and 13 .
- the capacitance of the dielectric film 45 made from an ONO film can be further increased by the substantially cylindrical openings 54 compared to the third embodiment.
- the capacitive coupling ratio can be increased.
- the etching rate controlled by the microloading effect can be increased or decreased by properly changing the diameter of the photoresist openings 53 in the above modification.
- the diameter may be made smaller than in the above modification to set the same etching rate as the photoresist openings 44 , and the polysilicon film 41 may be removed to the extent to which the underlying field oxide film 39 is not exposed.
- substantially cylindrical photoresist openings 55 having a smaller diameter are formed between the photoresist openings 43 and 44 as shown in FIG. 14 A.
- the polysilicon film 41 is selectively removed by dry etching. Since the width of the photoresist openings 44 and 55 is made smaller than the half width of the photoresist opening 43 , the supply of the etchant is reduced by the microloading effect when the polysilicon film 41 exposed in the photoresist openings 44 and 55 is etched. As a consequence, the etching rate is decreased in these portions.
- the progress in etching the polysilicon film 41 exposed in the photoresist opening 43 is faster than the progress in etching the polysilicon film 41 exposed in the photoresist openings 44 and 55 . Accordingly, the polysilicon film 41 exposed in the photoresist opening 43 is removed first, and the underlying BPSG film 39 is exposed.
- a silicon nitride film about 30 ⁇ thick is deposited on the entire surface by LPCVD and oxidized in an oxygen atmosphere at about 850° C., thereby forming the dielectric film 45 made from an ONO film.
- the polysilicon film 46 having a thickness of about 1,500 ⁇ and serving as an upper electrode of the stacked capacitor cells is formed on the dielectric film 45 by CVD and patterned together with the dielectric film 45 , thereby completing a stacked capacitor cell structure including the lower electrodes 48 , the dielectric film 45 , and the polysilicon film 46 as an upper electrode as shown in FIG. 14 C.
- the BPSG film 50 is formed on the entire surface and subjected to reflow, and the contact holes 47 are formed to expose portions of the drain regions 38 .
- the aluminum alloy film 51 as a bit line is filled in the contact holes 47 and deposited on the BPSG film by sputtering.
- the aluminum alloy film 51 is patterned to complete a stacked capacitor cell structure DRAM as shown in FIGS. 14E and 15 .
- a photoresist 6 may also be formed after the surface of a polysilicon film 5 is planarized as in the second embodiment. If this is the case, recesses can be formed in lower electrodes of capacitors without using the microloading effect as in the second embodiment. Additionally, since photolithography is performed by forming the photoresist 6 on the planarized polysilicon film 5 , the widths of the photoresist openings 43 and 44 can be set with higher controllability.
- an element isolation structure can be formed by a field shield structure or a trench element isolation structure.
- a silicon oxide film or an ONO film is used as a dielectric film.
- a dielectric film is not restricted to these films.
- a ferroelectric film may also be used.
- the polysilicon film 5 , 11 can be replaced with a film made of platinum, a titanium compound, a tungsten compound or a ruthenium compound. It may also be formed of a double layer structure in which a conductive film made of, for example, poly-silicon is provided under a platinum film.
- any material having a ferroelectric characteristic can be used as a material of the above-mentioned ferroelectric film.
- PZT(lead zirconate titanate), PLZT(lead lanthanum zirconate titanate), barium titanate, palladium titanate, barium strontium titanate and bismuth titanate can be used as the material of the ferroelectric film.
- a dielectric film made of, for example, tantalic oxides or Ta 2 O 5 BSTO, which has a high dielectric constant of more than 50, can be used instead of the ferroelectric film.
- the third embodiment described above may also be applied to a multi-value DRAM having three or more values.
- methods of read and write to multi-value DRAMs are described in Japanese Patent Laid-Open No. 60-239994.
- an insulating film including a silicon nitride film or an insulating film including a silicon oxide film and a silicon nitride film may be used as a charge storage film.
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Abstract
Description
Claims (33)
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US09/387,857 US6844268B1 (en) | 1997-04-18 | 1999-09-01 | Method for fabricating a semiconductor storage device having an increased dielectric film area |
US11/655,744 USRE42004E1 (en) | 1997-04-18 | 2007-01-18 | Method for fabricating a semiconductor storage device having an increased dielectric film area |
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US11/655,744 Expired - Fee Related USRE42004E1 (en) | 1997-04-18 | 2007-01-18 | Method for fabricating a semiconductor storage device having an increased dielectric film area |
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JP3008812B2 (en) * | 1995-03-22 | 2000-02-14 | 日本電気株式会社 | Nonvolatile semiconductor memory device and method of manufacturing the same |
JPH0936258A (en) * | 1995-07-19 | 1997-02-07 | Toshiba Corp | Semiconductor device and its manufacture |
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- 1998-04-20 JP JP10109179A patent/JPH113981A/en not_active Withdrawn
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1999
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- 2005-07-11 JP JP2005202177A patent/JP4901147B2/en not_active Expired - Lifetime
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2007
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JP2008182261A (en) | 2008-08-07 |
JP4352011B2 (en) | 2009-10-28 |
TW376534B (en) | 1999-12-11 |
JPH113981A (en) | 1999-01-06 |
US6288423B1 (en) | 2001-09-11 |
JP2005303334A (en) | 2005-10-27 |
JP2005184027A (en) | 2005-07-07 |
US6844268B1 (en) | 2005-01-18 |
JP4901147B2 (en) | 2012-03-21 |
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