USRE21521E - Process for catalytic reaction - Google Patents
Process for catalytic reaction Download PDFInfo
- Publication number
- USRE21521E USRE21521E US21521DE USRE21521E US RE21521 E USRE21521 E US RE21521E US 21521D E US21521D E US 21521DE US RE21521 E USRE21521 E US RE21521E
- Authority
- US
- United States
- Prior art keywords
- tubes
- furnace
- catalyst
- gases
- combustion gases
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/062—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Description
July 30, 1940. .1. H. sHAPLEIGH PROCESS FOR CATALYTIC REACTION Original Filed Aug. 50, 1937 2 Sheets-Shea#- 2 JAN ES H. SHAPLEIGH INVENTOR BYM- ATTORNEY Reissued July 30, 1940 UNITED STATES PATENT OFFICE to Hercules Powder Company,
Wilmington,
Del., a corporation of Delaware Original No. 2,173,984, dated September 26, 1939,
Serial No. 161,715, August 30, 1937. Application for reissue March 29, 1940, Serial No.
10 Claims.
This invention relates to improved apparatus and process for catalytic reactions involving the application of heat to gases and vapors, particularly adapted to the art of producing gas rich in free hydrogen from hydrocarbon gas with steam or other compounds co gyvhicrr may react with the carbon of the hydrocarbons.
In reacting hydrocarbon gases with steam to produce hydrogen, it is desirable to use high temperatures, e. g., up to 2000 F. Although special metal tubes, filled with catalyst, are known to the art, the economical use of such tubes and catalyst has not yet been disclosed. To prevent tubes heated to temperatures of 1600-2000 F. from failing, special methods have heretofore been used, due to the fact that combustion temperature in the heating furnace may be of the order of 3500 F., a temperature higher than the melting point of the alloy steel tubes used.
One of the special methods of heating heretofore known is to apply parallel flow, whereby combustion gases of the highest temperature contact the coolest portion of the reaction tube. Such a method sends gases from the furnace at its base at a very high temperature, since the lower end of the tubes may be as high as 2000 F., and with an endothermic reaction it is obviously necessary to have the supply of heat such that a temperature gradient can be maintained. An additional protective measure sometimes used by the prior art, even with the use of parallel iiow, has been the spacing of the reaction tubes at substantial distances one from the other so as to provide considerable room for the combustion gases Within the furnace. An example of such spacing is to have the distance from tube center to tube center equal to approximately nine tube diameters.
Another special method heretofore in use has been the use oi' high proportions of excess air in the combustion gases, in order to reduce the temperature of the gases to a suitable point.
All of the above special methods are uneconomical in use, in that they tend to low thermal emciency and require, for economy, recovery of excess or waste heat or the use of waste heat boilers or the like.
In all of the above cases, where parallel flow exists between process gas within the tube and hot combustion gas without, the objective has been to obtain safe mechanical and physical conditions. For example, a combustion gas of a temperature of about 3500" F., passing parallel to a tube with maximum end temperature of about 2000 F., must leave the apparatus at a temperature higher than 2000 F., say 2250 F. to 2500 F. Under this condition, the exit temperatures are all below the melting point of the alloy tube. The thermal efficiency is then about 28-35%, a very low value. In addition, the temperature differential for heating the hot end of the tube and furnace wall is low, 500 F. maximum at 28% thermal emciency. The construction and design of such old apparatus necessitates a substantial temperature difference (250 F.-500 F.) between the furnace wall and the metal tube, making high operating temperature diflicult to obtain. It is therefore evident that the old apparatus design, including provision for parallel flow, represents a common and specific state in the art and one not meeting the demand for cheap hydrogen.
I have found that I may use counter-current flow with the combustion gases containing a minimum of excess air, and by the use of high temperature combustion gases, without endangering the metal alloy catalyst tubes. Such I accomplish by the use of a heating furnace containing the catalyst tubes hereinafter more fully described.
When starting with the same gas at 3500 F. I obtain an exit gas of approximately 1300 F., or an eiiciency of about 63%, in marked contrast to the 2835% obtained by parallel flow. My use of from 1 to l0 square feet of parallel refractory wall surface radiating to each square foot of metal tube surface within the furnace, say 2 to 6, I find enables me to utilize small dierences between metal tube and refractory wall temperature at the hottest point of the tube. This temperature dierence may be 50 F. or less, depending upon the relationship used. This is in contrast to 250 to 500 F. by the disclosed art. Further, I find I can use a high differential (l000 to 1500 F.) between combustion gas and refractory wall at the process gas exit end of the apparatus, without any detrimental effect on the metal tube, even though its melting point is substantially below the combustion gas temperature.
Also, in my furnace I use counterow heating, with a defined relationship between combustion gas and metal tube surface, e. g., when using a natural gas containing approximately methane and 20% ethane, I prefer to use, per lineal foot of furnace height, about 10 to about cubic feet of gas per hour per square foot of metal tube wall contained within that unit foot of vertical height, with spatial velocity of cracking gas about 600 cubic feet per hour per cubic foot of catalyst. I contemplate the use of suitable burners, hereinafter more fully exemplied, at' a number of different levels for a multiple tube furnace, and I also contemplate passing burner gases initially substantially tangentially to the tubes, the gases thus producing a circulatory motion as they pass counter-current to the tubes.
My improved apparatus enables not only higher thermal efllciency to be obtained, but higher chemical emciency. This is due to the fact that the tube wall temperature can be very close to the refractory wall temperature, and for any specied thermal e'iciency for the furnace. as compared to a parallel flow operated furnace, the tube operating temperatures will be higher, which gives directly higher chemical efnciency.
My invention will be more fully understood by reference to the accompanying drawings, which illustrate one form of apparatus suitable for my invention. The drawings are, Figure l, an elevation, and Figure 2, a plan of apparatus constructed according to the present invention.
Referring now particularly to Figure l of the accompanying drawings, I represents a furnace, constructed preferably of nre brick, containing metal alloy catalyst tubes 2, placed vertically in planes parallel to the side walls of the furnace. Any number of such tubes may be used, arranged, for example, as is more fully described in connection with Figure 2. The tubes are constructed of a nickel-chromium-iron alloy adapted to withstand high temperatures. The tubes 2 project through the top and bottom of the furnace. passing through tiles 2. The projecting ends of the tubes and the outer surface of the furnace may, if desired, be covered with insulating material (not shown to enhance clarity). Tubes 2 are supported by means of any suitable support at the top of each tube, e. g., the upper flange l of tube 2 rests upon a short collar 6, through which tube 2 may pass freely. Collar 8 is supported by and fastened to steel beam 1, supported in any suitable manner upon the furnace housing. Any of tubes 2 may be readily removed from the furnace by disconnecting it at the ange and lifting it vertically from the furnace.
The gases or vapors are supplied through convenient pipes, which may diner from those shown in the accompanying drawings as circumstances and process may require. In the present example, a mixture of hydrocarbon gas and steam is forced through line II, controlled by valve I2, into tubes 2.
'I'he gases leaving the bottom of tubes 2 pass through separate lines I2 into headers Il, suitably supported (not shown) and free to move with expansion and contraction of tubes 2.
Burners I5, not all shown in detail, are located in the side wall of furnace I at various levels. Suitable burners are those giving a short flame, such as inspirator type N571-A, made by the Surface Combustion Corporation. Gas is supplied to the burners through gas pipes I6, the pressure being indicated by gauge I1. The combustion gases from the burners pass into the furnace sub-- stantially tangentially to tubes 2, and pass upward around the tubes with a circulatory motion, at the same time heating the inner surface walls to a high temperature and radiating heat from said walls to tubes 2. The gases of combustion finally escape from the furnace in a ue I8, connecting with a stack (not shown). Suitable heat exchange equipment or waste heat boilers may be used to recover heat remaining in said ue gas.
In the present process, a mixture of steam and hydrocarbon gas is passed down through pipes 2 and through catalyst mass 9, where it is heated rapidly to a temperature of about 1600D to about 2000*l F. At such temperatures there is a marked decrease in the strength of alloys used for the catalyst tubes, and serious bending and distortion occur if said tubes are supported at the bottom. Suspension of the tubes at the top, leaving the bottom and connections thereto free to move with thermal expansion of the tube, prevents this distortion.
In the preferred embodiment of my invention, I employ a furnace, each chamber of which contains catalyst tubes having the herein dened relation of tube surface to vertical -wall surface, preferably about 3 inches to about 8 inches in diameter, but not exceeding 12 inches in diameter, and preferably about 25 feet long, but not exceeding feet in length. It will be observed that, in my improved furnace, the hydrocarbon gases flow counter to the combustion gases, and very high temperature combustion gases flow against a very hot tube, and, by means of burners placed at various levels the temperature of the various zones is controlled as desired, at high velocity of combustion gases flowing counter-current to the hydrocarbon gas.
Suitable catalysts for the production of hydrogen by cracking hydrocarbon gases possess high activity and physical strength, and shrink very little at the operating temperatures employed. Oxides or metals of the iron group, admixed with aluminum oxide, form desirable catalysts. Calcium and magnesium oxides and silica may be added to produce catalysts of greater strength at high temperatures. Phosphoric acid with alumina and nickel oxide produce a very active catalyst, which shrinks very little at high temperaturcs. A particularly suitable catalyst is prepared from nickel oxides, magnesia and kaolin. The catalyst is usually prepared in the form of a paste, cut into small cubes, dried slowly, then heated slowly in the presence of steam to a temperature of about 500 F. higher than the operating temperature at which it is to be used, then held at this temperature for about 24-48 hours. Such roasting treatment causes most of the shrinkage to take place before use of the catalyst. Dried catalyst may also be charged into the tubes, and the final roasting step then performed with the tubes in place in the furnace, additional catalyst being added to make up for shrinkage. The catalyst should not be roasted at so high a temperature as to cause serious decrease in catalytic activity.
I prefer to use a catalyst in my furnace comprising diaspore impregnated with nickel nitrate so as to contain about 6% by weight of nickel, and heating to about 500 F. to decompose the nitrate, then reduced by passing therethrough hot reducing gases. Preferably, my catalyst, mass comprises particles from about to about in diameter.
The exist gas from the cracking of methane ullLi...
and steam consists almost entirely of hydrogen, carbon oxides, and excess steam, usually containing a high percentage of carbon monoxide. The gas may be cooled immediately after leaving the furnace, if a hydrogen-carbon monoxide mixture is desired for the production of synthetic alcohol, or, if a gas containing almost entirely hydrogen is desired, it is prt ferable to pass the exist gas, with added steam over iron oxides or other suitable catalyst in the known manner, for conversion of carbon monoxide to carbon dioxide, then cool the gas, scrub ouil the carbon dioxide by known means, leaving a hydrogen of about purity.
My apparatus may be operated at any desired pressure above or below atmospheric, limited only by strength of materials at the operating temperature employed.
What I claim is:
1. A process for preparing hydrogen which comprises passing reactants comprising gaseous hydrocarbons and steam downwardlyl through elongate vertical tubes contained in a heating zone, simultaneously heating said reactants indirectly by introducing hot flaming gases into said heating zone at a plurality of vertically spaced points along and adjacent to said tubes and substantially tangentially to said tubes, and withdrawing the resulting combustion gases at a point adjacent the top of said zone, whereby said flaming gases follow an upwardly ascending rotary path around said tubes, which are thereby uniformly heated without substantial flame impingement thereon.
2. Al process for preparing hydrogen which comprises passing reactants comprising gaseous hydrocarbons and steam downwardly through elongate vertical catalyst tubes contained in a heating zone, heating said reactants indirectly by introducing hot combustion gases into said heating zone at a plurality of vertically spaced points along and adjacent to said tubes and substantially tangentially to said tubes, withdrawing the treated reactants from adjacent the bottom of the said tubes and withdrawing the combustion gases at a point adjacent the top of said heating zone, whereby said hot combustion gases follow an upwardly ascending rotary path around said tubes, which are thereby uniformly heated without substantial flame impingement thereon.
3. A process for preparing hydrogen which comprises passing reactants comprising gaseous hydrocarbons and steam downwardly through a bank of substantially vertically disposed catalyst tubes contained in a heating zone, heating said reactants indirectly by introducing hot combustion gases into said heating zone substantially tangentially to said bank of tubes and at a plurality of vertically spaced points along and adjacent to said bank, withdrawing the treated reactants from adjacent the bottom of the tubes and withdrawing combustion gases at Ia point adjacent the top of said heating zone whereby said hot combustion gases follow an upwardly ascending rotary path around said bank of tubes, which is thereby uniformly heated without substantial flame ixnpingement thereon.
4. A process for preparing hydrogen which comprises passing reactants comprising gaseous hydrocarbons and steam downwardly through a bank of substantially vertically disposed catalyst tubes contained in a refractory-walled heating zone, maintaining a ratio of from l to 10 square feet of refractory wall surface to each square foot of catalyst tube surface, heating said reactants indirectly by introducing hot combustion gases into said heating zone substantially tangentially to said bank of tubes and at a plurality of vertically spaced points along and adjacent to said bank, withdrawing the treated reactants from adjacent the bottom of the tubes and withdrawing combustion gases at a point adjacent the top of said heating zone, whereby said hot combustion gases follow an upwardly ascending rotary path around said bank of tubes, which ls thereby uniformly heated without substantial flame impingement thereon.
5. A process for preparing hydrogen which comprises passing reactants comprising gaseous hydrocarbons and steam downwardly through a bank of substantially vertically disposed catalyst tubes contained in a refractory-walled heating zone, maintaining a ratio of from 2 to 6 square feet of refractory wall surface to each square foot of catalyst tube surface, heating said reactants indirectly by introducing hot combustion gases into said heating zone substantially tangentially to said bank of tubes and at a plurality of vertically spaced points along and adjacent to said bank, withdrawing the treated reactants from adjacent the bottom of the tubes and withdrawing combustion gases at a point adjacent the top of said heating zone, whereby said hot combustion gases follow an upwardly ascending rotary path around said bank of tubes, which is thereby uniformly heated without substantial flame impingernent thereon.
6. A process which comprises passing uid reactants to be treated downwardly through elongate vertical tubes contained in a heating zone. simultaneously heating said reactants indirectly by introducing hot naming gases into said heating zone at a plurality-ofverticaliy'spaced points along and adjacent to said tubes and substantially tangentially to said tubes, and withdrawing the resultig combustion gases at a point adjacent the top of said zone, whereby said naming gases follow an upwardly ascending rotary path around said tubes. which are thereby uniformly heated without substantial name impingement thereon.
'7. A process which comprises passing uid reactants to be treated downwardly through elongate vertical catalyst tubes contained in a heating zone, heating said reactants indirectly by introducing hot combustion gases into said heating zone at a plurality of vertically spaced points along and adjacent to said tubes and substantially tangentially to said tubes, withdrawing the treated fluid from adjacent the bottom of the said tubes and withdrawing the combustion gases at a point adjacent the top of said heating zone, whereby said hot combustion gases follow an upwardly ascending rotary path around said tubes, which are thereby uniformly heated without substantial name impingement thereon.
8. A process which comprises passing gaseous reactants to be treated downwardly through elongate vertical tubes contained in a heating zone, simultaneously heating said reactants indirectly by introducing hot naming gases into said heating zone at a plurality of vertically spaced points along and adjacent to said tubes and substantially tanggtially to said tubes. and withdrawing the resulting combustion gases at a point adjacent the top of said zone, whereby said naming gases follow an upwardly ascending rotary path around said tubes, which are thereby uniformly heated without substantial flame impingement thereon.
9. A process which comprises passing gaseous reactants to be treated downwardly through elongate vertical catalyst tubes contained in a heating zone, heating said reactants indirectly by introducing hot combustion gases into said heating zone at a plurality of vertically spaced points along and adjacent to said tubes and substantially tangentialy to said tubes, withdrawing the treated gas from adjacent the bottom of the said tubes and withdrawing the combustion gases at a point adjacent the top of said heating zone, whereby said hot combustion gases follow an upwardly ascending rotary path around said tubes, which are thereby uniformly heated without substantial flame impingement thereon.
10. A process which comprises passing a nu ture of gaseous reactants to be treated clotI wardly through elongate vertical tubes contained in a heating zone, simultaneously heating said reactants indirectly by introducing hot aming gases into said heating zone at a plurality of vertically spaced points along and adjacent to said tubes and substantially tangentially to said tubes, and withdrawing the resulting combustion gases at a point adjacent the top of said zone, whereby said naming gases follow an upwardly ascending rotary path around said tubes, which are thereby uniformly heated without substantial flame impingement thereon.
JAMES H. SHAPLEIGH.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US161715A US2173984A (en) | 1937-08-30 | 1937-08-30 | Apparatus and process for catalytic reactions |
Publications (1)
Publication Number | Publication Date |
---|---|
USRE21521E true USRE21521E (en) | 1940-07-30 |
Family
ID=22582393
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US21521D Expired USRE21521E (en) | 1937-08-30 | Process for catalytic reaction | |
US161715A Expired - Lifetime US2173984A (en) | 1937-08-30 | 1937-08-30 | Apparatus and process for catalytic reactions |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US161715A Expired - Lifetime US2173984A (en) | 1937-08-30 | 1937-08-30 | Apparatus and process for catalytic reactions |
Country Status (3)
Country | Link |
---|---|
US (2) | US2173984A (en) |
BE (1) | BE429915A (en) |
DE (1) | DE887801C (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2456554A (en) * | 1945-10-12 | 1948-12-14 | United Carr Fastener Corp | Connector for cords or cables |
US2628890A (en) * | 1946-06-20 | 1953-02-17 | Hercules Powder Co Ltd | Process for the decomposition of hydrocarbons |
US2680061A (en) * | 1951-02-07 | 1954-06-01 | Columbian Carbon | Carbon black |
US2707147A (en) * | 1948-02-07 | 1955-04-26 | Hercules Powder Co Ltd | Production of domestic gas |
US2860959A (en) * | 1954-06-14 | 1958-11-18 | Inst Gas Technology | Pressure hydrogasification of natural gas liquids and petroleum distillates |
US2914386A (en) * | 1954-12-20 | 1959-11-24 | Hercules Powder Co Ltd | Tubular furnace |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2571953A (en) * | 1947-09-19 | 1951-10-16 | Hercules Powder Co Ltd | Manufacture of hydrogen |
US2660519A (en) * | 1948-04-23 | 1953-11-24 | Chemical Construction Corp | Fluid heater |
US2645566A (en) * | 1949-12-12 | 1953-07-14 | Gas Machinery Co | High-temperature reactor |
US2638407A (en) * | 1949-12-31 | 1953-05-12 | Standard Oil Dev Co | Apparatus for close temperature control of catalyzed gas reactions |
US2667410A (en) * | 1950-01-04 | 1954-01-26 | Phillips Petroleum Co | Apparatus for reforming hydrocarbons |
US2730434A (en) * | 1950-05-01 | 1956-01-10 | Oxy Catalyst Inc | Catalytic contacting unit |
US2743171A (en) * | 1950-08-23 | 1956-04-24 | United Gas Improvement Co | Method for making gas rich in hydrogen |
US2788266A (en) * | 1951-10-13 | 1957-04-09 | Stirnemann Ernst | Catalytic reactor furnace |
US3055745A (en) * | 1952-11-07 | 1962-09-25 | Vulcan Cincinnati Inc | Catalytic reactor |
GB792827A (en) * | 1954-02-19 | 1958-04-02 | Hercules Powder Co Ltd | Improvements in or relating to process for catalytic treatment of hydrocarbons |
US2852358A (en) * | 1954-06-10 | 1958-09-16 | Commercial Solvents Corp | Process for reforming hydrocarbons |
US2867516A (en) * | 1954-08-18 | 1959-01-06 | Du Pont | Process for burning gaseous fuels |
US2982797A (en) * | 1957-09-25 | 1961-05-02 | Phillips Petroleum Co | Catalyst regeneration and apparatus |
US3069348A (en) * | 1959-07-22 | 1962-12-18 | Socony Mobil Oil Co Inc | Multi-stage, multi-zone static bed reforming process and apparatus therefor |
US3062197A (en) * | 1959-07-23 | 1962-11-06 | Selas Corp Of America | Tube heater |
US3190812A (en) * | 1960-01-22 | 1965-06-22 | Ruetgerswerke Ag | Device for the continuous production of hard pitch |
US3198727A (en) * | 1960-05-25 | 1965-08-03 | Socony Mobil Oil Co Inc | Quasi-isothermal hydrocarbon conversion and reactor therefor |
US3285847A (en) * | 1963-05-06 | 1966-11-15 | Phillips Petroleum Co | Fast thermal cracking of heavy carbonaceous materials |
FR2045712B1 (en) * | 1969-06-25 | 1973-11-16 | Onia Gegi | |
US4101376A (en) * | 1974-03-18 | 1978-07-18 | Metallgesellschaft Aktiengesellschaft | Tubular heater for cracking hydrocarbons |
US4454839A (en) * | 1982-08-02 | 1984-06-19 | Exxon Research & Engineering Co. | Furnace |
DE10023409A1 (en) * | 2000-05-12 | 2001-11-15 | Linde Gas Ag | Gas generator used for producing carbon monoxide- and hydrogen-containing treatment gas for heat treating metallic material comprises catalyst retort and device for heating partial regions of retort |
DE10023410A1 (en) * | 2000-05-12 | 2001-11-15 | Linde Gas Ag | Production of carbon monoxide- and hydrogen-containing treatment gas comprises forming treatment gas for catalytically converting hydrocarbon gas in catalyst retort to which heat can be fed and varied over its length |
DE10333854A1 (en) * | 2003-07-24 | 2005-02-17 | Uhde Gmbh | Tubular cracking furnace used for reforming hydrocarbons e.g. to produce synthesis gas, comprises vertical cracker tubes, downward pointing burners and wedge shaped horizontal ceramic tunnels for removing flue gas |
DE102007019830B3 (en) * | 2007-04-25 | 2008-07-31 | Uhde Gmbh | Reactor for catalytic primary reformation of hydrocarbons with water vapor under increased pressure, has device for top firring of reformation process furnace, and supply mechanism, which has main inlet channel and secondary inlet channel |
DE102013109209B4 (en) * | 2013-08-26 | 2015-09-03 | Thyssenkrupp Industrial Solutions Ag | Collector management for joint removal of process gases from a reformer fed from several reformer tubes |
KR20160088903A (en) * | 2013-11-21 | 2016-07-26 | 바스프 에스이 | Method and device for carrying out endothermic reactions with formation of a fluidized layer in reaction tubes |
-
0
- US US21521D patent/USRE21521E/en not_active Expired
- BE BE429915D patent/BE429915A/xx unknown
-
1937
- 1937-08-30 US US161715A patent/US2173984A/en not_active Expired - Lifetime
-
1938
- 1938-08-18 DE DEH3052D patent/DE887801C/en not_active Expired
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2456554A (en) * | 1945-10-12 | 1948-12-14 | United Carr Fastener Corp | Connector for cords or cables |
US2628890A (en) * | 1946-06-20 | 1953-02-17 | Hercules Powder Co Ltd | Process for the decomposition of hydrocarbons |
US2707147A (en) * | 1948-02-07 | 1955-04-26 | Hercules Powder Co Ltd | Production of domestic gas |
US2680061A (en) * | 1951-02-07 | 1954-06-01 | Columbian Carbon | Carbon black |
US2860959A (en) * | 1954-06-14 | 1958-11-18 | Inst Gas Technology | Pressure hydrogasification of natural gas liquids and petroleum distillates |
US2914386A (en) * | 1954-12-20 | 1959-11-24 | Hercules Powder Co Ltd | Tubular furnace |
Also Published As
Publication number | Publication date |
---|---|
BE429915A (en) | |
DE887801C (en) | 1953-08-27 |
US2173984A (en) | 1939-09-26 |
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