USRE14277E - Utilization op sttlpttr dioxid - Google Patents
Utilization op sttlpttr dioxid Download PDFInfo
- Publication number
- USRE14277E USRE14277E US RE14277 E USRE14277 E US RE14277E
- Authority
- US
- United States
- Prior art keywords
- dioxid
- sulfur
- reaction
- chamber
- mixture
- Prior art date
Links
- 238000006243 chemical reaction Methods 0.000 description 52
- RAHZWNYVWXNFOC-UHFFFAOYSA-N sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 38
- 239000003610 charcoal Substances 0.000 description 36
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 32
- 239000000203 mixture Substances 0.000 description 30
- 239000011593 sulfur Substances 0.000 description 30
- 229910052717 sulfur Inorganic materials 0.000 description 30
- 239000002023 wood Substances 0.000 description 26
- 239000007789 gas Substances 0.000 description 24
- 239000000446 fuel Substances 0.000 description 22
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 18
- 229910052739 hydrogen Inorganic materials 0.000 description 18
- 239000001257 hydrogen Substances 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 229910001868 water Inorganic materials 0.000 description 18
- RWSOTUBLDIXVET-UHFFFAOYSA-N dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 8
- 239000008246 gaseous mixture Substances 0.000 description 8
- 239000003034 coal gas Substances 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 239000003345 natural gas Substances 0.000 description 4
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- 125000001145 hydrido group Chemical group *[H] 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
Definitions
- the present invention relates to the utilization of sulfur dioxid and is based upon the discovery that when a mixture containing sulfur dioxid and gaseous fuel or fuels is permitted to react, under a suitable temperature, in the presence of a catalyzer such as wood-charcoal, elemental sulfur and other products will result, depending upon the composition of the gaseous fuels and the proportions in which they are present in the mixture.
- a catalyzer such as wood-charcoal, elemental sulfur and other products
- the giaseous fuels employed in ad-- mixture with e sulfur dioxid may be producer gas or natural hgas.
- the gaseous fuels employed may be coal gas, water gas, or hydrogemwhich gases, if used in excess of the quantities required for the complete conversion of carbon monoxid into carbon dioxid, react to that extent with the sulfur to form hydrogen sulfid, as will hereinafter more fully appear.
- reaction- Twelve volumes of sulfur dioxid and ten volumes of coal gas are led into a chamber more or less completely filled with wood charcoal.
- the mixture of gases may be either dry or may contain more or less moisture.
- the reaction chamber is heated to a minimum temperature of about 500 C. The mixture reacts quantitatively and smoothly to produce sulfur, The reaction-may be expressed-as follows:
- the products of the reaction issue from the reaction chamber and the sulfur and carbon dioxid and water.
- the carbon dioxid being permitted to escape into the air or it may be recovered by any suitable means.
- the reaction chamber containing the Wood charcoal and into which the mixture of about seven volumes of sulfur dioxid and forty ,volumes of producerigas is led is heated to a minimum temperature of about 500 C.
- the mixture reacts quantitatively and smoothly to produce sulfur, carbon dioxid and water.
- the reaction may be expressed as follows:
- the method of utilizing sulfur dioxid which comprises subjecting it to reaction with gaseous fuel capable of reducing sulfur dioxid in the presence of wood charcoal at a temperature of about 500 to 600 6.; substantially as described.
- the method of utilizing sulfur dioxid which comprises subjecting it to reaction with gaseous fuel containing hydrogen in the presence of wood charcoal at a temperature below that at which the charcoal would be consumed in the gaseous mixture, the gaseous fuel being employed in excess of thatnecessary for converting the sulfur dioxid into sulfur, whereby the hydrogen of the excess will react with the sulfur produced to form hydrogen sulfid; substantially as described.
Description
the United States, residing,
as follows:
UNITED STATES PATENT OFFICE.
.TmEs B. oAENEn AND HOWARD D. CLAYTON, 0F PITTSBURGH, PENNSYLVANIA,
.assmrroas To METALS RESEARCH COMPANY, or NEW Yonx, N. 1.; A conrona- Application for reissue To all whom it may concern:
Be it known that we, JAMES B. GARNER and HOWARD D. CnArroN, both citizens of respectively, at Pittsburgh, Allegheny county, State of Pennsylvania, have invented certain new and useful Improvements in the Utilization of Sulfur Dioxid; and we do hereby declare the following to be a full, clear, and exact description of the invention, such as will enable others skilled in the art to which it appertains to make and use the same.
The present invention relates to the utilization of sulfur dioxid and is based upon the discovery that when a mixture containing sulfur dioxid and gaseous fuel or fuels is permitted to react, under a suitable temperature, in the presence of a catalyzer such as wood-charcoal, elemental sulfur and other products will result, depending upon the composition of the gaseous fuels and the proportions in which they are present in the mixture. Where sulfur alone is to be produced, the giaseous fuels employed in ad-- mixture with e sulfur dioxid may be producer gas or natural hgas. Where either sulfur or hydrogen SM d are to be produced, the gaseous fuels employed may be coal gas, water gas, or hydrogemwhich gases, if used in excess of the quantities required for the complete conversion of carbon monoxid into carbon dioxid, react to that extent with the sulfur to form hydrogen sulfid, as will hereinafter more fully appear.
- The nature and scope of the invention will be made apparent from the following typi-.
cal instances which are given as illustrating the preferred practice of the invention: (1) One volume of sulfur-dioxid and two volumes of water-gas are led into a reaction chamber more or less completely filled with wood charcoal, the constituent gases being either dry, or containing more or=less moisture. The reaction chamber containing the wood charcoal and into which the mixture of sulfur dioxid and water-gas is led is heated to a minimum temperature of about 525 C. The mixture reacts quantitatively and smoothly to produce sulfur, water, and car bon dioxid. The reaction may be expressed These products pass from the reaction chamber and the sulfur and the water are Specification of lteissued Letters Patent.
hydrogen UTILIZATION OF SULFUR DIOXID.
.Reissued Mar. 2'7, 1917,.
- No Drawing. ori inal No. 1,173,506, dated February 2a, 1916, Serial No. 12,134, filed March 4,1.1915.
flied February a, 1917. Serial No. 147,440.}.
collected in suitable condensers while the i carbon-dioxidescapes into the air.
If it is desired to produce hydrogen sulfid an excess of water-gas may be used whereby the following reaction may be realized in the cooler portion of the chamber:
(2) One volume of sulfur dioxid and two volumes of hydrogen are led into areaction chamber more or less completely filled with wood charcoal. The mixture of gases may be either dry or maycontain more or less moisture. The chamber containing the wood charcoal and into which the mixture of one volume of sulfur dioxid and two volumes of is led is heated to a minimum temperature of about 500 G. The reaction may be. expressed as follows:
The products of the reaction pass from the chamber and are collected in suitable condensers. a
If it is desired to produce hydrogen sulfid an excess of hydrogen may be used, whereby the following reaction may be realized in the cooler parts of the chamber:
(3) Twelve volumes of sulfur dioxid and ten volumes of coal gas are led into a chamber more or less completely filled with wood charcoal. The mixture of gases may be either dry or may contain more or less moisture. The reaction chamber is heated to a minimum temperature of about 500 C. The mixture reacts quantitatively and smoothly to produce sulfur, The reaction-may be expressed-as follows:
The products of the reaction issue from the reaction chamber and the sulfur and carbon dioxid and water.
water are collected insuitable condensers,
the carbon dioxid .being permitted to escape into the air or it may be recovered by any suitable means.
If it is desired to produce hydro en sulfid, an excess of coalgas may be'us whereby the following reaction may be realized in the cooler parts of the chamber:
(4) Approximately eleven volumes of sulfur dioxid and five volumes of natural gas are led into a chamber more or less completely filled with wood charcoal. The mam constituents of natural gas are methane,
ethane, nitrogen and carbon dioxid, and the temperature of about 600 C. The mixture reacts quantitatively and smoothly to produce sulfur, carbon dioxid and water; The reaction may be expressed as follows:
The products of the reaction issue from the chamber and the sulfur and Water are collected in suitable condensers while the carbon dioxid is permitted to escape into the air or it may be recovered by any suitable means.
(5) Approximately seven volumes of sulfur dioxid and forty volumes of producer gas are led into a chamber more or less completely filled with wood charcoal. The producer gasconsists mainly of carbon monoxid, nitrogen, hydrogen and carbon dioxid, and the mixture of the gases is either dry or contains more or less moisture. The reaction chamber containing the Wood charcoal and into which the mixture of about seven volumes of sulfur dioxid and forty ,volumes of producerigas is led is heated to a minimum temperature of about 500 C. The mixture reacts quantitatively and smoothly to produce sulfur, carbon dioxid and water. The reaction may be expressed as follows:
The products of the reaction issue from the chamber and the water and sulfur are collected in suitable condensers while the carbon dioxid and nitrogen escape into the air or are recovered by suitable means.
It will be noted that in every case by varying the composition of the gaseous mixtures, as indicated by the foregoing equations, anyrelative quantity of sulfur or same reactions, for while the hydrogen sulfid first formed might be to a certain extent decomposed in-the reaction zone, (it decom- The chamber con-' tice of the invention, it is not intended that.
there should be any consumption of the carbon, the wood charcoal not being altered during the reaction, its function being that of an absorbent for the gases and a catalyzer for the first reaction, which is made to take place more smoothly and regularly than without charcoal.
' What we claim is:
l". The method of utilizing sulfur dioxid, which comprises subjecting it to reaction with gaseous fuel in the presence of wood charcoal'at a temperature below that at which the charcoal would be consumed in the gaseous mixture; substantially as described.
2. The method of utilizing sulfur dioxid, which comprises subjecting it to reaction with gaseous fuel capable of reducing sulfur dioxid in the presence of wood charcoal at a temperature of about 500 to 600 6.; substantially as described.
3. The method of utilizing sulfur dioxid, which comprises subjecting it to reaction with gaseous fuel containing hydrogen in the presence of wood charcoal at a temperature below that at which the charcoal would be consumed in the gaseous mixture, the gaseous fuel being employed in excess of thatnecessary for converting the sulfur dioxid into sulfur, whereby the hydrogen of the excess will react with the sulfur produced to form hydrogen sulfid; substantially as described.
4. The method of utilizing sulfur dioxid,- which comprises subjecting it to reaction with gaseous fuel containing carbon monoxid and hydro-gen in the presence of wood charcoal at a-temperature below that at which the charcoal would be consumed in the gaseous mixture, the gaseous fuel being employed in excess of that necessary for converting the carbon monoxid into carbon dioxid whereby the hydrogen of the excess will react with the sulfur produced to form hydrogen sulfid; substantially as described.
. In testimony whereof we aflix our signatures, in presence of two witnesses. JAMES B. GARNER. HOWARD D. CLAYTON. Witnesses:
W. J. MOORE, M. R. HAINER.
Family
ID=
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