US9889418B2 - Fluidized fuel gas combustor system for a catalytic dehydrogenation process - Google Patents

Fluidized fuel gas combustor system for a catalytic dehydrogenation process Download PDF

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US9889418B2
US9889418B2 US14/868,507 US201514868507A US9889418B2 US 9889418 B2 US9889418 B2 US 9889418B2 US 201514868507 A US201514868507 A US 201514868507A US 9889418 B2 US9889418 B2 US 9889418B2
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Prior art keywords
fuel gas
fluidized
combustor
vessel
distributors
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US14/868,507
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US20170087528A1 (en
Inventor
Matthew T. Pretz
Richard E. Walter
Don F. Shaw
Fermin A. Sandoval
Liwei Li
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Dow Global Technologies LLC
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Dow Global Technologies LLC
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Priority to US14/868,507 priority Critical patent/US9889418B2/en
Priority to ARP160102856A priority patent/AR106077A1/es
Priority to PCT/US2016/054081 priority patent/WO2017058854A1/en
Priority to BR112018004497A priority patent/BR112018004497A2/pt
Priority to RU2018113247A priority patent/RU2736375C2/ru
Priority to CA3000174A priority patent/CA3000174C/en
Priority to CN201680051848.4A priority patent/CN108025275B/zh
Priority to KR1020187010497A priority patent/KR102614557B1/ko
Priority to MX2018002989A priority patent/MX2018002989A/es
Priority to EP16784307.7A priority patent/EP3356023B1/en
Publication of US20170087528A1 publication Critical patent/US20170087528A1/en
Assigned to CARMAGEN ENGINEERING reassignment CARMAGEN ENGINEERING ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SHAW, Don F., WALTER, RICHARD E.
Assigned to THE DOW CHEMICAL COMPANY reassignment THE DOW CHEMICAL COMPANY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CARMAGEN ENGINEERING
Assigned to DOW GLOBAL TECHNOLOGIES LLC reassignment DOW GLOBAL TECHNOLOGIES LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: THE DOW CHEMICAL COMPANY
Assigned to DOW GLOBAL TECHNOLOGIES LLC reassignment DOW GLOBAL TECHNOLOGIES LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: LI, LIWEI, PRETZ, MATTHEW T., SANDOVAL, FERMIN A.
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J7/00—Apparatus for generating gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/02—Heat treatment
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00—Fluidised bed combustion apparatus
    • F23C10/02—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed
    • F23C10/12—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated exclusively within the combustion zone
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818—Feeding of the fluidising gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818—Feeding of the fluidising gas
    • B01J8/1827—Feeding of the fluidising gas the fluidising gas being a reactant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/34—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with stationary packing material in the fluidised bed, e.g. bricks, wire rings, baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/44—Fluidisation grids
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00—Fluidised bed combustion apparatus
    • F23C10/18—Details; Accessories
    • F23C10/20—Inlets for fluidisation air, e.g. grids; Bottoms
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00—Fluidised bed combustion apparatus
    • F23C10/18—Details; Accessories
    • F23C10/22—Fuel feeders specially adapted for fluidised bed combustion apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00504—Controlling the temperature by means of a burner
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Definitions

  • the instant invention relates to a fluidized fuel gas combustor system for a catalytic dehydrogenation process.
  • catalyst reactivation or regeneration processes that treat catalysts with a reduced catalytic activity due, at least in part, to deposition of coke on catalyst surfaces involve removal of that coke, generally by contacting such catalysts at high temperature (e.g. at least 450 degrees Celsius (° C.) for an ethanol dehydration catalyst and at least 650° C. for a fluid catalyst cracking (FCC) catalyst) with air or another oxygen-containing gas
  • high temperature e.g. at least 450 degrees Celsius (° C.) for an ethanol dehydration catalyst and at least 650° C. for a fluid catalyst cracking (FCC) catalyst
  • FCC fluid catalyst cracking
  • the supplemental fuel further deactivates the catalyst in a catalytic dehydrogenation process using a gallium-platinum catalyst on alumina or alumina silica support, i.e., catalysts used in catalytic dehydrogenation of ethane, propane, butane, isobutane, butene, and ethylbenzene.
  • a gallium-platinum catalyst on alumina or alumina silica support i.e., catalysts used in catalytic dehydrogenation of ethane, propane, butane, isobutane, butene, and ethylbenzene.
  • PDH propane dehydrogenation
  • the dehydrogenation activity is damaged due to the combustion of an external fuel source.
  • the distribution of the fuel source is critical to achieve maximum combustion of the external fuel source on the catalyst as well as minimize any potential deactivation of the catalyst due to uneven distribution of fuel.
  • One constraint is that the distributor pipes themselves cannot block a high percentage of the combustor open area or the combustor will flood at this level or the catalyst will not be able to backmix and form a dense bed.
  • the distributor pipes block ⁇ 26% of the open area.
  • the base superficial velocity is 3.5-4 ft/s at this level in the combustor. With the blockage, the actual velocity will be 4.7-5.4 ft/s which are below the maximum of 8.0 ft/s where the catalyst will not be able to flow downward.
  • the fuel is often injected at ambient temperature which causes it to heat up as it transverses the distributor pipe within the bed which is operated at 680-800° C. and preferably from 700-770° C.
  • the gas density decreases which leads to maldistribution.
  • the first part of the pipe will release more mass of fuel than the portion of the pipe that allows the gas to be in the vessel the longest. Therefore, maldistribution occurs.
  • the maldistribution may cause portions of the combustor to have more stoichiometric fuel than air locally which means the fuel will have to mix with additional air and/or catalyst prior to combusting. This fuel contacting of the catalyst at high temperature results in catalyst deactivation that is not desirable.
  • the instant invention provides a fluidized fuel gas combustor system for a catalytic dehydrogenation process comprising a vessel having a lower portion and an upper portion; a plurality of air injection diffusers located in the lower portion of the vessel; optional fuel oil distributors for startup; a plurality of fuel gas injection diffusers located on fuel gas distributors disposed in the vessel and spaced apart from and above a plurality of air injection diffusers, wherein the fuel gas diffusers are placed in a manner to maximize even mass distribution of a fuel gas injected through the fuel gas diffusers in the vessel; one or more optional grid assemblies disposed in the vessel spaced apart from and above the plurality of air injection diffusers and spaced apart from and below the fuel gas distributors to maximize even air mass distribution; and one or more grid assemblies disposed in the vessel spaced above the fuel gas distributors.
  • FIG. 1 is a cutaway elevational view of a vessel used in a catalyst reactivation according to the present disclosure
  • FIG. 2 is a top view of top view of a first embodiment of fuel gas distributors
  • FIG. 3 is an cross sectional view of a first embodiment of a reinforced tube
  • FIG. 4 is a top view of a second embodiment of fuel gas distributors
  • FIG. 5 is a cross sectional elevational schematic of a bottom portion of the vessel illustrating the fuel gas distributors and air gas distributors;
  • FIG. 6 is a cross sectional schematic of a second embodiment of a tube and fuel gas injection distributor.
  • FIG. 1 a cutaway elevational view of an embodiment of a vessel 1 used as a fluidized fuel gas combustor system for a catalytic dehydrogenation process is shown.
  • Vessel 1 includes a lower portion 2 generally in the shape of a cylinder and an upper frustrum section 3 .
  • the angle between the frustum 3 and an internal horizontal imaginary line drawn at the intersection of the frustrum 3 and the lower portion 2 may range from 10 to 80 degrees. All individual values and subranges from 10 to 80 degrees are included and disclosed herein; for example the angle between the tubular and frustum components can range from a lower limit of 10, 40 or 60 degrees to an upper limit of 30, 50, 70 or 80 degrees.
  • the angle can be from 10 to 80 degrees, or in the alternative, from 30 to 60 degrees, or in the alternative, from 10 to 50 degrees, or in the alternative, from 40 to 80 degrees.
  • the angle can change along the height of the frustum, either continuously or discontinuously.
  • the vessel 1 may be, or may not be, lined with a refractory material.
  • Spent or partially deactivated catalyst enters the vessel 1 through downcomer 4 .
  • the spent or partially deactivated catalyst may enter vessel 1 from a side inlet or from a bottom feed, passing upward through the air distributor.
  • the used catalyst impinges upon and is distributed by splash guard 5 .
  • the vessel 1 further includes air distributors 6 which are located at or slightly below the height of the splash guard 5 .
  • Above the air distributors 6 and the outlet 7 of downcomer 4 is a grid 8 .
  • One or more additional grids 10 may be positioned within the vessel above the fuel gas distributors 9 .
  • each fuel gas distributor 9 enter the vessel 1 and traverse substantially a chord of the vessel 1 .
  • each fuel gas distributor 9 comprises a tube 30 with a fuel inlet end 11 and a terminal end 12 .
  • each tube 30 may further include at least one reinforcing element 20 running along at least part of the length of the tube 30 .
  • the reinforcing element(s) 20 may be of any shape or material which adds strength to tube 30 , including for example, square bars (as shown in FIG. 3 ) and round bars.
  • Each fuel gas distributor 9 further comprises a plurality of fuel gas injection diffusers 13 .
  • the fuel gas injection diffusers 13 permit the fuel gas to exit the tube 30 at an acceptable velocity, generally 50-300 feet per second and enter the interior space of vessel 1 .
  • a small orifice 14 at the start of each fuel gas injection diffusers 13 creates pressure drop and ensures more even distribution of the fuel gas into the bed.
  • the fuel inlet ends 11 of adjacent fuel gas distributors 9 are on opposite sides of the vessel 1 . Such alternating fuel inlet ends 11 provide one manner to maximize even mass distribution of a fuel gas injected through the fuel gas diffusers 9 in the vessel 1 due to the heat up phenomenon.
  • the maximization of even fuel mass distribution may be achieved by using sets of two tubes which span only a portion of a chord entering from opposing sides of the vessel, as is shown in FIG. 2 by the fuel gas distributors marked as 9 a and 9 b .
  • Yet another method of maximizing even mass distribution of the fuel is the use of a gradient distribution of fuel gas injection diffusers 13 with a greater number of fuel gas injection diffusers 13 toward the terminal end 12 of each tube 30 .
  • Yet another method is to increase the size of the fuel gas injection diffusers 13 and the small orifices 14 toward the terminal end 12 of each tube 30 .
  • fuel gas injection configurations can be used such as pipe distributors that are fed from one or more headers 15 that allow a main fuel gas stream to enter either from the side, top or bottom of vessel 1 and be fed to multiple tubes 30 , each tube 30 having a plurality of fuel gas injection diffusers 13 , as is shown in FIG. 4 .
  • the inlet ends 11 of tubes 10 in FIG. 4 join to the header 15 and the terminal ends 12 are located proximate to the vessel wall.
  • the fuel gas may be fed at different elevations within the vessel 1 although the preferred embodiment is to feed the fuel gas in a single level.
  • FIG. 6 illustrates another embodiment of the tube and fuel gas injection diffusers.
  • tube 30 and a single fuel gas injection diffuser 39 both in cross section.
  • no reinforcing element or refractory is present.
  • Fuel gas injection diffuser 39 comprises a shroud 41 which is attached onto tube 30 and a bore 43 passing through the outer wall of tube 30 and communicating with an internal passage 45 of shroud 41 .
  • Shroud 41 is attached to tube 30 so as to not allow an exposed crack between the inside of the tube 30 and the fuel gas injection diffuser 39 . As shown in FIG. 6 , such attachment is made by a weld 47 which extends around the outer surface of shroud 41 at its juncture with an outer surface of tube 30 .
  • the fuel gas can be methane, natural gas, ethane, propane, hydrogen or any gas that comprises energy value upon combustion.
  • Vessel 1 may further include one or more components selected from the group consisting of oxygen containing gas inlet 33 which communicates with space 49 , supplemental fuel inlet, spent catalyst inlet 35 , regenerator recycle catalyst inlet, and vessel outlet 37 .
  • the disclosure further provides the system for fuel injection according to any embodiment disclosed herein except that one or more of the reinforced tubes are at least partially covered with a refractory material to minimize heat transfer from the bed to the gaseous fuel.
  • the tube 30 has two reinforcing elements 11 . Between each reinforcing elements 11 , the tube 30 is coated in an optional refractory material 16 . Likewise, the refractory material 16 may be located between the fuel gas injection diffusers 13 and the reinforcing elements 11 . Any appropriate refractory material and anchoring may be used, including for example, RESCOCAST AA22S, RESCOCAST 7, 8, and 9 and R-MAX MP (all of which are commercially available from Resco Products, Inc.
  • ACTCHEM 85 commercially available from ARTech Inc.
  • a thin layer of lining 1 ⁇ 2 to 1′′ of refractory in a specialized anchor system such as hex mesh or a pipe tab, as are known in the art, may be used.
  • Grid assembly 8 assists in maximizing even air mass distribution.
  • the grid assemblies 8 and 10 may have in certain embodiments, the forms disclosed in U.S. patent application Ser. No. 14/755,008, filed Jun. 30, 2015 and U.S. patent application Ser. No. 14/751,424, filed Jun. 26, 2015, the disclosures of which are incorporated herein by reference.
  • the outlet 7 of downcomer 4 is located below the fuel gas distributors 9 and the grid assembly 8 and empties into a space between the grid assembly 8 and air distributor 6 .
  • Air distributor 6 comprises a plurality of air injection diffusers 16 . Between the air injection diffusers 16 , an optional refractory material may be used. In a particular embodiment, three to seven inches of a refractory material, such as RESCOCAST 8, may be used to minimize the temperature of the air injection diffusers 16 .
  • the air entering the air injection diffusers may be at about 635° C., with the temperature of the grid 8 being at about 750° C. In such instance, the air injection diffusers would be at about 640° C.
  • the air injection diffusers 16 can be located on a flat grid plate and skirt, on a dished grid plate and skirt or on a pipe grid distributor.
  • the air distributor 6 may, in certain embodiments, have a thinner metal edging at a bottom portion of the distributor.
  • FIG. 5 shows the grid plate and skirt option for supporting the air injection diffusers 16 .
  • a skirt 17 extends downward from the air distributor 6 .
  • the length of the skirt 17 extending downward from the air distributor 6 may range from 3 to 7 feet.
  • the skirt 17 may have a thickness of from 0.75 to 3 inches over its length extending from the air distributor 6 to a length of 6 to 18 inches with a narrowing of the skirt thickness (not shown) to a 0.25 to 0.625 inch further down the length of the skirt.
  • Such a taper in the skirt thickness provides greater skirt strength proximate to the air distributor 6 for resistance to thermal and pressure stresses and for greater skirt flexibility at the lower portion of the skirt.
  • the air distributor 6 may have the configurations discussed above in connection with the fuel gas distributor. That is, the air distributor may comprise a plurality of tubes entering the side of vessel 1 or may be fed through a header.
  • splash plate 5 Used catalyst exiting the outlet 7 of downcomer 4 impinges upon and is distributed by splash plate 5 .
  • splash plate 5 may be at least partially covered in a refractory material, for example, by 0.5 to 1 inch thick hex mesh refractory.
  • each reinforced tube comprises two rows of fuel gas diffusers at a density of from 5 to 100 diffusers per square meter of the cross sectional area of the combustor wherein the rows are spaced apart and angled downward at 45 degrees at approximately 90 degrees from each other. All individual values and subranges from 5 to 100 diffusers per square meter are included and disclosed herein; for examples the density of fuel gas diffusers may range from a lower limit of 5, 10 or 15 to an upper limit of 100, 90 or 80 diffusers per square meter. For example, the density of fuel gas diffusers may range from 5 to 100 diffusers per square meter, or in the alternative, from 10 to 80 diffusers per square meter, or in the alternative, from 15 to 70 diffusers per square meter.
  • the disclosure further provides the fluidized fuel gas combustor system for a catalytic dehydrogenation process according to any embodiment disclosed herein except that the air distributor is a pipe distributor, dished plate or flat plate grid distributor with an air diffuser density of from 5 to 100 air diffuser per square meter. All individual values and subranges from 5 to 100 air diffusers per square meter are included and disclosed herein; for example, the density of air diffusers may range from a lower limit of 5, 10 or 15 diffusers per square meter to an upper limit of 100, 90 or 80 air diffusers per square meter. For example, the air diffuser density may range from 5 to 100 air diffusers per square meter, or in the alternative, from 10 to 90 diffusers per square meter, or in the alternative, from 20 to 80 diffusers per square meter.
  • the air distributor is a pipe distributor, dished plate or flat plate grid distributor with an air diffuser density of from 5 to 100 air diffuser per square meter. All individual values and subranges from 5 to 100 air diffuse
  • the disclosure further provides the fluidized fuel gas combustor system for a catalytic dehydrogenation process according to any embodiment disclosed herein except that the air distributor supplies sufficient air to provide greater than 110% of the stoichiometric required amount oxygen for fuel gas combustion. All individual values and sub-ranges greater than 110% are included and disclosed herein.
  • the air distributor may supply sufficient air to provide greater than 125% of the stoichiometric required amount oxygen for fuel gas combustion, or in the alternative, greater than 135%, or in the alternative, greater than 150%, or in the alternative, greater than 165%.
  • the disclosure further provides the fluidized fuel gas combustor system for a catalytic dehydrogenation process according to any embodiment disclosed herein except that the air distributor supplies sufficient air to provide greater than 105% of the stoichiometric required amount oxygen for fuel gas and coke combustion. All individual values and sub-ranges greater than 105% are included and disclosed herein.
  • the air distributor may supply sufficient air to provide greater than 125% of the stoichiometric required amount oxygen for fuel gas and coke combustion, or in the alternative, greater than 135%, or in the alternative, greater than 150%, or in the alternative, greater than 165%.
  • the disclosure further provides the fluidized fuel gas combustor system for a catalytic dehydrogenation process according to any embodiment disclosed herein except that the grid assembly sections comprise means for blocking open area that have an open area of from 30% to 98% with gas velocities through the openings less than 8 feet per second. All individual values and subranges from 30 to 98% are included and disclosed herein; for example, the open area may range from a lower limit of 30, 40, 50, 60, 70 or 80% to an upper limit of 50, 60, 70, 80, 90 or 98%. For example, the open area may range from 30 to 98%, or in the alternative, from 30 to 75%, or in the alternative, from 75 to 98%, or in the alternative, from 65 to 95%.
  • Such means include, for example, packing, chevrons and subway grating as well as any means disclosed in U.S. patent application Ser. No. 14/755,008, filed Jun. 30, 2015 and U.S. patent application Ser. No. 14/751,424, filed Jun. 26, 2015, the disclosures of which are incorporated herein by reference.
  • the partially deactivated, or used, catalyst is heated to a temperature of at least 660° C. but no greater than 850° C., preferably from 700° C. to 770° C., and more preferably from 720° C. to 750° C.
  • the combustor which serves as a part of the regeneration area and wherein the supplemental fuel and coke will be combusted (i.e., oxidized with an oxygen containing gas) to form H 2 O and CO 2 , comprise a lower section operating as a fast fluidized, turbulent, or bubbling bed and an upper section operating as a riser.
  • the WHSV in the fluidized fuel gas combustor system may conveniently range from about 0.1 to about 100 lb of air+fuel feed per hour (h) per lb of catalyst in the combustor (lb feed/h/lb catalyst).
  • the superficial gas velocity may range therein from about 1 feet per second (ft/s, about 0.3 meters per second, m/s) to about 80 ft/s (about 24.38 m/s), preferably from about 2 ft/s (about 0.61 m/s) to 10 ft/s (about 3.05 m/s), in the lower portion of the combustor, and from 20 ft/s (about 6.09 m/s) to about 70 ft/s (about 21.31 m/s) in the upper portion of the combustor.
  • a combustor comprises a lower portion that operates as a fast fluidized or turbulent reactor and an upper portion that operates as a riser reactor
  • the superficial gas velocity may range therein from about 1
  • the catalyst flux is preferably from about 1 pound per square foot-second (lb/ft 2 ⁇ s) (4.89 kg/m 2 ⁇ s) to about 20 lb/ft 2 ⁇ s (97.7 kg/m 2 ⁇ s) in the lower portion of the combustor, and from about 10 lb/ft 2 ⁇ s (48.9 kg/m 2 ⁇ s) to about 200 lb/ft 2 ⁇ s (489 kg/m 2 ⁇ s) in the upper portion of the combustor.
  • a catalyst flux of higher than about 200 lb/ft 2 ⁇ s may be employed, but is generally not preferred. Those skilled in the art will be able to appropriately adjust catalyst flux based upon WHSV and ratio of catalyst feed to air/supplemental fuel feed.
  • Pressure in the fluidized fuel gas combustor system ranges from 15 to 70 psia. All individual values and subranges from 15 to 70 psia are included and disclosed herein.
  • the pressure in the fluidized fuel gas combustor system may range from 15 to 70 psia, or in the alternative, from 15 to 45 psia, or in the alternative from 25 to 40 psia, or in the alternative, from 35 to 70 psia.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Fluidized-Bed Combustion And Resonant Combustion (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
US14/868,507 2015-09-29 2015-09-29 Fluidized fuel gas combustor system for a catalytic dehydrogenation process Active US9889418B2 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
US14/868,507 US9889418B2 (en) 2015-09-29 2015-09-29 Fluidized fuel gas combustor system for a catalytic dehydrogenation process
ARP160102856A AR106077A1 (es) 2015-09-29 2016-09-20 Un sistema de combustión de un gas combustible fluidizado para un proceso de deshidrogenación catalítica
EP16784307.7A EP3356023B1 (en) 2015-09-29 2016-09-28 A fluidized fuel gas combustor system for a catalytic dehydrogenation process
RU2018113247A RU2736375C2 (ru) 2015-09-29 2016-09-28 Система камеры сгорания топливного газа с кипящим слоем для процесса каталитической дегидрогенизации
CA3000174A CA3000174C (en) 2015-09-29 2016-09-28 A fluidized fuel gas combustor system for a catalytic dehydrogenation process
CN201680051848.4A CN108025275B (zh) 2015-09-29 2016-09-28 一种用于催化脱氢过程的流化燃料气体燃烧器系统
KR1020187010497A KR102614557B1 (ko) 2015-09-29 2016-09-28 촉매 탈수소화 공정을 위한 유동성 연료 가스 연소기 장치
MX2018002989A MX2018002989A (es) 2015-09-29 2016-09-28 Sistema de camara de combustion de gas combustible fluidizado para proceso de deshidrogenacion catalitica.
PCT/US2016/054081 WO2017058854A1 (en) 2015-09-29 2016-09-28 A fluidized fuel gas combustor system for a catalytic dehydrogenation process
BR112018004497A BR112018004497A2 (pt) 2015-09-29 2016-09-28 um sistema de combustor de gás de combustível fluidizado para um processo de desidrogenação catalítica

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AR106077A1 (es) 2017-12-13
CA3000174C (en) 2023-09-26
KR102614557B1 (ko) 2023-12-18
US20170087528A1 (en) 2017-03-30
EP3356023A1 (en) 2018-08-08
CA3000174A1 (en) 2017-04-06
RU2736375C2 (ru) 2020-11-16
WO2017058854A1 (en) 2017-04-06
BR112018004497A2 (pt) 2018-09-25
KR20180063136A (ko) 2018-06-11
EP3356023B1 (en) 2023-12-27
CN108025275B (zh) 2021-10-15
CN108025275A (zh) 2018-05-11

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