US9509030B2 - Power management system for a microbial fuel cell and microbial electrolysis cell coupled system - Google Patents
Power management system for a microbial fuel cell and microbial electrolysis cell coupled system Download PDFInfo
- Publication number
- US9509030B2 US9509030B2 US13/847,004 US201313847004A US9509030B2 US 9509030 B2 US9509030 B2 US 9509030B2 US 201313847004 A US201313847004 A US 201313847004A US 9509030 B2 US9509030 B2 US 9509030B2
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- mec
- mfc
- power
- power management
- management unit
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M16/00—Structural combinations of different types of electrochemical generators
- H01M16/003—Structural combinations of different types of electrochemical generators of fuel cells with other electrochemical devices, e.g. capacitors, electrolysers
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- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J4/00—Circuit arrangements for mains or distribution networks not specified as AC or DC
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04858—Electric variables
- H01M8/04925—Power, energy, capacity or load
- H01M8/04932—Power, energy, capacity or load of the individual fuel cell
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/02—Process control or regulation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B5/00—Electrogenerative processes, i.e. processes for producing compounds in which electricity is generated simultaneously
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04858—Electric variables
- H01M8/04925—Power, energy, capacity or load
- H01M8/04947—Power, energy, capacity or load of auxiliary devices, e.g. batteries, capacitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/16—Biochemical fuel cells, i.e. cells in which microorganisms function as catalysts
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/10—Fuel cells in stationary systems, e.g. emergency power source in plant
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02B90/10—Applications of fuel cells in buildings
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- Y02B90/14—
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Y02E60/366—
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y02E60/527—
-
- Y02E60/566—
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- Y10T307/352—
Definitions
- PMU Power Management Unit
- PMUs in general is used to control power applied to an electrical load depending on load conditions and/or input power applied to the system.
- PMUs are implemented using solid-state device such as BJTs or FETs and capacitors and/or inductors.
- PMUs are switching regulators capable of boosting or bucking a DC input voltage applied to them.
- Microbial Fuel Cells are used to generate electricity while treating waste-water.
- Microbial Electrolysis cells are used to produce hydrogen gas from waste-water by applying external power to it.
- MFC and MEC coupled systems are low-voltage systems (around 1V) and low current in the order of few hundred mA.
- the PMUs require electronic switches and other associated circuitry capable of operating under such low voltages and producing very little voltage drop across them.
- Carbon Nanotubes and nanowires are used to improve charge transfer between anaerobic bacteria and anode surface of a microbial fuel cell.
- Inverters together with PMUs and/or DC combiners are used to apply power to the electrical grid or local factory such as waste-water treatment plant either from an array of solar panels, stack of solid-oxide fuel cells using natural gas or other fuels, and farm of wind turbines.
- PMU has been designed that controls the power applied to an electrical load consisting of a hydrogen producing fuel cell and an electrical system that supplies power to the consumer such as waste-water treatment plant simultaneously.
- the PMU allows a means to control the production of hydrogen or electricity depending on demand conditions.
- FIG. 1 illustrates a typical electrical circuit connection between MFC-MEC systems to control hydrogen production.
- FIG. 2 illustrates an electrical circuit connection of MFC-MEC coupled system using electronic switches and controller to control hydrogen production and supply power to an external load simultaneously.
- FIG. 3 is an electrical circuit diagram using a switched capacitor implementation of Power Management Unit.
- FIG. 4 is a timing diagram of the PMU using PWM controller and electronic switches.
- FIG. 5 details the working of switched capacitor based PMU over time.
- FIG. 6 is a schematic diagram setup for an electrical circuit simulation in TINATM.
- FIG. 7 is the equation that governs the voltage applied to the MEC.
- FIG. 8 is the equation that governs the output voltage of PMU that is available to power an electrical system.
- FIG. 9 is a timing diagram that corresponds to more power being made available to an external electrical system while less power made available for hydrogen production in MEC.
- FIG. 10 is a timing diagram that corresponds to more power made available for increased hydrogen production while less power made available to the electrical system.
- FIG. 11 is a block diagram of the MFC-MEC fuel cell system with built-in PMU shown as a basic building block.
- FIG. 12 shows an array of the MFC-MEC fuel cell system configuration to use in a typical waste-water treatment plant.
- the equivalent circuit of MFC is represented by 10 , and that of MEC by 11 .
- the potentiometer 12 is used to control the voltage and hence power applied to the MEC in a typical laboratory setting to control the hydrogen production.
- the drawback of this scheme is that the power is dissipated as heat in 12 reducing the efficiency of the system.
- FIG. 2 shows the block diagram of the PMU design using electronic switch circuits 13 and 14 to obtain high efficiencies.
- the switch circuits 13 and 14 are controlled by 15 , a PWM controller with a feedback from output in order to maintain the set output voltage.
- the switch circuits can be implemented using a switching regulator. This switching regulator can be of either capacitor or inductor based switching circuits.
- FIG. 3 shows a typical implementation of PMU using switched-capacitor based circuit topology. This is a desired topology due to low currents and voltages of the MFC-MEC coupled system.
- Switches S 1 -S 5 can be a MOSFETs (or ultra-low voltage semiconducting switching device) with low channel resistance to minimize power loss.
- PWM controller can be implemented using an off-the-shelf IC.
- FIG. 4 shows the timing diagram of the PWM controller.
- the width of the timing pulse to S 1 with respect to the overall timing period T, the desired voltage is supplied to the cathode chamber of MFC.
- the width of the timing pulses, T 2 and T 3 determine the output voltage of the regulator for external use.
- T 1 , T 2 and T 3 are all required to be non-overlapping timing pulses.
- FIG. 5 details the working of the switched capacitor voltage regulator over a complete cycle of operation.
- the typical frequency of operation of the PWM controller is of the order of 100 KHz.
- FIG. 6 is a schematic diagram of the switched-capacitor based voltage regulator in a circuit simulator called TINATM.
- VG 1 -VG 3 represent the PWM controller operating at about 100 KHz repetition rate.
- S 1 -S 5 represent ideal switches with some resistance to reflect the channel resistance of MOSFETs. It is also set to have a low switching threshold voltage ( ⁇ 0.5V).
- the MFC and MEC is represented by a battery element with a reasonable internal resistance (5 ohms) typical of a large volume cell.
- Capacitors C 1 and C 2 are a typical low leakage capacitors such as tantalum.
- R load mimics the typical load expected of a single MFC-MEC coupled system.
- FIG. 7 and FIG. 8 are the equations governing the voltage applied to the MEC and external load respectively based on timing periods, external load resistance, switch resistance and capacitor values.
- FIG. 9 shows the timing waveform of the simulation setup corresponding to minimum hydrogen production or more power to external load.
- the voltage delivered to the external load is about 1.3 volts.
- the amount of voltage applied to cathode chamber of MEC is about 0.2 volts.
- FIG. 10 shows the timing waveform of the simulation setup corresponding to the maximum hydrogen production or less power to the external load.
- the voltage delivered to the external load is about 0.2 volts.
- the amount of voltage applied to cathode chamber is about 1.0 volt.
- FIG. 11 shows the basic building block of the MFC-MEC coupled system with a built-in PMU.
- the physical size of the building block is predominantly determined by the energy densities required at a waste-water treatment facility.
- FIG. 12 shows the inter-connection of the basic building block to form a larger electrical system.
- the building blocks are connected in series to increase the terminal voltage of the combined system while in parallel to increase the current production.
- Several of the systems are connected in parallel once a give terminal voltage has been setup in a DC combiner box before feeding into an Inverter.
- the inverter is then connected to either an electrical grid or used locally to power the plant or residential or commercial facility.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Manufacturing & Machinery (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Automation & Control Theory (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Power Engineering (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Fuel Cell (AREA)
Abstract
Description
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Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/847,004 US9509030B2 (en) | 2012-03-20 | 2013-03-19 | Power management system for a microbial fuel cell and microbial electrolysis cell coupled system |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261612981P | 2012-03-20 | 2012-03-20 | |
| US13/847,004 US9509030B2 (en) | 2012-03-20 | 2013-03-19 | Power management system for a microbial fuel cell and microbial electrolysis cell coupled system |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| US20140285007A1 US20140285007A1 (en) | 2014-09-25 |
| US9509030B2 true US9509030B2 (en) | 2016-11-29 |
| US20160372931A9 US20160372931A9 (en) | 2016-12-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| US13/847,004 Active 2035-03-06 US9509030B2 (en) | 2012-03-20 | 2013-03-19 | Power management system for a microbial fuel cell and microbial electrolysis cell coupled system |
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| US (1) | US9509030B2 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104926023B (en) * | 2015-03-09 | 2017-01-04 | 浙江大学 | Rural domestic sewage treatment system in conjunction with microbiological fuel cell Yu anaerobic manpower wetland |
| CN104828938B (en) * | 2015-04-28 | 2017-03-08 | 华南理工大学 | The device of hydrogen phosphide is produced in a kind of phosphor-containing organic wastewater multistage dephosphorization |
| CN106745772B (en) * | 2016-12-29 | 2020-06-30 | 东南大学 | Row-array type microbial fuel cell constructed wetland sewage treatment system |
| KR102095999B1 (en) * | 2017-11-10 | 2020-04-01 | 대한민국(농촌진흥청장) | Microbial Fuel Cell system for power management |
| CN109319942A (en) * | 2018-09-20 | 2019-02-12 | 江苏理工学院 | Construction method of a bioelectrochemical treatment system and application of treating copper and nickel in electroplating wastewater |
| JP7168541B2 (en) * | 2019-10-16 | 2022-11-09 | 株式会社豊田中央研究所 | water electrolysis system |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130076145A1 (en) * | 2011-09-23 | 2013-03-28 | The Penn State Research Foundation | Capacitor circuit for arrays of power sources such as microbial fuel cells |
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2013
- 2013-03-19 US US13/847,004 patent/US9509030B2/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130076145A1 (en) * | 2011-09-23 | 2013-03-28 | The Penn State Research Foundation | Capacitor circuit for arrays of power sources such as microbial fuel cells |
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| Publication number | Publication date |
|---|---|
| US20160372931A9 (en) | 2016-12-22 |
| US20140285007A1 (en) | 2014-09-25 |
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