CN104926023B - Rural domestic sewage treatment system in conjunction with microbiological fuel cell Yu anaerobic manpower wetland - Google Patents
Rural domestic sewage treatment system in conjunction with microbiological fuel cell Yu anaerobic manpower wetland Download PDFInfo
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- CN104926023B CN104926023B CN201510269360.6A CN201510269360A CN104926023B CN 104926023 B CN104926023 B CN 104926023B CN 201510269360 A CN201510269360 A CN 201510269360A CN 104926023 B CN104926023 B CN 104926023B
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- anaerobic
- anaerobic pond
- fuel cell
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- microbiological fuel
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- 239000010865 sewage Substances 0.000 title claims abstract description 40
- 239000000446 fuel Substances 0.000 title claims abstract description 18
- 230000002906 microbiologic effect Effects 0.000 title claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000012856 packing Methods 0.000 claims abstract description 13
- 239000007789 gas Substances 0.000 claims abstract description 9
- 239000002689 soil Substances 0.000 claims description 8
- 239000002322 conducting polymer Substances 0.000 claims description 6
- 229920001940 conductive polymer Polymers 0.000 claims description 6
- 239000004020 conductor Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000010802 sludge Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- -1 carbon nano tube compound Chemical class 0.000 claims description 3
- 239000002041 carbon nanotube Substances 0.000 claims description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 238000007667 floating Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 4
- 238000010276 construction Methods 0.000 abstract description 3
- 241000196324 Embryophyta Species 0.000 description 13
- 238000005516 engineering process Methods 0.000 description 8
- 244000005700 microbiome Species 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 241000195967 Anthoceros Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 241000628997 Flos Species 0.000 description 1
- 241000209490 Nymphaea Species 0.000 description 1
- 244000273256 Phragmites communis Species 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- 230000000703 anti-shock Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000007269 microbial metabolism Effects 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
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- Biological Treatment Of Waste Water (AREA)
- Inert Electrodes (AREA)
Abstract
The open one of the present invention combines microbiological fuel cell and anaerobic manpower wetland rural sewage processing system.It includes water inlet, anode, anaerobic pond, collection and confinement of gases mouth, load, wire, negative electrode, mozzle, floral region, packing area, outlet;Anode, negative electrode it is provided with in anaerobic pond, anaerobic pond bottom is provided with water inlet, anaerobic pond top is provided with collection and confinement of gases mouth and collects biogas, anode is connected with load two ends by wire respectively with negative electrode, anaerobic pond top is connected with the artificial wet land system being made up of floral region and packing area by mozzle, and sewage flows out through outlet.The device have the advantages that and be: 1. the planting cost of water plant is the lowest.2. due to the existence of electrode, electrochemical action is incorporated in traditional anaerobic bio-treated, improves the treatment effect of sewage.3. reduce the sewage time of staying in anaerobic pond, thus reduce the volume of anaerobic pond, reduce the floor space of system, saved land resource and reduced capital construction cost.
Description
Technical field
The present invention relates to water process and technical field of new energies, be specifically related to the rural domestic sewage treatment system of a kind of combination microbiological fuel cell and anaerobic manpower wetland.
Background technology
Along with the development of China's rural economy and improving constantly of life in the countryside level, the environmental pollution that domestic sewage in rural areas causes increases the weight of increasingly.
At present, China's domestic sewage in rural areas discharge capacity is about 8,000,000,000 90 hundred million t every year, and is continuously increased, but disposition allows of no optimist.The village of 96% does not has discharge conduit and sewage disposal system, and sanitary sewage arbitrarily discharges.The random discharge of domestic sewage in rural areas has become the main reason of rural areas in our country water environment pollution.
At present in China's distributing technology for treating domestic sewage in rural area, mainly based on anaerobic biogas generating pit treatment technology, stabilization pond treatment technology, Treatment Technology of Constructed Wetland, soil filtration technology etc..Wherein anaerobic manpower wetland technology has been widely used in rural domestic sewage treatment due to advantages such as its capital construction operating cost are low, easy and simple to handle, anti-shock loading performance is good.But anaerobic manpower wetland technology is relatively low for the treatment effeciency of sanitary sewage, effluent quality is usually unable to reach discharge standard, limits it and further applies.
On the other hand, utilizing the effect of microorganism to carry out energy conversion (such as the metabolism of carbohydrate or photosynthesis etc.), on the electron transmission that Repiration is produced to electrode, such device is microbiological fuel cell (MFC).Make biocatalyzer with microorganism, energy conversion can be carried out at normal temperatures and pressures.In recent years, MFC quickly grows, but never obtains large-scale actual application.Tracing it to its cause, electrode material is expensive, and efficiency of fuel cell generation is the most high, is the principal element restricting its engineer applied.
Summary of the invention
It is an object of the invention to overcome existing deficiency, it is provided that a kind of economic, practical, combination microbiological fuel cell of high treating effect and the rural domestic sewage treatment system of anaerobic manpower wetland.
Rural domestic sewage treatment system in conjunction with microbiological fuel cell Yu anaerobic manpower wetland includes water inlet, anode, anaerobic pond, collection and confinement of gases mouth, load, wire, negative electrode, mozzle, floral region, packing area, outlet;Anode, negative electrode it is provided with in anaerobic pond, anaerobic pond bottom is provided with water inlet, anaerobic pond top is provided with collection and confinement of gases mouth and collects biogas, anode is connected with load two ends by wire respectively with negative electrode, anaerobic pond top is connected with the artificial wet land system being made up of floral region and packing area by mozzle, and sewage flows out through outlet.
Described anode is material with carbon element, conducting polymer, CNT or the electrode of conducting polymer/carbon nano tube compound material.Containing anaerobic sludge and the mixed liquor of sewage in described anaerobic pond.The resistance of described load is 1000 ohm.Described wire uses titanium wire or copper conductor, and the insulated enclosure carrying out junction point processes.Described negative electrode is the electrode of porous, electrically conductive material.Described floral region planting plants is plant waterborne, phytobenthon, phytoplankton or large-scale emergent aquactic plant.Described packing area is made up of surface soil layer, middle level gravel, the little gravel of lower floor.
Due to the fact that the existence of electrode so that the speed of electron transfer improves, microbial metabolism speed is accelerated;Meanwhile, electrochemical action is incorporated in sewage disposal process by the existence of electrode so that the redox rate of pollutant is accelerated, and improves the treatment effect of sewage.And the raising of wastewater treatment efficiency, correspondingly can reduce the sewage time of staying in anaerobic pond, thus reduce the volume of anaerobic pond, reduce the floor space of system, saved land resource and reduced capital construction cost.On the other hand, owing to the planting cost of water plant is the lowest, and whole system is without using expensive permselectivity membrane and the traditional noble metal such as electrode material such as platinum, gold, significantly reduces operating cost.
Accompanying drawing explanation
Fig. 1 is the structural representation combining microbiological fuel cell with the rural domestic sewage treatment system of anaerobic manpower wetland.
In figure: water inlet 1, anode 2, anaerobic pond 3, collection and confinement of gases mouth 4, load 5, wire 6, negative electrode 7, mozzle 8, floral region 9, packing area 10, outlet 11.
Detailed description of the invention
As it is shown in figure 1, the rural domestic sewage treatment system combining microbiological fuel cell and anaerobic manpower wetland includes water inlet 1, anode 2, anaerobic pond 3, collection and confinement of gases mouth 4, load 5, wire 6, negative electrode 7, mozzle 8, floral region 9, packing area 10, outlet 11;Anode 2, negative electrode 7 it is provided with in anaerobic pond 3, anaerobic pond 3 bottom is provided with water inlet 1, anaerobic pond 3 top is provided with collection and confinement of gases mouth 4 and collects biogas, anode 2 and negative electrode 7 by wire 6 respectively with load 5 two ends and be connected, anaerobic pond 3 top is connected with the artificial wet land system being made up of floral region 9 and packing area 10 by mozzle 8, and sewage flows out through outlet 11.
Described anode 2 is material with carbon element, conducting polymer, CNT or the electrode of conducting polymer/carbon nano tube compound material.Containing anaerobic sludge and the mixed liquor of sewage in described anaerobic pond 3.The resistance of described load 5 is 1000 ohm.Described wire 6 uses titanium wire or copper conductor, and the insulated enclosure carrying out junction point processes.Described negative electrode 7 is the electrode of porous, electrically conductive material.
Described floral region 9 planting plants is plant waterborne, phytobenthon, phytoplankton or large-scale emergent aquactic plant.Selectable emergent aquactic plant has: phragmites communis, Caulis Zizaniae caduciflorae, Herba Scirpi Tabernaemontani, Rhizoma Acori Graminei, Herba Typhae, Medulla Junci etc.;Floating plant is: Herba Eichhorniae, Herba Spirodelae, Flos nymphaeae (Nymphaea teragona Georgi) etc.;Submerged plant is: Yi Lecao, hornwort, black algae etc..In artificial swamp, the degree of depth of water surface submergence root system of plant should be uniform.The planting density of described plant is preferably 9 strains/m225 strains/m2。
Described packing area 10 is by surface soil layer, middle level gravel, lower floor's little gravel up of three layers.Surface soil layer calcium content is at 2.0-2.5kg/100kg, and gravel layer particle diameter is at 5-50mm, and laying depth is 0.4-0.7m.The quality of artificial swamp planting soil is clay loam, and thickness of soil is 20 40cm, and infiltration coefficient is 0.025cm/h 0.35cm/h.
Sewage water treatment method in conjunction with microbiological fuel cell with the rural domestic sewage treatment system of anaerobic manpower wetland is: treatment sewage flows into anaerobic pond 3 from water inlet 1, it is sufficiently mixed with anaerobic sludge therein, processed under the dual function of electrochemistry and anaerobic digestion, then flowed in artificial swamp by mozzle 8.Flow into the sewage of artificial swamp at the bottom of surface longitudinal flow to bed, the packing area 10 and floral region 9 being made up of surface soil layer, middle level gravel, the little gravel of lower floor is sequentially passed through during longitudinal flow, sewage passes through microorganism, the physics of root system of plant, chemical and biological common pathway complete to purify, and then flow out from outlet 11.
Claims (7)
1. the rural domestic sewage treatment system combining microbiological fuel cell and anaerobic manpower wetland, it is characterised in that: include water inlet (1), anode (2), anaerobic pond (3), collection and confinement of gases mouth (4), load (5), wire (6), negative electrode (7), mozzle (8), floral region (9), packing area (10), outlet (11);Anode (2), negative electrode (7) it is provided with in anaerobic pond (3), anaerobic pond (3) bottom is provided with water inlet (1), anaerobic pond (3) top is provided with collection and confinement of gases mouth (4) and collects biogas, anode (2) is connected with load (5) two ends by wire (6) respectively with negative electrode (7), anaerobic pond (3) top is connected with the artificial wet land system being made up of floral region (9) and packing area (10) by mozzle (8), and sewage flows out through outlet (11);Containing anaerobic sludge and the mixed liquor of sewage in described anaerobic pond (3);Described floral region (9) planting plants is emergent aquactic plant, floating plant and submerged plant.
A kind of combination microbiological fuel cell the most according to claim 1 and the rural domestic sewage treatment system of anaerobic manpower wetland, it is characterised in that: described anode (2) is material with carbon element, conducting polymer or the electrode of conducting polymer/carbon nano tube compound material.
A kind of combination microbiological fuel cell the most according to claim 1 and the rural domestic sewage treatment system of anaerobic manpower wetland, it is characterised in that: described anode (2) is the electrode of CNT.
A kind of combination microbiological fuel cell the most according to claim 1 and the rural domestic sewage treatment system of anaerobic manpower wetland, it is characterised in that: the resistance of described load (5) is 1000 ohm.
A kind of combination microbiological fuel cell the most according to claim 1 and the rural domestic sewage treatment system of anaerobic manpower wetland, it is characterised in that: described wire (6) uses titanium wire or copper conductor, and the insulated enclosure carrying out junction point processes.
A kind of combination microbiological fuel cell the most according to claim 1 and the rural domestic sewage treatment system of anaerobic manpower wetland, it is characterised in that: described negative electrode (7) is the electrode of porous, electrically conductive material.
A kind of combination microbiological fuel cell the most according to claim 1 and the rural domestic sewage treatment system of anaerobic manpower wetland, it is characterised in that: described packing area (10) are made up of surface soil layer, middle level gravel, the little gravel of lower floor.
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CN106977044B (en) * | 2017-03-27 | 2020-12-29 | 南京工业大学 | Photovoltaic three-dimensional micro-electricity-magnetic field drive reinforced composite anaerobic wastewater treatment system and process |
CN107381779B (en) * | 2017-09-01 | 2020-09-01 | 上海理工大学 | Sewage biological electrical stimulation treatment and tail gas synergistic wetland purification system |
CN110697873B (en) * | 2019-09-27 | 2020-10-02 | 南通大学 | Method for modifying coupling cluster type microbial fuel cell of downstream artificial wetland device |
CN114590957B (en) * | 2022-02-21 | 2023-10-31 | 上海勘测设计研究院有限公司 | Device and method for removing high-concentration heavy metals in wastewater by electrolysis and wetland combination |
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CN103825041A (en) * | 2014-03-06 | 2014-05-28 | 安徽工程大学 | Single-chamber and film-free anaerobic type microbial fuel cell for processing acidic mine wastewater |
CN104148371A (en) * | 2014-07-25 | 2014-11-19 | 中国环境科学研究院 | Organic garbage treatment-energy regeneration combined device and organic garbage treatment method |
CN204661489U (en) * | 2015-03-09 | 2015-09-23 | 浙江大学 | A kind of rural domestic sewage treatment system in conjunction with microbiological fuel cell and anaerobic manpower wetland |
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CN103825041A (en) * | 2014-03-06 | 2014-05-28 | 安徽工程大学 | Single-chamber and film-free anaerobic type microbial fuel cell for processing acidic mine wastewater |
CN104148371A (en) * | 2014-07-25 | 2014-11-19 | 中国环境科学研究院 | Organic garbage treatment-energy regeneration combined device and organic garbage treatment method |
CN204661489U (en) * | 2015-03-09 | 2015-09-23 | 浙江大学 | A kind of rural domestic sewage treatment system in conjunction with microbiological fuel cell and anaerobic manpower wetland |
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