US896705A - Process for hardening tantalum. - Google Patents

Process for hardening tantalum. Download PDF

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Publication number
US896705A
US896705A US27816605A US1905278166A US896705A US 896705 A US896705 A US 896705A US 27816605 A US27816605 A US 27816605A US 1905278166 A US1905278166 A US 1905278166A US 896705 A US896705 A US 896705A
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United States
Prior art keywords
tantalum
hardening
carbon
hardness
degree
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Expired - Lifetime
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US27816605A
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Werner Von Bolton
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Siemens and Halske AG
Siemens Corp
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Siemens Corp
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Priority to US27816605A priority Critical patent/US896705A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/20Carburising

Definitions

  • A. G. A OORPORA PROCESS FOR HARDENING TANTALUM.
  • My invention relates to the treatment of tantalum for various purposes, and is more especially concerned with a process for the hardening of tantalum.
  • Tantalum has been found useful for very many purposes, in some of which it should be very hard and resistant, while in other uses it must be comparatively soft and malleable.
  • tantalum possesses, in many respects, properties which are similar to those of iron. For example, when iron has added to it a small proportion of carbon, we find that the iron becomes very much harder. In the same way, if one adds to tantalum a very slight proportion of carbon the tantalum also becomes very much harder. Tantalum bodies may be hardened in this way by heating them to lowing in the resence of carbon. I have a so found that s ight traces of silicon and boron have a similar effect upon tantalum. Further, traces of hydrogen and oxygen, which are probably present in the form of hydrids and oxids will produce this hardening effect in the same manner. Many metals, such as aluminum,
  • tin and titanium are also applicable for this purpose.
  • the process forming the subject matter of the present invention consists then in adding to the tantalum' slight traces of hardening agents, such as those mentioned above. I do not wish to restrict my process to any particular method of performing this mixture or addition.
  • the mixture may be made in different proportions, varying from an extremely smal proportion of the added subor more of the same, ac-
  • the tantalum becomes very hard and resistant as soon I as a very small fraction of 1% is added. If the proportion is greater than this, the tantalum soon becomes very brittle, so that it can no longer be used for most of its purposes.
  • the degree 0 hardness and also the degree of tensile strength of the metal may be altered within very wide bounds. If, for example, the tantalum is to be made into wire, especially into fine, drawn out wire, then the de ree of hardness must be selected which will aIlow the metal to be drawn out in the usual manner without becoming broken or receiving fissures upon its outer surface. Adapting tantalum in this way to the manufacture of drawn out wire need not, however, be the only application given consideration here.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Description

UNITED STATES PATENT OFFICE.
A. G., A OORPORA PROCESS FOR HARDENING TANTALUM.
Application filed September 12, 1905. Serial No. 278,166.
To all whom 'it may concern:
Be it known that I, WERNER VON BOLTON, a subject of the Em eror of Russia, and residing in Charlotten urg, near Berlin, Germany, have invented a certain new and useful Process for Hardening Tantalum, of which the following is a specification.
My invention relates to the treatment of tantalum for various purposes, and is more especially concerned with a process for the hardening of tantalum.
Tantalum has been found useful for very many purposes, in some of which it should be very hard and resistant, while in other uses it must be comparatively soft and malleable.
The process I'have discovered has 'for its object to give to tantalum the particular degree of hardness required by it in the use to which it is to be put.
I have ascertained that tantalum possesses, in many respects, properties which are similar to those of iron. For example, when iron has added to it a small proportion of carbon, we find that the iron becomes very much harder. In the same way, if one adds to tantalum a very slight proportion of carbon the tantalum also becomes very much harder. Tantalum bodies may be hardened in this way by heating them to lowing in the resence of carbon. I have a so found that s ight traces of silicon and boron have a similar effect upon tantalum. Further, traces of hydrogen and oxygen, which are probably present in the form of hydrids and oxids will produce this hardening effect in the same manner. Many metals, such as aluminum,
tin and titanium are also applicable for this purpose.
stanc'e, up to 1% The process forming the subject matter of the present invention consists then in adding to the tantalum' slight traces of hardening agents, such as those mentioned above. I do not wish to restrict my process to any particular method of performing this mixture or addition. The mixture may be made in different proportions, varying from an extremely smal proportion of the added subor more of the same, ac-
Specification of Letters Patent.
Patented. Aug. 25, 1908.
cording to the degree of hardness required. In the case of carbon, for instance, the tanta- WERNER VON BOLTON, OF CHARLOTTENBURG, GERMANY, ASSIGNOR TO SIEMENS & HALSKE TION OF GERMANY.
lum becomes very hard and resistant as soon I as a very small fraction of 1% is added. If the proportion is greater than this, the tantalum soon becomes very brittle, so that it can no longer be used for most of its purposes.
By changing the uantity of the added material, the degree 0 hardness and also the degree of tensile strength of the metal may be altered within very wide bounds. If, for example, the tantalum is to be made into wire, especially into fine, drawn out wire, then the de ree of hardness must be selected which will aIlow the metal to be drawn out in the usual manner without becoming broken or receiving fissures upon its outer surface. Adapting tantalum in this way to the manufacture of drawn out wire need not, however, be the only application given consideration here. If, on the other hand, it is to be used for the construction of tools for wood working, stone working, metal working or the like, or for the construction of bearings, wheels and the like for machines or clock works, etc., one must give the tantalum a very much higher degree of hardness and the malleability and tensile strength need not be given so much consideration. For this latter purpose, the
ro ortion of the added material would be liig er than it would be for the manufacture of drawn out wires and such uses.
Having thus described my invention, the following is what I claim as new therein and desire to secure by Letters Patent:
1. The herein described process for hardening tantalum, which consists in adding carbon to tantalum.
2. The herein described rocess for hardening tantalum which conslsts in adding to tantalum a small percentage of carbon.
3. The rocess of hardening tantalum, which consists in heating tantalum to glowing in the presence of carbon.
' WERNER VON BOLTON.
Witnesses:
HENRY HASPER, WOLDEMAR HAUPT.
US27816605A 1905-09-12 1905-09-12 Process for hardening tantalum. Expired - Lifetime US896705A (en)

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US27816605A US896705A (en) 1905-09-12 1905-09-12 Process for hardening tantalum.

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2453896A (en) * 1942-06-26 1948-11-16 Chicago Dev Co Treatment of titanium
US2832710A (en) * 1956-03-01 1958-04-29 Heraeus Gmbh W C Method for carburizing spinning nozzles composed of tantalum and alloys thereof
US3113893A (en) * 1960-10-14 1963-12-10 Sylvania Electric Prod Incandescent filament
US3486979A (en) * 1966-10-11 1969-12-30 Atomic Energy Commission Method of preventing plutonium leakage
US4447825A (en) * 1980-02-28 1984-05-08 Tokyo Shibaura Denki Kabushiki Kaisha III-V Group compound semiconductor light-emitting element having a doped tantalum barrier layer

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2453896A (en) * 1942-06-26 1948-11-16 Chicago Dev Co Treatment of titanium
US2832710A (en) * 1956-03-01 1958-04-29 Heraeus Gmbh W C Method for carburizing spinning nozzles composed of tantalum and alloys thereof
US3113893A (en) * 1960-10-14 1963-12-10 Sylvania Electric Prod Incandescent filament
US3486979A (en) * 1966-10-11 1969-12-30 Atomic Energy Commission Method of preventing plutonium leakage
US4447825A (en) * 1980-02-28 1984-05-08 Tokyo Shibaura Denki Kabushiki Kaisha III-V Group compound semiconductor light-emitting element having a doped tantalum barrier layer

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