US8945762B2 - Battery - Google Patents

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Publication number
US8945762B2
US8945762B2 US13/361,883 US201213361883A US8945762B2 US 8945762 B2 US8945762 B2 US 8945762B2 US 201213361883 A US201213361883 A US 201213361883A US 8945762 B2 US8945762 B2 US 8945762B2
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United States
Prior art keywords
gasket
current collector
base
rib
battery according
Prior art date
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US13/361,883
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US20120196179A1 (en
Inventor
Isao Suzuki
Yu Shiraishi
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GS Yuasa International Ltd
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GS Yuasa International Ltd
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Assigned to GS YUASA INTERNATIONAL LTD. reassignment GS YUASA INTERNATIONAL LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: Shiraishi, Yu, SUZUKI, ISAO
Publication of US20120196179A1 publication Critical patent/US20120196179A1/en
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/172—Arrangements of electric connectors penetrating the casing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H01M2/0456—
    • H01M2/08—
    • H01M2/22—
    • H01M2/30—
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/147—Lids or covers
    • H01M50/148—Lids or covers characterised by their shape
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/183—Sealing members
    • H01M50/184—Sealing members characterised by their shape or structure
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/183—Sealing members
    • H01M50/186—Sealing members characterised by the disposition of the sealing members
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/528—Fixed electrical connections, i.e. not intended for disconnection
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/172—Arrangements of electric connectors penetrating the casing
    • H01M50/174—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells
    • H01M50/176—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for prismatic or rectangular cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/183—Sealing members
    • H01M50/19—Sealing members characterised by the material
    • H01M50/191—Inorganic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/543—Terminals
    • H01M50/547—Terminals characterised by the disposition of the terminals on the cells
    • H01M50/55—Terminals characterised by the disposition of the terminals on the cells on the same side of the cell
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/543—Terminals
    • H01M50/552—Terminals characterised by their shape
    • H01M50/553—Terminals adapted for prismatic, pouch or rectangular cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/543—Terminals
    • H01M50/562—Terminals characterised by the material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the present invention relates to a battery including a nonaqueous electrolytic secondary battery.
  • a battery such as a nonaqueous electrolytic secondary battery includes a positive current collector and a negative current collector for electrically connecting a positive electrode and a negative electrode in an electrode assembly contained inside of a battery case to a positive external terminal and a negative external terminal, respectively.
  • a base of the current collector is fixed to a cover for sealing an upper opening of the battery case by means such as caulking using, for example, a rivet.
  • a gasket is interposed between the base of the current collector and a lower surface of the cover.
  • a current collector on a negative electrode side of, for example, a lithium ion battery need be securely insulated from a battery case and a cover (i.e., a package) via a gasket.
  • a satisfactory consideration is not always made on insulation between a current collector and a package via a gasket in conventional batteries inclusive of the battery disclosed in Japanese Unexamined Patent Application Publication No. 2009-277603.
  • An object of the present invention is to provide a gasket capable of securely insulating a current collector from a package.
  • a battery according to the present invention includes: a current collector having a base which is disposed at an inner surface of a package and is electrically connected to an external terminal and a connector which projects from the base and is electrically connected to an electrode assembly contained inside of the package; and a gasket having a body interposed between the base of the current collector and the package and a rib which is disposed at least at a portion corresponding to a position at the outer peripheral edge of the body where the connector projects from the base of the current collector and has a height more than a thickness of the base of the current collector.
  • the gasket is provided with the rib disposed along the outer peripheral edge of the body interposed between the base of the current collector and the package.
  • the rib has the height greater than the thickness of the base of the current collector. This rib satisfactorily ensures an insulation distance between the current collector and the package, thus securely insulating the current collector from the package.
  • the gasket preferably includes a contained portion which is contained in a recess formed at the inner surface of the package.
  • the contained portion of the gasket interposed between the current collector and the package is contained in the recess formed at the inner surface of the package. Consequently, the projection of the gasket from the inner surface of the package can be suppressed to the minimum.
  • the suppression of the projection of the gasket enables the end of the electrode assembly to be disposed sufficiently in the proximity of the inner surface of the package. Thus, energy density can be enhanced by increasing the occupancy of the electrode assembly with respect to the volume of the battery case.
  • the wall surface defining the recess of the package is formed into not a flat shape but a recessed shape.
  • the recessed wall surface restricts or restrains the position of the contained portion of the gasket which is contained in the recess.
  • the recess of the package and the contained portion of the gasket are not brought into contact with each other on the plane. Consequently, the gasket can be prevented from being rotated with respect to the package. Therefore, a load can be prevented from exerting on a part of the gasket (e.g., a caulked and joined portion via a rivet) which may be caused by such rotation of the gasket.
  • the current collector preferably includes a base which is electrically connected to the external terminal and a connector which projects from the base and is electrically connected to the electrode assembly; and the contained portion of the gasket should preferably include a caulked portion which is caulked and joined to the package together with the base, the thickness of the caulked portion being greater than those of other portions of the gasket.
  • the weight of the gasket and a material required for fabricating the gasket can be reduced while enhancing air-tightness of the gasket.
  • a clearance is preferably defined between the surroundings of the contained portion of the gasket and the wall surface of the recess of the package.
  • a clearance for deformation (relief) in a planar direction with respect to compression in a thickness direction of a caulked portion can be secured at the time of caulking and joining, so that a damage such as a crack of the gasket can be securely prevented at the time of caulking and joining.
  • FIG. 1 is a vertical cross-sectional view of a battery in an preferred embodiment according to the present invention
  • FIG. 2 is a perspective view of a cover
  • FIG. 3 is an enlarged view of a section III of FIG. 1 ;
  • FIG. 4 is an enlarged view of a section IV of FIG. 1 ;
  • FIG. 5 is a perspective view of the surroundings of a lower gasket on the side of a lower surface of the cover;
  • FIG. 6 is a partly cross-sectional perspective view of the surroundings of the lower gasket on the side of the lower surface of the cover;
  • FIG. 7 is a cross-sectional view taken along a line VII-VII of FIG. 2 ;
  • FIG. 8 is a cross-sectional view taken along a line VIII-VIII of FIG. 2 ;
  • FIG. 9 is an exploded perspective view of the lower gasket and a negative current collector, as viewed from the bottom.
  • FIG. 10 is an exploded perspective view of the lower gasket and the negative current collector, as viewed from the top.
  • FIG. 1 shows a nonaqueous electrolytic secondary battery 1 (hereinafter simply referred to as a battery) in an embodiment according to the present invention.
  • An electrode assembly 3 of the battery 1 is housed in a battery case 2 which is made of aluminum or an aluminum alloy and is formed into a rectangular parallelepiped shape.
  • An upper opening of the battery case 2 is sealed by a cover 4 .
  • the battery case 2 and the cover 4 constitute a package.
  • the upper surfaces of a negative external terminal 14 and a positive external terminal 15 are exposed to the outside of the cover 4 .
  • the electrode assembly 3 includes a negative electrode formed of a copper foil, a positive electrode formed of an aluminum foil, and a separator 7 made of a porous resin film and interposed in a wound manner between the negative electrode and the positive electrode.
  • the negative electrode is electrically connected to the negative external terminal 14 via a negative current collector 12 whereas the positive electrode is electrically connected to the positive external terminal 15 via a positive current collector 13 .
  • the cover 4 is made of an elongated metallic plate formed into a rectangular shape, as viewed on plane.
  • the cover 4 includes a safe valve 8 near the center thereof in a longitudinal direction and a liquid injection hole 9 formed at one end thereof.
  • the engagement receiving portion 11 has an engagement recess 11 a formed by depressing a lower surface 4 a of the cover 4 .
  • a through hole 11 b is formed at the center of a ceiling constituting the engagement recess 11 a.
  • the negative external terminal 14 and the negative current collector 12 are fitted to the engagement receiving portion 11 on the left via an upper gasket 16 and a negative lower gasket 17 which are made of an insulating resin, respectively.
  • the upper gasket 16 is a resin part having a terminal holding recess 16 b on the upper side and a mounting recess 16 c on the lower side which are partitioned by a partition wall 16 a .
  • a cylindrical portion 16 d extending downward and having openings at both ends thereof is formed at the center of the partition wall 16 a .
  • the upper gasket 16 is put on the engagement receiving portion 11 from above, and then, attached to the cover 4 by containing the engagement receiving portion 11 in the mounting recess 16 c .
  • the cylindrical portion 16 d is inserted into the through hole 11 b to intrude into the engagement recess 11 a .
  • engagement projections 19 projecting from the upper surface 4 b of the cover 4 are inserted into engagement holes 16 f formed at two tongue pieces 16 e provided in the upper gasket 16 .
  • the negative lower gasket 17 includes an expanded portion 17 a which is to be contained inside of the engagement recess 11 a of the cover 4 , and a flat portion 17 b which is disposed in a region adjacent to the engagement recess 11 a at the lower surface 4 a of the cover 4 and is formed into a substantially rectangular shape.
  • the expanded portion 17 a of the negative lower gasket 17 includes a caulked portion 17 c which is disposed with a step in a height direction with respect to the flat portion 17 b and extends in parallel to the flat portion 17 b.
  • the caulked portion 17 c in the negative lower gasket 17 is disposed on one short side of the flat portion 17 b , and further, is connected via three vertical walls 17 d , 17 e , and 17 f to the flat portion 17 b .
  • a through hole 17 g penetrating in a thickness direction is formed in the caulked portion 17 c .
  • the cylindrical portion 16 d of the upper gasket 16 is inserted into the through hole 17 g around the lower end thereof.
  • a rib 17 h projecting downward is disposed at the outer peripheral edge of the flat portion 17 b of the negative lower gasket 17 except a part of one short side (a short side forward in FIG. 9 ).
  • the negative external terminal 14 includes an aluminum plate-like member 21 having a rectangular shape, as viewed on plane, and a copper rivet 22 .
  • a flange 22 a is press-fitted into a through hole 21 a formed at the center of the plate-like member 21 so that the rivet 22 is fixed to the plate-like member 21 in the state in which a shaft 22 b projects.
  • the plate-like member 21 is contained in the terminal holding recess 16 b of the upper gasket 16 .
  • the copper negative current collector 12 includes a base 12 a and a pair of legs (connectors) 12 b and 12 b .
  • the base 12 a includes a fixed portion 12 c , which is contained inside of the engagement recess 11 a formed at the lower surface 4 a of the cover 4 and is fitted to the lower side of the caulked portion 17 c in the expanded portion 17 a of the negative lower gasket 17 , and a mount 12 d to be fitted onto the lower side of the flat portion 17 b of the negative lower gasket 17 at a position adjacent to the engagement recess 11 a .
  • a through hole 12 e penetrating in a thickness direction is formed in the fixed portion 12 c .
  • the fixed portion 12 c and the mount 12 d which are stepwise different in the height direction, are connected via a vertical wall 12 f .
  • the legs 12 b and 12 b extend downward from the mount 12 d .
  • the legs 12 b and 12 b are electrically connected to and mechanically coupled to the negative electrode in the electrode assembly 3 via a clip 10 schematically shown only in FIG. 1 .
  • the shaft 22 b of the rivet 22 in the negative external terminal 14 is inserted into the cylindrical portion 16 d of the upper gasket 16 , the through hole 17 g formed in the caulked portion 17 c of the negative lower gasket 17 , and the through hole 12 e formed in the fixed portion 12 c of the negative current collector 12 , and then, the tip is widened under pressure, thereby forming a large-diameter portion 22 c . Consequently, the negative external terminal 14 , the upper casket 16 , the caulked portion 17 c of the negative lower gasket 17 , and the base 12 a of the negative current collector 12 are securely caulked and joined to the cover 4 . Moreover, owing to the caulking and joining, the negative current collector 12 is electrically connected to the negative external terminal 14 .
  • the positive external terminal 15 and the positive current collector 13 are fixed to the engagement receiving portion 11 on the right side via the upper gasket 16 and a positive lower gasket 18 which are made of an insulating resin, respectively.
  • the upper gasket 16 is attached to the engagement receiving portion 11 .
  • the positive lower gasket 18 is formed into a plate having a through hole 18 a , and is disposed inside of the engagement recess 11 a.
  • the aluminum positive external terminal 15 includes a plate-like member 15 a formed into a rectangular shape, as viewed on plane, and a cylindrical shaft 15 b projecting from the center of the lower surface of the member 15 a .
  • the plate-like member 15 a is contained in a terminal holding recess 16 b of the upper gasket 16 .
  • the aluminum positive current collector 13 includes a base 13 a and a pair of legs (connectors) 13 b and 13 b .
  • the base 13 a includes a fixed portion 13 c , which is contained inside of the engagement recess 11 a and is fitted to the lower side of the positive lower gasket 18 , and a mount 13 d to be fitted to the lower surface 4 a of the cover 4 at a position adjacent to the engagement recess 11 a .
  • a through hole 13 e penetrating in a thickness direction is formed in the fixed portion 13 c .
  • the fixed portion 13 c and the mount 13 d which are stepwise disposed are connected via a vertical wall 13 f .
  • the legs 12 b and 12 b are electrically connected to and mechanically coupled to the electrode assembly 3 via a clip 10 schematically shown only in FIG. 1 .
  • the shaft 15 b of the positive external terminal 15 is inserted into the cylindrical portion 16 d of the upper gasket 16 , the through hole 18 a formed in the positive lower gasket 18 , and the through hole 13 e formed in the fixed portion 13 c in the positive current collector 13 , and then, the tip is widened under pressure, thereby forming a large-diameter portion 15 c . Consequently, the positive external terminal 15 , the upper gasket 16 , the positive lower gasket 18 , and the base 13 a of the positive current collector 13 are securely caulked and joined to the cover 4 . Moreover, owing to the caulking and joining, the positive current collector 13 is electrically connected to the positive external terminal 15 .
  • the battery 1 in the present embodiment is particularly featured by the following points.
  • the rib 17 h is disposed at the outer peripheral edge of the flat portion 17 b in the negative lower gasket 17 interposed between the lower surface 4 a of the cover 4 and the negative current collector 12 .
  • the height H of the rib 17 h (see FIGS. 5 and 9 ) is more than the thickness of the base 12 a of the negative current collector 12 c .
  • the rib 17 h sufficiently ensures an insulation distance defined between the negative current collector 12 c and the cover 4 , thus securely insulating the negative current collector 12 c from the cover 4 .
  • the rib 17 h having the thickness more than that of the base 12 a is disposed at a portion corresponding to a position at which the legs 12 b an 12 b project from the mount 12 d at a portion at which the electrode assembly 3 is electrically connected to the negative current collector 12 , and therefore, the negative lower gasket 17 can effectively insulate the negative current collector 12 c from the package (especially, the cover 4 ).
  • the position, in particular, at which the legs 12 b and 12 b project from the mount 12 d need be securely insulated from the package (especially, the cover 4 ).
  • the negative lower gasket 17 can effectively insulate the negative current collector 12 c from the cover 4 . According to the construction above, a weight saving of the gasket along with the insulating effect can be obtained.
  • the expanded portion 17 a of the negative lower gasket 17 interposed between the negative current collector 12 and the cover 4 is contained in the engagement recess 11 a formed at the lower surface 4 a of the cover 4 . Consequently, only the flat portion 17 b formed into a thin plate in the negative lower gasket 17 projects from the lower surface 4 a of the cover 4 , thereby suppressing the projection of the negative lower gasket 17 from the lower surface 4 a of the cover 4 to the minimum.
  • the entire positive lower gasket 18 is contained in the engagement recess 11 a formed at the lower surface 4 a of the cover 4 .
  • the wall surface constituting the engagement recess 11 a at the lower surface 4 a of the cover 4 is formed into a recess.
  • the recessed wall surface defines or restrains the position of the expanded portion 17 a of the negative lower gasket 17 contained in the engagement recess 11 a .
  • the engagement recess 11 a formed at the cover 4 and the expanded portion 17 a of the negative lower gasket 17 are brought into contact with each other not on the plane but in mutual engagement. As a consequence, the negative lower gasket 17 can be prevented from being rotated with respect to the cover 4 .
  • the negative external terminal 14 , the upper gasket 16 , the caulked portion 17 c of the negative lower gasket 17 , and the base 2 a of the negative current collector 12 are caulked and joined with respect to the cover 4 via the rivet 22 .
  • the expanded portion 17 a of the negative lower gasket 17 is contained in the engagement recess 11 a , so that the rivet 22 can prevent the rotation of the negative lower gasket 17 with respect to the caulked and joined portions.
  • the rivet 22 is concerned in electrically connecting the negative current collector 12 and the negative external terminal 14 , and therefore, the rotation of the negative lower gasket 17 at the caulked and joined portions via the rivet 22 is undesirable in view of the secureness of the favorable electric connection between the negative current collector 12 and the negative external terminal 14 .
  • the prevention of the rotation of the negative lower gasket 17 with the simple configuration in which the expanded portion 17 a of the negative lower gasket 17 is contained in the engagement recess 11 a of the cover 4 has a great advantage from the viewpoint of the favorable secureness of the electric connection between the negative current collector 12 and the negative external terminal 14 .
  • the thickness T of the caulked portion 17 c that is caulked and connected to the cover 4 in the negative lower gasket 17 is set to be more than those of other portions in the negative lower gasket 17 .
  • the thickness T of the caulked portion 17 c where a large force exerts by caulking is set to be large, so that the negative lower gasket 17 is reduced in weight and a material required for fabricating the negative lower gasket 17 is reduced while air tightness of the negative lower gasket 17 can be enhanced.
  • a clearance 31 is defined by the wall surface (i.e., the engagement receiving portion 11 ) surrounding the engagement recess 11 a at the lower surface 4 a of the cover 4 near a corner defined by the caulked portion 17 c and the vertical wall 17 d in the negative lower gasket 17 .
  • a clearance having a dimension indicated by reference numeral S 1 is defined between side wall surfaces surrounding the vertical wall 17 d of the negative lower gasket 17 and the engagement recess 11 a .
  • a clearance having a greater dimension indicated by reference numeral S 2 is defined between the tip of the caulked portion 17 c of the negative lower gasket 17 and the side wall surface surrounding the engagement recess 11 a at the lower surface 4 a of the cover 4 .
  • the clearances 31 , S 1 , and S 2 are defined between both ends of the caulked portion 17 c of the negative lower gasket 17 and the wall surface (i.e., the engagement recess 11 ) surrounding the engagement recess 11 a , and therefore, room can be secured such that the caulked portion 17 is deformed (relieved) in a planar direction when the caulked portion 17 is compressed in a thickness direction during caulking and joining. Consequently, it is possible to securely prevent a damage such as a crack on the negative lower gasket 17 during caulking and joining.
  • the present invention is not limited to the embodiment, various modifications can be implemented.
  • a part of a gasket i.e., a contained portion

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Connection Of Batteries Or Terminals (AREA)

Abstract

A negative lower gasket has a rib disposed along the outer periphery of a flat portion having a base of a negative current collector disposed thereat. The height of the rib is set to be more than a thickness of the negative lower gasket. The rib may be disposed only at a portion corresponding to a position where legs project from the base of the negative current collector at the outer periphery of the flat portion.

Description

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a battery including a nonaqueous electrolytic secondary battery.
2. Description of the Related Art
A battery such as a nonaqueous electrolytic secondary battery includes a positive current collector and a negative current collector for electrically connecting a positive electrode and a negative electrode in an electrode assembly contained inside of a battery case to a positive external terminal and a negative external terminal, respectively. A base of the current collector is fixed to a cover for sealing an upper opening of the battery case by means such as caulking using, for example, a rivet. A gasket is interposed between the base of the current collector and a lower surface of the cover. (See Japanese Unexamined Patent Application Publication No. 2009-277603 (FIG. 2).)
A current collector on a negative electrode side of, for example, a lithium ion battery need be securely insulated from a battery case and a cover (i.e., a package) via a gasket. However, a satisfactory consideration is not always made on insulation between a current collector and a package via a gasket in conventional batteries inclusive of the battery disclosed in Japanese Unexamined Patent Application Publication No. 2009-277603.
SUMMARY OF THE INVENTION
An object of the present invention is to provide a gasket capable of securely insulating a current collector from a package.
A battery according to the present invention includes: a current collector having a base which is disposed at an inner surface of a package and is electrically connected to an external terminal and a connector which projects from the base and is electrically connected to an electrode assembly contained inside of the package; and a gasket having a body interposed between the base of the current collector and the package and a rib which is disposed at least at a portion corresponding to a position at the outer peripheral edge of the body where the connector projects from the base of the current collector and has a height more than a thickness of the base of the current collector.
The gasket is provided with the rib disposed along the outer peripheral edge of the body interposed between the base of the current collector and the package. The rib has the height greater than the thickness of the base of the current collector. This rib satisfactorily ensures an insulation distance between the current collector and the package, thus securely insulating the current collector from the package.
The gasket preferably includes a contained portion which is contained in a recess formed at the inner surface of the package.
The contained portion of the gasket interposed between the current collector and the package is contained in the recess formed at the inner surface of the package. Consequently, the projection of the gasket from the inner surface of the package can be suppressed to the minimum. The suppression of the projection of the gasket enables the end of the electrode assembly to be disposed sufficiently in the proximity of the inner surface of the package. Thus, energy density can be enhanced by increasing the occupancy of the electrode assembly with respect to the volume of the battery case.
Moreover, the wall surface defining the recess of the package is formed into not a flat shape but a recessed shape. The recessed wall surface restricts or restrains the position of the contained portion of the gasket which is contained in the recess. In other words, the recess of the package and the contained portion of the gasket are not brought into contact with each other on the plane. Consequently, the gasket can be prevented from being rotated with respect to the package. Therefore, a load can be prevented from exerting on a part of the gasket (e.g., a caulked and joined portion via a rivet) which may be caused by such rotation of the gasket.
The current collector preferably includes a base which is electrically connected to the external terminal and a connector which projects from the base and is electrically connected to the electrode assembly; and the contained portion of the gasket should preferably include a caulked portion which is caulked and joined to the package together with the base, the thickness of the caulked portion being greater than those of other portions of the gasket.
With the configuration, the weight of the gasket and a material required for fabricating the gasket can be reduced while enhancing air-tightness of the gasket.
A clearance is preferably defined between the surroundings of the contained portion of the gasket and the wall surface of the recess of the package.
With the configuration, a clearance for deformation (relief) in a planar direction with respect to compression in a thickness direction of a caulked portion can be secured at the time of caulking and joining, so that a damage such as a crack of the gasket can be securely prevented at the time of caulking and joining.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a vertical cross-sectional view of a battery in an preferred embodiment according to the present invention;
FIG. 2 is a perspective view of a cover;
FIG. 3 is an enlarged view of a section III of FIG. 1;
FIG. 4 is an enlarged view of a section IV of FIG. 1;
FIG. 5 is a perspective view of the surroundings of a lower gasket on the side of a lower surface of the cover;
FIG. 6 is a partly cross-sectional perspective view of the surroundings of the lower gasket on the side of the lower surface of the cover;
FIG. 7 is a cross-sectional view taken along a line VII-VII of FIG. 2;
FIG. 8 is a cross-sectional view taken along a line VIII-VIII of FIG. 2;
FIG. 9 is an exploded perspective view of the lower gasket and a negative current collector, as viewed from the bottom; and
FIG. 10 is an exploded perspective view of the lower gasket and the negative current collector, as viewed from the top.
 DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
A detailed description will be given below of an embodiment according to the present invention with reference to the attached drawings.
FIG. 1 shows a nonaqueous electrolytic secondary battery 1 (hereinafter simply referred to as a battery) in an embodiment according to the present invention. An electrode assembly 3 of the battery 1 is housed in a battery case 2 which is made of aluminum or an aluminum alloy and is formed into a rectangular parallelepiped shape. An upper opening of the battery case 2 is sealed by a cover 4. The battery case 2 and the cover 4 constitute a package. The upper surfaces of a negative external terminal 14 and a positive external terminal 15 are exposed to the outside of the cover 4.
The electrode assembly 3 includes a negative electrode formed of a copper foil, a positive electrode formed of an aluminum foil, and a separator 7 made of a porous resin film and interposed in a wound manner between the negative electrode and the positive electrode. In the electrode assembly 3, the negative electrode is electrically connected to the negative external terminal 14 via a negative current collector 12 whereas the positive electrode is electrically connected to the positive external terminal 15 via a positive current collector 13.
As shown in FIG. 2, the cover 4 is made of an elongated metallic plate formed into a rectangular shape, as viewed on plane. The cover 4 includes a safe valve 8 near the center thereof in a longitudinal direction and a liquid injection hole 9 formed at one end thereof.
An engagement receiving portion 11 formed into a substantially rectangular shape, as viewed on plane, is formed at both ends of the cover 4 so as to expand upward from an upper surface 4 b. The engagement receiving portion 11 has an engagement recess 11 a formed by depressing a lower surface 4 a of the cover 4. Moreover, a through hole 11 b is formed at the center of a ceiling constituting the engagement recess 11 a.
As shown in FIGS. 3 and 5 to 8, the negative external terminal 14 and the negative current collector 12 are fitted to the engagement receiving portion 11 on the left via an upper gasket 16 and a negative lower gasket 17 which are made of an insulating resin, respectively.
Referring to FIGS. 2 to 4, 6, and 7, explanation will be made on the upper gasket 16. The upper gasket 16 is a resin part having a terminal holding recess 16 b on the upper side and a mounting recess 16 c on the lower side which are partitioned by a partition wall 16 a. A cylindrical portion 16 d extending downward and having openings at both ends thereof is formed at the center of the partition wall 16 a. The upper gasket 16 is put on the engagement receiving portion 11 from above, and then, attached to the cover 4 by containing the engagement receiving portion 11 in the mounting recess 16 c. The cylindrical portion 16 d is inserted into the through hole 11 b to intrude into the engagement recess 11 a. Moreover, engagement projections 19 projecting from the upper surface 4 b of the cover 4 are inserted into engagement holes 16 f formed at two tongue pieces 16 e provided in the upper gasket 16.
Referring to FIGS. 3 and 5 to 10, explanation will be made on the negative lower gasket 17. The negative lower gasket 17 includes an expanded portion 17 a which is to be contained inside of the engagement recess 11 a of the cover 4, and a flat portion 17 b which is disposed in a region adjacent to the engagement recess 11 a at the lower surface 4 a of the cover 4 and is formed into a substantially rectangular shape.
As most clearly shown in FIGS. 9 and 10, the expanded portion 17 a of the negative lower gasket 17 includes a caulked portion 17 c which is disposed with a step in a height direction with respect to the flat portion 17 b and extends in parallel to the flat portion 17 b.
The caulked portion 17 c in the negative lower gasket 17 is disposed on one short side of the flat portion 17 b, and further, is connected via three vertical walls 17 d, 17 e, and 17 f to the flat portion 17 b. A through hole 17 g penetrating in a thickness direction is formed in the caulked portion 17 c. As shown in FIGS. 3 and 6, the cylindrical portion 16 d of the upper gasket 16 is inserted into the through hole 17 g around the lower end thereof.
As most clearly shown in FIG. 9, a rib 17 h projecting downward is disposed at the outer peripheral edge of the flat portion 17 b of the negative lower gasket 17 except a part of one short side (a short side forward in FIG. 9).
Referring to FIGS. 3 and 5 to 7, a description will be given of the negative external terminal 14. The negative external terminal 14 includes an aluminum plate-like member 21 having a rectangular shape, as viewed on plane, and a copper rivet 22. A flange 22 a is press-fitted into a through hole 21 a formed at the center of the plate-like member 21 so that the rivet 22 is fixed to the plate-like member 21 in the state in which a shaft 22 b projects. The plate-like member 21 is contained in the terminal holding recess 16 b of the upper gasket 16.
Referring to FIGS. 3 and 5 to 10, explanation will be made on the negative current collector 12. The copper negative current collector 12 includes a base 12 a and a pair of legs (connectors) 12 b and 12 b. The base 12 a includes a fixed portion 12 c, which is contained inside of the engagement recess 11 a formed at the lower surface 4 a of the cover 4 and is fitted to the lower side of the caulked portion 17 c in the expanded portion 17 a of the negative lower gasket 17, and a mount 12 d to be fitted onto the lower side of the flat portion 17 b of the negative lower gasket 17 at a position adjacent to the engagement recess 11 a. A through hole 12 e penetrating in a thickness direction is formed in the fixed portion 12 c. The fixed portion 12 c and the mount 12 d, which are stepwise different in the height direction, are connected via a vertical wall 12 f. The legs 12 b and 12 b extend downward from the mount 12 d. The legs 12 b and 12 b are electrically connected to and mechanically coupled to the negative electrode in the electrode assembly 3 via a clip 10 schematically shown only in FIG. 1.
The shaft 22 b of the rivet 22 in the negative external terminal 14 is inserted into the cylindrical portion 16 d of the upper gasket 16, the through hole 17 g formed in the caulked portion 17 c of the negative lower gasket 17, and the through hole 12 e formed in the fixed portion 12 c of the negative current collector 12, and then, the tip is widened under pressure, thereby forming a large-diameter portion 22 c. Consequently, the negative external terminal 14, the upper casket 16, the caulked portion 17 c of the negative lower gasket 17, and the base 12 a of the negative current collector 12 are securely caulked and joined to the cover 4. Moreover, owing to the caulking and joining, the negative current collector 12 is electrically connected to the negative external terminal 14.
Referring to FIGS. 1 to 3, the positive external terminal 15 and the positive current collector 13 are fixed to the engagement receiving portion 11 on the right side via the upper gasket 16 and a positive lower gasket 18 which are made of an insulating resin, respectively.
In the same manner as the side of the negative electrode, the upper gasket 16 is attached to the engagement receiving portion 11. Moreover, the positive lower gasket 18 is formed into a plate having a through hole 18 a, and is disposed inside of the engagement recess 11 a.
The aluminum positive external terminal 15 includes a plate-like member 15 a formed into a rectangular shape, as viewed on plane, and a cylindrical shaft 15 b projecting from the center of the lower surface of the member 15 a. The plate-like member 15 a is contained in a terminal holding recess 16 b of the upper gasket 16.
The aluminum positive current collector 13 includes a base 13 a and a pair of legs (connectors) 13 b and 13 b. The base 13 a includes a fixed portion 13 c, which is contained inside of the engagement recess 11 a and is fitted to the lower side of the positive lower gasket 18, and a mount 13 d to be fitted to the lower surface 4 a of the cover 4 at a position adjacent to the engagement recess 11 a. A through hole 13 e penetrating in a thickness direction is formed in the fixed portion 13 c. The fixed portion 13 c and the mount 13 d which are stepwise disposed are connected via a vertical wall 13 f. The legs 12 b and 12 b are electrically connected to and mechanically coupled to the electrode assembly 3 via a clip 10 schematically shown only in FIG. 1.
The shaft 15 b of the positive external terminal 15 is inserted into the cylindrical portion 16 d of the upper gasket 16, the through hole 18 a formed in the positive lower gasket 18, and the through hole 13 e formed in the fixed portion 13 c in the positive current collector 13, and then, the tip is widened under pressure, thereby forming a large-diameter portion 15 c. Consequently, the positive external terminal 15, the upper gasket 16, the positive lower gasket 18, and the base 13 a of the positive current collector 13 are securely caulked and joined to the cover 4. Moreover, owing to the caulking and joining, the positive current collector 13 is electrically connected to the positive external terminal 15.
The battery 1 in the present embodiment is particularly featured by the following points.
First, referring to FIGS. 3 and 5 to 9, the rib 17 h is disposed at the outer peripheral edge of the flat portion 17 b in the negative lower gasket 17 interposed between the lower surface 4 a of the cover 4 and the negative current collector 12. The height H of the rib 17 h (see FIGS. 5 and 9) is more than the thickness of the base 12 a of the negative current collector 12 c. The rib 17 h sufficiently ensures an insulation distance defined between the negative current collector 12 c and the cover 4, thus securely insulating the negative current collector 12 c from the cover 4.
In particular, at the flat portion 17 b of the negative lower gasket 17, the rib 17 h having the thickness more than that of the base 12 a (especially, the mount 12 d) is disposed at a portion corresponding to a position at which the legs 12 b an 12 b project from the mount 12 d at a portion at which the electrode assembly 3 is electrically connected to the negative current collector 12, and therefore, the negative lower gasket 17 can effectively insulate the negative current collector 12 c from the package (especially, the cover 4). At the base 12 a of the negative current collector 12, the position, in particular, at which the legs 12 b and 12 b project from the mount 12 d, need be securely insulated from the package (especially, the cover 4). Consequently, even if the rib 17 h is not disposed over substantially the entire outer peripheral edge of the flat portion 17 b of the negative lower gasket 17, unlike the present embodiment, but only at the portion corresponding to the position at which the legs 12 b and 12 b project from the mount 12 d of the negative current collector 12 on the outer periphery of the flat portion 17 b, the negative lower gasket 17 can effectively insulate the negative current collector 12 c from the cover 4. According to the construction above, a weight saving of the gasket along with the insulating effect can be obtained.
Next, the expanded portion 17 a of the negative lower gasket 17 interposed between the negative current collector 12 and the cover 4 is contained in the engagement recess 11 a formed at the lower surface 4 a of the cover 4. Consequently, only the flat portion 17 b formed into a thin plate in the negative lower gasket 17 projects from the lower surface 4 a of the cover 4, thereby suppressing the projection of the negative lower gasket 17 from the lower surface 4 a of the cover 4 to the minimum. In contrast, the entire positive lower gasket 18 is contained in the engagement recess 11 a formed at the lower surface 4 a of the cover 4. In this manner, the projection of each of the negative lower gasket 17 and the entire positive lower gasket 18 from the lower surface 4 a of the cover 4 is suppressed to the minimum, and consequently, the upper end of the electrode assembly 3 can be disposed sufficiently near the lower surface 4 a of the cover 4. Thus, it is possible to increase the occupancy of the electrode assembly 3 with respect to the volume of the battery cell 2, so as to enhance energy density.
Moreover, the wall surface constituting the engagement recess 11 a at the lower surface 4 a of the cover 4 is formed into a recess. The recessed wall surface defines or restrains the position of the expanded portion 17 a of the negative lower gasket 17 contained in the engagement recess 11 a. Specifically, the engagement recess 11 a formed at the cover 4 and the expanded portion 17 a of the negative lower gasket 17 are brought into contact with each other not on the plane but in mutual engagement. As a consequence, the negative lower gasket 17 can be prevented from being rotated with respect to the cover 4. In the present embodiment, the negative external terminal 14, the upper gasket 16, the caulked portion 17 c of the negative lower gasket 17, and the base 2 a of the negative current collector 12 are caulked and joined with respect to the cover 4 via the rivet 22. The expanded portion 17 a of the negative lower gasket 17 is contained in the engagement recess 11 a, so that the rivet 22 can prevent the rotation of the negative lower gasket 17 with respect to the caulked and joined portions. As described above, the rivet 22 is concerned in electrically connecting the negative current collector 12 and the negative external terminal 14, and therefore, the rotation of the negative lower gasket 17 at the caulked and joined portions via the rivet 22 is undesirable in view of the secureness of the favorable electric connection between the negative current collector 12 and the negative external terminal 14. The prevention of the rotation of the negative lower gasket 17 with the simple configuration in which the expanded portion 17 a of the negative lower gasket 17 is contained in the engagement recess 11 a of the cover 4 has a great advantage from the viewpoint of the favorable secureness of the electric connection between the negative current collector 12 and the negative external terminal 14.
In addition, as shown in FIGS. 3, 6, and 7, the thickness T of the caulked portion 17 c that is caulked and connected to the cover 4 in the negative lower gasket 17 is set to be more than those of other portions in the negative lower gasket 17. In this manner, only the thickness T of the caulked portion 17 c where a large force exerts by caulking is set to be large, so that the negative lower gasket 17 is reduced in weight and a material required for fabricating the negative lower gasket 17 is reduced while air tightness of the negative lower gasket 17 can be enhanced.
Additionally, referring to FIGS. 3 and 6, a clearance 31 is defined by the wall surface (i.e., the engagement receiving portion 11) surrounding the engagement recess 11 a at the lower surface 4 a of the cover 4 near a corner defined by the caulked portion 17 c and the vertical wall 17 d in the negative lower gasket 17. In particular, a clearance having a dimension indicated by reference numeral S1 is defined between side wall surfaces surrounding the vertical wall 17 d of the negative lower gasket 17 and the engagement recess 11 a. Moreover, a clearance having a greater dimension indicated by reference numeral S2 is defined between the tip of the caulked portion 17 c of the negative lower gasket 17 and the side wall surface surrounding the engagement recess 11 a at the lower surface 4 a of the cover 4. In this manner, the clearances 31, S1, and S2 are defined between both ends of the caulked portion 17 c of the negative lower gasket 17 and the wall surface (i.e., the engagement recess 11) surrounding the engagement recess 11 a, and therefore, room can be secured such that the caulked portion 17 is deformed (relieved) in a planar direction when the caulked portion 17 is compressed in a thickness direction during caulking and joining. Consequently, it is possible to securely prevent a damage such as a crack on the negative lower gasket 17 during caulking and joining.
The present invention is not limited to the embodiment, various modifications can be implemented. For example, although the present invention has been described by way of the configuration in which the expanded portion 17 a of the negative lower gasket 17 is contained in the engagement recess 11 a of the cover 4, a part of a gasket (i.e., a contained portion) may be contained in a recess formed at not the cover but the inner surface of a battery case.

Claims (20)

What is claimed is:
1. A battery, comprising:
a current collector including a base which is disposed at an inner surface of a package and is electrically connected to an external terminal and a connector which projects from the base and is electrically connected to an electrode assembly contained inside of the package; and
a gasket including:
a body interposed between the base of the current collector and the package; and
a rib which is disposed at least at a portion corresponding to a position at an outer peripheral edge of the body where the connector projects from the base of the current collector, the rib having a height more than a thickness of the base of the current collector.
2. The battery according to claim 1, wherein the rib is disposed at the portion corresponding to the position at the outer peripheral edge of the body where the connector projects from the base of the current collector.
3. The battery according to claim 1, wherein the body of the gasket comprises a flat portion of substantially a rectangular plate shape, and the rib is disposed at an outer peripheral edge of the flat portion.
4. The battery according to claim 1, wherein the gasket includes a contained portion which is contained in a recess formed at the inner surface of the package.
5. The battery according to claim 4, wherein the base of the current collector comprises:
a first portion which is disposed in the recess; and
a second portion which is disposed at the inner surface of the package adjacent to the recess and in which the connector is provided, and
wherein the height of the rib is more than a thickness of the second portion.
6. The battery according to claim 4, wherein the contained portion of the gasket includes a caulked portion which is caulked and joined to the package together with the base of the current collector, a thickness of the caulked portion being greater than a thickness of other portions of the gasket.
7. The battery according to claim 4, wherein a clearance is defined between surroundings of the contained portion of the gasket and a wall surface of the recess of the package.
8. The battery according to claim 1, wherein the rib is an integral part of the gasket.
9. The battery according to claim 1, wherein the rib projects from the body of the gasket in substantially a same direction that the connector projects from the base of the current collector.
10. The battery according to claim 9, wherein the rib projects downward from the body of the gasket.
11. The battery according to claim 9, wherein the package comprises a battery case and a cover,
wherein the body of the gasket is disposed between the base of the current collector and an inner surface of the cover.
12. The battery according to claim 1, wherein the body of the gasket comprises a flat portion, the rib projects downward from the body of the gasket, and the rib is disposed at an outer peripheral edge of the flat portion.
13. The battery according to claim 12, wherein the base of the current collector comprises:
a fixed portion contained inside of a recess formed at a lower surface of the cover and fitted to a lower side of a calked portion of the gasket.
14. The battery according to claim 13, wherein the base of the current collector further comprises:
a mount fitted onto a lower side of the flat portion of the gasket at a position adjacent to the recess.
15. A battery, comprising:
a current collector including a base which is disposed at an inner surface of a package comprising a cover and is electrically connected to an external terminal and a connector which projects from the base and is electrically connected to an electrode assembly contained inside of the package; and
a gasket comprising:
a body interposed between the base of the current collector and the package; and
a rib which is disposed at least at a portion corresponding to a position at an outer peripheral edge of the body where the connector projects from the base of the current collector,
wherein the body of the gasket is disposed between the base of the current collector and an inner surface of the cover.
16. The battery according to claim 15, wherein the rib is an integral part of the gasket.
17. The battery according to claim 15, wherein the rib projects from the body of the gasket in substantially a same direction that the connector projects from the base of the current collector.
18. The battery according to claim 15, wherein the rib projects downward from the body of the gasket.
19. The battery according to claim 15, wherein the body of the gasket comprises a flat portion, the rib projects downward from the body of the gasket, and the rib is disposed at an outer peripheral edge of the flat portion, and
wherein the base of the current collector comprises:
a fixed portion contained inside of a recess fowled at a lower surface of the cover and fitted to a lower side of a calked portion of the gasket; and
a mount fitted onto a lower side of the flat portion of the gasket at a position adjacent to the recess.
20. The battery according to claim 1, wherein the connector projects from the base in a direction away from the external terminal and towards the electrode assembly,
wherein the connector is in a physical contact with the electrode assembly, and
wherein the connector comprises a plurality of connectors.
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JP5742260B2 (en) 2015-07-01
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KR20160110929A (en) 2016-09-23
CN102623711B (en) 2016-03-02
EP2482360B1 (en) 2017-07-12
US20120196179A1 (en) 2012-08-02
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DE202012013287U1 (en) 2015-12-16
CN105702886A (en) 2016-06-22

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