US8786390B2 - Power transformer with amorphous core - Google Patents
Power transformer with amorphous core Download PDFInfo
- Publication number
- US8786390B2 US8786390B2 US13/248,645 US201113248645A US8786390B2 US 8786390 B2 US8786390 B2 US 8786390B2 US 201113248645 A US201113248645 A US 201113248645A US 8786390 B2 US8786390 B2 US 8786390B2
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- Prior art keywords
- winding
- core
- transformer
- strip
- holding apparatus
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- 238000004804 winding Methods 0.000 claims abstract description 114
- 239000000463 material Substances 0.000 claims abstract description 36
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 239000003302 ferromagnetic material Substances 0.000 claims description 4
- 239000011810 insulating material Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- 239000011162 core material Substances 0.000 description 73
- 239000004020 conductor Substances 0.000 description 6
- 239000011152 fibreglass Substances 0.000 description 6
- 102100040287 GTP cyclohydrolase 1 feedback regulatory protein Human genes 0.000 description 5
- 101710185324 GTP cyclohydrolase 1 feedback regulatory protein Proteins 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 4
- 230000005291 magnetic effect Effects 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000010292 electrical insulation Methods 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 239000012811 non-conductive material Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009429 electrical wiring Methods 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F27/00—Details of transformers or inductances, in general
- H01F27/06—Mounting, supporting or suspending transformers, reactors or choke coils not being of the signal type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F41/00—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
- H01F41/02—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
- H01F41/0206—Manufacturing of magnetic cores by mechanical means
- H01F41/0213—Manufacturing of magnetic circuits made from strip(s) or ribbon(s)
- H01F41/0226—Manufacturing of magnetic circuits made from strip(s) or ribbon(s) from amorphous ribbons
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F27/00—Details of transformers or inductances, in general
- H01F27/28—Coils; Windings; Conductive connections
- H01F27/30—Fastening or clamping coils, windings, or parts thereof together; Fastening or mounting coils or windings on core, casing, or other support
- H01F27/306—Fastening or mounting coils or windings on core, casing or other support
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F30/00—Fixed transformers not covered by group H01F19/00
- H01F30/06—Fixed transformers not covered by group H01F19/00 characterised by the structure
- H01F30/12—Two-phase, three-phase or polyphase transformers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/4902—Electromagnet, transformer or inductor
- Y10T29/49073—Electromagnet, transformer or inductor by assembling coil and core
Definitions
- the disclosure relates to a power transformer of dry design having, for example, a core which can be in the form of a winding strip core and composed of amorphous material, which is sensitive to mechanical loads, having at least one winding former which can surround the core and is in each case formed from at least one primary winding and secondary winding, and having at least one holding apparatus.
- Transformers are used for power transmission for power supply purposes, by adapting the voltage from a first voltage level to a second.
- Power transformers of dry design so-called dry transformers, are being increasingly used instead of power transformers with an oil filling, as were previously widely used.
- the configuration of a power transformer of dry design is very similar to that of a power transformer with an oil filling to the extent that the respective winding formers are also fitted to cores composed of ferromagnetic material in a power transformer of dry design, which cores are each connected to yokes at both ends, and form a magnetic circuit.
- Resistive losses occur in the windings of a loaded transformer because of the winding currents and eddy currents in the conductor material. These resistive losses have no-load losses superimposed on them, and possibly short-circuit losses as well as hysteresis losses.
- the no-load losses are governed primarily by the induction and the nature of the core and are approximately independent of the operating temperature of the transformer.
- the short-circuit losses are temperature-dependent and rise with the temperature and the specific resistivity of the conductor material, if the load is constant. Core materials having a very low hysteresis loop can therefore be used in order to keep the hysteresis losses as low as possible.
- amorphous core material has recently been used, rather than grain-oriented core material.
- amorphous materials can involve new designs and processing forms since the amorphous material is highly pressure-sensitive, as a result of which this can result in an increase in the core losses.
- a transformer is disclosed of dry design having a core including an amorphous material that is sensitive to mechanical loads, comprising: at least one winding former which surrounds the core and is in each case formed from at least one primary winding and secondary winding; and at least one holding apparatus, wherein the holding apparatus is used to fix the at least one primary winding and secondary winding in the each case, and the holding apparatus acts on each end face of the at least one winding former.
- a method for production of a transformer having a winding strip core including an amorphous material that is sensitive to mechanical loads, at least one winding former which surrounds the core and is in each case formed from at least one primary winding and secondary winding, and at least one holding apparatus, the method comprising: producing a strip material from amorphous material; winding an annular core with the same cross section in each case from the amorphous strip material; placing two rectangular individual cores with their longitudinal limbs against one another; winding the strip material around the individual cores in a winding plane of the individual cores, such that the winding plane has three longitudinal limbs with a same cross section; providing outer limbs of the transformer core with at least one of the electrical lower-layer winding or the electrical upper-layer winding; and connecting the electrical windings.
- FIG. 1 shows a side view of an exemplary transformer with complete electrical wiring
- FIG. 2 shows an exemplary section view along the section line A-A in FIG. 1 ;
- FIG. 3 shows a side view of an exemplary supporting arrangement for fixing a winding former
- FIG. 4 shows a side view of an exemplary core support.
- a power transformer is disclosed whose physical design can be chosen so as to more completely exploit advantages of the amorphous core material without the pressure load in consequence increasing the core losses.
- a core composed of amorphous material can be held suspended by a holding apparatus, wherein the holding apparatus is used to fix an at least one primary winding and secondary winding in each case and for this purpose it acts on each of the end faces of the at least one winding former.
- the amorphous core can be produced as a winding strip core composed of strip material of amorphous material.
- the laminate windings which are prepared for use as cores are preferably held in shape by means of a tear-resistant strip, by looping the tear-resistant strip repeatedly around the laminate stack repeatedly, with the loops at a distance from one another, thus holding the laminate winding together.
- the winding strip cores formed in this way can, for example, have a rectangular outline, that is to say they each enclose a rectangular area. However, refinements with an oval or circular outline are also covered within the disclosure.
- the transformer can be in the form of a polyphase transformer and has three cores which are arranged alongside one another and are each surrounded by a winding or coil former.
- At least two winding strip cores are arranged with their longitudinal limbs alongside one another and, in order to connect them mechanically, strip material composed of amorphous material is wound around them in the winding plane, with all the limbs having the same winding cross section, that is to say they have the same thickness and width.
- the longitudinal limbs of at least two (for example, four), of the winding strip cores mentioned above are placed against one another.
- Strip material composed of amorphous material is then wound around the arrangement formed in this way, with this winding process resulting in a total of five limbs with the same winding cross section.
- a transformer can be characterized in that the holding apparatus is formed from at least two clamping elements, which are operatively connected to one another and are arranged on each of the end faces of a winding former.
- the holding structure is designed such that mechanical stresses which occur during the fixing of the winding formers are introduced exclusively into the holding structure and into the winding formers, as a result of which the cores which can be surrounded by the winding formers can be guided in the holding structure but they might not be braced, that is to say they might not be subject to mechanical stresses.
- each core is formed in a cylindrical shape from amorphous material with a layer structure, with at least two limbs and a yoke integrally formed at one end.
- the clamping elements of the holding structure can, for example, be composed of ferromagnetic material, and may at the same time be used as a yoke.
- each core it has been found to be advantageous in exemplary embodiments for each core to be magnetically conductively connected to the clamping elements of the holding apparatus.
- each core is surrounded at each end on two opposite sides by the clamping elements and without pressure, with the clamping elements being held exactly at a distance from the respective core by means of spacers which are firmly connected to the clamping elements, in order to avoid a pressure load on the core as a result of the core being clamped in and the mechanical load resulting from this.
- One end of the respective core is in this case inserted at the intended location into the free space between the clamping elements and is held by means of a supporting plate, which can be likewise firmly connected to the clamping elements, as a result of which, for example in the case of a transformer according to the disclosure in the form of a polyphase transformer, three cores can be arranged in the form of pillars alongside one another on the lower holding apparatus, which is used as the lower yoke, possibly engaging in the intermediate space bounded by the two clamping elements, while avoiding mechanical stresses.
- the holding structure is also possible for the holding structure to be composed of non-ferromagnetic material, in particular of fiber-reinforced plastics.
- the holding structure is not part of the magnetic field circuit, the entire arrangement, however, has considerably lower weight than an entirely-metal version for this purpose.
- the end faces of each core are provided with a coating composed of insulating material.
- This coating is used on the one hand as electrical insulation and on the other hand as means for shock absorption for the relevant core.
- This coating is, for example, composed of an insulating material, such as plastic, in particular glass-fiber-reinforced plastic or silicon rubber.
- supports which connect the yokes to one another that is to say, the lower yoke to the upper yoke
- these supports are passed along the external longitudinal sides of the core or of the cores and are surrounded by the relevant winding former, that is to say the supports are passed through in the interior of the winding former, parallel to the respective core, and are connected to the opposite yoke.
- tie rods can be provided which press the yokes formed from the clamping elements against the winding formers, without any adverse effect on any of the cores.
- the disclosure provides for a pressed coil structure to be used rather than a previously normal pressed core structure in which the coil or winding formers are fixed by pressing against the core.
- the winding formers are held by means of a holding structure, independently of the core.
- the core can be placed or suspended on plates of the holding structure provided for this purpose.
- the object of the present disclosure is also to specify a method for producing this novel transformer, specifically a transformer having a core which is composed of layered strips of amorphous material, which is sensitive to mechanical loads, having at least one winding former which surrounds the core and is in each case formed from at least one primary winding and secondary winding, and having at least one holding apparatus.
- an exemplary method for producing a transformer can be characterized by the features listed below, in for example the stated sequence:
- the short limbs of the winding rings can each form the magnetic yokes.
- Oval or circular cross sections can also be used for the cross section of the individual winding rings, rather than the rectangular shape.
- the transformer core is formed from a total of four windings with longitudinal limbs which are arranged alongside one another and are mechanically connected to one another, thus in this way producing a five-limb core.
- the mechanical connection as already indicated above for the three-limbed core, is for example produced by strip material being wound around the individual cores on the winding plane thereof thus resulting in the individual cores being assembled to form a five-limb core.
- mats composed of silicone rubber to be arranged on the end faces of each core for shock absorption and electrical insulation purposes.
- FIG. 1 shows a side view of an exemplary transformer 10 according to the disclosure with complete electrical external wiring which, as a polyphase transformer, can in each case have one core 11 in three winding formers 12 , whose upper electrical connections 14 , 16 , 18 in the illustrated example are identified by U, V, W, and are conductively connected to one another by means of connecting conductors 20 .
- the three winding formers 12 can be arranged close to one another, alongside one another, in a line and are held between a lower yoke 20 and an upper yoke 22 .
- Each yoke 20 , 22 can be composed of in each case two clamping elements 25 , which can each be in the form of a C-profile, that is to say they are formed from a web part 26 with flanges 28 which are integrally formed at right angles and face the same side on the longitudinal sides thereof.
- the clamping elements 24 are arranged parallel to one another, such that the flanges 28 face outward, while their rear faces, where there are no flanges, face one another.
- the flanges have a different width, to be precise such that those flanges 28 which are located on sides of the winding formers 12 are narrower than those which are on the side facing away from the winding formers 12 and which are approximately twice as wide.
- This configuration has been found to be particularly advantageous for the clamping elements 25 of the lower yoke 22 since the broader flanges 28 ensure a correspondingly larger footprint area, and therefore greater stability.
- Those flanges 28 of the clamping elements 25 which in each case face the winding formers 12 can be used for attachment of the winding formers 12 and therefore for force introduction when the yokes 22 , 24 are braced.
- cross-members 30 are fitted to the lower flange 28 of the lower yoke 20 , and rollers 32 are attached to the outer ends of these cross-members 30 , on which rollers 32 the complete transformer 10 can be moved, as can also be seen from the view in FIG. 2 .
- the winding formers 12 are supported on the lower yoke 20 by lateral supports 34 , which are composed of electrically non-conductive material and are preferably used as glass-fiber-reinforced plates 36 and strips 38 . These lateral supports 34 are connected on the one hand to the upper flange 28 of the lower yoke 20 , and on the other hand to the respective winding formers 12 placed on them.
- lateral supports 34 are arranged in a corresponding manner in order to anchor the winding formers 12 , which lateral supports 34 are formed from plates 36 and strips 38 , both of which are each composed of electrically non-conductive material, with the lateral supports 34 being provided for rigid connection of the winding formers 12 to the lower flange 28 of the upper yoke 22 .
- FIG. 2 which shows a cross section through the transformer 10 as shown in FIG. 1 , along the section line A-A illustrated there, the transformer 10 according to the disclosure is shown looking at a winding former 12 from the side.
- this view differs from the view shown in FIG. 1 in the view of the core 11 of amorphous material, which is held or suspended in the lower yoke 22 and the upper yoke.
- the lower flanges 28 of the clamping elements 25 which form the lower yoke 22 can be provided with a supporting plate 40 , on which the respective core 11 rests.
- tie rods 42 can in each case be provided, which pass through the clamping elements 25 of the lower yoke 22 and of the upper yoke 24 and the core 11 , thus helping to ensure that the core 11 is held in an interlocking manner.
- An insulator which can be used to hold the connecting conductor 20 , can be fitted to an upper flange 28 of a clamping element 25 , in the illustrated example of the right-hand clamping element 25 , of the upper yoke 24 .
- Connecting conductors which can be connected to at least one of the winding formers 12 , are likewise shown on the opposite, left-hand side of the upper yoke 24 in the illustrated example.
- FIG. 3 shows a side view of a supporting arrangement, which can be formed by a lateral support 34 , for fixing a winding former 12 , which can be manufactured to be narrow as a strip 38 or broad as a plate 36 , in each case composed of glass-fiber-reinforced plastic, depending on whether it is arranged on the outside or on the inside, as shown in FIG. 1 .
- FIG. 3 shows a lateral support 34 which is provided on the outside, in order to support a winding former 12 .
- Its design is as follows.
- a threaded rod 46 is inserted at each end of the strip 38 which forms the lateral support 34 , passing through the strip 38 and a plate located underneath this, consisting of the plate 48 , in each case being anchored in a further strip 54 , which is arranged at right angles to the strip 38 and is composed of glass-fiber-reinforced plastic.
- a plate 50 composed of silicone is in each case provided under these strips 38 which run on both sides of the transformer 10 , and a further strip 52 composed of glass-fiber-reinforced plastic is attached to said plate 50 .
- FIG. 4 shows a side view of a suspension for a core 11 composed of amorphous material.
- This suspension includes (e.g., consists of) an upper plate 58 composed of silicone, which can be supported by the supporting plate 42 composed of glass-fiber-reinforced plastic. Tie rods 42 pass through the supporting plate 42 composed of glass-fiber-reinforced plastic, itself, interacting with the clamping elements 25 , which are not illustrated here, of the upper yoke 22 , and being supported thereon.
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Coils Of Transformers For General Uses (AREA)
- Manufacturing Cores, Coils, And Magnets (AREA)
- Insulating Of Coils (AREA)
Abstract
Description
- a) strip material is produced from amorphous material;
- b) an annular core with the same (e.g., rectangular) cross section is in each case produced by winding from the amorphous strip material;
- c) two rectangular individual cores are placed with their longitudinal limbs against one another and the strip material is wound around them in the winding plane of the individual cores, such that it has three longitudinal limbs with the same cross section; (in this instance and in the description that follows, “winding plane” is understood to mean the plane in which the winding of the respective individual core takes place.)
- d) the outer limbs of the transformer core produced in this way are each provided with the electrical lower-layer winding or with the electrical upper-layer winding; and
- e) the electrical windings are then connected.
- 10 Transformer
- 12 Winding former
- 14 Electrical connection U
- 16 Electrical connection V
- 18 Electrical connection W
- 20 Connecting conductor
- 22 Lower yoke
- 24 Upper yoke
- 25 Clamping element
- 26 Web
- 28 Flange
- 30 Cross-member
- 32 Roller
- 34 Lateral support
- 36 Plate composed of GFRP
- 38 Strip composed of GFRP
- 40 Supporting plate
- 42 Tie rod
- 44 Insulator
- 46 Threaded rod
- 48 Plate composed of GFRP
- 50 Plate composed of silicone
- 52 Plate composed of GFRP
- 54 Plate composed of GFRP
- 56 Plate composed of silicone
Claims (9)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09005285.3 | 2009-04-11 | ||
EP09005285.3A EP2239745B1 (en) | 2009-04-11 | 2009-04-11 | Voltage transformer with amorphous coil |
EP09005285 | 2009-04-11 | ||
PCT/EP2010/001796 WO2010115516A1 (en) | 2009-04-11 | 2010-03-23 | Power transformer with amorphous core |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2010/001796 Continuation WO2010115516A1 (en) | 2009-04-11 | 2010-03-23 | Power transformer with amorphous core |
Publications (2)
Publication Number | Publication Date |
---|---|
US20120068800A1 US20120068800A1 (en) | 2012-03-22 |
US8786390B2 true US8786390B2 (en) | 2014-07-22 |
Family
ID=41050945
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/248,645 Active 2030-04-09 US8786390B2 (en) | 2009-04-11 | 2011-09-29 | Power transformer with amorphous core |
Country Status (8)
Country | Link |
---|---|
US (1) | US8786390B2 (en) |
EP (1) | EP2239745B1 (en) |
KR (1) | KR101695345B1 (en) |
CN (1) | CN102388424B (en) |
BR (1) | BRPI1010257B1 (en) |
CA (1) | CA2758282C (en) |
ES (1) | ES2404823T3 (en) |
WO (1) | WO2010115516A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102011081337A1 (en) * | 2011-08-22 | 2013-02-28 | Heinrich Georg Gmbh Maschinenfabrik | Device for transporting multi-layered, thin-layered strip material made of an amorphous material |
KR101706514B1 (en) * | 2016-10-20 | 2017-02-13 | 엘에스산전 주식회사 | Cast resin transformer |
GB2611596B (en) * | 2021-01-15 | 2023-11-01 | Zhongbian Group Shanghai Transf Co Ltd | Dry-type transformer with elliptical iron core |
CN114883107B (en) * | 2022-05-07 | 2024-06-04 | 朗峰新材料启东有限公司 | Winding equipment for manufacturing slowly-variable adsorption self-superposition type electronic components |
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DE2054567A1 (en) | 1970-11-06 | 1972-05-10 | Transformatorenunion Ag | transformer |
DE2934719A1 (en) | 1978-08-31 | 1980-03-13 | Hitachi Ltd | Encapsulated transformer with HV and LV winding - has insulators between HV winding and metal supporting elements, containing potential control capacitors (NL 4.3.80) |
JPS5666022A (en) | 1979-11-02 | 1981-06-04 | Hitachi Ltd | Molded transformer |
JPS58164205A (en) | 1982-03-24 | 1983-09-29 | Mitsubishi Electric Corp | Earthquake-proof dry type transformer |
US5396210A (en) * | 1993-03-17 | 1995-03-07 | Square D Company | Dry-type transformer and method of manufacturing |
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EP1298680A2 (en) | 2001-09-28 | 2003-04-02 | Siemens Aktiengesellschaft | Electrical winding arrangement |
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CN201036129Y (en) * | 2007-04-26 | 2008-03-12 | 南京大全变压器有限公司 | Iron core assembly and coil compaction structure of amorphous alloy drying transformer |
CN201138599Y (en) * | 2007-11-30 | 2008-10-22 | 广东钜龙电力设备有限公司 | Novel amorphous alloy magnet core and dry type transformer |
-
2009
- 2009-04-11 ES ES09005285T patent/ES2404823T3/en active Active
- 2009-04-11 EP EP09005285.3A patent/EP2239745B1/en active Active
-
2010
- 2010-03-23 BR BRPI1010257-4A patent/BRPI1010257B1/en active IP Right Grant
- 2010-03-23 CA CA2758282A patent/CA2758282C/en active Active
- 2010-03-23 CN CN201080017086.9A patent/CN102388424B/en active Active
- 2010-03-23 KR KR1020117023776A patent/KR101695345B1/en active IP Right Grant
- 2010-03-23 WO PCT/EP2010/001796 patent/WO2010115516A1/en active Application Filing
-
2011
- 2011-09-29 US US13/248,645 patent/US8786390B2/en active Active
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DE2054567A1 (en) | 1970-11-06 | 1972-05-10 | Transformatorenunion Ag | transformer |
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JPS5666022A (en) | 1979-11-02 | 1981-06-04 | Hitachi Ltd | Molded transformer |
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International Search Report (PCT/ISA/210) issued on Jun. 29, 2010, by European Patent Office as the International Searching Authority for International Application No. PCT/EP2010/001796. |
Also Published As
Publication number | Publication date |
---|---|
ES2404823T3 (en) | 2013-05-29 |
CN102388424A (en) | 2012-03-21 |
CA2758282A1 (en) | 2010-10-14 |
EP2239745A1 (en) | 2010-10-13 |
US20120068800A1 (en) | 2012-03-22 |
CA2758282C (en) | 2016-01-26 |
WO2010115516A1 (en) | 2010-10-14 |
KR101695345B1 (en) | 2017-01-13 |
KR20110137353A (en) | 2011-12-22 |
EP2239745B1 (en) | 2013-04-10 |
BRPI1010257A2 (en) | 2016-03-22 |
BRPI1010257B1 (en) | 2019-07-02 |
CN102388424B (en) | 2015-05-20 |
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