US852142A - Explosive. - Google Patents
Explosive. Download PDFInfo
- Publication number
- US852142A US852142A US33408206A US1906334082A US852142A US 852142 A US852142 A US 852142A US 33408206 A US33408206 A US 33408206A US 1906334082 A US1906334082 A US 1906334082A US 852142 A US852142 A US 852142A
- Authority
- US
- United States
- Prior art keywords
- explosive
- tetranitrodiglycerin
- ordinary
- nitroglycerin
- soda
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002360 explosive Substances 0.000 title description 9
- SNIOPGDIGTZGOP-UHFFFAOYSA-N Nitroglycerin Chemical compound [O-][N+](=O)OCC(O[N+]([O-])=O)CO[N+]([O-])=O SNIOPGDIGTZGOP-UHFFFAOYSA-N 0.000 description 10
- 229960003711 glyceryl trinitrate Drugs 0.000 description 10
- SKKBQEZMHMDRLE-UHFFFAOYSA-N [1-(2,3-dinitrooxypropoxy)-3-nitrooxypropan-2-yl] nitrate Chemical compound [O-][N+](=O)OCC(O[N+]([O-])=O)COCC(O[N+]([O-])=O)CO[N+]([O-])=O SKKBQEZMHMDRLE-UHFFFAOYSA-N 0.000 description 8
- 239000000006 Nitroglycerin Substances 0.000 description 5
- 229920001131 Pulp (paper) Polymers 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229940105990 diglycerin Drugs 0.000 description 2
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000006396 nitration reaction Methods 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- DSEKYWAQQVUQTP-UHFFFAOYSA-N Cerin Natural products CC12CCC3(C)C4CC(C)(C)CCC4(C)CCC3(C)C2CCC2(C)C1CC(O)C(=O)C2C DSEKYWAQQVUQTP-UHFFFAOYSA-N 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/14—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase comprising a solid component and an aqueous phase
Definitions
- the invention consists ina practical application of my discoveryof the valuable qualities of .tetranitrodiglyc'erin as an explosive, and to this end the invention consists in other porous substance preferably associated both with trinitroglyce'rin and nitrate of soda by. the excellent and nitroglycerin are uti 'zed While its objectionable features are avoided.
- the 111-- or other inorganic-oxidizing agent when mixed with trinitroglycerin (ordinary nitroglycerin) it imparts to it a non-freezing quality and lessens its dangerous sens'itiveness.
- the invention consists ina practical application of my discoveryof the valuable qualities of .tetranitrodiglyc'erin as an explosive, and to this end the invention consists in other porous substance preferably associated both with trinitroglyce'rin and nitrate of soda by. the excellent and nitroglycerin are uti 'zed While its objectionable features are avoided.
- the tetranitrodiglycerin is. formed by the nitration of diglycerin, the process being substantially the same as the nitration of glycerin to form the ordinary trinitroglycerin.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Description
. tetranitroglycerin absorbed in Wood pulp or UNITED STATES PATENT orrion 'FIN-SPARRE, ,oF WILMINGTON, DELAWARE, ASsI NQR-To THE DUPONT DE NEMOURS POWDER COMPANY, oF ILMI T N, DELAWARE, A COR- .PORATIGN OF NEW JERSEY? EXPLOSIVE.
Specification of Letters Patent.
Patented, April 3o, 1 907.
Application filed September 11,1906. SeriaLNo. 384,082.
T all, whiu'rfiit may concern:
Be it known that I, FIN SPARRE, a subject of the King'ofNorway,
'also stable and comparatively insensitive. I
have also discovered that when mixed with trinitroglycerin (ordinary nitroglycerin) it imparts to it a non-freezing quality and lessens its dangerous sens'itiveness. The invention consists ina practical application of my discoveryof the valuable qualities of .tetranitrodiglyc'erin as an explosive, and to this end the invention consists in other porous substance preferably associated both with trinitroglyce'rin and nitrate of soda by. the excellent and nitroglycerin are uti 'zed While its objectionable features are avoided. The 111-- or other inorganic-oxidizing agent. The trinitroglycerin and the tetranitrodiglycerin, and mostly 'so the trinitroglycerin, eachperform the function of a blasting oil, while the tetranitrodiglycerin also performs the functions of .lowering'the freezing point of the mixture and rendering it less sensitive, whereprincipal trate of soda acts both as a dope and as a supplier of oxygen to more readilyeifect the combustion of the wood pulp. r The tetranitrodiglycerin is. formed by the nitration of diglycerin, the process being substantially the same as the nitration of glycerin to form the ordinary trinitroglycerin.
The following are examples of explosives containing te tranitro diglycerin:
I. 25%- ordinary nitroglycerin, 15% tetranitrodigl cerin, nitrate of soda, ]0%
Wood p p.
eculiar qualities of'trithis 7th day of Sept, 1906.
II 115% ordinary nitroglycerin l57j tetranitrodiglycerin, 3% sulfur, 2% rosin," nitrate of soda, 5%-wood pulp, 5%-sawdust.- III. 20% ordinary nitroglycerin, 10% tetra--- nitrodiglycerin, 3% collodian1cotton, 27.% ammonium nitrate, 30% nitrate-'-i offf soda,-
10% wood pulp.
v The ingredients are si in the ordinary way ern loyed the manufacture of dynamite, ya though,prefera bly, the tetranitrodiglycerin is first. Iifixe'dj with iy'jmixedtqge i the ordinary Intro-glycerin beforethe other ingredients are added. Having now fully described myinventlon,
what I claim and desire'to protect-byLetters Patent is:
. 1. An explosive containing .tetranitr di glycerin", an inorganic oxidizing 'agent anda porous substancesubstantially as described. i
2. An explosive containing tetranitrddiglycerin, trinitroglycerinand a porous substance in which the same are absorbed sub stantially as described.
3 An explosive containing ttranitrodiglycerin, trinitroglycerin, an inorganic oxi-' diz'ing agent and a porous carbonaceous substance substantially as described.
4. An explosive containingtrinitroglyce erin, tetranitrodiglycerin, nitrate of soda and-- wood pulp substantially as described.
5. An explosive substance containing .of
tetranitrodiglycerin 5 to 30 per cent, of tri-'- nitroglycerin-l0 to '45 per cent, of an inor ganic oxidizing agent 15 to 75 per cent. and of a porous carbonaceous substance 5'to 25 per cent.,, substantially as described.
In testimony of which invention,I -have hereunto set "my hand, at Wilmington, on
" FIN SPARRE.
Witnesses:
FRA K H. MAsoN, .S. M. MUN-DA.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US33408206A US852142A (en) | 1906-09-11 | 1906-09-11 | Explosive. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US33408206A US852142A (en) | 1906-09-11 | 1906-09-11 | Explosive. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US852142A true US852142A (en) | 1907-04-30 |
Family
ID=2920600
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US33408206A Expired - Lifetime US852142A (en) | 1906-09-11 | 1906-09-11 | Explosive. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US852142A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5403035A (en) * | 1992-06-01 | 1995-04-04 | Oea, Inc. | Preparing air bag vehicle restraint device having cellulose containing sheet propellant |
-
1906
- 1906-09-11 US US33408206A patent/US852142A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5403035A (en) * | 1992-06-01 | 1995-04-04 | Oea, Inc. | Preparing air bag vehicle restraint device having cellulose containing sheet propellant |
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